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PARTICULATES TECHNOLOGY
Introduction
Solids, in general are more difficult to handle than liquids or gases. In processing, solids appear in a variety
of forms- angular pieces, continuous sheets, finely divided powders. They may be hard and abrasive, tough and
rubbery, soft or fragile, dusty, cohesive, free flowing or sticky. Whatever their form, means must be found to
manipulate the solids as they occur and, if possible, to improve their handling characteristics.
Of all the shapes and sizes that may be found in solids, the most important from a chemical engineering
standpoint is the small particle.
Properties of Solids
1. True (particle) density – usually expressed by the symbol, ρ, is defined as the mass per unit volume
ρ= mass of the particle / volume of the particle
2. Bulk (or apparent) density, ρB –is the total mass per total unit volume. It is not an intrinsic characteristic of a
material since it varies with the size distribution of the particles and their environment. The porosity of the
solid itself influence the bulk density. For a single non- porous particle, the true density equals the bulk
density.
Bulk density = total mass of material/ total volume of material
Volume of material = vol. of particles + vol of voids
3. Specific gravity- ratio of density of the material to the density of a reference substance
4. Hardness – for certain solids such as metals and plastics, may be defined as resistance to indentation. The
hardness of minerals is defined as resistance to scratching and is usually expressed in terms of the Mohs’
Scale.
5. Brittleness or friability- refers to the ease with which a substance may be broken by impact
6. Toughness – is the property of metals and alloys called impact resistance. Friability is the inverse quality to
toughness
7. Friction – is the resistance to sliding of one material to another material
2. Particle Shape – expressed in terms of sphericity, Φs, which is independent of particle size.
Φs = ( surface area of sphere of same volume as the particle) / (surface area of the particle)
Φs = (6vp) / ( DpSp),
where Dp= equivalent diameter of particle; Sp= surface area of one particle; vp= volume of one particle
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[CHE 511A: SEPARATION PROCESSES AND INTRODUCTION TO PARTICLE TECHNOLOGY]
• Equivalent diameter is sometimes defined as the diameter of a sphere of equal volume. For crushed
materials, Φs is between 0.6 and 0.8 but for particles rounded by abrasion, it may be as high as 0.95.
3. Density
Methods in determining particle Size
1. Microscope 5. Centrifugation
2. Screening 6. Magnetic Methods
3. Sedimentation 7. Optical Methods
4. Elutriation
SCREENING
- A unit operation where a mixture of various sizes of particles is separated into two or more portions, each of
which is more uniform in particle size than the original mixture by allowing the material to pass over a
surface provided with openings of the desired size
Dry screening – this refers to the treatment of a material containing a natural amount of moisture or a material that
has been dried before screening
Wet Screening – this refers to an operation where water is added to the material being treated for the purpose of
washing and facilitating the passage of the fine material through the screen.
Importance of Screening
1. It is a means of preparing a product for sale or for subsequent operation
2. It is a means of analysis, either to control or gage the effectiveness of another operation such as crushing or
grinding.
3. It can determine the value of a product for some specific application
Methods of Indication Particle Size Distribution
In making an analysis, a set of standard screens are nested together with the coarsest (lowest mesh no., usually 3
mesh) at the top and the finest (highest mesh no. usually 200 mesh) at the bottom. The sample is placed on the top
screen and the stack is shaken mechanically. The particles retained on each screen are removed and weighed and
the masses are converted to mass fractions.
Ways of Expressing Size Fractions (increments)
1st method 2nd method 3rd method Dpi
4 Mesh On 4 mesh +4 +4
Thru 4 mesh
6 mesh on 6 mesh -4+6 4/6 (Dpi (4 mesh) + Dpi (6 mesh)) /2
Thru 6 mesh
8 mesh On 8 mesh -6+8 6/8 (Dpi (6 mesh) + Dpi (8 mesh)) /2]
Screen Analyses
Testing sieves – these are used for particulate size control and analytical work. The screens are constructed
of wire mesh cloth, where the diameters of the wire and the spacing of the wires are specified
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Screen Aperture – clear space between the individual wires of the screen
Mesh– number of apertures per linear inch
Example: A 10-mesh screen will have openings per inch and the aperture will be 0.1 inch minus the
diameter of the wire.
Screen Interval –relationship between the successive sizes of screen openings in a series.
Types of Testing Sieves
1. Tyler Standard Sieve Series – this series of screens is based upon a 200 mesh screen with wire 0.0021 in
thick and with an opening of 0.0029 in. The other sizes vary by a fixed ratio of √2 or an area twice that of the
next screen. The mesh number is only up to 400
2. United States Sieve Series – introduced by the National Bureau of Standards differ slightly from the Tyler
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series being based on a 1-mm opening and varying by √2
3. International Test Sieve Series – similar to both but the wires heave different gauges.
Methods of Reporting Screen analysis
1. Differential Screen Analysis or Fractional Plot
2. Cumulative Analysis or Cumulative Plot
Effectiveness of Screens
Let x = mass fraction of the desired material
F = mass of feed
P = mass of product or undersize
R = mass of oversize
Recovery = (Pxp) / (FxF)
𝑃𝑃�1−𝑥𝑥 𝑝𝑝 �
Rejection = 1- recovery of Undesired Material = 1 −
𝐹𝐹(1−𝑥𝑥 𝐹𝐹 )
𝑃𝑃𝑥𝑥 𝑝𝑝 𝑃𝑃�1−𝑥𝑥 𝑝𝑝 �
Effectiveness = Recovery x Rejection, E = �1 − �
𝐹𝐹𝑥𝑥 𝐹𝐹 𝐹𝐹(1−𝑥𝑥 𝐹𝐹 )
Sample Problem:
It is desired to separate a mixture of sugar crystals into two fractions, a coarse fraction retained on an 8-mesh
screen, and a fine fraction into passing through it. Screen analysis of feed, coarse and fine fractions show
Mass fraction of +8 particles in feed =0.46
Mass fraction of +8 particles in coarse material = 0.88
Mass fraction of +8 particles in fine material = 0.32
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[CHE 511A: SEPARATION PROCESSES AND INTRODUCTION TO PARTICLE TECHNOLOGY]
SIZE REDUCTION
- Size reduction involves the production of smaller mass units from larger mass units of the same material.
Application of pressure on the larger solids is required to cause a fracture to take place. Fracture can be
caused by compressive loads because of the irregularity of the orientation of crystals of the solid matter.
Equipment for size reduction uses compression of shear or both as the disrupting force.
Objectives of Size Reduction
1. To meet the desired product specification (size, shape, number)
2. To increase reactivity of solids (i.e. increase surface availability)
3. To permit separation of unwanted components by mechanical methods
4. For easier handling and waste disposal
Comminution
- Is the generic term for size reduction. Solids may be broken in many different ways, but only four are
commonly used in size reduction machines.
1. Compression 2. Impact 3. Attrition 4. Cutting
Power Requirements for Size Reduction
Although it is impossible to estimate accurately the amount of energy required in order to effect a size reduction of a
given material, a number of empirical laws have been proposed. The two earliest are due to Kick (1885) and Von
Rittinger (1867) and a third law due to Bond (1952) has also been proposed.
1. Rittinger’s Law – which states that “ the work required in crushing is proportional to the new surface created”
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2. Bond’s Crushing Law – which states that “the work required to form particles of size Dp from very large feed
is proportional to the square root of the surface to volume ratio of the product”
3. Kick’s Law – states that “energy required for crushing is proportional to the leg of the initial and final
diameters”
** equations on handbook
Sample Problem
1. In crushing a certain ore, the feed is such that 80% is less than 50.8 mm in size and the product size is such
that 80% is less than 6.35 mm. The power required is 89.5 kW. Based on the Bond equation the power
required using the same feed so that 80% is less than 3.18 mm is? (ans: 146.7 kW)
2. A material is crushed in a Blake Jaw Crusher and the average size of particles reduced from 50 mm to 10
mm with the consumption of energy at the rate of 13 kW/kg.s. What is the energy consumption needed to
crush the same material of an average size 75 mm to an average size 25mm assuming (a) Kick’s Law
applies (b) Rittinger’s Law applies ? (ans 8.88 kW/kg.s)
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HANDLING OF SOLIDS
- Handling of materials deals with their movement over relatively short distances
Types:
1. Unassisted manpower – involves movement of materials over short distances, usually not exceeding 10 ft,
and only when the quantity does not exceed 4 to 5 tons (ex. Shovelling, pushing, carrying, lifting)
2. Assisted manpower – recommended when the radius of work is increases to 100 to 200 ft to lift loads
weighing more than 100 to 150 lbs, various mechanical devices are employed to amplify the force exerted
by the workman
Factors to consider in materials handling: (3M’s)
1. Material – it pertains to the characteristics of the material, physical as well as chemical, and its quantity. It
practically answers the question “WHAT”
2. Movement – it indicates the scope of movement, the distance that must be covered from source to
destination, the frequency of transfer, the speed or rate and the type of route involved. Answers the question
“WHERE” and “WHEN”
3. Method – it pertains to the choice of manpower (assisted or unassisted), shoice of an appropriate device or
equipment to be used.
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Angle of slide – is the angle of minimum slope measured from the horizontal at which any loose material will
flow
Angle of repose – is the angle of maximum slope measured from the horizontal at which a heap of loose
material will stand without sliding
MECHANICAL CONVEYOR
- Mechanical conveyors may move materials by a scraping action or by a carrying action
A. Scrapers
1. Screw or Helical Flight conveyors
- Consists of a steel shaft having a spiral or helical fin fastened to the shaft in a trough without touching the
trough
- The material is mixed as it passes through the conveyor
- Used to handle a wide range such as grain, asphalt, crushed coal, ashes, gravel and sand
Ribbon conveyor – a special type of screw conveyor I which the center portion of the helical fin is absent.
Suitable for sticky or gummy liquids
Advantages:
- Economical
- Mixing of materials is facilitated
- Casing can easily be sealed from outside atmosphere
- Casing can be designed with a drop bottom
Disadvantages:
- Hanger bearings supporting the blade can prevent the passage of materials along the trough (level of
materials should be below the hanger)
- It can contaminate materials
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[CHE 511A: SEPARATION PROCESSES AND INTRODUCTION TO PARTICLE TECHNOLOGY]
Problem
A screw conveyor is to be installed to convey 800 bushels of wheat per hour over a distance of 80 ft. Determine the
size (diameter), speed(rpm) and the horsepower requirements for the installation. (1 bushel= 1.2444 ft3)
2. Flight Conveyors
- Consists of one or two endless chains passing though a trough or a set of guides
- Are widely used for loose material that is non-abrasive (grain, food waste, garbage and coal) but they are
not suitable for friable abrasive materials such as clinker, gravel or crushed ore
Advantages:
- Simplest and cheapest of all conveyors
- May be operated in steeper inclines than belt conveyors
- Can handle large pieces
Disadvantages:
- High power requirement
- Heavy repair needed
- Short distance only
Capacities of flight conveyors (80% efficiency only) may be estimated from the following formula
𝐵𝐵𝐵𝐵𝐵𝐵𝜌𝜌𝑏𝑏
𝑇𝑇 =
6000
where: T= tons/hr; B= width of flight (in.); D= depth of flight (in.); S= speed of conveyor (fpm); ρb= bulk density of
material (lb/ft3)
The horsepower required to drive flight conveyors may be estimated
𝑎𝑎𝑎𝑎𝑎𝑎 + 𝑏𝑏𝑏𝑏𝑏𝑏𝑏𝑏 + 10𝐿𝐿
𝐻𝐻𝐻𝐻𝐻𝐻𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 =
1000
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[CHE 511A: SEPARATION PROCESSES AND INTRODUCTION TO PARTICLE TECHNOLOGY]
Where: T=capacity (tons/hr); L= length, ft; W= total weight (lb) of chain and flights per foot of distance between
centers; S= speed, fpm; a,b= constants from table 14(Unit Operations by George Brown)
Power Constants for Flight Conveyors
Inclination w/ Horizontal 0° 5° 10° 15° 20° 25° 30° 35° 40° 45°
Anthracite 0.343 0.42 0.50 0.586 0.66 0.73 0.79 0.85 0.90 0.945
a Bituminous 0.60 0.69 0.76 0.83 0.88 0.95 1.02 1.08 1.13 1.15
Ashes 0.54 0.62 0.72 0.80 0.85 0.90 0.97 1.03 1.06 1.10
Flights & chain
supported on blocks
0.03 0.03 0.03 0.029 0.028 0.027 0.026 0.025 0.023 0.020
w/c slide directly on the
b
track
Flights supported by 3
0.004 0.004 0.004 0.004 0.004 0.004 0.003 0.003 0.003 0.003
½ -in rollers
B. Carriers
1. Belt Conveyors
- Consist of endless belts, suitably supported and driven, which carry or transport solids from place to place
- Are adapted to wide varieties and quantities of materials, require relatively low power, and can transport
solids for long distances
- Solids can be transported horizontally or inclined up to an angle of 30° only
Power requirements for belt conveyors involve a nu,ber of variables and may be estimated by means if empirical
formulas such as the following
𝐹𝐹(𝐿𝐿+𝐿𝐿𝑜𝑜 )(0.03𝑊𝑊𝑊𝑊)
For empty belt conveyor: 𝐻𝐻𝐻𝐻 =
990
𝐹𝐹(𝐿𝐿+𝐿𝐿𝑜𝑜 )(𝑇𝑇)
For material (excluding belt) conveyed horizontally: 𝐻𝐻𝐻𝐻 =
990
𝑇𝑇∆𝑍𝑍
For elevating material (excluding belt which balances itself): 𝐻𝐻𝐻𝐻 = (negative when material travel downward)
990
𝐹𝐹(𝐿𝐿+𝐿𝐿𝑜𝑜 )(𝑇𝑇+0.03𝑊𝑊𝑊𝑊)+𝑇𝑇∆𝑍𝑍
Total Horsepower Requirement: 𝐻𝐻𝐻𝐻 =
990
Where:
F= friction factor = 0.05 (for plain bearings); 0.03 (for anti-friction bearings) L= length of conveyor b/n pulleys, ft
Lo= 100 (for plain bearings); 150 ( for anti-friction bearings) S= speed of belt (fpm)
ΔZ= increase in elevation of material (ft) T= amount of material (tons/hr)
W= mass (lb) of moving parts including belt and idlers per foot of distance
between centers of terminal pulleys(both runs)
2. Bucket Elevators
- Simplest and most dependable unit for vertical or lifting movement of solids
- Consists of a series of buckets carried either on chains or belts
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[CHE 511A: SEPARATION PROCESSES AND INTRODUCTION TO PARTICLE TECHNOLOGY]
Types:
a. Spaced- Bucket Centrifugal Discharge Elevator
b. Spaced- Bucket Positive- Discharge Elevator
c. Continuous discharge Bucket Elevators
d. Supercapacity Continuous Bucket elevators
Types of Buckets
a. Minneapolis Type – for grain and other dry, pulverized material
b. Flatter buckets – for wet or sticky materials
c. Stamped- steel bucket – for large lumps and heavy materials
2𝑇𝑇∆𝑍𝑍
Power Requirement: 𝐻𝐻𝐻𝐻 =
1000
where: T= elevator capacity (tons/hr); ΔZ= elevator height + 5ft (correction for satisfactory loading)
3. Apron Conveyors
- Similar to belt conveyors since solids are also moving by a moving trough
- Series of pans( either wood or steel) mounted between two strands of roller chains, wherein the pans are
overlapping to eliminate leaking during transit and upon discharge over sprockets located at the end of the
conveyor
- Can be used for both horizontal and inclined travel
- Used for lumpy, abrasive, or hot materials that can decrease life span of belt
𝑅𝑅𝑡𝑡 𝑆𝑆
Power Requirement: 𝐻𝐻𝐻𝐻 =
33000
where Rt= turning resistance; ΔZ= elevator height
Problems:
1. One hundred tons per hour of anthracite coal are to be moved horizontally a distance of 120 ft. Select a
conveyor of each of the three classes listed, and calculate the power required to operate the system. Choose the
smallest conveyor that will do the job. Assume a bulk density of 60 lb/ft3.
a. Screw conveyor b. Flight conveyor c. Belt conveyor
2. A screw conveyor is to be installed to convey 800 bushels of wheat per hour over a distance of 80 ft. Determine
the size (diameter), speed (rpm) and the horsepower requirements for the installation. (1 bushel= 1.2444ft3)
3. A belt conveyor is required to deliver crushed limestone having a bulk density of 75 lb/ft3 at the rate of 2000 tons
per hour. The conveyor is to be 200 ft between centers of pulleys with a rise of 25 ft. The largest lumps are 4 in.
and constitute 15% of the total. The conveyor will discharge over the end. For a belt speed of 200 fpm, what is
the minimum width of belt that can be used? Calculate the horsepower for the drive motor.
4. For the conditions in no.3, specify the type of conveyor and the size that will require the minimum power.
5. What is the capacity of a flight conveyor of 12 by 24 in travelling at 100 fpm and handling the crushed limestone
in problem 2?
6. A belt conveyor is required to deliver gravel at a rate of 175 tons/hr. The conveyor is to be 180ft between centers
if pulleys with a rise of 18 ft and discharge over the end. Choose the smallest conveyor that will do the job and
calculate the power required to operate the system. Compare using plain bearings and anti-friction bearings.
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