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Mr = 24 + 32 + 4(16) = 120
Percentage Composition
Eg. Determine which oxides of iron of Fe2O3 or Fe3O4 has more iron.
Solution
Percentage of Fe in Fe2O3
=
x 100 %
= (2 x 56)/160 x 100%
= 70%
x 200g
= (2 x 56)/160 x 200g
= 140g
Eg. Calculate water mass in 12.5g hydrated copper sulfate, CuSO 4.5H2O
x mass of sample
= (5 x 18)/250 x 12.5g
= 4.5g
Mole
Counting Particles
= 5 mol
Eg 2: Calculate the number of molecules in 0.25 mole of CO2. Hence, how many atoms
are present?
Molar mass
n = m / Mr
m = n x Mr
m = 0.4 x 56 = 22.4 g
Eg. Argon Fluorohydride gas, HArF, first known noble gas compound, has molar mass of
60g. Find the number of moles Argon atom in 6.66g of HArF.
n (HArF) = 6.66/60
= 0.111 mol
Molecular Formula – shows the actual formula and kinds of atoms present, e.g. C 2H6
Empirical Formula – shows the simplest whole number ratio of the atoms present, e.g.
C2H6, ratio 1:3, therefore C1H3, simply CH3
Structural Formula – shows how atoms are joined in the molecule. It can be
represented by ball-and-stick model or diagrammatically.
Find the empirical formula of an oxide of magnesium consisting of 0.32g of oxygen and
0.96g of magnesium.
n(Mg) =0.96 / 24
= 0.04 mol
n(O) = 0.32 / 16
= 0.02 mol
Mg = 0.04 / 0.02
=2
O = 0.02 / 0.02
=1
n(S) = 40 / 32
= 1.25 mol
n(O) = 60 / 16
= 3.75 mol
O = 3.75 / 1.25
=3
Find the molecular formula of propene, CH2, having molecular mass of 42.
Molecular formula will be CnH2n
Relative molecular mass = 12n(from carbon Ar) + 2n(2 x hydrogen Ar) = 14n
14 n = 42
n = 42 / 14 = 3
Equal volume of gases at same temperature and volume contain equal number of particles or
molecules.
Formulae:
Concentration of Solutions
m = 0.9 x 40
= 36g
Reacting Masses
Eg. X + 2Z --> 2Y
2. Then multiply the ratio by no. of moles of Y to find the reacting mole of X.
1/2 x 0.25 = 0.125 mole
3. To find the reacting mass of X, e.g. Y is given as 35g, we just multiply the mole by the mass
of Y as they are always in ratio:
0.125 x 35 = 4.375 g
Example
Find the amount of hydrogen gas, in cm3, formed when 14.6g of HCl is reacted.
m(HCl) = 14.6/36.5
=0.4 mol
Example Questions
1 mole of CO2 is equal to
2. 20 cm3 of carbon monoxide are reacted with 10 cm3 of oxygen. The equation for the
reaction is shown:
2CO + O2 --> 2CO2
Which volume of carbon dioxide will be produced?
a. 10 cm3
b. 20 cm3
c. 30 cm3
d. 40 cm3
7. Magnesium reacts with hydrochloric acid. Which solution would give the fastest initial
rate of reaction?
a. 40 g of HCl in 1000 cm3 of water
b. 20 g of HCl in 1000 cm3 of water
c. 10 g of HCl in 100 cm3 of water
d. 4 g of HCl in 50 cm3 of water
8. One mole of hydrated copper(II) sulphate, CuSO 4.5H2O is dissolved in water. How many
moles of ions does the solution contain?
a. 1
b. 2
c. 6
d. 7
10. Which of the following contains the same number of molecules as 9 g of water?
a. 2 g of hydrogen gas
b. 14 g of nitrogen gas
c. 32 g of oxygen gas
d. 44 g of carbon dioxide gas
What is the total mass of the solution that remains when 40g of calcium reacts with 100 g
of water?
a. 58 g
b. 74 g
c. 138 g
d. 140 g
12. 20 cm3 of oxygen are reacted with 20 cm3 of carbon monoxide. What are the volumes
of the gases remaining, at the original temperature and pressure?
carbon
oxygen/cm3 carbon dioxide/cm3
monoxide/cm3
a 0 0 20
b 0 0 40
c 10 0 20
d 10 10 20
14. A volume of ethane, C2H6, at r.t.p. has a mass of 20 g. What is the mass of an equal
volume of propene, C3H6 at r.t.p.?
a. 20 g
b. 21 g
c. 28 g
d. 42 g
17. The equation for the burning of hydrogen is: 2H2 (g) + O2 (g) ---> 2H2O (g)
One mole of hydrogen gas is made to react with one mole of oxygen gas. What will be
present after the reaction?
a. 1 mol of steam only
b. 1 mol of steam + 0.5 mol of oxygen gas
c. 1 mol of steam + 1 mol of hydrogen gas
d. 2 mol of steam + 0.5 mol of oxygen gas
18. The compound SO2Cl2 reacts with water according to the equation:
SO2Cl2 + 2H2O ---> H2SO4 + 2HCl
How many moles of sodium hydroxide will neutralise the solution produced by one mole of SO2Cl2
and excess water?
a. 1
b. 2
c. 3
d. 4
22. Which of the following compounds contain the same percentage by mass of nitrogen as
ammonium cyanate, NH4CNO?
a. NH4NO3
b. NH4Cl2
c. N2H2
d. (NH2)2CO
23. A hydrocarbon contains 20% of carbon and 80% of hydrogen. What is its molecular formula if
it has a relative molecular mass of 30?
a. CH3
b. CH4
c. C2H6
d. C2H4
24. 0.1 mol of metal X (Ar = 27) was burned in oxygen to give an oxide with mass of 5.1g. What is
the formula of the metal oxide if it has a relative molecular mass of 30?
a. XO
b. XO2
c. X2O3
d. X2O
25. 100cm3 of gaseous hydrogen contains n molecules. How many molecules are there in 100cm3 of
gaseous methane (CH4) under the same temperature and pressure?
a. n
b. n/5
c. 5n/2
d. 2n/5
28. Which of the following formulae for ionic compounds is not correct?
a. Mg(OH)2
b. KF
c. Al2O3
d. Ca2Cl
29. What is the maximum mass of chromium, Cr, that can be extracted from 76g of chromium(III)
oxide?
a. 38g
b. 48g
c. 52g
d. 152g
30. How many oxygen atoms are present in 0.2 moles of N2O5?
a. 6.02 x 1023
b. 4.05 x 1023
c. 3.01 x 1022
d. 6.02 x 1021
MCQ Answers
1. d
2. b
3. b
4. d
5. c (Avogadro's law)
6. c
7. c
8. b
9. a
10. b
11. c (no. of moles of Ca = 40/40 = 1; no. of moles of water = 100/18. So Ca is the limiting reactant and
H2O was present in excess. Mass of hydrogen gas liberated/lost = 2g. Mass of solution = 140 - 2 = 138 g)
12. c
13. c
14. c
15. b
16. d
17. b
18. d
19. a
20. c
21. c
22. d
23. c
24. d
25. a
26. a
27. d
28. d
29. c
30. a
Solution
2. CFCs are compounds that contain only carbon, chlorine and fluorine. They are
atmospheric pollutants and destroy ozone in the upper atmosphere.
a. 'CFC11' has the following composition by mass
C: 8.7%
F: 13.8%
Cl: 77.5%
b. 'CFC12' has the molecular formula CF2Cl2. It can be made by the reaction of hydrogen
fluoride, HF, with tetrachloromethane, CCl4
What is the maximum mass of CFC12 that can be made from 10.0 g of hydrogen fluoride?
Solution
2a.
C F Cl
% mass 8.7 13.8 77.5
Ar 12 19 35.5
8.7/12 13.8/19 77.5/35.5
molar ratio = 0.725 = 0.726 = 2.183
=1 =1 =3
2b. Mr of HF = 20
Mr of CF2Cl2 = 121
2 x 20 g of HF give 121 g of CF2Cl2
a. show that 1.0 g of potassium superoxide will supply about 0.25 dm 3 of oxygen at room
temperature and pressure.
bi. name the compound formed when carbon dioxide reacts with solid potassium
hydroxide
Solution
3a. Mr of KO2 = 71
4 x 71 = 284 g of KO2 give 3 x 24 = 72 dm3 of O2 at r.t.p.
3bii. CO2 (g) + 2KOH (s) --> K2CO3 (s) + H2O (l)
4. Many cars are fitted with air-bags which inflate in an accident. Air-bags contain the
solid sodium azide, NaN3, which decomposes rapidly to form sodium and nitrogen. The
nitrogen fills the air-bag.
a. construct the equation, including state symbols, for the decomposition of sodium
azide.
b. in a crash, an air-bag fills with 72 dm3 of nitrogen at room temperature and pressure.
What mass of sodium azide is needed to provide the nitrogen?
c. Sodium azide, NaN3 reacts with dilute hydrochloric acid to give sodium chloride and a
compound A.
Compound A contains 2.33% hydrogen and 97.7% nitrogen by mass.
ii. construct the equation for the reaction between sodium azide and dilute hydrochloric
acid.
Solution
4ci.
element H N
% 2.33 97.7
Ar 1 14
No. of moles 2.33 6.98
Ratio 1 3
5. Lead white, a white pigment used in old paintings, contains lead(II) carbonate. It darkens when
exposed to air containing traces of hydrogen sulphide, due to the formation of black lead(II)
sulphide, PbS. The white colour can be restored by treating the painting with aqueous hydrogen
peroxide which converts lead(II) sulphide into lead(II) sulphate and water.
ai. Write the chemical equation of the reaction between lead(II) sulphide and hydrogen peoxide.
aii. Calculate the volume of 0.100 mol/dm3 hydrogen peroxide required to react with 0.25 g of
lead(II) sulphide.
b. The element germanium (Ge) was once an important component of transistors. The flow chart
below shows how germanium can be made from its ore germanite.
When 1.00 g of germanite was treated in this way, the germanium present was completely
converted into 0.177 g of a chloride containing 33.9% by mass of germanium.
i. Determine the empirical formula of the chloride.
ii. Write down the valency of germanium in the chloride.
iii. Calculate the percentage of germanium in germanite
Solution
bi.
Elements Germanite Chloride
Mass in % 33.9 66.1
Ar 73 35.5
No. of moles 33.9 / 73 = 0.464 66.1 / 35.5 = 1.861
Divide by smallest
0.464 / 0.464 = 1 1.861 / 0.464 = 4
number
bii. valency = 4
biii. Mass of germanium in germanium chloride = 33.9 / 100 x 0.177
= 0.0600 g
% of germanium in germanite = 0.0600 / 1.00 x 100%
= 6.00% (3 sf)
Solutions
6b. no. of mol of H2SO4 = concentration x volume = 0.25 x 55/1000 = 0.01375 --> 0.01 mol (2 dp)
6c. Mr of N2 gas = 28
no. of mol of N2 gas = 17/28 = 0.6071 mol --> 0.61 mol (2 dp)
7. Calculate
a. the concentration of 32g of KOH in 500cm3 of water
b. the mass of iron (Fe) that can be extracted from 14.9g of iron(II) oxide (Fe2O3)
c. the volume of 100g of CO2 at normal atmospheric pressure and temperature
Solutions
7a. Mr of KOH = 56
no. of mol of KOH = 32/56 = 0.5714mol --> 0.57mol (2 dp)
conc of KOH = no. of mol/(500/1000) = 1.14 mol/dm3
7c. Mr of CO2 = 44
no. of mol of CO2 = 100/44 = 2.272 mol --> 2.27 mol (2 dp)
vol of CO2 = 2.27mol x 24dm3 = 54.48dm3
8. A solution of 250cm3 of ethanol in water contained 22.3g of ethanol, C2H5OH. Calculate the
concentration of ethanol in g/dm3 and mol/dm3.
Solutions