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2.1. INTRODUCTION
There are several types of absober depend on the criteria and economic factors. The
type absorbers that are used in the industries are trayed or plated tower, packed column,
spray tower and bubble column and centrifugal contractor [3].
Plated and packed column are favourable compared to other absorbers in the
industry [3]. Spray, bubble and centrifugal contactor were not chosen as spray column only
has one or two stages, which means the contact between gas mixture and liquid will be
limited. Meanwhile, bubble column was not preferred as it has low vapor throughput and
only efficient for solute which has low solubility in liquid and centrifugal contractor was not
chosen due to space limitations [3].
On the other hand, packed column is more favourable compared to plated column.
Packed tower is chosen over plated tower due to low cost over plated column, and easy for
replacement and storage. It is affordable because the tower diameter is not too large and
make it relatively cheaper construction and material. Moreover, corrosive gases like ethanol
are more suitable for packed tower as the packing can be made from ceramics. The required
pressure drop in packed tower also is less than the plate column [4].
Below is the assumptions which are applied to design the packed tower.
1) Steady state
2)
3)
The absorber was designed to obtain the residue of ethanol from the stream 9 by
washing it with the supply of water. The remaining ethylene in stream 13 will be recycle
back into the reactor together with the small amount of water and ethanol. Below is the
diagram, data inlet and outlet of absorber and calculation of the column diameter.
Stream 13
Stream 12
T-201
Stream 9
Stream 14
Stream 9
Component Moles flow M Mass flow Xi
Water - 18.015 - -
Ethylene 27.33 28.05 766.61 0.9063
ethanol 1.71 46.07 78.78 0.0931
Total 29.05 845.9 1
Stream 12
Component Moles flow M Mass flow Xi
Water 18.90 18.015 340.48 1
Ethylene - 28.05 - -
ethanol - 46.07 - -
Total 11.89 340.48 1
Stream 13
Component Moles flow M Mass flow Xi
Water 0.9 18.015 16.21 0.0206
Ethylene 27.33 28.05 766.60 0.9748
ethanol 0.07 46.07 3.225 0.0041
Total 28.31 786.4 1
Stream 14
Component Moles flow M Mass flow Xi
Water 10.9881 18.015 197.95 0.7235
Ethylene 0.00126 28.05 0.0353 0.00013
ethanol 1.641 46.07 75.6 0.2763
Total 12.63 273.5861 1
To determine the column diameter, the first step is to calculate the average molecular
weight for the inlet gas at stream 9.
Am wi , gas =∑ x i y i (2.1.)
kg kg
¿
[( ) ] [ ( ) ] [
27.33
29.05
h
kg
h
x 28.05
kg
kmol
+
1.71
29.05
h
kg
h
x 46.07
kg
kmol
+ ( 0 ) x 18.015
kg
kmol ]
kg
¿ 29.1017
kmol
Critical temperature and pressure will be determined and needed for prediction correlate
physical properties with the reduced conditions [6]. In this case, the values are needed to
determine density for gas mixture. Thus, the density for liquid and gas mixture can be
determined. Table xx indicate the critical values for both temperature and pressure of
ethylene and ethanol by using Perry’s Chemical Engineering Handbbok 8 th Edition as the
source [7].
The critical value in the Table xx will be used to obtain the compressibility factor, z which
will be determined from a generalized compressibility plot. The compressibility graph was
included in Figure xx (Appendix xx).
Pc ,m of gas
Pc .m =∑ Pc , j y i (2.2)
¯ )) + ( 81.39 ( 0.0931
¿ [ ( 50.40 ( 0.9063 ¯ ) )]
¿ 53.25 ¯¿
T c ,m of gas
T c. m=∑ T c , j y i (2.3)
¿ [ ( 282.3 K ( 0.9063 ) ) + ( 512.64 K ( 0.0931 ) ) ]
¿ 318.82 K
Pr of gas
P
Pr = (2.4)
Pc . m
5
¿
53.25
¿ 0.0939
T r of gas
T
T r= (2.5)
T c. m
323.15
¿
318.82
¿ 1.014
Based on the compressibility chart in Figure xx (Appendix B) and the obtained value of Pr
and T r, the value of compressibility factor, z is 0.28. Thus, the specific volume of inlet gas,
with the value of R, R=8.314 x 10−5 m 3 . .̄ K −1 . mol−1 :
V RT
n
=Z
P ( ) (2.6)
The density of gas mixture, ρ v at the inlet stream 10 in the absorber is:
Amw i ,gas
ρ v=
V (2.7)
n
kg
29.1017
kmol
¿
m3
1.5045
kmol
kg
¿ 19.3431
m3
kg
The density, ρ L of water inlet at stream 15 is 997 . Based on P. Kiselev et., the viscosity, µL of
m3
water at 30°C is 0.7978 x 10−3 kg .m −1 . s−1 .
All of the properties have been acquired, therefore the calculation diameter of column shall
be proceeded.
L∗w ρv
F LV =
V ∗w √ ρL
(2.8)
kg kg
√
0.0595 19.3431
s m3
¿
kg kg
0.2350 997 3
s m
¿ 0.0353
Based on Coulson and Richardson, the recommended design value for pressure drop, which
is mm water per m packing for absorber are 15 to 50 (Coulson & Richardson’s, 1999) . Thus,
42 mm H 2 O
is chosen as the design value for pressure drop. Based on the Figure xx
m
(Appendix xx), K4 value is 1.7 and the flooding line is 5.6. Therefore, the percentage flooding
is:
1.7
Percentage flooding=
√ 5.6
x 100 %
¿55.09%
The percentage flooding is 55.09% which is satisfactory because the packed towers normally
operated at a gas velocity of 50-80% of flooding conditions *reference kat cek 5*. To
¿
determine column area, the gas mass flow rate per unit column cross sectional area, V w
must be calculated first. The formula is rearranged from the function of K 4. Since, Pall rings
metal are used, F p from the appendix is 52m-1.
0.1
µL
K4=
13.1 ( V
¿ 2
w) Fp ( )
ρL (2.9)
ρV ( ρL −ρV )
0.5
K 4 ρV ( ρL −ρV )
[ ]
¿
V =
w 0.1
µL
13.1 F p
( )
ρL
0.5
kg kg
[ ]
1.7 x(19.3431
3
)( 997−19.3431 ) 3
m m
¿
kg 0.1
0.797 x 10−3
13.1( 230 m−1 )
(
kg
997 3
m
m. s
)
kg
¿ 6.591 2
m s
kg
0.2350
s
¿
kg
6.591 2
m s
¿ 0.0357 m2
π
Area= D 2 (2.11)
4
4
D=
√ π
¿)
¿ 0.2132 m
π
Area= (0.25)2
4
Area=0.049 m2
The chosen design value for the size of Pall rings is 16mm. Thus, the packing size to column
diameter ratio is:
0.25
Packing ¿ column diameter ratio= =15.625
16 x 10−3
The ratio of diameter of the tower to the packing is satisfactory because based on *cek 6*
the minimum value is 15.
Lastly is to find the percentage flooding which then will be used to determine the column
height. Percentage flooding at the selected diameter:
0.0357 m 2
Percentage flooding= x 55.09 %=40.14 %
0.049 m 2
The methods used for calculation of column height based on Cornell’s method. Both
methods will be compared and tested, and the most appropriate height will be taken as the
height of the column.
[(
y ethylene . M ethylene
µethylene )(+
y ethanol . M ethanol
µ ethanol ) ]
×0.001
(2.12)
29.1017
¿
[( 0.9063 ×28.05
0.01 06 )(
+
0.0931× 46.07
0.983 ) ] × 0.001=1.2112 x 10−5 Pa . s
The equation to estimate diffusion coefficient of gases was developed by Fuller et al. (1996),
while the equation liquid diffusivity was developed by Wilke and Chang (1955). Both
equations were used throughout design to determine height of the column reference kat
buku coulsonn.
1
1 1
Dv =
1.013 x 10−7 T 1.75 ( +
Ma Mb ) 2
(2.13)
1 1 2
P
[( ∑
a
vi +
) (∑ v ) ]
3
b
i
3
Where the ∑ vi and ∑ vi are the summation of the special volume coefficients for
a b
component of a and b which are ethanol and ethylene respectively. The values were
obtained in the table in the Appendix .
∑ v i=[ ( 16.5 x 2 ) + ( 6 x 1.98 )+ (5.48 ) ]=50.3 6
a
Thus, D v is
1
1.75 1 1
( )
−7
1.013 x 10 x 323.15 K + 2
kg kg
28.05 46.07
kmol kmol
Dv = 2
¯ 1 1
[
5 ( 50.36 ) + ( 40.92 ) 3
3
]
2
−6 m
¿ 2.3450 x 10
s
Where all of these data were obtained from Coulson & Richardson’s, Chemical Engineering,
Volume 6)
HOG is expected to be around 1m, thus, as the first estimation, z value can be taken as 2.
µL
( Sc ) L = (2.15)
ρL DL
0.001
( Sc ) L =
997 × 7.1399 x 10−6
¿ 0.14 05
µv
( Sc ) v = (2.16)
ρv D v
1.2112 x 10−5
( Sc ) v =
19.3431 ×2.3450 x 10−6
¿ 0.2671
2
0.5
H L=0.305 ( 0.045 ) ( 0.145 ) 0.99 ( )
3.05
H L=0.0049m
As the liquid temperature has been taken as 30˚C and the liquid is water, thus, f1 = f2 = f3 = 1
¿ 0.1727 m
2.2.2.3.3. The Overall Gas Phase Transfer Unit and Individual Film Transfer
Unit
H OG=H G + K 4 + H L
¿ 0.1727+1.7+ 0.0049
¿ 1.878 m
Z=Z estimated × H OG
¿ 2 ×1.878
¿ 3.756 m
Round off to 4m
4
N OG = =2.1299
1.878
1
N OG =ln
1−eff
e ff =88.11 %
The purpose of the support plate is to bear the weight of the wet packing, while allowing
the gas and liquid to flow freely. *reference buku coulson*
In the system absorber, the operating pressure and temperature are as follow:
Operating Temperature = 323.13K
Operating Pressure = 5 bar
The minimum thickness value will be added with corrosion allowance, 0.417 + 2 =
2.417mm.
Round up to 3mm.
2.3.2. Analysis of Head Closure Thickness
Pi Rc C s
e= (2.20)
2. f . J + P i ( C s−0.2 )
P i Di
e= (2.21)
2. J . f −0.2 Pi
0.55× 250
e= =0.4168 mm
2× 165−( 0.2× 0.55 )
H v = Height or length between tangent line of the vessel, the estimated value
is 3m.
Volume of insulation,
V i=π D i H v ×t i (2.23)
¿ π (0.25)(3)(75 x 10−3 )
¿ 0.1767 m 3
Weight of insulation, W i =V i ρg
¿ 0.1767 ×130 × 9.81
¿ 0.2 251 kN
The value is doubled to allow fitting = 0.4502kN
¿ 0.25+2 ( 0.012+0.075 )
¿ 0.424 m
¿ 1280 ×0.42 4
¿ 542.72 N /m
P Di
Longitudinal stress , σ h= (2.27)
2t
0.55× 250
σ h=
2( 12)
¿ 5.7292 N /mm2
P Di
Circumferential stress , σ L = (2.28)
4t
0.55× 250
σ L=
4 (12)
¿ 2.8646 N /mm2
M x Di
Bending stress , σ b =±
Iv 2 ( )
+t (2.30)
Where,
π
I v= ( D 4o −D 4i )
64
π
I v=
64
( [ Di +2 t ]4−D4i )
π 4 4
I v = ( [ 250+2(12) ] −250❑ )
64
¿ 8.4929 x 107 mm 4
2.4422 x 106 250
σ b=±
8.4929 x 10 7 2 (
+12 )
¿ 3.94 N /mm2
12
¿ ( 2 x 10 4 )
274
¿ 875.91 N /mm2
On the skirt, the maximum dead weight load should occur when the vessel is full of
the liquid.
2.3.5.5. Dead weight in the skirt as vessel full of water for the hydraulic test.
W tot
σ ws= (2.35)
π ( D s +t s ) t s
3093
¿
π ( 250+12 ) 12
¿ 0.3131 N /mm2
In the estimating total weight, the weight of liquid on the plates has been
counted twice. The weight has not been adjusted to allow for this as the
error is small and the safe side.
ts
σ^s (compressive) ≯ 0.125 E sinθ (2.38)
Ds
( 12 )
16.1279 N /mm2 ≯ 0. 123 ( 200000 ) sin 9 0
250
16.1279 N /mm2 ≯ 1 180.8
Both criteria are satisfied, add 2mm for corrosion, this give thickness value of
16mm.
The number of bolts used will be 8. Since the minimum bolt pinch is less than
600mm, a conical skirt should be used. Based on Coulson, bolt design value is
125N/mm2
1 4 ×9769
Ab =
8× 125 [ 0.45
−3065 ]
¿ 83.77 mm2
2.3.6.4. Hgfdr
2.3.6.5. hjfs