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1)
f̂il
i (10.89)
xi fil
that is a measure of the departure of the component behaviour
from an ideal solution.
leaving us with
y iP
i
x i Pisat
(10.97)
GE
xi ln i
With this information, they
RT cani generate model equations that
practicing engineers apply routinely.
yP
ln 1 ln 1 sat
x1P1
y P
ln 2 ln 2 sat
x 2P2
GE / RT x1 ln 1 x 2 ln 2
we find:
ln 1 Bx 22 and ln 2 Bx12
yP
ln 1 ln 1 sat
x1P1
y P
ln 2 ln 2 sat
x 2P2
GE / RT x1 ln 1 x 2 ln 2
therefore,
A12 ln 1 A 21 ln 2
and similarly
to yield:
ln 1 x 22 [ A12 2( A 21 A12 )x1]
(11.8ab)
ln 2 x12 [ A 21 2( A12 A 21)x 2 ]
where
V2 a V1 a (11.24)
12 exp 12 21 exp 21
V1 RT V2 RT
Vi is the molar volume at T of the pure component i.
aij is determined from experimental data.
12 21
ln 2 ln( x 2 x1 21) x1 (11.18)
x1 x 2 12 x 2 x1 21
Comparison of experimental
values with those obtained from
several equations whose
parameters are found from the
infinite-dilution activity
coefficients.
(1) Experimental data.
(2) Margules equation.
(3) van Laar equation.
(4) Scatchard-Hamer equation.
(5) Wilson equation.