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Bibliografía

[1] Thuy V. T., Cam L. L., Tien C. H., “Synthesis of MOF-199 and application to CO2 adsorption”,
Institute of Chemical Technology, Vietnam Academy of Science and Technology. XDR mof-199

[2] Oficina del alto comisionado para la paz, “tipos de minas”, tomado de
http://www.accioncontraminas.gov.co/accion/desminado/Paginas/Tipos-de-minas.aspx.

[3] Adina Morozan and Frederic Jaouen, “Metal organic frameworks for electrochemical
applications”, Energy and environmental science.

[4]Oficina del alto comisionado para la paz, Gobierno Nacional de Colombia,


http://www.accioncontraminas.gov.co/Paginas/AICMA.aspx. Consultado el 08/07/2019.

[5] Lantao Liu, Yanli Zhou, “The applications of metal-organic frameworks in Electrochemical
Sensors”, ChemPubSoc Europe, Chemelectro.

[6] Heather F. Greer, Yuehao Liu, “Synthesis and formation mechanism of textured MOF-5”, Crystal
Growth & Desing. 2016

[7] Zhong Lin Wang, “Nanostructures of zinc oxide”, materialsToday, junio 2004.

[8] Ming Cai, “Oxidation of zinc in alkaline Solutions studied by electrochemical impedance
spectroscopy”, journal of the electrochemical society, julio de 1995.

[9] Qing Min Wang, “Metallo-organic molecular sieve for gas separation and purification”
ScienceDirect, septiembre 2002.

[10] M. Thirumoorthi, “Structure, optical and electrical properties of indium tin oxide ultra thin
films prepared by jet nebulizer spray pyrolysis technique”, journal of asian ceramic societies.

[11] Morales U., López V., “BASIC ASPECTS IN THE INTERPRETATION OF THE DIAGRAMS OF
ELECTOCHEMICAL IMPEDANCE”. DYNA, 30 noviembre, 2009.

[12] “Common equivalent circuits models”, Gamry Instruments.

[13] ChangHoon Lim, “Transport Phenomena, Lecture 20: Warburg Impedance”. MIT
OpenCourseWare, Electrochemical energy systems. 2014

[14] Li-Long Jiang, “Rapid electrochemical synthesis of HKUST-1 on indium tin oxide”, Royal society
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[15] H.‐D. Speckmann, “The growth and reduction of duplex oxide films on copper”, Wiley online
library, abril 1985.

[16] “Standard electrode potentials”, tomado de


https://chem.libretexts.org/Courses/Mount_Royal_University/Chem_1202/Unit_6%3A_Electroche
mistry/6.2%3A_Standard_Electrode_Potentials, recuperado el 15 julio 2019.

[17] Hui-min YANG, “In situ electrochemical synthesis of MOF-5 and its application in improving
photocatalytic activity of BiOBr”, College of Chemistry and Chemical Engineering, Taiyuan
University of Technology. 2015.
[18] Scott T. Meek, Jeffery A. Greathouse, “Metal‐Organic Frameworks: A Rapidly Growing Class of
Versatile Nanoporous Materials”, 2004.

[19] Jesse L.C., “Metal-organic frameworks: a new class of porous materials”, 2004, 3-14.

[20] Armarego, W. L. F.; Chai, C. L. L., Purification of Laboratory Chemicals (5th Edition). Elsevier:
2003.

[21] Tatiana R. C., “Síntesis y caracterización de redes metal-orgánicas (MOF) a partir de ligantes
orgánicos tipo fenilenvinileno modificados con grupos electrodonores”, universidad nacional de
Colombia, 2014.

[22] Minyuan Miller L., “Cathodic Electrodeposition of Metal-Organic Frameworks”, 2015.

[23] Omar Y., “H2S sensors: fumarate-based fcu-MOF thin film grown on a capacitive interdigitated
electrode”, 2016.

[24] Lizi, yang, Cailing xu., “An electrochemical sensor for H2O2 based on a new Co-metal-
organic framework modified electrode”, 2015.

[25] Chung-wei kung, “Porphyrin-based metal–organic framework thin films for


electrochemical nitrite detection”, 2015.

[26] Xuan Zhang, “Ultrasensitive binder-free glucose sensors based on the pyrolysis of in
situ grown Cu MOF”, 2018.

[27] Hadi H., Hamid A., “Au-SH-SiO2 nanoparticles supported on metal-organic framework
(Au-SH-SiO2@Cu-MOF) as a sensor for electrocatalytic oxidation and determination of
hydrazine”. 2013

[28] Hanan Al-kutubi, “Electrosynthesis of Metal–Organic Frameworks: Challenges and


Opportunities”, 2015.

[29] U. Meller, M. Schubert, “Metal-organic frameworks-prospective industrial


applications”, 2005

[30] Hong-Cai Z., “Introduction to metal-organic frameworks”, 2012, 673-674.

[31] Ilaria C., Mary P., “Electrophoretic deposition: From traditional ceramics to
nanotechnology”, 2008.

[32] Darren B., Ashesh G., “Metal–organic framework growth at functional interfaces: thin
films and composites for diverse applications”. 2011
TABLA DE CONTENIDO
Pág.

RESUMEN
LISTA DE FIGURAS
LISTA DE TABLAS
INTRODUCCIÓN
IDENTIFICACIÓN DEL PROBLEMA
OBJETIVOS
OBJETIVO GENERAL
OBJETIVOS ESPECÍFICOS
1 ESTADO DEL ARTE
1.1 Redes metal-orgánicas
1.2 Caracterización de MOFs
1.3 Síntesis por vía electroquímica
1.3.1 Electrosíntesis directa
1.3.2 Electrosíntesis indirecta
1.4 Sensores basaos en redes metal-orgánicas
2 MATERIALES Y MÉTODOS
2.1 Disolventes
2.2 Electrodos
2.3 Reactivos
2.4 Instrumentación
2.4.1 Proceso de síntesis, Voltamperometrías cíclicas y EIS
2.4.2 Difracción de rayos X
2.4.3 Microscopía electrónica de barrido (SEM)
3 SÍNTESIS DE LAS PELÍCULAS DE MOF
3.1 Síntesis de la película del MOF-199
3.2 Síntesis de la película del MOF-5

4 CARACTERIZACIÓN DE LAS PELÍICULAS DE MOF


4.1 Microscopia electrónica de barrido (SEM)
4.2 Difracción de rayox X
4.2.1 MOF-199
4.2.2 MOF-5
4.3 Perfilometría
4.4 Espectroscopia de impedancia electroquímica
5 EVALUACIÓN DE LA PELÍCULA DEL MOF-199 EN LA DETECCIÓN DE AMONIACO
5.1 Blancos
5.2 Rango de concentraciones más bajo
5.3 Rango de concentraciones más alto
6 CONCLUSIONES
BIBLIOGRAFÍA

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