Chemdpp PDF

DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |
PREFACE
This book contains the Daily Practice Problems (DPPs) designed for the aspirants
JEE(Main+Advanced). It is a collection of problems (Physics, Chemistry & Mathematics in
separate booklets) from multiple topics to understand the application of concepts learned in
theory. Each DPP is kind of a timed test with marking scheme and prescribed time to be spent
on each problem. It is according to the latest pattern of JEE(Advanced) and serves as a great
tool for the students to simulate examination conditions at home. It enables a student to
practice time management while solving a problem which helps him/her to better prepare for
the target exam.
Every effort has been taken to keep this book error free, however any suggestions to improve
are welcome at smdd@resonance.ac.in.
(i)
DPP
DAILY PRACTICE PROBLEMS
CHEMISTRY
TARGET: JEE (Main + Advanced)
COURSE : VIJETA (01&02JPBH & 01&02JPABH)
Physical / Inorganic Chemistry DPPs (A1 to A20)
Organic Chemistry DPPs (A1 to A14)
INDEX
PHYSICAL / INORGANIC CHEMISTRY DPPS
S. No. Particulars Page No.

1. DPP No. A1 001 – 003
2. DPP No. A2 003 – 006
3. DPP No. A3 006 – 009
4. DPP No. A4 009 – 011
5. DPP No. A5 012 – 014
6. DPP No. A6 014 – 016
7. DPP No. A7 016 – 019
8. DPP No. A8 019 – 021
9. DPP No. A9 022 – 024
10. DPP No. A10 024 – 026
11. DPP No. A11 026 – 029
12. DPP No. A12 029 – 031
13. DPP No. A13 031 – 034
14. DPP No. A14 034 – 036
15. DPP No. A15 036 – 038
16. DPP No. A16 038 – 041
17. DPP No. A17 041 – 043
18. DPP No. A18 043 – 046
19. DPP No. A19 046 – 049
20. DPP No. A20 049 – 052
(ii)
ORGANIC CHEMISTRY DPPS
1. DPP No. A1 053 – 055
2. DPP No. A2 055 – 057
3. DPP No. A3 057 – 061
4. DPP No. A4 061 – 062
5. DPP No. A5 063 – 066
6. DPP No. A6 066 – 070
7. DPP No. A7 070 – 072
8. DPP No. A8 073 – 074
9. DPP No. A9 075 – 078
10. DPP No. A10 079 – 083
11. DPP No. A11 084 – 087
12. DPP No. A12 087 – 091
13. DPP No. A13 091 – 094
14. DPP No. A-14 094 – 097
ANSWER KEY 098 – 101
NOTE:
  Marked Questions may have for Revision Questions.
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(iii)
DPP No. # A1 (JEE-ADVANCED)

Total Marks : 71 Max. Time : 42min.
Single choice Objective ('–1' negative marking) Q.1 (3 marks, 2 min.) [03, 02]
Multiple choice objective ('–1' negative marking) Q.2 to Q.7 (4 marks, 2 min.) [24, 12]
Numerical value Questions ('0' negative marking) Q.8 to Q.11 (4 marks, 3 min.) [16, 12]
Match the Following (no negative marking) Q.12 (8 marks, 6 min.) [08, 06]
ChemINFO : 5 Questions ('–1' negative marking) Q.13 to Q.17 (4 marks, 2 min.) [20, 10]
1. 'kq) ty esa] BaSO4 dh foys;rk 4 × 10–5 M gSA 0.01 M BaCl2 foy;u esa BaSO4 dh foys;rk gksxh &
(A) 2 × 10–3 M (B) 1.6 × 10–5 M (C) 1.6 × 10–7 M (D) 4 × 10–5 M
(E) 8 × 10–5 M
2. lgh dFku¼uksa½ dk p;u dhft, %
(A) Co3+ vk;u ds dsoy pØ.k pqEcdh; vk?kw.kZ dk eku (BM esa) = 24
(B) ,d 3p-d{kd esa f=kT; uksM dh la[;k = 1
(C) Mn2+ vk;u esa (m = 0) eku okys bysDVªkWuksa dh la[;k = 11
6h
(D) V4+ esa v;qfXer bysDVªkWu ds fy, dz{kd dks.kh; laosx =
4
3. VSEPR fl)kUr ds vuqlkj] fuEu esa ls dkSulh Lih'kht mudh lajpuk ds lkFk lqesfyr gS \
(A) BrF6+  v"VQydh; (B) SnCl5–  f=kdks.kh; f}fijsfefM;
(C) ClF2–  js[kh; (D) IF4+  lh&lkW
4. lEihM~;rk xq.kkad (Z) ds lanHkZ esa fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A) U;wu nkc {ks=k esa] nkc esa o`f) ds lkFk Z ds eku esa izkjEHk esa deh gksrh gS] ;|fi H2 rFkk He xSl blds fy,
viokn gSaA
(B) ,d vkn'kZ xSl ds fy, Z, ,d ls vf/kd gksrk gSA
(C) ,d vukn'kZ xSl ds fy,] Z dk eku ,d ls vf/kd vFkok de gks ldrk gS rFkk ;g rki rFkk nkc ij fuHkZj
djrk gSA
(D) tc Z < 1 gS] rc vUrjvk.kfod vkd"kZ.k] vUrjvk.kfod izfrd"kZ.k ij izHkkoh gksrk gSA
5. ,d vkn'kZZ xSl dh fu;r ek=kk ds fy, rhu izØe AB, APB o AQB fd;s tkrs gSaA lgh fodYi pqfu;sA
(A) SAB izØe ds izdkj ij fuHkZj ugha djrkA

(B) ;fn AB iFk ,d mRØe.kh; lerkih; izØe gS] rks SAB = QAB/T gS] tgka QAB izØe AB ls lEcfU/kr Å"ek gS
rFkk lerkih; izØe ds fy, rkieku T (K esa) gSA
(C) SAB via AQB > SAB via APB.
(D) SAB via AQB < SAB via APB.
6. fuEu foy;u ds leku vk;ru fefJr fd;s x;s] buesa ls fdl fLFkfr esa pH dk eku nkukas foy;u ds pH dk vkSlr
eku gksxkA
(A) pH = 2 HCl rFkk pH = 12 NaOH (B) pH = 2 HCl rFkk pH = 4 HCl
(C) pH = 2 HCN rFkk pH = 12 NaOH (Ka of HCN = 10–10)
(D) pH = 5 CH3COOH rFkk pH = 9 NH3(aq), Ka (CH3COOH) = Kb (NH3 (aq))
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PAGE NO.-1
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7. ,d foy;u dks Ag2CrO4 rFkk Ag2C2O4 nksuksa dks ?kksydj cuk;k tkrk gS tc rd fd nksuksa yo.kks a ds laxr larÌrrk
izkIr u gks tk;sA
fn;k gS Ksp (Ag2C2O4) = 10–12, Ksp (Ag2CrO4) = 2×10–12
1
fn;k gS : 36  3  3.3
mijksDr nh x;h lwpuk ds laxr fuEu es ls dkSulk@dkSuls dFku lgh gS@gSa \
(A) vfUre foy;u esa [Ag+] rFkk [CrO24 ] Øe'k% 1.8×10–4 M rFkk 0.6×10–4 M gSA
(B) vfUre foy;u esa [Ag+] rFkk [CrO24 ] Øe'k% 0.9×10–4 M rFkk 0.6×10–4 M gSA
(C) vfUre foy;u esa [Ag+] rFkk [C2O24 ] Øe'k% 3.6×10–4 M rFkk 0.3×10–4 M gSA
(D) vfUre foy;u esa [Ag+] rFkk [C2O24 ] Øe'k% 1.8×10–4 M rFkk 0.3×10–4 M gSA
8. fuEu esa ls fdrus ijkWDlkbM iztkfr;ka j[krs gSa ?
(i) CO2 (ii) NO2 (iii) BaO2 (iv) PbO2 (v) KO2 (vi) Na2O2
(viii) MnO2 (viii) CrO5
9. pH = 8.65 dk cQj nsus ds fy, NH4Cl ds 0.2 M foy;u ds 0.3 M NH4OH feyk;k tkuk pkfg,A
fn;k gS% pkbNH OH = 4.75 rFkk izfry?kqxq.kd ( 0.6) = 0.25 .
4
10. 414 g H2O(s) ds H2O() esa :ikUrj.k ds fy, fuEu izØe ds fy, twy esa G dk fu/kkZj.k dhft,A
H2O(s)  H2O()
(6 atm, 273 K) (6 atm, 273 K)
fn;k gS: H2O(s) dk ?kuRo = 0.92 g/cm3, H2O() dk ?kuRo = 1 g/cm3
viuk mÙkj 6 ls foHkkftr djus ds i'pkr~ nhft, (yhft, 1 atm L = 100 J)A
11. fuEu esa ls fdrus dFku lR; gS \
(a) BeO dh mHk;/kehZ çd`fr gSA (b) LiHCO3 Bksl voLFkk esa ugha ik;k tkrk gSA
(c) K2O2 çfrpqEcdh; gS ijUrq KO2 vuqpEq cdh; gSA
(d) lQsn QkWLQksjl] dkWfLVd lksMk ls fØ;k dj QkWLQhu xSl cukrk gSA
(e) AlCl3, NaOH ds vkf/kD; esa foys; gS rFkk lksfM;e esVk ,Y;qfeusV cukrk gSA
(f) futZyh; ikSVsf'k;e ukbVªsV dks ikSVsf'k;e /kkrq ds lkFk xeZ djus ij ikSVsf'k;e vkWDLkkbM vkSj ukbVªkstu xSl curh gSA
(g) fyfFk;e DyksjkbM ty esa vR;f/kd foys; gSA
(h) ty;ksftr eSXusf'k;e DyksjkbM dks 'kq"d gok esa xeZ djus ij futZyh; MgCl2 çkIr gksrk gSA
12. ,d fudk; ftlesa dh vkn'kZ xSl dh fuf'fpr ek=kk mifLFkr gS] ds fy, fuEufyf[kr dk feyku dhft,A
LrEHk I LrEHk II
(A) pfØ; izØe (Cyclic process) (p) H = 0 rFkk U = 0
(B) mRØe.kh; lerkih; izØe (Reversible isothermal process) (q) Q = –W
(C) mRØe.kh; :)ks "e iz Ø e (Reversible adiabatic process) (r) W = 0 rFkk Q = U
(D) levk;ruh izØe (Isochoric process) (s) Q = 0 rFkk dH = Vdp
ChemINFO Solution & Colligative Properties

Daily Self-Study Dosage for mastering Chemistry gsujh fu;e
tc ,d xSl dks foyk;d esa ?kksyk tkrk gS rks fuEu lkE; LFkkfir gksrk gSA
xSl + foyk;d foy;u
xSl dh foys;rk o blds nkc ds chp lEcUèk dks gsujh fu;e ds inksa esa O;Dr fd;k tkrk gS tks crkrk gS fd fdlh rki ij
,d foyk;d dks nh xbZ ek=kk esa ?kksyh x;h xSl dh ek=kk foyk;d ds Åij xSl ds nkc ds lekuqikrh gksrh gSA ;g crkrk gS
fd fu;r rkieku ij ,d foyk;d esa ?kksys x;s xSl dk eksy fHkUu xSl ds vkaf'kd nkc ds lh/ks lekuqikrh gksrk gSA
ekuk rki T ij nzo dh ,d fuf'pr ek=kk esa ?kksys x;s ,d xSl dk eksy fHkUu x gSA ;fn foyk;d ij xSl dk vkaf'kd nkc patm
gS] rks x  P ; x = KHP ;k P = KH' X ; KH = lekuqikrh fu;rkad vFkok gsujh fu;rkad
gsujh fu;e fu;rkad (KH) d vfHky{k.k %
PAGE NO.-2
(i) nkc ds leku bdkbZ (eksy/ L atm, L atm/eksy)
(ii) fofHkUu xSl tks KH ds fHkUu eku j[krh gS
Gases KH(mol/I.atm)
O2 1.3 × 10–3
N2 7 × 10–4
CO2 2.3 × 10–2
H2 8.5 × 10–4
(iii) ,d xSl dk KH eku fofHkUu foyk;dksa esa fHkUu gksrk gS o blesa rkieku o`f) ds lkFk
o`f) gksrh gSA
(iv) ,d xSl ds fy, KH dk eku ftruk mPp gksrk gS mruh gh bldh foys;rk dk eku de
gksxkA
gsujh fu;e ds vuqiz;ksx
(i) e`nq is; o lksMkokVj esa CO2 dh foys;rk c<kus ds fy;s cksry dks mPp nkc ij eqag cUn dj nsrs gSaA
(ii) Å¡pkbZ ij vkWDlhtu dk vkaf'kd nkc Hkwfe Lrj ls de gSaA blds ifjek.kLo:i vfèkd Å¡pkbZ vFkok ioZrkjksgh ij jgus
okys O;fDr ds jDr o Ård esa vkWDlhtu dh lkUnzrk de gks tkrh gSA fuEu jDr vkWDlhtu ds dkj.k ioZrkjksgh
nqcZy gks tkrk gS o Li"V :i ls lkspus esa l{ke ugha gks ikrk bl izdkj dh fLFkfr ,uksfDl;k dgykrk gSA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
13. 298 K o 1 atm nkc ij ty esa N2 dh foys;rk 6.8 × 10–4 mol/L gSA ;fn N2 dk vakf'kd nkc 0.78 atm gS] rks
ok;qe.Myh; ifjfLFkfr;ksa ij ty esa ?kksyh xbZ N2 dh lkUærk D;k gS \
(A) 2.4 × 10–3 m (B) 5.3 × 10–4 m (C) 9 × 10–4 m (D) 16.5 × 10–4 m
14. pkj vk;fud yo.kksa X, Y, Z, W ds fy, foys;rk oØ uhps fn;s x;s gS %
fdl ifjfLFkfr esa Hsol. < 0 dk eku gS
(A) X
(B) Y
(C) Z
(D) W
15. ty esa H2, O2 o CO2 ds fy, gsujh fu;e fu;rkad Øe'k% 1282 L atm/mol, 769.2 Latm/ mol o 29.41 L atm/
Mol gSA 250C ij ty ds ,d izkn'kZ esa fdl xSl dh lkUærk mPpre gS tc ty ds Åij nkc 1 atm gSA
(A) H2 (B) O2 (C) CO2 (D) buesa ls dksbZ ugha
16. 298 K ij ty esa N2 xSl dh foys;rk ds fy, gsujh fu;e fu;rkad 2.0 × 105 atm gSA ok;q esa N2 ds fy, eksy fHkUu
0.8 gSA 3 atm o 298 K ij ty ds 5 eksyksa esa ?kksyh xbZ ok;q ls N2 ds eksyks dh la[;k fuEu gS&
(A) 2 × 10–5 (B) 6 × 10–5 (C) 9 × 10–4 (D) 9 × 10–5
17. lgh dFku dk p;u dhft,&
(A) og xSl] ftuds fy, ok.Mj okWYl fu;rkad ‘a’ dk eku mPp gksrk gS] dks vklkuh ls æohd`r fd;k tk ldrk gSA
(B) vklkuh ls æohd`r gksus okyh xSls ty&foys;h gksrh gSA
(C) ,d foyk;d esa vk;u fuekZf.kr xSl ml foyk;d esa foys;h gksrs gS A
(D) leku ifjfLFkfr;ksa ij NH3 ds fy, foys;rk CO2 ls de gksrh gSA
DPP No. # A2 (JEE-MAIN)

Total Marks : 100 Max. Time : 55 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (4 marks, 2 min.) [80, 40]
1. 1 eksy vkn'kZ xSl] 10 L ls 100 L rd lerkih; rFkk mRØe.kh; :i ls izlkfjr gksrh gSA izØe ds fy, fuEu esa ls
dkSulk dFku lgh gS %
(A) T  0 (B) H  0
(C) nh xbZ Å"ek (q)  0 (D) E  0
PAGE NO.-3
2. ,d vkn'kZ xSl dk ,d izkjfEHkd fuf'pr voLFkk ls lerkih; rFkk :)ks"e izlkj.k ds fy, lgh xzkQ gksxk&
lerkih; lerkih;
(A) L)ks"e (B) (C) L)ks"e (D) lerkih;
lerkih; L)ks"e L)ks"e
3. lgh fodYi @ fodYiksa dk p;u dhft, %

S1 : fof'k"V vk;ru rFkk eksyj Å"ek /kkfjrk] ek=kkLora=k ekiØe (intensive parameters) gSaA
S2 : ,d vkn'kZ xSl ds ,d lenkch; izØe ds fy,] vkUrfjd ÅtkZ esa ifjorZu dks U = nCV (T2 – T1) }kjk iznf'kZr
fd;k tkrk gS] tgk¡ iz;qDr in viuk lkekU; vFkZ j[krs gSaA
S3 : ;fn ,d vuqRØe.kh; izØe ds iFk dks O;qRØfer ¼reverse½ fd;k tkrk gS] rc fudk; rFkk ifjos'k nksuksa viuh
okLrfod voLFkk iqu% izkIr dj ysrs gSaA
S4 : :)ks"eh; mRØe.kh; lEihM+u esa] lerkih; mRØe.kh; lEihM+u dh rqyuk esa] xSl ij de dk;Z fd;k tkrk gS]
;fn lEihM+u leku izkjfEHkd rFkk vfUre vk;ruksa ds e/; lEiUu djk;k tk,A
(A) T T T F (B) F F T T (C) F T F T (D) T T F F
4. bl dkYifud vfHkfØ;k ij fopkj djks
A(s) 2B(g) + 3C(g)
;fn C dh lkUnzrk lkE; ij nqxuh dj nh tk;s rc lkE; iqu% LFkkfir gksus ij B dh lkUnzrk gksxh&
(A) vius okLrfod (original) eku dh nks xquh (B) vius okLrfod (original) eku dh vk/kh
1
(C) vius okLrfod (original) eku dh xquh (D) vius okLrfod (original) eku dh 2 2 xquh
2 2
5. izØe H2O() (1 bar, 373 K)  H2O(g) (1 bar, 373 K) ds fy,, Å"ekxfrdh ekiØeksa dk lgh lewg gSA
(A) G = 0, S = + ve (B) G = 0, S = – ve
(C) G = + ve, S = 0 (D) G = – ve, S = + ve
6. mRikn (x) rFkk (y) esa dsUnzh; ijek.kqvksa ds ladj.k dh voLFkk Øe'k% D;k gS \
(A) sp3 rFkk sp3d (B) sp2 rFkk sp3 (C) nksuksa esa sp3 (D) nksuksa esa sp3d
7. fuEu esa ls dkSulk yo.k dk _.k&vk;fud ty vi?kVu n'kkZrk gSA

(A) CuSO4 (B) NH4Cl (C) FeCl3 (D) Na2CO3
okLrfod xSl
8. P
vkn'kZ xSl
V
fuEu esa ls dkSulk dFku P-V oØ ds lUnHkZ esa xyr gS?
(A) mPp nkc {ks=k esa xSl /kukRed fopyu n'kkZrh gSA
(B) fuEu nkc {ks=k ij ekfir rFkk ifjdfyr vk;ru ,d nwljs ds fudV vkrs gSA
(C) mPp nkc {ks=k esa Z > 1 gksrk gS vr% xSl vkn'kZ xSl dh vis{kk de lEihM~; gksrh gSA
(D) fuEu nkc {ks=k esa Z < 1 gksrk gS vr% xSl vkn'kZ xSl dh vis{kk de lEihM~; gksrh gSA
9. fuEu esa ls dkSulk fp=k d.k ds laosx esa ifjorZu rFkk lacaf/kr Mh&czksXyh rjax nS/;Z dks iznf'kZr djrk gSA
(A) (B) (C) (D)
PAGE NO.-4
10. ftad vkSj gkbMªksDyksfjd vEy dh fØ;k fuEu vfHkfØ;k ds vuqlkj gksrh gS %
Zn(s) + 2HCl(aq.)  ZnCl2(aq.) + H2(g)
;fn HCl ds 0.52 eksy esa Zn ds 0.3 eksy dks feyk fn;k tk;s] rks H2 ds fdrus eksy cusxsa %
(A) 0.26 (B) 0.52 (C) 0.14 (D) 0.30
11. ijek.oh; la[;k c<+us ds lkFk {kkjh; e`nk /kkrqvksa ds fdl xq.kksa esa o`f) gksrh gS %
(A) vk;uu ÅtkZ (B) muds gkbMªksDlkWbM dh foys;rk
(C) muds lYQsV dh foys;rk (D) fo|qr _.kkRedrk
12. pH = 5.4 ds ,d foy;u esa gkbMªkstu vk;uksa dh lkanzrk ¼eksy@yhVj esa½ gksxh %
(A) 3.98 × 108 (B) 3.88 × 106 (C) 3.68 × 10–6 (D) 3.98 × 10–6
13. 109º 28' dk ca/k dks.k ik;k tkrk gS %
(A) NH3 (B) H2O (C) CH3+ (D) NH4+
14. ok"i izkoLFkk esa csUthu (PB0= 150 torr) rFkk VkWyqbZu (PT0 = 50 torr) dk eksy vuqikr D;k gS] ;fn fn, x, foy;u
dk ok"i nkc 120 torr gS ?
(A) 7 : 1 (B) 7 : 3 (C) 8 : 1 (D) 7 : 8
15. ,d nqcZy izksfVd vEy HA dk 0.20 eksyj foy;u 3.0 dh pH j[krk gSA vEy dk vk;uu fu;rkad gS&
(A) 5.0 × 10–7 (B) 2.0 × 10–7 (C) 5.0 × 10–6 (D) 5.0 × 10–3
16. 310 K ij 'kq) nzo A dk ok"inkc 40 mmHg gSA bl nzo dk] nzo B ds lkFk foy;u esa ok"i nkc 32 mmHg gSA
;fn foy;u jkmYV fu;e dk ikyu djrk gS rks foy;u esa A dh eksy fHkUu gS %
(A) 0.8 (B) 0.5 (C) 0.2 (D) 0.4
17. ty (B.P. = 100ºC) rFkk HCI (B.P. = 86ºC) dk fLFkjdokaFkh(azeotropic) feJ.k yxHkx 120ºC ij mcyrk gSA bl
feJ.k ds izekih vklou ds nkSjku fuEu dks izkIr djuk laEHko gS :
(A) 'kq) HCI dks (B) 'kq) H2O dks
(C) 'kq) H2O ds lkFk–lkFk 'kq) HCI dks (D) 'kq) H2O rFkk 'kq) HCI nksuks dksbZ ughaA
18. foy;u ds /kukRed fopyu ds fy, fuEu esa ls lgh dFku dkSulk gSA
(A) foyk;du esa eqDr ÅtkZ] vUrZfØ;k @ vUrjkf.od cyksa dks rksM+us esa iz;qDr ÅtkZ ls vf/kd gksrh gSA
(B) foys;&foyk;d vUrZfØ;k ¼interaction½ buds Loa; dh vUrZfØ;k ¼interaction½ dh rqyuk esa nqcZy gksrh gSA
(C) foy;u fuekZ.k ij vk;ru esa ladqpu gksrk gSA
(D) foy;u dk DoFkukad vuqekfur eku ls mPp gksxkA
19. nks nzOkksa ds ,d fLFkj DokFkh foy;u dk DoFkukad nksuksa nzoksa ls de gksxk tc %
(A) ;g jkmYV fu;e ls _.kkRed fopyu n'kkZrk gSA (B) ;g jkmYV fu;e ls dksbZ fopyu ugha n'kkZrk gSA
(C) ;g jkmYV fu;e ls /kukRed fopyu n'kkZrk gSA (D) ;g larÌRk gSA
20. A rFkk B æo ds ,d vkn'kZ foy;u ds fy, tc xA = 0.2 gS rc foy;u ij dqy ok"i nkc 560 Vksj Fkk rFkk A dk
vkaf'kd nkc 80 Vksj FkkA ok"i dk la?kVu D;k gksxk] tc xA = 0.8 gS ?
1 8 3 9
(A) yA = (B) yA = (C) yB = (D) yB =
7 11 7 11
21. NO3– esa N ds pkjksa rjQ fdrus bysDVªkWu ca/k ;qXe ik;s tkrs gSa \
22. Mkbcksjsu lajpuk esa fjDr ladfjr d{kdksa dh la[;k crkb;s tks 3-dsUnz 2 bysDVªkWu ca/k vFkkZr~ cukuk ca/k (banana
bonds) fuekZ.k esa Hkkx ysrs gSaA
23. 0.1 M RCOOH (Ka = 10–5) ds tyh; foy;u dk pH gS %
PAGE NO.-5
24. ,d 10 M Na2S foy;u esa As2S3 dh foys;rk Kkr dhft;s \ ¼ekuk fd] /kuk;fud vFkok _.kk;fud Hkkx dk
–2
1
fdlh Hkh izdkj dk ty vi?kVu ugha gksrk gS½ ¼fn;k gS: As2S3 ds fy, Ksp = × 10–24) viuk mÙkj Y ds :i esa
625
nhft;s tgk¡ foys;rk (mol/L esa) = Y × 10–11.
25. fuEu vk¡dM+ks ls ,Fkkbyhu ds gkbMªkstuhdj.k dh Å"ek dk fu/kkZj.k dhft,&
cU/k cU/k ÅtkZ cU/k cU/k ÅtkZ
HH 104 k Cal CC 80 k Cal
CH 99 k Cal C=C 145 k Cal

ChemINFO: 5 Questions ('–1' negative marking) Q.13 to Q.17 (4 marks, 2 min.) [20, 10]
1. veksfu;k ¼nzo½ esa {kkjh; /kkrq rFkk {kkjh; e`nk /kkrq ds foy;u ds fy, fuEu esa ls dkSulk@dkSuls dFku lR; gSaA
(A) veksfu;k esa {kkjh; /kkrq dk lkfUnzr foy;u dk¡ijµcksUt jax j[krk gS rFkk /kkfRod pedhyk cukrk gSaA
(B) {kkjh; e`nk /kkrq dk ruq foy;u fo;ksftr bysDVªku ls LisDVªe ds dkj.k jax esa pedhyk uhyk @xgjk uhyk dkyk
gksrk gSaA
(C) veksfu;k esa {kkjh; e`nk /kkrq dk lkfUnzr foy;u cksUt jax j[krk gSaA
(D) /kkjh; /kkrq ds foy;u ls veksfu;k ds ok"ihdj.k ls /kkrq dk fuekZ.k gksrk gS] ijUrq {kkjh; e`nk /kkrq ds lkFk
veksfu;k ds ok"ihdj.k ls /kkrq dk N % veksfu;k;qDr ;kSfxd curk gSaA
2. ;kSfxdksa dk ;qXe tks tyh; foy;u esa ,d lkFk vfLrRo esa ugha jg ldrk gS %
(A) NaH2 PO4 rFkk Na2HPO4 (B) Na2 CO3 rFkk NaHCO3
(C) NaOH rFkk NaH2 PO4 (D) NaHCO3 rFkk NaOH.
3. fuEu esa ls dkSulk@dkSuls flfydkWuksa ds fy, lR; gS@gSa \

(A) ;s Å"ek ds izfr LFkk;h gksrs gSA
(B) budh '’;kurk rki ds lkFk fof'k"V :i ls ifjofrZr ugha gksrh gSA
(C) ;s fo|qr ds vPNs pkyd gksrs gSA
(D) ;s tyLusgh izd`fr ds gksrs gSA
4. ;fn leku nkc rFkk nks fHkUu rkieku ij ukbVªkstu o vkWDlhtu ds rms osx leku gks rc
(A) v.kqvksa dk vkSlr osx Hkh leku gksrk gSA
(B) ukbVªkstu rFkk vkWDlhtu dk ?kuRo (xzke/yhVj) Hkh leku gksrk gSA
(C) izR;sd xSl ds eksyksa dh la[;k cjkcj gksrh gSA
(D) v.kvksa dk lcls izkf;d osx (Vmp) Hkh leku gksrk gSA
5. 1 M Xywdksl (C6H12O6) dk foy;u (?kuRo = 1.18 g/ml) fuEu esa ls fdl foy;u ds lerqY; gSA
(A) % w/w = 18% (foy;u) (B) izfr yhVj foy;u esa 180 xzke foys;
(C) % w/v = 18% (foy;u) (D) 1 eksyy foy;u
6. ,d foy;u Cu2+ rFkk Cd2+ vk;u nksuksa esa 0.01M gSA foy;u esa 'ks"k cps Cd2+ dh lkUnzrk (M es) D;k gksxh tc
99.9% Cu2+ vk;u S2– ds ;ksx }kjk CuS ds :i esa vo{ksfir gksrk gS \
fn;k gS Ksp (CuS) = 8.7 × 10–36
Ksp (CdS) = 3.6 × 10–29
viuk mÙkj 100 ls xq.kk djds nhft,A
PAGE NO.-6
7. HCl rFkk CH3COOH dk ,d fuf'pr feJ.k izR;sd vEy esa 0.1 M gSA bl foy;u ds 20 ml dks 0.1M NaOH ds
lkFk mipkfjr fd;k tkrk gSA fdruh bdkbZ }kjk pH ifjorZu gksxk izkjEHk ls ml voLFkk rd tc HCl yxHkx
iw.kZr% mnklhuhÑr gksrk gS rFkk ,lhfVd vEy vuvfHkÑr jgrk gS\ ,lhfVd vEy ds fy, Ka = 2 x 105.
8. ;fn ,d nqcZy {kkj BOH ds 0.2 M foy;u dh pH 10.3 gS] rc mDr {kkj ds 20 mL foy;u esa feyk;s tkus okys
0.4 M HCl foy;u dk vk;ru (mL esa) Kkr dhft,] ftlls foy;u dh ifj.kkeh pH 7.3 ds cjkcj gks ldsA (yhft,
log 2 = 0.3)
9. 1 kg CaC2 j[kus okyk ,lhVhyhu ysEi fdrus ?kaVs rd dk;Z djsxkA ;fn 27ºC rki rFkk 1 atm nkc ij] 1 ?kaVs ds
fy, 60 yhVj ,lhVhyhu dh vko';drk gksrh gSA (viuk mÙkj fudVorhZ iw.kk±d esa fy[kksaA)
10. 10 yhVj ty esa 25ºC ij NaOH ds 10–2 eksy feyk;s tkrs gS] rc pH ifjorZu Kkr djks&
11. A rFkk B dk nzo ,d vkn'kZ foy;u cukrk gSA ,d fuf'pr rki ij] feJ.k A rFkk B dk dqy ok"i nkc 400 mm.
gSA ok"i voLFkk ds lkE; esa nzo feJ.k esa A dk eksy izHkkt 0.4 gSA ;fn blh rki ij 'kq) nzo ds fy, ok"i nkc
 A dk vkaf'kd nkc 
vuqikr (PA0/PB0) 1/6 gSA ok"i voLFkk esa   gksxkA
 10 
12. fuEu dks lqesfyr dhft,&
LrEHk  LrEHk 
(A) 1 yhVj foy;u esa 120 xzke CH3COOH dfoy;u = 1.2 g / mL (p) M=2
(B) 1 yhVj foy;u esa 120 xzke Xyqdksl foys; (dfoy;u = 1.2 g/mL) (q) 10% Hkkj/Hkkj foy;u
(C) XNH2CONH2 = 1/31 (tyh; foy;u) (r) 12% Hkkj/vk;ru foy;u
(D) 19.6 % (Hkkj@vk;ru) H2SO4 foy;u (dfoy;u = 1.2 g/mL) (s) m = 1.85

Daily Self-Study Dosage for mastering
voLFkk@izkoLFkk D;k gS ?
 voLFkk inkFkZ dk :i gksrh gS] tks jklk;fud rFkk HkkSfrd la?kBu es letkr gksrh gSA
 Bksl] nzo rFkk xSl rhu fHkUu&fHkUu voLFkk,sa gSA nks vfeJ.kh; nzo nks fofHkUu voLFkkvksa ls cus gksrs gSaA nks feJ.kh; nzo
dsoy ,d vOkLFkk ls cus gksrs gSaA nks fofHkUu Bksl] nks fofHkUu voLFkkvksa ls cus gksrs gSaA
 vij:i (Allotropes) rFkk cgq:i (polymorphs) Hkh nks fofHkUu voLFkkvksa ls cus gksrs gSaA mnkgj.k ds fy, yky
QkWLQksjl rFkk lQsn QkWLQksjl fHkUu&fHkUu voLFkk,sa gS] ghjk rFkk xzsQkbV fHkUu&fHkUUk voLFkk,sa gSaA
 vki fofHkUu voLFkkvksa dh mifLFkfr dks igpku ldrs gS D;ksafd buds e/; ,d Li"V lhek gksrh gS] Bksl cQZ rFkk nzo ty
ds eè; ,d lhek gksrh gSA mnkgj.k ds fy, nks nzoksa ds e/; dh lhekA
voLFkk vkjs[k D;k gS ?
 voLFkk vkjs[k rki rFkk nkc dh fofHkUu ifjfLFkfr;ksa ds vUrxZr ,d inkFkZ dh HkkSfrd vOkLFkkvksa dk xzkfQ; izn'kZu gSA
 ,d izk:fid voLFkk vkjs[k y-v{k ij nkc rFkk x-v{k ij rki j[krk gSA
 tSls gh ge voLFkk vkjs[k ij js[kkvksa ;k oØks dks ikj djrs gS] rks voLFkk ifjorZu izkIr gksrk gSA
 js[kkvksa ;k oØks ij lkE; es lgvfLRkRo ds :i es inkFkZ dh nks voLFkkvksa dks feykrs gSA lkE; dh ;g js[kk,sa voLFkk lhek
(phase boundaries) voLFkk dgykrh gSA
 bl vkjs[k dk izR;sd fcUnq fudk; ds fy, rki rFkk nkc ds lEHkkfor
la;kstu dks iznf'kZr djrk gSA bl vkjs[k dks rhu {ks=kksa es foHkkftr djrs
gS] tks inkFkZ dh Bksl] nzo rFkk xSl voLFkkvksa dks iznf'kZr djrk gSaA
,d 'kq) inkFkZ ds voLFkk vkjs[k ds dqN egRoiw.kZ vfHky{k.k%
PAGE NO.-7
f=kd fcUnq
voLFkk vkjs[k ij og fcUnq] ftl ij inkFkZ dh rhu voLFkk,sa gS ;k rhuksa voLFkkvksa dk lgvfLrRo (coexist) gksrk gSA bu
fcUnqvksa ij lkE; dh js[kk,¡ ,d nwljs dks dkVrh gSA
 ØkfUrd fcUnq
;g nzo rFkk xSl ds e/; dh voLFkk lhek gS] tks fujUrj vfuf'pr dky rd ugh gksrh gSA blds ctk; ;g voLFkk
vkjs[k ij ØkfUrd fcUnq ij lekIr gksrh gSA ;g bl rF; dks Li"V djrh gS fd vR;f/kd mPp rki rFkk nkc ij nzo rFkk
xSl vOkLFkk,sa vfoHksfnr gks tkrh gSA ;g vfrØkfUrd rjy (supercritical fluid) dgykrk gSA
 laxyu (Xkyu) (;k fgeu) oØ (BD) – voLFkk vkjs[k ij og oØ] tks nzo rFkk Bksl voLFkkvksa ds e/; laØe.k dks iznf'kZr
djrk gSA
 ok"ihdj.k (;k la?kuu) oØ (BC) – voLFkk vkjs[k ij og oØ] tks xSl rFkk nzo voLFkkvksa ds e/; laØe.k dks iznf'kZr
djrk gSA
 Å/oZikru (;k fu{ksi.k] deposition) oØ (AB) – voLFkk vkjs[k ij og oØ] xSl rFkk Bksl voLFkkvksa ds e/; laØe.k dks
iznf'kZr djrk gSA
 lkekU; xyukad rFkk DoFkukad 1 ok;qe.Myh; nkc ij ,d js[kk [khapus ij voLFkk vkjs[k ls izkIr gks ldrs gSA
CO2 dk voLFkk vkjs[k%
CO2 ds mijksDr voLFkk vkjs[k dk iz;ksx djrs gq;s fuEu iz'uks ds mÙkj nhft;sA
13. voLFkk ifjorZu dk dkSulk izdkj izkIr gksxk] ;fn Bksl S dks lkekU; ifjfLFkfr;ksa ds vUrxZr [kqyk j[krs gS ?
(A) Å/oZikru (B) xyu (C) ok"ihdj.k (D) dksbZ ifjorZu ugh gksrk gSA
14. dkSulh ifjfLFkfr ds vUrxZr lkE; esa fudk; S dh leLr rhuksa voLFkk,sa izkIr gksrh gS ?
(A) T > 304.2 K rFkk P > 72.9 atm
(B) T = 216 K rFkk P = 5.2 atm
(C) T > 304.2 K
(D) P > 72.9 atm
PAGE NO.-8
15. X1 fcUnq ij fudk; dk rki X4 fcUnq rd igqpusa ds fy, fu;r nkc ij c<+rk gSA fuEu esa ls dkSulk dFku fofHkUu
voLFkkvksa ij fudk; dh izkoLFkkvksa ds lUnHkZ es xyr gS \
(A) X1 fcUnq ij Bksl voLFkk dk vfLrRo gksrk gSA
(B) X2 fcUnq ij Bksl&nzo lkE; voLFkk dk vfLrRo gksrk gSA
(C) X3 fcUnq ij Bksl&nzo&xSl lkE; voLFkk dk vfLrRo gksrk gSA
(D) X4 fcUnq ij ok"i voLFkk dk vfLrRo gksrk gSA
16. ;fn nkc c<+krs gS] rks xSl S dk xyu rki gksxk &
(A) dksbZ ifjorZu ugh gksxk (B) c<+sxk
(C) ?kVsxk (D) dqN ugh dg ldrs
17. X5 fcUnq ij fudk; ds fy, D;k ?kfVRk gksrk gS] ;fn rki dks fu;r j[krs gq,s nkc dks /khjs&/khjs ifjofrZr djrs gS \
(A) mPp nkc ij fudk; nzo gksxkA (B) fuEu nkc ij fudk; nzo gksxkA
(C) fudk; leku voLFkk esa gksxkA (D) buesa ls dksbZ ugh
DPP No. # A4 (JEE MAIN)

1. fdl ifjfLFkfr esa okUV gkWQ dkjd vf/kdre gS
(A) 50% vk;fur KCl (B) 40% vk;fur K2SO4
(C) 20% vk;fur SnCl4 (D) 30% vk;fur FeCl3
2. nks nzo X rFkk Y iw.kZr;k vfeJ.kh; gS ;fn X rFkk Y dk eksyj nzO;eku vuqikr 1 : 2 gS] rks vuqikr 2 : 3 esa cuk;k x;k
X rFkk Y ds feJ.k dk dqy ok"i nkc fuEu gksuk pkfg,A (PX0 = 400 torr, PY0 = 200 torr)
(A) 300 torr (B) 466.7 torr (C) 600 torr (D) 700 torr
3. 1 atm fu;r nkc ij nks vfeJ.kh; nzoksa ds ,d feJ.k dk DoFkukad %
(A) vf/kd ok"i'khy nzo ds lkekU; DoFkukad ds cjkcj gksrk gSA
(B) nks nzoksa ds lkekU; DoFkukadksa ds ek/; ds cjkcj gksrk gSA
(C) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls vf/kd gksrk gSA
(D) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls de gksrk gSA
4. U;wu nkc mifLFkfr ij ,d okLrfod xSl tks fd ok.MjokWy lehdj.k dk ikyu djrh gS ds fy,] fuEu esa ls dkSulk
oØ lgh gS\
(A) (B) (C) (D)
M
5. Xywdkst (C6H12O6) dk og nzO;eku] tks blds tyh; foy;u ds 50 mL dks cukus ds fy, vko';d gS] fuEu gS %
9
(A) 10 xzke (B) 1 mg (C) 1 xzke (D) 100 mg
6. mikip;h vfHkfØ;k MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O ds fy,

MnO4–, C2O42– rFkk H+ ds fy, lgh iw.kk±d jllehdj.kfefr xq.kkad Øe'k% fuEu gSa &
(A) 2, 5, 16 (B) 5, 2, 8 (C) 2, 5, 8 (D) 5, 2, 16
7. nks xSlksa ¼ftudk eksyj nzO;eku leku gS½ ds ?kuRoksa dk vuqikr 1 : 2 gS o muds rkieku dk vuqikr 2 : 1 gS] rks
muds laxr nkc dk vuqikr fuEu gS %
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 2 : 3
PAGE NO.-9
8. KO2 dk mi;ksx vUrfj{k ok;q ;ku o iuMqCch esa vkWDlhtu flys.Mj es gksrk gS D;ksafd ;g
(A) CO2 vo'kksf"kr djrk gS o O2 ?kVd c<+rk gSA (B) ueh fu"dkflr djrk gSA
(C) CO2 vo'kksf"kr djrk gSA (D) O2 mRiUu djrk gSA
9. tc cksjsDl dks ty esa ?kksyk tkrk gS] rks %

(A) dsoy B(OH)3 curk gSA (B) dsoy [B(OH)4]– curk gSA
(C) B(OH)3 rFkk [B(OH)4]– nksuksa curs gSaA (D) dsoy [B3O3(OH)4]– curk gSA
10. fuEu esa ls dkSulk dFku xyr gS &

(A) vkstksu (O3) leryh; v.kq gSA (B) MkbZvkWDlhtu (O2) izfrpqEcdh; Lih'kht gSA
(C) N2 dk cU/k Øe N 2 ls vf/kd gksrk gSA (D) C2–2 , C2 dh vis{kk vf/kd LFkk;h gSA
11. fuEu esa ls dkSulk yo.k ty eas U;wure foys; gksrk gS \

(A) CaF2 : Ksp = 3.9 × 10–11 (B) PbCl2 : Ksp = 1.6 × 10–5
(C) AgCl : Ksp = 1.8 × 10–10 (D) AgIO3 : Ksp = 3.1 × 10–8
(E) lHkh leku foys; gksrs gS A
12. osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy, f}xa'kh DokaVe la[;k dk eku 'b' gS] rc (b) dk eku Kkr
dhft,A
(A) 6 (B) 2 (C) 3 (D) 1
(E) 'kwU;
13. 29Cu esa dsoy nks uksM j[kus okys iw.kZiwfjr d{kdksa dh la[;k gS &
(A) 5 (B) 9 (C) 3 (D) 7
14. fuEu esa ls dkSu mHk;/kehZ izÑfr n'kkZrk gS \
(A) Li2O (B) BeO (C) Cs2O (D) BaO
15. Si/P/S/Cl o vkWDlhtu ds e/; cU/k ;qDr ;kSfxdksa esa p  d vU;ksU; fØ;k dk Øe gS &
(A) P > Si > Cl > S (B) Si < P < S < Cl (C) S < Cl < P < Si (D) Si > P > S > Cl
16. fuEu esas ls dkSulk dFku xyr gSa\
(A) HF > H2O > NH3 : H– ca/ku dh lkeF;Z
(B) F  H....O  O  H....O  F  H....F : H– ca/ku dh lkeF;Z
(C) H2 O  H2 Te  H2 Se  H2 S : DoFkukad
(D) HF  H2 O  NH3 : f}/kqzo vk?kw.kZ
17. esfFkyhulYQjVsVªk¶yksjkbM (CH2SF4) dh lajpuk esa] fdrus ijek.kq leku ry esa] mifLFkr gksrs gS \
18. ml pH dh x.kuk dhft,] ftl ij] 0.10 M Mg2+ vk;u j[kus okys ,d foy;u ls Mg(OH)2 dk vo{ksi.k çkjEHk gks
tkrk gSA Mg(OH)2 dk ksp = 1.0 × 10–11.
19. vkWDlsfyd vEy dh mnklhuhdj.k Å"ek – 25.4 Kcal mol–1 gS tc izcy {kkj NaOH dks iz;qDr fd;k tkrk gSA
rc izØe] H2C2O4 2H+ + C2O42– ds fy, ,UFkSYih ifjorZu Kkr djksaA
[izcy vEy dh izcy {kkj ds lkFk mnklhuhdj.k dh Å"ek = – 13.7 Kcal mol–1]
20. ,d 10 yhVj vk;ru okys fiLVu ;qDr ik=k esa ty ok"i ls larÌr gkbMªkstu xSl dks
fp=kkuqlkj j[kk tkrk gSA ik=k esa dqN ek=kk esa nzo ty Hkh mifLFkr gSA nzo ty ds
Åij] H2 dk vkaf'kd nkc] Hg dkWye ds 80 cm ds cjkcj gSA ;fn vc fiLVu dks
bl izdkj xfr djk;k tk;s fd ik=k dk vk;ru nqxquk gks tk,] rc ik=k es a nzo ty
ds Åij dqy nkc D;k gksxk \ (H2O dk i`"Bh; ruko = 20 cm of Hg) (H2O nzo ds
vk;ru dks ux.; yhft;s)
dqy nkc ¼ Hg ds lseh - esa)
(viuk mÙkj y ds :i esa nhft,] tgk¡ y = )
10
PAGE NO.-10
21. ,d dkcZfud ;kSfxd esa Hkkjkuqlkj 44.44% dkcZu mifLFkr gSA ;fn ;kSfxd ds iz R;sd v.kq dk Hkkj 2.25 × 10–22 xzke
gS] rks dkcZfud ;kSfxd ds ,d v.kq esa mifLFkr C-ijek.kqvksa dh la[;k Kkr dhft;sA

Daily Self-Study Dosage for mastering Chemistry
I. vukn'kZ foy;u
,d vukn'kZ foy;u og gS tks jkÅYV fu;e dk ikyu ugha djrk gSA bUgs nks çdkj ls foHkkftr djrs gSaA
1. vukn'kZ /kukRed fopyu foy;u 2. vukn'kZ _.kkRed fopyu foy;u
/kukRed fopyu foy;u _.kkRed fopyu foy;u
(i) 
PT  XAPA0  XBPB0  (i) PT  XAPA0  XBPB0
(ii) fdlh ,d 'kq+) vo;o esa vU;ksU; fØ;k dh vis{kk (ii) fdlh ,d 'kq+) vo;o esa vU;ksU; fØ;k dh vis{kk
vUrjk vkf.od vU;ksU; fØ;k nqcZy gksrh gSA vUrjk vkf.od vU;ksU; fØ;k vf/kd gksrh gS
(iii) fefJr djus ij ;gk¡ vk;ru esa deh gksrh gS o

(iii) ;gk¡ fefJr djus ij vk;ru esa o`f+) gksrh gS o
Å"ek dk fu"dklu gksrk gSA
Å"ek dk vo'kks"k.k gksrk gSA
VfeJ.k  ve HfeJ.k   ive
VfeJ.k  /kukRed HfeJ.k  /kukRed
SfeJ.k   ive GfeJ.k   ive
SfeJ.k   ive GfeJ.k   ive
mnk- H2O + HCOOH, H2O + CH3COOH
mnk. H2O + CH3OH, C2H5OH + gSDlsu
H2O + HNO3, CHCl3 + CH3OCH3
C2H5OH + lkbDyksgSDlsu, CHCl3 + CCl4
22. og feJ.k igpkfu;s tks _.kkRed fopyu dk foy;u n'kkZrk gS %

(A) csUthu + (CH3)2CO (B) (CH3)2CO+ C6H5NH2
(C) CHCl3 + C6H6 (D) (CH3)2CO + CS2
23. 55ºC, ij ,FksukWy ds fy, ok"i&nkc 168 mm gS o esfFky lkbDyksgSDlsu ds fy, ok"i&nkc 280 mm gSA bu nks
foy;uksa esa ftlesa ,FksukWy dk eksy&fHkUUk 0.68 gS o dqy ok"i nkc 376 mm gSA ;g foy;u fuEu ds lkFk blds
vo;oksa ls curk gSA
(A) Å"ek ds fu"dklu
(B) Å"ek ds vo'kks"k.k
(C) u rks Å"ek ds vo'kks"k.k vkSj uk gha Å"ek ds fu"dklu lsA
(D) nh xbZ tkudkjh ds vk/kkj ij buesa ls fdlh dks crk;k ugha tk ldrk gSA
24. 
1 eksy A PA0  150mm  o 2 eksy B PB0  240mm  ds feJ.k dk dqy ok"i nkc 200 mm gSaA bl fLFkfr esa
(A) jkÅYV fu;e ls /kukRed fopyu gksrk gSA
(B) jkÅYV fu;e ls _.kkRed fopyu gksrk gSA
(C) jkÅYV fu;e ls dksbZ fopyu ugha gksrk gSA
(D) fopyu dks tk¡pus ds fy, A o B ds v.kqHkkjksa dh Hkh vko';drk gksrh gSA
25. ml feJ.k dks igpkfu, tks vukn'kZ foy;u ds /kukRed fopyu dks n'kkZrk gSA
(A) CH3COCH3 + CS2 (B) gSDlsu + gsIVsu
(C) DyksjkscsUthu + czksekscsUthu (D) ,lhVksu + DyksjksQkWeZ
PAGE NO.-11

Comprehension ('–1' negative marking) Q.8 to Q.10 (3 marks, 2 min.) [09, 06]
1. 0.1 M lkanzrk okys 10 mL nqcZy {kkj BOH ds 0.1 M HCl ds lkFk vuqekiu esa rqY;kad fcUnq ij pH = 5 gSA BOH
dk pKb Kkr dhft;s& (log 2 = 0.30)
(A) 6.3 (B) 5.3 (C) 4.3 (D) 7.3
(E) buesa ls dksbZ ugha
2. 1L cQj foy;u 1 eksy (CH3COO)2Ca rFkk 1 eksy CH3COOH ;qDr gSA fuEu esas ls dkSulk dFku lgh gS ?
(pKa = 4.7) (log 2 = 0.30)
(A) pH = 9 (B) pOH = 9 (C) pH = 4.4 (D) pOH = 8.6
(E) pH = 14
3. fuEu esa ls dkSulk dFku lgh gSA
(A) TC esa uhps rkieku ij lg laca/k lEHko ugh gS fd ,d xSl dks lEihfMr fd;k tk ldrk gSA
(B) TC, ls uhps rkieku ij vkd"kZ.k cy ds dkj.k v.kq ,d nwljs ds dkQh utnhd vk tkrs gSa rFkk lEihM~u gksrk gSA
(C) TC ds Åij lEihM~u lEHko ugha gSA
(D) TC, ds Åij xSl v.kqvksa dh xfrt ÅtkZ vf/kd gksrh gSA bUgs vrh ØkafUrd nzo ekuk tkrk gSA
4. (SiH3)3N ds fy, fuEu esa ls dkSulk dFku xyr gSa &
(A) (SiH3)3N leryh; gSA
(B) (SiH3)3N js[kh; gSA
(C) (SiH3)3N ds fy, N esa mifLFkr ,dkdh ;qXe i'p&vkcU/ku ds vUrZxr ugha vkrk gSA
(D) mijksDr v.kq esa 9 flXek cU/k gksrs gSA
5. izkjfEHkd nkc Pi vk;ru Vi ij ,d vkn'kZ xSl ;k rks lerkih; ;k :)ks"eh; ij leku vk;ru Vf ds lkFk mRØe.kh;
:i ls izlkfjr gksrs gSA fuEufyf[kr dFkuksa esa ls dkSu dFku lgh gS@gSa \ tgk¡ izrhd Loa; dk lkekU; vFkZ j[krs gSA
(A) |Pf (:)ks"eh;) < Pf (lerkih;)| (B) |W(:)ks"eh;)| < |W (lerkih;)|
(C) |Tf (:)ks"eh;) < Tf (lerkih;)| (D) |q(:)ks"eh;)| < |q (lerkih;)|
6. fgekad fcUnq ds vou;u iz;ksx ds fy, , fuEu esa ls dkSulk@dkSuls dFku lgh gS /gSa :
(A) 'kq) foyk;d dk ok"inkc,foy;u fd rqyuk esa vf/kd gksrk gSA
(B) 'kq) foyk;d dk ok"inkc,foy;u fd rqyuk esa de gksrk gSA
(C) fgekad fcUnq ij dsoy foy; ds v.kq] Bksl esa ifjofrZr gksrs gSA
(D) fgekad fcUnq ij dsoy foyk;d ds v.kq Bksl esa ifjofrZr gksrs gSA
7. fuEu esa ls dkSuls foy;u ;qXeksa ds fy, okUVgkWQ dkjd (factor) dk eku leku gksxkA
(A) 0.05 M K4 [Fe(CN)6] rFkk 0.10 M FeSO4
(B) 0.10 M K4[Fe(CN)6] rFkk 0.05 M FeSO4.(NH4)2SO4. 6H2O
(C) 0.20 M NaCl rFkk 0.10 M BaCl2
(D) 0.05 M FeSO4.(NH4)2SO4.6H2O rFkk 0.02 M KCl.MgCl2.6H2O.
vuqPNsn #
rki T ij A rFkk B nks 'kq) nzo ds nkc Øe'k% 400 mm rFkk 800 mm Hg gSa, tks fd vkn'kZ foy;u cukrs gSA ,d
nzo] tks fd 3 : 1 eksyj laxBu j[krk gS] dk nkc ifjofrZr gks ldrk gSA foy;u rki T ij /khjs &/khjs ok"ihd`r gksrk
gS tc yxk;s x;s nkc esa deh dh tkrh gS] ;g yxk;k x;k nkc 760 mm Hg ls izkjEHk gksrk gSA yxk;s x;s nkc ds
ekiu ds fy;s ,d nkcekih (mm esa) yxk;k x;k gSA
PAGE NO.-12
8. tc dsoy nzo voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad gS \
(A) 499 (B) 399 (C) 299 (D) dksbZ ugha
9. cqycqyk fcUnq ij nkc ekih dk ikB~;kad gSA
(A) 500 (B) 600 (C) 700 (D) dksbZ ugha
10. tc dsoy ok"i voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad fuEu gSA
(A) 501 (B) 457.14 (C) 425 (D) 525
11. ,d eksuksdkcksZfDlfyd vEy ds lksfM;e yo.k ds 0.01 M foy;u dh pH = 9 gSA vEy dk pKa ……… gksxkA
12. 500 xzke ty esa ,d f}yd oS|qr vi?kV~; ds 20 xzke (vkf.od Hkkj = 100) dks ?kksyk tkrk gSaA foy;u dk fgekad
0.74°C ; Kf = 1.86 K eksyjrk–1 gSA oS|qr vi?kV~; dk izfr'kr fo;kstu Kkr djksA
13. gkbMªkstu gSykbM ds xq.kèkeksZ esa fuEu izo`fÙk dk voyksdu dhft,&
1. vEyh; lkeF;Z : HF < HCl < HBr < HI 2. rkih; LFkkf;Ro : HF > HCl > HBr > HI
3. f}èkzqo vkèkw.kZ : HF < HCl < HBr < HI 4. vipk;d {kerk : HF > HCl > HBr > HI
lgh izo`fr dh la[;k Kkr djks A
14. feyku dhft,A
LrEHk I LrEHk II
(A) 0.1 M Al2(SO4)3 (p) mPpre DoFkukad dk foy;uA
(B) 0.1 M AlPO4 (q) okWUV gkWQ dkjd 1 ls vf/kdA
(C) 0.1 M ;wfj;k (r) U;wure ijklj.k nkc dk foy;uA
(D) 0.1 M MgCl2 (s) U;wure fgekad dk foy;uA

Daily Self-Study Dosage for mastering Chemistry vfeJ.kh; nzo
tc ,d ok"i'khy nzo dks vU; ok"i'khy nzo esa feyk;k tkrk gS] tks ,d&nwljs ds lkFk iw.kZ :i ls vfeJ.kh; gS] izR;sd nzo
vU; nzo ds lkFk Lora=k :i ls O;ogkj djrk gS o blds Lo;a dk Okk"i&nkc yxk;sxkA vf/kd ?kuRo okyk nzo (A) fupyh ijr
cuk,xk o de ?kuRo okyk nzo (B) dks nzo (A) esa ls izokfgr djsaxsA rU=k ds dqy ok"inkc] nksuksa ok"i'khy nzoksa ds ok"inkc dk
;ksx gksxkA
Pdqy = PA + PB = PA0 + PB0 (pwafd XA & XB = 1)
,d nzo dk DoFkukad og rkieku gS ftl ij bldk ok"i&nkc blds cká nkc ds cjkcj gksxkA vfeJ.kh; ok"i'khy
nzo ;qDr ,d feJ.k dk dqy ok"i&nkc] buesa ls izR;sd 'kq) vo;o ls vf/kd gksrk gSA bl izdkj feJ.k ,d rkieku ij
mcyrk gS tks fd buesa ls fdlh Hkh 'kq) vo;o ds DoFkukad ls de gksrk gSA
;g Hkkih; vklou dk vk/kkj cukrk gS] ftlesa ,d ok"i'khy nzo ty gSA
nzo feJ.k ds Åij ok"i ds bl laxBu dks fuEu dks iz;qDr dj ifjdfyr fd;k tkrk gSA
vkaf'kd nkcksa dk MkWYVu fu;e
PA = PA0 = PTotal XA’ .......(i)
PB = PB0 = PTotal XB’ .......(ii)
XA' o XB' ;gka ok"i izkoLFkk esa A o B ds eksy&fHkUu dks iznf'kZr djrs gSA
PTotal XB ' PB WB PB  MB
 
PTotal XA ' PAº WA PA  MA
ok"i ¼vklou½ esa vo;oksa dk nzO;eku] ok"inkc ds Øe'k% eksy nzO;eku ds lekuqikrh gksaxsA
PAGE NO.-13
15. 90ºC o 732 Vksj nkc ij ,d dkcZfud nzo o ty ds vfeJ.kh; nzo ds ,d feJ.k dks mckyk tkrk gSA vklou
dkcZfud nzo ds Hkkj dk 73% j[krk gSA dkcZfud nzo dk eksyj&nzO;eku ifjdfyr dhft, (90ºC ij ty dk
ok"inkc 526 Vksj gS)
(A) 168.2 xzke eksy–1 (B) 228.8 xzke eksy–1 (C) 122.2 xzke eksy–1 (D) 62.7 xzke eksy–1
16. tc 740.2 mm Hg, ds ,d cká nkc ij ty o DyksjkscsUthu ds ,d feJ.k dks vklfor fd;k tkrk gS] rks feJ.k
dks 90.3ºC ij mckyk x;k] ftl rkieku ij 'kq) ty dk ok"inkc 350.1 mmHg gSA vklou eas DyksjkcsUthu ds
Hkkj dk izfr'kr ifjdfyr dhft,A( v.kqHkkj 112).
(A) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
17. ,d vKkr ;kSfxd ty ds lkFk vfeJ.kh; gSA bldk Hkkih; vklou 98.0ºC ij gS o P = 737 Vksj]
Pº(H2O) = 707 Vksj gSA ;g vklou ty ds Hkkj dk 75% gSA vKkr dk v.kqHkkj ifjdfyr dhft,A
(A) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8

1. vfHkfØ;k esa A(s) + B(g) + Å"ek 2C(s) + 2D(g) esa] lkE; LFkkfir gksrk gSA B dk nkc lkE; dks iqu% LFkkfir
djus ds fy, nqxquk fd;k tkrk gS D fdl dkjd ls ifjofrZr gksxkA)
(A) 2 (B) 3 (C) 2 (D) 3
2. dSFkksM fdj.k ds fy, e/m vuqikr
(A) fu;r gksrk gSa
(B) ifjofrZr gksrh gSa tSls gh foltZu ufydk esa cuk;s x;s dSFkksM es mifLFkr rRo dk ijek.kq Øekad ifjofrZr gksrk gSA
(C) ifjofrZr gksrk gS tSls gh foltZu ufydk esa xSl dk ijek.kq Øekad ifjofrZr gksrk gSA
(D) lcls de eku gksrk gSa tc folZtu ufydk dks gkbMªkstu ds lkFk Hkjk tkrk gSA
3. ,d xSl 'X' ds fuf'pr vk;ru dks ,d lw{e fNnz }kjk folfjr gksus esa yxk le; 2 feuV gSA leku ifjfLFkfr;kssa esa
vkWDlhtu xSl ds folj.k esa yxk le; 5.65 feuV gSA rc 'X' dk eksyj nzO;eku gSA .
(A) 8 (B) 4 (C) 16 (D) 32
4. H–ijek.kq (Z = 1) ds fy, cksgj d{kk dh f=kT;k yxHkx 0.53 Å gSA rc izFke mRrsftr d{kk voLFkk ds fy, f=kT;k
gksxhA
(A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D) 2.12 Å
+
5. pH = 13 ds 1cc foy;u esa H vk;uksa dh la[;k D;k gS \
(A) 6.023 × 107 (B) 1 × 10–13 (C) 6.023 × 1013 (D) 1 × 1016
6. H = – 176 kJ, S = – 284.5 JK–1 gS rks fdl rki ij vfHkfØ;k Lor% gksxh&
(A) 380 K (B) 480 K (C) 580 k (D) 680 K
7. ,d 0.1 A dk lksfM;e ,flVsV dk foy;u cuk;k tkrk gSA ftldh Kh = 5.6 × 10–10 gSA lgh dFku gS&
(A) ty vi?kVu dh ek=kk 7.48 × 10–4 gSA (B) [OH–] = 7.48 × 10–5 gSA
(C) [OH–] = 7.48 × 10–6 M gSA (D) pH yxHkx 7 ds cjkcj gSA
8. ;fn 25ºC ij ¶yksjkbM vk;u ds fy, pKb dk eku 10 gS] rks bl rki ij ty esa gkbMªks¶yksfjd vEy dk vk;uu
fLFkjkad gksxk&
(A) 10–5 (B) 10–3 (C) 10–4 (D) 10–2
9. vfHkfØ;k Fe2O3(s) + 3CO(g)  3CO2(g) + 2 Fe() ds fy,] fuEu esa ls dkSulk lR; gS&
(A) Hº = Eº + 3RT (B) Hº = Eº + RT (C) Hº = Eº (D) Hº = Eº  RT
PAGE NO.-14
10. fuEu esa ls fdl izØe esa ,UVªkWih esa deh vkrh gS %
(A) Bksl dk nzo esa ifjorZu (B) ,d xSl dk izlkj
(C) fØLVy dk ty esa foys; gksuk (D) cgqyhdj.k (E) H2 dk leka'k fo[k.Mu
11. ,d rRo Z dh izFke rhu Øekxr vk;uu ÅtkZ;s Øe'k% 900, 1757 rFkk 14850 kJ mol–1 gSA rRo Z lEcfU/kr gS %
(A) oxZ-1 ls (B) oxZ-2 ls (C) oxZ-15 ls (D) oxZ-17 ls
12. (i) Br2 + 2NaOH [BaMk]  NaBr + (X) + H2O
(ii) 2Br2 + 6NaOH [xeZ]  NaBr + (Y) + H2O
X rFkk Y esa Br dk vkWDlhdj.k vad Øe'k% gS \
(A) +1, +7 (B) +1 , +5 (C) +4, +5 (D) +3, +5
13. fuEu esa ls fdldh mifLFkfr ds dkj.k] lksfM;e /kkrq dk nzo veksfu;k esa foy;u] çcy vipk;d gksrk gS %
(A) lksfM;e ijek.kq (B) lksfM;e gkbMªkbM (C) lksfM;e ,ekbM (D) foyk;fdr bysDVªkWu
14. lkj.kh-I dks lkj.kh-II ls lqesfyr dhft, rFkk fn;s gq;s dksM dk mi;ksx djrs gq, lgh mÙkj p;fur dhft,A
lkj.kh-I lkj.kh-II
A. (SiH3)3N 1. f=kdsUnzh; nks bysDVªkWu ca/k
B. BF3 2. sp3-ladj.k
C. SiO2 3. p–p ca/k
D. B2H6 4. p–d ca/k
A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D) 4 3 2 1
15. cksjsDl dk ,d tyh; foy;u gS %
(A) mnklhu (B) mHk;/kehZ (C) {kkjh; (D) vEyh;
16. og vkWDlkbM tks fd vipk;d ugha gS] fuEu gS %

(A) CO2 (B) CO (C) SO2 (D) nksuksa (A) rFkk (C)
17. HBr dk f}/kzwo vk/kw.kZ 7.95 fMckbZ gSa rFkk vUrkZf.od i`Fkd~ dj.k 1.94 × 10–10 m gSaA HBr v.kq esa % vk;fud y{k.k
Kkr dhft,A
18. ,d foy;u ftldh pH = 12 gS esa 25º C ij 0.5 M NH3 ds fo;kstu dksfV ds % dh x.kuk djksA
19. ,d jklk;fud vfHkfØ;k : A  P (Hº = 2.8 kJ) dsoy 400 K rki ls vf/kd rki ij gh Lor% gksrh gSA rc bl
vfHkfØ;k ds fy, Sº dk U;wure eku (J/K esa) Kkr djks \
20. tc CaCO3 dks vR;f/kd xeZ djrs gS] rks N.T.P. ij 5.6 yhVj CO2 rFkk ,d vo'ks"k curk gSaA izkIr gksus okys bl
vo'ks"k dk Hkkj Kkr dhft,\
21. fuEu esa ls fdruh ¼Lih'kht dh vf/kdre la[;k½ Lih'kht N2 ds lkFk lebySDVªkWfud gSa \
CN–, Si, NO–, CO, O22+, C22–, C2H4, CH3+, MgH2

Daily Self-Study Dosage for mastering Chemistry f}yo.k rFkk fQVdjh ¼,ye½
f}yo.k rFkk fQVdjh ¼,ye½ : lkèkkj.k ;k ,dd yo.k ,d èkuk;fud ?kVd rFkk ,d _.kk;fud ?kVd j[krk gSA mnkgj.k
NaCl, Ca(OH)2, Na2SO4 vkfnA f}yo.k fuf'pr vuqikr esa fy;s x;s nks fHkUu yo.kksa ds feJ.k ls cukrk gS ftlesa ,d ls
vfèkd èkuk;u rFkk _.kk;u gks rs gSaA tks fd leku fu;r vk;fud tkyd esa fØLVyhd`r gksrs gSaA f}yo.k lekU;r% cMs
fØLVy cukrs gSaA rFkk ,d 'kq) inkFkZ ds :i esa izkIr gksrs gaSA okLro esa] fØLVyhd`r f}yo.k Bksl :i esa Bksl dk foy;u
gksrk gSA
f}yo.k rFkk ladqy yo.k esa vUrj % f}d~yo.k dsoy Bkslksa ds :i esa gksrk gSA tc f}yo.k dks ty esa ?kksyk tkrk gS rks ;g
lkèkkj.k vk;uksa esa iw.kZ :i ls fo;ksftr gks tkrk gS] tcfd ladqy yo.k fo;ksftr ugh gksrk gS] ladqy vk;u vifjofrZr jgrs gSA
PAGE NO.-15
+ 3+
mnkgj.k ds fy,- KCeF4 f}yo.k gksrk gS rFkk ty esa ?kksyus ij K , Ce rFkk F vk;u nsrk gS] tcfd K4 [YbI6] ladqy yo.k
–
gksrk gS rFkk fooZr [YbI6]4– vk;u j[krk gS tks tyh; foy;uksa esa fo;ksftr ugha gksrk gSA
f}yo.k foy;u esa lHkh O;fDrxr (individual) vk;uksa dk èkukRed ijh{k.k ns ldrs gSaA ijUrq] ladqy yo.k O;fDrxr vk;uksa
dk èkukRed ijh{k.k ugha ns ldrs gSA
f}yo.k rFkk ladqy yo.k ds eè; Hkze dks nwj djus ds fy,] ladqy vk;u ;k Hkkx dks xq: dks"Bd [ ] esa fy[krs gaSA
f}yo.k ds mnkgj.k: feujy MksyksekbV: CaMg(CO3)2;
eksj yo.k : (NH4)2SO4·FeSO4·6H2O
dkusZykbV : KCl.MgCl2·6H2O
iksVk'k ,ye : K2SO4·Al2(SO4)3·24H2O i.e. KAl(SO4)2·12H2O
,ye : f}yo.k dk lokZfèkd lkekU; mnkgj.k ,ye gSA ,ye~ f}d~ lYQsV yo.k gksrs gSaA ftudk lkekU; lw=k
AM(SO4)2·12H2O gS] tgk¡ A ,dd la;ksth èkuk;u tSls K ;k Na gS rFkk M, f=kla;ksth èkkrq èkuk;u tSls Al ;k Cr gSA
,ye ds mnkgj.k % lksMk ,ye : NaAl(SO4)2·12H2O

veksfu;e ,ye: NH4Al(SO4)2·12H2O,
Økse ,ye : KCr(SO4)2·12H2O
,ye ds mi;ksx %
i. jDr LdUnu ds :i esa ¼lkekU;r 'ksafox (shaving) ds ckn iz;qDr)
ii. Losn jksèkh (antiperspirant) rFkk izfrthokf.od (antibacterial) xq.k ds dkj.k ç;qDr
iii. ,ye dk mi;ksx] 'kh?kzrk ls volknu izØe }kjk ty ds 'kqf}dj.k esa fd;k tkrk
gSA bl izØe esa Å.kZu izfØ;k (NksVs fuyfEcr d.kksa dk ijLij laxqf.kr gksuk ) ds varZxr
ty esa mifLFkr vokaNfu; d.k ijLij] laxqf.kr gSA (,ye dh mifLFkfr esa
fo|qr vkos'k iz;qDr djus ij ) gksdj cM+s vkdkj ds d.kksa dk fuekZ.k djrs gaSA tks fd ik=k ds ry esa vo{ksfir gks tkrs gS
ftUgsa ljyrk ls i`Fkd fd;k tk ldrk gSA
22. fuEu esa ls dkSulk f}yo.k gS\
(A) Al2(SO4)3 (B) NaOH
(C) Na2SO4.Al2(SO4)3.24H2O (D) [Cr(H2O)6]Cl3
23. 1 eksy dkusZykbV tyh; foy;u esa vk;uksa ds fdrus eksy nsxk \
(A) 2 (B) 4 (C) 5 (D) 6
24. iksVk'k ,ye dk tyh; foy;u fuEu esa ls fdl vk;u dk èkukRed ijh{k.k nsxk\
(A) K+ (B) Al3+ (C) SO42– (D) mijksDr lHkh
25. K3[Fe(CN)6] dk tyh; foy;u fuEu esa ls fdl vk;u dk èkukRed ijh{k.k nsxk\
(A) K+ (B) Fe2+ (C) Fe3+ (D) CN–

1. pH < 7 okys cQj foy;u esa CH3COOAg dh foys;rk ds fy, lgh dFkuksa dk p;u dhft,A
(A) CH3COOAg dh foys;rk] pH esa deh ds lkFk c<+rh gSA
(B) CH3COOAg dh foys;rk] pH esa deh ds lkFk ?kVrh gSA
(C) pH = 5 ds cQj foy;u esa CH3COOAg dh foys;rk] 'kq) ty esa foys;rk dh rqyuk esa vf/kd gksxhA
(D) pH = 6 ds cQj foy;u ds CH3COOAg dh foys;rk] K sp dh rqyuk esa de gksxhA tgk¡ Ksp, CH3COOAg
dk foys;rk xq.kuQy gSA
PAGE NO.-16
2. fuEu esa ls dkSuls dFku H3BO3 ds fy, lgh ugha gSa ?
(A) ;g fo"ke bysDVªkWu v.kq gSA
(B) ;g ty esa izksVksu nkrk dh rjg dh rjg dk;Z djrk gSA
(C) ;g Bksl voLFkk esa gkbMªkstu ca/ku j[krk gSA
(D) ;g vEyksa ds lkFk vuqekiu ds fy, mi;ksxh izkFkfed ekud foy;u gSA
3. ca/k dks.k dk lgh Øe gS@gSa %
(A) H2O > H2S > H2Se > H2Te (B) C2H2 > C2H4 > CH4 > NH3
(C) SF6 < NH3 < H2O < OF2 (D) ClO2 > H2O > H2S > SF6
4. pH = x okys ,d cQj foy;u esa Fe(OH)3 dh foys;rk 4.32 × 10–2 mol/L gSA fn;k gS% Fe(OH)3 dk
Ksp = 4.32 × 10–32 M4 rks x dk eku gS (Fe3+ vk;uksa ds tyvi?kVu dks udkfj,) &
5. fu"dkflr xSl dh ijek.oh;rk D;k gksxh tc 'osr QkLQksjl dh dkfLVd lksMk ds lkFk fØ;k djkbZ tkrh gS \
6. v.kq lw=k NanAlnSi94O192 esa n dk eku gS %
7. vkorZ lkj.kh esa 18 oxZ (group) gSA fta+d (Zn) ds ,d leLFkkfud (isotope) ij U;wVªkWu (neutron) ls ceckjh
(bombardment) djus ij uhps fn[kkbZ x;h ukfHkdh; vfHkfØ;k (nuclear reaction) gksrh gS ftleas rRo X izkIr gksrk
gSA rRo X vkorZ lkj.kh ds fdl lewg esa gS\ 3064
Zn 10 n  X  2 11 H
8. fuEu ds fy, IUPAC uke fyf[k,&
(a) Na2[Fe(CN)5NO] (b) [Ni(DMG)2] (c) NH4[Cr(SCN)4(NO)2] (NO is nitrosyl)
(d) [Pd(H2O)2 I2(ONO)2] (e) [Co(NH3)4 Cl(NCS)]+ (f) K4[FeO4]
(g) K2[Co(N3)4] (h) [Ni(PPh3)2Cl2] (i) [Cr(acac)3] (j) [Pt(C5H5N)4][PtCl4]
9. fuEu IUPAC ukeksa ds laxr izR;sd ds lajpuk lw=k dks fyf[k,&
(a) gSDlk,Dokvk;ju(II) DyksjkbM (b) iksVSf'k;eVsVªk¶yksjkbMksvtsZUVsV (III)
(c) isUVkDyksjkbMksVkbVusV(II) vk;u (d) VsªVk,EehuMkbDyksjkbMksdksckYV (III) DyksjkbM
(e) Mkblk;ukbMks-C-vtsZUVsV(I) vk;u (f) Mkb,EehuVsVªkDyksjkbMksfudysV(II) vk;u
(g) fVªl~ (,FkkbyhuMkb,ehu)dkWij (II) lYQsV (h) lksfM;eMkb,DokVsVªkgkbMªkWDlkbMks,Y;qfeusV (III)
(i) ,EehuDyksjkbMksfcl~(,FkkbyhuMkb,ehu~)Øksfe;e (III) lYQsV (j) iksVSf'k;eVsVªklk;ukbMks-C-ftadsV(II)
10. dkWye–I esa lwph c) fyxs.Mksa dks

dkWye–II esa lwph c) vfHkyk{kf.kd fyxs.Mksa ds izdkj xq.kksa ls lqesfyr dhft;sA
dkWye-I dkWye-II
A. ,flfVy,lhVksusVkas (p) vuqukn ds dkj.k LFkkf;Ro
B. vkWDlsyV s ks (q) ,dy _.kk;u
C. MkbZesfFkyXykbvkWfDlesVkas (r) dhysV fyxs.M
D. ukbVªkbVks (s) mHk;narqd fyxs.M
(t) ,dynarqd
uksV % vuqukn LFkk;hdj.k ds fy, fyxs.M dks dsoy eqDr vk;uksa ds :i esa ekuk tk;sA
ChemINFO Coordination Compounds

Daily Self-Study Dosage for mastering Chemistry lsrq fyxs.M ds lkFk cgq dsUædh; ladqyks dk ukedj.k
;fn ladqy nks ;k nks ls vf/kd dsUæh; /kkrq ijek.kq ;k vk;u j[krk gS] cgqdsUnzdh; dgykrk gSA fdlh cgqdsUnzdh; ladqyksa esa
fyxs.M nks /kkrq ijek.kqvksa ;k vk;uksa ls tqMs gksrs gSA os fyxs.M tks cgqdsUædh; ladqyksa esa nks /kkrq ijek.kqvksa ;k vk;uksa ls tqMs
gksrs gSaA lsrq fyxs.M dgykrs gSaA ;s lsrq fyxs.M] 'ks"k ladqy dks gk;Qu (–)}kjk i`Fkd djrs gaS rFkk iwoZyXu m }kjk n'kkZrs gSA
fu;e 1: ;fn ;kSfxd es lsrq ds nksuks rjQ ds Hkkx vlefer gaS] rc gesa ,d vksj dk uke fy[kuk pkfg, fQj lsrq dk rFkk fQj
nwljh vksj dk uke fy[kuk pkfg, tSls %
PAGE NO.-17
VªsVk,DokdksckYV (III)-m-,ekbMks-mgkbMªksDlkbMksVªsVk,ehuØksfe;e (III) lYQsV

fu;e 2: tc v.kq lefer gS] rc ;kSfxd dk uke] lsrq fyxs.M ds uke dks igys fy[kdj fn;k tkrk gSA
5
 3 1 3 
(NH3 )5 Cr OH – Cr (NH3 )5  Cl5
 
m-gkbMªksDlkbMksfcl (isUVk,Eehu Øksfe;e (III)) DyksjkbM ;k
ge lsrq ds ,d vksj dk uke fQj lsrq ladqy dk uke rFkk fQj lsrq ds nwljh vksj dk uke çFke fu;e ds vuqlkj Hkh fy[k
ldrs gSA tSls % isUVk,Eehu Øksfe;e (III)-m-gkbMªksDlkbMksisUVk,Eehu Øksfe;e (III) DyksjkbM
fu;e 3: ;fn leku çdkj ds nks ;k nks ls vf/kd lsrq lewg mifLFkr gksa] rks ;g MkbZ –m–, VªkbZ –m– vkfn }kjk n'kkZ;s tkrs
gSA
(SO4)2
MkbZ-m-gkbMªksDlkbMksfcl(VªsVk,Dokvk;ju(III)) lYQsV
mnkgj.k:
(SO4)2
m-,ekbMks-m-gkbMªksDlkbMksfcl (fcl(,FkkbyhuMkbZ,Eehu)dksckYV(III)) lYQsV

;k
fcl(,FkkbyhuMkbZ,Eehu) dksckYV(III)-m-,ekbMks-m-gkbMªksDlkbMksfcl(,FkkbyhuMkbZ,Eehu)dksckYV(III) lYQsV
11. dk lgh uke D;k gS\
(A) -,ekbMks--gkbMªksDlkbMksfcl (VªsVk,EehudksckYV (III)) vk;u

(B) -gkbMªksDlkbMks--,ehMksMkbZ(VªsVk,EehudksckYV (III)) vk;u
(C) MkbZ--,ekbMks-gkbMªksDlkbMksfcl(VªsVk,EehudksckYV (III)) vk;u
(D) VªsVk,EehudksckYV(III)--,ekbMks--gkbMªksDlkbMks VªsVk,Eehu dksckYV (III) vk;u
4+
NH3 NH3
H3N O2 NH3
12. Co Co
H3N N NH3
H3N H2 H3N
;fn nksuksa dksckYV vk;u +3 vkWDlhdj.k voLFkk j[krs gaS rks mDr ladqy esa lsrq fyxs.M gksxkA
(A) ,ekbM rFkk MkbZvkWDlhtu (B) ,ekbM rFkk ijkWDlkbM
(C) ,ekbM rFkk lqijkWDlkbM (D) ,ehu rFkk ijkWDlkbM
PAGE NO.-18
13. ;fn nksuks dksckYV vk;u leku vkWDlhdj.k la[;k j[krs gaS rks [(NH3)5Co–NH2–Co(NH3)5](NO3)5 dk IUPAC uke
gS
(A) -,ehuksfcl(isUVk,EehudksckYV(III)) ukbVªsV (B) -,ekbMksfcl(isUVk,EehudksckYV(III)) ukbVªsV
(C) -,ekbMksfcl(isUVk,EehudksckYV(III)) isUVkukbVsªV (D) MkbZ--,ekbMksfcl(isUVk,EehudksckYV(III)) ukbVsªV
14. fcl ¼,FkkbyhuMkbZ,ehu½dksckYV(III)--bekbMks--gkbMªksDlkbMksfcl¼,FkkbyhuMkbZ,ehu½ dksckYV (III) DyksjkbM vk;uksa

dh la[;k cjkcj gS %
(A) 1 (B) 2 (C) 3 (D) 4

1. lkE; ij ,d can fudk; es fuEu vfHkfØ;k dk voyksdu dhft,A
CaCO3(s) CaO(s) + CO2(g)
CO2 dh lkE; lkUnzrk ij CaCO3 dks feykus dk D;k izHkko gksxk \
(A) o`f) gksxh (B) dgk ugha tk ldrk gS
(C) deh gksxh (D) vizHkkfor jgsxk
2. ,d dkcZfud ladqy ;kSfxd dkcZu ds 21 ijek.kq izfreksy j[krk gSA ;kSfxd esa dkcZu dk 70% mifLFkr gSA ;fn 36
xzke inkFkZ (substance) dks 100 mL ikuh es feyk;k tk;s rc foy;u dh eksyjrk gksxh –
(A) 1 (B) 0.1 (C) 1.43 (D) 0.143
3. vfHkfØ;k esa] CO2 rFkk SO2 nksuksa dh laHkou Å"ek;s _.kkRed gS rFkk 4 : 3 ds vuqikr esa gSA CS2 dh laHkou dh
,UFkSYih +26kcal/mol gSA SO2 dh laHkou dh ,UFkSYih x.kuk dhft;s \
(A) – 90 kcal/mol (B) – 52 kcal/mol (C) – 78 kcal/mol (D) – 71.7 kcal/mol
4. 25°C ij vfHkfØ;k X2O4()  2XO2(g) ds fy, H = 2.1 Kcal rFkk S = 20 cal K–1 gSA vfHkfØ;k %
(A) Lor% gksxh (B) vLor% gksxh
(C) lkE; ij gksxh (D) ds fy, dgk ugha tk ldrk gS
5. fuEu esa ls dkSulk dFku vlR; gS \
(A) fHkUu foyk;dksa ls cus leku eksyyrk ds lwØkst ds nks fHkUu foy;uksa dk fgekad esa voueu leku gksrk gSA
(B) foy;u dk ijklj.k nkc lehdj.k  = CRT }kjk fn;k tkrk gS (tgk¡ C foy;u dh eksyjrk gS).
(C) csfj;e DyksjkbM] iksVsf'k;e DyksjkbM] ,flfVd vEy rFkk lwØkst ds 0.01 M tyh; foy;u ds ijklj.k nkc ds
fy, ?kVrk gqvk Øe gS % BaCl2 > KCl > CH3COOH > lwØkst
(D) jkWÅYV ds fu;ekuqlkj foy;u ds ok"i'khy ?kVd }kjk yxk;k x;k ok"inkc foy;u esa blds eksy izHkkt ds
lekuqikrh gksrk gSA
6. Lih'kht C2 j[krk gSA
(A) ,d  ca/k rFkk ,d  ca/k (B) nksuksa  ca/k
(C) nksuksa  ca/k (D) vfLrRo ugha j[krk gSA
7. pH = 6 ds ,d vEy foy;u dks 1000 xquk ruq fd;k x;kA rc ifj.kkeh foy;u dk pH D;k gks tkrk gSA
(A) 6.99 (B) 6 (C) 3 (D) 9
8. fuEu esa ls fdldh bySDVªkWu ca/kqrk vf/kdre gS \
(A) Li+ (B) Na+ (C) F– (D) Cl–
9. igys ,d [kkyh ik=k dk Hkkj eki dj NTP ij mls vkDlhtu ls Hkjdj Hkkj ekirs gSA vc bl ik=k dks fuokZfrr
djds mlh leku rki vkSj nkc ij SO3 ls Hkjdj nksckjk Hkkj ekirs gSA vkDlhtu dk Hkkj gksxk
(A) SO3 ds leku (B) SO3 dk 4 xquk (C) SO3 dk 0.4 xquk (D) SO3 dk 0.25 xquk
PAGE NO.-19
+
10. fuEu esa ls fdldks ikuh esa ?kksyus ij [H ] vk;u dh lkUnzrk vf/kdre gksxhA ;fn lcds eksy cjkcj gks &
(A) LiOH (B) NaOH (C) KOH (D) RbOH
11. ,d DyksjkbM B.Ms ikuh es ?kqy tkrk gSA tc bls IysVhue ¼platinum½ ds rkj ij j[kdj cqUlsu Tokyk esa xeZ djrs
gS rks dksbZ jax izkIr ugh gksrk gSA og /kuk;u gS&
(A) Ca2+ (B) Mg2+ (C) Ba2+ (D) Pb2+
12. DoFkkukadekih (ebullioscopic) vuqekiu ds nkSjku dkSuls foyk;d dk mi;ksx djuk vPNk gSA
(A) mPp Kb (B) fuEu Kb (C) Kb = Kf (D) Kf < Kb
13. CO2 ds lEHkou dh ekud eksyj ,UFkSYih fdlds cjkcj gS -

(A) 'kwU;
(B) xSlh; dkcZu ds ngu dh ekud eksyj ,UFkSYih ds cjkcj gS
(C) CO vkSj O2 dh ekud eksyj ,UFkSYih ds ;ksx ds cjkcj gS
(D) C(s) ds ngu dh ekud eksyj ,UFksYih ds cjkcj gS
14. fuEu esa ls dkSu {kkjh; e`nk /kkrqvksa ds ty;ksftr vk;u dh f=kT;k ds ?kVrs gq, lgh Øe dks n'kkZrk gS%
(A) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Sr2+ (aq) > Ba2+ (aq)
(B) Ba2+ (aq) > Sr2+ (aq) > Ca2+ (aq) > Mg2+ (aq) > Be2+ (aq)
(C) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Ba2+ (aq) > Sr2+ (aq)
(D) Ba2+ (aq) > Sr2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Be2+ (aq)
15. fuEu ladqy ds uke rFkk lw=k ds ;qXeksa esa ls dkSulk ;qXe lgh ugha gS \
(A) VsVªk,EehudkWij(II) lYQsV............. [Cu(NH3)4]SO4
(B) MkbZ,EehuflYoj(I) DyksjkbM................ [Ag(NH3)2]Cl
(C) iksVsf'k;e gsDlklk;ukbMks-C-QsjsV(II) ............... K4[Fe(CN)6]
(D) iksVsf'k;e ,EehuisUVkDyksjkbMksIysfVusV (II) ................. K[Pt(NH3)Cl5]
16. fuEufyf[kr iztkfr;ksa] NF3, BF3, PF5 rFkk [SiF6]2– esa dsUnzh; ijek.kq ds ladj.k dk lgh Øe gS :
(A) sp2, sp3, sp3d2, sp3d (B) sp3, sp2, sp3d, sp3d2
(C) sp2, sp3, sp3d, sp3d2 (D) sp3, sp2, sp3d2, sp3d3
17. fuEu esa ls fdrus v.kq@vk;u f}narqd fyxs.M dh rjg O;ogkj dj ldrs gS \
CO32– NH2 – CH2 – COO– EDTA4– C2O42– SO42–
CH3COCHCOCH3– CH3C  N SCN¯ DMG
18. P4 ds ,d v.kq dh] NaOH ds lkFk fo"kekuqikru vfHkfØ;k esa] NaOH ds fdrus v.kq vfHkd`r gksrs gS \ .............. .
19. vk/kqfud vkorZ lkj.kh ds pth oxZ ls lEcfU/kr ,d rRo dks Une çrhd ls çnf'kZr fd;k tkrk gS rFkk ,d rRo ftldh
bySDVªkWu xzg.k ,UFkSYih ¼eqDr ÅtkZ½ mPpre gSA bldk ijek.kq Øekad q gSA rc (q –p) dk eku Kkr dhft;s\
20. ,d cQj foy;u dks ,d nqcZy vEy HA (Ka = 10–6) ds lkFk blds yo.k NaA dks leku eksyj ek=kk esa feykdj
cuk;k tkrk gSA 180 ml cQj foy;u dks cukus ds fy, vEy o yo.k ds fdrus ehyheksy feykus pkfg;s\ ftlesa ;fn
bl cQj foy;u ds 1 L esa 0.1 eksy izcy vEy feykus ij pH esa bdkbZ ifjorZu gksrk gS ?
21. 300 K ij ,d [kqys ik=k esa fd;k x;k dk;Z dk ifjek.k (dSyksjh esa) ifjdfyr dhft,] tc 112 xzke vk;ju] ruq HCl
ds lkFk fØ;k djrk gSA (vius mÙkj dks 100 ls Hkkx nsdj iznf'kZr djsaA)
PAGE NO.-20

Daily Self-Study Dosage for mastering Chemistry xq.kkRed fo'ys"k.k esa milgla;kstu ;kSfxd
milgla;kstu ;kSfxdksa dk mi;ksx cgqr ls xq.kkRed jklk;fud fo'ys"k.k esa fd;k tkrk gSA /kkrq vk;u }kjk vfHkfØ;k esa
mRiUu jax dks leku jax fyxs.Mksa dh fuf'pr la[;k ds lkFk] milgla;kstu xksyd ;k Hkkx ds fuekZ.k ds }kjk iznf'kZr
fd, tkrs gSaA bl vk/kkj ij budh igpku rFkk fu"d"kZ.k] fo'ys"k.k dh :<+ ;k ikjEifjd fof/k;ksa }kjk gksrk gSA
lw=k IUPAC uke rFkk jax fVIi.kh rFkk lkekU; uke
tc NH3 ds vkf/kD; eas CuSO4 ds lkFk
VªsVk,ehudkWij (II) lYQsV :
(a) [Cu(NH3)4]SO4 fØ;k gksrh gS rks xgjk uhyk ;kSfxd izkIr
xgjk uhyk:
gksrk gSA
,ehuks vEy Xykblhu ds _.kkRed dk
(b) Co(gly)3 fVªl (XykflusVks½dksckYV(III): tkequh
f}nUrqd fyxs.M
isUVk,DokFkk;kslk;usVks&S–vk;ju(III):
(c) [Fe(H2O)5(SCN)]2+ Fe3+ vk;u ds fo'ys"k.k esa izkIr gksrk gSA
yky
fØLVy bl ladqy dk {kkjh; foy;u]
iksVsf'k;e VsVªkvk;ksfMMksejD;wjsV (II):
(d) K2[HgI4] uslyj vfHkdeZd dgykrk gS] tks NH3 ds
Qhds ihys
fo'ys"k.k esa iz;qDr gksrk gSA
dksckYV(II) VsVªkFkk;kslk;usVks–S–ejD;wjsV(II): Hg2+ ds xq.kkRed fo'ys"k.k eas xgjk uhyk
(e) Co[Hg(SCN)4]
xgjk uhyk fØLVyh; vo{ksi izkIr gksrk gSA
vk;ju(III)gsDlklk;ukbMksQsjsV(II): Fe2+ ds fo'ys"k.k eas QsjhQsjks lk;ukbM
(f) Fe4[Fe(CN)6]3
izqf'k;e uhyk izkIr gksrk gSA
iksVsf'k;e gsDlkukbVªkbVks–N–dksckYVsV(III): Co2+ ds fo'ys"k.k esa ihyk vo{ksi izkIr
(g) K3[Co(NO2)6]
ihyk gksrk gSA ¼fQ'kj yo.k½
fcl(MkbZesfFkyXykbZvkWfDlesVks)fudy(II): Ni2+ vk;uksa ds fo'ys"k.k esa xqykch yky
(h) [Ni(dmg)2]
xqykch yky vo{ksi izkIr gksrk gSA
iksVsf'k;e gsDlk DyksjhMksIysfVusV(IV): K+ vk;uksa ds fo'ys"k.k esa ihyk vo{ksi
(i) K2[PtCl6]
ihyk izkIr gksrk gSA
lksfM;e isUVklk;ukbMksukbVªkslksfu;eQsjsV (II): S2– vk;u ;k lYQj ds fo'ys"k.k esa
(j) Na2[Fe(CN)5NO+]
yky lksfM;e ukbVªksizqlkbM iz;qDr gksrk gSA
isUVk,DokukbVªkslksfu;evk;ju(I) lYQsV:
(k) [Fe(H2O)5(NO+)]SO4 Fe2+ vk;u ds fo'ys"k.k esa izkIr gksrk gSA
Hkwjh oy;
KCN foy;u dks vkf/kD; esa feykus ij
3–
VsVªklk;ukbMksD;wizsV(I):
(l) [Cu(CN)4] Cu2+ ds fo'ys"k.k esa ;g LFkk;h jaxghu
jaxghu
foys;'khy ladqy ds :i esa izkIr gksrk gSA
veksfu;e gsDlkDyksjhMksIysfVusV(IV): veksfu;e vk;uksa ds dqN gh ;kSfxd ds
(m) (NH4)2[PtCl6]
ihyk vo{ksi izkIr gksrs gSaAs
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
22. Hkwjh oy; okys ladqy eas Fe dh vkWDlhdj.k voLFkk D;k gS?
(A) 0 (B) 1 (C) 2 (D) 3
2+
23. Ni ds fo'ys"k.k esa cus xqykch yky ladqy ds fy, lgh fodYi dk p;u dhft,A
(A) Ni dh leUo; la[;k 4 gSA (B) ladqy oxZleryh; gSA
(C) ladqy esa fdysV fyxs.M mifLFkr gSA (D) mDr lHkh fodYi lgh gSaA
24. fuEu esa ls dkSulk ladqy uhys jax dk ugha gS ?
(A) Co[Hg(SCN)4] (B) Fe4[Fe(CN)6]3 (C) [Cu(NH3)4]SO4 (D) [Fe(H2O)5(SCN)]2+
25. fuEu esa ls dkSuls vo{ksi ihys gSa ?
(A) K3[Co(NO2)6 (B) (NH4)2[PtCl6] (C) K2[PtCl6] (D) [Fe(H2O)5(NO+)]SO4
PAGE NO.-21

1. ,d ok.Mj oky xSl ds 1 eksy ds fy, tc a = 0 gS rks fuEu esa ls dkSulk vkjs[k lgh gS@gSa \
(T = fu;r) (T = fu;r) (P = fu;r) (P = fu;r)
(A) PV (B) PV (C) PV (D) PV
P P T T
2. CCl4 o ,lhVksu ,d dkWij ik=k esa dejs ds rki ij ,d vu-vkn'kZ foy;u cukrs gSA bl izØe ds fy, lgh dFku gS@gSa %
(A) G /kukRed gksrk gSA (B) Sfudk; /kukRed gksrk gSA
(C) Sifjos'k < 0 (D) H > 0
3. fuEufyf[kr esa ls dkSulk@dkSuls dFku lR; gS@gSa \

(A)oy;dj.k izHkko (Chelation effect) ik¡p rFkk N% lnL; oy; ds fy, vf/kdre gksrk gSA
(B)oy;dkjd fyxs.M (Chelating ligands) de ls de f}nUrqd fyxs.M gksrs gSa
(C)ladqy esa oy;ksa dh la[;k esa o`f) ds lkFk ladqy (fdysV) (Chelate) ds LFkkf;Ro esa Hkh o`f) gksrh gSA
(D),tkbM vk;u (N3–) nkrk ijek.kqvksa ds :i esa nks N ijek.kq j[krk gS rFkk ,d oy;dkjd fyxs.M ds leku
O;ogkj djrk gSA
4. ;g ,d izk;ksfxd rF; gS fd &

DMG + Ni() yo.k + NH4OH  yky vo{ksi
bl yky vo{ksi ds lanHkZ esa fuEu esa ls dkSuls dFku lR; gS@gSa &
(A) ;g ,d vu&vk;fud ladqy gSA (B) blesa var% vkf.od H-ca/ku lfEefyr gSA
3
(C) Ni() sp ladfjr gSA (D) ;g ,d izfrpqEcdh; ladqy gSA
H2O
Li + H2 A B+C
5.
(gas)
AlH3
D
(A) A vipk;d dh rjg dk;Z djrk gSA (B) C vuqpqEcdh; xSl gSA
(C) D ladqy ;kSfxd gSA (D) B {kkj gSA
B 
6. ,d xSl iFk  rFkk }kjk A ls C voLFkk esa ifjorZu ls lEcfU/kr gSA ;fn 5 C
 N 
P 2 
iFk ds fy, U 2J gS rc iFk  esa xSl }kjk vo'kksf"kr Å"ek (twy esaKkr m 

3 A
dhft;sA
1 2 V(m3)
7. ladqyks [Fe(H2O)5(NO)]2+ rFkk [Fe(CN)5(NO)]2– esa vk;ju dh vkWDlhdj.k voLFkk;sa Øe'k% x rFkk y gSA rc
(x + y) cjkcj gS&
PAGE NO.-22
8. MkbZcksjsu veksfu;k ls vfHkfØ;k djds (A) ds ?kus 'osr /kwe nsrk gSA dejs ds rki ij (A) Bksl gSA nkc dh mifLFkrh
esa xeZ djus ij] ;g ngu'khy xSl eqDr djds nzo (B) mRikfnr djrk gS o vUrr% ,d lQsn Bksl (C) nsrk gSA (C)
ds v.kqlw=k esa dqy gkbMªkstu ijek.kqvksa dh la[;k gS&
9. tc 25ºC ij AB dsk ty esa ?kksydj lUrÌr foy;u cuk;k tkrk gS rks DoFkukad esa mé;u 2 × 10–4 ºC gksrk gS rFkk
AB dk Ksp 4 × 10–x gSA rc x dk eku fu/kkZfjr dhft, (ekfu,  = 1, eksyyrk  eksyjrk
(fn;k gS Kb = 0.5 K/m.)
10. fuEu esa ls fdrus f}nUrqd fyxs.M gS \

vkDlsysV] XykbflusV] gkbMªsthu] lk;ukbM] ,lhfVy,lhVksusV] MkbZ,FkkbyhuVªkbZ,ehu dmg, veksfu;k] lYQsV] ty
11. ,d vkn'kZ ,dyijekf.o; xSl izkjEHk esa nkc P1 = 20 atm o vk;ru V1 = 1500 cm3 ds lkFk voLFkk 1 esa gSA blds
Ik'pkr bls nkc P2 = 1.5 P1 o vk;ru V2 = 2V1 ds lkFk voLFkk 2 esa ys tk;k gS A bl izØe esa vkUrfjd ÅtkZ esa
ifjorZu ( KJ esa) Kkr dhft, (yhft, 1 atm lit  100 J)
12. fuEu esa ls fdrus izfrpqEcdh; gSa \
(a) K4[Fe(CN)6] (b) Na3[Co(ox)3] (c) [Pt(NH3)3Cl] Br (d) [Fe(H2O)6]2+
(e) [Zn(NH3)4] Cl2 (f) [MnO4]2– (g) Li[AlH4] (h) [V(H2O)6]2+
13. fuEu esa ls fdrus v.kqvksa@vk;uksa esa  vkf.od d{kd ( o * nksuksa) esa bysDVªkWu dh la[;k 9 ds cjkcj ;k vf/kd gksrh
gS ¼vk| voLFkk esa½
(a) N2 (b) N2 (c) Be2 (d) B 2 (e) B2 (f) C22
(g) C2 (h) H2 (i) Li2 (j) O 2 (k) F2
14. feyku dhft,A

dkWye I dkWye II
A. O2, O2+, O2– (p) izfrpqEcdh;
B. O22–, C2 ,C22– (q) leku ca/k Øe
C. N2 ,CO, NO+ (r) vuqpEq cdh;
D. He2, Be2, B22+ (s) lebysDVªksfud

fofHké milgla;kstu T;kferh;ksa ds fy, d-d{kdksa dk fØLVy {ks=k foikVu fp=k
fyxs.M dh vuqifLFkfr esa dsUnzh; /kkrq vk;u ds 5 d-d{kd leHkza'k gksrs gSa vFkkZr~ ;s leku ÅtkZ j[krs gSaA d-d{kdksa esa bysDVªkWu
rFkk leku vkos'kksa ds e/; izfrd"kZ.k ds dkj.k os bysDVªkWu tks fyxs.M esa gSa] ,d nwljs dks izfrdf"kZr djrs gSaA
vr% d-d{kdksa esa bysDVªkWu tks fyxs.Mksa ds lehi gSa] fyxs.Mksa ls nwj okys bysDVªku dh vis{kk mPp ÅtkZ j[ksaxsA ftldk ifj.kke
d-d{kdksa esa ÅtkZ dk foikVu gksrk gSA
foikVu () dk ifjek.k fuEu dkjdksa ls izHkkfor gksrk gS :
1. /kkrq vk;u dh izd`frA
2. /kkrqvksa dh vkWDlhdj.k voLFkk] mPp vkWDlhdj.k voLFkk eas vf/kd foikVu gksrk gSA
3. /kkrq vk;u ds pkjksa vksj fyxs.Mksa dh O;oLFkk
4. /kkrq vk;u dks ?ksjs gq, fyxs.Mksa dh izd`frA izcy fyxs.Mksa ds dkj.k d-d{kdksa ds ÅtkZ ry esa vf/kd foikVu gksrk gSA
PAGE NO.-23
;g fp=k leku /kkrq fyxs.M la;kstu ds fy, prq"Qydh;] v"VQydh;] prq"ddks.kh; o oxZ leryh; T;kferh;ksa esa d-d{kdksa
ds fØLVy {ks=k foikVu dks n'kkZrk gSA
15. fuEu esa ls dkSulk lEcU/k lgh ugha gS ?
(A) o < t (B) o  (9/4)t (C) sp > t (D) sp = 1.30
16. lgh dFku dk p;u dhft,A
(A) prq"Qydh; {ks=k esa z2 ,xy dh vis{kk mPp ÅtkZ j[krs gSaA
(B) oxZlery {ks=k esa foikVu] prq"Qydh; {ks=k esa foikVu ls de gksrk gSA
(C) oxZ lery {ks=k esa ikap d-d{kdksa dk] nks fHkUu ÅtkZ ryksa esa foikVu gksrk gSA
(D) v"V Qydh; {ks=k esa t2g d{kd] eg d{kdksa dh vis{kk fuEu ÅtkZ j[krs gSaA
17. oxZlery {ks=k esa dkSuls d-d{kd vf/kdre ÅtkZ j[krs gS?
(A) x2 – y2 (B) z2 (C) xy (D) yz
18.  dk ifjek.k fuHkZj djrk gSA
(A) /kkrqvksa dh vkWDlhdj.k voLFkk ij (B) /kkrq dh izd`fr ij
(C) /kkrq dks ?ksjs gq, fyxs.Mksa dh la[;k ij (D) fyxs.M ds lkeF;Z ij

1. CsBr(s) ds foy;u dh ,UFkSYih 10 kJ mol1 gS ;fn Cs+ (g) rFkk Br– (g) dh ty;kstu ,UFkSYih Øe'k% 475 rFkk
655 kJ.mol gS] rc CsBr(s) dh tkyd ÅtkZ kJ.mol1 esa D;k gksuh pkfg;s \
(A) 1120 (B) 1130 (C) 1140 (D) 1150
2. vfHkfØ;k xVO + yFe2O3  FeO + V2O5 esa x o y ds eku Øe'k% fuEu gSA
(A) 1, 1 (B) 2, 3 (C) 3, 2 (D) buesa ls dksbZ ugh
3. 225 xzke ty esa NaCl dh fdruh ek=kk foys; dh tkuh pkfg, fd izkIr foy;u dk DoFkukad] 225 xzke ty esa 20
xzke Xywdkst (M – 180) rFkk 30 xzke lwØkst (M – 342) j[kus okys foy;u ds leku gksrk gS (Na – 23, Cl – 35.5)
(A) 5.8 (B) 11.6 (C) 12.3 (D) buesa ls dksbZ ugha
4. ,d lkE; vfHkfØ;k A(g) + B (g) C (g), H =+ ve ds fy,] rkieku esa o`f) fuEu esa ls fdldk dkj.k gksxkA
(A) Keq ds eku esa o`f) dkA
(B) Keq ds eku esa deh dkA
(C) Keq ds eku esa dksbZ ifjorZu ugha gksxkA
(D) Keq esa ifjorZu dk tks fd xq.kkRed :i ls ifjdfyr ugha fd;k tk ldrk gSaA
PAGE NO.-24
+
5. gkbMªkstu ijek.kq dh ykbeu Js.kh dh lcls NksVh rjaxnS/;Z 'x' gS] rc He ds ckej Js.kh dh lcls yEch rjaxnS/;Z gSA
9x 36x x 5x
(A) (B) (C) (D)
5 5 4 9
6. 4°C ij ikuh dk ?kuRo 1.0 × 103 kg m–3 gSA ikuh ds ,d v.kq }kjk ?ksjk x;k yxHkx vk;ru gS&
(A) 3.0 × 10–23 mL (B) 6.0 × 10–22 mL (C) 3.0 × 10–21 mL (D) 9.0 × 10–23 mL
7. He dk lEihM~;rk xq.kkad gS
(A) vk;ru ds lkFk js[kh; :i ls c<rk gqvkA (B) nkc ds lkFk js[kh; :i ls c<rk gqvkA
(C) 1 ds cjkcj (D) nkc ds lkFk js[kh; :i ls ?kVrk gqvkA
8. fuEu vfHkfØ;k lkE; ij nh x;h gS %
N2(g) + 3H2 (g) 2NH3 (g)
fu;r vk;ru ij blesa dqN vfØ; xSl feyk;h x;hA fuEu esa ls] mu rF;ksa dks crkb;s] tks dh çHkkfor gksaxs %
(A) NH3(g) vf/kd mRiUu gksrh gSA (B) NH3(g) de mRiUu gksrh gSA
(C) lkE; ij vfHkfØ;k o`f) dh ek=kk (degree of advancement of the reaction) çHkkfor ugha gksrh gSA
(D) vfHkfØ;k ds Kp esa o`f) gksrh gSA
9. ijek.kq esa izksVkWu] U;wVªkWu o bysDVªkWu mifLFkr gksrs gS ;fn U;wVªkWu dk nzO;eku mlds okLrfod eku dk vk/kk rFkk
bysDVªkWu dk nzO;eku mlds okLrfod eku dk nqxuk eku fy;k tk;s rks C612 dk ijek.kq Hkkj gksxkA
(A) nqxuk (B) 75% de (C) 25% de (D) mlds okLrfod eku dk vk/kk
10. fuEu esa ls dkSulk la;kstu ;ksxt (adduct) cukus ds fy, vf/kdre izo`fr j[krk gS \
(A) BF3 + NH3 (B) BCl3 + NH3 (C) BBr3 + NH3 (D) B3 + NH3
11. fuEu lHkh ladqy vk;u vuqpacq dh; ik, x, gSa &
P : [FeF6]3– ; Q : [CoF6]3– ; R : [V(H2O)6]3+ ; S : [Ti(H2O)6]3+
buds vuqpaqcdh; vk?kw.kksZ ¼dsoy pØ.k½ dk lgh Øe gS &
(A) P > Q > R > S (B) P < Q < R < S (C) P = Q = R = S (D) P > R > Q > S
3+
12. v"VQydh; {ks=k esa Cr ds fy;s fØLVy&{ks=k foikVu] I , H2O, NH3 , CN fyx.Mksa ds fy;s c<rk gS] bldk Øe gS
– –
(A) I– < H2O < NH3 < CN– (B) CN– < I– < H2O < NH3
(C) CN– < NH3 < H2O < I– (D) NH3 < H2O < I– < CN–
13. fuEu esa ls fdl foU;kl esa] fyxs.M dh izd`fÙk ij fuHkZj djrs gq,] vuqpqEcdRo o izfrpqEcdRo nksuksa dh lEHkkouk gksxh&
(A) d7 (B) d3 (C) d6 (D) d5
14. og ladqy] ftlds fy, vo'kks"k.k LisDVªe dks tkudj cgqr vklkuh ls fØLVy {ks=k foikVu dk ifjdyu fd;k tk
ldrk gSa] gksxk&
(A) [TiCl6]2– (B) [Fe(H2O)6]2+ (C) [Ti(CN)6]3– (D)[CoF6]3–
15. fuEu ladqyksa ds fy, CFSE (vkafdd eku) dk lgh Øe gS &
ladqy P Q R S
lw=k [CoF6]3– [Co(CN)6]3– [Co(NH3)6]3+ [Co(H2O)6]3+
(A) P > Q > R > S (B) Q > R > S > P (C) S > R > P > Q (D) R > Q > P > S
16. dFku-1 : pfØ; izØe (cyclic process) ds fy, U = 0
dFku-2 : tc ra=k esa ifjorZu (change of state) gksrk gS rc gh dk;Z rFkk Å"ek lkFkZdrk j[krs gSaA
(A) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
17. fo|qr HkV~h esa 2273-3273 K rki rd dSfYle vkWDlkbM dks dksd ds lkFk xeZ djus ij cus dSfYl;e ;kSfxd dk
jklk;fud lw=k gksxk
(A) Ca2C (B) CaC2 (C) CaCO3 (D) Ca(OH)2
PAGE NO.-25
18. ghjs rFkk Qqyjhu (C60) esa dkcZu ijek.kq dh ladfjr voLFkk,¡ Øe'k% gS
(A) sp3 o sp2 (B) sp2 o sp3 (C) sp3 o sp (D) nksuksa esa sp3
19. 0.21 g dkcZfud ;kSfxd ds ngu ij 0.308 g CO2 xSl izkIr gksrh gSA ;kSfxd esa dkcZu dh izfr'krrk gS
(A) 40% (B) 4% (C) 14.67% (D) 13.5%
20. vkf.od d{kd fl)kUr ds vuqlkj O2, O2 , O2– rFkk O2–
2 ds LFkkf;Ro dk lgh Øe gSA
(A) O2 > O2 > O2– > O2–

2 (B) O2 > O2 > O2– > O2–
2
(C) O2 > O2 > O2– –

2 > O2 (D) O2 > O2 > O2– –
2 > O2
21. lQsn QkWLQksjl (P4) v.kq esa fdrus P-P ,dy ca/k mifLFkr gSA
22. ,d milgla;ksth ladqy dh leUo; la[;k N% gS] bldk lw=k CoCl3.5NH3.H2O gSA fo|qr pkydrk ekiu ,d lw=kh;
bdkbZ esa rhu vk;uksa dh mifLFkfr bafxr djrh gSA ladqy ds ,d eksy dks AgNO3 ds lkFk mipkfjr djus ij AgCl
ds fdrus eksy vo{ksfir gksxsa \
23. ,d ra=k esa] tgk¡ E = – 15 kJ gS ,d fiLVu] 1.2 atm ds ckg~; nkc ds fo:) izlkfjr gksdj] 75 lt dk vk;ru esa
ifjorZu n'kkZrk gS bl ra=k ds fy, Å"ek esa ifjorZu dk ifjek.k D;k gS \ (1 lt atm = 100 J).
24. nks 'kq) nzoks A rFkk B dk ok"i nkc Øe'k% 5 rFkk 10 Vksj gS] rc 2 eksy A rFkk 3 eksy B ds lfEeJ.k ls izkIr foy;u
dk dqy nkc (Vksj) ifjdfyr dhft,A
25. vkDlhtu ds lUnHkZ esa A dk vkisf{kd ?kuRo 1/4 gSA xSl A ds ,d v.kq dk nzO;eku (amu esa) D;k gksxkA
DPP No. # A11 (REVISION DPP)
1. rhu foy;uksa A, B o C ds fy, ok"i nkc o rki ds chp oØ fn;s x;s gSaA tc
ok"i&nkc 1 atm ds cjkcj gks tkrk gS] rks ;g rkieku foy;u ds DoFkukad ds :i esa
tkuk tkrk gSA
lkUnzrk A, B o C dk lgh Øe fuEUk gS] ;fn A, B o C ds fy, i dk eku leku gksa %
(A) A > C > B (B) B > A > C
(C) C > A < B (D) C > A > B
2. 300 K ij nks 'kq) nzo X rFkk Y, tks ,d vkn'kZ foy;u cukrs gS ds ok"i nkc Øe'k% 200 rFkk 300 mm Hg gSA X
rFkk Y ds ,d nzo foy;u] ftlesa X dh eksy fHkUu 0.5 gS dks ,d fiLVu ;qDr can ik=k eas] fy;k x;k gS bl fiLVu
ij nkc ifjofrZr gks ldrk gS %
(A) dsoy ;fn foy;u ds Åij nkc 200 torr ls de gks] rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
(B) dsoy ;fn foy;u ds Åij nkc 300 torr ls de gks] rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
(C) dsoy ;fn foy;u ds Åij nkc 200 torr ls vf/kd gks] rHkh nzo voLFkk vfLrRo eas gSA
(D) dsoy ;fn foy;u ds Åij nkc 250 torr ds cjkcj vFkok de gks rHkh ok"i voLFkk vfLrRo esa gks ldrh gSA
3. nks nzoksa A(pº = 80 mm) o B(pº = 120 mm) ds foy;u dk ok"i nkc 100 mm ik;k x;k] tc xA = 0.4 gSA ifj.kke
n'kkZrk gS fd
(A) foy;u vkn'kZ O;ogkj iznf'kZr djrk gSA
(B) foy;u /kukRed fopyu n'kkZrk gSA
(C) foy;u _.kkRed fopyu n'kkZrk gSA
(D) foy;u fuEu lkanzrk ds fy, /kukRed rFkk mPp lkaUnzrk ds fy, _.kkRed fopyu n'kkZrk gSaA
PAGE NO.-26
4. fuEu esa ls fdl feJ.k }kjk jkÅYV fu;e ls /kukRed fopyu dks n'kkZ;k tkrk gS :
(A) csUthu o VkWyqbu (B) CHCl3 o ,lhVksu (C) ,FksukWy o ty (D) HCl o ty
5. xUuk 'kdZjk ds ,d 10% w/w foy;u dk fuEu vfHkfØ;k ds vuqlkj vkaf'kd izfriu gksrk gSA
lqØksl + ty  Xywdksl + ÝDVksl
foy;u dk DoFkukad 100.7°C gSA
'kdZjk ds fHkUu dk izfriu D;k gksrk gS \
Kb (H2O) = 1.8 K.kg/mol.
(A) 0.5 (B) 0.2 (C) 0.3 (D) 0.4
6. fuEu esa ls dkSuls ladqy izfrpqEcdh; gS ?

[Pt (NH3)4]2+ [Co (SCN)4]2– [Cu (en)2]2+ [Hg4]2–
oxZ leryh; prq"Qydh; oxZ leryh; prq"Qydh;
(i) (ii) (iii) (iv)
(A) (i) rFkk (ii) (B) (ii) rFkk (iii) (C) (i) rFkk (iv) (D) (iii) rFkk (iv)
7. ,d vkn'kZ xSl ds 1 eksy dks ,d ok;qe.My ds fu;r ckâ; nkc ij 300K ls 400K rd xeZ fd;k x;k ;fn
Cv,m   21.686  103 T  J / molK gS rc izØe ds fy, H gS %
(A) 3000 (B) 3035 (C) 3350 (D) 30350
8. (A) ,ehMksMkbZdkcksZfuyvk;ksMkbMksfcl (VªkbQsfuyQkWLQhu)vk;ju(II)

(B) ,ehuMkbZdkcksZfuyvk;ksMkbMksfcl (VªkbQsfuyQkWLQhu)vk;ju(II)
(C) ,ehMksMkbZdkcksZfuyvk;ksMkbMksfcl (VªkbQsfuyQkWLQhu)QSjsV(II)
(D) buessa ls dksbZ ugha
9. dkWye-I dks dkWye-II ds lkFk lqesfyr dhft,] rFkk ladj.k ds izdkj ds lanHkZ esa uhps fn;s x;s dksM dk mi;ksx djrs
gq;s lgh mÙkj dk p;u dhft,A
dkWye- I dkWye- II
(ladqy) (ladj.k)
2–
(I) [Ni(CN)4] (p) dsp2 ladj.k
(II) [Cu(CN)4]3– (q) sp3 ladj.k
(III) [Co(C2O4)3]3– (r) sp3d2 ladj.k
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 ladj.k
dksM %
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B) p q s r
(C) p q r s (D) q p s r
10. ,d vkn'kZ xSl ij fuEu esa fdl çØe esa] fudk; dh ,UVªkWih esa o`f) gksrh gS %
(A) mRØe.kh; lerkih çlkj (B) vuqRØe.kh; :)ks"eh; laihMu
(C) lerkih eqDr çlkj ¼fuokZr ds fo:)½ (D) mRØe.kh; :)ks"eh; çlkj
11. lEHkou dh ekud ,UFkSYih ds lanHkZ esa fuEu esa ls dkSulk dFku lgh gS \
(A) ;g lnSo _.kkRed gksrh gSA
(B) ekud voLFkk esa ,d eksy ;kSfxd ds fy, Kkr djrs gSA
(C) ekud voLFkk esa lHkh Lih'kht ds fy, 'kwU; gksrh gSA
(D) 'osr QkWLQksjl ds fy, 'kwU; gksrh gS] tks fd QkWLQksjl dk U;wure LFkk;h :i gSA
PAGE NO.-27
12. fuEu rU=k dk voyksdu dhft,&
rhu fHkUu tyh; foy;u] izR;sd dk vk;ru 100 ml ysrs gS rFkk fp=k esa fn[kk, vuqlkj lEidZ es j[krs gSaA
100 ml v)ZikjxE; 100 ml v)ZikjxE; 100 ml

0.2 M ;wfj;k f>Yyh 0.15 M KCl f>Yyh 0.1 M AlCl3
i;kZIr le; ds i'pkr~ (rki fu;r rFkk izcy oS|qr vi?kV~; dk 100% fo;kstu ekurs gq,)
100
(A) ;wfj;k foy;u dk vk;ru ml gksxkA
3
400
(B) AlCl3 foy;u dk vk;ru ml gksxkA
3
(C) KCl foy;u ds vk;ru es dksbZ ifjorZu ugha gksxkA
(D) KCl rFkk AlCl3 nksuks foy;uksa dk vk;ru c<+sxkA
vuqPNsn #
vkn'kZ xSl ds ,d izkn'kZ dks fuEu nks izØeksa esa iz;qDr fd;k tkrk gS %
izØe-I : 300 K rFkk 10 atm ij 4.4 xzke vkn'kZ xSl (v.kqHkkj = 44) dks 1 atm fu;r ckÐ; nkc ds fo:) lerkih;
:i ls izlkfjr fd;k tkrk gSA
izØe-II : vc 1 atm nkc ij izØe-1 ds i'pkr~ izkIr xSl izkn'kZ dks 10 atm fu;r ckÐ; nkc ds fo:) lerkih; :i
ls laihfM+r fd;k tkrk gSA 1 Latm = 100 J ysdj, fuEu iz'uksa ds mÙkj nhft, %
13. xSl }kjk izØe-I esa vo'kksf"kr Å"ek fuEu gS %
(A) 200.5 KJ (B) 212.5 J (C) 221.4 J (D) 242.4 J
14. fuEu esa ls dkSulk dFku xyr gS %
(A) izØe-I esa xSl }kjk fd;k x;k dk;Z] izØe-II esa ifjos'k }kjk fd;k x;k dk;Z dh rqyuk esa de gksrk gSA ¼ifjek.k ls½
(B) izØe-I esa xSl }kjk vo'kksf"kr Å"ek] izØe-II esa xSl }kjk eqDr dh xbZ Å"ek dh rqyuk esa de gksrh gSA ¼ifjek.k ls½
(C) xSl izkn'kZ ij izØe-I o II ds iw.kZ :i ls gksus ds i'pkr~ fudk; o ifjos'k nksuksa viuh okLrfod voLFkk esa iqu% vk
tkrs gSaA
(D) buesa ls dksbZ ugha
15. C – Cl ca/k (kJ/mol) dh ca/k ,UFksYih Kkr dhft,A fn;k x;k gS %
C2H6(g) + Cl2(g) C2H5 Cl(g) + HCl (g) H = –117 KJ/mol
Cl – Cl = 242 kJ/mol
C – H = 412 kJ/mol
H–Cl = 431 kJ/mol
viuk mÙkj 10 ls Hkkx nsdj nhft,A
B
(1.5Pa,2m )
–3
16. fp=k esa n'kkZ;s vuqlkj 1 mol vkn'kZ xSl mRØe.kh; izØe iznf'kZr djrh gSA izØe
A
P(pascal)
esa fd;s x;s dk;Z dh x.kuk (twy esa) dhft;s [ln 2 = 0.7] (1Pa,1m–3)
vius mÙkj dks 10 ls xq.kk djds nsA
1
(m –3)
V
PAGE NO.-28
17. fuEu esa ls fdruh vfHkfØ;k,¡ ;k izØe Å"ek{ksih gS@gSa \
(i) 2H(g)  H2(g) (ii) C(ghjk)  C(xzsQkbV) (iii) CH4 + O2  CO2 + H2O (iv)
C2H6  C2H4(g) + H2(g) (v) lei{k-2-C;wfVufoi{k-2-C;wfVu (vi) lQsn P  yky P.
(vii) H2O()  H2O(s) (viii) Na+(g) + aq  Na+(aq)
(ix) NaOH + H2SO4  Na2SO4 + H2O (x) HNO3 + ty foy;u (xi) ,FksukWy + ty  foy;u
18. ,d xSl 'X' 1.5 atm dqy nkc ij ty nzo ij larÌr ty ok"i ds lkFk 'X' dk
vkaf'kd nkc
mifLFkr gSA leku rki ij H2O dk ok"i nkc 0.5 atm gSA 10 eksy <+ky = 38 × 105 torr
H2O() esa fefyeksyksa ds inks esa xSl 'X' dh foys;rk D;k gS \
( nH2O  nx )
H2O esa 'X' dk eksy fHkUu
1. lgh dFku@dFkuksa dk p;u dhft,s&
(A) ge nkc dks iz;qDr dj ok"i dks ljyrk ls la?kfur dj ldrs gSA
(B) xSl dks nzohd`r djus ds fy, rkieku dks Tc ls de djuk pkfg, rFkk lkFk gh nkc Hkh iz;qDr djuk pkfg,A
(C) Tc ij] nzo rFkk ok"i voLFkk esa dksbZ foHksn ugha gksrk gS vr% nzo dk ?kuRo] ok"i ds ?kuRo ds yxHkx cjkcj jgrk gSA
(D) buesa ls dksbZ ugha
2. AOH rFkk BOH dk leeksyj foy;u rS;kj fd;k x;kA A rFkk B dk vk;uu foHko Øe'k% 5.1 rFkk 13.0eV gSA A rFkk
B dh fo|qr _.kkRedrk 0.9 rFkk 3.2 gSA bu vadks ds vk/kkj ij lR; dFku@dFkuksa dk p;u djsaA
(A) BOH dk ?kksy lksfM;e dkcksZusV ds lkFk cqncqnkgV iSnk djrk gSaA
(B) fQukW¶Fksyhu AOH ds ?kksy ds lkFk xqykch jax çnku djrk gSaA
(C) BOH dk ?kksy PH > 7 nsrk gSA
(D) NH4Cl AOH ds lkFk mipkfjr djus ij ;g veksfu;k fu"dkflr djrk gSA
3. gjs jax dk ladqy K2[Cr(CN)4(NH3)(NO)] vuqpcq dh; gS rFkk bldk vuqpqcdh; vk?kw.kZ ¼dsoy pØ.k½ 1.73 B.M. gSA
fuEu esa ls blds lanHkZ esa D;k lgh gS@gSaA
(A) bldk IUPAC uke iksVSf'k;e ,EehuVsVªklk;uksukbVªkslksfu;eØksesV () gSA
(B) Øksfe;e dh ladj.k voLFkk d2sp3 gSA
(C) ;g ca/ku leko;ork iznf'kZr dj ldrk gSA
(D) ;g T;kferh; leko;ork iznf'kZr ugha dj ldrk gSA
4. dkSuls lgh dFku gS ?

(A) [Ag(NH3)2]+, sp ladfjr Ag+ vk;u js[kh; vkd`fr dk gS
(B) NiCl42–, VO43– rFkk MnO4– leprq"Qydh; T;kfefr j[krs gS
(C) [Cu(NH3)4]2+ , [Pt(NH3)4]2+ rFkk [Ni(CN)4]2–, /kkrq vk;u dk ladj.k dsp2 j[krs gS
(D) Fe(CO)5, dsp3 ladfjr vk;ju ds lkFk f}fijkfeMy lajpuk j[krk gS
5. fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa \

(A) NaF ,oa NaBF4 esa ls] NaF ty esa vkisf{kd :i ls de ?kqyu'khy gksrk gSA
(B) tkyd ,UFkSYih dk cM+k _.kkRed eku vk;fud ca/k fuekZ.k ds fy, vuqdwy ifjfLFkfr gSA
(C) lkekU;r;k] vk;fud ;kSfxd Bksl voLFkk esa oS|qr /kkjk dk pkyu ugha djrs gSaA
(D) {kkjh; e`nk /kkrq ds dkcksZusVksa dh tyh; foys;rk] oxZ esa uhps dh vksj tkus ij c<+rh gSA
PAGE NO.-29
6. fuEu esa ls fdldk vfLrRo ugha gS \
(A) SH6 (B) HFO4 (C) FeI3 (D) HClO3
7. 0.12 M, 50 ml nqcZy vEy foy;u dks 0.06 M, 50 ml NaOH ds lkFk vuqekfir djus ij izkIr foy;u dh pH Kkr
dhft,] nqcZy vEy dk fo;kstu fu;rkad 2  10–2 gSA viuk mÙkj 10 ls xq.kk djds nhft,A
8. 0.01 eksyy tyh; CH3COOH ds fgekad dk voueu 0.0198ºC gSA 1 eksyy ;wfj;k foy;u –1.8ºC ij terk gSA
eksyjrk dks eksyyrk ds cjkcj ekurs gq, CH3COOH foy;u dh pH gS&
9. fuEu esa ls fdrus dFku lgh gS@gSa \
(a) gsDlkdkcksZfuyØksfe;e(0) d2sp3 ladfjr vkSj izfrpqEcdh; gksrk gSA
(b) d6, fuEu pØ.k] v"VQydh; ladqy es v;qfXer bysDVªkWuksa dh la[;k 2 gSA
(c) [Ag(NH3)2]Cl vuqpEq cdRo ugh n'kkZrk gSA
(d) /kkrq vk;u dk fuEu vkos'k ?kuRo /kkrq vk;u ladqy ds LFkkf;Ro dks c<+krk gSA
(e) Qsjkslhu ,sjksesfVd ;kSfxd gSA
(f) Qsjkslhu es vk;ju dh vkWDlhdj.k voLFkk +3 gSA
(g) /kkrq dkcksZfuy [Mn(CO)6]+, [Cr(CO)6] dh vis{kk izcy C–O ca/k j[krk gSA
(h) ladqy [Co(CN)6]3–, ladqy [Co(H2O)6]3+ dh vis{kk o dk vf/kd eku j[krk gSA
(i) ,tkbM vk;u mHk;nUrqd fyxs.M gSA
(j) K2[PtCl6] dk IUPAC uke iksVsf'k;e gsDlkDyksjkbMksIysfVue(IV) gSA
10. mRiknksa [X] o [Y] esa mifLFkr lHkh S ijek.kqvksa ds O;fDrxr (individual) vkWDlhdj.k vadksa dk dqy ;ksx---------------- gSA
11. [Cr(NO3)3 (NH3)3] ds fy, f=kfoe leko;oh dh la[;k = x
K3[CoCl2(C2O4)2] ds fy, f=kfoe leko;oh dh la[;k = y
[CoBrCl(en)2] ds fy, f=kfoe leko;oh dh la[;k = z
x + y + z Kkr dhft,A
12. tc 'osr QkLQksjl (P4) dkfLVd lksM+k foy;u ds lkFk fØ;k dj PH3 o NaH2PO2 cukrk gSA tc vfHkfØ;k dks
lUrqfyr fd;k tkrk gS rks P4, dkfLVd lksM+k PH3 o NaH2PO2 ds jllehdj.kferh; xq.kkadksa dk ;ksx x gS] x Kkr
dhft,A
13. feyku dhft, %
dkWye-I dkWye-II
A. [Cr(NH3)6]3+ (p) d2sp3
B. [Co(en)3]3+ (q) CFSE = – 1.2 0
C. [Co(NO2)6]4– (r) vuqpEq cdh;
D. [Co(H2O)6]2+ (s) sp3d2
ChemINFO Solid State

Daily Self-Study Dosage for mastering Chemistry Crystal Systems
;gk¡ vla[; la[;k esa lEHko tkyd gksrs gS D;ksafd ;gk¡ muds chp fdlh çdkj ds tkyd :ikUrj.k dh yEckbZ vFkok dks.k
ij çfrcU/k ugha gSA T;kferh; voyksdu ds vk/kkj ij lS)kfUrd :i ls ;gk¡ fØLVy dh leferrk ds 32 fofHkUu la;kstu
gks ldrs gSA
nwljh vksj czsfol fØLVy ra=k ds dsoy lkr çdkj n'kkZrk gSA
(a) ?kuh; (b) f}leyack{k (c) fo"keyack{k (d) f=kleurk{k (e) "kV~dks.kh; (f) ,durk{k (g) f=kurk{k
PAGE NO.-30
lkr fØLVy ra=k
fØLVy ra=k v{kh; varjky v{kh; dks.k mnkgj.k ,dd~ dksf"Bdk ds izdkj
?kuh; a=b=c  =  =  = 90° Cu, ZnS, KCl S,BCC,FCC
f}leyack{k a=b c  =  =  = 90° Sn('osr fVu), SnO2,TiO2 S,BC
fo"keyack{k a  b c  =  =  = 90° jkWfEcd lYQj, CaCO3 S,BCC,FCC,ECC
,durk{k a b  c  =  = 90°;  90° ,durk{k lYQj, PbCrO2 S,BCC
"kV~dks.kh; a=b c  =  = 90°; = 120° xzsQkbV, ZnO S
f=kleurk{k a=b=c  =  =   90° CaCO3(dsYlkbV), HgS(flusckj) S
f=kurk{k a  b c  90° K2Cr2O7, CuSO4.5H2O S
c
?kuh;   ; f}leyack{k c
; fo"keyack{k ; ,durk{k ;
b c
b c
b
a  a a
b
a
c
c c
"kV~dks.kh; ; f=kleurk{k ; f=kurk{k
b
b
a a
b
a
14. ,d fn, x, fØLVy ds fy, tkyd çkpky a = 8.42 Å, b = 8.42 Å rFkk c = 9.80 Å gSA muds funsZ'kh; v{k ,d
nwljs ds vU;ksU; :i ls yEcor gSaA fØLVy fuEu gSA
(A) f}leyack{k (B) fo"keyack{k (C) ,durk{k (D) f=kdks.kh;
15. fØLVy foek a = b  c ;  =  = 90º  = 120º çnf'kZr djrh gSA
(A) f}leyack{k (B) "kV~dks.kh; ra=k (C) ,durk{k (D) fo"keyack{k
16. fuEu esa ls fdl ,dd dksf"Bdk ds fy, lcls de leferrk gS \

(A) f}leyack{k (B) ,durk{k (C) f=kurk{k (D) ?kuh;
17. fups fn;s x;s ,dd dksf"Bdkvksa esa ls fdles a lokZf/kd leferrk gS \
(A) "kV~dks.kh; (B) fo"keyEck{k (C) ?kuh; (D) ,durk{k

Single correct Objective ('–1' negative marking) Q.1 (3 marks, 2 min.) [03, 02]
A+ -
1. AB Bksl lajpuk ij fopkj dhft, o blds mi;ksx ls r+ / r– dks ifjdfyr dhft,A M N B
(A) 0.155
(B) 0.225
.
(C) 0.414
(D) 0.732 K . L
a
PAGE NO.-31
2. ladqy [PtCl2(NH3)(OH2)] ds lanHkZ esa fuEu esa ls dkSulk@dkSuls dFku lR; gS@gSaA [Pt dk ijek.kq Øekad = 78]
(A) blds lei{k o foi{k nks T;kferh; leko;oh gksaxsA (B) ;g ,d oxZ leryh; ladqy gSA
(C) ;g ,d izfrpqEcdh; ladqy gSA (D) ;g gkbMªsV leko;ork iznf'kZr dj ldrk gSA
3. dkSulk@dkSuls dFku lgh gS ?

(A) [Co(en)3] [Cr(CN)6] milgla;ksth leko;ork n'kkZ;saxsA (B) [Mn(CO)5(SCN)] fyadst leko;ork n'kkZ;saxsA
(C) [Co(NH3)5(NO3)]SO4 vk;uu leko;ork n'kkZ;saxsA (D) dksbZ lgh ugha gSA
4. ;kSfxd Na2IrCl6] VªkbZQsfuyQkWfLQu ds lkFk] MkbZ,fFkyhu Xykbdksy esa rFkk CO ds okrkoj.k esa vfHkd`r gksdj
[IrCl(CO)(PPh3)2] nsrk gSA ;g ;kSfxd *okWLdks ;kSfxd* ('Vaska's compound') dgykrk gSA
(Ir dk ijek.kq Øekad = 77 gSA)
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa ?
(A) ladqy dk IUPAC uke] dkcksZfuyDyksjhMksfcl¼VªkbZQsfuyQkWfLQu½bZfjMh;e (I) gSA
(B) /kkrq vk;u dk ladj.k sp3 gSA
(C) ladqy dk pqEcdh; vk?kw.kZ ¼dsoy pØ.k½ 'kwU; gSA
(D) ladqy T;kferh; leko;ork ds lkFk&lkFk vk;uu leko;ork Hkh n'kkZrk gSA
5. Bkslks esa =kqfV;ksa ds lanHkZ esa dkSulk@dkSuls dFku lgh gS@ gSaA
(A) lkekU;r% 'kkSVdh =kqfV] /kuk;u rFkk _.kk;uksa ds vkdkj esa cgqr de vUrj ds dkj.k gksrh gSA
(B) 'kkSVdh =kqfV ds dkj.k Bkslksa ds ?kuRo esa deh vkrh gSA
(C) ;kSfxd ftuesa F-dsUnz mifLFkr gksrs gSa] og izfrpqEcdh; gksrs gaSA
(D) Ýsady =kqfV ,d izdkj dh LFkku ifjorZu (dislocation) =kqfV gSA
6. jkWd lkYV fØLVy ds fy,] fuEu esa ls dkSulk@dkSuls dFku lgh ugha gS@ gSaA
(A) ;fn 'kkWVdh =kqfV }kjk lHkh dk; dsUnzhr Na+ vk;uksa dks i`Fkd dj fn;k tk;s rc] ;kSfxd dk lw=k Na3Cl4 gksxkA
(B) ;fn ,dkUrfjr prq"Qydh; fjfDr;ksa esa] Na+ vk;u mifLFkr gks rc] ;kSfxd dk lw=k Na2Cl gksxkA
(C) ;fn lksfM;e ok"i dh mifLFkfr esa] tkyd ls dqN Cl– vk;uksa dks foLFkkfir dj fn;k tk;s rc] ;kSfxd dk jax
ifjofrZr gks tk;sxkA
(D) ;fn fØLVy esa vUrjvk;fud nwjh 4.2 Å gS] rc bdkbZ dksf"Bdk dh dksj yEckbZ 8.4 Å ds cjkcj gksxhA
7. fuEu O;oLFkk dk voyksdu dhft,A xSls leku nkc ij gSA ekuk fd O2 o N2

vkn'kZ :i ls O;ogkj djrh gSA rc foHkktu X (/khjs ls) dks gVkus ij] bl
çØe ds fy, fuEu esa ls fdrus vuqekfur fodYi lgh gS\
(i) Sfudk; < 0 (ii) Sifjos'k < 0 (iii) Sczá.M > 0
(iv) U > 0 (v) H > 0 (vi) G < 0
8. N% (six) Si–O–Si cU/ku ;qDr flfydkWu R3Si–(OSiR2)n–SiR3 izkIr djus ds fy, R2SiCl2 dh x bdkbZ o R3SiCl dh
y bdkbZ yh tkrh gSA (x + y) dk eku gS&
9. ,d H ds leku Lih'kht dk izkn'kZ fdlh mÙksftr voLFkk 'A' esa gS rFkk 10.2 eV ÅtkZ dk ,d QksVkWu vo'kksf"kr djds
u;h voLFkk B esa tkrh gSA tc voLFkk 'B' ls bysDVªkWu izR;{k ;k vizR;{k :i ls (directly or indirectly) vk| voLFkk esa
ykSVdj vkrs gS rks fofHkUu rjaxnS/;Z ds 15 QksVkWu izsf{kr gksrs gS ftuesa ls dsoy 9 QksVkWu 10.2 eV ls vf/kd ÅtkZ
j[krs gSaA H ds leku Lih'kht dk ijek.kq Øekad Kkr djksA viuk mÙkj 7 ls xq.kk djus ds i'pkr~ nhft;sA
10. ,d :afMr prq"Qyd (truncated tetrahedron) esa mifLFkr "kV~Qyd o f=kdks.kh; Qyd dh la[;k dk ;ksx gS %
11. 0.1892 mol kg–1 KCN ;qDr ,d tyh; foy;u dk fgekad 0.70°C gSA Hg(CN)2 ds 0.09 eksy dks mijksDr foy;u
ds 1kg esa feykus ij foy;u dk fgekad –0.53°C ik;k x;kA Ekkukfd fuEu lehdj.k ds vuqlkj ladqy curk gS %
Hg(CN)2  X(CN)  [Hg(CN)X  2 ] X 
X Kkr dhft, (fn;k gS % ty dk Kf = 1.86K/molal):
PAGE NO.-32
12. vkWxZu fcc O;oLFkk esa fØLVyhd`r gksrk gS rFkk Bksl rFkk nzo vkxZu ds ?kuRo Øe'k% 1.59 g cm– 3 rFkk 1.42 g
cm–3 gSa rks nzo Ar esa fjDr LFkku dk izfr'kr ¼yxHkx½ Kkr dhft,A
13. feyku dhft, %
dkWye I dkWye II
A. 74% ladqy {kerk ¼izfr'kr ?kuRo½ (p) ¶yksjkbV lajpuk esa /kuk;u dh leUo; la[;k
B. leUo; la[;k -8 (q) ?kuh; fufcM ladqyu
C. CaF2 esa Ca2+ vk;u (r) "kV~dks.kh; fufcM ladqyu
D. leUo; la[;k – 12 (s) dk; dsUnzh; ?kuh; ladqyu

Daily Self-Study Dosage for mastering Chemistry Ionic solid AB Type
vk;fud fØLVy esa tkyd esa rqY;kad ek=kk esa ,d /kuk;uksa o _.kk;uksa esa bl çdkj ls Øe esa O;ofLFkr fd;k tkrk gS fd
tkyd esa vk;uksa dh fLFkfrt ÅtkZ U;wUkre gksa o bl çdkj ds fØLVy lkekU; :i ls vk;fud ;kSfxd esa çkIr gksrs gSA
NaCl  Na+ + Cl –
Limiting radius ratio
r +/r– C.N Shape
vk;fud ;kSfxd <0.155 2 linear
0.155 –0.225 3 planar triangle
AB çdkj AB2 çdkj 0.225 – 0.414 4 Tetrahedral
0.414 – 0.732 4 Square planar
NaCl CsCl ZnS CaF2 TiO2
0.414 – 0.732 6 Octahedral
0.732 – 0.999 8 Body- centered cubic
NaCl çdkj
r
NaCl dk eku 0.52 gSA ;g çdkj v"VQydh; vkÑfÙk dk crkrk gSA blesa çR;sd Na+ vk;u ds pkjksa vksj N% Cl–
r–
vk;uksa }kjk f?kjk jgrk gS o çR;sd CI– vk;u N % Na+ vk;uksa }kjk f?kjk jgrk gSA NaCldh v"VQydh; lajpuk esa Cl–
vk;u c.c.p O;oLFkk j[krk gSA ftlesa lHkh v"VQydh; fNæksa dks Na+ vk;uksa }kjk Hkjk tkrk gSA bl lajpuk ds vU; mnkgj.k
Li. Na, K, Rb o Ag (AgF ds flok;) ds gSykbM o Mg, Sr, Ba ds lYQkbM gSA
Anion Cation
ZnS çdkj % ZnS esa /kuk;u o _.kk;u dh f=kT;k 0.40 gS tks bls vkd`fÙk dksa prq"Qydh; crkrh gSA çR;sd Zn2+ vk;u pkj
S2– vk;uksa }kjk prq"Qydh; :i ls f?kjk gksrk gS o çR;sd S2– vk;u pkj Zn2+ vk;uksa }kjk prq"Qydh; :i ls f?kjk gksrk
gSA vFkkZr ZnS dh leUo; la[;k 4 gSA bl çdkj ;g lajpuk 4 : 4 O;oLFkk j[krh gS] ;g /;ku nsus ;ksX; gS fd ftUd Cys.M
(ZnS) dh ccp ljapuk j[krk gSA tcfd oqVZtkbV (ZnS) hcp j[krk gSA vU; mnkgj.k CuCI, CuBr, CuI, o BeS gSA
14. ftUd Cys.M ljapuk esa ftUd vk;u ,dkUrfjr] prq"Qydh; fjfDr;ksa ls f?kjk gksrk gS o S2– vk;u ccp dsa :i esa
gksrk gSA Zn2+ o S2– vk;uksa dh f=kT;k Øe'k% 0.83 Å o 1.74 Å gaSA ZnS ,dd~ dksf"Bdk ds fy, dksj yEckbZ fuEu gSA
(A) 2.57 Å (B) 5.14 Å (C) 5.93 Å (D) 4.86 Å
PAGE NO.-33
+
15. ;fn NaCl fØLVYk esa Na o Cl vk;uksa ds fy, nwjh ‘a’ pm gS] rks dksf"Bdk dh dksj yEckbZ D;k gS \
–
(A) 2a (B) a/2 (C) 4a (D) a/4

16. jkWd lkYV çdkj ljapuk ds fy, fuEu esa ls dkSulk dFku xyr gS \
(A) ;g Na+ vk;uksa ds fy, FCC O;oLFkk gS
(B) ;g Na+ o Cl– vk;uksa ds fy, leUo; la[;k 6 :6 gSA
(C) NaCl ds fy, ,dd~ dksf"Bdk pkj NaCl bdkbZ j[krk gSA
(D) {kkj /kkrqvksa ds lHkh gSykbM jkWd lkWYV çdkj dh ljapuk j[krs gSA
17. ftUd Cys.M ljapuk esa S2– ccp O;oLFkk o Zn2+ vk;u
(A) v"VQydh; O;oLFkk j[krs gSA (B) "kV~dks.kh; O;oLFkk j[krs gSA
(C) prq"Qydh; O;oLFkk j[krs gSA (D) dksbZ ugha j[krs gSA

1. ,Fkhu dh gkbMªkstuhdj.k Å"ek x1 rFkk csUthu dh x2 gS blfy, csUthu dh vuqukn ÅtkZ gSA
(A) x1 – x2 (B) x1 + x2 (C) 3x1 – x2 (D) x1 – 3x2
2. vR;f/kd eksyj vk;ru okyh ,d okLrfod xSl ds fy, fuEu esa ls dkSulh lehdj.k lokZf/kd mi;qDr :i ls iz;qDr
dh tk ldrh gS %
a Pb a
(A) Z = 1 – (B) PVm = RT (C) Z = 1 + (D) PVm – RT =
VmRT RT Vm
3. vkWDlhtu dk Økafrd rki 154K rFkk Økafrd nkc 50 atm fn;k x;k gSA fuEu esa ls dkSuls dFku lR; gSa\
I. 154K rFkk 50 atm ij ,d cUn ik=k esa, vkWDlhtu dh Bksl] nzo rFkk xSl voLFkkvksa esa lkE;koLFkk gksxhA
II. vkWDlhtu xSl dks dejs ds rki ij nzfor fd;k tk ldrk gSA
III. ;g dgk tk ldrk gS fd veksfu;k dk ØkfUrd rki 154 K ls vf/kd gSA
(A) I lR; gS (B) II rFkk III lR; gS (C) III lR; gSA (D) I rFkk III lR; gSA
4. v.kq XF4 ds f}/kqzo vk?kw.kZ dk eku v'kwU; gS] rc X gS :
(A) Xe (B) Si (C) S (D) buesa dksbZ ugha
5. fuEu esa ls dkSUk NaOH ds lkFk vfHkfØ;k djds ,d xSl eqDr djrk gSA
(A) S8 (jksgfEcd lYQj) (B) Cl2
(C) P4 (lQsn QkLQksjl) (D) C (xzsQkbV)
6. ,d inkFkZ CO2 dks vo'kksf"kr djrk gS rFkk 'kh?kzrk ls ty ds lkFk vfHkfØ;k djrk gSA inkFkZ gS
(A) CaCO3 (B) CaO (C) H2SO4 (D) ZnO
7. 4 g X (ijek.oh; nzO;eku = 40), tks BCC O;oLFkk esa fØLVyhÑr gksrk gS] esa ,dd dksf"Bdkvksa dh dqy la[;k gS &
(NA = vkoksxknzks la[;k)&
0.1 NA
(A) 0.1 NA (B) 2 × 0.1 NA (C) (D) 2 × NA
2
8. BaCl2, NaCl ,oe~ Xywdksl ds leeksyj foy;ukas ds ijklj.k nkc dk Øe gSA
(A) Xywdksl > NaCl > BaCl2 (B) BaCl2 > NaCl > Xywdksl
(C) NaCl > BaCl2 > Xywdksl (D) NaCl > Xywdksl > BaCl2
9. fuEu esa ls dkSu vf/kdre vk;fud pkydrk çnf'kZr djrk gS \

(A) K4[Fe(CN)6] (B) [Co(NH3)6]Cl3 (C) [Cu(NH3)4]Cl2 (D) [Ni(CO)4]
PAGE NO.-34
10. fuEu esa ls dkSulk ladqy lcls T;knk leko;oh j[krk gS \
(A) [Co(NH3)4Cl2] (B) [Ni (en)(NH3)4]2+ (C) [Ni(C2O4)en2]2– (D) [Cr(SCN)2(NH3)4]+
11. Cr rFkk Fe ds ijek.kq Øekad Øe'k% 24 o 26 gSaA bysDVªkWu ds çpØ.k ds lkFk dkSulk vuqpqEcdh; gS\
(A) [Cr(CO)6] (B) [Fe(CO)5] (C) [Fe(CN)6]4– (D) [Cr(NH3)6]3+
12. IUPAC ukedj.k ds vuqlkj] lksfM;e ukbVªksizwlkbM dk uke gS :
(A) lksfM;e ukbVªksQSfjlk;ukbM (B) lksfM;e ukbVªksQSjkslk;ukbM
(C) lksfM;e isUVklk;ukbMksukbVªkslksfu;eQSjsV (II) (D) lksfM;e isUVklk;uks ukbVªksflyQSjsV (III)
13. fuEu esa ls dkSulk ;kSfxd çdk'kh; leko;rk çnf'kZr djsxk\

(A) isUVk,EehuukbVªksdksckWYV (III) vk;ksMkbM
(B) Mkb,EehuMkbDyksjksIysfVue (II)
(C) foi{k&Mkblk;uksfcl~ ¼,Fkkbyhu Mkb,ehu Øksfe;e (III) DyksjkbM)
(D) fVªl&¼,FkkbyhuMkb,ehu½ dksckYV (III) czksekbM
14. fuEu esa ls dkSulk ladqy mPpre vuqpEq cdh; O;ogkj çnf'kZr djrk gS \
tgk¡, gly = Xykblhu, en = ,fFkyhuMkbZ,ehu rFkk bpy = ckbZikbZjhfMy lewg)
(ijek.kq la[;k Ti = 22, V = 23, Fe = 26, Co = 27)
(A) [V(gly)2(OH)2(NH3)2]+ (B) [Fe(en)(bipy)(NH3)2]2+
(C) [Co(OX)2(OH)2]– (D) [Ti(NH3)6]3+
15. fuEu esa ls dkSulk ladqy vk;u n`'; izdk'k dks vo'kksf"kr ugha djrk gS \
(A) [Ni(CN)4]2– (B) [Cr(NH3)6]3+ (C) [Fe(H2O)6]2+ (D) [Ni(H2O)6]2+
16. fuEu esa ls dkSulk ladqy ;qXe izdkf'kd leko;ork n'kkZrk gS \
(A) lei{k-[Cr(C2O4)2Cl2]3–, lei{k-[Co(NH3)4Cl2] (B) [Co(en)3] Cl3 ,lei{k-[Co(en)2Cl2]Cl
(C) [PtCl(dien)Cl] , [NiCl2Br2]2– (D) [Co(NO3)3(NH3)3], lei{k-[Pt(en)2Cl2]
17. ;kSfxd [Ir(en)2(NH3)(NO2)]2+ ds fy, lHkh laHko leko;oh;ksa ¼lajpukRed rFkk f=kfoe leko;oh½ dh la[;k Kkr
djksA
18.  Si2O5 n2n esa izfr SiO44 bdkbZ lkWf>r vkWDlhtu ijek.kqvksa dh dqy la[;k gS &
19. ;fn pH = 2 rFkk pH = 4 ds nks foy;uksa dks Øe'k% 1 : z ds vk;ru vuqikr esa fefJr fd;k x;k ifj.kkeh foy;u dk
pH = 2.75 ik;k x;kA rc z dk eku Kkr dhft;s \ (fn;k gS : log 1.75 = 0.25)
20. xSlh; H2, Cl2 rFkk HCl dh cU/k fo;kstu ÅtkZ Øe'k% 104, 58 rFkk 103 kcal mol–1 gSA HCl xSl ds fy, lEHkou dh
,UFkSYih ifjdfyr dhft,A
21. v"VQyd esa dksuksa dh la[;k fdruh gksxh\

Daily Self-Study Dosage for mastering Chemistry Magnetic properties
tc inkFkksZ dks pqEcdh; {ks=k esa j[krs gS rc buds O;ogkj ds vk/kkj ij bUgs ik¡p Jsf.k;ksa esa j[kk tkrk gSA
xq.k oxhZdj.k lajs[k.k mnkgj.k vuqiz;ksx
pqEcdh; {ks=k +}kjk fu"df"kZrA os
;qfXer e– j[krk gS o v;qfXer lHkh ;qfXer e gksA
–
çfrpqEcdh; TiO2, V2O5. dqpkyd

e– vuqifLFkr gksrs gSA
v/kkfRod rRo ¼flok;s O2, S½
LFkk;h pqEcdh; vk?kq.kZ dh de ls de v;qfXer
O2, Cu2+, Fe3+, VO2, bySDVªkWfud
mifLFkfr ds dkj.k pqEcdh; {ks=k e gksA
–
vuqpEq cdh;
CuO vuqç;ksx
)kjk vkd"kZ.k
PAGE NO.-35
leku fn'kk esa f)/kzqo JO; o n`'; nksuksa
pqEcdh; {ks=k dh vuqifLFkfr esa Hkh lajsf[kr gksrs gSA
ykSgpqEcdh; Fe, Ni, CO, CrO2 esa CrO2 ç;qDr
LFkk;h pqEcdRo
gksrk gSA
;g gksrk gS tc leku o foijhr MnO, MnO2, Mn2O,
çfrykSgpqEcdh; lajs[k.k ds dkj.k tc f}/kzqo FeO, FeO2; NiO, -
vk?kw.kZ 'kwU; gksrk gSA Cr2O3, CoO, CO3O4
;g gksrk gS tc ifj.kkeh f}/kzqo FeO3O4 (Magnetite),
y?kqykSgpqEcdh; ferrites like MgFe2O4, -
vk?kw.kZ gksA ZnFe2O4
22. fuEu esa ls dkSulk fodYi lgh gSA
(A) O2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA (B) S çfrpqEcdh; xq.k/keZ n'kkZrk gSA
(C) TiO2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA (D) VO2 çfrpqEcdh; xq.k/keZ n'kkZrk gSA
23. fuEu esa ls fdldk lgh feyku gksrk gS \

(A) çfrpqEcdh;  (B) vuqpEq cdh; 
(C) ykSgpqEcdh;  (D) çfrykSgpqEcdh; 
24. fuEu esa ls dkSulk fodYi lgh gS

(A) çfrpqEcdh; xq.k/keZ pqEcdh; {ks=k }kjk çfrdf"kZr inkFkZ dks n'kkZrk gSA
(B) vuqpEq cdrk T.V o /kksus dh e'khu dks cukus ds fy, ç;qDr inkFkZ ds xq.k/keZ dks n'kkZrk gSA
(C) nksuksa lgh gSA
(D) dksbZ ughaA
25. fuEu esa ls dkSu lk lgh ugha gS

(A) ykSgpqEcdh; esa f}/kzqo leku fn'kk esa lajsf[kr gksrs gSaA
(B) y?kqykSgpqEcdh; esa ifj.kkeh f}/kzqo vk/kw.kZ 'kwU; gksrk gSA
(C) ykSgpqEcdh; xq.k/keZ JO; o n`'; dks cukus ds fy, ç;qDr inkFkZ dks n'kkZrk gSA
(D) çfrykSgpqEcdh; çkIr gksrk gS tc f}/kzqo vk?kw.kZ 'kwU; gksrk gSA

Single correct Objective ('–1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06]
1. 'kq) voLFkk esa 100 Vksj ok"i nkc j[kus okyk nzo A, 50 Vksj rFkk 25 Vksj ok"i nkc n'kkZrk gS] tc bldh fLFkj ek=kk
dks Øe'k% nzo B rFkk nzo C dh fuf'pr ek=kk esa ?kksyk x;kA A dk ok"i nkc D;k gksxk] tc nksuksa foy;uksa dks fefJr
fd;k tkrk gS\ (vkn'kZ feJ.k ekus)
(A) 37.5 Vksj (B) 75 Vksj (C) 12.5 Vksj (D) 33.3 Vksj (E) 25 Vksj
2. ,d ?kuh; fudk; dh n ,dd dksf"Bdkvksa ;qDr ,d ?ku ij fopkj fdft;s \

A
A
D B
D B
C C
Arrangement of atoms
PAGE NO.-36
blds leku Qydks ds fdukjksa ds e/; fcUnqvksas dks tksM+ dj izkIr ,d ry ABCD ds ijek.kqvksa dh O;oLFkk fuEu
izdkj gS% ekuk p ladqyu n{krk gSA lgh fodYi dk p;u fdft;sA
22 11 11 11 3
(A) n = 1 , p = (B) n = 8 , p = (C) n = 8, p = (D) n = 1 , p =
21 2 21 14 28
3. cksjsDl dk ,d tyh; foy;u :

(A) uhys fyVel dks yky esa ifjofrZr djrk gSA
(B) ,d izcy vkDlhdkjd gSA
(C) dkxt rFkk iYi m|ksx esa ,d pfpZr fojatd ds :i esa iz;qDr gksrk gSA
(D) HCl ls vuqekfir fd;k tk ldrk gSA
4. ;fn PCl3 (g) rFkk PH3 (g) ds lEHkou dh Å"ek Øe'k% 140 rFkk 8 KJ eksy–1 gSa rFkk QkWLQksjl P4(s), Dyksjhu rFkk
gkbMªkstu ds ijek.oh;dj.k dh Å"ek Øe'k% 320, 120 rFkk 216 KJ eksy–1 gSa] rks fuEu esa ls dkSulk@dkSuls dFku
lgh gS@gSa\
(A) P–Cl dh ca/k ÅtkZ 63 KJ mol–1 gSA
(B) P–H dh ca/k ÅtkZ 210 KJ mol–1 gSA
(C) foyfxr xSlh; gkbMªkstu ijek.kq ds laHkou dh Å"ek 108 KJ mol–1 gSA
(D) foyfxr xSlh; Dyksjhu ijek.kq ds laHkou dh Å"ek 60 KJ mol–1 gSA
5. 1 atm ij ,d lhyc) ¶ykLd esa fufgr ,d eksy vkn'kZ xSl dks 27ºC ls 127ºC rd xeZ fd;k tkrk gSA
(fn;k gS : S(JK–1) = 10 + 12× 10–3 T, R = 0.082 atm L/mol K, 1 atm L = 101.3 J) lgh foDYi@fodYiksa dk
p;u dhft,&
(A) V = 12.3 L (B) vfUre nkc 4/3 atm gSA
(C) G = –589.34J (D) G = 322.5 J
vuqPNsn #
la;kstdrk ca/k fl)kUr esa] d{kdksa dk ladj.k ca/k fuekZ.k dk ,d egRoiw.kZ Hkkx gSA lad j.k esa **'kq)** ijekf.o;
d{kdksa dk lfEeJ.k vFkok js[kh; la;kstu bl izdkj gksrk gS fd ftlds }kjk u;s ladfjr d{kd curs gSa] tSls sp,
sp2, sp3, sp3d, sp3d2 bR;kfnA
vc fuEufyf[kr iz'uksa ds mÙkj nhft, %
6. fuEu esa ls dkSulk@dkSuls ijekf.o; d{kd f=kdks.kh; f}fijkfefM; ladj.k vFkkZr~ sp3d ladj.k esa Hkkx ysrs gS@gSa ?
(I) dZ2 (II) d (III) dxy (IV) pz
x2 –y2
(A) II, IV (B) III, IV (C) I, IV (D) dsoy II
7. fuEu esa ls dkSuls ijekf.o; d{kd [Pt(NH3)4]+2 ds lkFk&lkFk [Cr(CN)6]3– ds ladj.k esa Hkh Hkkx ysrs gSa \
(I) s (II) d (III) d (IV) px
x2 –y2 z2
(A) III, IV (B) I, III, IV (C) I,II,III, IV (D) I, II, IV
8. pKb1 = 5.2 o pKb2 = 16.7 ds N2H4 ,d f}izksfVd {kkj gSA N2H62+(Cl–)2 dk 0.1 M tyh; foy;u pH (yxHkx)
................. j[krk gSA (fudVre iw.kkZad dks pqfu;s)
2R
9. f=kT;k R ds N% leku xksyksa dks fp=k esa n'kkZ, vuqlkj fizTe ds izR;sd dksus ij O;ofLFkr
fd;k tkrk gSA bldk ladqyu izHkkt x gS] rc 10x gS &
2R
PAGE NO.-37
2
10. 1 cm vuqizLr dkV {ks=kQy ;qDr ,d le:i ufydk dks ,d fljk v)ZikjxE; f>Yyh ls can gSaA ufydk esa] izfr
100 ml , 6 xzke Xywdksl ;qDr foy;u Hkjk tkrk gS rFkk ;g ufydk 27C ij 'kq) ty esa j[kh tkrh gSA tc lkE;
LFkkfor gksrk gS rc] ijklj.k nkc (ehVj esa) D;k gS (m)Zokgj dkWye dh izkIr ÅpkbZ ds :i esa ) Xywdksl foy;u dk
?kuRo 1 gm/ml gSA (fyft;s R = 0.08 L atm mol–1 k–1, Hg dk ?kuRo = 13.8 g/cc)
11. ladqy [CoL2Cl2]– ds fy, lEHko leko;oh;ksa dh la[;k (vlefer f}nUrqd fyxs. M L = H2NCH2CH2O–) gksxh&
12. ,d tyh; foy;u essa Øe'k% nqcZy vEy (HA) rFkk ;wfj;k Hkkj ds vuqlkj 6% rFkk 4% lfEefyr gSA ;fn fgekad esa
13.6
voueu ºC gSA ;fn HA dk Ka, x gS] rks 100x dk eku Hkfj;sA [Kf = 1.8 K-Kg/mole] (HA dk v.kqHkkj = 60,
3
dfoy;u = 1gm/ml). ekuk HA rFkk ;wfj;k ds e/; vfHkfØ;k ugha gksrh gSA
13. fuEu esa dkcZ/kkfRod ;kSfxdksa dh la[;k gaS&

[PtCl3(η 2-C2H4)]–, [Ni(CO)4], Al2(CH3)6, (C2H5)3B, (CH3)2CuLi, Na2CO3, [Fe(η 5-C5H5)2], CH3MgX,
(CH3COO)2Pb
14. ikWVys.M lhesUV esa fuEu esa ls fdrus ;kSfxd lfEefyr gS \
MgO, MgCO3, MgCl2, CaO, SiO2, Fe2O3, CaSO4, FeSO4, SO3, Al2O3 rFkk CaCl2.
viuk mÙkj 4 ls xq.kk djus ds i'pkr~ nhft,A
15. 0.2 M CH3COOH ds leku vk;ru dks 0.2 M NaOH foy;u ds lkFk fefJr fd;k tkrk gS] rks ifj.kkeh foy;u
dh pH dk fu/kkZj.k dhft,A viuk mÙkj 9 ls xq.kk djus ds i'pkr~ nhft,A [Ka(CH3COOH) = 10–5]
16. Co(NH3)4 Cl3 dk 0.25 eksyy tyh; foy;u –0.93ºC ij terk gSA bl milgla;kstd ;kSfxd ds fy, f=kfoe
leko;oh;ksa dh la[;k ifjdfyr dhft,A H2O ds fy, eksyy voueu fLFkjakd 1.86 K/eksyy gSA ¼milgla;kstd
;kSfxd dk blds vk;uks es iw.kZ fo;kstu ekurs gq,½
1. ,d dkYifud xSl X (v.kqHkkj = 8 amu) dk ?kuRo STP ij g/L ls de iszf{kr fd;k x;k gS] rks mijksDr ifjfLFkfr;ksa
esa xSl X ds fy, fuEu esa ls dkSulk@dkSuls dFku lgh gSa %
(A) xSl X ds v.kqvksa esa izfrd"kZ.k izo`fÙk izHkkoh gSA
(B) xSl X ds fy, TB (ckW;y rki) dk eku 273.15 K ls vf/kd gSA
(C) xSl X ds fy, Vm (eksyj vk;ru) dk eku 22.4 L ls de gSA
(D) vkn'kZ xSl dh rqyuk esa xSl X dh laihM~;rk de gSA
2. NH2–, NH3 ,NH4+ ds fy, D;k lR; gS \

(A) N dk ladj.k leku gSA (B) N ij ,dkdh bysDVªkWu ;qXe dh la[;k leku gSA
(C) vk.kfod T;kfefr (vFkkZr vkd`fr) fHkUu gSA (D) cU/k dks.k leku gSA
3. fuEu esa ls fdu v.kqvksa esa dsUnzh; ijek.kq esa v"V~d dk izlkj gksrk gS \
(A) PCl5 (B) SO4– – (C) NH3 (D) ClO3–
4. bySDVªkWu] izksVksu rFkk d.kksa ds fy, MhczksXyh rjaxnS/;Z dk xq.kkRed Øe e > P >  gSa] ;fn&
(A) lHkh d.kksa ds fy, xfrt ÅtkZ leku gksa
(B) lHkh d.kksa ds fy, Rofjr foHkokUrj 'V' leku gksa ¼fojkeoLFkk ls½
(C) lHkh d.kksa ds fy, osx leku gksa ]
(D) mijksDr esa ls dksbZ ugha
PAGE NO.-38
5. ,d yhVj ik=k esa ,d lkE; A(g) 2B(g) LFkkfir gSA lkE;koLFkk ij A ds eksYl rFkk B ds eksYl leku (çR;sd
ds 2 eksy) ik;s x;s gaSA vc fLFkj rki ij ;fn vfHkfØ;k ik=k dk vk;ru vk/kk dj nsa rFkk lkE;koLFkk iqu% LFkkfir
gksus nh tk;s rks fuEu esa ls dkSulk@dkSuls dFku lR; gSa ?
(A) ubZ lkE;koLFkk esa A rFkk B dh lkUnzrk Øe'k% 4.5 M rFkk 3 M gSaA
(B) vk;ru dks vk/kk djus ij lkE; vxz fn'kk esa foLFkkfir gksxkA
(C) vk;ru dks vk/kk djus ij lkE; i'p fn'kk esa foLFkkfir gksxkA
(D) vk;ru dks vk/kk djus ij lkE; fdlh Hkh fn'kk esa foLFkkfir ugha gksxk D;ksafd çkjfEHkd lkE; esa A rFkk B ds eksy
leku (çR;sd ds 2 eksy) gaSA
6. ,d ?kuh; dksf"Bdk esa A ijek.kq dksuks ij mifLFkr gS tcfd Qyd dsUnzks ls A ijek.kq yqIr gSA B ijek.kq dksj dsUnz
rFkk dk; dsUnz ij gSA C ijek.kq izR;sd lw{e ?ku (dksj yEckbZ a/2) ds dk; dsUnz ij mifLFkr gSA rc lgh
dFku@dFkuksa dk p;u dhft,& (a = dksj yEckbZ ?ku)
(A) ;kSfxd dk lw=k ABC2 gSA
(B) ;fn ,d dk; fod.kZ ds vuqfn'k lHkh ijek.kqvksa dks gVk nsrs gS] rks ifj.kkeh lajpuk esa A,B,C ijek.kq dk vuqikr
1 : 4 : 8 gSA
(C) ,d lw{e ?ku esa A,B,C ijek.kq (izHkkoh) dk vuqikr 1 : 4 : 8 gSA
(D) lw{e ?ku esa dsoy ik¡p dksus f?kjs gq, gSA
7. 0.01 eksyy tyh; CH3COOH foy;u ds fgekad dk voueu 0.02046° gSA ,d eksyy tyh; ;wfj;k foy;u
–1.86°C ij terk gSA ekuk fd eksyyrk eksyjrk ds cjkcj gS rc CH3COOH foy;u dh pH Kkr dhft;sA
8. fuEufyf[kr esa ls fdrus ;kSfxdksa @ feJ.kksa ds tyh; foy;u dh pH, foy;u dks ruq djus ij Hkh fu;r jgrh gS %
(1) NH4Cl
(2) Na2CO3
(3) Na2S rFkk HCl dk 1 : 2 eksyj vuqikr dk ,d feJ.k
(4) NaOH rFkk H3PO4 dk 5 : 2 eksyj vuqikr dk ,d feJ.k
(5) CH3COONa rFkk HCl dk 5 : 4 eksyj vuqikr dk ,d feJ.k
(6) NaH2PO4
(7) HCl rFkk NaHCO3 dk 2 : 1 eksyj vuqikr dk ,d feJ.k
(8) CH3COONH4
(9) NH4OH rFkk HCl dk 4 : 3 eksyj vuqikr dk ,d feJ.k
500
9. ,d vok"i'khy rFkk vuoS|qrvi?kV; foys; ds m tyh; foy;u dks ,d cUn ik=k es fy;k tkrk gSA lkE; ij
81
ik=k ds vUnj mifLFkr vkisf{kd vknzZrk izfr'kr ifjdfyr dhft,A
10. fuEu esa ls fdruh Lih'kht esa dsUnzh; ijek.kq nks ,dkdh bysDVªkWu ;qXe j[krk gS \
XeF4 XeF5– F2SeO2 XeF3+ XeOF4 ClOF3
ICl4– SCl2 OSF4
11. tfVy lw=k [Co(NH3)3(NO2)2Cl] ds fy, ;
dsUnzh; ijek.kq dh leUo; la[;k = a
dsUnzh; ijek.kq dk vkWDlhdj.k vad = b
T;kehfr; leko;oksa dh dqy la[;k ¼lHkh lajpukRed leko;oksa dks ysrs gq,½ = c
izdk'kh; leko;oksa dh dqy la[;k ¼lHkh lajpukRed leko;oksa dks ysrs gq,½ = d
fn;s x;s tfVy ds fy, (a + b - c+ d) dk eku gS&
12. fuEu v.kqvks ij fopkj dhft, : O2, Cl2, Li2, H2, B2, C2 rFkk N2
ekuk
a = (ca/k Øe = 1) j[kus okys v.kqvks dh la[;k b = (ca/k Øe = 2) j[kus okys v.kqvks dh la[;k
c = (ca/k Øe = 3) j[kus okys v.kqvks dh la[;k d = vuqpqEcdh; v.kqvks dh la[;k]
(a × b × c × d × 4.2) Kkr dhft,A
PAGE NO.-39
13. feyku dhft,A
dkWye– I dkWye– II
(A) H+ (tyh;) (p) Hf0 = 0
(B) H (xSl) (q) Hf0  0
(C) H2 (xSl) (r) Gf0 = 0
(D) C (s, ghjk) (s) Hf0 > 0
ChemINFO ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Topic: Galvanic Cell & Salt Bridge
og lSy ftls jsMkWDl vfHkfØ;k ls mRiUu jklk;fud ÅtkZ dks oS|qr ÅtkZ esa :ikUrfjr djus ds fy, iz;qDr fd;k tkrk gS ,d
oS|qr jklk;fud lSy ;k lkekU; jklk;fud lSy dgykrk gSA bUgsa Y;wxh XkSYosuh (1780) rFkk ,yslsUMªks oksYVk (1800) ds uke
ds i'pkRk~ xSYosfud lSy ;k oksYVsbZd lSy Hkh dgk tkrk gSA
;fn xsYosfud lSy esa bysDVªkWM vkUrfjd :i ls tqM+s gq, ugh gS rks izkjEHk esa lSy fo|qr ÅtkZ mRiUu djrk gSA bysDVªkWM le;
xqtjus ds lkFk&lkFk èkqzohd`r gksrk gS rFkk lSy dk;Z djuk can dj nsrk gSA lrr~ fo|qr ÅtkZ ds fy, bysDVªkWMksa dk vkUrfjd
:i ls tqM+k gksuk vko';d gksrk gSA
,d yo.k lsrq izk;% xsYosfud lSy ds bysDVªkWMksa dks tksMus ds fy, iz;qDr gksrk gSA ;g vklkuh ls cuk;k tk ldrk gS rFkk ,d
LoPN U ufydk esa tSy dk cuk gksrk gSA tSy dks KCl ds leku vfØ; fo|qr vi?kV~; okys ,d mcyrs gq, ty esa
vxkj&vxkj esa feykdj cuk;k tkrk gSA lkekU;r% KCl dks izkFkfedrk nh tkrh gS] D;ksa fd K+ rFkk Cl– dh vk;fud
pkydrk;sa izk;% leku gksrh gSA tSy fuEu fp=k esa n'kkZ;s vuqlkj ufydk esa bysDVªksMksa dks jksdrk gSA
Fig : yo.k lsrq rFkk oS|qr vi?kV~;

tSls gh xsYosfud lSy esa vfHkfØ;k,sa gksrh gS] ;gk¡ bysDVªksMksa ds pkjksa vkSj fo'ks"k vk;uksa dk laxzg.k gksxkA blds ifj.kkeLo:i
bysDVªkWM vfHkfØ;k;sa èkheh gks tkrh gSA yo.k lsrq KCl ds oS|qr vi?kV~; ls K+ rFkk Cl– vk;u yo.k lsrq ds fljs dh vksj xeu
djrs gSA K+ vk;u] vip;u bysDVªkWM (dSFkksM) dh vksj tcfd Cl– vk;u] vkWDlhdj.k bysDVªkWM (,uksM) dh vksj xeu djrs gSA
vkWDlhdj.k bysDVªkWM (,uksM) ij vk;u buds Lo;a dh vksj dqN foifjr vkosf'kr vk;uksa dks èkzqoh;d`r ¼vkdf"kZr½ djsaxsaA blds lkFk
gh K+ vk;u] vip;u bysDVªkWM ¼dSFkksM½ dh vksj xfr djsxas rFkk /kkrq ds pkjks vksj mifLFkr _.kkosf'kr vk;uksa dks /kzqoh;d`r
djsxsaA bl izdkj lSy lkekU; :i esa dk;Z djrk gSA blfy, ,d yo.k lsrq fuEu izdkjksa esa lgk;d gksrk gS&
1. ;g bysDVªkWMksa ds eè; vkUrfjd lEidZ ykrk gSA
2. ;g æo lfUèk foHko dks U;wure djrk gSA
3. ;g èkzqoh;dj.k dks U;wure djrk gSA
14. fuEu es ls dkSuls lsy es yo.k lsrq dh vko';drk ugha gksrh gSA
(A) Pb | PbSO4(s) | H2SO4 | PbO2 | Pb (B) Cd | CdO(s) | KOH(aq) | NiO2(s) | Ni
(C) Fe(s) | FeO(s) | KOH (aq.), Ni2O3(s) | Ni (D) Zn | ZnSO4 | CuSO4 | Cu
15. vfHkfØ;k 1/2 H2(g) + AgCl(s)  H(aq) + Cl–(aq) + Ag(s) xSyosfud lsy es gksrh gSA
(A) Ag | AgCl(s) | KCl (sol) | AgNO3 | Ag (B) Pt | H2(g) | HCl(sol) | AgNO3(sol) |Ag
(C) Pt | H2(g) | HCl (sol) | AgCl(s) | Ag (D) Pt | H2(g) | KCl(sol) | AgCl(s) |Ag
PAGE NO.-40
16. KNO3 dk larÌr foy;u yo.k lsrq cukus es iz;qDRk gksrk gS D;ksafd
(A) K dh xfr'khyrk NO3– dh rqyuk es vf/kd gksrh gSA
(B) NO3– dh xfr'khyrk Kdh rqyuk esa vf/kd gksrh gSA
(C) K rFkk NO3– dh xfr'khyrk yxHkx leku gksrh gSA
(D) KNO3 ty esa vf/kd foys;'khy gksrk gSA

Total Marks: 80 Max. Time: 55 min.
1. 1 eksy okLrfod xSl ds fy, fofj;y lehdj.k fuEu gSA
 A B C 
PV = RT 1     ..... n dh mPp ?kkrks rd 
2 3
 V V V 
;gk¡ A,B rFkk C fofj;y fLFkjkad gSA ok.Mj okWy lehdj.k dks ;fn fofj;y lehdj.k ds :i esa fy[kk tk;s rks A dk
eku gksxkA
b a a RT  b
(A) a – (B) RT – (C) b – (D)
RT b RT a
2. mijksDr oØ esa fn[kk;s vuqlkj xSlksa ds nzohdj.k dh lqxerk dk c<rk gqvk

lgh Øe gSA
(A) H2 < N2 < CH4 < CO2
(B) CO2 < CH4 < N2 < H2
(C) H2 < CH4 < N2 < CO2
(D) CH4 < H2 < N2 < CO2
3. CaCN2 esa gksrs gS %

(A) 2  ca/k , 2  ca/k (B) 3  ca/k, 1  ca/k (C) 1  ca/k, 2  ca/k (D) 3  ca/k , 2  ca/k
4. fuEu esa ls dkSulk dFku lgh gS ?

(A) izR;sd ukbVªkstu ijek.kq ij N2F3+ leryh; gSA
(B) N3H esa] H – N – N cU/k dks.k ,dne 120° ik;k tkrk gSA
(C) N(SiMe3)3 dh vkd`fr f=kdks.kh; leryh; gSA
(D) (A) rFkk (C) nksuksaA
5. Lih'kht tks ijkWDlkbM vk;u ugha j[krh gS %
(A) PbO2 (B) H2O2 (C) SrO2 (D) BaO2
6. fn;s x;s xSYosfud lSy esa&
Pt | H2g | NaClaq || AgNO3aq | Ag
L.H.S. Hkkx esa ty esa feykus ij lSy dk e.m.f. –
(A) c<+rk gSA (B) ?kVrk gS (C) vifjofrZr jgrk gS (D) buesa ls dksbZ ugha
7. Xykscj yo.k dk v.kqlw=k gS %

(A) MgSO4.7H2O (B) CuSO4.5H2O (C) FeSO4.7H2O (D) Na2SO4.10H2O
8. O2 }kjk SO2 dk SO3 esa vkWDlhdj.k ,d Å"ek{ksih vfHkfØ;k gS] SO3 dh yfC/k (yield) vf/kdre gksxh ;fn µ
(A) rki esa o`f) rFkk nkc fu;r j[kk tk,A
(B) rki esa deh rFkk nkc esa o`f) dh tk,A
(C) rki rFkk nkc nksuksa esa o`f) dh tk,A
(D) rki rFkk nkc nksuksa esa deh dh tk,A
PAGE NO.-41
9. xSYosuhd lsy esa &
(A) jklk;fud vfHkfØ;k fo|qr ÅtkZ mRiUu djrh gS (B) fo|qr ÅtkZ jklk;fud vfHkfØ;k mRiUu djrh gS
(C) ,suksM+ ij vip;u gksrk gS (D) dSFkksM+ ij vkWDlhdj.k gksrk gS
10. dqN v)Z lsy vfHkfØ;kvksa ds fy, E° uhps fn;s x;s gSaA
Sn+4 + 2e–  Sn2+ ; E° = 0.151 V
2Hg2+ + 2e–  Hg2+2 ; E° = 0.92 V
PbO2 + 4H+ + 2e–  Pb2+ + 2H2O ; E° = 1.45 V
fn;s x;s vkdMksa ds vk/kkj ij dkSulk dFku lgh gSA
(A) Sn4+ , Pb+4 dh rqyuk esa izcy vkWDlhdkjd gSA (B) Sn2+ , Hg22+ dh rqyuk esa izcy vipk;d gSA
(C) Hg2+ , Pb4+ dh rqyuk esa izcy vkWDlhdkjd gSA (D) Pb+2 , Sn2+ dh rqyuk esa izcy vipk;d gSA
Cr2O72 Fe3 
11. bysDVªkWM A o B ls cus ,d lSy ds fy,] bysDVªkWM+ A : , Eºyky = + 1.33 V o bysDVªkWM+ B : ,
Cr 3 Fe2
Eºyky = 0.77 V gSA fuEu esa ls dkSulk okD; lgh ugh gS&
(A) tc la;ksftr fd;k tkrk gS] rks bysDVªkWu B ls A dh vksj ¼ckà; ifjiFk esa½ izokfgr gkssaxs A
(B) lsy dk ekud emf 0.56 V gksaxk A
(C) A /kukRed bysDVªkWM gksxkA
(D) buesa ls dksbZ ughaA
12. ekud vip;u foHko ds fy, dkSulk dFku lgh gS&

(A) EH / H = fdlh Hkh rki ij 'kwU;

2

(B) E D / D2
= 'kwU; (298 K rki ij)
(C) ,d jsMkDl vfHkfØ;k gksrh gS ;fn vkWDlhdkjd ds SRP rFkk vipk;d ds SRP dk ;ksx ,d /kukRed ek=kk gS
(D) K2Cr2O7 (vEy)( KMnO4 (vEy) dh rqyuk esa izcyre vkWDlhdkjd gSA

[fn;k gS : EMnO /Mn2
= 1.51 V; E 2 –  = 1.33 V]
–
4 Cr O 2 7 / Cr 3
13. leku rki ij Na2SO4 dk 0.004 M foy;u Xywdksl ds 0.010 M foy;u ds lkFk leijkljh gSA Na2SO4 dk
fdruk izfr'kr Hkkx fo;ksftr gksxk \
(A) 25% (B) 50% (C) 75% (D) 85%
14. KN3 ds 0.01 M foy;u esa eqDr HN3 dh lkUnzrk D;k gS ;fn Ka = 1.9 × 10–5 gSa %
(A) 2.3 mol/ML (B) 3.3 mol/ML (C) 4.3 mol/ML (D) 5.3 mol/ML
15. 0.01 eksyj MkbZDyksjksVsVªk,DokØksfe;e (III) DyksjkbM ds 100 mL foy;u esa AgNO3 dh vf/kdre ek=kk feykbZ xbZ gSA
AgCl ds vo{ksfir gksus okys eksyksa dh la[;k gksxh %
(A) 0.002 (B) 0.003 (C) 0.01 (D) 0.001
16. 1 kg nzO;eku dh ,d xsan] ftldh xfrt ÅtkZ 0.5 J gS] ds lkFk la;ksftr Mh czkWXyh rjax&nS/;Z fuEu gS %
(A) 6.626  10–34 m (B) 13.20  10–34m (C) 10.38  10–21 m (D) 6.626  10–34 Å
17. n`'; {ks=k esa vo'kksf"kr rjax}S/;Z ds fy, lgh Øe fuEu gS %
(A) [Ni(NO2)6]4– < [Ni(NH3)6]2+ < [Ni(H2O)6]2+ (B) [Ni(NO2)6]4– < [Ni(H2O)6]2+ < [Ni(NH3)6]2+
(C) [Ni(H2O)6]2+ < [Ni(NH3)6]2+ < [Ni(NO2)6]4+ (D) [Ni(NH3)6]2+ < [Ni(H2O)6]2+ < [Ni(NO2)6]4–
vuqPNsn #
fuEu vuqPNsn dks i<+dj rFkk iz'u 18 ls 20 rd ds mÙkj nhft,A ;g dsoy ,d lgh fodYi j[krs gSA
fofHkUu fudk;ksa ds eku vip;u foHko (SRP) dks ,d vfHkfØ;k dh Lorrk dks fu/kkZfjr djus esa iz;qDr fd;k tk
ldrk gS mnkgj.k ds fy, EZn 2 Zn = – 0.76V vr% Zn + 2H+  Zn2+ + H2 vfHkfØ;k ds fy, G° _.kkRed gS]
;g iz;ksfxd :i ls ik;k x;k gS fd tc (,d vkWDlhdkjd dk SRP– ,d vipk;d dk SRP) 1.7 V ls vf/kd gS]
rc ;g la;kstu foLQksfVr gks ldrs gSA ¼gkyk¡fd bls xfrdh dkjdks }kjk jksdk tk ldrk gS½
fuEu vk¡dM+kas ds vk/kkj ij iz'uksa ds mÙkj nhft,A
PAGE NO.-42

vk¡dM+s : EAg /Ag = 0.80 V ; EN
2 /N3 ¯
= – 3.09 V
E = 1.23 V ; 
ENa  = – 2.71 V
ClO4¯ / ClO3 /Na

EFe3
/ Fe2
= 0.77 V ; EO2 / H2O2 = – 1.03 V
 
EH = 1.76 V ; EO 3 / O2
= 2.07 V
2O2 / H2O

EMnO /Mn2
= 1.54 V ; E  = 1.33 V
–
4 Cr2O72 –
/ Cr 3
18. fuEu esa ls dkSulk vk;fud la;kstu foLQksVd inkFkZ ds fuekZ.k esa iz;qDr gksrs gS \
(A) lksfM;e vk;u rFkk ,tkbM vk;u (B) flYoj vk;u rFkk ijDyksjsV vk;u
(C) flYoj vk;u rFkk ,tkbM vk;u (D) mijksDr lHkh
19. H2O2 ds mRizsjdh; fo?kVu ds fy, fuEu esa ls dkSulk vk;u mi;qDr gksxk \
(A) Fe3+ (B) Fe2+ (C) nksuksa (D) buesa ls dksbZ ugha
20. H2O2 rFkk O3 ds e/; vfHkfØ;k ds fy, dkSulk lgh gS

(A) ;g ikjLifjd vip;u dh fLFkfr gS
(B) O3; H2O2 dks O2 esa vkWDlhd`r djrh gS
(C) ;g jsMkWDl vfHkfØ;k ugha gS
(D) pwafd H2O2 ,d izcy vkWDlhdkjd gS] vr% ;g vkstksu dks vkWDlhtu esa fo?kfVr djrk gSA
21. js[kkafdr Lih'kht NOHSO4 dk ca/k Øe gSA

22. fuEu ladqyksa esa ls lokZf/kd LFkk;h ladqy dh igpku dhft,A (vius mÙkj dks 1 vFkok 2 vFkok 3 ds :i esa fyf[k,)
1. [Fe(NH3)6]3+ , 2. [Fe(en)3]3+ , 3. [Fe(dien)2]2+
23. ;fn He+ vk;u dh pth d{kk esa bySDVªkWu dh rjax nS/;Z 11.66 Å gS] rc p dk eku Kkr dhft,A ¼fn;k gS % H-ijek.kq
dh izFke d{kk dh f=kT;k 0.53 Å gSA)
a b c d
24.  8  6  2  1  dk eku Kkr dhft;s] tgk¡ a = BCC lajpuk esa leUo; la[;k; b = ljy ?kuh; lajpuk esa leUo;
 
la[;k; c = BCC bdkbZ dksf"Bdk esa d.kksa dh izHkkoh la[;k d = ljy ?kuh; bdkbZ dksf"Bdk esa d.kksa dh izHkkoh la[;kA
25. ,d oS|qr ysEi esa Hkjs x;s ,d xSl dk ?kuRo 0.75 kg/m3 gSA tc ysEi dks tyk;k tkrk gS] rks blds nkc esa 4 Pa ls
25 Pa rd o`f) gks tkrh gS, rks urms (m/sec esa) esa o`f) D;k gS \

Total Marks: 71 Max. Time : 42 min.
1. okLrfod xSl ds fy, voLFkk lehdj.k nh x;h gS tgk¡ A rFkk B fu;rkad gSA P : nkc rFkk V : eksyj vk;ru
A 2B 1
PV = RT –  Økafrd fcUnq ij Kkr dhft,A
V V2 Z
(A) 3 (B) 2 (C) 1 (D) buesa ls dksbZ ugha
2. tc ft;ksykbV] tks fd lksfM;e ,Y;qfefu;e lhfydsV gS dks dBksj ty ds lkFk mipkfjr djrs gS rc lksfM;e
vk;uks dk fofue; dkSuls vk;uks ls gksrk gSA
(A) H+ vk;u (B) Ca2+ vk;u (C) SO42– vk;u (D) Mg2+ vk;u
PAGE NO.-43
3. Na dk nzo veksfu;k esa vR;Ur 'kq) ruq foy;u %
(A) uhyk jax n'kkZrk gSA (B) oS|qr pkydrk iznf'kZr djrk gSA
(C) lksfM;e ,ekbM cukrk gSA (D) gkbMªkstu xSl mRiUu djrk gSA
4. dqN v)Z lsy vfHkfØ;kvksa ds ekud vip;u foHko uhps fn, gSa &
PbO2 + 4H+ + 2e– Pb2+ + 2H2O Eº = 1.455 V
MnO4– + 8H+ + 5e– Mn2+ + 4H2O Eº = 1.51 V
Ce4+ + e– Ce3+ Eº = 1.61 V
+
H2O2 + 2H + 2e– 2H2O Eº = 1.71 V
lgh dFku dks pqfu;s &
(A) Ce+4, Pb2+ dks PbO2 esa vkWDlhd`r djsxk (B) MnO-4 , Pb2+ dks PbO2 esa vkWDlhd`r djsxk
(C) H2O2, Mn+2 dks MnO-4 esa vkWDlhd`r djsxk (D) PbO2, Mn+2 dks MnO- esa vkWDlhd`r djsxk
4
5. fuEu esa ls dkSuls dkjd oS|qr la;kstdrk dk leFkZu ugha djrs gSa \
(A) vk;u ij fuEu vkos'k (B) vk;u ij mPp vkos'k
(C) cM+k /kuk;u rFkk NksVk _.kk;u (D) NksVk /kuk;u rFkk cM+k _.kk;u
6. ,d gkbMªkstu leku Lih'kht esa izFke cksj d{kk ls f}rh; d{kk esa mRrstu ds fy, 40.8 eV dh ÅtkZ vko';d gSA
rc fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A) H- leku Lih'kht dk ijek.kq Øekad 2 gSA (B) H-leku Lih'kht dh vk;uu ÅtkZ 122.4 eV gSA
st
(C) 1 d{kk esa bysDVªkWu dh xfrt ÅtkZ 54.4 eV gSA (D) f}rh; d{kk dh ÅtkZ –13.6 eV gSA
10 m
7. xSl (P) rFkk (Q) Øe'k% gks ldrh gS&
(ijek.oh; nzO;eku% N = 14, B = 10.7, H = 1, O = 16,
Br = 80, As = 75) xSl (P) xSl (Q)
(A) H2, N2 (B) B2H6, NH3 M n`'; oy; dk izFke
(C) B2H6, AsH3 (D) NH3, HBr ¼e/; fcUnq½ izdVhdj.k(appearance)
8. lgh dFku@dFkuksa dks pqfu;s &

(A) s-p feJ.k dh vuqifLFkfr esa B2 v.kq izfrpqEcdh; gksrk gSA
(B) F2 dk jax HOMO – LUMO laØe.k ds dkj.k gksrk gSA
(C) O2 dk ca/k Øe O2+ ls vf/kd gksrk gSA
(D) fuEu vk;uksa@v.kq ds LFkkf;Ro dk Øe Li 2  Li 2  Li 2 gSA
9. ,d Li"V% fØLVyh; Bksl ds fy, (CP)m = aT3 gS tgk¡ a ] ,d fu;rkad gS ;fn 10K ij] (CP)m dk eku 0.375 J/K-
mol gS rc] 20K ij eksyj ,UVªksih dk eku (J/K-mol esa) Kkr dhft;sA
10. ,d nqcZy vEy HA ds 0.1 M foy;u dks 0.05 N NaOH foy;u ds fo:) vuqekfir fd;k tkrk gSA vEy ds 1/4th
rFkk 3/4th Lrj ij mnklhuhdj.k ds fy, pH dh x.kuk dhft,A fn;k gS fd 0.1 M HA foy;u dh pH 3 gSA
pH1  pH2
viuk mÙkj ds :i esa nsaA
2
11. vko`fÙk esa n'kkZ;s vuqlkj Nk;kafdr ryksa dh vksj fcc tkyd Hkkx dk voyksdu
dhft;sA vkÑfr esa bl izdkj dk ry n'kkZ;k x;k gSA ry DBF esa ijek.kqvksa dh
la[;k nhft;s tks /kkfRod fcc tkyd ds fcUnq ij ,d ijek.kq ds lkFk uhps lEidZ esa
j[ks x;s gSaA
PAGE NO.-44
12. x.kuk dhft;ss (a) ,d ,dy{kkjh; vEy ds fy, Ka dk eku] ftlds 0.10 M foy;u dh pH 4.5 gSA
(b) ,d ,dyvEyh; {kkj ds fy, Kb dk eku] ftlds 0.10 M foy;u dh pH 9.7 gSA
viuk mÙkj 2Kb / Ka ds :i esa nhft;sA
13. feyku dhft,A
dkWye-I dkWye-II
(A) 74% ladqy {kerk ¼izfr'kr ?kuRo½ (p) ¶yksjkbV lajpuk esa /kuk;u dh leUo; la[;k
(B) leUo; la[;k-8 (q) ?kuh; fufcM ladqyu
(C) CaF2 esa Ca2+ vk;u (r) "kV~dks.kh; fufcM ladqyu
(D) leUo; la[;k – 12 (s) dk; dsUnzh; ?kuh; ladqyu
Daily Self-Study Dosage for mastering Chemistry Topic: lhlk
lapk;d lSy (lhlk&vEy cSVjh)
dkjksa esa iz;qDr lhlk lapk;d cSVjh dks loZizFke xSLVu IykUV }kjk foKku dh ÝSap vdsMeh }kjk 1860 esa iznf'kZr fd;k x;kA
blesa ukS lSy lekukUrj ry esa gksrs gSa rFkk ;g vk'p;Ztud :i ls vf/kd /kkjk igqapkus esa l{ke gksrk gSA lSy dks ¶ysuy] tks
10% H2SO4 foy;u esa Mwch gqbZ gS] dh ijrksa }kjk i`Fkd ysM ;k lhlk dh IysVksa ls cuk;k x;kA vis{kkd`r :i ls fudk; vc
lhlk&vEy cSVjh dgykrk gSA
lhlk lapk;d lSy esa LikWUth ysM ls Hkjh gqbZ ysM fxzM gksrh gS] tks ,uksM ds :i esa dk;Z djrh gS rFkk ysM vkWDlkbM ls
ladqfyr ysM fxzM dSFkksM ds :i esa dk;Z djrh gSA bl izdkj ds bysDVªkWM ;qXeksa dh la[;k (lkekU;r% N%) dks lY¶;wfjd vEy
foy;u (20%) esa Mwcksrs gSa] tks fo|qr vi?kV~; ds leku dk;Z djrh gS rFkk ;g vfØ; o fNfnzr Hkkxks }kjk i`Fkd gksrs gSaA
tc cSVjh dks fujkosf'kr djrs gSa rks PbO2 , PbSO4 esa vipf;r gksrk gSA tc bls vkosf'kr djrs gSa rks vfHkfØ;k O;qRØe gksrh
gSA v)Z vfHkfØ;k ds fy, ekud bysDVªkWM foHko 1.682 V gSA lSy vfHkfØ;k,a fuEu izdkj gS %
,uksM ij : Pb(s) + SO42– (aq)  PbSO4(s) + 2e–
dSFkksM ij : PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–  PbSO4(s) + 2H2O(I)
lEiw.kZ vfHkfØ;k: Pb(s) + PbO2(s) + 2H2SO4 (aq)  2PbSO4(s) + 2H2O(I)
lSy vfHkfØ;k n'kkZrh gS fd fo|qr vi?kV~; H2SO4 dk vfHkfØ;k ds nkSjku miHkksx gksrk gS vr% vfHkfØ;k lEiUu gksrh gS]
H2SO4 dh lkUnzrk ?kVrh gSA H2SO4 dh lkUnzrk fuf'pr Lohd`r Lrj rd de gksrh gSA cSVjh dks fujkos'ku vfHkfØ;k ds
O;qRØe }kjk iqu% vkosf'kr djus dh vko';drk gksrh gSA blds fy, lSy foHko ls mPp ckáre foHko iz;qDr fd;k tkrk gSA
ckn esa lSy ,d oS|qr vi?kV~; lSy ds leku lapkfyr gksrk gS rFkk bysDVªkWM ij fu{ksfir PbSO4 fuEu vfHkfØ;kvksa }kjk Pb
rFkk PbO2 eas cnyrk gS :
,uksM ij : PbSO4(s) + 2H2O(I)  PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–
dSFkksM ij : PbSO4(s) + 2e–  Pb(s) + SO42–(aq)
lEiw.kZ vfHkfØ;k: 2PbSO4(s) + 2H2O(I)  Pb(s) + PbO2(s) + 4H+ (aq) + 2SO42–(aq)
lSy vfHkfØ;k,¡ n'kkZrh gS fd H2SO4 dh lkUnzrk lSy ds

iqu%vkos'ku (recharging) ds nkSjku c<rh gSA izR;sd bysDVªkWu
;qXe }kjk mRiUu foHko yxHkx 2V gksrk gS rFkk mPp foHko JS.kh
esa bysDVªkWu ;qXeksa dh la[;k dks tksM+dj izkIr gks ldrk gSA ;g
cSVfj;ka¡ jsyksa] vLirkyksa bR;kfn esa fo|qr izokg ds fy, iz;qDr
gksus ds ctk; vkWVkseksckby cSVfj;ksa ds :i esa ek=kkRed
(extensive) mi;ksx ds :i esa ik;h tkrh gSA
The Lead Storage battery
PAGE NO.-45
14.ysM vEy cSVjh ds vkos'ku ds nkSjku dSFkksM+ vfHkfØ;k esa gksrk gSA
(A) PbSO4 dk fuekZ.k (B) Pb2+ dk Pb es vip;u
(C) PbO2 dk fuekZ.k (D) ,uksM ij Pb dk fu{ksi.k
15. lhlk lapk;d lsy es

(A) ,uksM+ ij Pb, PbSO4 es vkWDlhd`r gksrk gSA
(B) dFkkSM+ ij PbO2, PbSO4 es vipf;r gksrk gSA
(C) nksuks bysDVªkWM H2SO4 ds leku tyh; foy;u es Mwcs jgrs gSA
(D) mijksDr lHkh lR; gSA
16. lhlk lapk;d cSVjh ds iqu% vkos'ku ds nkSjku ,uksM+ ij fuEUk esa ls dkSulh vfHkfØ;k gksrh gSA
(A) Pb + SO42–  PbSO4 + 2e– (B) Pb + PbO2 + H2SO4 2PbSO4 + 2H2O
(C) PbSO4 + 2e– Pb + SO42– (D) PbSO4 + 2H2O PbO2 + 4H+ + SO42– + 2e–
17. tc lhlk lapk;d lsy fujkosf'kr gksrk gS%&
(A) SO2 eqDr gksrh gSA (B) ysM curk gSA
(C) ysM lYQsV iz;qDRk gksrk gSA (D) lY¶;wfjd vEy iz;qDRk gksrk gSA

1. SiO2 rFkk MgO dh lEHkou Å"ekvksa ds eku Øe'k% –48.4 rFkk –34.7 kJ gSA 2Mg + SiO2  2MgO + Si
vfHkfØ;k dh Å"ek gksxh %
(A) 21.16 kJ (B) – 21.00 kJ (C) – 13.62 kJ (D) 13.6 kJ
2. CO2(g) + H2(g)  CO(g) + H2O(g) vfHkfØ;k esa; H = 2.8 kJ, H iznf'kZr djrk gSA
(A) vfHkfØ;k dh Å"ek (B) ngu dh Å"ek (C) lEHkou Å"ek (D) foy;u dh Å"ek
3. ,d izcy {kkj }kjk ,d izcy vEy dh mnklhuhdj.k dh Å"ek dk eku fuEu esa ls fdlds H ds cjkcj gS %
(A) H+ + OH– = H2O (B) H2O + H+ = H3O+
(C) 2H2 + O2 = 2H2O (D) CH3COOH + NaOH = CH3COONa + H2O
4. fuEu esa ls dkSulk lEcU/k lgh gSA ¼tgk¡ fn;s x;s izrhd budk lkekU; vFkZ j[krs gSa ½
 T2   T 
(A)  a  C  (B)  b  C  (C) A rFkk B nksuksa (D) buesa ls dksbZ ugha
 PC   PC 
5. fuEu dFkuksa esa ls dkSulk lgh gS ?

(a) CH2 = C = C = CH2 esa flXek ca/kksa dh la[;k 7 gSA
(b) CH2 = C = C = CH2 esa lHkh gkbMªkstu ijek.kq ,d gh ry esa gSA
(A) dsoy (a) (B) dsoy (b) (C) (a) rFkk (b) nksuksa (D) uk rks (a), uk gh (b)
6. ,d p-bysDVªkWu dk d{kd dks.kh; laosx bl izdkj fn;k tkrk gS %
h h 3h h
(A) (B) 3 (C) (D) 6.
2 2 2 2
7. fuEu esa ls fdl ifjfLFkfr esa] I dh rqyuk esa ok"i nkc vf/kd gSA (;g ekudj fd lHkh foys; vok"i'khy foys; gSaA)
I = C12H22O11 dk 0.2 m foy;u
II = 1011.6 g, 0.2 eksyy ,lhVksu o 1012 g, 0.2 eksyy ;wfj;k dk feJ.k
III = 1 Kg ty esa 0.2 mol NaOH dk foy;u
IV = 3 Kg ty esa 0.2 mol NaCl dk foy;u
(A) II (B) III (C) IV (D) dksbZ ugha
PAGE NO.-46
8. fuEu esa ls dkSu vuqpqEcdh; izÑfr dk gS \
II
(A) K 4 [F e(CN)5 (O2 )] (B) Na 4 [Fe(CN)5 (NOS)]
3
(C) [Co(H2O)6 ] (D) (A) & (C)
9. fuEu esa ls fdl vfHkfØ;k ds fy, Hº dk eku 'kwU; gS \
(A) H2(g)  2H+(g) + 2e (B) 2H(g) 2H+(g) + 2e
(C) H2(g) + aq 2H+(aq) + 2e (D) 2H(g) + aq 2H+(aq) + 2e
10. [Pt(NH3)4Cl2][PtCl4] dk lgh uke gS :
(A) VsVªk,EehuMkbDyksjkbMksIysfVue(II) VsVªkDyksjkbMksIysfVusV(IV)A
(B) MkbDyksjkbMksVsVªk,EehuIySfVue(IV) VsVªkDyksjkbMksIysfVusV(II)A
(C) VsVªk,EehuMkbDyksjkbMksIysfVue(IV) VsVªkDyksjkbMksIysfVusV(II)A
(D) VsVªkDyksjkbMksIysfVue(II) MkbDyksjkbMksVsVªk,EehuIySfVusV(IV)A
11. oS|qr jlk;fud lsy esa mifLFkr yo.k lsrq (Salt bridge) dk fuEufyf[kr esa ls dkSulk dk;Z ugha gS \
(A) foy;u dh oS|qr mnklhurk dks cuk;s j[kuk
(B) oS|qr ifjiFk (electrical circuit) dks iwjk djuk] ftlls fo|qr dk izokg gks ldsA
(C) dSFkksM o ,uksfMd d{k dh vksj vk;uksa dks izokfgr djukA
(D) lsy foHko esa o`f) djukA
12. ;fn 0.1 M AgNO3 rFkk 0.1 M NaCl ds leku vk;ru ,d lkFk fefJr fd;s tkrs gSa] rks ukbVªsV vk;uksa dh lkUnzrk
D;k gksxh:
(A) 0.1 M (B) 0.2 M (C) 0.05 M (D) 0.25 M
13. fuEu fp=k esa inkFkksZ ds fofHkUu laØe.kksa dh ,UFkSYih dks fuEukuqlkj iznf'kZr fd;k x;k gS]
fuEu esa ls fdl voLFkk esa mifLFkr gksus ij inkFkZ dh ,UFkSYih dk eku vf/kdre gksrk gSA
(A) Bksl voLFkk (B) nzo voLFkk
(C) xSl voLFkk (D) lHkh voLFkkvksa esa cjkcj
14. 75% 'kq) Xywdkst (C6H12O6) dk og nzO;eku] tks blds M/9 tyh; foy;u ds 50 mL dks cukus ds fy, vko';d
gS] fuEu gS&
4
(A) 4 g (B) 1 mg (C) 1 g g (D)
3
15. lhft;e dk ijek.kq nzO;eku 133 u gS rFkk Dyksjhu dk ijek.kq nzO;eku 35.5 u gSA 16.85 g CsCl esa mifLFkr ,dd
dksf"Bdk dh la[;k fdruh gS \
(A) 6.023 × 1022 (B) 1.204 × 1022 (C) 6.023 × 1021 (D) 1.204 × 1023
16. ljy Jà[kyk cgqyd dk fuekZ.k fuEu }kjk fd;k tkrk gS %
(A) (CH3)3 SiCl dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(B) (CH3)2 SiCl2 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(C) (CH3) SiCl3 dk ty&vi?kVu rRki'’pkr~ la?kuu cgqydhdj.k
(D) (CH3)4 Si dk ty&vi?kVu rRi’pkr~ la?kuu cgqydhdj.k
17. ekuk fd ath dks'k esa d{kdksa dh dqy la[;k 16 gS rFkk osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy, f}xa'kh
DokaVe la[;k dk eku ‘b’ gS rc (a + b) ds ;ksx dk eku Kkr dhft,A
(A) 4 (B) 5 (C) 6 (D) 3
18. P4S3 ds ,d v.kq esa mifLFkr P-P ca/kks rFkk P-S cU/kksa dh la[;k dk ;ksx Kkr dhft, \
19. [Pt(NH3)2Cl2(H2O)2]2+ ds fdrus T;kferh leko;oh lEHko gS \
20. N% dk; dsUnzh; ?kuh; bdkbZ lSyksa ls ijek.kqvksa dks ysdj Qyd dsUnzh; lajpuk cuk;h x;hA çkIr Qyd dsUnzh;
bdkbZ lSyksa dh la[;k Kkr dhft,A
PAGE NO.-47
24
21. 10 yhVj vk;ru ds ik=k esa mifLFkr ,d xSl ds 6 × 10 d.kksa ftlesa izR;sd d.k dk nzO;eku 3 × 10–22 gm gS]
}kjk yxk;s x;s nkc dh x.kuk dhft;s \ oxZ ek/; ewy osx (rms speed) 105 mm sec–1 gSA
22. 25ºC ij] fuEu lsy ds ,uksMhd Hkkx esa foy;u dh pH, x gSaA tc Elsy – Eºlsy = 0.0591 V gSA Pt(H2) (1 atm) |
pH = x | | Ni2+ (1 M) | NiA x dk eku Kkr dhft;sA
Daily Self-Study Dosage for mastering Chemistry Topic: Fuel Cell
ijaijkxr (Conventionally) ÅtkZ thok'eh; bZa/ku ds ngu }kjk izkIr gksrh gSA oS|qr ÅtkZ es :ikUrj.k vusd inks esa gksrk gS
rFkk ;gk¡ izR;sd in ij ÅtkZ dh gkfu gksrh gSA izØe dh n{krk yxHkx 40% gksrh gSA ;gk¡ bZa/ku dh jklk;fud ÅtkZ dks lh/ks
mRizsjdh; lfØ;r jsMkWDl vfHkfØ;kvksa }kjk oS|qr ÅtkZ ess :ikUrfjr djus ds fy, Hkh vusd rjhds gksrs gSA bl izdkj dh
;qfDRk;k¡ bZa/ku lSy dgykrh gSA vU; 'kCnks esa bZa/ku lsy XksYosfud lSy gksrs gS] ftuesa oS|qr ÅtkZ bZa/ku dh jsMkWDl vfHkfØ;kvksa
ls lh/ks O;qRiUu gksrh gSA
b±èku lSy dk izn'kZu gS % b±èku | bysDVªkWM | oS|qr vi?kV~; | bysDVªkWM | vkWDlhdkjh
lEiw.kZ lSy vfHkfØ;k : b±èku + vkWDlhdkjh  vkWDlhdj.k mRikn + vip;u mRikn
gkbMªkstu&vkWDlhtu bZa/ku lSy
;g bZ/kau lSy gkbMªkstu rFkk vkWDlhtu dks tksM+dj fo/kqr] Å"ek rFkk ty mRiUu djrs gSA ;g jklk;fud ÅtkZ dks fo/kqr
ÅtkZ esa cnyrs gS rFkk bl izdkj cSVjh ds rqY; gks ldrs gSA dsoy vUrj ;g gS fd vf/kd yEcs le; rd gkbMªkstu izokfgr
djus ij ;g fujUrj fujkosf'kr gq, fcuk fo/kqr mRiUu djrk gSA
fp=k % gkbMªkstu&vkWDlhtu b±èku lSy dk ,d CykWd fp=k

cukoV rFkk dkf;Zdh
lEiw.kZ O;oLFkk esa dks"B (fp=k) gksrs gSA izFke dks"B gkbMªkstu ds fy, izosf'kdk ds :i esa dke djrk gSA tcfd f}fr;
vkWDlhtu ds fy, izosf'kdk ds :i es dke djrk gSA ;gk¡ nks dkcZu bysDVªkWM gSA gkbMªkstu dks ,uksM ij rFkk vkWDlhtu dks
dSFkksM+ ij izokfgr djrs gSA e/; esa ,d izksVksu fofu;e f>Yyh gksrh gS tks ,d nwljs ls nks bysDVªkWMks dks i`Fkd djrh gS] tgk¡
nks xSls ijLij vU;ksU; fØ;k dj ldrh gSA nks bysDVªkWMks dks i`Fkd djus okyk oS/kqr vi?kV~; ,d vk;u pkyd inkFkZ] lkfUnzr
tyh; lksfM;e gkbMªkWDlkbM ds leku gksrk gSA fuEu vfHkfØ;k;sa nks bysDVªkWMks ij gksrh gSA
,uksM+ ij : 2H2  4H+ + 4e–
dSFkksM+ ij : O2  4H+ + 4e–  2H2O
lEiw.kZ lSy vfHkfØ;k : 2H2  O2  2H2O
ty pkSFks dks"B es fu"dkflr gksrk gSA ,uksfMd vfHkfØ;k izksVkWu rFkk bysDVªkWu nsrh gSA budks i`Fkd djrs gS rFkk gkbMªkstu
vk;uks dks dSFkksM+ rd fo/kqr vi?kV~; ds }kjk xqtkjrs gS tcfd bysDVªkWu 'kfDr fo/kqr ;qfDr;ksa rd izR;{k /kkjk ds :i es
ckg~;re ifjiFk ds }kjk xfr djrs gSA dSFkksM+ esa gkbMªkstu vk;u vkWDlhtu ds lkFk tqMdj Å"ek ds lkis{k ty cukrs gS bl
izdkj ifjiFk iw.kZ gksrk gSA
PAGE NO.-48
23. H2 – O2 bZ/ku lsy es] dSFkksM ij vfHkfØ;k gksrh gS%&

(A) 2H2 + O2 2H2O (l) (B) H  O H  H2O
(C) O2 + 2H2O + 4e– 4OH– (D) He– 1/2 H2
24. bZ/ku lsy dh Å"ekxfrdh; {kerk fuEu }kjk nh tkrh gSA
H nFE nFE
(A) (B) (C)  (D) nEF–
G G H
25. bZ/ku lsy dh lsy vfHkfØ;k gS %&
(A) 2H2O(l)  2H2 (g) + O2(g) (B) 2H2(g) + O2(g)  2H2O(l)
(C) CH4(g) + O2(g)  CO2(g) + H2O (l) (D) C(s) + O2(g) CO2(g)

1. 0.4 M BaCl2 foy;u esa Al2(SO4)3 dh Bhd i;kZIr ek=kk bl izdkj feykbZ tkrh gS rkfd BaSO4 iw.kZr% vo{ksfir gks
tkrk gS ¼foy;u dk vk;ru fLFkj j[krs gq,½ rks
(A) okLrfod foy;u dk fgekad c<rk gSA (B) okLrfod foy;u dk DoFkukad c<rk gSA
(C) okLrfod foy;u dk ok"i nkc c<rk gSA (D) foy;u ds v.kqla[;d xq.k/kek±s es dksbZ ifjorZu ugh gksrk gSA
2. fuEu esa ls lgh dFku dkSulk gS \

(A) okUMjokWYl~ fu;rkad ‘a’ vkd"kZ.k cy dk ekiu djrk gSaA
(B) okUMjokWYl~ fu;rkad ‘b’ dks lg&vk;ru vFkok vlfEefyr vk;ru ¼fudkyk x;k vk;ru½ Hkh dgrs gSaA
(C) ‘b’ dks L mol–1 esa O;Dr djrs gSa
(D) ‘a’ dks atm L2 mol–2 esa O;Dr djrs gaSA
3. Lih'kht ds fn;s x;s ;qXeks esa ls prq"Qydh; rFkk vuqpqEcdh; bdkbZ gS@gSa&
(A) [MnO4]2–,[NiCl4]2– (B) [MnBr4]2–, [CoCl4]2–
(C) [CrO2F2], [Cr2O7]2– (D) [Ni(CO)4], [Ni(dmg)2]
4. vf/kdrj vk;fud ;kSfxd dk gksrk gS %
(A) mPp xyukad rFkk fuEu DoFkukad
(B) mPp xyukad rFkk vfn'kkRed cU/k
(C) /kzqoh; foyk;d esa mPp foys;rk rFkk v/kqoh; foyk;d esa fuEu foys;rk
(D) f=kfofe; fØLVyh; lajpuk rFkk xfyr voLFkk esa oS|qr dk vPNk pkyd gSA
5. gkbMªkstu ijek.kq ds 1s d{kd ds fy, f=kT;h; rjax Qyu fuEu izdkj n'kkZ;k tkrk gS &
3/2
1  1  –r / ao
R(r) =   e (tgk¡ ao = 0.529 Å)
  ao 
r = ao ij bysDVªkWu ds ik;s tkus dk f=kT;h; izkf;drk ?kuRo rFkk ukfHkd ij bysDVªkWu ds ik;s tkus ds f=kT;h;
izkf;drk ?kuRo dk vuqikr (xe–y) ds :i es n'kkZ;k tkrk gSA
(x + y)3 dk eku ifjdfyr dhft,A
6. 300 K rFkk 20 atm ij ,d xSl dk lEihM~;rk dkjd 0.8 gSA bu ifjfLFkfr;ksa esa] xSl ds 8 mmol }kjk ?ksjs x;s
vk;ru dh x.kuk dhft,A (yhft, R = 1/12 L atm K–1 mol–1)
7. oS|qr :i ls fu{ksfir flYoj dh eksVkbZ Kkr dhft, ;fn i`"B lrg {ks=kQy] ftl ij fu{ksi.k gqvk gS] 100 cm2 ik;k
x;k gS rFkk 0.2 A dh fo|qr /kkjk 1 ?k.Vs ds fy, izokfgr dh tkrh gS o dSFkksM dh n{krk 80% gSA
Ag dk ?kuRo = 10 g/cc (Ag = 108).
PAGE NO.-49
8. fn;s x;s js[kkfp=k esa oS|qr vi?kV~; lsy ,d tyh; 1 M dkWij (II) lYQsV foy;u dk 1
yhVj j[krk gSaA ;fn lsy ds }kjk bysDVªkWu ds 0.4 eksy izokfgr fd;s x;s rks vkos'k ds
izokfgr gksus ds ckn dkWij vk;u dh eksyj lkUnzrk D;k gksxhA
9. ,d dkcZfud ;kSfxd dk 4×10–2 M tyh; foy;u] 1.5 ×10–2 M NaCl (iw.kZ vk;uu) ds tyh; foy;u ls lEkijkljh
gSA ;fn ;kSfxd f}ydhd`r gksrk gS vkSj mldh dksfV  gS rFkk okUV gkWQ dkjd i gSaA (8i + 2 ) dk eku Kkr djsaA
iSysfM;e iUuh 76 cm Hg
10. foHkktu dks gVkus ds i'pkr~ nksuksa Hkq tkvksa ij Hg Lrj (cm esa) esa
D;k vUrj gksxk \ 76 cm Hg
uksV : dsoy gkbMªkstu iSysfM;e iUuh ls xqtj ldrh gSA
(esuksehVj dk vk;ru ux.; ekfu,];g i;kZIr yEch gS rFkk dksbZ foHkktu
vfHkfØ;k ugha gksrh gSA ½
76 cm Hg
11. fuEu ;kSfxdksa esa ls ,sls ;kSfxdksa dh dqy la[;k Kkr dhft,] tgk¡ d x2  y2 d{kd ladj.k esa Hkkx ugha ysxkA
(1) [Pt(NH3)Cl (H2O)Br] (2) SF4 (3) [Cu(NH3)4]2+ (4) XeO3F2
(5) XeO2F2 (6) [Co(en)3]3+ (7) [Ni(CO)4] (8) POCl3
(9) PCl5 (10) XeO64–
12. nks chdj A rFkk B esa fp=k esa n'kkZ, vuqlkj Øe'k% 0.1 M rFkk 0.01 M lkanzrk ds AgNO3 foy;u mifLFkr gSA
izR;sd chdj esa vc 'kq) flYoj bysDVªkWM dks j[kk tkrk gSA vc NH3 dks chdj A vkSj B esa NH3 dh lkUnzrk Øe'k%
0.1 M rFkk 0.2 M gksus rd izR;sd chdj esa feyk;k tkrk gSA ;fn vc nksuksa chdj xSYosfud lSy O;oLFkk esa tksM+s tkrs
gSa] rks 298 K ij ifj.kkeh lSy dk EMF (feyhoksYV es) Kkr dhft,A viuk mÙkj 16 ls Hkkx yxkus ds i'pkr~
RT
nhft,A [iz;ksx djs log10 2 = 0.3, 298 K ij (2.303) = 0.06 V] fn;k gS : E ºAg / Ag = 0.8 Volt
F
Ag Ag
AgNO3 0.1M 0.01M AgNO3

chdj (A) chdj (B)
13. dkWye-I dh iztkrh;ksa ;k v.kqvksa dks dkWye-II esa mifLFkr buds xq.kksa ds lkFk lqesfyr dhft;sA
dkWye-I dkWye-II
 –
(A) CIF5 , BrF 4 , IF 6 (p) lHkh v.kq@vk;u izd`fr esa /kzqfo; gSA
 –
(B) CIF3, BrF 2 , ICI 4 (q) lHkh v.kq @vk;u esa leku la[;k esa ,dkdh bysDVªkWu ;qXe rFkk leku vkd`fr gSA
– –
(C) XeF2, ICI 2 , I 3 (r) lHkh v.kq@vk;u esa dsUnzh; ijek.kq dh leku vkWDlhdj.k voLFkk gSA
 –
(D) CIOF3, CIF 4 , IO2F 2 (s) lHkh v.kq@vk;u esa dsUnzh; ijek.kq dk leku ladj.k gSA
PAGE NO.-50
Daily Self-Study Dosage for mastering Chemistry Topic: la{kkj.k
vk/kqfud vkS|ksfxd leqnk;ksa esa ,d eq[; leL;k la{kkj.k (Corrosion) gSA ;g crkrk gS fd okf"kZd mRiUu yxHkx 30-40%
vk;ju rFkk LVhy tax yxs vk;ju inkFkksZ dks gVkus ds fy, iz;qDr gksrs gSaA la{kkj.k ?kj ds vUnj rFkk ckgj lHkh midj.kksa eas]
lM+dksa ij] leqnzksa ij] ikniksa esa rFkk ok;oh; ifg;ksa esa iz;qDr gksrk gSA la{kkj.k] /kkrq vFkok blds ok;qe.My ds lkFk feJ /kkrq
dh ,d Lor% eUn jklk;fud vU;ksU; fØ;k gS] blds ifj.kkeLo:i vkWDlkbM] ty;ksftr vkWDlkbM] dkcksZusV] lYQkbM] lYQsV
bR;kfn ds leku blds ,d ;kSfxd dk fuekZ.k gksrk gSA
la{kkj.k dks buds ok;qe.My ds lkFk jklk;fud vU;ksU; fØ;k }kjk inkFkksZ ds voufr (deterioration) ds :i esa ifjHkkf"kr dj
ldrs gSaA inkFkksZa dk la{kkj.k ok;qe.My }kjk /kkrq ij fo|qr jklk;fud okrkoj.k }kjk vFkok izR;{k jklk;fud vkØe.k }kjk
izkIr gksrk gSA la{kkj.k dk lokZf/kd ikfjokfjd mnkgj.k ok;qe.Myh; ifjfLFkfr;ksa eas [kqyk NksM+us ij vk;ju dk tax yxuk gSA
2Fe(s) + 3/2 O2 (g) + xH2O(I)  Fe2O3· xH2O(s)
(tax dk jklk;fud laxBu)
vk;ju dk tax yxuk ,d tfVy jklk;fud vfHkfØ;k gS ftlesa vkWDlhtu rFkk ueh (fp=k ns[ksa) nksuksa gksrs gSaA vk;ju ij 'kq)
ty esa tax ugha yxrk gS D;ksafd ;g vkWDlhtu eq Dr gksrk gS rFkk bl ij ueh dh vuqifLFkfr eas 'kq) vkWDlhtu esa tax ugha
yxrk gSA ;g crkrk gS fd laa{kkj.k izØe ,d oS|qr jklk;fud izd`fr dk gksrk gSA /kkrq dh ,d lrg ij vk;ju ty dh
mifLFkfr eas vkWDlhd`r gksrk gS rFkk Fe2+ ds :i esa foy;u esa izos'k djrk gS rFkk ;g /kkrq lrg dh ,uksfMd fLFkfr gSA ,uksM
ij gksus okyh vfHkfØ;k gS&
fp=k % ykSgs dk la{kkj.k

Fe(s)  Fe (aq) + 2e
2+ –
bysDVªkWu tks fu"dkflr gksrs gS] tc vk;ju vkWDlhd`r gksrk gS] rc ;g bysDVªkWu dqN ,sls vU; LFkku ij /kkrq ds }kjk xfr'khy
gksrs gSa] tgk¡ vk;ju dks vkWDlhtu esa [kqyk NksMrs gSaA ;g /kkrq lrg dk dSFkksfMd {ks=k gS] tgk¡ vip;u gksrk gS ,oa vkWDlhtu
vipf;r gksdj gkbMªkWDlkbM vk;u nsrh gSA dSFkksM ij gksus okyh vfHkfØ;k gS %
1/2O2(aq) + H2O(I) + 2e– 2OH– (aq)
vk;ju (II) vk;u rc curs gSa tc ;g ,uksfMd {ks=k ij ty ds }kjk /khjs&/khjs folfjr gksrs gS rFkk vUr esa gkbMªkWDlkbM vk;uksa
ds lEidZ eas vkrs gSaA blds dkj.k Fe(OH)2 dk vo{ksi curk gS] tks vf/kd vklkuh ls O2 }kjk vkWDlhd`r gksdj Fe(OH)3
nsrk gSA ;g gkbMªkWDlkbM rsth ls ty fu"dkflr djrk gSA okLro esa iw.kZ futZyhdj.k vkWDlkbM nsrk gSA
2Fe(OH)3 Fe2O3 + 3H2O
tc Fe(OH)3 dk vkaf'kd futZyhdj.k izkIr gksrk gS rks tax curk gSA ;g ,slk laxBu curk gS ftleas gkbMªkWDlkbM rFkk
vkWDlkbM] Fe2O3 ds e/; ;g izkIr gksrk gS rFkk ;g izk;% ty;ksftr vkWDlkbM ds :i eas gksrk gS] blds lw=k dks lkekU;r%
Fe2O3· xH2O ds :i eas iznf'kZr djrs gSaA
PAGE NO.-51
14. ykSgs ij tax yxuk ,d gS%&
(A) fo?kVu (decompostion) izØe (B) izdk'kjklk;fud izØe
(C) fo|qr jklk;fud izØe (D) vip;u izØe
15. ykSgs ij tax yxus es fuEUk es ls dkSulh lsy vfHkfØ;k dSFkksM ij gksrh gS \
(A) Fe2+ | Fe (B) O2 | H2O (C) Fe3+ | F2+ (D) Fe | Fe3+
16. fuEu es ls dkSulk dFku ykSgs ij tax yxus ds lUnHkZ es lgh gS@gSa \
(A) ;g ue ok;q es gksrk gSA (B) ;g CO2 ds okrkoj.k es cUn gks tkrk gSA
(C) ;g Fe (III) vkWDlkbM cukrk gSA (D) ;g ,d fo|qrjlk;fud izØe gSA
17. fuEUk es ls fdlesa ykSgs dk la{kkj.k vf/kd rsth ls gksxk \

(A) 'kq) ty esa (B) 'kq) vkWDlhtu esa
(C) ok;q o ueh esa (D) ok;q o yo.kh; ty esa
18. ykSgs ij tax yxuk fuEu izdkj ls gksrk gS%&

2H + 2e– + 1/2 O2  H2O(l) ; E– = +1.23 V
Fe2+ + 2e–  Fe(s) ; E– = –0.44 V
lEiw.kZ izØe ds fy, G– dh x.kuk dhft,
(A) –322 kJ mol–1 (B) –161 kJ mol–1 (C) –152 kJ mol–1 (D) –76 kJ mol–1
PAGE NO.-52

Numerical Value Questions ('0' negative marking) Q.21 to Q.25 (4 marks, 3 min.) [20, 15]
1. T;kferh; leko;oh;ksa esa vUrj gksrk gS %
(A) v.kqlw=k (B) lajpukRed lw=k (C) f=kfoejlk;u lw=k (D) ewykuqikrh lw=k
2. fuEu esa ls dkSulk ;kSfxd T;kferh; leko;ork n'kkZrk gS %

(A) CH2 = CH2 (B) CH3–CH=CH2 (C) CH3–CC–CH3 (D) CH3–CH=CH–CH3
3. fuEu esa ls fdlesa T;kferh; leko;ork lEHko ugha gS %
CH 3 CH3 CH3 CH3 CH3
CH3
(A) (B) (C) (D)
CH3
CH3
4. fuEu esa ls dkSulk lei{k&foi{k leko;ork n'kkZrk gS %

H
(A) H–CC–H (B) ClCH=CHCl (C) CH3–C–COOH (D) Cl–CH2–CH2–Cl
H
5. fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr djrk gS\
(A) C;wV-1-bZu (B) vkblksC;wVhu (C) C;wV-1-vkbZu (D) isUV-2-bZu
6. fuEu esa ls fdl ;kSfxd esa T;kferh; leko;ork lEHko ugha gS %

12
CH3 H CH3 H
(A) 14
(B) (C) CH3–CH=NH (D)
CH3 Cl Cl D
7. fuEu esa ls dkSu lei{k&foi{k leko;ork n'kkZrk gS \
(A) (B) (C) (D)
8. fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr ugha djrk gS \

(A) 1-QsfuyC;wV-1-bZu (B) gsDl-2-bZu (C) 1-Dyksjks,sFkhu (D) 1-Dyksjksizksihu
9. fuEu esa ls dkSulk ;kSfxd T;kferh; leko;ork çnf'’kZr djrk gS\

(A) 2-esfFkyC;wV-2-bZu (B) 2, 3-MkbZesfFkyC;wV-1-bZu
(C) 2,3-MkbZesfFkyC;wV-2-bZu (D) 1,2-MkbZesfFkylkbDyksC;wVsu
10. fuEu esa ls dkSulk T;kferh; leko;ork n'kkZrk gS %
(A) (B) (C) (D)
11. fuEu esa dkSulk Z vfHkfoU;kl j[krk gSA

H CH3 CH3 H F CH2Cl
H
(A) N N (B) D N (C) (D)
H H CH3 ClCH2 CHF2
12. fuEu v.kqvksa esa lgh lEcU/k gksxkA
(A) fLFkfr leko;oh (B) Jà[kyk leko;oh (C) letkr (D) T;kferh; leko;oh
PAGE NO.-53
13. fuEu esa ls fdl ;kSfxd esa izR;sd f}ca/k ij lei{k foU;kl gS \
(A) (B)
(C) (D)
14. fuEu ;kSfxd dk lgh IUPAC uke gSa&
(A) (1Z, 2Z, 3E) gsIVk-1,3,5-VªkbbZu (B) (2E, 4Z, 6Z) gsIVk-2,4,6-VªkbbZu
(C) (3Z, 5E) gsIVk-1,3,5-VªkbbZu (D) (2E, 4Z) gsIVk-2,4,6-VªkbbZu
15. fuEu esa ls dkSulk T;kferh; leko;oh j[krk gS %
(A) (B) (C) (D) mijksDr lHkh
16. fuEu esa E-leko;oh dk p;u dhft,%
(A) (B)
(C) (D)
17. fuEu esa ls Z-leko;oh gksxk %
(A) (B)
(C) (D)
18. lei{k-2-C;qVhu rFkk foi{k-2-C;qVhu esa dkSulk y{k.k leku gS%

(A) foys;rk (B) çfrcaf/kr ?kw.kZu (C) LFkkf;Ro (D) xyukad rFkk DoFkukad
19. fLVychu (PhCH=CHPh) nks foofje leko;oh :i (X) vkSj (Y) esa jgrk gS vkSj ik;k x;k fd (X), (Y) ls vfèkd
ty esa foys; gS rks fuEu esa ls lgh dFku gSA
(A) X foi{k leko;oh gS (B) X dk LFkkf;Ro > Y dk LFkkf;Ro
(C) X dk xyukad < Y dk xyukad (D) X dk DoFkukad < Y dk DoFkukad
20. bZuksu (X = C5H8O) tks T;kferh; leko;ork iznf'kZr djrk gS@gSa :

H
I. II. III. IV.
O O O
(A) I rFkk IV (B) II rFkk IV (C) III rFkk IV (D) dsoy II
21. C3H5Cl ds fdrus lajpukRed leko;oh T;kferh; leko;ork n'kkZ;sxsa\
22. tc lkbDyksizksisuksu rFkk 2-C;wVsuksu NH2OH ds vkf/kD; ds lkFk vfHkfØ;k djrs gSa] rks fdrus vkWfDle izkIr gksrs gS %
PAGE NO.-54
23. fuEu esa ls dkSu T;kferh; leko;ork iznf'kZr ugha djrk gS \
(i) (ii) (iii) (iv)
H CH3
(v) CH3 (vi) (vii) (viii)
HO CH3
(ix) (x) (xi) (xii)
24. uhps fn;s x;s ;kSfxd esa fdrus f=kfoedsUnz ¼T;kferh; dsUæ½ mifLFkr gS \

CH2=CH–CH=CH–CH= N H
25. Msdhu ds fdrus fLFkfr leko;oh T;kferh; leko;ork n'kkZ ldrs gS \

1. fuEu esa ls dkSuls fodYi esa lHkh ;kSfxd T;kferh; leko;ork iznf'kZr djrs gSA
Cl
(A) , (B) , C2FClBrI
Br
(C) , Ph2N2 (D) CH3–CH=N–OH, H2C=CH–CH=CH–CN
2. fuEu esa ls dkSu T;kferh; leko;ork ugha n'kkZrk gS\
(A) (B) (C) (D)
3. ;kSfxdksa ds fuEu esa ls dkSuls ;qXe esa lgh ladsr fn;k x;k gS \
(A) (B)
,UVh ,tkscsUthu flu ,tkscsUthu flu ,lhVsYMksfDte ,UVh ,lhVsYMksfDte
(C) (D)
foi{k-o-,ehuksflusfed vEy lei{k-o-,ehuksflusfed vEy Z-leko;oh E-leko;oh
PAGE NO.-55
4. fuEu esa ls dkSuls ;kSfxd dk Z foU;kl gksxk?
(A) (B)
(C) (D)
5. fuEu ;kSfxdksa ds ;qXeksa ds fy, iznf'kZr xq.k/keZ esa dkSulk Øe xyr gSA
(A) < ¼LFkkf;Ro½
¼foi{k½ ¼lei{k½
(B) < ¼LFkkf;Ro½
(C) > ¼DoFkukad½
(D) > ¼f}/kqzo vk?kw.kZ½ ()
vuqNsn # 1
fuEu ;kSfxd dk izs{k.k dhft,A
CH3–CH=CH
6. blds T;kfefr leko;oh;ksa dh dqy la[;k gksxh \

(A) 2 (B) 4 (C) 8 (D) 16
7. dqy fdrus cgqcU/k ¼Qsfuy leqg dh x.kuk djrs gq,½ T;kferh; leko;ork dks iznf'kZr djsaxsaA
(A) 3 (B) 2 (C) 1 (D) 4
vuqNsn # 2
dkcksZfuy ;kSfxd] tks ,YQk gkbMªkstu ije.kq j[krs gS( tyh; foy;u es j[kus ij pyko;ork n'kkZrs gSA
OH–/H2O
CH3–CH2–CHO CH3–CH=CH–OH
mRikn bZukWy T;kfefr; leko;ork n'kkZ ldrs gSaA
CH3 OH CH3 H
C=C C=C
H H OH
H
(lei{k) (foi{k)
8. fuEu es ls dkSulk ;kSfxd tyh; foy;u es nks bZukWy nsxk\

(A) CH3–CHO (B) Ph–C–CH2–CH3 (C) CH3–C–CH3 (D) CH3–CH–CHO
O O CH3
PAGE NO.-56
9. dqy fdrus bZukWfyd :i ¼f=kfoe leko;oh lfgr½ C;wVsukWu ds fy, lEHko gSa \
(A) 1 (B) 2 (C) 3 (D) 4
10. fuEu esa ls fdrus v.kq ;k ;kSfxdksa es T;kferh; leko;ork lEHko gS \
Cl
NH Br
(1) (2) (3) (4)
NH
Me
NH

(5) (6) (7) (8) MeS
NH
(9) (10)
11. VsVªkDyksjks lkbDyks C;wVsu ds dqy fdrus fLFkfr leko;oh T;kferh; leko;ork n'kkZrs gSA
O3/Zn NH2–OH
12. isUVk-1,3-MkbbZu dkcksZfuy ;kSfxdks dh vkWfDleks dh
dqy la[;k vkf/kD; dqy la[;k
[X] [Y]
viuk mÙkj X Y ds :i es nhft,&
13. dkWye-I dks dkWye-II ls lqesfyr dhft, %
dkWye I dkWye II
(A) T;kferh; leko;ork (p)

Cl
(B) Z-leko;oh (q)
Cl
(C) lei{k&leko;oh (r)
CH3
CH3
(D) E-leko;oh (s)
H Br

1. fuEu esa ls dkSulk ;kSfxd f=kfoe leko;ork n'kkZrk gS ?

(A) 1-Qsfuy,Fksusehu (B) Qsfuy Dyksjks,FksukW,V
(C) 3-Dyksjks-3-,FkkbfuyisUVk-1,4-MkbZvkbu (D) 3-esfFkyC;wVsukWbd vEy
2. os v.kq fdjSy v.kq gksrs gS ftuesa %

(A) muds niZ.k izfrfcEc v/;kjksfir gksrs gS (B) muds niZ.k izfrfcEc v/;kjksfir ugha gksrs gSa
(C) tks niZ.k izfrfcEc ugha j[krs gSa (D) T;kfefr leko;ork n'kkZus esa l{ke gksA
3. fuEu esa ls fdlesa vlefer dkcZu ijek.kq gS \
(A) (B) (C) (D)
PAGE NO.-57
4. fuEu esa ls dkSu U;wure v.kq Hkkj ;qDr gkbMªksdkcZu tks fd fdjSy gSA
(A) 3-esfFkygsDlsu (B) 2, 4-MkbesfFkyisUVsu
(C) 2, 2-MkbesfFkyisUVsu (D) 3, 3-MkbesfFkyisUVsu
5. fuEu esa ls dkSulk v.kq 2 fdjSy dkcZu ijek.kq j[krk gS %

H H
CH3
(A) C=O (B) CH3–C–C–CH3 (C) (D)
CH3 Cl OH
6. uhps fn;s x;s ;kSfxd dk lgh fQ'kj iz{ksi.k lw=k dkSulk gS %
(A) (B) (C) (D)
7. fuEu esa ls fdl ;kSfxd dk (L) foU;kl gS\

C2H5
(A) (B) (C) (D) H CH3
NH2
8. fuEu esa ls dkSulk D-ysfDVd vEy dks ugha n'’kkZrk gS
(A) (B) (C) (D)
9. fuEu esa ls dkSulk ;kSfxd D-vfHkfoU;kl j[krk gS %
(A) (B) (C) (D)
10. fuEu esa ls dkSulk ;kSfxd R vfHkfoU;kl j[krk gS %
(A) (B) (C) (D)
11. uhps fn;s x;s ;kSfxd esa nksuksa fdjSy dkcZu ijek.kqvksa dk lgh R/S vfHkfoU;kl gS %
(A) 2S, 3R (B) 2R, 3S (C) 2S, 3S (D) 2R, 3R

PAGE NO.-58
12. uhps fn;s x;s ;kSfxd esas fdjSu ijek.kqvksa dk R/S vfHkfoU;kl gS %
(A) 1R, 3S (B) 1R, 3R (C) 1S, 3S (D) 1S, 3R

13. (2R, 3R) CH3CH(OH)CH(OH)COOH dh lajpuk gS &
COOH COOH COOH COOH
H OH OH H H OH HO H
(A) (B) (C) (D)
H OH H OH HO H HO H
CH3 CH3 CH3 CH3
14. dkSuls fodYi esa fn;s x;s lewgksa ,oa ijek.kqvksa ds f=kfoe vfHkfoU;kl lajpuk P ls fHkUu gSA
Cl
P = H3C H
D
CH3 CH3 Cl
D CH3
(A) Cl D (B) D H (C) (D) D CH3

Cl
H Cl H
H
15. uhps fn;s x;s ;kSfxd esa nksuksa fdjSy dkcZu ijek.kqvksa dk lgh R/S vfHkfoU;kl gS %
(A) 2S, 3R (B) 2R, 3S (C) 2S, 3S (D) 2R, 3R

16. fuEu esa ls dkSulk ;kSfxd fdjSy gS %
(A) CH3–CH2–OH (B) CH3–CH2–CH2–CH2–OH
(C) CH3–CH–CH3 (D) CH3–CH–CH2–CH3
OH OH
17. dksdhu ,d hallucinogen gS] ftldk vR;f/kd mi;ksx gksrk gSA blesa fdrus fdjSy dkcZu ik;s tkrs gSA
18. fn;s x;s ;kSfxd esa fdrus fdjSy ijek.kq mifLFkr gS \
PAGE NO.-59
19. fn;s x;s ;kSfxd esa fdrus fdjSy ijek.kq mifLFkr gS \
20. uhps fn;s x;s ;kSfxd esa fdrus fdjSy dsUnz mifLFkr gS %
Ph
HO
D OH
21. uhps fn;s x;s ;kSfxd esa fdrus fdjSy dsUnz mifLFkr gS %
ChemINFO Lab Test of Acidic hydrogen

Daily Self-Study Dosage for mastering Chemistry Lab Test of Acidic Hydrogen
tc dksbZ ;kSfxd lksfM;e vFkok ikSVsf'k;e vFkok {kkj /kkrq vFkok lksMkekbM ds lkFk vfHkfØ;k djus ij H2 xSl eqDr djrk
gS rks blls ;g izrhr gksrk gS fd blesa vEyh; gkbMªkstu mifLFkr gSA
lfØ; H : ,sls H ijek.kq tks vf/kd oS|qr_.kh ijek.kqvksa tSls O, N,S, X, Csp ls tqM+s gksrs gSa] mUgsa lfØ; H dgrs gSaA
i.e., CH3 — O — Ha CH3 — C  C — Ha CH3 — S — Ha
Ha
uksV : fuEu ;kSfxd rFkk CH3–C–CH–C–CH3 Hkh vEyh; gkbMªkstu j[krs gSaA
O Ha O
1
lkekU; vfHkfØ;k : Z– + Na  + H2 
2
1 1
(a) R  COOH 
Na
R  COONa  H2  (b) PhOH 
Na
PhONa  H2 
2 2
1 1
(c) R—C  CH + Na  R—C  C–Na+ + H2  (d) R—SO3H + Na  R—SO3–Na+ + H2 
2 2
1
(e) R —CH2—O —CH3 + Na  No reaction. (f) HCl  NaCl  H2 
Na
22. fuEu esa ls dkSulk ;kSfxd vEyh; gkbMªkstu j[krk gS

(A) CH3–CH3 (B) CH3–N–CH2–CH3 (C) CH3–COOH (D) CH3–O–CH3
CH3
23. fuEu esa ls dkSulk ;kSfxd lksfM;e /kkrq ds lkFk vfHkfØ;k ds Ik'pkr~ H2 xSl eqDr djsxk ?
(A) (B) (C) (D)
24. fuEu esa ls dkSulk ;kSfxd lksfM;e /kkrq ds lkFk vfHkfØ;k ds Ik'pkr~ H2 xSl eqDr ugha djsxk ?
(A) CH3–S–H (B) CH3–CHO (C) CH3–CH2–CCH (D) CH3–C–CH2–C–CH3
O O
PAGE NO.-60
25. fuEu esa ls dkSulk ;kSfxd lksfM;e /kkrq ds lkFk vfHkfØ;k ds Ik'pkr~ H2 xSl eqDr ugha djsxk ?
CH2 —COOH
CH2 —O — H CH2 —O — H CH2 —S — CH3
CH — O — H
(A) (B) (C) CH2 — CHO (D)
CH2 O —CH3 CH2 — NH2
CH2 — S — H

1. fuEu esa ls buesa ls dkSulk lkbDyksisUVsu O;qRiUu izdkf'kd lfØ; gS \
(A) (B) (C) (D)
2. fuEu esa ls dkSu nksgjh&eqM+h gq;h (two-fold) v{k lefefr dk v{k j[krk gS\
(A) ,Fkkbyhu (B) lkbDyksizksisu (C) lkbDyksC;wVsu (D) csUthu
3. fn;s x;s ;kSfxd ds fy, fuEu esa ls dkSulk lgh gS \
(A) blesa lefefr dsUnz mifLFkr gSA (B) blesa lefefr C3 v{k mifLFkr gSA
(C) blesa lefefr ry mifLFkr gSA (D) blesa lefefr C2 v{k mifLFkr gSA
4. fuEu esa ls dkSu izdkf'kd vfØ; gS%

(A) fll-1,2-MkbczksekslkbDyksC;wVsu (B) Vªkal-1,2-MkbczksekslkbDyksC;wVsu
(C) Vªkal-1,3-Mkbczkseks-1-DyksjkslkbDyksC;wVsu (D) Vªkal-1,3-MkbczksekslkbDyksC;wVsu
5. fn;s x;s ;kSfxdks esa ls fdjSy v.kq gSa %
(A) (B)
(C) (D)
vuqNsn #
,d vlarÌr ;kSfxd X (C5H10O) ds pkj f=kfoe leko;oh lEHko gSA Y, (X dk lajpukRed leko;oh) uk rks vlarÌr
gS vkSj uk gh f=kfoe leko;ork n'kkZ ldrk gSA X o Y esa leku fØ;kRed lewg ik;k tkrk gSA rhljk leko;oh
(Z), X dk fLFkfr leko;oh gS rFkk dsoy nks f=kfoe leko;oh j[krk gSA
PAGE NO.-61
6. fuEu esa ls ;kSfxd Z ugha gks ldrk gS\
(A) CH2=CH– CH –CH2 CH3 (B) H2C = CH–CH2– CH –CH3
| |
OH OH
CH3
|
(C) CH3–CH=CH–CH2–CH2–OH (D) H2C=C–CH–CH3
|
OH
7. Y gks ldrk gS %
CH2OH
|
(A) (B) (C) (D) (B) rFkk (C) nksuksa
|
O OH
8. CH4 es mifLFkr ry lefefr dh dqy la[;k gS&
9. fuEu esa ls fdl ;kSfxd esa lefefr dk dsUnz ugha ik;k tkrk gS %
H
(i) (ii) (iii) H3C C (iv) BeCl2(linear)

D
T
Cl
CH3
H H H Cl Cl
(v) (vi) H (vii) (viii)
H Br
Cl Cl Cl
10. fuEu eas ls fdrus lefefr dk ry j[krs gS\
H CH3
H CH3 H H H Br D
(i) CH3 (ii) H (iii) (iv) C
H CH3
CH3 H CH3 Br Br
(v) (vi) (vii) (viii)
11. BF3 esa lefefr dh aC2 v{k X gS rFkk lefefr dh C3 v{k Y gSA viuk mÙkj X + Y ds :i esa nhft,A
12. fuEu dks lqesfyr dhft,A
dkWye-I dkWye -II
(A) (p) T;kferh; leko;oh
(B) (q) izdkf'kd leko;oh
(C) (r) ;kSfxd esa leferh ry gSA
(D) (s) ;kSfxd esa leferh dsUnz gSA
PAGE NO.-62

1. fuEu ;qXe ds e/; lEc/k gS&

CI Br
H F & F Cl
Br H
(A) izfrfcEc:iksa leko;oh (B) foofje:ih leko;oh
(C) le:I (D) dksbZ lEc/k ugh
2. eSysbd vEy rFkk ¶;wesfjd vEy esa lEca/k gS %

(A) le:ih (B) izfrfcEc:ih (C) foofje:ih (D) Jà[kyk leko;oh
3. fuEufyf[kr ;kSfxadks ds e/; laca/k gS :

COOH COOH
H OH rFkk H OH
H OH HO H
COOH COOH
(A) izfrfcEc:ih (B) foofje:ih (C) le:ih (D) T;kferh; leko;oh
4. D-ySfDVd vEy rFkk L-ySfDVd vEy gSa :

(A) letkr (B) la:ih (C) izfrfcEc:ih (D) foofje:ih
5. fuEu esa ls dkSulk felks ;kSfxd gSA

CH3
CH3 Cl CH3
H Cl
(A) (B) (C) H Cl (D)
C2H5 H Cl
H
6. fuEu esa ls dkSulk felksa ;kSfxd gS %
(A) CH 3–CH–CH–CH 3 (B) CH3–CH–CD–CH3 (C) CH3–CH–CH–CH3 (D) CH3–CH–CH–CH3
Cl Br OH OH CH3 Cl Cl Cl
7. fuEu esa ls dkSulk ;kSfxd fdjSy gS %
CH3
H Cl
(A) (B) (C) (D) mijksDr lHkh
Cl H
CH3
8. fuEu esa ls dkSulk felks ;kSfxd ugha gS %
COOH
CH3 CH3 H OH
H Cl H Cl HO H CHO
(A) H OH (B) HO H (C) HO H (D) H OH
H Cl H Cl H OH
CH3 CH 3 COOH CH3
PAGE NO.-63
9. fuEu esa ls dkSulk ;kSfxd 2- esfFky C;wVsuksbd vEy ds jslsfed feJ.k ds izdkf'kd fo;kstu ds fy, mi;qDr gS :
(A) 2-C;wVsukWy (B) 1-izksisukWy
(C) 2-izksisukWy (D) lkbDyksC;wVsu dkcksZfDlfyd vEy
10. ,d ;kSfxd dk [] = 40.3º gS ftls iksyjs hehVj iz;ksx ls nf{k.kkorZ fn'kk esa Kkr fd;k x;k gSA vr% bldh lajpuk
gksxhA
(A) (B)
. (C) (D)
11. dk izdkf'kd ?kw.kZu –45° gS] rks dk izdkf'kd ?kw.kZu gksxkA
(A) + 45° (B) 0° (C) –45° (D) dqN dgk ugha tk ldrkA
12. ;fn }kjk mRiUu izdkf'kd ?kw.kZu +36º gS rks }kjk mRiUu izdkf'kd ?kw.kZu gksxk&
(A) – 36º (B) 0º (C) + 36º (D) vKkruh;
13. fuEu esa ls dkSulk ehlks ;kSfxd gS ?
(A) (B) (C) (D)
14. uhps fn;s x;s ;kSfxd (I) rFkk (II) ds e/; laca/k gS %
CH3 CH3
HO — C — H H — C — OH
HO — C — H H — C — OH
H — C — OH H — C — CH3
CH3 OH
(I) (II)
(A) izfrcEc:ih leko;oh (B) foofje:ih leko;oh
(C) le:ih ;k leku (D) lajpukRed leko;oh
PAGE NO.-64
Br Br
C C
15. & H
H CH2Cl C2H5
C2H5 Cl
mijksDr ;kSfxdks dk ;qXe fuEu esa ls fdl izdkj lEcfU/kr gSa\
(A) izfrfcEc :ih leko;oh (B) foofje :ih leko;oh
(C) ltkrh; (D) le:i ;kSfxd
16. fuEu esa ls dkSulk felks ;kSfxd gS %
(A) (B) (C) (D)
17. ;kSfxd 'X' ds fdrus foU;kl gks ldrs gSa\

CH2–CH3
CH3
CH
X= H–C–C=C CH3
CH3
OH H
18. lajpukRed lw=k CH3 – CH  CH – CH – CH  CH2 ds izdkf'kd lfØ; ,YdkMkbZbZu dh la[;k gS %

|
Cl
19. C;wVsu-2,3-MkbvkWy ds fy;s laHkkfor f=kfoe izdkf'kd lfØ; leko;fo;ksa dh la[;k fuEu esa ls gksxh \
20. fn;s x;s ;kSfxd ds T;kfefr leko;oh;ksa dh la[;k D;k gksxhA
21. 2, 3- MkbZDyksjksC;wVsu ds fdrus izdkf'kd lfØ; leko;oh laHko gS \
ChemINFO Lab test of amide, ester & nitro group

Daily Self-Study Dosage for mastering Chemistry Lab Test of Amide, ester & nitro group
,sekbM dk ijh{k.k
tc vEy ,sekbM dks {kkj ds lkFk xeZ fd;k tkrk gS] rks veksfu;k xSl dh xa/k vkrh gSA
,LVj dk ijh{k.k
,LVj e/kqj xa/k ¼Qyksa tSlh½ okys nzo gksrs gSaA
tc budh vfHkfØ;k NaOH rFkk fQukWY¶FkSyhu ds lkFk djkrs gSa rks xeZ djus ij xqykch jax foyqIr gks tkrk gSA

RCOOR’ + NaOH + fQukWY¶FkSyhu (xqykch jax)  RCOOH + R’OH (jaxghu foy;u)
ukbVªks lewg ds fy, ijh{k.k ¼eqyhdu&ckdZj ijh{k.k½
ukbVªks,sYdsu ,oe~ ukbVªkscsUthu dks Zn o veksfu;e DyksjkbM ls vipf;r djus ds ckn VkWysu vfHkdeZd ls
mipkfjr djus ij dkyk vo{ksi izkIr gksrk gSA bls eqyhdu ijh{k.k dgrs gSA
(a) R–NO2 R–NHOH Ag
PAGE NO.-65
AgNO3 NH4 OH
(b) + Zn + NH4Cl    

22. ,d dkcZfud ;kSfxd X (C4H8O2), NaOH vkSj fQukW¶Fkyhu ds lkFk /kukRed ijh{k.k nsr k X dh lajpuk gksxhA
(A) CH3  CH2  CH2  C  OH (B) CH3  C  C  CH3
|| || ||
O O O
(C) CH3  C  O  C2H5 (D) CH3  C  OCH3
|| ||
O O
23. dkSulk ;kSfxd lkUnz NaOH ds lkFk NH3 dh xa/k nsrk gSA
(A) CH3  CH2  C  NH2 (B) CH3  C  CH2  NH2
|| ||
O O
(C) (D) CH3  CH2  C  OH

||
O
24. ,d ;kSfxd tks ftad pw.kZ ,oa veksfu;e DyksjkbM ds lkFk xeZ fd;k tkrk gS izkIr vfHkfØ;k feJ.k dks VkWysu
vfHkdeZd esa Nkuus ij jtr niZ.k curk gSA ;g fØ;k fuEu esa ls fdl lewg dh mifLFkfr n'kkZrh gSaA
(A) –CHO (B) (C) –NO2 (D) –NH2

25. ukbVªks lewg ds ijh{k.k ds fy, fuEu esa ls fdl lewg vfHkdeZd dk mi;ksx fd;k tkrk gS :
(A) VkWyus ijh{k.k (B) ywdkl ijh{k.k (C) eqyhdu ijh{k.k (D) czksehu ty ijh{k.k

1. fuEu esa ls fdl pØh; ;kSfxd esa vf/kdre dks.kh; foÑfr mifLFkr gS %
(A) (B) (C) (D)
2. fuEu esa ls fdl iztkfr esa la:i.k leko;rk lEHko gS %

(A) (B) CH2 = CH2 (C) CH3–CH2–CH3 (D) H–CC–H
3. n-C;wVsu dk lokZf/kd LFkk;h la:i.k gS %

(A) xkml (B) ,UVh (C) iw.kZr% xzflr (D) vkaf'kd xzflr
4. XykbdkWy dk lokZf/kd LFkk;h la:i.k gS %
(A) (B) (C) (D)
PAGE NO.-66
5. 2,3-MkbesfFky C;wVsu dk lokZf/kd LFkk;h la:i.k leko;oh gS %
Me
Me H
(A) (B) (C) (D) lHkh dk LFkk;hRo leku gS
H Me
Me
6. vkblksisUVsu dk og la:i.k ftlesa vf/kdre ,sBu ruko (torsional) vkSj okUMjoky fod`fr gS%
(A) (B) (C) (D)
7. dkSulk/dkSuls dFku lgh gS%

(S-1) ,Fksu ds lHkh la:i.k leko;oh leHkaz'k gSA
(S-2) n-C;wVsu ds lHkh la:i.k leko;oh leHkaz'k gSA
(S-3) ,Fksu dh la:i.k ÅtkZ n-C;wVsu ls vf/kd gSA
(S-4) HOCH2CH2OH dk lcls LFkk;h la:i.k xkÅl gSA
(A) T F F T (B) F F F T (C) T F F F (D) F T F F
8. 1-czkseks-2-esfFky izksisu esa C1–C2 cU/k ds lkis{k fuEu esa ls dkSulk U;weSu iz{ksi.k lw+=k lgh gS \
(A) (B) (C) (D)
9. 2,2-MkbDyksjksC;wVsu ds U;weSu iz{ksi.k ds fy, dkSulk dFku lgh gS \
(A) ;fn ‘X’, H gS rc ‘Y’, CH3 gksxk (B) ;fn ‘X’, H gS rc ‘Y’, Cl gksxk
(C) ;fn ‘X’, H gS rc ‘Y’, C2H5 gksxk (D) ;fn ‘X’, Cl gS rc ‘Y’, CH3 gksxk
10. fn;s x;s ;qXe esa lEca/k gS %

CH3 CH3
H CH3 H3C H
H H H H
H H
(A) la:i.k izfrfcEc :ih (B) la:i.k foofje :ih
(C) T;kferh; leko;oh (D) letkr
11. f=klnL;h; pfØ; ;kSfxd ds vf/kdre fØ;k'khy gksus dk dkj.k gS:

(A) ,saBu fod`fr dh mPp ek=kk (B) dks.kh; fod`fr dh mPp ek=kk
(C) f=kfoe fod`fr dh mPp ek=kk (D) mijksDr lHkh
PAGE NO.-67
13. uhps n'kkZ;h x;h lajpukvksa esa dkSu U;wure fLFkfrt ÅtkZ j[krk gS\
(A) (B) (C) (D)
14. lfDlfud vEy dk {kkjh; ekè;e esa lcls vfèkd LFkk;h la:i.k gksxk%
(A) (B) (C) (D)
15. lkbDyksgsDlsu dk dkSulk la:i.k lefefr dk ry ugh j[krk gS\

(A) ukSdk (B) eqM+h gqbZ ukSadk (C) dqlhZ (D) vk/kh dqlhZ
16. lkbDyksgsDlsu dk la:i.k leko;oh ftldh ÅtkZ U;wure gS og gS :

(A) dqlhZ :i (B) ukSdk :i
(C) f}dkjh ukSdk :i (Twist boat form) (D) v/kZ dqlhZ :i
17. fuEu esa ls fdl la:i.k dh ÅtkZ vfèkdre gS \
(A) (B)
(C) (D)
18. 1-Dyksjksizksisu dk lokZfèkd èkzqoh; rFkk LFkk;h la:i.k gS&
(A) (B) (C) (D)
19. C;wVsu ds fdrus la:i.k leko;oh fdjSy gksrs gSa \

20. ,Fksu ds fn;s x;s la:i.k esa f}ry dks.k gksxk %
H
H H
H H
H
21. fn;s x;s ;kSfxd ds dqy fdrus f=kfoeleko;oh lEHko gS %
CH3–CH=CH–CH=CH–CH=CH–CH3
22. (P)
;kSfxd P ds T;kfefr leko;oh vkSj izdkf'kd leko;oh dh la[;k Øe'k% gSA
PAGE NO.-68
ChemINFO Lab Test of amines

Daily Self-Study Dosage for mastering Chemistry Lab Test of Amines
,ehu ds fy, ijh{k.k %
(i) NaNO2 + tyh; HCl ijh{k.k %
bldk mi;ksx 1º, 2º rFkk 3º ,ehuksa ds e/; foHksnu djus ds fy;s fd;k tkrk gS rFkk blds }kjk ,fyQSfVd rFkk
,sjkseSfVd ,ehuksa ds e/; Hkh foHksnu fd;k tkrk gSA
1° ,fyQSfVd ,ehu % R–CH2–NH2 R–CH2–OH + N2 
1° ,sjkseSfVd ,ehu % ¼Mkb,stksfu;e yo.k)
2° ,ehu % R–NH–R (N-ukbVªkslks ,ehu) ihyk rsy tSlk nzo
3° ,ehu : R3N vLFkk;h ukbVªkbV
(ii) dkfcZy ,ehu ijh{k.k (CHCl3 + KOH) :

CHCl3 KOH
1° ,ehu % R–CH2–NH2   R–CH2–NC + 3KCl + 3H2O
vfiz; xaèk ¼vk;lks lk;ukbM½
CHCl3 KOH
Ph – NH2 
 Ph–NC
* 2° ,ehu rFkk 3° ,ehu ;g ijh{k.k ugha nsrs gSA
(iii) gkWQeku eLVMZ vkW;y ijh{k.k %

;g ijh{k.k 1º ,ehu ,oa ,fuyhu nsrs gSaA izkFkfed ,ehu] dkcZuMkbZlYQkbM ds lkFk vfHkfØ;k djds
MkbZFkk;ks,fYdy dkcZsfed vEy cukrs gSaA tks edZjh DyksjkbM (HgCl2) ds lkFk xeZ djus ij fo?kfVr gksdj
vkblksFkk;kslk;usV nsrk gSA ftldh xa/k ljlksa ds rsy tSlh gksrh gSA
SH
(a) R–NH2 + S=C=S 
 R–NH– C HgCl2
  R–N=C=S + HgS + 2HCl
|

S
||
MkbZFkk;ks,fYdy dkcZsfed vEy ,fYdyvkblksFkk;kslk;usV

(b) CH3CH2NH2 + S = C=S  HgCl2
  CH3CH2–N=C=S + HgS + 2HCl

(1º ,ehu) ,fFkyvkblksFkk;kslk;usV

blh izdkj ls ,fuyhu vfHkfØ;k djds QsfuyvkblksFkk;kslk;usV nsrs gSaA
(i) S=C=S
(c) C6H5NH2 C6H5N=C=S
(ii) HgCl2/ 
QsfuyvkblksFkk;kslk;usV
* 2° ,ehu ,oa 3° ,ehu ;g ijh{k.k ugha nsrs gSaA
(iv) fgalcxZ vfHkdeZd (C6H5SO2Cl) :

bl vfHkdeZd dk mi;ksx 1°,2° rFkk 3° ,ehu ds e/; foHksnu djus ds fy, fd;k tkrk gSA
fifjMhu {kkj
1° ,ehu % R–NH2 + PhSO2Cl  R–NH–SO2–Ph   ;kSfxd {kkj esa foys;'khy gSA 
fifjMhu {kkj
2° ,ehu % R2NH + PhSO2Cl  R2N–SO2–Ph   ;kSfxd {kkj esa v?kqyu'khy gSA
fifjMhu
3° ,ehu % R3N PhSO2Cl  dksbZ vfHkfØ;k ughaA
PAGE NO.-69
23. fuEu esa ls dkSu NaNO2 / HCl ds lkFk N2 xSl nsrk gSA
(A) CH3–CH2–NH–CH3 (B) CH3–CH2–CH2–NH2
(C) Ph–NH2 (D) (CH3CH2)3N
24. fglacxZ çØe ç;qDr djrs gS %
(A) çkFkfed ,ehu ds la'ys"k.k ds fy, (B) f}rh;d ,ehu ds la'ys"k.k ds fy,
(C) r`rh;d ,ehu ds la'ys"k.k ds fy, (D) ,ehu feJ.k ds i`FkDdj.k ds fy,
25. fuEu esa ls dkSulh ,ehu fglacxZ vfHkdeZd (Hinsberg's reagent) ls vfHkfØ;k ugha djrk gSA
(A) CH3CH2NH2 (B) Ph–NH2 (C) (CH3CH2)2NH (D) Ph–CH2–NH2

Total Marks : 53 Max. Time: 32 min.
Integer Type Questions Q.9 to Q.12 (4 marks, 2 min.) [12, 08]
Matching List Type (Only One options correct) ('–1' negative marking) Q.13
(4 marks, 2 min.) [03, 02]
1. fuEu esa ls fdlds lHkh la:i.k leko;oh leHkza'k gSa\

(A) ,Fksu (B) izksisu (C) fu;ksisUVsu (D) vkblksC;wVsu
2. ;fn 2-esfFkyC;wVsu dk U;weSu iz{ksi.k lw=k fuEu izdkj n'kkZ;k tk;s] rks X, Y rFkk Z Øe'k% ldrs gS%&
(A) H, CH3 rFkk C2H5 (B) CH3, CH3 rFkk CH3

(C) C2H5, H rFkk H (D) H, H rFkk CH(CH3)2
3.
I II III
mijksDr ;kSfxdks esa lgh lEc/ak gSA
(A) I rFkk II fLFkfr leko;oh gSA (B) I rFkk II Jà[kyk leko;oh gSA
(C) II rFkk III e/;ko;oh gSA (D) II rFkk III le:i gSA
4.
lgh dFku@dFkuksa dk p;u dhft,&

(A) lHkh le:i ;kSfxd gSA
(B) III rFkk IV le:ih rFkk ehlks ;kSfxd gSA
(C) I rFkk II izdkf'kd lfØ; ;kSfxd gSA
(D) I rFkk II vfHkfoU;klh leko;oh gS tcfd II rFkk IV la:i.k leko;oh gSA
PAGE NO.-70
5. fuEu esa dkSuls la:i.kks dk f}/kzqo vk/kq.kZ v'kqU;
(A) (B) (C) (D)
6. fuEu esa ls dkSulk lgh gS\

(A) fdjsy v.kq Lo;a dh fdjsyrk iz;qDr dj niZ.k izfrfcEc ds e/; foHksnu dj ldrs gSaA
(B) dqlhZ la:i.k ij izfrLFkkih v{kh; fLFkfr;ksa ij jgus dh izo`fr n'kkZrk gSA
(C) Msdkyhu ¼ckblkbDyks[4.4.0]Msdsu½ T;kehfr leko;ork n'kkZrk gSA
(D) lkbDyksgsDlsu dk f}dkjh ukSdk la:i.k fdjSy la:i.k gSA
vuqPNsn #
dkcksZfuy ;kSfxd] tks ,YQk vlefer dkcZu (C) ijek.kq rFkk –H ijek.kq j[krk gS] tyh; foy;u esa j[kus ij
pyko;ork ds dkj.k jslsehd`r gksrk gSA
7. fuEu esa ls dkSulk ;kSfxd tyh; foy;u esa j[kus ij jslsehd`r gksxk\
CH3 Me
| |
(A) CH3–CH2–CHO (B) Ph  C  C  CH3 (C) Ph  C  C  CH3 (D) Ph  CH  CH2  C  CH3
| || | || | ||
H O Et O D O
8. fuEu vfHkfØ;k ds fy, dkSulk dFku xyr gS \

OD / D2O vkf/kD;
 
(A) blesa jslsehdj.k gksrk gSA

(B) vlefer C* dkcZu ijek.kq ij D-fofue; gksrk gSA
(C) jslsehdj.k dh nj D-fofue; dh nj ds cjkcj gksrh gSA
(D) izkIr mRikn oke/kzqo.k ?kw.kZd gksrk gSA
9.
viuk mÙkj X Y ds :i esa fyf[k;sA

PAGE NO.-71
10. fn, x, ;kSfxd X ds fy, izdkf'kd lfØ; f=kfoe leko;oh;ksa (optically active stereoisomers) dh lEiw.kZ
la[;k……. gSA
OH OH
bl izdkj dk vkca/k ;g n'kkZrk gS fd fof'k"V dkcZu ij foU;kl vkSj

f}&vkca/k dh T;kfefr fLFkj gSA
bl izdkj dk vkca/k ;g n'kkZrk gS fd fof'k"V dkcZu ij foU;kl vkSj
OH
f}&vkca/k dh T;kfefr fLFkj ugha gSA
Br
11. fuEu ds fdrus la:i.k leko;oh /kqzoh; gksxsa A

Cl–CH2–CH2–Cl.
12. ds fy;s fdrus bZukWy :i laHko ¼f=kfoe leko;oh;ksa ds lkFk½ gSA

13. fuEu dk feyku dhft,&
LrEHk-I LrEHk-II
(A) (p) lei{k-foi{k
(B) (q) foi{k-:i
(C) (R) tc ;kSfxd f¶yi djrk gS rc Keq dk eku ,d ls T;knk gksxkA
(D) (s) tc ;kSfxd f¶yi djrk gS rc Keq dk eku ,d ls de gksxkA
(t) tc ;kSfxd f¶yi djrk gS rc Keq dk eku yxHkx ,d gksxkA

14. dkWye-I dks dkWye-II ls lqesfyr dhft,%
dkWye I dkWye II
(A) (p) bZukWfyd :i ds T;kferh; leko;oh gksxsaA
(B) (q) bZukWy :i fdjsy gSA
bldk pyko;oh 2,4–DNP ds lkFk /kukRed ijh{k.k nsrk

(C) (r)
gSA
(D) (s) dhVks-bZukWy pyko;ork }kjk jslsfedj.k gks tkrk gSA
PAGE NO.-72

1. fuEu esa ls dkSulk bySDVªkWuLusgh gS %

(A) CH3 (B) Br (C) NO2 (D) mijksDr lHkh
2. fuEu esa ls dkSu ukfHkdLusgh dh Hkkafr O;ogkj djsxk %


(A) CH3 (B) NH3 (C) I (D) mijksDr lHkh
3. fuEu esa fdldh ukfHkdLusfgrk vf/kdre gS %

   
(A) CH3 (B) NH2 (C) OH (D) F
4. fuEu esa dkSu izcyre ukfHkdLusfg gS %

 
(A) F (B) Cl (C) Br (D) I
5. fuEu esa ls dkSulk vPNs ukfHkdLusfg ds lkFk&lkFk vPNk fu"d"khZ lewg Hkh gS %

(A) NH2 (B) OH (C) I (D) CH3–O
6. fuEu esa ls dkSulk vPNk fu"d"khZ lewg gS %
(A) (B) (C) HO (D) CH3–O
7. /kqzoh; vizksVhd foyk;d gS %

CH3–S–CH3
(A) CH3COOH (B) H2O (C) O (D)
(DMSO)
8. /kqzoh; izksVhd foyk;d gS %

(A) CH3–O–CH3 (B) CCl4 (C) (D) H2O
9. v/kqzoh; foyk;d gS %
(A) ,FksukWy (B) ,lhVksu (C) DMF (D) CS2
10. fuEu esa ls dkSulk ,d bysDVªkWuLusgh gS\
(A) H2O (B) NH3 (C) CH3OH (D) AlCl3
11. fuEu esa ls dkSulk ,d bysDVªkWuLusgh ugha gS \
(A) PCl5 (B) SO3 (C) Ph–OH (D) HCHO
12. dkSulk nqcZy fu"dklu lewg gS\
(A) OH (B) SH (C) OPh (D) CH3COO
13. fuEu esa ls dkSulh iztkfr mHk;/kehZ ukfHkdLusgh gS \
(A) C6H5O– (B) NO3– (C) HSO3– (D) NH3
14. fuEu esa ls dkSulk lcls vPNk fu"dklu lewg gS \
(A) (B) CH3–O– (C) OH– (D) CF3SO3–
PAGE NO.-73
15. fn;s x, fu"dklu lewgksa dh fu"dklu ;ksX;rk dk ?kVrk gqvk lgh Øe gS \
I. OH– II. III. CH3COO– IV. CH3SO3–
(A) IV > III > II > I (B) III > IV > II > I (C) II > IV > III > I (D) IV > II > III > I
16. fuEu dk fu"dklu ;ksX;rk dk lgh Øe gSA

I. C6H5O–, II. p-(CH3) C6H4O– III. p-(OCH3)C6H4O– IV. p-(NO2)C6H4O–
(A) I > II > III > IV (B) III > II > I > IV (C) IV > I > II > III (D) IV > III > II > I
17. CH3–CH2–CH2–CH3 + Cl2, fuEu vfHkfØ;k mnkgj.k gS:
(A) vEy-{kkj vfHkfØ;k (B) izfrLFkkiu vfHkfØ;k (C) ;ksxkRed vfHkfØ;k (D) fioyksiu vfHkfØ;k
18. fuEu vfHkfØ;k gS :

Cl OH

+ OH + Cl¯
NO2 NO2
(A) ,d ;ksxkRed vfHkfØ;k (B) ,d ukfHkdLusgh izfrLFkkiu vfHkfØ;k
(C) ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k (D) ,d eqDrewyd izfrLFkkiu vfHkfØ;k
19. fuEu esa ls dkSulh vfHkfØ;k vEy&{kkj vfHkfØ;k dk mnkgj.k gSA

(A) CH2– CH2 
Zn
 CH2=CH2 + ZnBr2 (B) CH3COOH + NaNH2  CH2COONa + NH3
Br Br
H2 O
CH OH

3
  
(C) (D) 
H
20. fn;s x;s lajpukRed lw=k esa dqy f=kfoe leko;oh;ksa dh la[;k gSA
(A) 16 (B) 32 (C) 64 (D) 128

21. fuEu lajpuk ds fy, fdjsy dsUæksa (x) dh dqy la[;k rFkk izfrfcEc:ih;ksa (y) ds ;qXeksa dh dqy la[;k dk ;ksx gS&
22. CH3 – CH – CH – CH  CH – CH3 ds f=kfoe leko;oh;ksa dh dqy la[;k gSA

| |
Br Cl
23. fn;s x;s ;kSfxd ds fy, dqy izdkf'kd leko;fo;ksa dh la[;k gS %

CH3  CH  CH  CH  CH3
| | |
Cl Br Cl
24. fn;s x;s ;kSfxd ds dqy fdrus f=kfoeleko;oh lEHko gS %

25. D-Xywdkst esa fdrus fdjSy dkcZu ijek.kq mifLFkr gS\
PAGE NO.-74

1. fuEu esa ls dkSulk ;kSfxd bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gS\
CHO OCH3 Cl
(A) (B) (C) (D)
2. fuEu esa ls dkSu fÝMy&Øk¶V vfHkfØ;k ds izfr lcls de fØ;k'khy gS%

Ph CH3 Cl O=C–CH3
(A) (B) (C) (D)
3. fuEufyf[kr esa ls dkSulk lewg esVk&funsZ'kh izd`fr dk gS\

(A) –CH3 (B) –OCH3 (C) –CN (D) –Cl
4. fuEufyf[kr esa ls dkSulk lewg vkWFkksZ&iSjk funsZ'kh izd`fr dk gS\
(A) –CCl3 (B) –CHO (C) –NO2 (D) –OCH3
5. fuEu esa ls dkSuls ;kSfxd esa vkFkksZ&iSjk fuZns'kh o folfØ;.kdkjh lewg mifLFkr gS&
(A) (B) (C) (D)
6. fuEu esa ls dkSulk ;kSfxd ,d fo'ks"k bysDVªkWuLusgh ds izfr vfèkdre izfr'kr iSjk mRikn nsrk gSA
F Cl Br I
(A) (B) (C) (D)
ICl / ZnCl
7. 
2
mRikn( mijksDr vfHkfØ;k dk mRikn gS%
Cl Cl I I
(A) (B) (C) (D)

Cl
Cl
NO 2

H
8. + lkUnz HNO3 

mijksDr vfHkfØ;k ds nkSjku cuus okyk e/;orhZ gS%

(A) dkcZ_.kk;u (B) dkcZ/kuk;u (C) eqDr ewyd (D) dkchZu
9. fuEu vfHkfØ;kvksa esa ls fdlesa izkFkfed leLFkkfud izHkko izsf{kr gksrk gS&
(A) Dyksjhfudj.k (B) ukbVªhdj.k
(C) esfFkfydj.k (D) lYQksfudj.k
PAGE NO.-75
10. lYQksfudj.k vfHkfØ;k ds fy, xyr dFku gS&
(A) lYQksfudj.k ds fy, lkUæ H2SO4 mfpr gSA
(B) folYQksfudj.k ds fy, ruq H2SO4 mfpr gSA
(C) ;g ,d vuqRØe.kh; vfHkfØ;k gSA
(D) fuEu rki lYQksfudj.k ds fy, mfpr gS rFkk mPp rki folYQksfudj.k ds fy, mfpr gSA
11. mRizsjd futZyh; AlCl3 dh mifLFkfr esa fuEu esa ls fdldh fØ;k }kjk ,fFkycsUthu (PhEt) curk gS?
(A) CH3–CH2OH + C6H6 (B) CH3–CH=CH2 + C6H6
(C) C2H5Cl + C6H6 (D) CH3–CH3 + C6H6
12. csUthu dh lY¶;wfjd vEy dh mifLFkfr esa vkblksC;wVhu ds lkFk fØ;k ij curk gS%
(A) vkblksC;qfVy csUthu (B) r`rh;d-C;qfVy csUthu
(C) n-C;qfVy csUthu (D) vfHkfØ;k ugha
13. fuEu esa ls dkSulk dkcZfud DyksjkbM csUthu vkSj AICI3 ds lkFk xeZ djus ij ÝhMy&Øk¶V ,fYdyhdj.k vfHkfØ;k
ugha nsxkA
(A) CH3)3CCI (B) CH2=CHCH2CI (C) CH3CH2CI (D) CH2=CHCl
14. tc csUthu dh fØ;k HNO3/H2SO4 ds lkFk dh tkrh gS rc e/;orhZ D;k gksxk&
(A) (B) (C) (D)
lkUæ HNO  lkUæH SO 4 Cl / FeCl3

15. 3 2  X 2 Y
mRikn Y gS %
(A) p-Dyksjks ukbVªkscsUthu (B) m-Dyksjks ukVªkscsUthu
(C) o-Dyksjks ukbVªkscsUthu (D) o,p-MkbZDyksjks ukbVªkscsUthu
16. 
mijksDr vfHkfØ;k ds fy, fuEu esa ls dkSulh vfHkfØ;k ifjfLFkfr mfpr gS \

(A) CH3–CH2–CH2–Cl / AlCl3
(B) / AlCl3 blds i'pkRk~ NH2–NH2 / KOH
(C) CH2=CH2–CH2–Cl / AlCl3

(D) CH2=CH–CH2–Cl / AlCl3 blds i'pkRk~ H2 / Ni
17. fuEu esa ls fdrus ,sUVh&,sjksesfVd ;kSfxd gS\

(i) (ii) (iii) (iv)
PAGE NO.-76
18. fuEu esa ls fdrus ukWu&,sjksesfVd ;kSfxd gS\
(i) (ii) (iii) (iv)
(ix)
19. fuEu esa ls fdrus ,sjksesfVd ;kSfxd gS\
(i) (ii) (iii) (iv)
(ix)
20. fdrus eksuksukbVªks czkseks&csUthu ds fy, laHko gS\
21. fuEu vfHkfØ;k dks iw.kZ dhft,A

Br / Fe

2

(1 eq.)
dkSulh fLFkfr ij czksehuhdj.k gksrk gSA
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry ,sjksesfVd ik'oZ Jà[kyk dk vkWDlhdj.k
,sjksesfVd ik'oZ Jà[kyk dk vkWDlhdj.k
izcy vkWDlhdkjd inkFkZ tSls KMnO4/H/ ;k K2Cr2O7/H/ csfUtfyd dkcZu dks –COOH lewg esa vkWDlhd`r dj nsrs gSa
;fn v.kq esa csfUtfyd gkbMªkstu ijek.kq ;k vlarÌrrk mifLFkr gksrh gSA
PAGE NO.-77
lkekU;r vfHkfØ;k,sa:
COOH
KMnO / H KMnO / H

4

 
4


 
CH3
COOH CH3 C CH3

4

 
4
 dksbZ
 vfHkfØ;k ugha gksxh
 
uksV :- r`rh; C;wVhy (CH3)3C– vkWDlhdkjh vfHkdeZd }kjk vkWDlhd`r ugha gksrk gSA
KMnO / H

4

 KMnO / H
Ex.1  Ex.2 
4



CH2–CH3
KMnO / H
22. 
4

 mRikn ; mRikn gksxk :

O COOH CHO CH2OH
(A) (B) (C) (D)
23. fuEu esa ls dkSulk vfHkdeZd csfUty ,YdksgkWy dks csUtksbd vEy esa ifjofrZr djus ds fy, mi;qDr gSS \
(A) K2Cr2O7/H+ / (B) KMnO4/H+ / (B) m–CPBA (D) (A) rFkk (B) nksuksa
24. fuEu esa ls dkSulk] nh xbZ vfHkfØ;k dk vkWDlhdj.k mRikn gS\
KMnO / H

4



(A) (B) (C) (D)
KMnO / H
25. 
4

 mRikn ; mRikn gksxk :

(A) (B) (C) (D)
PAGE NO.-78

(4 marks, 2 min.) [03, 02]
1.
fuEu esa ls dkSulk@dkSuls ,d ;k vf/kd lgh mÙkj gS
(A) 1, (B) 2, (C) 3, (D) 4,
2. fuEu vfHkfØ;k ds fjft;ksp;ukRed izd`fr ds fy, dkSulk dkjd mÙkjnk;h gSA
Cl / FeCl
2
3
 +
(A) gSykstu dk –I izHkko (B) gSykstu dk +I izHkko (C) gSykstu dk +M izHkko (D) gSykstu dk –M izHkko
3. fuEu esa ls fdlesa fÝMy ØkW¶V ,lhyhdj.k vfHkfØ;k izsf{kr ugha gksrh gS@gSa \
(A) (B) (C) (D)
4. fuEu esa ls fdlesa bysDVªkWu Lusgh ,sjksesfVd izfrLFkkiu vfHkfØ;k cka;h vksj dh Qsfuy oy; ij gksxhA
(A) (B)
(C) (D)
5. fuEu esa ls dkSulh bysDVªkWu Lusgh izfrLFkkiu vfHkfØ;k esa lgh mRikn n'kkZ;k x;k gSA
Br / FeBr
(A) 2
3

Br / FeBr
(B) 2
3

PAGE NO.-79
Br / FeBr
(C) 2
3

Br / FeBr
(D) 2
3

vuqNsn #
COCl AlCl Zn-Hg/HCl
3
6. + (X) [Y]
COCl
Y gS %
(A) (B) (C) (D)
AlCl Zn(Hg / HCl)

7. 

3
 P 
 Q; mRikn Q gS&
COCl
OH
(A) COOH (B) (C) OH (D)
8. fuEu esa ls dkSulh vfHkfØ;k esa 1–Dyksjks–3–,fFky csUthu fufeZr gksrk gSA
Cl / AlCl Zn  Hg/HCl
(A) 
2 3
 

Cl /AlCl Zn  Hg/HCl
(B) 
2 3
  
Cl /AlCl
(C) 
2 3

Cl /Fe
(D) 
2

9. fuEu vfHkfØ;k dks iw.kZ dhft,A

Br / Fe HNO / H SO

2
 
3 2 4

(1 eq.) (1 eq.)
dkSulh fLFkfr ij ukbVªhdj.k gksrk gSA

10. v.kqlw=k C8H10O ds fdrus izfrLFkkih fQukWy lEHko gS\
PAGE NO.-80
11. lwph I (tc lewg Qsfuy oy; ij gks) dks lwph II ¼izHkko½ ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn;s x;s dksM dk
iz;ksx djds lgh mRrj pqfu;s:
lwph I lwph II
(P) –Cl (1) +m o +I

(Q) –O (2) +m o –I
(R) –CH2–CH3 (3) dsoy –I

(S) – N H3 (4) +I o vfrla;qXeu
dksM :
P Q R S P Q R S
(A) 1 3 2 4 (B) 3 4 2 1
(C) 4 2 3 1 (D) 2 1 4 3
12. dkWye-I dks dkWye-II ls lqesfyr dhft, %
dkWye-I dkWye-II
(A) (p) xje {kkjh; KMnO4 ds lkFk csUtksbd vEy nsrk gS
(B) (q) o/p funsZ'kkadh gS
CMe3
(C) (r) bysDVªkWu Lusgh izfrLFkkiu vfHkfØ;k ds fy, cSathu ls de fØ;k'khy gSA
(D) (s) vipf;r vkstksuhdj.k ij ,LVj nsrk gSA
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Oxidation
,ydhuks o ,Ydkbuksa dk flu gkbMªksDlhyhdj.k
lkekU; vfHkfØ;k :
H.A. H.A.
 —CC— 
H.A.
mnk- 
H.A. = gkbMªksfDlyhdj.k vfHkdeZdA bues ls ,d gks ldrk gSA

(a) cs;j vfHkdeZd % BaMk ruq 1% {kkjh; KMnO4 (xqykch jax ) ;k
(b) (i) OsO4 (ii) NaHSO3
uksV : 1. ,sjksesfVd oy; ds f}cU/k bu vfHkdeZdksa ls vfHkfØ;k ugha djrs gaSA
2. ;g flu (syn) ;ksx gSA nksuks OH lewg pi-cU/k ds ,d gh i{k dh rjQ ls tqMrs gSaA
PAGE NO.-81
cs;j vfHkd eZd

13.   mRikn ( mRikn gksxk %
(A) (B) HO OH
OH
(C) (D)
HO OH OH
14.
vfHkdeZd x gksxk %
(A) 1% {kkjh; KMnO4 (cs;j vfHkdeZd) (B) OsO4 /NaHSO3
(C) ij vEy /H3O+ (D) (A) ,oe~ (B) nksuksa
cs;j vfHkd eZd
15. CH3–CC–CH3  mRikn( mRikn gksxk %
or OsO4 / NaHSO3
(A) (B)
(C) (D) bues ls dksbZ ugha
ELECTROPHILIC SUBSTITUTION REACTIONS

fuEu vfHkfØ;k esa eq[; mRikn ds fy, mfpr fLFkfr crkb;sA
Br Br Br
1. 
2
 2. 
2
 3. 
2

Fe Fe Fe
Br Br Br
4. 
2
 5. 
2
 6. 
2

Fe Fe Fe
Br Br Br
7. 
2
 8. 
2
 9. 
2

Fe Fe Fe
Br Br Br
10. 
2
 11. 
2
 12. 
2

Fe Fe Fe
PAGE NO.-82
Br Br Br
13. 
2
 14. 
2
 15. 
2

Fe Fe Fe
Br Br Br
16. 
2
 17. 
2
 18. 
2

Fe Fe Fe
Br Br Br
19. 
2
 20. 
2
 21. 
2

Fe Fe Fe
3
2
Br Br Br
22. 
2
 23. 
2
 24. 
2

Fe Fe N 1 Fe
Br2
25.  
 26. 
2

Br
Fe
Br Br
27. 
2
 28. 
2

Fe Fe
2
Br Br
1    
29. 2
30. 2
Fe Fe
NH
1. 3 2. 3 3. 3 4. 2 5. 2
6. 2 7. 4 8. 1 9. 3 10. 3
11. 1 12. 1 13. 3 14. 1 15. 3
16. 2 17. 2 18. 1 19. 1 20. 1
21. 5 22. 3 23. 3 24. 2 25. 2
26. 3 27. 3 28. 1 29. 1 30. 3
PAGE NO.-83
DPP No. : A11 (JEE-MAIN)

1. fuEu esa ls dkSulh vfHkfØ;k lEHko gSa \
(A) + AgClO4  + 2 AgCl 
HClO4
(B)
NaH
(C) 
(D) mijksDr lHkh
2. fuEu esa ls dkSulk@dkSuls /kzqoh; LFkkbZ v.kq gSA
(A) (B) (C) (D)
3. fuEu esa ls dkSulh vfHkfØ;k esa H2 xSl eqDr gksrh gS %

K( èkkrq) K( èkkrq)
(A )  (B) 
K( èkkrq) K( èkkrq)
(C)  (D) 
4. fn;s x;s ;kSfxd dh Dyksjhuhdj.k vfHkfØ;k dh nj dks izHkkfor djus okyk fuEu ls dkSu lk lewg izfrLFkkih X ds
fy;s mi;qDr gksxk\
(A) –CF3 (B) –C(CH3)3 (C) –CH3 (D) –CH = O
CO, HCl
5.  (Y) mRikn gksxk
AlCl3
(A) (B) (C) (D)
PAGE NO.-84
6. fuEu esa ls dkSu lk ;kSfxd ukfHkd Lusgh ,sjkseSfVd izfrLFkkiu vfHkfØ;k vR;f/kd rhoz xfr ls nsrk gS \
 (A) (B) (C) (D)
7. fuEu vfHkfØ;k esa eq[; dkcZfud mRikn igpkfu;s]
+ NaSCH3  mRikn
 (A) (B) (C) (D)
8. fuEu vfHkfØ;k ds eq[; mRikn gSa %
H O / 
3 
 mRikn
(A) HCHO (B) (C) PhCHO (D) CH3CH2OH
9. fuEu vfHkfØ;k n'kkZrh gSA

300 350 C
C6H5Cl + 2NaOH    C6H5ONa + NaCl + H2O
300 atm
(A) MkWm fofèk (B) dksYcs fofèk
(C) dkfcZy,ehu ijh{k.k (D) gSyksQkWeZ vfHkfØ;k
10. QhukWy + CHCl3 + NaOH  mRikn gS :

(A) csUtksbd vEy (B) p-DyksjksQhukWy
(C) lsfyflysfYMgkbM (D) lsfyflfyd vEy
11. (A ,oa B Øe'k% gksxsa%)
(A) (B)
(C) (D)
12. fuEu vfHkfØ;k esa nj fu/kkZjr in gS %
(A) 1 (B) 2 (C) 3 (D) 4
PAGE NO.-85
RONa / 
13.  
mijksDr vfHkfØ;k dh vfHkfØ;k nj vf/kdre dc gksxh

(A) Y = – I (B) Y = – Br (C) Y = – Cl (D) Y = – F
14. fuEu esa ls dkSulk ;kSfxd vf/kdre~ lfØ;dkjh oy; j[krk gS %
(A) CCl4 esa (B) ruq NaOH esa (C) ruq HCl esa (D) ruq HCl esa
15. lkUnz HNO3 vkSj lkUnz H2SO4 ds ,d feJ.k dk mi;ksx dj csUthu ls ukbVªkscsUthu cukrs gSA feJ.k esa ukbfVªd
vEy ds :i esa dk;Z djrk gS %
(A) mRizsjd (B) vipk;d (C) vEy (D) {kkj
NaOH
16. + C2H5I   X, X gS %
(1 eq.)
(A) C6H5OC2H5 (B) C2H5OC2H5 (C) C2H5OH (D) C6H5I
17. fdruh VkWyqbZMhu] NaNO2/HCl ds lkFk vfHkfØ;k ds i'pkr H3PO2 ds lkFk mipkfjr gksus ij VkWyqbZu nsrh gS \
NO2
Sn/HCl NaNO H O, 
18.  
2

 
2

 mRikn Z
HCl 05C
Z dk v.kqHkkj Kkr dhft,A
19. ;fn esVk fØlkWy czksehu ty ds lkFk fØ;k djrk gS rks fdrus czksehu ijek.kq csUthu oy; ij tqM+s gq, gSA 
20. fdruh fQukWfyd oy; lw=k C7H8O ds fy, laaHko gS\

HBF
21. csUthu MkbZ,stksfu;e DyksjkbM 
4
 mRikn (P)

mRikn (P) esa csUthu oy; ij fdrus ¶yksjhu ijek.kq tqM+s gq, gS\
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry ,Ydhuksa dk ,s.Vh gkbMªksfDlyhdj.k
,Ydhuksa dk ,UVh gkbMªkWfDlyhdj.k
ijkWDlh vEy dh lkekU; lajpuk ¼lw=k½ (RCO3H) gksrk gSA ;g eq[; :i ls vLFkk;h gksrs gS rFkk vklkuh
ls uotkr O ns nsrs gSA vr% ;g vkWDlhdkjd inkFkZ dh Hkk¡fr dk;Z djrs gSA ;g ,Ydhu dks ,ikWDlkbM esa ifjofrZr dj
nsrs gSA RCO3H dk la;kstu blds ckn bldk tyvi?kVu [RCO3H(H3O+)] djus ij ;g vkxs ,ikWDlkbM dks ,UVh
gkbMªkWDlhyhdj.k esa rksMrk gSA
lkekU; vfHkfØ;k :
Peroxyacid H O

 
3
1. ;g ,UVh (anti) ;ksx gSA nksuksa OH lewg ikbZ&caèk dh foifjr fn'kk ls ;ksx djsxsaA
2. ,jksesfVd oy; ds f}cU/k bu vfHkdeZdks ls fØ;k ugh djrs gSA
PAGE NO.-86
OH
(i) ijkWD lh vEy
Ex.1  
(ii) H3O OH
lkbDyksgsDlhu foi{k&lkbDyksgsDlsu
1,2-Mkbvksy
bues ls dksbZ Hkh ij vEy gks ldrk gSA
CO H
– 3
(a) = m-CPBA ¼esVkDyksjks ijcsUtkWbd vEy½
–
Cl
(b) CH3CO3H = PAA (ij,flfVd vEy)
(c) PhCO3H = PBA ¼ijcsUtkWbd vEy½
(d) CF3CO3H = TFPAA (VªkbZ¶yksjks ij,flfVd vEy½
Ex.2
22. gS&
OH OH OH H
(A) (B) (C) (D) 50% B vkSj 50% C
H H H HO
ijkWD lh vEy
23. CH2 = CH2   X , X gS&
OH O
| CH2 — CH2
(A) CH2 — CH2 (B) | | (C) (D)
| OH OH
OH
(i) ijkWD lh vEy

24.   P ; mRikn gS&
(ii) H3O
(A) (B) (C) (D) bues ls dksbZ ughA
25. buesa ls fdlds }kjk ,Ydhu dk ,UVh gkbMªkWfDlyhdj.k gksxk &

(A) m-CPBA/ H3O (B) CH3 COOOH/H3O

(C) F3CCOOOH/H3O   
(D) mijksDr lHkh

(4 marks, 2 min.) [03, 02]
ChemINFO: 4 Questions ('–1' negative marking) Q.11 to Q.14 3 marks, 2 min.) [12, 08]
PAGE NO.-87
1. fuEu esa ls fdl vfHkfØ;k esa cuus okys mRikn lgh fn,s x;s gS \
OH
OH
Br Br
Br /H O
(A) 
2 2

Br
O O
C–O C–O
Br (1 mol)/Fe
(B) 
2

Br
OH OH
Dilute ruq HNO , 20ºC O2N NO2
3



(C)
NO2
OH O–C2H5
(C H ) SO NaOH / 
(D) 25
2
4

2. fuEu nh xbZ vfHkfØ;k esa fuEu esa ls dkSuls mRIkkn curs gSA

O / heat
H3O / heat
Ph3C – H 2
    
(A) PhCH2OH (B) Ph–OH (C) Ph2C=O (D) Ph–CHO

3. fuEu esa ls dkSulh vfHkfØ;k bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k gS %
OH OD
D D
D O
(A) 3 

D
N = N – Ar
ArN
+ H
2
(B) 

HO HO
SO3H
H / H O
(C) 
2
 + H2SO4
OH ONa
CO / NaOH
COONa
(D) 
2


vuqNsn #
I
 II
 III 
 Iv 
 v vI 

 (X) ¼nnZ fuokjd½
4. in-I esa fuEu esa ls dkSulh vfHkfØ;k gks jgh gSA

(A) bysDVªkWuLusgh izfrLFkkiu (B) ukfHkdLusgh izfrLFkkiu
(C) bysDVªkWuLusgh ;ksxkRed (D) ukfHkdLusgh ;ksxkRed
5. in-V esa fuEu esa ls dkSulh vfHkfØ;k gks jgh gSA

(A) fÝl iquZfoU;kl (B) dkWYcs fLeV vfHkfØ;k
(C) dkfcZy ,ehu vfHkfØ;k (D) (A) rFkk (B) nksuksa
PAGE NO.-88
6. in-VI esa vfHkdeZd rFkk mRikn (X) Øe'k% gksxsaA
(A) SOCl2, (B) ,
(C) MeOH, (D)
7. tkbyhu ds fdrus ,sjkseSfVd MkbZ,tksfu;e DyksjkbM dks H3PO2 ds }kjk esVk&tkbyhu esa ifjofrZr dj ldrs gS \
H PO , 

3 2
 (m-tkbyhu)
8. fuEu ;kSfxd Br2/H2O ds vkf/kD; esa mipkfjr fd;k tkrk gS] rks mu fLFkfr;ksa dh dqy la[;k Kkr djks] tgk¡
czksehuhdj.k vklkuh ls gksrk gSA
Cl
|
9. Dyksjy +  
Conc.H2SO4
 PmRikn
mRikn dhVuk'kh gS rFkk eysfj;k fu;U=k.k ds fy, f}rh; fo'o ;q) esa iz;qDr gqvk FkkA dhVuk'kh ds ,d v.kq esa
Dyksjhu ijek.kqvksa dh la[;k gS&
10. lwph I ¼vfHkdkjd½ dks lwph II ¼mRikn½ ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn;s x;s dksM dk iz;ksx djds lgh
mRrj pqfu;s :
lwph I lwph II
OH
CH2OH
(P) (1) Br / CS (1)
22 
 OH
( 2) (CH3 )2 SO 4 / OH
NH2 OCH3
(1) NaNO / HCl

(Q) 
2
 (2)
( 2) H2O, 283 K
OCH3 OH
OH OH

(1) CHCl / O H
(R)   3 
 (3)
( 2) H2O
(3 ) NaBH 2
OH
Br OCH 3
(1) Br / Fe
(S)  
2
 (4)
( 2) Mg / Ether
(3 ) O2
( 4 ) H2O Br
PAGE NO.-89
dksM :
P Q R S P Q R S
(A) 4 2 3 1 (B) 3 1 4 2
(C) 4 2 1 3 (D) 2 4 1 3
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Topic: C = C/CC dk vkWDlhdkjh fo[k.Mu
KMnO4 rFkk K2Cr2O7 izcyre vkWDlhdkjd vfHkdeZd gksrs gSaA ;s C=C ;k CC dks iw.kZ:i ls rksM+rs gS rFkk C=C ;k CC
dh lajpuk ds vkèkkj ij vkWDlhd`r mRikn tSls vEy rFkk dhVksu cukrs gSA vkWDlhdkjh vfHkdeZd (O.A) }kjk C=C ;k CC
dk vkWDlhdkjh fo[k.Mu fuEu vkWDlhdkjh inkFkZ }kjk gksrk gSA
(a) KMnO4 (b) K2Cr2O7 or CrO3/H (c) O3/H2O ;k O3/H2O2
lkekU; vfHkfØ;k %
O.A. O.A.
 
O.A. O.A.
 + CO2+ H2O  2RCOOH
O.A.
 + CO2 + H2O
mnkgj.k %
O.A. O.A.
  + H2O
O.A. O.A.
 + CO2+ H2O  2CH3COOH
O.A.
 + CO2+H2O
uksV % 1. ,Ydhu o ,YdkbZu tks =CH2 ;k C–H j[krs gS tks vkWDlhdkjh vfHkdeZd KMnO4 rFkk K2Cr2O7 ;k CrO3/H+
ds }kjk CO2 ds :i esa ,d vkWDlhdkjh mRikn nsrs gSA
O.A.
2. HCOOH (QkfeZd vEy) ;k H2C2O4 (vkDtsfyd vEy)  CO2H2O
K Cr O
11. 2 2
7
 P ; mRikn gS :
(A) CH3–CH2–CHO (B) (C) CH3–CH2–COOH (D) CH3–COOH
12. fuEu vfHkfØ;k esa dkSu lk mRikn izkIr gksrk gS \

KMnO / H

4


OH
(A) (B) (C) (D) O
OH
O
KMnO / H
13. A  4
 CH3COOH + CH3CH2COOH. ,YdkbZu 'A' gks ldrh gS%

(A) CH3–CH=CH–CH3 (B) CH3–CC–CH3
(C) CH3–CH=CH–CH2–CH3 (D) CH3–CC–CH2–CH3
PAGE NO.-90
+
14. fuEu esa ls dkSulh ,Ydhu KMnO4 / K2Cr2O7 /H ds lkFk vfHkfØ;k djds vkWDlhdkjh mRikn ds :i esa CO2 nsrh
gSA
(A) CH3–CH=CH–CH3 (B) CH3–CH=CH2
(C) (D)

One or more than one choice Objective Q.1 to Q.5 (4 marks, 2 min.) [15, 10]
Matching List Type (One Option Correct) ('–1' negative marking) Q.12 (4 marks, 2 min.) [03, 02]
1. fuEu esa ls fdl vfHkfØ;k esa iSjk czkseksfQukWy eq [; mRikn ds :i esa curk gSA
NH2 OH CH3–C–Cl / Pyridine
NaNO /HCl Hkki
 O Br2 ty ruq H2SO4 /
(A) 
2
 (B)    
Br
Br OH
1 rqY;kad NaOH Sn/HCl NaNO /H SO CuBr/HBr

(C) 
 (D)  
2 2 4
 
Br NO2
2. izkFkfed (1º) ,ehu lewg fuEu esa ls fdlesa cusxk %
NaHS Br /KOH
(A) 
 (B) 
2

CH NH /Cu O/ H2O

(C) 
3 2 2

 (D)  
3. fuEu vfHkfØ;k esa vfHkdeZd gS \
(a) (b) (c) (d) (e)

  
    
 
Cl / Fe 4 HNO  H SO , 
KCN NH HS NaNO / HCl
   
2
(A) 
2 3 2 4
 
(a) (b) (c) (d) H2O/ (e)
.
HNO3  H2SO4 ,  NH4HS NaNO2 / HCl, H2O/ Sn / HCl CO2 / NaOH/ 

(B)        
(a ) (b) (c) (d) (e)
HNO  H SO
2 Sn / HCl (i) Cl / Fe Cl / Fe KCN
(C) 
3 2 4
    
2
 

(a ) (ii) NaOH/  (c ) ( d) (e) H3O 
(b)
HNO3  H2SO4 ,  NH4HS NaNO2 / HCl, H2O/ Sn / HCl KCN

(D)       
(a ) (b) (c) (d) (e) H3O 
PAGE NO.-91
4. vfHkfØ;k esa izkIr gksus okys mRikn ds fo"k; esa fuEu esa ls dkSulk fodYi lgh gS
NaNO / HCl H O / rki ( X) / OH  ( ruq )


2
 (X) 2 
 (Y)  (Z)
(0  5C)
KI
(A) X   (B) Z =

(C) Y (D) Y =
5. ,sjkseSfVd ;kSfxdksa esa MkbZ,tks;qXeu vfHkfØ;k ,d bysDVªkWuLusgh izfrLFkkiu vfHkfØ;k gksrh gSA fuEu esa ls dkSulh
vfHkfØ;k esa oy; izfrLFkkiu MkbZ,tks;qXeu vfHkfØ;k ds fy, vf/kd mi;qDr gS \
(A) + (B) +
(C) + (D) +
vuqPNsn # (Q.6 ls 8)
NH2
+ CuCN H O
HNO 3 Fe / H NaNO
  X    2      3 
 'Z'
HCl 
+
CH3 Y CH3
+
Fe / H NaNO CuBr
W    2    
 ' V '
HBr 
6. ;kSfxd 'V' gS
CH3 CH3 CH3 CH2Br
Br
(A) (B) (C) (D)
Br
Br
7. ;kSfxd 'X' rFkk 'Y' gS&

(A) eè;ko;oh (B) Jà[kyk leko;oh (C) fLFkfr leko;oh (D) fØ;kRed leko;oh
8. ;kSfxd 'Z' gS
CH3 CH3 CH3 CH3
COOH CN
(A) (B) (C) (D)
COOH CN
PAGE NO.-92
(i) Conc .HNO3  Conc .H2SO 4

(ii) Sn / HCl
9.           mRikn.
(iii) Br2 / H2O
(iv ) NaNO2  HCl (0 5C)
( v ) Cu2Br2  HBr
vfUre mRikn esa mifLFkr gSykstu ijek.kqvksa dh la[;k D;k gksxh \
10. tc C8H9NO v.kqlw=k okys 1° ,ekbZM ¼csUtsuksbM½ ds feJ.k dh vfHkfØ;k Br2/NaOH ds lkFk djkrs gS] rks fdrus
1 ,ehu mRikn ds :i esa izkIr gksrs gS %
11. A esa fdrus ik¡p lnL;h oy; gS\
NH2
Aq.NaNO2
  A
HCl (0C)
NH2
12. lwph I (vfHkfØ;k) dks lwph II (mRikn) ds lkFk lqesfyr dhft, rFkk lwphc) fd;s x;s dksM ds vk/kkj ij lgh mÙkj
dkSulk gSA
lwph-I lwph-II
(P) QhukWy + NaOH + C2H5I (1) fQukWY¶FkSyhu
(Q) QhukWy + NaOH +CHCI3 (2) lSfyflfyd vEy
(R) QhukWy + FkSfyd ,ugkbMªkbM + lkUnz H2SO4 (3) ,uhlkWy
(S) QhukWy + CO2 + NaOH (4) lSfyflysfYMgkbM

dksM :
P Q R S P Q R S
(A) 1 2 3 4 (B) 4 3 2 1
(C) 3 4 1 2 (D) 4 3 1 2
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry cs;j&foyxj vkWDlhdj.k
ijkWDlh vEy dh lkekU; lajpuk (RCO3H) gksrh gSA ;g vkisf{kd :i ls vLFkk;h gksrs gS rFkk vklkuh ls
uotkr O ns nsrs gSA vr% ;g vkWDlhdkjd inkFkZ dh rjg dk;Z djrs gSA ;g dhVksu dks ,LVj esa ifjofrZr dj nsrs gSA
lkekU; vfHkfØ;k,sa :
O. A.
 
O. A.
 
foLFkkiu dh ojh;rk (O xzg.k djus dh izo`fr)

LFkkukUrj.k {kerk : –H > –Ph > –Et > –Me
O.A. = vkDlhdj.k vfHkdeZd fuEu es ls dksbZ Hkh vkDlhdkjd vfHkdeZd ds :i es ç;qDr fd;k tk ldrk gSA
CO3H
–
(a) = m-CPBA (esVk Dyksjks ijcsUtksbd vEy)

–
Cl
(b) CH3CO3H = PAA (ij&,sflfVd vEy)
PAGE NO.-93
m-CPBA
mnk--1: CH3—C—CH3 CH 3—C—O—CH 3
O O
mnk--2:
mnk--3:
13. fuEufyf[kr vfHkfØ;k ds fy, dkSulk vfHkdeZd ç;qDr fd;k tkuk pkfg,A
(A) PhCOOOH (PBA) (B) CH3COOOH (PAA)

(C) m-Dyksjks ijcsUtksbd vEy (m-CPBA) (D) mijksDRk lHkh
14. fuEUkfyf[kr vfHkfØ;k ds fy, dkSulk vfHkdeZd ç;qDr fd;k tkrk gSA

vfHkdeZd

(A) KMnO4 / H+ (B) K2Cr2O7 / H+
(C) m-Dyksjks ijcsUktksbd vEy (m-CPBA) (D) CrO3 / H+
15. nh xbZ vfHkfØ;k ds fy,] fuEu es ls dkSulk eq[; mRikn çkIr gksxk \
(A) (B) (C) (D) buesa ls dksbZ ugh
16. nh xbZ vfHkfØ;k ds fy,] fuEu es ls dkSulk eq[; mRikn çkIr gksxk \
(A) CH3CHO (B)
(C) (D)

1. tc csatfYMgkbM dks CH3MgBr ds lkFk vfHkÑr fd;k tkrk gS ,oa blls izkIr ;ksxkRed mRikn dk vEyh; ty
vi?kVu fd;k tkrk gS rks fuEu esa ls dkSulk ;kSfxd izkIr gksrk gS %
(A) f}rh;d ,Ydksgy (B) ,d izkFkfed ,Ydksgy
(C) fQukWy (D) r`rh;d C;wfVy ,Ydksg y
2. fuEu esa ls dkSulk@dkSuls dkcksZfuy ;kSfxd mi;qDr fxzU;kj vfHkdeZd ds lkFk fØ;k djus ij 2-QsfuyC;wVsu-2-vkWy
cuk ldrk@ldrs gSA
(A) CH3–CO–CH2–CH3 (B) Ph–CO–CH3
(C) Ph–CO–CH2–CH3 (D) mijksDr lHkh
PAGE NO.-94
3. fuEu esa ls dkSu&dkSu lgh gSa \
H O/ H
(A) CH3–CH2MgBr + HCHO  CH3–CH2–CHO
2
DO
(B) CH3–CH2–CHO + LiAlH4   CH3–CH2–CHD–OH
2
HO
(C) CH3–CH2–CHO + NaBD4   CH3–CH2–CHD–OH
2
H SO
(D) CH3–CH2–CHO + NaCN  
2 4
4. ,lhVsfYMgkbM dh gkbMªkstu lk;ukbM ds lkFk vfHkfØ;k ds i'pkr~ ty vi?kVu }kjk ,d ;kSfxd curk gS , tks
n'kkZrk gS
(A) izdkf'kd leko;ork (B) T;kferh; leko;ork
(C) e/;ko;ork (D) pyko;ork
5. fuEu esa ls dkSUklk fxzU;kj vfHkØed ds lkFk vfHkfØ;k ugh djrk gSA
(A) (B) D2O (C) CH2=CH2 (D) fQukWy
6. fuEu esa ls ;kSfxdksa dk dkSulk ;qXe SN2 Th vfHkfØ;k ugh n'kkZ ldrk gS\
(A) CH3COOH & CH3COCl (B) CH3COOCOCH3 & CH3COOCH3
(C) CH3COOCH3 & CH3COCH3 (D) CH3COOH & C2H5COOC2H5
7. fuEu esa ls dkSulh vfHkfØ;k mfpr ugh gS\

(A) CH3COOH + PCl3 CH3COCl + H3PO3
(B) CH3COCl + CH3COONa CH2COOCOCH3 + NaCl
(C) CH3COOCOCH3 + C2H5ONa CH3COOC2H5 + CH3COONa
(D) CH3CONH2 + C2H5ONa CH3COOC2H5 + NaNH2
8. fuEu vfHkfØ;k vuqØe esa vfUre mRikn P + Q gS %
O
||
PCl3
CH3 – C – OH  CH3COONa C2H5ONa
   P + Q
(A) CH3COOCOCH3 + C2H5ONa (B) CH3COOC2H5 + CH3COONa
(C) CH3–COOCl + CH3COONa + C2H5ONa (D) CH3COOCOCH3 + CH3COONa
9.
(X)
;kSfxd X, SN2 Th vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gksrk gS] tc P gS&
(A) –CH3 (B) –Br (C) –OCH3 (D) –NO2
10. ; Z ugha gks ldrk gS&
(A) PCl5 (B) PCl3  (C) SOCl2 (D) SO2Cl2
H O
11. 2 A + B
A rFkk B Øe'k% gSa&

18 18
(A) CH3CH2COOH & C2H5 OH (B) CH3CH2COONa & C2H5OH
18 18
 (C) CH3CH2 COONa & C2H5OH (D) CH3CH2 COONa & CH3CH2ONa
PAGE NO.-95
12. fuEu esa ls dkSulk vEy ,LVjhdj.k vfHkfØ;k ds izfr lokZf/kd fØ;k'khy gS \
(A) Me–COOH (B) n-PrCOOH  (C) Me3CCOOH (D) Et3CCOOH
13. CH3COOH ds lkFk ,LVjhdj.k dh nj lokZfèkd gksxhA
(A) (B) (C) (D)
14. fuEu vfHkfØ;k esa eq[; mRikn ¼,LVj½ gSaA
H SO
+ 2 
4

(A) ,d ,dy f=kfoe leko;oh ¼izdkf'kd lfØ;½

(B) foofje leko;fo;ksa dk ,d feJ.k ¼nksuksa izdkf'kd lfØ;½
(C) ,d jSflehd feJ.k ¼izdkf'kd fuf"Ø;½
(D) pkj f=kfoe leko;oh;ksa dk ,d feJ.k ¼nks jSflfed feJ.k½
15. ;fn isUVsu-2-vksu dk NaBH4 dh mifLFkfr esa vip;u ds ckn D2O }kjk ty vi?kVu ls izkIr mRikn gksxk:
(A) CH3–CH(OD)CH2CH2CH3 (B) CH3CD(OH)CH2CH2H3
(C) CH3CH(OH)CH2CH2CH3 (D) CH3CD(OD)CH2CH2CH3
16. izksisukWu dks fuEu esa ls fdlds lkFk xeZ djus ij curk gS\
(A) CH3MgI rFkk D2O (B) LiAlH4 rFkk D3O+ (C) LiAlD4 rFkk H3O+ (D) NaBH4 rFkk D3O+
(i) CH3MgBr ( vkfèkD;)

17. Qsfuy ,flVsV   P', 'P' gks ldrk gS

(ii) H
Ph Me Ph Ar Ph Me
(A) (B) (C) (D)
H OH
Me OH Et OH
18. fuEu esa ls tyvi?kVu vfHkfØ;k ds fy;s lcls de fØ;k'khy gksxkA
(A) (B)
(C) (D)
19. vEyh; ty vi?kVu fuEu esa ls lcls de gksrk gS

O O
O – COR O – COR O–C–R
O–C–R
(A) (B) (C) (D)

NO2
| |
NO2 OC2H5
O O
– –
20. vfHkfØ;k] R – C + Nu R–C +X
X Nu
vR;Ur rhoz gksxh tc X gksxk :
(A) Cl (B) Br (C) I (D) F
PAGE NO.-96
21. 6-czkseks-2-gsDlsuksu dks THF dh mifLFkfr es eSfXuf'k;e ds lkFk fØ;k djkus ij X ,d eq[; mRikn ds :i es curk
gSA
22. dqN vfHkfØ;kvksa ds vadu fuEu izdkj fn;s x;s gS vfHkfØ;k dk dkSulk vad SN2Th vfHkfØ;k gS\
(1) CH3COOH + NaOH CH3COONa + H2O
(2) CH3COOH + SOCl2CH3COCl + SO2 + HCl
AlC·KOH
 
(3) 
(4) CH3Br + NaOH CH3OH + NaBr
23. +   + HCl
vfHkfØ;k izdkj ds vadu fuEu izdkj fn;s x;s gSA dkSulk vad mijksDr vfHkfØ;k ds fy, fn;k x;k gS \
(1) SN2Th vfHkfØ;k (2) ukfHkdLusgh ;ksxkRed vfHkfØ;k
(3) ;ksxkRed vfHkfØ;k (4) foyksiu vfHkfØ;k
24. ,LVj A
,LVj 'A' esa fdrus ijek.kq pfØ; ra=k esa mifLFkr gS \

25. fdrus fxzxukj vfHkdeZd 1 eksy ,flfVy DyksjkbM ls fØ;k djus ds fy, vko';d gS\
PAGE NO.-97
ANSWERS KEY
PHYSICAL / INORGANIC CHEMISTRY

DPP No. # A1
8. 3 9. 5 10. –3 11. 6
12. (A – p,q) ; (B – p,q) ; (C – s) ; (D – r)
DPP No. # A2
21. 4 22. 2 23. 3 24. 2 25. 29 k Cal
DPP No. # A3
6. 01 7. 02 8. 5 9. 6 10. 4
11. 4 12. [A – p,q,r,s] ; [B – q, r] ; [C – q, s] ; [D – p].
DPP No. # A4
17. 6 18. 9 19. 2 20. 6 21. 5
DPP No. # A5
11. 06 12. 0 13. 2
14. [A - p,q,s]; [B - q]; [C - r]; [D - q]
DPP No. # A6
17. 85% 18. 2% 19. 7 20. 14 g 21. 6
DPP No. # A7
4. 4 5. 4 6. 2 7. 7
8. (a) Sodium pentacyanido-C-nitrosoniumferrate(II) (Sodium nitroprusside-diamagnetic)

(b) Bis (dimethylglyoximato) nickel (II)
(c) Ammonium dinitrosyltetrathiocyanato-S chromate (III)
(d) Diaquadiiodidodinitrito-O palladium (IV)
(e) Tetraamminechloridothiocyanato-N cobalt (III) ion
(f) Potassium tetraoxidoferrate (IV)
(g) Potassium tetraazidocobaltate (II) [N3¯ is azide]
(h) Dichloridobis(triphenylphosphine) nickel (II)
PAGE NO.-98
(i) Tris(acetylacetonato)chromium (III) [(acac)¯ is ]
(j) Tetrakis(pyridine)platinum(II) tetrachloridoplatinate (II)
9. (a) Fe2+ + 6H2O + Cl¯  [Fe(H2O)6]2+ Cl¯

Cation is a complex ion and carries + 2 charge, hence its structure is [FeII(H2O)6]Cl2
Oxidation state of the metal ion has been given in the structure. Students may omit it.

(b) K + Ag3+ + 4F¯  K+ [AgF4]¯ anion is a complex K+ [AgIIIF4]¯
cation
(c) [TiIICl5]3– (d) [CoIII(NH3)4Cl2]Cl (e) [AgI(CN)2]¯ (f) [Ni(NH3)2Cl4]2–
(g) [CuII(en)3]SO4 (h) Na[AllII(H2O)2(OH)4] (i) [CrIII(NH3)Cl(en)2]SO4 (j) K2[ZnII(CN)4]
10. (A) – p,q,r ; (B) – p,r ; (C) – p,q,r ; (D) – p,q,s,t
DPP No. # A8
17. 6 18. 3 19. 8 20. 22 m mol 21. 12
DPP No. # A9
6. 6 7. 3 8. 00 9. 8 10. 5
11. 9 12. 5 13. 5
14. [A - r]; [B - p]; [C - p,q,s]; [D - q,p].
DPP No. # A10
21. 6 22. 2 23. 6 kJ 24. 8 25. 8
15. 34 16. 6 17. 09 (i, ii, iii, v, vi, vii, viii, ix, x) 18. 2
DPP No. # A12
7. 20 8. 03 9. 05 10. 2 11. 8
12. 8 13. [A – p,q,r]; [B – p]; [C – p,r]; [D – s,r]
DPP No. # A13
7. 02 8. 07 9. 21 10. 8 11. 2
12. 34 13. (A) q,r ; (B) p,s ; (C) q ; (D) q,r
DPP No. # A14
17. 6 18. 3 19. 5 20. 22.0 kcal 21. 6
PAGE NO.-99
DPP No. # A15
8. 1 9. 6 10. 83.9 11. 5 12. 90.00
13. 7 14. 24 15. 81 16. 02
DPP No. # A16
7. 3 8. 5 9. 90 10. 5 11. 1
12. 67.20 13. (A)  p, r ; (B)  q, s ; (C)  p, r ; (D)  q, s
DPP No. # A17
21. 3 22. 3 23. 7 24. 4 25. 6
DPP No. # A18
9. 1 10. 5 11. 3 12. 5
13. (A)  q, r ; (B)  p, s ; (C)  q ; (D)  q, r
DPP No. # A19
18. 9 19. 5 20. 3 21. 6 22. 1
DPP No. # A20
5. 27 6. 8 × 10–3 lt. 7. 6.4 × 10–4 cm 8. 1 9. 7
10. 38 11. 6 12. 6
13. (A - p, r); (B - r); (C - q, s); (D - p, q, r, s).
ORGANIC CHEMISTRY
DPP No. # A1
21. 1 22. 3 23. 5 24. 2 25. 4
DPP No. # A2
10. 6 (2, 3, 4, 5, 6, 8) 11. 3 12. 36
13. (A)  (q, r, s); (B)  (q, r); (C)  (q, r, s); (D) (s)
DPP No. # A3
17. 5 18. 5 19. 2 20. 8 21. 0
PAGE NO.-100
DPP No. # A4
8. 6 9. 4 10. 6 11. 4
12. (A)  p,q ; (B)  p,q ; (C)  p, r, s ; (D)  p,r
DPP No. # A5
17. 8 18. 4 19. 2 20. 8 21. 2
DPP No. # A6
19. 2 20. 60 21. 6 22. 2
DPP No. # A7
9. 2 2 10. 08 11. 2 12. 7
13. (A – p,t) ; (B – q,s) (C – p,t) ; (D – q,r)
14. (A)  (p, q) ; (B)  (p, s) ; (C)  (p, r) ; (D)  (p, s)
DPP No. # A8
21. 3 22. 8 23. 4 24. 6 25. 5
DPP No. # A9
17. 4 18. 4 19. 7 20. 3 21. 6
DPP No. # A10
9. 4 10. 9 12. (A – q , s) ; (B – p, q) ; (C – q) ; (D – p, r)
DPP No. # A11

17. 03 18. 94 19. 3 20. 3 21. 1
DPP No. # A12
7. 3 8. 7 9. 5
DPP No. # A13
9. 4 10. 4 11. 1
DPP No. # A14
21. 5 22. 2 23. 1 24. 5 25. 2
PAGE NO.-101
PREFACE
This book contains the Daily Practice Problems (DPPs) designed for the aspirants
JEE(Main+Advanced). It is a collection of problems (Physics, Chemistry & Mathematics in
separate booklets) from multiple topics to understand the application of concepts learned in
theory. Each DPP is kind of a timed test with marking scheme and prescribed time to be spent
on each problem. It is according to the latest pattern of JEE(Advanced) and serves as a great
tool for the students to simulate examination conditions at home. It enables a student to
practice time management while solving a problem which helps him/her to better prepare for
the target exam.
Every effort has been taken to keep this book error free, however any suggestions to improve
are welcome at smdd@resonance.ac.in.
(i)
DPP
DAILY PRACTICE PROBLEMS
CHEMISTRY
TARGET: JEE (Main + Advanced)
COURSE : VIJETA (01&02JPB & 03&04JPAB)
Physical / Inorganic Chemistry DPPs (A1 to A20)
Organic Chemistry DPPs (A1 to A14)
INDEX
PHYSICAL / INORGANIC CHEMISTRY DPPS
1. DPP No. A1 01 – 03
2. DPP No. A2 03 – 05
3. DPP No. A3 06 – 09
4. DPP No. A4 09 – 11
5. DPP No. A5 11 – 14
6. DPP No. A6 14 – 16
7. DPP No. A7 16 – 18
8. DPP No. A8 18 – 21
9. DPP No. A9 21 – 23
10. DPP No. A10 23 – 24
11. DPP No. A11 25 – 27
12. DPP No. A12 27 – 29
13. DPP No. A13 29 – 32
14. DPP No. A14 32 – 34
15. DPP No. A15 34 – 36
16. DPP No. A16 36 – 38
17. DPP No. A17 39 – 41
18. DPP No. A18 41 – 43
19. DPP No. A19 44 – 46
20. DPP No. A20 47 – 49
(ii)
ORGANIC CHEMISTRY DPPS
1. DPP No. A1 50 – 52
2. DPP No. A2 52 – 54
3. DPP No. A3 54 – 57
4. DPP No. A4 58 – 59
5. DPP No. A5 60 – 63
6. DPP No. A6 63 – 66
7. DPP No. A7 66 – 69
8. DPP No. A8 69 – 71
9. DPP No. A9 71 – 74
10. DPP No. A10 74 – 80
11. DPP No. A11 80 – 83
12. DPP No. A12 83 – 86
13. DPP No. A13 86 – 89
14. DPP No. A-14 89 – 92
ANSWER KEY 93 – 97
NOTE:
  Marked Questions may have for Revision Questions.
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All rights reserved. Any photocopying, publishing or reproduction of full or any part of this study material is strictly prohibited. This material belongs
to enrolled student of RESONANCE only. Any sale/resale of this material is punishable under law, subject to Kota Jurisdiction only.
(iii)

1. Solubility of BaSO4 in pure water is 4 × 10–5 M. Solubility of BaSO4 in 0.01 M BaCl2 solution will be :
(A) 2 × 10–3 M (B) 1.6 × 10–5 M (C) 1.6 × 10–7 M (D) 4 × 10–5 M
(E) 8 × 10–5 M
2. Select the correct statement(s) :
(A) The value of spin only magnetic moment of Co3+ ion (in BM) = 24
(B) The number of radial nodes in a 3p-orbital = 1
(C) The number of electrons with (m = 0) in Mn2+ ion = 11
6h
(D) The orbital angular momentum for the unpaired electron in V4+ =
4
3. Which of the following species are correctly matched with their shapes according to the VSEPR theory?
(A) BrF6+  octahedral. (B) SnCl5–  trigonal bipyramidal.
(C) ClF2  linear.
–
(D) IF4+  see – saw.
4. Which of the following statements regarding compressibility factor (Z) is/are correct:
(A) In the lower pressure region, value of Z initially decreases on increasing pressure, however H2 and
He gases are exception to this.
(B) Z for an ideal gas is greater than one.
(C) Z for a non-ideal gas can be greater than or less than unity depending on temperature and
pressure.
(D) When Z < 1, intermolecular attraction dominates over intermolecular repulsion.
5. For fixed amount of an ideal gas, three processes are carried out via AB, APB & AQB. Select correct
options:
(A) SAB does not depend upon the type of process.

(B) If AB path is a reversible isothermal process, then SAB = QAB/T, where QAB is heat involved in
process AB and T is the temperature for the isothermal process in K.
(C) SAB via AQB > SAB via APB.
(D) SAB via AQB < SAB via APB.
6. Equal volumes of following solutions are mixed, in which case the pH of resulting solution will be
average value of pH of two solutions.
(A) pH = 2 HCl & pH = 12 NaOH
(B) pH = 2 HCl & pH = 4 HCl
(C) pH = 2 HCN & pH = 12 NaOH (Ka of HCN = 10–10)
(D) pH = 5 CH3COOH & pH = 9 NH3(aq), Ka (CH3COOH) = Kb (NH3 (aq))
PAGE NO.-1
7. A solution is made by dissolving both Ag2CrO4 and Ag2C2O4 until saturation is reached with respect to
both the salts.
Given Ksp (Ag2C2O4) = 10–12
Ksp (Ag2CrO4) = 2 × 10–12
1
Given :  36  3  3.3
Which of the following statement(s) is/are correct with respect to above given information?
(A) In the final solution [Ag+] and [CrO24 ] are 1.8×10–4 M and 0.6 × 10–4 M respectively.
(B) In the final solution [Ag+] and [CrO24 ] are 0.9×10–4 M and 0.6 × 10–4 M respectively.
(C) In the final solution [Ag+] and [C2O24 ] are 3.6×10–4 M and 0.3 × 10–4 M respectively.
(D) In the final solution [Ag+] and [C2O24 ] are 1.8×10–4 M and 0.3 × 10–4 M respectively.
8. How many of the following contain peroxide species?

(i) CO2 (ii) NO2 (iii) BaO2 (iv) PbO2 (v) KO2 (vi) Na2O2
(viii) MnO2 (viii)CrO5
9. How much of 0.3 M NH4OH should be mixed with 30 ml of 0.2 M solution of NH4Cl to give a buffer of
pH = 8.65 . Given pkbNH OH = 4.75 and antilog ( 0.6) = 0.25 .
4
10. Determine G in Joule for the following process for conversion 414 g of H2O(s) to H2O()
H2O(s)  H2O()
(6 atm, 273 K) (6 atm, 273 K)
Given : density of H2O(s) = 0.92 g/cm 3, density of H2O() = 1 g/cm3
Give your answer after dividing it by 6 (Take 1 atm L = 100 J)
11. How many of the following statements are correct ?
(a) BeO is amphoteric in nature.
(b) LiHCO3 is not found in solid state.
(c) K2O2 is diamagnetic but KO2 is paramagnetic.
(d) White phosphorous react with castic soda and gives phosphine gas.
(e) AlCl3 is soluble in excess of NaOH and form sodium meta aluminate.
(f) Anhydrous potassium nitrate on heating with potassium metal gives potassium oxide and nitrogen
gas.
(g) Lithium chloride is highly soluble in water.
(h) Hydrated magnesium chloride on heating in dry air gives anhydrous MgCl 2.
12. Match the following for a system involving fixed amount of ideal gas.
Column I Column II
(A) Cyclic process (p) H = 0 & U = 0
(B) Reversible isothermal process (q) Q = –W
(C) Reversible adiabatic process (r) W = 0 and Q = U
(D) Isochoric process (s) Q = 0 and dH = Vdp

Henry’s Law :
When a gas is dissolved in a solvent the following equilibrium is established.
Gas + Solvent solution
The relationship between solubility of gas and its pressure is expressed in terms of Henry’s law, which states
that the amount of gas dissolved in the given amount of a solvent at any temperature is proportional to pressure
of the gas above solvent. It may also be stated as, at constant temperature the mole fraction of gas dissolved in
a solvent is directly proportional to the partial pressure of gas. Let x be the mole fraction of a gas dissolved in a
definite amount of liquid at temperature T. If the partial pressure of gas over the solvent patm then x  P; x =
KHP or P = KH' X KH = Proportionality constant or Henry constant.
PAGE NO.-2
Characteristics of Henry law constant (KH)
(i) Unit same as those of pressure (mol/ L atm, L atm/mole)
(ii) Different gas have different value of KH
Gases KH(mol/I.atm)
O2 1.3 × 10–3
N2 7 × 10–4
CO2 2.3 × 10–2
H2 8.5 × 10–4
(iii) The KH values of a gas is different in different solvent and it increase with
the increase in temperature.
(iv) Higher the value of KH of a gas lower will be its solubility
Application of Henry’s law
(i) To increase the solubility of CO2 in soft drinks and soda water the bottle is sealed under high pressure.
(ii) At high altitude the partial pressure of oxygen is less than that at the ground level. This leads to low
concentration of oxygen in the blood and tissue of people living at high altitudes or climbers. Low blood
oxygen causes climbers to become weak and unable to think clearly, symptoms of a condition known
as anoxia
13. At 298 K and 1 atm pressure solubility of N2 in water was found to be 6.8 × 10–4 mol/L. If partial
pressure of N2 is 0.78 atm, then what is the concentration of N2 dissolved in water under atmospheric
conditions
(A) 2.4 × 10–3 m (B) 5.3 × 10–4 m (C) 9 × 10–4 m (D) 16.5 × 10–4 m
14. Solubility curves of four ionic salts X, Y, Z, W are given below : In
which case the value of Hsol. < 0
(A) X
(B) Y
(C) Z
(D) W
15. The henry’s law constant s for H2 O2 and CO2 in water are 1282 L atm/mol, 769.2 Latm/ mol, 29.41 L
atm/ Mol respectively which of these gas has highest concentration in a sample of water at 25 0C when
pressure over water is 1 atm.
(A) H2 (B) O2 (C) CO2 (D) None of these
16. The Henry’s law constant for the solubility of N2 gas in water at 298 K is 2.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The no. of moles of N2 from air dissolved in 5 moles of water of 298 K and 3
atm pressure is:
(A) 2 × 10–5 (B) 6 × 10–5 (C) 9 × 10–4 (D) 9 × 10–5
17. Select correct statements :
(A) Gases which have high value of van der Waals constant ‘a’ are easily liquefied
(B) Easily liquefiable gases are water soluble
(C) Ions forming gases in a solvent are soluble in that solvent
(D) Under same conditions, NH3 has low solubility than that of CO2 .

1. 1 mole of an ideal gas is expanded isothermally and reversibly from 10L to 100L. Which of the following
are correct for the process :
(A) T  0 (B) H  0
(C) heat supplied (q)  0 (D) E  0
PAGE NO.-3
2. The correct figure representing isothermal and adiabatic expansions of an ideal gas from a particular
initial state is :
(A) (B) (C) (D)
3. Select the correct option(s) :

S1 : Specific volume and molar heat capacity are intensive parameters.
S2 : Change in internal energy for an ideal gas for an isobaric process is expresed as
U = nCV (T2 – T1), where the terms used have their usual meaning.
S3 : If the path of an irreversible process is reversed, then both system and surroundings shall be
restored to their orginal states.
S4 : Less work is done on the gas in adiabatic reversible compression than in isothermal reversible
compression, if compression is performed between same initial and final volumes.
(A) T T T F (B) F F T T (C) F T F T (D) T T F F
4. Consider the general hypothetical reaction
A(s) 2B(g) + 3C(g)
If the concentration of C at equilibrium is doubled, then after the equilibrium is re-established, the
concentration of B will be
(A) two times the original value (B) one half of its original value
1
(C) times the original value (D) 2 2 times the original value
2 2
5. For the process H2O() (1 bar, 373 K)  H2O(g) (1 bar, 373 K), the correct set of thermodynamic
parameters is:
(A) G = 0, S = + ve (B) G = 0, S = – ve
(C) G = + ve, S = 0 (D) G = – ve, S = + ve
6. XeF6 + SiO2  XeO3 (x) + SiF4 (y)
The hybridisation states of central atoms in the products (x) and (y) are respectively :
(A) sp3 and sp3d (B) sp2 and sp3 (C) both sp3 (D) both sp3d
7. Which of the following salts undergoes anionic hydrolysis?
(A) CuSO4 (B) NH4Cl (C) FeCl3 (D) Na2CO3
Real gas
8. P Ideal gas
V
Which of following statement is incorrect regarding above P-V curve ?
(A) At higher pressure region gas shows positive deviation.
(B) At low pressure region measured and calculated volumes approach each other.
(C) In high pressure region Z > 1 hence gas is less compressible than ideal gas.
(D) In low pressure region Z < 1 hence gas is less compressible than ideal gas.
9. Which of the following figures represents the variation of particle momentum and associated de-Broglie
wavelength.
(A) (B) (C) (D)
PAGE NO.-4
10. Zinc and hydrochloric acid react according to the reaction :
Zn(s) + 2HCl(aq.)  ZnCl2(aq.) + H2(g)
If 0.3 mole of Zn are added to hydrochloric acid containing 0.52 mole HCl, how many moles of H 2 are
produced:
(A) 0.26 (B) 0.52 (C) 0.14 (D) 0.30
11. Property of the alkaline earth metals that increases with their atomic number is :
(A) ionisation energy (B) solubility of their hydroxides
(C) solubility of their sulphates (D) electronegativity
12. Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be:
(A) 3.98 × 108 (B) 3.88 × 106 (C) 3.68 × 10–6 (D) 3.98 × 10–6
13. Bond angle of 109º 28' is found in:
(A) NH3 (B) H2O (C) CH3+ (D) NH4+
14. What is the mole ratio of benzene (PB0=
150 torr) and toluene (PT0 = 50 torr) in vapour phase if the
given solution has a vapour pressure of 120 torr?
(A) 7 : 1 (B) 7 : 3 (C) 8 : 1 (D) 7 : 8
15. A 0.20 molar solution of a weak monoprotic acid, HA, has a pH of 3.0. The ionization constant of the
acid is :
(A) 5.0 × 10–7 (B) 2.0 × 10–7 (C) 5.0 × 10–6 (D) 5.0 × 10–3
16. The vapour pressure of a pure liquid A is 40 mmHg at 310 K. The vapour pressure of this liquid in a
solution with liquid B is 32 mmHg. Mole fraction of A in the solution, if it obeys Raoult’s law is:
(A) 0.8 (B) 0.5 (C) 0.2 (D) 0.4
17. The azeotropic mixture of water (B.P. = 100ºC) and HCI (B.P. = 86ºC) boils at about 120ºC During
fractional distillation of this mixture it is possible to obtain:
(A) pure HCI (B) pure H2O
(C) pure H2O as well as pure HCI (D) neither pure H2O nor HCI
18. Which is the correct statement for positive deviation of solution.
(A) The energy released in solvation exceeds the energy used in breaking up interactions/
intermolecular forces.
(B) Solute-solvent interaction is weaker than their own interactions.
(C) Volume would contract during formation of solution.
(D) Boiling point of solution will be higher than expected.
19. An azeotropic solution of two liquids has boiling point lower than that of either of the liquids when it
(A) Shows a negative deviation from Raoult's law
(B) Shows no deviation from Raoult's law
(C) Shows positive deviation from Raoult's law
(D) Is saturated
20. For an ideal solution of A and B liquid, when x A = 0.2, total vapor pressure over solution was 560 torr
and partial pressure of A was 80 torr. What will be the composition of vapor when x A = 0.8 ?
1 8 3 9
(A) yA = (B) yA = (C) yB = (D) yB =
7 11 7 11
21. How many bond pairs of electrons are around N in NO3– ?
22. The number of vacant hybrid orbitals which participate in the formation of 3-centre 2 electron bonds i.e.,
banana bonds in diborane structure is :
23. The pH of 0.1 M RCOOH (Ka = 10–5) aqueous solution is :
24. Find the solubility of As2S3 in a10–2M Na2S solution assuming no hydrolysis of cationic or anionic part.
1
Given: Ksp for As2S3 = × 10–24. Report your answer as Y where : solubility (in mol/L) = Y × 10–11.
625
25. Determine the heat of hydrogenation of ethylene from the following data .
Bond Bond energy Bond Bond energy
HH 104 k Cal CC 80 k Cal
CH 99 k Cal C=C 145 k Cal
PAGE NO.-5

1. Which of the following statement (s) is/are true for the solutions of alkali metals and alkaline earth
metals in ammonia () ?
(A) Concentrated solutions of alkali metals in ammonia are copper-bronzed coloured and have a
metallic lusture.
(B) Dilute solutions of alkaline earth metals are bright blue/deep bule black in colour due to the
spectrum from the solvated electron.
(C) Concentrated solutions of the alkaline earth metals in ammonia are bronze coloured.
(D) Evaporation of the ammonia from solutions of alkali metals yields the metal, but with alkaline earth
metals evaporation of ammonia gives hexammoniates of the metals.
2. The pairs of compound which cannot exist together in aqueous solution are :
(A) NaH2 PO4 and Na2HPO4 (B) Na2 CO3 and NaHCO3
(C) NaOH and NaH2 PO4 (D) NaHCO3 and NaOH.
3. Which of the following is(are) true for silicones?
(A) They are stable towards heat.
(B) Their viscosity does not vary significantly with temperature.
(C) They are good conductors of electricity.
(D) They are hydrophilic in nature.
4. If the rms velocity of nitrogen and oxygen molecule are same at two different temperature and same
pressure then
(A) Average speed of molecules is also same.
(B) density (gm/lt.) of nitrogen and oxygen is also equal.
(C) Number of moles of each gas is also equal.
(D) most probable velocity of molecules is also equal.
5. 1 M of glucose (C6H12O6) solution (density = 1.18 g/ml) is equivalent to which of the following solution
(A) % w/w = 18% (solution) (B) 180 g solute per litre solution
(C) % w/v = 18% (solution) (D) 1 molal solution
6. A solution is 0.01M both in Cu2+ and Cd2+ ion. What will be the concentration (in M) of Cd2+ remains in
the solution when 99.9% Cu2+ ion has been ppt. as CuS by addition of S2–?
Given Ksp (CuS) = 8.7 × 10–36
Ksp (CdS) = 3.6 × 10–29
give your answer by multiplying 100.
7. A certain mixture of HCl and CH3COOH is 0.1 M in each of the acids. 20 ml of this solution is titrated
against 0.1M NaOH. By how many units does the pH change from the start to the stage when the HCl
is almost completely neutralised and acetic acid remains unreacted ? Ka for acetic acid = 2 x 105.
8. If the pH of a 0.2 M solution of a weak base BOH is 10.3, then find the volume of 0.4 M HCl solution (in
mL) to be added to 20 mL of above base solution to make the pH of the resulting solution equal to 7.3.
(Take log 2 = 0.3)
9. Calculate the number of hours of service that can be derived from an acetylene lamp containing 1 kg
CaC2 if 60 liter acetylene gas at 1 atm & 27°C is needed for 1 hour. (Report your answer in nearst
integer)
10. 10–2 mole of NaOH was added to 10 litre of water at 25ºC, calculate the pH change.
PAGE NO.-6
11. Liquids A and B form an ideal solution. At a certain temperature the total vapour pressure of a mixture
of A and B is 400 mm. The mole fraction of A in the liquid mixture in equilibrium with the vapour phase
is 0.4. If the vapour pressure ratio (PA0/PB0) for the pure liquids at this temperature is 1/6, what is the
 Partial pressure of A 
 10  in the vapour phase?
 
12. Match the following :
Column  Column 
(A) 120 g CH3COOH in 1 Ltr solution dsol = 1.2 g / mL (p) M = 2
(B) 120 g glucose dissolved in 1 Ltr solution (dsol = 1.2 g/mL) (q) 10% w/w solution
(C) XNH2CONH2 = 1/31 (aquous solution) (r) 12% w/v solution
(D) 19.6 % (w/v) H2SO4 solution (dsolution = 1.2 g/mL) (s) m = 1.85

What is a phase?
 A phase is the form of the matter that is homogeneous in chemical and physical composition.
 Solid, liquid and gases are three different phases. Two immiscible liquids constitute two different phases.
Two miscible liquids constitute only one phase. Two different solids constitute two different phases.
 Allotropes and polymorphs also consitute two different phases. for ex. Red phosphorus and White
phosphorus are different phases, Diamond and Graphite are different phases.
 You can recognise the presence of the different phases because there is an obvious boundary between
them -a boundary between the solid ice and the liquid water, for example, or the boundary between the two
liquids
What is Phase diagram?
 Phase diagram is a graphical representation of the physical states of a substance under different conditions
of temperature and pressure.
 A typical phase diagram has pressure on the y-axis and temperature on the x-axis.
 As we cross the lines or curves on the phase diagram, a phase change occurs.
 In addition, two states of the substance coexist in equilibrium on the lines or curves. These lines of
equilibrium are called phase boundaries.
 Every point in this diagram represents a possible combination of temperature and pressure for the system.
The diagram is divided into three areas, which represent the solid, liquid, and gaseous states of the
substance.
Some important characteristics of phase diagram of a pure substance.

Triple point
The point on a phase diagram at which the three states of matter or three phases coexist: At these points,
lines of equilibrium intersect.
PAGE NO.-7
Critical point
The phase boundary between liquid and gas does not continue indefinitely. Instead, it terminates at critical
point on the phase diagram This reflects the fact that, at extremely high temperatures and pressures, the
liquid and gaseous phases become indistinguishable,[2] in what is known as a supercritical fluid.
 Fusion(melting) (or freezing) curve(BD) – the curve on a phase diagram which represents the transition
between liquid and solid states
 Vaporization (or condensation) curve(BC) – the curve on a phase diagram which represents the
transition between gaseous and liquid states
 Sublimation (or deposition) curve (AB) – the curve on a phase diagram which represents the transition
between gaseous and solid states
 Normal melting and boiling points can be found from the phase diagram by drawing a line across at 1
atmosphere pressure.
Phase diagram of CO2
Give the answer of following question by using above phase diagram of CO2.
13. What kind of phase change will take place if solid S is kept in the open under normal condition?
(A) Sublimation (B) Melting
(C) Evaporation (D) No change
14. Under which condition, are all the three phases of the system S in equilibrium?
(A) T > 304.2k and P > 72.9 atm (B) T = 216 K and P = 5.2 atm
(C) T > 304.2 K (D) P > 72.9 atm
15. Temperature of the system at X1 is increased at constant pressure to reach X4. Which of the following is
incorrect about the phases of the system at different state.
(A) At X1 solid phase exists.
(B) At X2 solid liquid equilibrium phase exists
(C) At X3 solid-liquid gas equilibrium phase exists.
(D) At X4 vapour phase exists.
PAGE NO.-8
16. If the pressure is increased, the melting temperature of solid S will
(A) Not change (B) Increase (C) Decrease (D) Can’t say
17. What happens to the system at X5 if pressure is changed slowly keeping temperature constant?
(A) At a higher pressure, the system will become liquid
(B) At a lower pressure, the system will become liquid.
(C) The system will be in the same phase
(D) None of these

1. In which case van’t Hoff factor is maximum ?
(A) KCl, 50% ionised (B) K2SO4, 40% ionized
(C) SnCl4, 20% ionised (D) FeCl3, 30% ionised
2. Two liquids X and Y are perfectly immiscible. If X and Y have molecular masses in ratio 1:2, the total
vapour pressure of a mixture of X and Y prepared in weight ratio 2:3 should be (PX0 = 400 torr,
PY0 = 200 torr)
(A) 300 torr (B) 466.7 torr (C) 600 torr (D) 700 torr
3. A mixture of two immiscible liquids at a constant pressure of 1 atm boils at a temperature.
(A) equal to the normal boiling point of more volatile liquid
(B) equal to the mean of the normal boiling points of the two liquids
(C) greater than the normal boiling point of either of the liquid
(D) smaller than the normal boiling point of either of the liquid.
4. For a real gas obeying vander waal equation under low pressure conditions, which of the following
graph is correct?
(A) (B) (C) (D)
M
5. The mass of Glucose (C6H12O6) required to prepare 50 mL of its aqueous solution is:
9
(A) 10 g (B) 1 mg (C) 1 g (D) 100 mg
6. For the redox reaction MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O, the correct whole number
stoichiometric coefficients of MnO4–, C2O42– and H+ are respectively :
(A) 2, 5, 16 (B) 5, 2, 8 (C) 2, 5, 8 (D) 5, 2, 16
7. Densities of two gases (having same molar mass) are in the ratio 1 : 2 and their temperatures are in the
ratio 2 : 1, then the ratio of their respective pressure is :
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 2 : 3
8. KO2 is used in oxygen cylinder in space air craft and submarines because it
(A) absorbs CO2 and increase O2 content (B) eliminates moisture
(C) absorbs CO2 (D) Produce O2
9. When borax is dissolved in water :
(A) B(OH)3 is formed only (B) [B(OH)4]– is formed only
(C) both B(OH)3 and [B(OH)4]– are formed (D) [B3O3(OH)4]– is formed only
10. Which statement is incorrect –
(A) Ozone (O3) is a planar molecule. (B) Dioxygen (O2) is a diamagnetic species.
(C) Bond order of N2 is greater than N
2 . (D) C2–2 is more stable than C2.
PAGE NO.-9
11. Which of the following salts is least soluble in water ?
(A) CaF2 : Ksp = 3.9 × 10–11 (B) PbCl2 : Ksp = 1.6 × 10–5
(C) AgCl : Ksp = 1.8 × 10 –10
(D) AgIO3 : Ksp = 3.1 × 10–8
(E) All are equally soluble.
12. Value of azimuthal quantum number for the unpaired electron in vanadium atom (Z = 23) be 'b', then
find the value of (b).
(A) 6 (B) 2 (C) 3 (D) 1
(E) zero
13. The number of completely filled orbitals in 29Cu which have only two nodes is :
(A) 5 (B) 9 (C) 3 (D) 7
14. Which of the following exhibits amphoteric nature ?

(A) Li2O (B) BeO (C) Cs2O (D) BaO
15. The order of p  d interaction in the compounds containing bond between Si/P/S/Cl and oxygen is in
the order.
(A) P > Si > Cl > S (B) Si < P < S < Cl (C) S < Cl < P < Si (D) Si > P > S > Cl
16. Which of the following statement is incorrect ?

(A) Strength of H-bonding : HF > H2O > NH3
(B) Strength of H-bonding : F  H....O  O  H....O  F  H....F
(C) Boiling point : H2 O  H2 Te  H2 Se  H2 S
(D) Dipole moment : HF  H2 O  NH3
17. How many maximum number of atoms lie in the same plane in the sructure of
methylenesulphurtetrafluoride (CH2SF4) ?
18. Calculate the pH at which Mg(OH)2 begins to precipitate from a solution containing 0.10 M Mg2+ ions.
ksp for Mg(OH)2 = 1.0 × 10–11.
19. Heat of neutralization of oxalic acid is – 25.4 Kcal mol–1 using strong base, NaOH. Then, find the
enthalpy change for the given process:
H2C2O4 2H+ + C2O42–
[Take heat of neutralization of strong acid with strong base = – 13.7 Kcal mol–1]
20. Hydrogen gas saturated with water vapour is confined under a piston in a container with confined
volume 10 litres as shown. The container also contains some liquid water. The partial pressure of H 2
over liquid water is 80 cm of Hg column. If now the piston is moved such that confined volume is
doubled, then find final total pressure over water liquid in the container. (aq. tension = 20 cm of Hg
column)
Total pressure in cm of Hg
(Neglect volume of liquid H2O). (Report your answer as y, where y = )
10
21. An organic compound contains 44.44% carbon by mass. If each molecule of the compound weighs
2.25 × 10–22 g, find the number of C-atoms present in one molecule of organic compound.
PAGE NO.-10

I. Non ideal solution
A non-ideal solution is defined as the one which does not obey Raoult’s law. These are divided into two types.
1. Non-ideal positive deviation solution
2. Non-ideal negative deviation solution.
Positive deviation solution Negative deviation solution
(i)  0
PT  XAPA  XBPB 
0 (i) PT  XAPA0  XBPB0
(ii) The inter molecular interaction is more than
(ii) The inter molecular interaction is weaker as
the interaction found in any of the pure
interaction found in any one of the pure
components
components. A............A
A............A molecular interaction
molecular interaction A.............B
A.............B is more than B............B
B............B is Stronger than
(iii) There is decrease in volume on mixing and
(iii) There is increase in volume on mixing and
evolution of heat takes place on mixing
absorption of heat.
Vmix  ve Hmix   ive
Vmix  positive Hmix  positive
Gmix   ive
Smix   ive Gmix   ive Smix   ive
Ex. H2O + CH3OH, C2H5OH + Hexane Ex. H2O + HCOOH, H2O + CH3COOH
C2H5OH + Cyclohexane, CHCl3 + CCl4 H2O + HNO3, CHCl3 + CH3OCH3
22. Identify the mixture that shows negative deviation solutions.
(A) Benzene + (CH3)2CO (B) (CH3)2CO+ C6H5NH2
(C) CHCl3 + C6H6 (D) (CH3)2CO + CS2
23. At 55ºC, ethanol has a vapour pressure of 168 mm, and the vapour pressure of methyl cyclohexane is
280 mm. A solution of the two in which the mole fraction of ethanol is 0.68, has a total vapour pressure
of 376 mm. This solution is formed from its components with
(A) The evolution of heat
(B) The absorption of heat.
(C) Neither absorption nor evolution of heat
(D) Nothing can be predicted on the basis of given information
24. Total vapour pressure of mixture of 1 mole of A PA0  150mm   

and 2 mole of B PB0  240mm is 200 
mm. In this case :
(A) There is a positive deviation from Raoult’s law.
(B) There is a negative deviation from Raoult’s law
(C) There is no deviation from Raoult’s law.
(D) Molecular masses of A & B are also required for calculating deviation.
25. Identify the mixture showing positive deviation of non-ideal solution.
(A) CH3COCH3 + CS2 (B) Hexane + Heptane
(C) Chlorobenzene + Bromo benzene (D) Acetone + Chloroform

PAGE NO.-11
1. The pH at the equivalence point of titration of 10 mL, 0.1 M weak base BOH with 0.1 M HCl is 5. Find
the pKb of BOH : (log 2 = 0.30)
(A) 6.3 (B) 5.3 (C) 4.3 (D) 7.3
(E) none of these
2. 1L of a buffer solution contains one mole of (CH3COO)2Ca and one mole of CH3COOH. Which of the
following statement is correct ? (pKa = 4.7) (log 2 = 0.30)
(A) pH = 9 (B) pOH = 9 (C) pH = 4.4 (D) pOH = 8.6
(E) pH = 14
3. Which of the following statements are correct
(A) It is not possible to compress a gas at a temperature below T C
(B) At a temperature below TC, the molecules are close enough for the attractive forces to act, and
condensation occurs
(C) No condensation takes place above TC
(D) The kinetic energy of the gas molecule is higher above TC, so is considered as super critical fluid.
4. Which is wrong statement about (SiH3)3N is
(A) (SiH3)3N is planar.
(B) (SiH3)3N is linear.
(C) in (SiH3)3N lone pair is present on N doesnot undergo back bonding.
(D) there are 9 sigma bond in the above molecule.
5. An ideal gas at initial pressure Pi and volume Vi undergoes reversible expansion to the same volume Vf
either isothermally or adiabatically. Which of the following statement(s) is (are) correct ?
Where the symbols have their usual meaning.
(A) |Pf (adiabatic) < Pf (isothermal)| (B) |W(adiabatic)| < |W(isothermal)|
(C) |Tf (adiabatic) < Tf (isothermal)| (D) |q(adiabatic)| < |q(isothermal)|
6. For the depression of freezing point experiment involving non-volatile solute. The correct statement(s)
is/are:
(A) Vapour pressure of pure solvent is more than that of solution
(B) Vapour pressure of pure solvent is less than that of solution
(C) Only solute molecules solidify at the freezing point
(D) Only solvent molecules solidify at the freezing point
7. In which of the following pairs of solutions will the values of the van't Hoff factor be the same?
(A) 0.05 M K4 [Fe(CN)6] and 0.10 M FeSO4.
(B) 0.10 M K4[Fe(CN)6] and 0.05 M FeSO4.(NH4)2SO4. 6H2O.
(C) 0.20 M NaCl and 0.10 M BaCl2
(D) 0.05 M FeSO4.(NH4)2SO4.6H2O and 0.02 M KCl . MgCl2 . 6H2O
Comperhension #
The pressure of two pure liquid A and B which form an ideal solutions are 400 mm Hg and 800 mm Hg
respectively at temperature T. A liquid containing 3 : 1 molar composition pressure can be varied. The
solutions is slowly vaporized at temperature T by decreasing the applied pressure starting with a
pressure of 760 mm Hg. A pressure gauge (in mm) Hg is connected which given the reading of
pressure applied.
8. The reading of pressure Gauge at which only liquid phase exists.
(A) 499 (B) 399 (C) 299 (D) None
9. The reading of pressure Gauge at bubble point is:

(A) 500 (B) 600 (C) 700 (D) None
10. The reading of pressure Gauge at which only vapour phase exists is:
(A) 501 (B) 457.14 (C) 425 (D) 525
11. The pH of a 0.01 M solution of the sodium salt of a monocarboxylic acid is 9. The pKa of the acid will be
………
PAGE NO.-12
12. 20 g of a binary electrolyte (molecular weight = 100) are dissolved in 500 g of water. The freezing point
of the solution is – 0.74°C; Kf = 1.86 K moIality–1, Calculate percentage degree of dissociation of
electrolyte.
13. Consider the following trends in properties of hydrogen halides :
1. Acidic strength : HF < HCl < HBr < HI 2. Thermal stability : HF > HCl > HBr > HI
3. Dipole moment : HF < HCl < HBr < HI 4. Reducing power : HF > HCl > HBr > HI
Find number of correct trends.
14. Match the Column.
Column I Column II
(A) 0.1 M Al2(SO4)3 (p) Solution with highest boiling point
(B) 0.1 M AlPO4 (q) Van't Hoff factor is greater than 1.
(C) 0.1 M urea. (r) Solution with lowest osmotic pressure.
(D) 0.1 M MgCl2 (s) Solution with lowest freezing point.

Daily Self-Study Dosage for mastering Chemistry Immiscible Liquid
When a volatile liquid is added to another volatile liquid, which are completely immiscible with each other, each
liquid will behave independent of the other and will exert its own vapour pressure. The more dense liquid (A) will
form lower layer and less dense liquid (B) is passed into liquid (A). The total vapour pressure of the system will
be the sum of vapour pressure of both the volatile liquids.
Ptotal = PA + PB = PA0 + PB0 (as XA & XB = 1)
The boiling point of a liquid system is the temperature at which its vapour pressure becomes equal to
the external atmospheric pressure. The total vapour pressure of a mixture containing immiscible volatile liquids
is greater than either of the pure constituents, thus the mixture will boil at a temperature, which is lower than the
boiling point of either of the pure constituents.
This forms the basis of steam distillation, in which one of the volatile liquids is water.
This composition of the vapour above the liquid mixture can be calculated using
Dalton’s law of partial pressures.
PA = PA0 = PTotal XA’ .......(i)
PB = PB0 = PTotal XB’ .......(ii)
XA' and XB' represents the mole fraction of A and B in the vapour phase.
PTotal XB ' PB WB PB  MB
 
PTotal XA ' PAº WA PA  MA
The masses of the constituents in the vapour (distillate) will be proportional to their respective molar mass of
vapour pressure.
15. A mixture of immiscible liquids of an organic liquid and water boils at 90ºC and 732 torr pressure. The
distillate contains 73% by weight of the organic liquid. Calcualte the molar mass of the organic liquid
(vapour pressure of water at 90ºC is 526 torr.)
(A) 168.2 g mol–1 (B) 228.8 g mol–1 (C) 122.2 g mol–1 (D) 62.7 g mol–1
16. When a mixture of water and chlorobenzene (mutually immiscible) is distilled at an external pressure of
740.2 mm Hg, the mixture is found to boil at 90.3ºC, at which temperature the vapor pressure of pure
water is 350.1 mmHg. Calculate the per cent by weight of chlorobenzene in the disillate. (Molecular
weight is 112).
(A) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
PAGE NO.-13
17. An unknown compound is immiscible with water. It is steam distilled at 98.00C and P = 737 torr, Pº
(H2O) = 707 torr at 98.0ºC. This distillate was 75% by weight water. Calculate the molecular weight of
the unknown.
(A) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8

1. In the reaction A(s) + B(g) + Heat 2C(s) + 2D(g) equilibrium is established. The pressure of B is
doubled to re-established the equilibrium. The factor by which D is changed is:
(A) 2 (B) 3 (C) 2 (D) 3
2. The e/m ratio for cathode rays.
(A) is constant
(B) varies as the atomic number of the element forming the cathode in the discharge tube changes
(C) varies as the atomic number of the gas in the discharge tube varies
(D) has the smallest value when the discharge tube is filled with hydrogen.
3. The time taken for a certain volume of a gas 'X' to diffuse through a small hole is 2 minutes. It takes
5.65 minutes for oxygen to diffuse under the similar conditions. The molecular weight of 'X' is.
(A) 8 (B) 4 (C) 16 (D) 32
4. The Bohr orbit radius for the H–atom (Z = 1) is approximately 0.53 Å. The redius for the first excited
state orbit is:
(A) 0.13 Å (B) 1.06 Å (C) 4.77 Å (D) 2.12 Å
5. The number of H+ in 1 cc of a solution of pH = 13 is:
(A) 6.023 × 107 (B) 1 × 10–13 (C) 6.023 × 1013 (D) 1 × 1016
6. At which temperature the, reaction will be spontaneous if H = – 176 kJ, S = – 284.5 JK–1
(A) 380 K (B) 480 K (C) 580 k (D) 680 K
7. A 0.1 A sodium acetate solution was prepared. The Kh = 5.6 × 10–10. The correct statement is:
(A) Degree a hydrolysis is 7.48 × 10–4 (B) [OH–] = 7.48 × 10–5
(C) [OH ] = 7.48 × 10 M
– –6
(D) pH is approximately 7
8. If pKb for fluoride ion at 25ºC is 10, the ionisation constant of hydrofluoric acid in water at this
temperature is:
(A) 10–5 (B) 10–3 (C) 10–4 (D) 10–2
9. For the reaction, Fe2O3(s) + 3CO(g)  3CO2(g) + 2 Fe() which of the following is correct
(A) Hº = Eº + 3RT (B) Hº = Eº + RT (C) Hº = Eº (D) Hº = Eº  RT
10. In which of the following cases, entropy decreases.
(A) Solid changing to liquid (B) Expansion of a gas
(C) Crystal dissolves in water (D) Polymerisation (E) Homolytic fission of H2
11. The first three successive ionisation energies of an element Z are 900, 1757 and 14850 kJ mol–1
respectively. The element Z belongs to
(A) group-1 (B) group-2 (C) group-15 (D) group-17
12. (i) Br2 + 2NaOH [cold]  NaBr + (X) + H2O
(ii) 2Br2 + 6NaOH [hot]  NaBr + (Y) + H2O
What is the oxidation number of Br in (X) and (Y) respectively
(A) +1, +7 (B) +1 , +5 (C) +4, +5 (D) +3, +5
13. A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of
(A) sodium atoms (B) sodium hydride
(C) sodium amide (D) solvated electrons
PAGE NO.-14
14. Match List-I with List-II and select the correct answer using the codes given below the lists:
List-I List-II
A. (SiH3)3N 1. 3 centre-2 electron bond
B. BF3 2. sp3-hybridization
C. SiO2 3. p–p bond
D. B2H6 4. p–d bond
A B C D A B C D
(A) 4 2 1 2 (B) 2 3 2 1
(C) 1 2 3 4 (D) 4 3 2 1
15. An aqueous solution of borax is:
(A) Neutral (B) Amphoteric (C) Basic (D) Acidic
16. The oxide which is not a reducing agent is :
(A) CO2 (B) CO (C) SO2 (D) Both (A) & (C)
17. The dipole moment of HBr is 7.95 debye and the intermolecular separation is 1.94 × 10–10 m. Find the
% ionic character in HBr molecule.
18. Calculate % degree of dissociation of 0.5 M NH3 at 25°C in a solution of pH = 12
19. The chemical reaction : A  P (Hº = 2.8 kJ) is spontaneous only above 400 K. Find least value of Sº
of the reaction (in J/K).
20. Calculate the weight of residue obtained when CaCO3 is strongly heated and 5.6 litre CO2 is produced
at N.T.P.
21. What is the maximum number of species among the following which are isoelectronic with N2?
CN–, Si, NO–, CO, O22+, C22–, C2H4, CH3+, MgH2

Daily Self-Study Dosage for mastering Chemistry Double Salts and Alums
Double Salt:
Simple or “single” salts consist of one cationic component and one anionic component, e.g. NaCl, Ca(OH) 2,
Na2SO4 etc. Double salts are salts containing more than one cation or anion, obtained by combination of two
different salts in a definite proportion which were crystallized in the same regular ionic lattice. Double salts
commonly form large crystals and appear to be one pure substance. In reality, a crystallized double salt is a
solution of solid in solid type.
Difference between Double salt and Complex Salt:

Double salts exist only as solids. When dissolved in water, a double salt completely dissociates into simple ions
while complexes do not; the complex ion remains unchanged.
For example, KCeF4 is a double salt and gives K+, Ce3+ and F– ions when dissolved in water, whereas K4 [YbI6]
is a complex salt and contains the discrete [YbI6]4– ion which remains intact in aqueous solutions.
Double salt will give positive test for all the individual ions in solution. But, complex salt will not give positive test
for all the individual ions. To avoid confusion between double salt and complex, complex ion or part is written in
square brackets.
Examples of double salts:

Mineral dolomite : CaMg(CO3)2;
Mohr’s Salt : .(NH4)2SO4·FeSO4·6H2O
Carnallite : KCl.MgCl2·6H2O
Potash Alum : K2SO4·Al2(SO4)3·24H2O i.e. KAl(SO4)2·12H2O
Alums :
Most common examples of double salts include alums. Alums are double sulphate salts, with the general
formula AM(SO4)2·12H2O, where A is a monovalent cation such as K or Na and M is a trivalent metal cation
such as Al or Cr.
PAGE NO.-15
Examples of Alums:
Soda alum: NaAl(SO4)2·12H2O, Ammonium alum: NH4Al(SO4)2·12H2O, Chrome alum: KCr(SO4)2·12H2O
Uses of Alums:
i. as a blood coagulant (usually used after shaving)
ii. as an deodorant due to its antiperspirant and antibacterial properties.
iii. Alum is used to clarify water by hastening sedimentation through the
process of flocculation (sticking together of small suspended particles).
Small, undesirable particles in water stick together (through the use of
electric charge imparted by the alum) forming larger particles which settle
down and can be easily removed. (You will learn more about this point in
Surface Chemistry).
22. Which of the following is a double salt?
(A) Al2(SO4)3 (B) NaOH
(C) Na2SO4.Al2(SO4)3.24H2O (D) [Cr(H2O)6]Cl3
23. 1 mole of Carnallite will give how many moles of ions in aqueous solution?
(A) 2 (B) 4 (C) 5 (D) 6
24. Aqueous solution of potash alum will give positive test of which of the following ions?
(A) K+ (B) Al3+ (C) SO42– (D) all of these
25. Aqueous solution of K3[Fe(CN)6] will give positive test of which of the following ions?
(A) K+ (B) Fe2+ (C) Fe3+ (D) CN–

1. Select correct statements about solubility of CH3COOAg in a buffer solution of pH < 7.
(A) Solubility of CH3COOAg increases with decrease in pH
(B) Solubility of CH3COOAg decreases with decrease in pH
(C) Solubility of CH3COOAg in a buffer solution of pH = 5 will be greater than that in pure water
(D) Solubility of CH3COOAg in a buffer solution of pH = 6 will be smaller than K sp where Ksp is the
solubility product of CH3COOAg.
2. Which of the following statement(s) are incorrect for H3BO3 ?
(A) It is an odd electron molecule.
(B) It in water acts as proton donor.
(C) It in solid state have hydrogen bonding.
(D) It is a useful primary standard for titrating against acids.
3. Correct order about bond angle is/are :
(A) H2O > H2S > H2Se > H2Te (B) C2H2 > C2H4 > CH4 > NH3
(C) SF6 < NH3 < H2O < OF2 (D) ClO2 > H2O > H2S > SF6
4. The solubility of Fe(OH)3 in a buffer solution of pH = x is 4.32 × 10–2 mol/L. Given Ksp of
Fe(OH)3 = 4.32×10–32 M4 then the value of x is (Ignore the hydrolysis of Fe3+ ions):
5. Atomicity of gas evolved when white phosphorous is reacted with caustic soda ?
6. The value of n in the molecular formula NanAlnSi94O192 is :
7. The periodic table consists of 18 groups. An isotope of Zn, on bombardment with neutron, undergoes a
nuclear reaction yielding element X as shown below. To which group, element X belongs in the periodic
64
table ? 30 Zn 10 n  X  2 11 H
PAGE NO.-16
8. Write IUPAC names of the following
(a) Na2[Fe(CN)5NO] (b) [Ni(DMG)2] (c) NH4[Cr(SCN)4(NO)2] (NO is nitrosyl)
(d) [Pd(H2O)2 I2(ONO)2] (e) [Co(NH3)4 Cl(NCS)]+ (f) K4[FeO4]
(g) K2[Co(N3)4] (h) [Ni(PPh3)2Cl2] (i) [Cr(acac)3] (j) [Pt(C5H5N)4][PtCl4]
9. Write the structural formula corresponding to each of the following IUPAC names :
(a) hexaaquairon (II) chloride (b) potassium tetrafluoridoargentate (III)
(c) pentachloridotitanate (II) ion (d) tetraamminedichloridocobalt (III) chloride
(e) dicyanido-C-argentate (I) ion (f) diamminetetrachloridonickelate (II) ion
(g) tris(ethylenediamine)copper(II) sulphate (h) sodium diaquatetrahydroxidoaluminate (III)
(i) amminechloridobis(ethylene diamine)chromium(III) sulphate
(j) potassium tetracyanido-C-zincate (II)
10. Match the ligands listed in column–I with the characteristic(s)/type of ligands listed in column–II.
Column-I Column-II
A. Acetyl acetonato (p) Resonance stabilization
B. Oxalato (q) Monoanion
C. Dimethyl glyoximato (r) Chelating ligand
D. Nitrito (s) Ambidentate ligand
(t) Monodentate
NOTE : For resonance stabilization consider the ligands as only free ions.

Daily Self-Study Dosage for mastering Chemistry Naming of Polynuclear Complexes with Bridging Ligands
Naming of Polynuclear Complexes with Bridging Ligands :
If a complex contains two or more central metal atoms or ions, it is termed as polynuclear. In certain
polynuclear complexes. ligands may link the two metal atoms or ions. Such ligands which link the two metal
atoms or ions in polynuclear complexes are termed as bridging ligands. These bridging ligands are separated
from the rest of the complex by hyphens and denoted by the prefix .
Rule 1: If the compound is unsymmetrical on both sides of the bridge then we have to write the name of one
side then that of the bridge and then that of the second side, like
Tetraaquacobalt(III)––amido––hydroxidotetramminechromium(III) sulphate
Rule 2: When the molecule is symmetrical a more compact name can be given by listing the bridging ligands first:
5
 3 1 3 
(NH3 )5 Cr OH – Cr (NH3 )5  Cl5
 
–hydroxidobis(pentaamminechromium(III)) chloride
OR
we could also use Rule 1 to write the name of one side of the bridge then the name of bridging complex
and then the name of the other side of the bridge, like
pentaamminechromium(III)––hydroxidopentaamminechromium(III) chloride
Rule 3: If there are two or more bridging groups of the same kind, this is indicated by di––, tri–– etc.
(SO4)2
di––hydroxidobis(tetraaquairon(III)) sulphate
PAGE NO.-17
Example:
(SO4)2
–amido––hydroxidobis(bis(ethylenediammine)cobalt(III)) sulphate
OR
bis(ethylenediammine)cobalt(III)––amido––hydroxidobis(ethylenediammine)cobalt(III) sulphate
11. What is the correct name of
(A) -amido--hydroxidobis(tetraamminecobalt (III)) ion

(B) -hydroxido--amidodi(tetraamminecobalt (III)) ion
(C) di--amido-hydroxidobis(tetraamminecobalt (III)) ion
(D) tetraamminecobalt(III)--amido--hydroxidotetraamminecobalt(III) ion
4+
NH3 NH3
H3N O2 NH3
12. Co Co
H3N N NH3
H3N H2 H3N
The bridging ligands in the above complex, if both cobalt ions are in+3 oxidation state, are:
(A) Amide and dioxygen (B) Amide and peroxide
(C) Amide and superoxide (D) Amine and peroxide
13. What is the IUPAC name of [(NH3)5Co–NH2–Co(NH3)5](NO3)5 if both cobalt ions have the same
oxidation number.
(A) –aminobis(pentaaminecobalt(III))nitrate
(B) –amidobis(pentaamminecobalt(III))nitrate
(C) –amidobis(pentaamminecobalt(III))pentanitrate
(D) di-–amidobis(pentaamminecobalt(III))nitrate
14. Number of chloride ions in the compound Bis(ethylenediamine)cobalt(III)--imido- hydroxidob is

(ethylenediamine) cobalt (III) chloride is equal to
(A) 1 (B) 2 (C) 3 (D) 4

1. Consider the reaction CaCO3(s) CaO(s) + CO2(g) in a closed container at equilibrium. What would
be the effect of addition of CaCO3 on the equilibrium concentration of CO2 ?
(A) Increases (B) Unpredictable (C) Decreases (D) Remains unaffected
2. A complex organic compound contains 21 atoms of carbon per molecule. The percentage of carbon in
the compound is 70%. If 36 gram of the substance is dissolved in 100 mL of water then the molarity of
the solution will be–
(A) 1 (B) 0.1 (C) 1.43 (D) 0.143
PAGE NO.-18
3. In the reaction CS2 () + 3O2 (g)  CO2 (g) + 2SO2 (g) H = 265 kcal. The enthalpies of formation of
CO2 and SO2 are both negative and are in the ratio 4 : 3. The enthalpy of formation of CS2 is
+26kcal/mol. Calculate the enthalpy of formation of SO2.
(A) – 90 kcal/mol (B) – 52 kcal/mol (C) – 78 kcal/mol (D) – 71.7 kcal/mol
4. For the reaction at 25°C, X2O4()  2XO2(g); H = 2.1 Kcal and S = 20 cal K–1.
The reaction would be :
(A) spontaneous (B) non-spontaneous (C) at equilibrium (D) unpredictable
5. Which of the following statement is false ?
(A) Two different solutions of sucrose of same molality prepared in different solvents will have the same
depression in freezing point.
(B) The osmotic pressure of a solution is given by the equation  = CRT (where C is the molarity of the
solution).
(C) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium
chloride, acetic acid and sucrose is BaCl 2 > KCl > CH3COOH > sucrose
(D) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is
directly proportional to its mole fraction in the solution.
6. The species C2
(A) Has one  bond and one  bond (B) Has both  bond
(C) Has both  bonds (D) Does not exist
7. An acid solution of pH = 6 is diluted 1000 times, the pH of the final solution becomes.
(A) 6.99 (B) 6 (C) 3 (D) 9
8. Which of the following has highest electron affinity?
(A) Li+ (B) Na+ (C) F– (D) Cl–
9. A pre-weighed vessel was filled with oxygen at NTP and weighed. It was then evacuated, filled with
SO3 at the same temperature and pressure and again weighed. The weight of oxygen will be–
(A) Same as that of SO3 (B) 4 times that of SO3
(C) 0.4 times that of SO3 (D) 0.25 times that of SO3
10. Which will give maximum [H+] ion concentration by dissolving equal moles in water
(A) LiOH (B) NaOH (C) KOH (D) RbOH
11. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame, no
distinctive colour is noticed. The cation is–
(A) Ca2+ (B) Mg2+ (C) Ba2+ (D) Pb2+
12. The solvent which is better to be used during ebullioscopic, measurement has–
(A) High Kb (B) Low Kb (C) Kb = Kf (D) Kf < Kb
13. Standard molar enthalpy of formation of CO2 is equal to -
(A) zero
(B) the standard molar enthalpy of combustion of gaseous carbon
(C) the sum of standard molar enthalpies of CO & O2
(D) the standard molar enthalpy of combustion of C(s)
14. Arrange the alkalline earth metals in decreasing order of size of their hydrated ion :
(A) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Sr2+ (aq) > Ba2+ (aq)
(B) Ba2+ (aq) > Sr2+ (aq) > Ca2+ (aq) > Mg2+ (aq) > Be2+ (aq)
(C) Be2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Ba2+ (aq) > Sr2+ (aq)
(D) Ba2+ (aq) > Sr2+ (aq) > Mg2+ (aq) > Ca2+ (aq) > Be2+ (aq)
15. Which of the following pairs of name and formula of complexes, is not correct?
(A) Tetraamminecopper(II) sulphate............. [Cu(NH3)4]SO4
(B) Diamminesilver(I) chloride ................ [Ag(NH3)2]Cl
(C) Potassium hexacyanido-C-ferrate(II) ............... K4[Fe(CN) 6]
(D) Potassium amminepentachloridoplatinate(II) ................. K[Pt(NH3)Cl5]
16. The correct order of hybridisation of the central atom in the following species NF3, BF3, PF5 and [SiF6]2–is:
(A) sp2, sp3, sp3d2, sp3d (B) sp3, sp2, sp3d, sp3d2
2 3 3 3 2
(C) sp , sp , sp d, sp d (D) sp3, sp2, sp3d2, sp3d3
PAGE NO.-19
17. How many of the following molecules / ions may act as a bidentate ligand ?
CO32– NH2 – CH2 – COO– EDTA4– C2O42– SO42–
CH3COCHCOCH3 –
CH3C  N SCN¯ DMG
18. In the disproportionation reaction of NaOH with one molecule of P4, number of molecules of NaOH
reacting are .............. .
19. The element respresented by the symbol Une belong to pth group of moden periodic table. Also the
element having highest value of electron gain enthalpy (released energy) has atomic number q. Find
the value of (q –p).
20. A buffer solution is made by mixing a weak acid HA (Ka = 10–6) with its salt NaA in equal molar amounts.
What should be the millimoles of acid or salt that should be added to make 180 ml of buffer solution in
which if 0.1 mole of strong acid are added into 1 L of this buffer solution then change in pH is unity ?
21. Calculate the magnitude of work done (in cal.) an open vessel at 300 K, when 112 g iron reacts with dil.
HCl. (Report your answer after division with 100)

Daily Self-Study Dosage for mastering Chemistry Topic : Coordination Compounds in Qualitative Analysis
Coordination compounds find use in many qualitative chemical analysis. The familiar colour reactions given by
metal ions with a number of ligands, as a result of formation of coordination entities, form the basis for their
detection and estimation by classical methods of analysis. Some important examples are:
Formula IUPAC Name and Colour Remark & Common Name
Tetraamminecopper(II) sulphate: obtained when CuSO4 is treated
(a) [Cu(NH3)4]SO4
Deep blue: with excess of NH3
tris(glycinato)cobalt(III): didentate ligand of anion of
(b) Co(gly)3
Purple amino acid glycine
Pentaaquathiocyanato–S–iron(III):
(c) [Fe(H2O)5(SCN)] 2+
formed in detection of Fe3+ ion
Red:
CrystalsAlkaline solution of this
Potassium tetraiodidomercurate(II):
(d) K2[HgI4] complex is called Nessler’s
Faint Yellow
Reagent,used in detection of NH3
Cobalt(II) tetrathiocyanato–S–mercurate(II): crystalline precipitate obtained in
(e) Co[Hg(SCN)4]
Deep blue qualitative detection of Hg2+
Iron(III) hexacyanidoferrate(II): Ferriferrocyanide obtained in
(f) Fe4[Fe(CN)6]3
Prussian blue detection of Fe2+
Potassium hexanitrito–N–cobaltate(III): precipitate obtained in detection
(g) K3[Co(NO2)6]
Yellow of Co2+ (Fischer salt)
Bis(dimethylglyoximato)nickel(II): precipitate obtained in
(h) [Ni(dmg)2]
Rosy red detection of Ni2+ ions
Potassium hexachloridoplatinate(IV): precipitate obtained in detection
(i) K2[PtCl6]
Yellow of K+ ions
Sodium pentacyanidonitrosoniumferrate(II): Sodium nitroprusside used in
(j) Na2[Fe(CN)5NO+]
Red detection of S2– ions or sulphur
Pentaaquanitrosoniumiron(I) sulphate:
(k) [Fe(H2O)5(NO+)]SO4 obtained in detection of Fe2+ ion
Brown ring
stable soluble complex obtained
Tetracyanidocuperate(I):
(l) [Cu(CN)4]3– in detection of Cu2+ on adding
Colourless
excess of KCN solution
Ammonium hexachloridoplatinate(IV): one of the only few compounds
(m) (NH4)2[PtCl6]
Yellow of NH4+ ion which precipitates
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
22. What is the oxidation state of Fe in the brown ring complex?
(A) 0 (B) 1 (C) 2 (D) 3
PAGE NO.-20
23. Select the correct option for the rosy red complex obtained in the detection of Ni 2+.
(A) Coordination number of Ni is 4 (B) The complex is square planar
(C) Chelating ligand is present in the complex (D) All of the above are correct
24. Which of the following complexes is not blue?
(A) Co[Hg(SCN)4] (B) Fe4[Fe(CN)6]3 (C) [Cu(NH3)4]SO4 (D) [Fe(H2O)5(SCN)]2+
25. Which of the following precipitates are yellow?
(A) K3[Co(NO2)6 (B) (NH4)2[PtCl6] (C) K2[PtCl6] (D) [Fe(H2O)5(NO+)]SO4

1. For one mole of a vander Waal gas when a = 0, which of the following graph is/are correct ?
(T = const.) (T = const.) (P = const.) (P = const.)
(A) PV (B) PV (C) PV (D) PV
P P T T
2. CCl4 and acetone form a non-ideal solution at room temperature in a copper container. For this
process, the true statement(s) is (are) :
(A) G is positive (B) Ssystem is positive (C) Ssurroundings < 0 (D) H > 0
3. Which of the following statement(s) is/are true.
(A) Chelation effect is maximum for five and six membered rings.
(B) Chelating ligands are at least bidentate ligand.
(C) As the number of rings in a complex increase stability of complex (Chelate) also increases.
(D) Azide ion (N3–) has two N as donor atoms and behaves as a chelating ligand.
4. It is an experiment fact that :
DMG + Ni()salt + NH4OH  Red ppt.
Which of the following is/are true about this red ppt :
(A) It is a non–ionic complex (B) It involves intra molecular H–bonding
(C) Ni() is sp3 hybridised (D) It is a diamagnetic complex
H2O
5. Li + H2 A B+C
(gas)
AlH3
D
(A) A can act as reducing agent (B) C is a paramagnetic gas
(C) D is a complex compound (D) B is a base.
B 
5 C
A real gas is subjected to change in state from A to C by path  and  N 
P 2 
6. , if U for path  is 2J then find the heat absorbed by gas in path  m 

(in joule 3 A
1 2 V(m3)
7. Oxidation states of iron in the complexes [Fe(H2O)5(NO)]2+ and [Fe(CN)5(NO)]2– are x and y
respectively. Then (x + y) is equal to :
8. Diborane reacts with ammonia to produce dense white fumes of (A). (A) is solid at room temperature.
On heating under pressure, it releases a combustible gas to produce a liquid (B) and finally a white
coloured solid (C). The total number of hydrogen atoms in molecular formula of (C) is:
9. If elevation in boiling point when AB is dissolved in water to make saturated solution at 25°C is
2 × 10–4 ºC and Ksp of AB is 4 × 10–x then determine the value of x. (Assume  = 1, Molality  Molarity
(Given Kb = 0.5 K/m.)
PAGE NO.-21
10. How many of the following are bidentate ligand?
Oxalate, Glycinate, Hydrazine, Cyanide, Acetylacetonate, Diethylenetriamine, dmg, Ammonia,
Sulphate, Water.
11. An ideal monoatomic gas initially in state 1 with pressure P 1 = 20 atm and volume V1 = 1500 cm3. It is
then taken to state 2 with pressure P2 = 1.5 P1 and volume V2 = 2V1. Find the change in internal energy
in this process in KJ. (Take 1 atm lit  100 J)
12. How many of the following are diamagnetic ?
(a) K4[Fe(CN)6] (b) Na3[Co(ox)3] (c) [Pt(NH3)3Cl] Br (d) [Fe(H2O)6]2+
(e) [Zn(NH3)4] Cl2 (f) [MnO4]2– (g) Li[AlH4] (h) [V(H2O)6]2+
13. In how many of the following molecules/ions, the number of electrons in  molecular orbital (both  &
*) are more than or equal to 9. (In ground state)
(a) N2 (b) N2 (c) Be2 (d) B 2 (e) B2 (f) C22
(g) C2 (h) H2 (i) Li2 (j) O 2 (k) F2
14. Match the column :
Column I Column II
A. O2, O2+, O2– (p) Diamagnetic
B. O22–, C2 ,C22– (q) Same bond order
C. N2 ,CO, NO+ (r) Paramagnetic
D. He2, Be2, B22+ (s) Isoelectronic

Crystal Field Splitting Diagrams of d-orbitals for various Coordination Geometries
In absence of ligand all 5 d-orbitals of the central metal ion are degenerate i.e. they have the same energy. The
electrons in the d-orbitals and those in the ligand repel each other due to repulsion between like charges. Thus,
the electorns in d-orbitals which are closer to the ligands will have a higher energy than those further away
which results in the d-orbitals splitting in energy.
The magnitude of splitting () is affected by the following factors:
1. the nature of the metal ion.
2. the metal’s oxidation state. A higher oxidation state leads to a larger splitting.
3. the arrangement of the ligands around the metal ion.
4. the nature of the ligands surrounding the metal ion. Stronger ligands cause greater splitting in energy
levels of d-orbitals.
The following diagram shows the crystal field splitting of d-orbitals in tetrahedral, octahedral, tetragonal and
square planar geometries for the same metal-ligand combination.
PAGE NO.-22
15. Which of the following relations is not correct?
(A) o < t (B) o  (9/4)t (C) sp > t (D) sp = 1.30
16. Select the correct statement?
(A) In tetrahedral field z2 lies higher in energy than xy
(B) Splitting in square planar field is less than that in tetrahedral field
(C) In square planar field five d-orbitals are split into 2 different energy levels.
(D) In octahedral field t2g orbital lie lower in energy than eg orbitals
17. Which d-orbital has the highest energy in square planar field?]
(A) x2 – y2 (B) z2 (C) xy (D) yz
18. Magnitude of  depends on
(A) the metal’s oxidation state (B) nature of the metal
(C) number of ligands surrounding the metal (D) strength of ligand

1. Enthalpy of solution of CsBr(s) is 10 kJ.mol1. If the enthalpies of hydration of Cs+(g) and Br(g) are
475 and 655 kJ.mol, what should be the lattice energy of CsBr(s) in kJ.mol 1 ?
(A) 1120 (B) 1130 (C) 1140 (D) 1150
2. In the reaction, xVO + yFe2O3  FeO + V2O5. What is the value of x and y respectively?
(A) 1, 1 (B) 2, 3 (C) 3, 2 (D) None of these
3. How many grams of NaCl must be dissolved in 225 g of water to yield a solution having the same
boiling point as that containing 20 g glucose (M – 180) and 30 g sucrose (M – 342) in 225 g of water?
(Na – 23, Cl – 35.5)
(A) 5.8 (B) 11.6 (C) 12.3 (D) None of these
4. For an equilibrium reaction A(g) + B (g) C (g), H =+ ve
an increase in temperature would cause
(A) an increase in the value of Keq (B) a decrease in the value of Keq
(C) no change in the value of Keq.
(D) a change in Keq which cannot be qualitatively predicted.
5. If the shortest wavelength of H atom in Lyman series is x. Then longest wavelength in Balmer series of
He+ is :
9x 36x x 5x
(A) (B) (C) (D)
5 5 4 9
6. The density of water at 4°C is 1.0 × 103 kg m–3. The volume occupied by one molecule of water is
approximately.
(A) 3.0 × 10–23 mL (B) 6.0 × 10–22 mL (C) 3.0 × 10–21 mL (D) 9.0 × 10–23 mL
7. The compressibility factor of He is:
(A) Linearly increasing with volume (B) Linearly increasing with pressure
(C) Equal to 1 (D) Linearly decreasing with pressure
8. Given the following reaction at equilibrium
N2(g) + 3H2 (g) 2NH3 (g)
Some inert gas is added at constant volume. Predict which of the following facts will be affected ?
(A) More of NH3(g) is produced.
(B) Less of NH3(g) is produced
(C) No affect on the degree of advancement of the reaction at equilibrium.
(D) Kp of the reaction is increased.
9. It is known that atoms contain protons, neutrons and electrons. If the mass of neutron is assumed tobe
half of its original value whereas that of electron is assumed to be twice of this original value. The
atomic mass of C612 will be :
(A) Twice (B) 75% less (C) 25% less (D) one-half of its
PAGE NO.-23
10. Which of the following combination has maximum tendency to form adduct?
(A) BF3 + NH3 (B) BCl3 + NH3 (C) BBr3 + NH3 (D) B3 + NH3
11. All the following complex ions are found to be paramagnetic :
P : [FeF6]3– ; Q : [CoF6]3– ; R : [V(H2O)6]3+ ; S : [Ti(H2O)6]3+
The correct order of their paramagnetic moment (spin only) is :
(A) P > Q > R > S (B) P < Q < R < S (C) P = Q = R = S (D) P > R > Q > S
12. The crystal field-splitting for Cr3+ ion in octahedral field increases for ligands I–, H2O, NH3 , CN– and the
order is :
(A) I– < H2O < NH3 < CN– (B) CN– < I– < H2O < NH3
(C) CN < NH3 < H2O < I
– –
(D) NH3 < H2O < I– < CN–
13. In which of the following configurations will there be the possibility of both para and diamagnestism,
depending on the nature of the ligands?
(A) d7 (B) d3 (C) d6 (D) d5
14. The complex for which the calculation of crystal field splitting can be most easily done, by knowing its
absorption spectrum, will be:
(A) [TiCl6]2– (B) [Fe(H2O)6]2+ (C) [Ti(CN)6]3– (D)[CoF6]3–
15. The correct order for the CFSE (numerical value) for the following complexes is:
Complex P Q R S
Formula [CoF6]3– [Co(CN)6]3– [Co(NH3)6]3+ [Co(H2O)6]3+
(A) P > Q > R > S (B) Q > R > S > P (C) S > R > P > Q (D) R > Q > P > S
16. Statement-1 : For cyclic process U = 0
Statement-2 : Work & heat are significant only when the system undergoes a change.
(A) Statement-1 is True, statement-2 is True; statement-2 is a correct explanation for statement-1.
(B) Statement-1 is True, statement-2 is True; statement-2 is NOT a correct explanation for statement-1
(C) Statement-1 is True, statement-2 is False
(D) Statement-1 is False, statement-2 is True
17. The chemical formula of the compound of calcium obtained by heating calcium oxide with coke in
electric furnace up to 2273-3273 K temperature will be
(A) Ca2C (B) CaC2 (C) CaCO3 (D) Ca(OH)2
18. The hybridised states of carbon atoms in diamond and fullerene (C60) respectively are
(A) sp3 and sp2 (B) sp2 and sp3 (C) sp3 and sp (D) sp3 in both
19. 0.308 g CO2 is obtained on the combustion of 0.21 g organic compound. The percentage of carbon in
the compound is
(A) 40% (B) 4% (C) 14.67% (D) 13.5%
20. The correct order of stability of O2, O2 , O2– and O2–
2 according to Molecular Orbital theory is
(A) O2 > O2 > O2– > O2–

2 (B) O2 > O2 > O2– > O2–
2
(C) O2 > O2 > O2– –

2 > O2 (D) O2 > O2 > O2– –
2 > O2
21. How many P-P single bonds are present in white phosphrus (P4) molecule ?
22. A six co-ordinate complex has the formula CoCl 3.5NH3 .H2O. Electrical conductance measurements
indicate the presence of three ions in one formula unit. How many moles of AgCl will be percipitated
with AgNO3 solution with one mole of complex ?
23. In a system, where E = – 15 kJ, a piston expanded against a external pressure of 1.2 atm giving a
change in volume of 75 lt. What was the magnitude of change in heat energy of this system (in kJ) ?
(Take 1 lt atm = 100 J).
24. The vapour pressure of two pure liquids A and B are 5 and 10 torr respectively then calculate the total
pressure of the solution (in torr) obtained by mixing 2 moles of A and 3 moles of B.
25. The relative density of a gas A with respect to oxygen gas is 1/4. What would be the mass (in amu) of
one molecule of the Gas A.
PAGE NO.-24

1. Vapour pressure verses temperature curves are given for three solutions A, B and C. When vapour
pressure become equal to 1 atm then this temperature is known as boiling point of solution.
Correct order of conc of A, B, C. if value of i is same for A, B & C.

(A) A > C > B (B) B > A > C (C) C > A < B (D) C > A > B
2. The vapour pressure of two pure liquids X and Y which from an ideal solution are 200 and 300 mm of
Hg respectively at 300 K. A liquid solution of 'X' and 'Y' in which the mole fraction of 'X' is 0.5 is
contained in a cylinder closed by a piston on which pressure can be varied.
(A) Only if pressure above solutions is less than 200 torr, vapour phase can exist.
(B) Only if pressure above solutions is less than 300 torr, vapour phase can exist.
(C) Only if pressure above solutions is more than 200 torr, liquid phase exist.
(D) Only if pressure above solutions is less than or equal to 250 torr, vapour phase can exist.
3. The vapour pressure of the solution of two liquids A(pº = 80 mm) and B(pº = 120 mm) is found to be
100 mm when xA = 0.4. The result shows that
(A) solution exhibits ideal behaviour
(B) solution shows positive deviation
(C) solution shows negative deviation
(D) solution will show positive deviations for lower concentration and negative deviations for higher
concentrations.
4. Positive deviation from raoults law is shown by which of the following mixtures :
(A) Benzene and toluene (B) CHCl3 & acetone
(C) ethanol & water (D) HCl & water
5. A 10% w/w solution of cane sugar has undergone partial inversion according to the reaction.
Sucrose + water  glucose + fructose
The boiling point of the solution is 100.7°C.
What fraction of sugar has inverted ?
Kb (H2O) = 1.8 K.kg/mol.
(A) 0.5 (B) 0.2 (C) 0.3 (D) 0.4
6. Which of the following complexes are diamagnetic ?
[Pt (NH3)4]2+ [Co (SCN)4]2– [Cu (en)2]2+ [Hg4]2–
square planar tetrahedral square planar tetrahedral
(i) (ii) (iii) (iv)
(A) (i) and (ii) (B) (ii) and (iii) (C) (i) and (iv) (D) (iii) and (iv)
7. 1 mol of an ideal gas is heated at a constant pressure of one atmosphere from 300 K to 400 K
if Cv,m = (21.686 + 10–3 T) J/molK the H for the process is :
(A) 3000 (B) 3035 (C) 3350 (D) 30350
8. The IUPAC name of [Fe(NH2)(CO)2I(PPh3)2] is :
(A) Amidodicarbonyliodidobis(triphenylphosphine)iron(II)
(B) Aminedicarbonyliodidobis(triphenylphosphine)iron(II)
(C) Amidodicarbonyliodidobis(triphenylphosphine)ferrate(II)
(D) None of these
PAGE NO.-25
9. Match Column-I with Column-II and select the correct answer with respect to hybridisation using the
codes given below :
Column - I Column - II
(Complex) (Hybridisation)
(I) [Ni(CN)4]2– (p) dsp2 hybridisation
3–
(II) [Cu(CN)4] (q) sp3 hybridisation
(III) [Co(C2O4)3]3– (r) sp3d2 hybridisation
(IV) [Fe(H2O)5NO]2+ (s) d2sp3 hybridisation
Codes :
(I) (II) (III) (IV) (I) (II) (III) (IV)
(A) q p r s (B) p q s r
(C) p q r s (D) q p s r
10. In which of the following processes on an ideal gas, there occurs an increase in entropy of the system :
(A) Reversible Isothermal expansion.
(B) Irreversible adiabatic compression.
(C) Isothermal free expansion (against vacuum)
(D) Reversible adiabatic expansion.
11. Which of the following is correct for standard enthalpy of formation?
(A) It is always negative.
(B) It is found for one mole of compound in standard state.
(C) It is zero for all species in standard state.
(D) It is zero for white phorphrous, which is least stable form of phosphorous.
12. Consider the following system :
Three different aqueous solution each having volume 100 ml are taken and kept in contact as shown.
100 ml SPM 100 ml SPM 100 ml

0.2 M Urea 0.15 M KCl 0.1 M AlCl3
After sufficient time (Consider temp. constant & 100% dissociation of strong electrolyte) :
100
(A) Volume of urea solution will be ml.
3
400
(B) Volume of AlCl3 solution will be ml.
3
(C) There will be no change in volume of KCl solution.
(D) Volume of both KCl and AlCl3 solutions will increase.
Comprehension #
A sample of ideal gas is made to undergo the following two processes :
Process-I : 4.4 g of an ideal gas (mol.wt = 44) at 300 K and 10 atm is allowed to expand isothermally
against a constant external pressure of 1 atm.
Process-II : Now, the gas sample obtained after process-I at 1 atm pressure is allowed to compress
isothermally against constant external pressure of 10 atm.
Taking 1 Latm = 100 J, answer the following questions :
13. Heat absorbed in process-I by the gas is :
(A) 200.5 KJ (B) 212.5 J (C) 221.4 J (D) 242.4 J
PAGE NO.-26
14. Which of the following statements is false :
(A) Work done by the gas in process-I is less than the work done by surroundings in process-II
(magnitude wise).
(B) Heat absorbed by the gas in process-I is less than the heat released by the gas in process-II
(magnitude wise).
(C) Both system and surroundings are restored back to their original state after process-I and II have
been performed on gas sample.
(D) None of these
15. Find the bond enthalpy of C – Cl bond (kJ/mol),given that
C2H6(g) + Cl2(g)  C2H5Cl(g) + HCl (g) H = –117 KJ/mol
Cl – Cl = 242 kJ/mol
C – H = 412 kJ/mol
H–Cl = 431 kJ/mol
Given your answer by dividing it by 10.
16. 1 mole of an ideal gas is subjected to a reversible process as shown in the figure.
B
(1.5Pa,2m )
–3
A
P(pascal)
(1Pa,1m–3)
1
(m –3)
V
Calculate the work done (in joule) in the process. [ln 2 = 0.7]
Report your answer after multipling with 10.
17. How many of the following reactions or processes is/are exothermic ?
(i) 2H(g)  H2(g) (ii) C(diamond)  C(graphite) (iii) CH4 + O2  CO2 + H2O
(iv) C2H6  C2H4(g) + H2(g) (v) cis-2-butene  trans-2-butene (vi) white P  red P.
(vii) H2O()  H2O(s) (viii) Na+(g) + aq  Na+(aq) (ix) NaOH+H2SO4Na2SO4+H2O
(x) HNO3 + water Solution. (xi) ethanol + water  Solution.
A gas 'X' is present with saturated water vapour over water Partial
pressure
liquid at total pressure of 1.5 atm. Vapour pressure of H2O at of 'X' Slope = 38 × 105 torr
18. same temperature is 0.5 atm. What is the solubility of gas 'X' in
terms of millimoles in 10 mole H2O() ? ( nH2O  nx )
Mole fraction of 'X' in H2O

1. Select correct statement(s):
(A) we can condense vapour simply by applying pressure
(B) to liquefy a gas one must lower the temperature below Tc and also apply pressure
(C) at Tc, there is no distinction between liquid and vapour state, hence density of the liquid is nearly
equal to density of the vapour
(D) None of these
PAGE NO.-27
2. Equimolar solution of AOH and BOH are prepared. The I.P. of A and B are 5.1 and 13.0eV respectively.
The E.N. of A and B are 0.9 and 3.2 respectively. Reviewing the data pick out the correct statement(s).
(A) Solution of BOH will give effervescence with sodium carbonate.
(B) Phenolphthalein will give pink colour with AOH solution.
(C) BOH solution will show a PH > 7.
(D) Treatment of NH4Cl with AOH will lead to liberation of ammonia.
3. The green coloured complex K2[Cr(CN)4(NH3)(NO)] is paramagnetic and its paramagnetic moment
(spin only) is 1.73 B.M. Which of the following is/are correct about it :
(A) Its IUPAC name is Potassium amminetetracyanonitrosoniumchromate ()
(B) Hybridisation state of chromium is d2sp3
(C) It can show linkage isomerism
(D) It cannot show geometrical isomerism
4. Which are correct statements ?
(A) [Ag(NH3)2]+ is linear with sp hybridised Ag+ ion.
(B) NiCl42–, VO43– and MnO4– have tetrahedral geometry
(C) [Cu(NH3)4]2+, [Pt(NH3)4]2+ and [Ni(CN)4]2– have dsp2 hybridisation of the metal ion
(D) Fe(CO)5 have bipyramidal structure with dsp3 hybridised iron.
5. Which of the following statements is/are correct :
(A) Among NaF & NaBF4, NaF is relatively less soluble in water.
(B) Larger negative value of lattice enthalpy is a favourable condition for formation of ionic bond.
(C) In general, ionic compounds do not conduct electricity in solid state.
(D) The water solubility of alkalline earth metal carbonates increases on moving down the group.
6. Which of the following do not exist?
(A) SH6 (B) HFO4 (C) FeI3 (D) HClO3
7. Find pH of solution obtained by titrating 0.12 M, 50 ml solution of weak acid with 0.06 M, 50 ml NaOH.
The dissociation constant of weak acid is 2  10–2. Give your answer by multiplying with 10.
8. Depression of freezing point of 0.01 molal aqueous CH3COOH is 0.0198ºC. 1 molal urea solution
freezes at –1.8ºC. Assuming molarity is equal to molality, pH of CH3COOH solution is :
9. How many of the following statement(s) is/are correct ?
(a) Hexacarbonylchromium(0) is d2sp3 hybridised and diamagnetic.
(b) The number of unpaired electron in d6, low spin, octahedral complex is 2.
(c) [Ag(NH3)2]Cl does not show paramagnetism.
(d) Lower charge density of metal ion increases the stability of metal ion complex.
(e) Ferrocene is an aromatic compound.
(f) Oxidation state of iron in ferrocene is +3.
(g) Metal carbonyl [Mn(CO)6]+ has stronger C–O bond than [Cr(CO)6].
(h) Complex [Co(CN)6]3– has larger value of o than the complex [Co(H2O)6]3+.
(i) Azide ion is an ambidentate ligand.
(j) IUPAC name of K2[PtCl6] is Potassium hexachloridoplatinum(IV).

10. NaOH + S  [X] + [Y] + H2O
Total sum of individual oxidation number of all S atoms present in product [X] & [Y] is .............
11. Number of stereo isomers of [Cr(NO3)3 (NH3)3] = x
Number of stereo isomers of K3[CoCl2(C2O4)2] = y
Number of stereo isomers of [CoBrCl(en)2] = z
find x + y + z :
12. When white phosphorus (P4) reacts with caustic soda solution PH3 & NaH2PO2 are obtained. When
reaction is balanced x is the sum of stochiometric coefficients of P4, caustic soda, PH3 & NaH2PO2, find x.
13. Match the following
Column I Column II
A. [Cr(NH3)6]3+ (p) d2sp3
B. [Co(en)3]3+ (q) CFSE = – 1.2 0
C. [Co(NO2)6]4– (r) Paramagnetic
D. [Co(H2O)6]2+ (s) sp3d2
PAGE NO.-28

Daily Self-Study Dosage for mastering Chemistry Crystal Systems
There is an unlimited number of possible lattices because there is no restriction on the length of lattice
translation vector or on the angle  between them. on the basis of geometrical consideration theoritically there
can be 32 different combinations of symmetry of crystal.
On other hand bravais show there is only seven types of crystal system.
(a) Cubic (b) Tetragonal (c) Orthorhombic (d) Rhombohedral (e) Hexagonal (f) Monoclinic (g) Triclinic
Seven Crystal system
Axial
Crystal System Axial angles Examples Type of Unit cells
distances
Cubic a=b=c  =  =  = 90° Cu, ZnS, KCl S,BCC,FCC
Tetragonal a=b c  =  =  = 90° Sn(white tin), SnO2,TiO2 S,BC
Orthorhombic a  b c  =  =  = 90° Rhombic sulphur, CaCO3 S,BCC,FCC,ECC
Monoclinic a b  c  =  = 90°;  90° Monoclinic sulphur, PbCrO2 S,BCC
Hexagonal a=b c  =  = 90°; = 120° Graphite, ZnO S
Rhombohedral a=b=c  =  =   90° CaCO3(Calcite), HgS(Cinnabar) S
Triclinic a  b c  90° K2Cr2O7, CuSO4.5H2O S
c
Cubic   ; Tetragonal c
; Orthorhombic ; Monoclinic ;
b c
b c
 b
a a a
b
a
c
c c
Hexagonal ; Rhombohedral ; Triclinic
b
b
a a
b
a
14. The lattice parameters of a given crystals are a = 8.42 Å, b = 8.42 Å and c = 9.80 Å. There coordinate
axes are mutually perpendicular to each other. The crystal is:
(A) Tetragonal (B) Ortho rhombic (C) Monoclinic (D) Trigonal
15. The crystal dimensions a = b  c;  =  = 900  = 1200 represents.
(A) Tetragonal (B) Hexagonal system (C) Monoclinic (D) Orthorhombic system
16. Which of the following unit cells has least symmetry ?
(A) Tetragonal (B) Monoclinic (C) Triclinic (D) Cubic
17. Among the unit cells given below, which has highest symmetry?
(A) Hexagonal (B) Orthorhombic (C) Cubic (D) Monoclinic

Single correct Objective ('–1' negative marking) Q.1 (3 marks, 2 min.) [03, 02]
PAGE NO.-29
1. Look at the AB solid structure and use it to calculate r+ / r– .
A+ -
M N B
.
K . L
a
(A) 0.155 (B) 0.225 (C) 0.414 (D) 0.732
2. Which of the following is/are true about the complex [PtCl 2(NH3)(OH2)];[Atomic no. of Pt = 78]
(A) It will have two geometrical isomeric forms, cis and trans
(B) It is a square planar complex
(C) It is a diamagnetic complex (D) It can show hydrate isomerism
3. Which is/are correct statement (s)?
(A) [Co(en)3] [Cr(CN)6] will display coordination isomerism.
(B) [Mn(CO)5(SCN)] will display linkage isomerism.
(C) [Co(NH3)5(NO3)]SO4 will display ionisation isomerism
(D) None is correct.
4. The compound Na2IrCl6 reacts with triphenylphosphine in diethyleneglycol in an atmosphere of CO to
give [IrCl(CO)(PPh3)2], known as 'Vaska's compound'. (Atomic number of Ir = 77)
Which of the following statements is /are correct?
(A) The IUPAC name of the complex is carbonylchloridobis(triphenylphosphine)iridium(I).
(B) The hybridisation of the metal ion is sp3 .
(C) The magnetic moment (spin only) of the complex is zero.
(D) The complex shows geometrical as well as ionization isomerism.
5. The correct statement(s) regarding defects solids is (are)
(A) Schottky defect is usually favoured by small difference in the sizes of cation and anion.
(B) Schottky defect lowers the density of solids.
(C) Compounds having F-centres are diamagnetic.
(D) Frenkel defect is a dislocation defect.
6. Which of the following is/are incorrect for Rock salt crystal :
(A) If all Na+ ions occupied at body centre are removed according to schottky defect then formula of
resulting ionic compound would be Na3Cl4.
(B) If Na+ ions would be present in alternate tetrahedral voids then formula would be Na2Cl.
(C) If some Cl– get displaced from the lattice in the presence of Na vapours then colour of compound
will change.
(D) If interionic distance in crystal is 4.2 Å then edge length of unit cell becomes equal to 8.4 Å.
7. Consider the following arrangement :
O2,(g) N2,(g) Adiabatic The gases are at same pressure.

300 K 300 K walls.
x
If O2 and N2 are assumed to behave ideally, then on removing partition X (smoothly), how many of the
following are expected to be correct for this process ?
(i) Ssys < 0 (ii) Ssurr < 0 (iii) Suniv > 0 (iv) U > 0
(v) H > 0 (vi) G < 0
8. To get the silicone R3Si–(OSiR2)n–SiR3 having six Si–O–Si linkage x unit of R2SiCl2 and y unit of R3SiCl
is taken. Value of (x + y) is:
PAGE NO.-30
9. A sample of H-like species is in some excited state 'A' and on absorbing a photon of energy 10.2 eV
gets promoted to a new state B. When the electrons from state 'B' return back to ground state directly
or indirectly, photons of 15 different wave lengths are observed in which only 9 photon have energy
greater than 10.2 eV. Determine atomic number of H-like species. Give your answer after multiplying by 7.
10. The sum of number of hexagonal and triangular faces that are present in a truncated tetrahedron is :
11. The freezing point of an aqueous solution of KCN containing 0.1892 mol kg–1 was 0.70°C. On adding
0.09 mol of Hg(CN)2 in 1kg of above solution the freezing point of solution was –0.53°C. Assuming that
complex is formed according to the equation. Hg(CN)2  X(CN)  [Hg(CN)X  2 ] X 
find X (given Kf of water = 1.86K/molal):
12. Argon crystallizes in fcc arrangement, and the density of solid and liquid Ar is 1.59 g cm – 3 and 1.42 g
cm–3 respectively find the approximate percentage of empty space in liquid Ar.
13. Match the following :
Column I Column II
A. 74% occupancy of space (p) Coordination No. of cation in fluorite structure
B. Coordination No -8 (q) Cubic close packing
C. Ca2+ ion in CaF2 (r) Hexagonal close packing
D. Coordination No. – 12 (s) body centred cubic packing.

Daily Self-Study Dosage for mastering Chemistry Ionic solid AB Type
The lattices in ionic crystals consists of alternative positive and negative ions in equivalent amount arranged in
an order so that the potential energy of the ions in the lattice is minimum and
such crystal normally found in ionic compound.
NaCl  Na+ + Cl –
Limiting radius ratio
r +/r– C.N Shape
<0.155 2 linear
0.155 –0.225 3 planar triangle
0.225 – 0.414 4 Tetrahedral
0.414 – 0.732 4 Square planar
0.414 – 0.732 6 Octahedral
0.732 – 0.999 8 Body- centered cubic
NaCl Type
r
IIn NaCl –
value is 0.52 This value suggests it to be octahedral in shape. In this each Na+ ion surrounded by
r
six Cl– ion and each CI– is surrounded by six Na+ ions. In the octahedral structure of NaCl, Cl – ion may be
regarded as having c.c.p arrangement in which all the octahedral holes are filled by Na+ ions.
Other examples of this structure are halide of Li. Na, K, Rb and Ag (except AgF) oxide and sulphides of Mg,
Sr, Ba.
Anion Cation
PAGE NO.-31
ZnS Type
In ZnS the radius of cation to anion is 0.40 which suggests it to be tetrahedral in shape. Each Zn2+ ion is
tetrahedrally surrounded by four S2– ions and each S2– is tetrahedrally surrounded by four Zn2+ ions. i.e.,
coordination no. of ZnS. is 4.
Thus this structure is termed as 4:4 arrangement it should be noted that zinc blend (ZnS) has ccp structure
while wurtzuite (ZnS) has hcp structure. Other example are CuCI, CuBr, CuI, and BeS.
14. In the zinc blende structure, zinc ions occupy alternate tetrahedral voids and S2– ions exist as ccp. The
radii of Zn2+ and S2– ions are 0.83 Å and 1.74 Å respectively. The edge length of the ZnS unit cell is
(A) 2.57 Å (B) 5.14 Å (C) 5.93 Å (D) 4.86 Å
15. If the distance between Na+ and Cl – ions in NaCl crystal is ‘a’ pm, what is the length of the cell edge?
a a
(A) 2a (B) (C) 4a (D)
2 4
16. Which of the following statement is incorrect about rock salt type structure?
(A) It has FCC arrangement of Na+
(B) Na+ & Cl– ions have co-ordination number of 6 : 6.
(C) A unit cell of NaCl consists of four NaCl units
(D) All halides of alkali metals have rock salt type structure.
17. In the zinc blende structure S2– adopt ccp arragement and Zn2+ occupy.
(A) Octahedral sites (B) Hexagonal sites (C) Tetrahedral sites (D) None of these

1. Heat of hydrogenation of ethene is x 1 and that of benzene is x 2. Hence, resonance energy of benzene
is:
(A) x1 – x2 (B) x1 + x2 (C) 3x1 – x2 (D) x1 – 3x2
2. For a real gas with very large value of molar volume, which of the following equation can most suitably
be applied:
a Pb a
(A) Z = 1 – (B) PVm = RT (C) Z = 1 + (D) PVm – RT =
VmRT RT Vm
3. Given that the critical temperature of oxygen is 154K and its critical pressure is 50 atm, which of the
following statements is are true :
I. In a closed container at 154K and 50 atm, the solid, liquid, and gaseous phase of oxygen are in
equilibrium.
II. Oxygen gas can be liquefied at room temperature.
III. It can be reasoned that ammonia has a critical temperature above 154 K.
(A) I is true (B) II and III are true (C) III is true (D) I and III are true
4. Molecule XF4 has non-zero value of dipole moment. Then X is
(A) Xe (B) Si (C) S (D) none of these
5. Which of the following reacts with NaOH to liberate a gas?
(A) S8 (rhombic sulphur) (B) Cl2
(C) P4 (white phosphorus) (D) C (graphite)
PAGE NO.-32
6. A substance absorbs CO2 and violently reacts with water. The substance is :
(A) CaCO3 (B) CaO (C) H2SO4 (D) ZnO
7. Total number of unit cells in 4 g of X (atomic mass = 40), which crystallises in BCC pattern is (N A =
Avogadro's number):
0.1 NA
(A) 0.1 NA (B) 2 × 0.1 NA (C) (D) 2 × NA
2
8. The osmotic pressure of equimolar solutions of BaCl 2, NaCl and glucose will be in the order
(A) glucose > NaCl > BaCl2 (B) BaCl2 > NaCl > glucose
(C) NaCl > BaCl2 > glucose (D) NaCl > glucose > BaCl2
9. Which of the following will exhibit maximum ionic conductivity?
(A) K4[Fe(CN)6] (B) [Co(NH3)6]Cl3 (C) [Cu(NH3)4]Cl2 (D) [Ni(CO)4]
10. Which of the following will give maximum number of isomers ?
(A) [Co(NH3)4Cl2] (B) [Ni (en)(NH3)4]2+ (C) [Ni(C2O4)en2]2– (D) [Cr(SCN)2(NH3)4]+
11. Atomic number of Cr and Fe are respectively 24 and 26, which of the following is paramagnetic with the
spin of electron?
(A) [Cr(CO)6] (B) [Fe(CO)5] (C) [Fe(CN)6]4– (D) [Cr(NH3)6]3+
12. According to IUPAC nomenclature, sodium nitroprusside is named as :
(A) Sodium nitroferricyanide (B) Sodium nitroferrocyanide
(C) Sodium pentacyanidonitrosoniumferratae(II) (D) Sodium pentacyano nitrosylferrate (III)
13. Which of the following coordination compounds would exhibit optical isomerism?
(A) Pentaamminenitrocobalt (III) iodide
(B) Diamminedichloroplatinum (II)
(C) Trans-dicyanobis (ethylenediamine chromium (III) chloride)
(D) Tris-(ethylenediamine) cobalt (III) bromide
14. Which of the following complexes exhibits the highest paramagnetic behaviour?
Where, gly = glycine, en = ethylenediamine and bipy = bipyridyl moities)
(At no Ti = 22, V = 23, Fe = 26, Co = 27)
(A) [V(gly)2(OH)2(NH3)2]+ (B) [Fe(en)(bipy)(NH3)2]2+
(C) [Co(OX)2(OH)2] –
(D) [Ti(NH3)6]3+
15. Which of the following complex ions is not expected to absorb visible light ?
(A) [Ni(CN)4]2– (B) [Cr(NH3)6]3+ (C) [Fe(H2O)6]2+ (D) [Ni(H2O)6]2+
16. In which of the following pairs, both the complexes show optical isomerism ?
(A) cis-[Cr(C2O4)2Cl2]3– , cis-[Co(NH3)4Cl2] (B) [Co(en)3] Cl3 ,cis-[Co(en)2Cl2]Cl
(C) [PtCl(dien)Cl] , [NiCl2Br2]2– (D) [Co(NO3)3(NH3)3], cis-[Pt(en)2Cl2]
17. Calculate total number of possible isomers (structrural and stereoisomers) of the compound
[Ir(en)2(NH3)(NO2)]2+
Total number of oxygen atoms shared per SiO44 unit in  Si2O5 n

2n
18. are :
19. If two solutions of pH = 2 and pH = 4 be mixed respectively in volume ratio 1 : z, the pH of the resulting
solution was found to be 2.75. Find the value of z. (Given : log 1.75 = 0.25)
20. The bond dissociation energy of gaseous H2, Cl2 and HCl are 104, 58 and 103 kcal mol –1 respectively.
Calculate the enthalpy of formation for HCl gas.
21. How many corners are there in octahedron ?
PAGE NO.-33

Daily Self-Study Dosage for mastering Chemistry Magnetic properties
Based on the behaviour of substances when placed in the magnetic field, they are classified into five classes.
Properties Description Alighment Examples Application
Replled by the magnetic field.
They contains paired electron All paired e–
Diamagnetic and unpaired electrons are TiO2, V2O5. Insulator
absent. Non metallic \
elements (excepts O2,S).
Attracted by the magnetic At least unpaired
O2, Cu2+, Fe3+, Electronic
Paramagnetic field due to the presence of electron
VO2, CuO appliances
permanent magnetic dipoles
Dipoles are
Permanent magnetism even aligned in the CrO2 is used in
Ferromagnetic in the absence of magnetic same direction Fe, Ni, CO, CrO2 audio and video
field. tapes
MnO, MnO2,
This arises when the dipole
Mn2O, FeO, FeO2;
Antiferromagnetic alignment is zero due to equal -
NiO, Cr2O3, CoO,
and opposite alignment.
CO3O4
FeO3O4
(Magnetite),
This arises when there is net
Ferrimagnetic ferrites like -
dipole moment.
MgFe2O4,
ZnFe2O4
22. Which of the following is correct option
(A) O2 is show diamagnetic properties. (B) S is show diamagnetic properties.
(C) TiO2 show diamagnetic properties. (D) VO2 show diamagnetic properties.
23. Which is the following is correctly match
(A) Diamagnetic  (B) Paramagnetic 
(C) Ferromagnetic  (D) Antiferromagnetic 
24. Which of the following is correct option.

(A) Diamagnetic properties showing material repelled by magnetic field.
(B) Paramagnetic showing properties material used for making T.V and washing machine
(C) Both are correct.
(D) None of these
25. Which of the following statement is not true
(A) In ferromagnetic the dipoles are aligned in same direction.
(B) In the ferrimagnetic the net dipole moment is zero
(C) Ferromagnetic properties showing material used for making audio & video tapes.
(D) Antiferromagnetic arises when dipole moment is zero.

Single correct Objective ('–1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06]
PAGE NO.-34
1. Liquid A having vapour pressure of 100 torr in pure state exhibited vapour pressures of 50 torr and 25
torr when its fixed amount was dissolved in certain amounts of liquid B and liquid C respectively. What
will be the vapour pressure of A when both the solutions are mixed? (Assume ideal mixtures)
(A) 37.5 torr (B) 75 torr (C) 12.5 torr (D*) 33.3 torr
(E) 25 torr
2. Consider a cube containing n unit cells of a cubic system.
A
A
D B
D B
C C
Arrangement of atoms
A plane ABCD obtained by joining the mid points of the edges on one of the its identical faces had
atoms arranged as shown. Let p be the packing fraction. Choose the correct option :
22 11 11 11 3
(A) n = 1 , p = (B*) n = 8 , p = (C) n = 8, p = (D) n = 1 , p =
21 2 21 14 28
3. An aqueous solution of borax :

(A) Turns blue litmus to red
(B) Is a powerful oxidising agent
(C) Is a popular bleach used in paper and pulp industry
(D*) Can be titrated with HCl.
4. If heat of formation of PCl3 (g) and PH3 (g) are 140 and 8 KJ mol–1 respectively and heat of atomization
of phosphorous P4(s), chlorine and hydrogen are 320, 120 & 216 KJ mol –1 respectively then, find which
of the following is/are correct statement(s).
(A) The bond energy of P–Cl is 63 KJ mol–1
(B) The bond energy of P–H is 210 KJ mol–1
(C*) Heat of formation of isolated gaseous hydrogen atom is 108 KJ mol –1
(D*) Heat of formation of isolated gaseous chlorine atom is 60 KJ mol –1
5. One mole of an ideal gas contained in a sealed flask at 1 atm is heated from 27ºC to 127ºC. (Given :
S(JK–1) = 10 + 12× 10–3 T, R = 0.082 atm L/mol K, 1 atm L = 101.3 J). Select correct option(s):
(A) V = 12.3 L (B*) Final pressure is 4/3 atm
(C*) G = –589.34J (D) G = 322.5 J
Comprehension #
In the valence bond theory, hybridisation of orbitals is an integral part of bond formation. Hybridisation
consists of mixings or linear combination of the "pure" atomic orbitals in such a way as to form new
hybrid orbitals such as sp, sp2, sp3, sp3d, sp3d2 etc.
Now answer the following questions:
6. Which of the following atomic orbital(s) participates in trigonal bipyramidal hybridisation i.e. sp 3d
hybridisation?
(I) dZ2 (II) d 2 2 (III) dxy (IV) pz
x –y
(A) II, IV (B) III, IV (C*) I, IV (D) Only II
7. Which of the following atomic orbitals participitates in hybridisation in [Pt(NH 3)4]+2 as well as in
[Cr(CN)6]3–?
(I) s (II) d 2 2 (III) d 2 (IV) px
x –y z
(A) III, IV (B) I, III, IV (C) I,II,III, IV (D*) I, II, IV
8. N2H4 is a diprotic base with pKb1 = 5.2, pKb2 = 16.7, 0.1 M aq. solution of N2H62+(Cl–)2 has pH closest to
................. (choose the nearest integer).
PAGE NO.-35
9. Six identical spheres of radius R are arranged at each corner of prism as shown in the figure. Its
packing fraction is x, then 10x is :
2R
2R
10. A tube of uniform cross sectional area 1 cm 2 is closed at one end with semi permeable membrane. A
solution having 6 g glucose per 100 ml is placed inside the tube and dipped in pure water at 27C.
When the equilibrium is established, what will be the osmotic pressure, height developed in vertical
column (in meters). Density of glucose solution is 1 gm/ml. (Take R = 0.08 L atm mol –1 k–1, density of
Hg = 13.8 g/cc)
11. Total number of geometric isomers possible for the complex [CoL2Cl2]– (unsymmetrical bidentate ligand
L = H2NCH2CH2O–) is:
12. An aqueous solution contains 6% and 4% by weight weak acid (HA) and urea respectively. Depression
13.6
in freezing point of solution is ºC. If Ka of HA is x, then fill the value of 100x. [Kf = 1.8 K-Kg/mole]
3
(Molecular weight of HA = 60, dsolution = 1gm/ml). Assume no reaction between HA and urea.
13. Number of organometallic compounds in the following are –

[PtCl3(η 2-C2H4)]–, [Ni(CO)4], Al2(CH3)6, (C2H5)3B, (CH3)2CuLi, Na2CO3, [Fe(η 5-C5H5)2], CH3MgX,
(CH3COO)2Pb
14. Portland cement contains how many of the following compounds?

MgO, MgCO3, MgCl2, CaO, SiO2, Fe2O3, CaSO4, FeSO4, SO3, Al2O3 and CaCl2.
write your answer after multiplying by 4.
15. Equal volume of 0.2 M CH3COOH is mixed with 0.2 M NaOH solution then determine pH of resulting
solution? Write your answer after multiplying by 9. [Ka(CH3COOH) = 10–5]
16. A 0.25 molal aqueous solution of Co(NH3)4Cl3 freezes at –0.93ºC. Calculate the number of
stereoisomers for this coordination compound. Molal depression constant for H2O is 1.86 K/molal.
(Assume complete dissociation of the coordination compound into its ions)

1. The density of a hypothetical gas X (mol. wt = 8 amu) has been observed to be less than g/L at STP.
Then, which of the following statements is/are correct for gas X under above conditions :
(A) Repulsive tendencies are dominant among molecules of gas X.
(B) The value of TB (Boyle's temperature) for gas X is greater than 273.15 K.
(C) The value of Vm (molar volume) for gas X is less than 22.4 L
(D) Gas X is less compressible with respect to an ideal gas.
2. Which is true about NH2–, NH3 ,NH4+ ?
(A) Hybridization of N is same.
(B) No. of lone pair of electron on N are same.
(C) Molecular geometry (i.e. shape) is different.
(D) Bond angle is same.
PAGE NO.-36
3. In which of the following molecules central atom involve expansion of octet?
(A) PCl5 (B) SO4– – (C) NH3 (D) ClO3–
4. The qualitative order of Debroglie wavelength for electron, proton and  particle is e > P >  if
(A) If kinetic energy is same for all particles
(B) If the accelerating potential difference 'V' is same for all the particles (from rest)
(C) If velocities are same for all particles
(D) None of the above
5. An equilibrium A(g) 2B(g) has been established in a one litre container. At equilibrium, moles of A
and moles of B are found to be equal (2 moles each). Now, if the volume of reaction vessel is halved
keeping the temperature constant and the equilibrium is allowed to restablish, then which of the
following statements is/are true ?
(A) The concentrations of A and B at new equilibrium are 4.5 M and 3 M respectively.
(B) The equilibrium can be said to be shifted in forward direction upon reducing the volume to half.
(C) The equilibrium can be said to be shifted in backward direction upon reducing the volume to half.
(D) The equilibrium will not shift in any direction upon reducing the volume to half as moles of A and B
at initial equilibrium are equal (2 each.)
6. In a cubic cell atoms A are present at corners while A atoms are missing from face centers. B atoms
are at edge centers and body center. C atoms are present at the body center of each small cube (edge
length a/2).Then select the correct statement(s) : (a = edge length cube)
(A) Formula of compound is ABC2
(B) If all the atoms along one of the body diagonal are removed then ratio of atoms A,B,C is 1 : 4 : 8 in
resultant structure
(C) Ratio of A, B, C atoms (effectively) in a small cube is 1 : 4 : 8
(D) In small cube only five corners are occupied
7. Depression of freezing point of 0.01 molal aqueous CH3COOH solution is 0.02046°. 1 molal aqueous
urea solution freezes at –1.86°C. Assuming molality to be equal to molarity, calculate pH of CH3COOH
solution.
8. For aqueous solution of how many of the following compounds / mixtures, does the pH remains constant
even upon dilution:
(1) NH4Cl (2) Na2CO3
(3) A 1 : 2 molar ratio mixture of Na2S and HCl. (4) A 5 : 2 molar ratio mixture of NaOH and H3PO4.
(5) A 5 : 4 molar ratio mixture of CH3COONa and HCl.
(6) NaH2PO4 (7) A 2 : 1 molar ratio mixture of HCl and NaHCO3.
(8) CH3COONH4 (9) A 4 : 3 molar ratio mixture of NH4OH and HCl.
500
9. An aqueous m solution of a non-volatile and non-electrolyte solute is taken in a closed container.
81
Calculate percentage relative humidity present inside the container at equilibrium.
10. In how many following species, the central atoms have two lone pairs of electrons ?
XeF4 XeF5– F2SeO2 XeF3+ XeOF4 ClOF3
ICl4–
SCl2 OSF4
11. For the Complex formula [Co(NH3)3(NO2)2Cl] :
The coordination number of central atom = a
The oxidation number of central atom = b
Total number of geometrical isomres (considering all structural isomers) = c
Total number of optical isomres (considering all structural isomers) = d
The value of (a + b - c+ d) for given complex is :
12. Consider the following molecules: O2, Cl2, Li2, H2, B2, C2 and N2
Let a = number of molecules having (bond order = 1)
b = number of molecules having (bond order = 2)
c = number of molecules having (bond order = 3)
d = number of paramagnetic molecules.
Find the value of (a × b × c × d × 4.2).
PAGE NO.-37
13. Match the column
Column – I Column – II
(A) H+ (aq) (p) Hf0 = 0
(B) H (gas) (q) Hf0  0
(C) H2 (gas) (r) Gf0 = 0
(D) C (s, diamond) (s) Hf0 > 0
Daily Self-Study Dosage for mastering Chemistry Topic: Galvanic Cell & Salt Bridge
A device used to convert chemical energy produced in a redox reaction into electrical energy is called an
electrochemical cell or simply chemical cell. These are also called galvanic cells or voltaic cells, after the name
of Luigi Galvani (1780) and Alessandro Volta (1800).
If the electrodes in a galvanic cell are not connected internally, initially the cell generates electrical energy. The
electrodes get polarized with passage of time and the cell stops working. For continuous of electrical energy,
the electrodes need to be internally connected.
A salt bridge is usually used to connect the electrodes of a galvanic cell. It is easy to construct and
consists of a gell drawn into a clean U-tube. The gel is formed by adding agar-agar into boiling water containing
a inert electrolyte like KCl. Generally, KCl is preferred because the ionic conductances of K+ and Cl– are almost
the same. The gel holds the electrolyte in the tube as shown in below Fig.
Fig : Salt bridge and electrolyte

As the reactions proceed in the galvanic cell, there will be accumulation of particular ions around the
electrodes. This results in a slowdown of the electrode reactions. From the electrolyte of the salt bridge, say
KCl, the K+ and Cl– ions migrate towards the end of the salt bridge K+ ions would migrate towards the
reducation electrode (cathode) while Cl– ions would migrate towards the oxidation electrode (anode). At the
oxidation electrode (anode), ions would polarize (attract) some of the oppositely charged ions towards
themselves. Simultaneously, the K+ ions would move towards the reduction electrode (cathode) and polarize
the negatively charged ions surrounding the metal. Thus, the cell works as usual. Hence, a salt bridge is helpful
in the following ways.
1. It brings about internal contact between the electrodes.
2. It minimizes the liquid junction potential.
3. It minimizes polarization.
14. In which of the following cells salt bridge is not needed ?
(A) Pb | PbSO4(s) | H2SO4 | PbO2 | Pb (B) Cd | CdO(s) | KOH(aq) | NiO2(s) | Ni
(C) Fe(s) | FeO(s) | KOH (aq.), Ni2O3(s) | Ni (D) Zn | ZnSO4 | CuSO4 | Cu
15. The reaction 1/2 H2(g) + AgCl(s)  H(aq) + Cl–(aq) + Ag(s) occurs in the galvanic cell
(A) Ag | AgCl(s) | KCl (sol) | AgNO3 | Ag (B) Pt | H2(g) | HCl(sol) | AgNO3(sol) |Ag
(C) Pt | H2(g) | HCl (sol) | AgCl(s) | Ag (D) Pt | H2(g) | KCl(sol) | AgCl(s) |Ag
16. A saturated solution of KNO3 is used to make salt bridge because
(A) The velocity of K is greater than that of NO3–.
(B) The velocity of NO3– is greater than that of K
(C) The velocities of K and NO3– are nearly the same
(D) KNO3 is highly soluble in water.
PAGE NO.-38

1. The virial equation for 1 mole of a real gas is written as
 A B C 
PV = RT 1     .....to higher power of n
V 2 3
 V V 
Where A,B and C are known as virial cofficients. If Vander waal's equation is written in virial form, then
what will be the value of A.
b a a RT  b
(A) a – (B) RT – (C) b – (D)
RT b RT a
2. What is the correct increasing order of liquifiability of the gases shown

as in above graph ?
(A) H2 < N2 < CH4 < CO2
(B) CO2 < CH4 < N2 < H2
(C) H2 < CH4 < N2 < CO2
(D) CH4 < H2 < N2 < CO2
3. CaCN2 has :
(A) 2  bonds , 2  bonds (B) 3  bonds , 1  bond
(C) 1  bond , 2  bonds (D) 3  bonds , 2  bonds
4. Which of the following statements is correct ?
(A) N2F3+ is planar at each nitrogen atom.
(B) In N3H, the H – N – N bond angle is exactly of 120°.
(C) The shape of N(SiMe3)3, is trigonal planar.
(D) (A) and (C) both.
5. The species that do not contain peroxide ions are :
(A) PbO2 (B) H2O2 (C) SrO2 (D) BaO2
6. In given galvanic cell : Pt | H2 g | NaClaq || AgNO3 aq | Ag
On adding water into L.H.S. compartment e.m.f. of the cell :
(A) Increases (B) decreases (C) remains unchanged (D) None of these
7. Molecular formula of Glauber`s salt is :
(A) MgSO4.7H2O (B) CuSO4.5H2O (C) FeSO4.7H2O (D) Na2SO4.10H2O
8. The oxidation of SO2 by O2 to SO3 is an exothermic reaction. the yield of SO3 will be maximum if
(A) temperature is increased and pressure is kept constant.
(B) temperature is reduced and pressure is increased.
(C) both temperature and pressure are increased.
(D) both temperature and pressure are reduced.
9. In Galvanic cell :
(A) Chemical reaction produces electrical energy (B) Electrical energy produces chemical reaction
(C) Reduction occurs at anode (D) Oxidation occurs at cathode
10. E° for some half cell reactions are given below
Sn+4 + 2e–  Sn2+ ; E° = 0.151 V
2Hg2+ + 2e–  Hg2+2 ; E° = 0.92 V
PbO2 + 4H+ + 2e–  Pb2+ + 2H2O ; E° = 1.45 V
based on the given data which statement is correct.
(A) Sn4+ is a stronger oxidising agent than Pb+4 (B) Sn2+ is a stronger reducing agent than Hg22+
(C) Hg2+ is a stronger oxidising agent than Pb4+ (D) Pb+2 is a stronger reducing agent than Sn2+
PAGE NO.-39
Cr2O72 0
11. For the cell prepared from electrode A and B, electrode A : , Ered = +1.33 V and electrode B:
3
Cr
3
Fe 0
, Ered = 0.77 V, which of the following statement is not correct?
2
Fe
(A) The electrons will flow from B to A (in the outer circuit) when connections are made.
(B) The standard emf of the cell will be 0.56 V.
(C) A will be positive electrode.
(D) None of the above.
12. Which statement about standard reduction potentials is correct

(A) EH 
/H
= Zero at all temperature
2

(B) ED 
/D2
= zero at 298 K
(C) A redox reaction is feasible if sum of SRP of oxidant and that of reductant is a positive quantity
(D) K2Cr2O7 (acid) is stronger oxidising agent than KMnO4 (acid)

[Given : EMnO –
/Mn2
= 1.51 V ; E 2 – 3  = 1.33 V]
4 Cr2O7 / Cr
13. A 0.004 M solution of Na2SO4 is isotonic with 0.010 M solution of glucose at same temperature. The
apparent percentage dissociation of Na2SO4 is -
(A) 25% (B) 50% (C) 75% (D) 85%
14. The concentration of free HN3 in a 0.01 M solution of KN3 if Ka = 1.9 × 10–5 is
(A) 2.3 mol/ML (B) 3.3 mol/ML (C) 4.3 mol/ML (D) 5.3 mol/ML
15. An excess of AgNO3 is added to 100 mL of a 0.01M solution of dichlorotetraaquachromium (III)
chloride. The number of moles of AgCl precipitated would be :
(A) 0.002 (B) 0.003 (C) 0.01 (D) 0.001
16. The de Broglie wavelength associated with a ball of mass 1 kg having kinetic energy 0.5 J is :
(A) 6.626  10–34 m (B) 13.20  10–34m (C) 10.38  10–21 m (D) 6.626  10–34 Å
17. The correct order for the wavelength of absorption in the visible region is :
(A) [Ni(NO2)6]4– < [Ni(NH3)6]2+ < [Ni(H2O)6]2+ (B) [Ni(NO2)6]4– < [Ni(H2O)6]2+ < [Ni(NH3)6]2+
2+ 2+ 4+
(C) [Ni(H2O)6] < [Ni(NH3)6] < [Ni(NO2)6] (D) [Ni(NH3)6]2+ < [Ni(H2O)6]2+ < [Ni(NO2)6]4–
Comprehension #
(Read the following passage and answer the questions numbered 18 to 20. They have only one
correct option)
Standard reduction potentials (SRP) for different systems can be used to decide the spontaneity of a
reaction e.g. EZn 2 Zn = – 0.76V, hence for the reaction Zn + 2H+  Zn2+ + H2, G° is negative. It has
been found experimentally that if (SRP of an oxidant – SRP of a reductant) is more than 1.7V, then
their combination may lead to explosion (though it may be prevented by kinetic factors).
Now go through the following data and answer the questions.

Data : EAg /Ag = 0.80 V ; EN /N ¯ = – 3.09 V
2 3
E ¯ = 1.23 V ; 
ENa  = – 2.71 V
ClO4 / ClO3 /Na

EFe3
/ Fe2
= 0.77 V ; EO2 / H2O2 = – 1.03 V
 
EH 2O2 / H2O
= 1.76 V ; EO 3 / O2
= 2.07 V

EMnO /Mn2
= 1.54 V ; E  = 1.33 V
–
4 Cr2O72 –
/ Cr 3
18. Which of the following ionic combinations may lead to the formation of explosive substance.
(A) Sodium ion and azide ion (B) Silver ion and perchlorate ion
(C) Silver ion and azide ion (D) All the above
PAGE NO.-40
19. Which of the following ions will be capable of causing catalytic decomposition of H2O2.
(A) Fe3+ (B) Fe2+ (C) both (D) None of these
20. Which is correct about the reaction between H2O2 and O3
(A) It is a case of mutual reduction
(B) O3 will oxidise H2O2 into O2
(C) It is not a redox reaction
(D) H2O2 being a stronger oxidising agent will decompose ozone into oxygen
21. The bond order of the underlined species; NOHSO4 is :
22. Specify the most stable complex among the following complexes. (Report your answer as 1 or 2 or 3).
1. [Fe(NH3)6]3+ , 2. [Fe(en)3]3+ , 3. [Fe(dien)2]2+
23. If the de-Broglie wavelength of electron in pth orbit of He+ ion is 11.66 Å, find the value of p. Given
radius of Ist orbit of H-atom is 0.53 Å.
a b c d
24. Find the value of      , where a = coordination number in BCC structure; b = coordination
8 6 2 1
number of simple cubical structure; c = effective number of particles in BCC unit cell and d = effective
number of particles in simple cubical unit cell.
25. The density of a gas filled in an electric lamp is 0.75 kg/m 3. When lamp is switched on, the pressure in it
increases from 4 Pa to 25 Pa, then what is increase in urms in m/sec.

Total Marks: 71 Max. Time : 42 min.
1. Given is an equation of state for real gas, where A and B are constants. P : Pressure and V : Molar
A 2B
volume, PV = RT – 
V V2
Find 1/Z at critical point.
(A) 3 (B) 2 (C) 1 (D) None of these
2. When zeolite, which is hydrated sodium aluminium silicate, is treated with hard water the sodium ions
are exchanged with
(A) H+ ions (B) Ca2+ ions (C) SO42 – ions (D) Mg2+ ions
3. Highly pure dilute solution of sodium in liquid ammonia :
(A) shows blue colour. (B) exhibits electrical conductivity.
(C) produces sodium amide. (D) produces hydrogen gas.
4. The standard reduction potentials of some half cell reactions are given below:
PbO2 + 4H+ + 2e– Pb2+ + 2H2O Eº = 1.455 V
MnO4– + 8H+ + 5e– Mn2+ + 4H2O Eº = 1.51 V
Ce4+ + e– Ce3+ Eº = 1.61 V
+
H2O2 + 2H + 2e– 2H2O Eº = 1.71 V
Pick out the correct statement :
(A) Ce+4 will oxidise Pb2+ to PbO2 (B) MnO-4 will oxidise Pb2+ to PbO2
(C) H O will oxidise Mn+2 to MnO-
2 2 4 (D) PbO will oxidise Mn+2 to MnO-
2 4
5. Which of the following factors do not favour electrovalency?

(A) Low charge on ions (B) High charge on ions
(C) Large cation and small anion (D) Small cation and large anion
PAGE NO.-41
6. An energy of 40.8 eV is required to excite a Hydrogen-like species from 1st Bohr orbit to second. Which
is/are correct statement(s) :
(A) Atomic number of H-like species is 2.
(B) Ionisation energy of H-like species is 122.4 eV.
(C) Kinetic energy of electron in 1st orbit is 54.4 eV.
(D) Energy of second orbit is –13.6 eV.
10 m
7. Gas (P) Gas (Q)

M First appearance of visible ring
(Mid Point)
Gases (P) and (Q) may respectively be (Atomic masses : N = 14, B = 10.7, H = 1, O = 16, Br = 80,
As = 75)
(A) H2, N2 (B) B2H6, NH3 (C) B2H6, AsH3 (D) NH3, HBr
8. Select correct statement (s):
(A) In absence of s-p mixing B2 molecule is diamagnetic
(B) Colour of F2 is due to HOMO – LUMO transition
(C) Bond order of O2 is more than O2+
 
(D) Stability order of following ions/molecule is : Li 2  Li 2  Li 2
9. For a perfectly crystalline solid, (CP)m = aT3, where a is a constant. If (CP)m at 10K is 0.375 J/K-mol,
then find the value of molar entropy at 20K (in J/K-mol).
10. 0.1 M solution of a weak acid HA is titrated against 0.05 N NaOH solution. Calculate pH at 1/4th and
3/4th neutralization of acid. Given that the pH of 0.1 M HA solution is 3.
pH1  pH2
Report your answer as .
2
11. Consider an fcc lattice sectioned along the shaded plane shown in figure.
One such plane is shown in figure. Give the number of atoms in plane
DBF which are in direct contact with an atom placed at point C of metallic
fcc lattice.
12. Calculate (a) Ka for a monobasic acid whose 0.10 M solution has pH of 4.5.
(b) Kb for a monoacidic base whose 0.10 M solution has a pH of 9.7.
Report your answer as 2Kb / Ka.
13. Match the column :

Column-I Column-II
(A) 74% occupancy of space (p) Coordination No. of cation in fluorite structure
(B) Coordination No-8 (q) Cubic close packing
(C) Ca2+ ion in CaF2 (r) Hexagonal close packing
(D) Coordination No.-12 (s) body centred cubic packing.
Daily Self-Study Dosage for mastering Chemistry Topic: Lead Storage Batterty (Lead-Acid Battery)
The lead storage battery used in cars was first demonstrated to the French Academy of Sciences by Gaston
plante in 1860. It contained nine cells in parallel and was able to deliver extraordinarily large currents. The cells
were constructed from lead plates separated by layers of flannel that were immersed in a 10% H2SO4 solution.
As might be expected, the system soon became known as the
PAGE NO.-42
Lead-acid battery
Lead storage cell consists of lead grid filled with spongy lead which acts as the anode and a lead grid packed
with lead oxide that acts as the cathode. A number of (generally six) such electrode pairs are dipped in
sulphuric acid solution (20%) which acts as the electrolyte and these are separated by inert and porous
partitions. When the battery discharges, PbO2 is reduced to PbSO4 . When it is charged, the reaction is
reversed. The standard electrode potential for the half-reaction is 1.682 V. The cell reactions are as follows:
At the anode: Pb(s) + SO42– (aq)  PbSO4(s) + 2e–
At the cathode: PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–  PbSO4(s) + 2H2O(I)
Overall reaction: Pb(s) + PbO2(s) + 2H2SO4 (aq)  2PbSO4(s) + 2H2O(I)
The cell reaction shows that the electrolyte H2SO4 is consumed during the reaction, so as the reaction
proceeds, the concentration of H2SO4 decreases. Once the concentration of H2SO4 has fallen to a certain
permissible level, the battery needs to be recharged by reversing the discharge reaction. For this, an external
potential higher than the cell potential is applied. The cell then operates like an electrolyte cell and the PbSO 4
deposited on the electrodes is reverted to Pb and PbO2 by the following reactions:
At the anode: PbSO4(s) + 2H2O(I)  PbO2(s) + 4H+ (aq) + SO42– (aq) + 2e–
At the cathode: PbSO4(s) + 2e–  Pb(s) + SO42–(aq)
Overall reaction: 2PbSO4(s) + 2H2O(I)  Pb(s) + PbO2(s) + 4H+ (aq) + 2SO42–(aq)
The cell reactions show that the concentration of H2SO4 increases during recharging of the cell. The potential
developed by each electrode pair is about 2V and higher potential can be obtained by connecting a number of
electrode pairs in series. These batteries find extensive use as automobile batteries, besides being used for
electrical supply in trains, hospitals, etc.
The Lead Storage battery
14.Th cathode reaction during the charging of a lead-acid battery leads to the
(A) Formation of PbSO4 (B) Reduction of Pb2+ to Pb
(C) Formation of PbO2 (D) Deposition of Pb at the anode
15. In a lead storage battery
(A) Pb is oxidized to PbSO4 at the anode
(B) PbO2 is reduced to PbSO4 at the cathode
(C) Both electrodes are immersed in the same aqueous solution of H2SO4
(D) All the above are true
16. Which of the following reactions occurs at the anode during the recharging of lead storage battery ?
(A) Pb + SO42– PbSO4 + 2e– (B) Pb + PbO2 + H2SO4 2PbSO4 + 2H2O
(C) PbSO4 + 2e– Pb + SO42– (D) PbSO4 + 2H2O PbO2 + 4H+ + SO42– + 2e–
17. When a lead storage battery is discharged,
(A) SO2 is evolved (B) Lead is formed
(C) Lead sulphate is consumed (D) Sulphuric acid is consumed
PAGE NO.-43

1. Values of heats of formation for SiO2 and MgO are –48.4 and –34.7 kJ respectively. The heat of the
reaction 2Mg + SiO2 2MgO + Si is -
(A) 21.16 kJ (B) – 21.00 kJ (C) – 13.62 kJ (D) 13.6 kJ
2. In the reaction CO2(g) + H2(g) CO(g) + H2O(g); H = 2.8 kJ H represents

(A) heat of reaction (B) heat of combustion (C) heat of formation (D) heat of solution
3. Heat of neutralisation of a strong acid by a strong base is equal to H of -

(A) H+ + OH– = H2O (B) H2O + H+ = H3O+
(C) 2H2 + O2 = 2H2O (D) CH3COOH + NaOH = CH3COONa + H2O
4. Which of the following relations hold good (where symbols have their usual meaning) :
 T2   T 
(A)  a  C  (B)  b  C  (C) A and B both (D) None of these
 PC   PC 
5. Which of the following statements are correct ?

(a) The number of sigma bonds in CH2 = C = C = CH2 is 7.
(b) All the hydrogen atoms in CH2 = C = C = CH2 lie in the same plane.
(A) Only (a) (B) Only (b) (C) Both (a) and (b) (D) Neither (a) nor (b)
6. The orbital angular momentum of a p-electron is given as :

h h 3h h
(A) (B) 3 (C) (D) 6.
2 2 2 2
7. In which of the following cases, vapour pressure is more as compared to I. (Consider all solutes to be
non-volatile solutes).
I = 0.2 m solution of C12H22O11.
II = Mixture of 1011.6 g, 0.2 molal acetone and 1012 g, 0.2 molal urea.
III = Solution of 0.2 mol NaOH in 1 Kg water.
IV = Solution of 0.2 mol NaCl in 3 Kg water.
(A) II (B) III (C) IV (D) None
8. Which of the following is paramagnetic in nature?
II
(A) K 4 [F e(CN)5 (O2 )] (B) Na 4 [Fe(CN)5 (NOS)]
3
(C) [Co(H2O)6 ] (D) (A) & (C)
9. Hº of which of the following reactions is zero?

(A) H2(g)  2H+(g) + 2e (B) 2H(g) 2H+(g) + 2e
(C) H2(g) + aq 2H+(aq) + 2e (D) 2H(g) + aq 2H+(aq) + 2e
10. The correct name of [Pt(NH3)4Cl2][PtCl4] is :

(A) tetraamminedichloridoplatinum(II) tetrachloridoplatinate (IV).
(B) dichloridotetraammineplantinum(IV) tetrachloridoplatinate(II).
(C) tetraamminedichloridoplatinum(IV) tetrachloridoplatinate(II).
(D) tetrachloridoplantinum(II) dichloridotetraammineplatinate(IV).
PAGE NO.-44
11. Which of the following is not a function of salt bridge in an electrochemical cell ?
(A) To maintain electrical neutrality of the solution
(B) To complete the circuit so that current can flow.
(C) To supply ions to cathodic and anodic compartment.
(D) To increase cell voltage
12. What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO 3 and 0.1 M NaCl are mixed
together:
(A) 0.1 M (B) 0.2 M (C) 0.05 M (D) 0.25 M
13. From the figure representing enthalpy change of various transitions as indicated,
a substance has maximum enthalpy when present in -
(A) solid state (B) liquid state
(C) gaseous state (D) equal in all states
14. The mass of 75% pure Glucose (C6H12O6) required to prepare 50 mL of its M/9 aqueous solution is :
4
(A) 4 g (B) 1 mg (C) 1 g (D) g
3
15. Atomic mass of Cesium is 133 u and atomic mass of Chlorine is 35.5 u. How many unit cell are present
in 16.85 g of CsCl ?
(A) 6.023 × 1022 (B) 1.204 × 1022 (C) 6.023 × 1021 (D) 1.204 × 1023
16. The straight chain polymer is formed by :

(A) hydrolysis of (CH3)3 SiCl followed by condensation polymerization.
(B) hydrolysis of (CH3)2 SiCl2 followed by condensation polymerization.
(C) hydrolysis of (CH3) SiCl3 followed by condensation polymerization.
(D) hydrolysis of (CH3)4 Si followed by condensation polymerization.
17. Let the total number of orbitals in ath shell be 16 and value of azimuthal quantum number for the
unpaired electron in vanadium atom (Z = 23) be ‘b’, then find the sum (a + b).
(A) 4 (B) 5 (C) 6 (D) 3
18. Find the sum of number of P-P bonds and P-S bonds in a molecule of P4S3.
19. How many geometrical isomers of [Pt(NH3)2Cl2(H2O)2]2+ are possible ?

20. Atoms from six body centered cubical unit cell are taken and rearranged into FCC structure. Find the
number of FCC unit cells created.
21. Calculate the pressure (in bar) exerted by 6 × 1024 gas particles each of mass 3 × 10–22 gm in a
coutainer of volume 10 litre. The rms speed is 105 mm sec–1.
22. pH of the solution in the anode compartment of the following cell at 25ºC is x when
Ecell – Eºcell = 0.0591 V, Pt(H2) (1 atm) | pH = x | | Ni2+ (1 M) | Ni. Find out x.
Daily Self-Study Dosage for mastering Chemistry Topic: Fuel Cell
Conventionally energy is obtained by the combustion of the fossil fuel. The conversion into electrical energy
involves a number of steps and there is loss of energy at every step. The efficiency of the process is around
40%. There is also a viable way of converting the chemical energy of fuel directly into elecrtical energy through
catalytically activated redox reactions. Such devices are called fuel cells. In other words, fuel cells are galvanic
cells in which the electrical energy is directly derived from the redox reactions of the fuel.
The representation of the fuel cell is Fuel | Electrode | Electrolyte | Electrode | Oxidant
Overall cell reaction: Fuel + Oxidant  Oxidation product + Reduction product
PAGE NO.-45
Hydrogen–Oxygen Fuel Cell
This fuel cell combines hydrogen and oxygen to produce electricity, heat and water. It converts chemical energy
to electrical energy and thus can be compared to a battery. the only difference being that as long as hydrogen
is upplied, it continues to produce electricity without being discharged.
Fig. A block diagram of hydrogen-oxygen fuel cell

Design and working :
The whole setup consists of chambers (Fig.). The first chamber serves as an inlet for hydrogen, while the
second one serves as an inlet for oxygen. There are two carbon electrodes. Hydrogen passes over the anode
and oxygen passes over the cathode. In the middle is a proton exchange membrane separting the two
electrodes from one another, where these two gases can interact with each other. The electrolyte separating
the two electrodes is an ion-conducting material, such as concentrated aqueous sodium hydroxide. The
following reactions take place at the two electrodes :
At the anode : 2H2  4H+ + 4e–
At the cathode : O2  4H+ + 4e– 2H2O
Overall cell reaction : 2H2  O2  2H2O
The water is released in the fourth chamber. The anodic reaction gives protons and electrons. These are
separated and hydrogen ions are allowed to pass through the electrolyte to the cathode while the electrons
travel via an external circuit as direct current to power electrical devices. In the cathode, hydrogen ions combine
with oxygen to form water along with heat, thus completing the circuit.
23. In H2 – O2 fuel cell, the reaction occuring at cathode is


(A) 2H2 + O2  2H2O (l) (B) H  O H  H2O
(C) O2 + 2H2O + 4e–  4OH– (D) He–  1/2 H2
24. The thermodynamic efficiency of fuel cell is given by
H nFE nFE
(A) (B) (C)  (D) nEF–
G G H
25. The cell reaction of a fuel cell is
(A) 2H2O(l)  2H2 (g) + O2(g) (B) 2H2(g) + O2(g)  2H2O(l)
(C) CH4(g) + O2(g)  CO2(g) + H2O (l) (D) C(s) + O2(g)  CO2(g)
PAGE NO.-46

1. Just sufficient Al2(SO4)3 (s) is added to a 0.4 M solution of BaCl2 such that all the BaSO4 is precipitated
completely (volume of solution is maintained constant then) :
(A) Freezing point of the original solution is raised
(B) Boiling point of the original solution is raised
(C) Vapour pressure of the original solution is raised
(D) No change occurs in the colligative properties of solutions
2. Which of the following are correct statements?
(A) vander Waals constant ‘a’ is a measure of attractive force
(B) van der Waals constant ‘b’ is also called co-volume or excluded volume
(C) ‘b’ is expressed in L mol–1
(D) ‘a’ is expressed in atm L2 mol–2
3. The tetrahedral and paramagnetic unit amongs given pair of species is/are:
(A) [MnO4]2–,[NiCl4]2– (B) [MnBr4]2–, [CoCl4]2–
2–
(C) [CrO2F2], [Cr2O7] (D) [Ni(CO)4], [Ni(dmg)2]
4. Most ionic compounds have :

(A) high melting points and low boiling points
(B) high melting points and non-directional bonds
(C) high solubilities in polar solvents and low solubilities in nonpolar solvents
(D) three-dimensional crystal structures, and are good conductors of electricity in the molten state
5. For 1s orbital of hydrogen atom radial wave function is given as :

3/2
1  1  –r / ao
R(r) =   e (where ao = 0.529 Å)
  ao 
The ratio of radial probability density of finding electron at r = ao to the radial probability density of
finding electron at the nucleus is given as (xe–y).
Calculate value of (x + y)3 .
6. At 300 K and 20 atm, the compression factor of a gas is 0.8. Calculate the volume occupied by 8 mmol
1
of the gas under these conditions ? (Take R = L atm K–1 mol–1)
12
7. Find the thickness of the electro deposited silver if the surface area over which deposition occurred was
100 cm2 and a current of 0.2 A flowed for 1hr with the cathodic efficiency of 80%. Density of
Ag = 10 g/cc (Ag = 108).
8. In the adjacent diagram the electrolytic cell contains 1 L of an aqueous 1 M
Copper (II) sulphate solution. If 0.4 mole of electrons are passed through the
cell, the molar concentration of copper ion after passage of the charge will be :
PAGE NO.-47
9. 4×10 M aqueous solution of an organic compound is isotonic with 1.5 ×10–2 M aqueous solution of
–2
NaCl (complete ionisation). The compound gets dimerised with degree of dimerisation  and Van't Hoff
factor i. Find the value of (8i + 2 ).
10. After removing partition what will be difference in Hg level (in 76 cm of Hg
cm) on both arm ?

76 cm of Hg
Note : Only hydrogen can pass the palladium foil.
partition
(Neglect volume of manometer, it is sufficiently long and no
reaction is occuring.) 76 cm of Hg
11. Find the total number of compounds amongs the following, where d orbital will not take part in
x2  y2
hybridization.
(1) [Pt(NH3)Cl (H2O)Br] (2) SF4 (3) [Cu(NH3)4]2+ (4) XeO3F2
(5) XeO2F2 (6) [Co(en)3]3+ (7) [Ni(CO)4] (8) POCl3
(9) PCl5 (10) XeO64–
12. Two beaker A and B contains AgNO3 solutions of concentrations 0.1 M and 0.01 M respectively as
shown in figure. Pure silver electrodes are now placed in each beaker. Now NH3 is added in each
beaker till conc. of NH3 in beaker A and B become 0.1 M and 0.2 M respectively. If two beakers are
now connected in Galvanic cell arrangement, find the EMF (in millivolt) of the resulting cell at 298 K.
Give your answer after dividing by 16.
RT
[Use log10 2 = 0.3, (2.303) = 0.06 V at 298 K] Given : E ºAg / Ag = 0.8 Volt
F
Ag Ag
AgNO3 0.1M 0.01M AgNO3

Beaker (A) Beaker (B)
13. Match the species/molecules listed in column-I with their characteristics listed in column-II.
Column-I Column-II
 –
(A) CIF5 , BrF 4 , IF 6 (p) All molecules/ions are polar in nature.
(B) CIF3, BrF 2 , ICI 4– (q) All molecules/ions have same number of lone pair (s) and same shape.
– –
(C) XeF2, ICI , I
2 3 (r) All molecules/ions have same oxidation state of central atoms.
 –
(D) CIOF3, CIF , IO2F
4 2 (s) All molecules/ions have same hybridisation of central atoms.
Daily Self-Study Dosage for mastering Chemistry Topic: Corrosion
Corrosion is one of the most significant problems faced by advanced industrial societies. It is estimated that
about 30-40% of iron and steel produced annually is used just to replace the rusted iron materials. Corrosion
toches all appliances used inside and outside home, on the road,on the sea, in plants and in aerospace
vehicles. corrosion is a spontaneous slow chemical interaction of metal or alloy with its environment, resulting in
the formation of one of its compounds such as oxide, hydrated oxide, carbonate, sulphide, sulphate, etc.
Corrosion can be defined as the deterioration of materials by chemical interaction with their environmnet.
Corrosion of metals occurs either by direct chemical attack or by electrochemical attack on the metal by the
PAGE NO.-48
corrosive environment. The most familiar example of corrosion is rusting of iron exposed to the atmospheric
3
conditions. 2Fe(s) + O2 (g) + xH2O(I)  Fe2O3 · xH2O(s)
2
(Chemical composition of rust)
The rusting of iron is a complex chemical reaction that involves both oxygen and moisture (see Fig.). Iron does
not rust in pure water that is oxygen free, and it does not rust in pure oxygen in the absence of moisture. This
suggests that the corrosion process is electrochemical in nature. At one place on the surface, iron becomes
oxidized in the presence of water and enters solution as Fe2+ and this is the anodic location of the metal
surface. Reaction taking place at the anode is
Fig. Corrosion of iron

Fe(s)  Fe2+ (aq) + 2e–
The electrons that are released when the iron is oxidized travel through the metal to some other place where
the iron is exposed to oxygen. This is the cathodic region of the metal surface where reduction takes place,
and oxygen is reduced to give hydroxide ion. The reaction taking place at the cathode is
1
O2(aq) + H2O(I) + 2e–  2OH– (aq)
2
The iron (II) ions that are formed at the anodic regions gradually diffuse through the water and eventually
contact the hydroxide ions. This causes a precipitate of Fe(OH)2 to form, which is very easily oxidized by O2 to
give Fe(OH)3. This hydroxide readily loses water. In fact, complete dehydration gives the oxide,
2Fe(OH)3  Fe2O3 + 3H2O
When partial dehydration of the Fe(OH)3 occurs, rust is formed. It has a composition that lies between that of
the hydroxide and that of the oxide, Fe2O3, and is usually referred to as a hydrated oxide. Its formula is
generally represented as Fe2O3 · xH2O.
14. Rusting of iron is
(A) A decomposition process (B) A photochemical process
(C) An electrochemical (D) A reduction process
15. In the rusting of iron, which of the following cell reactions occurs at the cathode ?
(A) Fe2+ | Fe (B) O2 | H2O (C) Fe3+ | F2+ (D) Fe | Fe3+
16. Which of the following statements regarding rusting of iron is/are correct ?
(A) It takes palce is moist air (B) It is stopped in CO2 atmosphere
(C) It produces Fe (III) oxide (D) It is an electrochemical process.
17. In which of the following will the corrosion of iron be most rapid ?
(A) In pure water (B) In pure oxygen (C) In air and moisture (D) In air and saline water
18. The rusting of iron takes place as follows :
2H + 2e– + 1/2 O2  H2O(l) ; E– = +1.23 V
Fe2+ + 2e–  Fe(s) ; E– = –0.44 V
Calculate G– for the net process :
(A) –322 kJ mol–1 (B) –161 kJ mol–1 (C) –152 kJ mol–1 (D) –76 kJ mol–1
PAGE NO.-49

1. Geometrical isomers are different in :
(A) molecular formula (B) structural formula
(C) stereochemical formula (D) emperical formula
2. Which of the following compound show geometrical isomerism:
(A) CH2 = CH2 (B) CH3–CH=CH2 (C) CH3–CC–CH3 (D) CH3–CH=CH–CH3
3. Geometrical isomerism is not possible in :
CH 3 CH3 CH3 CH3 CH3
CH3
(A) (B) (C) (D)
CH3
CH3
4. Which one of the following can exhibit cis-trans isomerism:

H
(A) H–CC–H (B) ClCH=CHCl (C) CH3–C–COOH (D) Cl–CH2–CH2–Cl
H
5. Which of the following compound can show geometrical isomerism?
(A) But-1-ene (B) Isobutene (C) But-1-yne (D) Pent-2-ene
6. In which of the following compound geometrical isomerism is not possible:
12
CH3 H CH3 H
(A) 14 (B) (C) CH3–CH=NH (D)
CH3 Cl Cl D
7. Cis-trans isomerism is shown by:
(A) (B) (C) (D)
8. Which of the following cannot show geometrical isomerism ?

(A) 1-phenylbut-1-ene (B) Hex-2-ene
(C) 1-Chloroethene (D) 1-Chloropropene
9. Which of the following compound can show geometrical isomerism?
(A) 2-Methylbut-2-ene (B) 2,3-Dimethylbut-1-ene
(C) 2,3-Dimethylbut-2-ene (D) 1,2-Dimethylcyclobutane
10. Which of the following can show geometrical isomerism :
(A) (B) (C) (D)
11. Which of the following has Z configuration -

H CH3 CH3 H F CH2Cl
H
(A) N N (B) D N (C) (D)
H H CH3 ClCH2 CHF2
12. Write correct relation between following molecules.
(A) Position isomers (B) Chain isomers

(C) Homologus (D) Geometrical isomers
PAGE NO.-50
13. In which of the following compound has cis configuration at each double bond?
(A) (B)
(C) (D)
14. Write correct IUPAC name of following compound:
(A) (1Z, 2Z, 3E) Hepta-1,3,5-triene (B) (2E, 4Z, 6Z) Hepta-2,4,6-triene
(C) (3Z, 5E) Hepta-1,3,5-triene (D) (2E, 4Z) Hepta-2,4,6-triene
15. Which of the following has geometrical isomer.
(A) (B) (C) (D) All of these
16. Select the E-isomer among the following.
(A) (B)
(C) (D)
17. The Z-isomer among the following is:
(A) (B)
(C) (D)
18. The common characteristic of cis-2-butene and trans-2-butene is:

(A) Solubility (B) Restricted rotation
(C) Stability (D) Melting and boiling point
19. Stilbene (PhCH=CHPh) can exist in two diastereomeric forms (X) and (Y), and (X) is found to be more
soluble in water than (Y). Predict which of the following statement is correct.
(A) X is trans isomer (B) stability of X > stability of Y
(C) melting point of X < melting point of Y (D) boiling point of X < boling point of Y
20. The enone (X = C5H8O) which show(s) geometrical isomerism is/are :
H
I. II. III. IV.
O O O
(A) I and IV (B) II and IV (C) III and IV (D) II only
21. How many structural isomers of C3H5Cl will show geometrical isomerism?
22. How many oximes obtained when cyclopropanone and 2-Butanone react with excess of NH2OH:
PAGE NO.-51
23. How many of following can show geometrical isomerism?
(i) (ii) (iii) (iv)
H CH3
(v) CH3 (vi) (vii) (viii)
HO CH3
(ix) (x) (xi) (xii)
24. How many stereocenters (Geometrical centre) are present in given species -

CH2=CH–CH=CH–CH= N H
25. How many positional isomers of Decene can show geometrical isomerism.

Numerical Questions ('0' negative marking) Q.10 to Q.12 (4 marks, 3 min.) [12, 09]
1. In which options both compounds can show geometrical isomerism.

Cl
(A) , (B) , C2FClBrI
Br
(C) , Ph2N2 (D) CH3–CH=N–OH, H2C=CH–CH=CH–CN
2. Which of the following can not show geometrical isomerism?
(A) (B) (C) (D)
3. For which of the following pairs of compounds are the CORRECT notations given.
(A) (B)
anti azobenzene syn azobenzene syn acetaldoxime Anti acetaldoxime
(C) (D)
Trans-o-aminocinnamic acid Cis-o-aminocinnamic acid Z-isomer E-isomer
PAGE NO.-52
4. Which of the following compound has Z configuration?
(A) (B)
(C) (D)
5. The incorrect order with respect to the properties mentioned for the following pair of compounds is:
(A) < (Stability)
(B) < (Stability)
(C) > (Boiling point)
(D) > dipole moment ()
Comprehension # 1
Observe the following compound :
CH3–CH=CH
6. The total number of its geometrical isomers is :

(A) 2 (B) 4 (C) 8 (D) 16
7. Total number of multiple bonds which shows geometrical isomerism including multiple bond of phenyl
group.
(A) 3 (B) 2 (C) 1 (D) 4
Comprehension # 2
The carbonyl compounds which have alpha hydrogen atom, tautomerise on keeping in aqueous
solution
OH–/H2O
CH3–CH2–CHO CH3–CH=CH–OH
Product enol can show geometrical isomerism.
CH3 OH CH3 H
C=C C=C
H H OH
H (Trans)
(cis)
8. Which of the following compound will give two enol in aqueous solution.
(A) CH3–CHO (B) Ph–C–CH2–CH3 (C) CH3–C–CH3 (D) CH3–CH–CHO
O O CH3
PAGE NO.-53
9. How many total enolic forms (including stereoisomers) are possible for butanone.
(A) 1 (B) 2 (C) 3 (D) 4
10. Geometrical isomerism is possible in how many of the following molecules/compounds.
Cl
NH Br
(1) (2) (3) (4)
NH
Me
NH

(5) (6) (7) (8) MeS
NH
(9) (10)
11. Total number of position isomers of tetrachlorocyclobutane which can shows geometrical isomerism
are:
O3/Zn NH2–OH
12. Penta-1,3-diene Total no. of carbonyl excess Total no. of
compounds oximes
[X] [Y]
Report your answer as X Y
13. Match the column-I with column-II:

Column I Column II
(A) Geometrical isomerism (p)

Cl
(B) Z-isomer (q)
Cl
(C) Cis-isomer (r)
CH3
CH3
(D) E-isomer (s)
H Br

1. Which of the following compound will show stereoisomerism?
(A) 1-Phenylethanamine (B) Phenyl chloroethanoate
(C) 3-Chloro-3-ethynylpenta-1,4-diyne (D) 3-Methylbutanoic acid
2. Chiral molecules are those which are:
(A) Superimposable on their mirror image (B) Not superimposable on their mirror image
(C) Having no mirror images (D) Capable of showing geometrical isomerism
3. Which of the following has asymmetric carbon atom?
(A) (B) (C) (D)
PAGE NO.-54
4. Which of the following is the lowest molecular weight hydrocarbon which is chiral?
(A) 3-Methylhexane (B) 2, 4-Dimethylpentane
(C) 2, 2-Dimethylpentane (D) 3, 3-Dimethylpentane
5. Which of the following molecule has 2 chiral carbon atoms :
CH3 H H
(A) C=O (B) CH3–C–C–CH3 (C) (D)

CH3
Cl OH
6. Correct fischer projection formula of given compound is :
(A) (B) (C) (D)
7. Which among the following compound has (L) configuration?
C2H5
(A) (B) (C) (D) H CH3
NH2
8. Which of the following does not represent D-Lactic acid:
(A) (B) (C) (D)
9. Compound having D-configuration is :
(A) (B) (C) (D)
10. Compound having R configuration is :
(A) (B) (C) (D)
11. Identify the R/S configuration of both chiral carbon atoms in given molecule:
(A) 2S, 3R (B) 2R, 3S (C) 2S, 3S (D) 2R, 3R

PAGE NO.-55
12. Identify the R/S configuration of both chiral atoms in given molecule :
(A) 1R, 3S (B) 1R, 3R (C) 1S, 3S (D) 1S, 3R

13. The structure of (2R, 3R) CH3CH(OH)CH(OH)COOH is-
COOH COOH COOH COOH
H OH OH H H OH HO H
(A) (B) (C) (D)
H OH H OH HO H HO H
CH3 CH3 CH3 CH3

14. In which of the following spatial representation of group/atoms is different from the given structure P.
Cl
P = H3C H
D
CH3 CH3 Cl
D CH3
(A) Cl D (B) D H (C) (D) D CH3

Cl
H Cl H
H
15. Identify the R/S configuration of both chiral carbon atoms in given molecule :
(A) 2S, 3R (B) 2R, 3S (C) 2S, 3S (D) 2R, 3R

16. Which of the following compound is chiral :
(A) CH3–CH2–OH (B) CH3–CH2–CH2–CH2–OH
(C) CH3–CH–CH3 (D) CH3–CH–CH2–CH3
OH OH
17. Cocaine is hallucinogen used widely. How many chiral carbon does it have.
18. How many chiral atoms are present in given species.
PAGE NO.-56
19. How many chiral atoms are present in given species.
20. Number of chiral centres in given molecule are :

Ph
HO
D OH
21. Number of chiral centres in given molecule are :
ChemINFO Lab Test of Acidic hydrogen

Daily Self-Study Dosage for mastering Chemistry Lab Test of Acidic Hydrogen
When any compound release H2 gas after reaction with sodium or potassium or alkali metals then this
reflects the presence of acidic hydrogen.
Active H : Those H atoms which is attached with more electronegative atoms like O,N,S,X, C sp.
i.e., CH3 — O — Ha CH3 — C  C — Ha CH3 — S — Ha
Ha
Note : The following compound are also have acidic hydrogen and CH3–C–CH–C–CH3
O Ha O
1
General reaction : Z– + Na  + H2 
2
1 1
(a) R  COOH 
Na
R  COONa  H2  (b) PhOH 
Na
PhONa  H2 
2 2
1 1
(c) R—C  CH + Na  R—C  C–Na+ + H2  (d) R—SO3H + Na  R—SO3–Na+ + H2 
2 2
1
(e) R —CH2—O —CH3 + Na  No reaction. (f) HCl 
Na
NaCl  H2 
2
22. Which of the following compound has Acidic hydrogen.
(A) CH3–CH3 (B) CH3–N–CH2–CH3 (C) CH3–COOH (D) CH3–O–CH3
CH3
23. Which of the following compound liberates H2 gas after reaction with Na metal.
(A) (B) (C) (D)
24. Which of the following compound does not liberates H2 gas after reaction with Na – metal.
(A) CH3–S–H (B) CH3–CHO (C) CH3–CH2–CCH (D) CH3–C–CH2–C–CH3
O O
25. Which of the following compound does not liberates H2 gas after reaction with Na – metal.
CH2 —COOH
CH2 —O — H CH2 —O — H CH2 —S — CH3
CH — O — H
(A) (B) (C) CH2 — CHO (D)
CH2 O —CH3 CH2 — NH2
CH2 — S — H
PAGE NO.-57

1. Which of the following cyclopentane derivatives are optically active?
(A) (B) (C) (D)
2. Which of the following has two-fold axis of symmetry?

(A) Ethylene (B) Cyclopropane (C) Cyclobutane (D) Benzene
3. Which of the following is correct for the given compound?
(A) It possesss centre of symmetry (B) It possesss C3 axis of symmetry

(C) It possesss plane of symmetry (D) It possesss C2 axis of symmetry
4. Which one of the following is optically inactive?
(A) Cis-1,2-Dibromocyclobutane (B) Trans-1,2-Dibromocyclobutane
(C) Trans-1,3-Dibromo-1-chlorocyclobutane (D) Trans-1,3-Dibromocyclobutane
5. Identify which of the the given substance is/are chiral:
(A) (B)
(C) (D)
Comprehension #
An unsaturated compound X (C5H10O) exists as four stereoisomers. Y, (structural isomer of X) is
neither unsaturated nor shows any stereoisomerism. X and Y have same functional group. The third
isomer (Z) is a positional isomer of X, and has only two stereoisomers.
6. The compound Z cannot be ?
(A) CH2 = CH– CH –CH2 CH3 (B) H2C = CH–CH2– CH –CH3
| |
OH OH
CH3
|
(C) CH3 – CH = CH–CH2–CH2–OH (D) H2C=C–CH–CH3
|
OH
PAGE NO.-58
7. Y can be :
CH2OH
|
(A) (B) (C) (D) (B) and (C) both
O |
OH
8. Total number of plane of symmetry present in CH4.
9. How many of following centre of symmetry is present.
H
C
(i) (ii) (iii) H3C (iv) BeCl2(linear)
D
T
Cl
CH3
H H H Cl Cl
(v) (vi) H (vii) (viii)
H Br
Cl Cl Cl
10. How many of following have plane of symmetry.
H CH3
H CH3 H H H Br D
CH3 H C
(i) (ii) (iii) (iv) H
CH3
CH3 H CH3 Br Br
11. In BF3 C2 axis of symmetry are X and C3 axis of symmetry are Y. Report your answer as X + Y.
12. Matching the column :
Column-I Column-II
(A) (p) Geometrical isomerism
(B) (q) Optical isomerism
(C) (r) Compound contaning plane of symmetry
(D) (s) Compound containing centre of symmetry
PAGE NO.-59

1. The following two compounds are:
CI Br
H F & F Cl
Br H
(A) Enantiomers (B) Diastereomers (C) Identical (D) No relation
2. Relation between maleic acid and fumaric acid is :
(A) Identical (B) Enantiomer (C) Diastereomer (D) Chain isomer
3. Relation between given compounds is :
COOH COOH
H OH and H OH
H OH HO H
COOH COOH
(A) Enantiomer (B) Diastereomer (C) Identical (D) Geometrical isomer
4. D-Lactic acid and L-Lactic acid are :
(A) Homologous (B) Conformer (C) Enantiomer (D) Diastereomer
5. Meso compound is :
CH3
CH3 Cl CH3
H Cl
(A) (B) (C) H Cl (D)
C2H5 H Cl
H
6. Which of the following can be meso compound :
(A) CH 3–CH–CH–CH 3 (B) CH3–CH–CD–CH3 (C) CH3–CH–CH–CH3 (D) CH3–CH–CH–CH3
Cl Br OH OH CH3 Cl Cl Cl
7. Identify the Chiral compound :
CH3
H Cl
(A) (B) (C) (D) All of these
Cl H
CH3
8. Which of the following is not a meso compound :
COOH
CH3 CH3 H OH
H Cl H Cl HO H CHO
(A) H OH (B) HO H (C) HO H (D) H OH
H Cl H Cl H OH
CH3 CH 3 COOH CH3
9. Which of the following compound is suitable for optical resolution of racemic mixture of 2- methyl
butanoic acid :
(A) 2-Butanol (B) 1-Propanol
(C) 2-Propanol (D) Cyclobutane carboxylic acid
PAGE NO.-60
10. A compound was having [] = 40.3º in polarimeter experiment in clockwise direction what can be the
structure is:
(A) (B)
(C) (D)
11. has optical rotation –45°, so optical rotation of will be:
(A) + 45° (B) 0° (C) –45° (D) Can not be predicted
12. If the optical rotation produced by is +36º, then the optical rotation produced by
will be:
(A) – 36º (B) 0º (C) + 36º (D) Unpredictable
13. Which of the following is a meso compound?
(A) (B) (C) (D)
14. Relation between (I) and (II) (whose configuration in given below is):
CH3 CH3
HO — C — H H — C — OH
HO — C — H H — C — OH
H — C — OH H — C — CH3
CH3 OH
(I) (II)
(A) Enantiomers (B) Diastereomers
(C) Identical or homomers (D) Constitutional isomers
PAGE NO.-61
D D
C C
15. & H
H CH2COOH C2H5
C2H5 COOH
The above pair has relation
(A) Enantiomers (B) Diastereomers (C) Homologous (D) Identical
16. Meso compound is :
(A) (B) (C) (D)
17. The compound 'X' can exist in how many orientation:

CH2–CH3
CH3
CH
X= H–C–C=C CH3
CH3
OH H
18. Optically active alkadienes of structural formula CH3 – CH  CH – CH – CH  CH2 are:

|
Cl
19. Total number of optically active stereoisomers possible for butane-2,3-diol is:
20. How many geometrical isomers are possible for given compound?
21. How many optical active isomer of 2, 3, dichlorobutane are possible.
ChemINFO Lab test of amide, ester & nitro group

Daily Self-Study Dosage for mastering Chemistry Lab Test of Amide, ester & nitro group
Test of Acid Amide
Acid amide gives smell of ammonia when heated with alkali.
Test of Ester
Esters are sweet (fruity) smelling liquids.
When react with NaOH & Phenophthalein then pink colour will disappear on heating.

RCOOR’ + NaOH + Phenophthalein (Pink)  RCOOH + R’OH (Colourless solution)
Test of Nitro group : (Mulliken- Barker’s Test)
Nitroalkane & nitrobenzene give black ppt on reduction with Zn and ammonium chloride followed by
treating with Tollen’s reagent. This is also said to be Mulliken’s test.
(a) R–NO2 R–NHOH Ag
AgNO3 NH4 OH
(b) + Zn + NH4Cl    

PAGE NO.-62
22. An oragnic compound X (C4H8O2) gives positive test with NaOH and Phenopthalein. Structure of X will
be:
(A) CH3  CH2  CH2  C  OH (B) CH3  C  C  CH3
|| || ||
O O O
(C) CH3  C  O  C2H5 (D) CH3  C  OCH3
|| ||
O O
23. Which of the following compound will give smell of NH3 with conc. NaOH.
(A) CH3  CH2  C  NH2 (B) CH3  C  CH2  NH2
|| ||
O O
(C) (D) CH3  CH2  C  OH

||
O
24. A compound is heated with zinc dust and ammonium chloride followed by addition of the Tollen's
reagent. Formation of silver mirror indicates the presence of following group
(A) –CHO (B) (C) –NO2 (D) –NH2

25. The group reagent for the test of nitro group:
(A) Tollen’s test (B) Lucas test (C) Mulliken’s test. (D) Bromine water test

1. In which of the following cyclic compound maximum angle strain is present:
(A) (B) (C) (D)
2. Which of the following species can show conformational isomerism :

(A) (B) CH2 = CH2 (C) CH3–CH2–CH3 (D) H–CC–H
3. Most stable conformor of n-butane is :

(A) Gauche (B) Anti (C) Fully eclipsed (D) Partially eclipsed
4. Most stable conformor of glycol is :
(A) (B) (C) (D)
5. Most stable conformational isomer of 2,3-dimethyl butane is :

Me
Me H
(A) (B) (C) (D) All are equally stable
H Me
Me
PAGE NO.-63
6. The conformation of isopentane having maximum torsional and maximum Vander Waal strain is:
(A) (B) (C) (D)
7. Select true & false statement in given:

(S-1) All conformational isomers of ethane are degenerate.
(S-2) All conformational isomers of n-butane are degenerate.
(S-2) Conformational energy of ethane is more than that of n-butane.
(S-4) Most stable conformational isomer of HOCH2CH2OH is Gauche.
(A) T F F T (B) F F F T (C) T F F F (D) F T F F
8. Which of the Newmann projections shown below represents the conformation about the C1–C2 bond of
1-Bromo-2-methyl propane?
(A) (B) (C) (D)
9. In the Newman projection for 2,2-Dichlorobutane
Which one statement is correct?

(A) If ‘X’ is H then ‘Y’ will be CH3 (B) If ‘X’ is H then ‘Y’ will be Cl
(C) If ‘X’ is H then ‘Y’ will be C2H5 (D) If ‘X’ is Cl then ‘Y’ will be CH3
10. Relation between following pair is :
CH3 CH3
H CH3 H3C H
H H H H
H H
(A) Conformational enantiomer (B) Conformational diasteromer
(C) Geometrical isomer (D) Homologous
11. Three membered cyclic compounds are highly reactive because of:
(A) High degree of torsional strain (B) High degree of angle strain
(C)High degree of steric strain (D) All of these
13. Among the structure shown below, which has lowest potential energy?
(A) (B) (C) (D)
14. Most stable conformation of succinic acid in basic medium will be:
(A) (B) (C) (D)
15. Which conformation of cyclohexane has no plane of symmetry?

(A) Boat (B) Twist Boat (C) Chair (D) Half chair
PAGE NO.-64
16. Conformational isomer of cyclohexane having minimum energy is:
(A) Chair form (B) Boat form (C) Twist boat form (D) Half chair form
17. Which of the following conformations has maximum energy?
(A) (B)
(C) (D)
18. The most polar as well as stable conformation of 1-chloropropane is:
(A) (B) (C) (D)
19. How many conformational isomers of butane are chiral?

20. Dihedral angle (in degree) in given conformation of ethane is :
H
H H
H H
H
21. Find total number of stereoisomers for given molecule -
22. (P)
The no. of geometrical isomers is X and optical isomers is Y. Value of (X + Y)
ChemINFO Lab Test of amines

Daily Self-Study Dosage for mastering Chemistry Lab Test of Amines
Test for Amines :
(i) NaNO2 + aqueous HCl test : It is used to distinguish between 1º, 2º and 3º amines and also
distinguish between aliphatic and aromatic primary amines.
1° Aliphatic Amine : R–CH2–NH2 R–CH2–OH + N2 
1° Aromatic Amine : ¼diazonium salt)
2° Amine : R–NH–R (N -Nitroso amine) yellow oily liquid

3° Amine : R3N unstable nitrite
(ii) Carbyl amine test (CHCl3 + KOH) :
1° Amine (Aliphatic or Aromatic) %
CHCl3 KOH
R–CH2–NH2   R–CH2–NC + 3KCl + 3H2O
(unpleasent smell of isocyanide)
CHCl3 KOH
Ph–NH2   Ph–NC * 2° Amine and 3° Amine do not give this test.
PAGE NO.-65
(iii) Hofmann mustard oil test
It is a test for 1º amine and aniline. Primary amine reacts with carbon disulphide to form dithioalkyl carbamic
acids which decompose on heating with mercuric chloride (HgCl2) to give alkyl isothiocyanates having smell
like mustard oil.
SH
(a) R–NH2 + S=C=S   R – NH – C HgCl2
  R–N=C=S + HgS + 2HCl
|
|| S 
Dithioethylcarbamic acid Alkylisothiocyanate

(b) CH3CH2NH2 + S=C=S  HgCl2
  CH3CH2–N=C=S + HgS + 2HCl

(1º amine) Ethyl isothiocyanate

Similarly aniline gives phenlyisothiocyanate
(i) S=C=S C6H5N=C=S
(c) C6H5NH2
(ii) HgCl2/  Phenylisothiocyanate
* 2° Amine and 3° Amine do not give this test.
(iv) Hinsberg reagent (C6H5SO2Cl) :

This is used to distinguish between 1°, 2° & 3° amine.
Pyridine Base
 R–NH–SO2–Ph  Compund is soluble in base.
1° Amine : R–NH2 + PhSO2Cl 
Pyridine Base
 R2N–SO2–Ph  Compund is insoluble in base.
2° Amine : R2NH + PhSO2Cl 
Pyridine
3° Amine : R3N PhSO2Cl 
 No reaction.
23. Which of the following liberate N2 gas with NaNO2 / HCl
(A) CH3–CH2–NH–CH3 (B) CH3–CH2–CH2–NH2
(C) Ph–NH2 (D) (CH3CH2)3N
24. The Hinsberg's method is used for :

(A) preparation of primary amines (B) preparation of secondary amines
(C) preparation of tertiary amines (D) separation of amine mixtures
25. Which of the following amine does not give mustard oil test ?
(A) CH3CH2NH2 (B) Ph–NH2 (C) (CH3CH2)2NH (D) Ph–CH2–NH2

(3 marks, 2 min.) [03, 02]
1. Which shows all conformational isomers of degenerate level.
(A) Ethane (B) Propane (C) Neopentane (D) Isobutane
2. If the newmann's projection fromula for 2-methylbutane is given as then X, Y and Z may be:
(A) H, CH3 and C2H5 (B) CH3, CH3 and CH3

(C) C2H5, H and H (D) H, H and CH(CH3)2
PAGE NO.-66
3.
I II III
Correct relation between above compounds:
(A) I & II are position isomers (B) I & II are chain isomers
(C) II & III are metamers (D) II & III are identical
4.
Select the correct statement/s.

(A) All are identical compounds
(B) III and IV are identical and meso compounds
(C) I and II are optically active compounds
(D) I and II are configurational isomers while II and IV are conformational isomers
5. Which conformations have non-zero dipolemoment?
(A) (B) (C) (D)
6. Which of the following is correct?

(A) Chiral molecule can use its own chirality to differentiate between mirror images.
(B) Substituents on chair conformers of cyclohexane ring prefer to occupy axial positions.
(C) Decalin (bicyclo[4.4.0]decane) shows Geometrical isomerism.
(D) Twist boat conformation of cyclohexane is chiral conformation
Comprehension #
The carbonyl compounds which have alpha asymmetric carbon (C) atom and have –H hydrogen
atom, racemise due to tautomerisation on keeping in aqueous solution.
PAGE NO.-67
7. Which of the following compounds will racemise on keeping in aqueous solution
CH3 Me
| |
(A) CH3–CH2–CHO (B) Ph  C  C  CH3 (C) Ph  C  C  CH3 (D) Ph  CH  CH2  C  CH3
| || | || | ||
H O Et O D O
8. Which statement is incorrect about the following reaction?
(A) It undergoes racemisation

(B) It undergoes D-exchange at asymmetric C* atom
(C) Rate of racemisation is equal to rate of D-exchange
(D) The product is laevorotatory
9.
Report your answer as X Y
10. For the given compound X, the total number of optically active stereoisomers is …….
OH OH
This type of bond indicates that the configuration at the

specific carbon and the geometry of the double bond is fixed
This type of bond indicates that the configuration at the
specific carbon and the geometry of the double bond is NOT fixed
Br OH
11. How many conformational isomers of Cl–CH2–CH2–Cl are polar.
12. How many total enolic forms (including stereoisomers) are possible for .
13. Match the column:
Column-I Column-II
(A) (p) Cis-form
(B) (q) trans-form
(C) (r) Keq is greater than one when compound undergo flip.
(D) (s) Keq is less than one when compound undergo flip.
(t) Keq is equal to one when compound undergo flip.

PAGE NO.-68
14. Match the column-I with column-II:
Column I Column II
(A) (p) The enolic form has geometrical isomers
(B) (q) The enol form is chiral
(C) (r) Its tautomer gives 2, 4–DNP test positive
(D) (s) Keto-enol tautomerism results into racemisation.

1. Which of the following is electrophile:
(A) CH3 (B) Br (C) NO2 (D) All of these
2. Which of the following can act as nucleophile:


(A) CH3 (B) NH3 (C) I (D) All of these
3. Which of the following has maximum nucleophilicity among them:

   
(A) CH3 (B) NH2 (C) OH (D) F
4. Which of the following is strongest nucleophile:

 
(A) F (B) Cl (C) Br (D) I
5. Which of the following is good nucleophile as well as good leaving group:

(A) NH2 (B) OH (C) I (D) CH3–O
6. Which of the following is best leaving group:
(A) (B) (C) HO (D) CH3–O
7. Polar aprotic solvent is :

CH3–S–CH3
(A) CH3COOH (B) H2O (C) (D)
O
(DMSO)
8. Polar protic solvent is :
(A) CH3–O–CH3 (B) CCl4 (C) (D) H2O
9. Non polar solvent is:

(A) Ethanol (B) Acetone (C) DMF (D) CS2
10. Which of the following is an electrophile?
(A) H2O (B) NH3 (C) CH3OH (D) AlCl3
PAGE NO.-69
11. Which of the following is not an electrophile?
(A) PCl5 (B) SO3 (C) Ph–OH (D) HCHO
12. Which is poor leaving group
(A) OH (B) SH (C) OPh (D) CH3COO
13. Which among the following species is an ambident nucleophile?
(A) C6H5O– (B) NO3– (C) HSO3– (D) NH3
14. Which of the following is best leaving group?
(A) (B) CH3–O– (C) OH– (D) CF3SO3–
15. Identify correct order of leaving group ability for given leaving groups?
I. OH– II. III. CH3COO– IV. CH3SO3–

(A) IV > III > II > I (B) III > IV > II > I (C) II > IV > III > I (D) IV > II > III > I
16. Leaving group ability order amongst the following.
I. C6H5O–, II. p-(CH3) C6H4O– III. p-(OCH3)C6H4O– IV. p-(NO2)C6H4O–
(A) I > II > III > IV (B) III > II > I > IV (C) IV > I > II > III (D) IV > III > II > I
17. The following reaction is an example of CH3–CH2–CH2–CH3 + Cl2
(A) Acid-base reaction (B) Substitution reaction
(C) Addition reaction (D) Elimination reaction
18. The following reaction is:
Cl OH

+ OH + Cl¯
NO2 NO2
(A) An addition reaction (B) A nucleophilic substitution reaction
(C) An electrophilic substitution reaction (D) A free radical substitution reaction
19. Which of the following reaction is an example of Acid-base reaction.
(A) CH2– CH2  Zn
 CH2=CH2 + ZnBr2 (B) CH3COOH + NaNH2  CH2COONa + NH3
Br Br
H2 O
CH OH

3
  
(C) (D) 
H
20. Total number of stereoisomers having following structural formula is :
(A) 16 (B) 32 (C) 64 (D) 128

21. Sum of total number of chiral centres (x) and total number of pairs of enantiomers (y) for following
structure is :
PAGE NO.-70
22. Total number of stereoisomers of CH3 – CH – CH – CH  CH – CH3 is :
| |
Br Cl
23. Total number of optical isomers for given compound is:

CH3  CH  CH  CH  CH3
| | |
Cl Br Cl
24. Find total number of stereoisomers for given molecule.

25. How many chiral carbon atoms present in D-glucose.

1. Which of the following compound is most reactive towards electrophilic substitution reaction?
CHO OCH3 Cl
(A) (B) (C) (D)
2. Which of the following is least reactive towards Friedel-Craft reaction:

Ph CH3 Cl O=C–CH3
(A) (B) (C) (D)
3. Which of the following group is meta directing in nature?

(A) –CH3 (B) –OCH3 (C) –CN (D) –Cl
4. Which of the following group is ortho-para directing in nature?
(A) –CCl3 (B) –CHO (C) –NO2 (D) –OCH3
5. In which of the following compound ortho-para directing and deactivating group is present
(A) (B) (C) (D)
6. Which of the following compound gives maximum % of para product with a particular electrophile?
F Cl Br I
(A) (B) (C) (D)
ICl / ZnCl
7. 
2
product; Product is :
Cl Cl I I
(A) (B) (C) (D)

Cl
Cl
PAGE NO.-71
NO 2

H
8. + conc.HNO3 

Which intermediate is formed during the above reaction:

(A) carbanion (B) Carbocation (C) Free radical (D) Carbene
9. In which of the following reaction primary isotopic effect is observed-
(A) Chlorination (B) Nitration (C) Methylation (D) Sulphonation
10. Incorrect statement for sulphonation reaction is:
(A) Con. H2SO4 favours to sulphonation
(B) Dil. H2SO4 favours to desulphonation
(C) It is an irreversible reaction
(D) Low temprature favours to sulphonation and higher temprature favours to desulphonation.
11. Using anhydrous AlCl3 as catalyst, which one of the following reaction produce ethylbenzene (PhEt)?
(A) CH3–CH2OH + C6H6 (B) CH3–CH=CH2 + C6H6
(C) C2H5Cl + C6H6 (D) CH3–CH3 + C6H6
12. The treatment of benzene with isobutene in the presence of sulphuric acid gives:
(A) isobutyl benzene (B) tert-butyl benzene
(C) n-butyl benzene (D) no reaction
13. Which of the following organic chloride will not give a Friedel-Craft alkylation product when heated with
benzene and AICI3.
(A) CH3)3 CCI (B) CH2=CHCH2CI (C) CH3CH2CI (D) CH2=CHCl
14. When benzene reacts with HNO3/H2SO4 structure of intermediate formed is:
(A) (B) (C) (D)
Conc .HNO  Conc .H SO Cl / FeCl

15. 3
2

4
 X 2
3
Y
The product Y is:

(A) p-chloro nitrobenzene (B) m-chloro nitrobenzene
(C) o-chloro nitrobenzene (D) o,p-dichloro nitrobenzene
16.  
For above reaction which of the following reaction condition is suitable.

(A) CH3–CH2–CH2–Cl / AlCl3 (B) / AlCl3 followed by NH2–NH2 / KOH
(C) CH2=CH2–CH2–Cl / AlCl3 (D) CH2=CH–CH2–Cl / AlCl3 followed by H2 / Ni

17. How many of following are anti-aromatic compound.
(i) (ii) (iii) (iv)
PAGE NO.-72
18. How many of following are non-aromatic compound.
(i) (ii) (iii) (iv) (v)
(vi) (vii) (viii) (ix)
19. How many of following are aromatic compound.
(i) (ii) (iii) (iv)
(v) (vi) (vii) (viii) (ix)
20. How many mononitro Bromo-benzenes are possible for
21. Complete the following reaction.
Br / Fe

2

(1 eq.)
At which position major bromination takes place?
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Aromatic side chain oxidation
Aromatic side chain oxidation
Strong oxidising agents like KMnO4/H/ or K2Cr2O7/H/, oxidises benzylic carbon to – COOH group if
benzylic hydrogen or unsaturation is present.
General Reaction
COOH

4

 
4


 
COOH CH3
CH3 C CH3
KMnO / H

4


 KMnO / H

4

 No reaction

Note : Tertiary butyl (CH3)3C– will not oxidise by oxidising reagent
PAGE NO.-73
KMnO / H

4

 KMnO / H
Ex.1  Ex.2 
4



CH2–CH3

KMnO 4 / H
22.   Product ; Product will be:

(A) (B) (C) (D)
23. Which of the following reagent is suitable for the conversion of benzyl alcohol to benzoic acid?
(A) K2Cr2O7/H+ / (B) KMnO4/H+ / (B) m–CPBA (D) (A) and (B) both
24. Which of the following is oxidation product of given reaction.
KMnO / H

4



(A) (B) (C) (D)

KMnO 4 / H
25.   Product; Product is:

(A) (B) (C) (D)

(3 marks, 2 min.) [03, 02]
PAGE NO.-74
1.
Out of the followings which one is/ are correct.
(A) 1, (B) 2, (C) 3, (D) 4,
2. Which factor is responsible for the regioselective nature of the following reaction.
Cl / FeCl
2
3
 +
(A) –I effect of halogens (B) +I effect of halogens

(C) +M effect of halogens (D) –M effect of halogens
3. Friedel craft acylation is/are not observed in
(A) (B) (C) (D)
4. In which of following electrophilic aromatic substitution reaction takes place on left hand side phenyl
ring.
(A) (B)
(C) (D)
5. Which of the following electophilic substitution reaction represent correct product.
Br / FeBr
(A) 2
3

Br / FeBr
(B) 2
3

Br / FeBr
(C) 2
3

Br / FeBr
(D) 2
3

PAGE NO.-75
Comprehension #
Friedel Craft's Acylation: Acylation of benzene may be brought about with acid chlorides or
anhydrides in presence of Lewis acids.
Step-1 : Formation of an acylium ion.
:O:
|| ..
+ - -
R – C – Cl
.. – AlCl3 AlCl4 +
complex
Step-2 : Electrophilicattack.
O
O ||
|| C
C+ R
| + H
R H
sigma complex
Step-3 : Loss of a proton. Complexation of the product.
O
|| .. -
C :Cl
.. – AlCl3
R
+ H
H
sigma complex
COCl AlCl Zn-Hg/HCl

3
6. + (X) [Y]
COCl
Y is :
(A) (B) (C) (D)
AlCl Zn(Hg / HCl)

7. 

3
 P 
 Q
COCl
The products Q is:
OH
(A) COOH (B) (C) OH (D)
PAGE NO.-76
8. Which step is used to produce 1–Chloro–3–ethylbenzene.
Cl2 /AlCl3 Zn  Hg / HCl

(A)   
Cl /AlCl Zn  Hg / HCl
(B) 
2 3
 
Cl /AlCl
(C) 
2 3

Cl /Fe
(D) 
2

9. Complete the following reaction.
Br / Fe HNO / H SO

2
 
3 2 4

(1 eq.) (1 eq.)
At which position nitration takes place?

10. How many substituted phenol are possible by the molecular formula C8H10O.
11. Match List I (Group when attached to phenyl ring) with List II (Effect shown) and select the correct
answer using the code given below the lists:
List I List II
(P) –Cl (1) + m & + I

(Q) (2) + m &– I
–O
(R) –CH2–CH3 (3) only – I

(S) – N H3 (4) +I & Hyperconjugation
Codes:
P Q R S P Q R S
(A) 1 3 2 4 (B) 3 4 2 1
(C) 4 2 3 1 (D) 2 1 4 3
12. Match the column-I with column-II:
Column-I Column-II
(A) (p) Gives Benzoic acid with hot alkaline KMnO4.
(B) (q) o/p directing.
CMe3
(C) (r) Less reactive than benzene for electrophilic subsitution reactions.
(D) (s) Gives an ester on reductive ozonolysis.
PAGE NO.-77
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Oxidation
Syn hydroxylation of Alkenes and Alkynes
General Reactions :
H.A. H.A.
 —CC— 
H.A.
Ex. 
H.A. = Hydroxylating agent. It may be any one of these:

(a) Baeyer’s reagent: cold dilute 1% alkaline KMnO4 (pink colour) or
(b) i) OsO4 ii) NaHSO3
Note :
1. Double bond of Aromatic ring cannot react with these reagents.
2. It is syn addition. Both OH groups add on the same side of pi-bond.
Baeyer ' s reagent

13. 
 Product; Product will be:
(A) (B) HO OH
OH
(C) (D)
HO OH OH
14.
Reagent x will be:

(A) 1% alkaline KMnO4 (Baeyer’s reagent) (B) OsO4 /NaHSO3
(C) Peracid/H3O+ (D) (A) and (B) both
Baeyer ' s Re agent

15. CH3–CC–CH3  Product; Product will be:
or OsO4 / NaHSO3
(A) (B)
(C) (D) None of these
PAGE NO.-78
ELECTROPHILIC SUBSTITUTION REACTIONS

Find the appropriate position for major product in the following reaction.
Br Br Br
1. 
2
 2. 
2
 3. 
2

Fe Fe Fe
Br Br Br
4. 
2
 5. 
2
 6. 
2

Fe Fe Fe
Br Br Br
7. 
2
 8. 
2
 9. 
2

Fe Fe Fe
Br Br Br
10. 
2
 11. 
2
 12. 
2

Fe Fe Fe
Br Br Br
13. 
2
 14. 
2
 15. 
2

Fe Fe Fe
Br Br Br
16. 
2
 17. 
2
 18. 
2

Fe Fe Fe
Br Br Br
19. 
2
 20. 
2
 21. 
2

Fe Fe Fe
3
2
Br Br Br
22. 
2
 23. 
2
 24. 
2

Fe Fe N 1 Fe
Br2
25.  
 26. 
2

Br
Fe
Br Br
27. 
2
 28. 
2

Fe Fe
2
Br Br
1    
29. 2
30. 2
Fe Fe
NH
PAGE NO.-79
1. 3 2. 3 3. 3 4. 2 5. 2
6. 2 7. 4 8. 1 9. 3 10. 3
11. 1 12. 1 13. 3 14. 1 15. 3
16. 2 17. 2 18. 1 19. 1 20. 1
21. 5 22. 3 23. 3 24. 2 25. 2
26. 3 27. 3 28. 1 29. 1 30. 3

1. Which of the following reaction is possible?
(A) + AgClO4  + 2 AgCl 
NaH
(B)
HClO4
(C) 
(D) All of these

2. Which of the following is/are polar stable molecule/s.
(A) (B) (C) (D)
3. In which of the following reactions H2 gas is liberated:

K(Metal ) K(Metal ) K(Metal ) K(Metal )
(A ) 
 (B) 
 (C) 
 (D) 

4. Which is the most likely group for substituent 'X' based on the relative rate factors for chlorination in the
given compound.
(A) –CF3 (B) –C(CH3)3 (C) –CH3 (D) –CH = O
CO, HCl
5.  (Y) Product will be:
AlCl3
(A) (B) (C) (D)
PAGE NO.-80
6. Which one of the following undergoes nucleophilic aromatic substitution at the fastest rate?
 (A) (B) (C) (D)
7. Identify the principal organic product of the following reaction,
+ NaSCH3  product
 (A) (B) (C) (D)
8. The major products of the following reaction are:
H O / 
3 
 Products
(A) HCHO (B) (C) PhCHO (D) CH3CH2OH
9. Following equation illustrates.

300 350 C
C6H5Cl + 2NaOH    C6H5ONa + NaCl + H2O
300 atm
(A) Dow’ process (B) Kolbe’s process (C) Carbylamine test (D) Haloform reaction
10. Phenol + CHCl3 + NaOH  product is:
(A) Benzoic acid (B) p-chlorophenol (C) Salicylaldehyde (D) salicylic acid
11. A and B are respectively:
(A) (B)
(C) (D)
12. The rate determing step of following reaction is:
(A) 1 (B) 2 (C) 3 (D) 4
RONa / 
13.  
Above reaction has maximum rate when:

(A) Y = – I (B) Y = – Br (C) Y = – Cl (D) Y = – F
PAGE NO.-81
14. The most activated ring is available in :
(A) in CCl4 (B) in dil NaOH (C) in dil HCl (D) in dil HCl
15. Nitrobenzen can be prepared from benzene by using a mixture of conc. HNO3 and conc. H2SO4. In the
mixture, nitric acid acts as a/an.
(A) Catalyst (B) Reducing agent (C) Acid (D) Base
NaOH
16. + C2H5I   X , X is:
(1 eq.)
(A) C6H5OC2H5 (B) C2H5OC2H5 (C) C2H5OH (D) C6H5I
17. How many toluidines on reaction with NaNO2/HCl followed by H3PO2 treatment gives Toluene.
NO2
Sn/HCl
NaNO2 H O, 
18.    

2
 Product Z
HCl 05C
Find the molecular weight of Z.

19. If Meta cresol is subjected to react with bromine water, how many Br atoms are attached on the
benzene ring.
20. How many phenolic rings are possible of formula C7H8O.
HBF
21. Benzenediazonium chloride 
4
 Product (P).

How many flourine atoms attached on the benzene ring in product (P)
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Syn hydroxylation of Alkenes and Alkynes
Anti hydroxylation of Alkenes
Peroxy acid have general structure as (RCO3H). They are relatively unstable and easily gives
nascent O hence, acting as oxidant. It converts alkene into epoxides. A combination of RCO 3H followed by
hydrolysis [RCO3H(H3O+)] further breaks epoxide to anti hydroxylation product.
General Reaction :
Peroxyacid H O

 
3
Note : 1. It is anti addition. Both OH groups add on the opposite side of pi-bond.
2. Double bond of aromatic ring cannot react with these reagents.
OH
(i) Peroxy acid


(ii) H3O OH
Ex.1
Trans-cyclohexane-1,2-diol
Peroxyacid may be any one of these

CO3H
–
(a) = m-CPBA (Metachloro perbenzoic acid) (b) CH3CO3H = PAA (Peracetic acid)
–
Cl
(c) PhCO3H = PBA (Per benzoic acid) (d) CF3CO3H = TFPAA (Trifluoro peracetic acid).
Ex.2
PAGE NO.-82
m-CPBA
22. x , x is
OH OH OH H
(A) (B) (C) (D) 50% B and 50% C
H H H HO
Peroxyacid
23. CH2 = CH2  X, X is:
OH O
| CH2 — CH2
(A) CH2 — CH2 (B) | | (C) (D)
| OH OH
OH
(1) Peroxyacid
24.  P; Product is:
( 2) H3O
(A) (B) (C) (D) None of these
25. Anti hydroxylation of alkene takes place by:

(A) m-CPBA/ H3O (B) CH3 COOOH/H3O (C) F3CCOOOH/H3O (D) All of these

(3 marks, 2 min.) [03, 02]
ChemINFO: 4 Questions ('–1' negative marking) Q.11 to Q.14 3 marks, 2 min.) [12, 08]
1. Identify the options in which the correct products have been reported in the reactions:
OH OH
Br /H O Br Br
(A) 
2 2

Br
O O
C–O C–O
Br (1 mol)/Fe
(B) 
2

Br
OH OH
Dilute HNO3, 20ºC O2N NO2
(C) 

NO2
OH O–C2H5
(C H ) SO NaOH / 
(D) 25
2
4

2. Which of the following products will be formed in the given reaction :


O / heat
H3O / heat
Ph3C – H     
2
(A) PhCH2OH (B) Ph–OH (C) Ph2C=O (D) Ph–CHO

PAGE NO.-83
3. Select the electrophilic substitution reaction/s.
OH OD
D D ArN N = N – Ar
D O 2
(A) 3   (B) 
 + H
HO HO
D
SO3H OH ONa

H /H O CO / NaOH COONa
(C) 
2
 + H2SO4 (D) 
2


Comprehension #
I
 II
 III 
 Iv 
 v vI 

 (X) (Pain killer)
4. Which reaction would be involved in step-I :

(A) Electrophilic substitution (B) Nucleophilic substitution
(C) Electrophilic addition (D) Nucleophilic addition
5. Which of the following reaction is involve in step-V :
(A) Fries rearrangement (B) Kolbe schmit reaction
(C) Carbyl amine reaction (D) (A) & (B) both
6. In step-VI reagent and product (X) is respectively :
(A) SOCl2, (B) ,
(C) MeOH, (D)
7. How many aromatic diazonium chlorides of xylene can be reduced to meta-xylene by H3PO2?
H PO , 

3 2
 (m-Xylene)
8. The following compound is treated with excess of Br2/H2O. Find the total number of positions, where
bromination will occur significantly:
Cl
|
Conc.H2SO4
9. Chloral +  Product
Product is insecticide and was used in II world war to control malaria.The number of chlorine atoms in
one molecule of insecticide is –
PAGE NO.-84
10. Match List I (Reactants) with List II (Products) and select the correct answer using the code given below
the lists:
List I List II
OH
CH2OH
(P) (1) Br2 / CS2 (1)

 OH
( 2) (CH3 )2 SO 4 / OH
NH2 OCH3
(1) NaNO / HCl

(Q) 
2
 (2)
( 2) H2O, 283 K
OCH3 OH
OH OH

(1) CHCl / O H
(R)   3 
 (3)
( 2) H2O
(3 ) NaBH 2
OH
Br OCH 3
(1) Br / Fe
(S)  
2
 (4)
( 2) Mg / Ether
(3 ) O2
( 4 ) H2O Br
Codes:
P Q R S P Q R S
(A) 4 2 3 1 (B) 3 1 4 2
(C) 4 2 1 3 (D) 2 4 1 3
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Topic: Oxidative cleavage of C=C/CC
KMnO4 and K2Cr2O7 are amongst the strongest oxidising agent. They completely rupture the C=C or CC and
form oxidised products as Acids and ketones depending on structure of C=C and CC. Observe the following
oxidative cleavage of C=C and CC by oxidising agents (O.A) as
(a) KMnO4 (b) K2Cr2O7 or CrO3/H (c) O3/H2O or O3/H2O2
General Reactions:
O.A. O.A.
 
O.A. O.A.
 + CO2+ H2O  2RCOOH
O.A.
 + CO2 + H2O
Examples :
O.A. O.A.
  + H2O
O.A. O.A.
 + CO2+ H2O  2CH3COOH
O.A.
 + CO2+H2O
Note : 1. Alkene & alkyne having = CH2 &  C–H will give CO2 as one of the oxidation product by oxidising
agent KMnO4 and K2Cr2O4 or CrO3/H+.
O.A.
2. HCOOH (Formic Acid) or H2C2O4 (Oxalic Acid)  CO2 + H2O.
PAGE NO.-85
K Cr O
11. 2 2
7
 P ; Products is:
(A) CH3–CH2–CHO (B) (C) CH3–CH2–COOH (D) CH3–COOH
12. Which Product obtained by the following reaction.

KMnO / H

4


OH
(A) (B) (C) (D) O
OH
O
KMnO 4 / H
13. A   CH3COOH + CH3CH2COOH. The Alkyne 'A' can be:
(A) CH3–CH=CH–CH3 (B) CH3–CC–CH3
(C) CH3–CH=CH–CH2–CH3 (D) CH3–CC–CH2–CH3
14. From which of the following alkene, CO2 is one of the oxidation product by KMnO4/K2Cr2O7 /H . +
(A) CH3–CH=CH–CH3 (B) CH3–CH=CH2
(C) (D)

One or more than one choice Objective Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Matching List Type (One Option Correct) ('–1' negative marking) Q.12 (3 marks, 2 min.) [03, 02]
1. Which of them yields para Bromophenol as major product.
NH2
NaNO /HCl
(A) 
2
 
Steam


Br
OH CH3–C–Cl / Pyridine
O Br water dil H SO / 
(B) 2 
2
4
Br OH
1 eq. NaOH Sn / HCl NaNO / H SO
CuBr / HBr
(C) 
 (D)   
2 2 4

  
Br NO2
2. Primary (1º) amine group is formed in :
NaHS Br /KOH
(A) 
 (B) 
2

CH NH /Cu O/ H2O

(C) 
3 2 2

 (D)  
PAGE NO.-86
3. The reagents are :
(a) (b) (c) (d) (e)


 
 
  
 
Cl / Fe 4 HNO KCN  H SO ,  NH HS NaNO / HCl

   
2
(A) 
2 3 2 4
 
(a) (b) (c) (d) H2O/ (e)
.
HNO3  H2SO4 ,  NH4HS NaNO2 / HCl, H2O/ Sn / HCl CO2 / NaOH/ 

(B)        
(a ) (b) (c) (d) (e)
HNO 2 H SO
Sn / HCl (i) Cl / Fe Cl / Fe KCN
(C) 
3 2 4
    
2
 

(a ) (ii) NaOH/  (c ) ( d) (e) H3O 
(b)
HNO3  H2SO4 ,  NH4HS NaNO2 / HCl, H2O/ Sn / HCl KCN

(D)       
(a ) (b) (c) (d) (e) H3O 
4. Which of the following observations may be correct
H O / heat ( X) / OH  ( dilute )
 (X) 
NaNO 2 / HCl 2
 (Y)  (Z)
(0  5C)
KI
(A) X   (B) Z =

(C) Y (D) Y =
5. Diazocoupling reaction in aromatic compounds is an electrophilic substitution reaction. In which of the
following reaction the ring subsitution is most suitable for diazocoupling reaction?
(A) + (B) +
(C) + (D) +
Write up : (Q.6 to Q.8)

NH2
+ CuCN H O
HNO 3 Fe / H NaNO
  X    2      3 
 'Z'
HCl 
+
CH3 Y CH3
+
Fe / H NaNO CuBr
W    2    
 ' V '
HBr 
PAGE NO.-87
6. Compound 'V' is:
CH3 CH3 CH3 CH2Br
Br
(A) (B) (C) (D)
Br
Br
7. Compound 'X' and 'Y' are:
(A) Metamers (B) Chain isomers (C) Position isomers (D) Functional isomers
8. Compound 'Z' is:
CH3 CH3 CH3 CH3
COOH CN
(A) (B) (C) (D)
COOH CN
(i) Conc .HNO3  Conc .H2SO 4
(ii) Sn / HCl
9.           Proudct
(iii) Br2 / H2O
(iv ) NaNO2  HCl (0 5C)
( v ) Cu2Br2  HBr
What is the number of halogen atoms in final product ?
10. A mixture of 1° amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/NaOH. The
number of 1° amines products formed will be:
11. How many Five member ring present in A.
NH2
Aq.NaNO

2
 A
HCl (0C)
NH2
12. Match list I (reaction) with II (products) and then select the correct answer from the codes given below
the lists:
List-I List-II
(P) Phenol + NaOH + CH3 (1) Phenolphthalein
(Q) Phenol + NaOH +CHCI3 (2) Salicylic acid
(R) Phenol + Phthalic anhydride + conc. H2SO4 (3) Anisole
(S) Phenol + CO2 + NaOH (4) Salicylaldehyde
Codes:
P Q R S P Q R S
(A) 1 2 3 4 (B) 4 3 2 1
(C) 3 4 1 2 (D) 4 3 1 2
ChemINFO Oxidation
Daily Self-Study Dosage for mastering Chemistry Baeyer–Villiger oxidation
Peroxy acid have general structure as (RCO3H). They are relatively unstable and easily gives
nascent O hence, acting as oxidant. It converts ketone into ester.
General reactions :
O. A. O. A.
   
PAGE NO.-88
Migratory aptitude : –H > –Ph > –Et > –Me
O.A. = Oxidizing agent. Peroxy acids as an oxidizing agent may be one of these
CO H
– 3
(a) = m-CPBA (Metachloro perbenzoic acid)
–
Cl
(b) CH3CO3H = PAA (Peracetic acid)
m-CPBA
Ex-1: CH3—C—CH3 CH 3—C—O—CH 3 Ex-2:
O O
Ex-3:
13. Which reagent is used for the following reaction?
(A) PhCOOOH (PBA) (B) CH3COOOH (PAA)

(C) m-Chloroperbenzoic acid (m-CPBA) (D) All of these
14. Which reagent is used for the following conversion?

Reagent

(A) KMnO4 / H+ (B) K2Cr2O7 / H+

(C) m-Chloroperbenzoic acid (m-CPBA) (D) CrO3 / H+
15. Which of the following is the main product obtained by the given reaction.
(A) (B) (C) (D) None of these
16. Which of the following is the main product obtained by the given reaction:
Peroxy

acid
(A) CH3CHO (B)
(C) (D)

1. Which of the following products is formed when benzaldehyde is treated with CH3MgBr and the addition
product so obtained is subjected to acid hydrolysis.
(A) Secondary alcohol (B) A primary alcohol
(C) Phenol (D) Tert-Butyl alcohol
2. Which carbonyl compound (s) can be used to produce 2-Phenylbutan-2-ol on reaction with a suitable
grignard reagent ?
(A) CH3–CO–CH2–CH3 (B) Ph–CO–CH3
(C) Ph–CO–CH2–CH3 (D) All of these
PAGE NO.-89
3. Which of the following are correct?

H2O/ H
(A) CH3–CH2MgBr + HCHO  CH3–CH2–CHO
DO
(B) CH3–CH2–CHO + LiAlH4   CH3–CH2–CHD–OH
2
HO
(C) CH3–CH2–CHO + NaBD4   CH3–CH2–CHD–OH
2
H SO
(D) CH3–CH2–CHO + NaCN  
2 4
4. Reaction of acetaldehyde with HCN followed by hydrolysis gives a compound which shows
(A) Optical isomerism (B) Geometrical isomerism
(C) Metamerism (D) Tautomerism
5. Which of the following can not react with Grignard reagent?
(A) (B) D2O (C) CH2=CH2 (D) Phenol
6. Which of the following pair of compounds can not show SN2Th reaction:
(A) CH3COOH & CH3COCl (B) CH3COOCOCH3 & CH3COOCH3
(C) CH3COOCH3 & CH3COCH3 (D) CH3COOH & C2H5COOC2H5
7. Which of the following reaction is not feasible?

(A) CH3COOH + PCl3 CH3COCl + H3PO3
(B) CH3COCl + CH3COONa CH2COOCOCH3 + NaCl
(C) CH3COOCOCH3 + C2H5ONa CH3COOC2H5 + CH3COONa
(D) CH3CONH2 + C2H5ONa CH3COOC2H5 + NaNH2
8. In the following sequence of reaction the final product mixture P + Q is :

O
||
PCl3
CH3 – C – OH  CH3COONa C2H5ONa
   P + Q
(A) CH3COOCOCH3 + C2H5ONa (B) CH3COOC2H5 + CH3COONa
(C) CH3–COOCl + CH3COONa + C2H5ONa (D) CH3COOCOCH3 + CH3COONa
9.
(X)
Compound X is most reactive towards SN2 Th reaction when P is:
(A) –CH3 (B) –Br (C) –OCH3 (D) –NO2
10. ; Z can not be:
(A) PCl5 (B) PCl3  (C) SOCl2 (D) SO2Cl2

H O
11. 2 A + B
A and B are respectively-

18 18
(A) CH3CH2COOH & C2H5 OH (B) CH3CH2COONa & C2H5OH
18 18
 (C) CH3CH2 COONa & C2H5OH (D) CH3CH2 COONa & CH3CH2ONa
PAGE NO.-90
12. Which of the following acid is most reactive toward esterification reaction?
(A) Me–COOH (B) n-PrCOOH  (C) Me3CCOOH (D) Et3CCOOH
13. The rate of esterification of CH3COOH is fastest with.
(A) (B) (C) (D)
14. The major product (ester) of the following reaction is:
H SO
+ 2 
4

(A) A single stereoisomer (optically active)

(B) A mixture of diastereomers (both optically active)
(C) A racemic mixture (optically inactive)
(D) A mixture of four stereoisomers (two racemic mixtures)
15. If pentan-2-one is reduced with NaBH4 followed by hydrolysis with D2O, the product will be:
(A) CH3–CH(OD)CH2CH2CH3 (B) CH3CD(OH)CH2CH2H3
(C) CH3CH(OH)CH2CH2CH3 (D) CH3CD(OD)CH2CH2CH3
16. Which of the following give when heated with propanone?
(A) CH3MgI then D2O (B) LiAlH4 then D3O+ (C) LiAlD4 then H3O+ (D) NaBH4 then D3O+
(i) CH MgBr ( excess )

17. Phenyl acetate 
3
 'P', 'P' can be:
(ii) H
Ph Me Ph Ar Ph Me
(A) (B) (C) (D)
H OH
Me OH Et OH
18. Which one of the following is least reactive for hydrolysis reaction?
(A) (B)
(C) (D)
19. Acidic hydrolysis is minimum in

O O
O – COR O – COR O–C–R
O–C–R
(A) (B) (C) (D)

NO2
| |
NO2 OC2H5
PAGE NO.-91
20. The reaction,
O O
– –
R–C + Nu R–C +X
X Nu
is fastest when X is :
(A) Cl (B) Br (C) I (D) F
21. 6-Bromo-2-hexanone is treated with magnesium in presence of THF produce X as major product.
How many carbon atoms present in the ring of product 'X'.
22. Numbering of some reactions are given as following. Which number of the reaction is SN2Th Reaction.
(1) CH3COOH + NaOH CH3COONa + H2O
(2) CH3COOH + SOCl2CH3COCl + SO2 + HCl
AlC·KOH
 
(3) 
(4) CH3Br + NaOH CH3OH + NaBr
23. +   + HCl
Numbering of type of reaction are given as following which number is given for above reaction
(1) SN2Th reaction (2) Nucleophilic addtition reaction
(3) Addition reaction (4) Elimination Reaction
24. Ester A
In Ester 'A' How many atoms present in the cyclic system.
25. How many grignard reagent required to react 1 mole of acetyl chloride.
PAGE NO.-92
ANSWERS KEY
PHYSICAL / INORGANIC CHEMISTRY
DPP No. # A1
8. 3 9. 5 10. –3 11. 6
12. (A – p,q) ; (B – p,q) ; (C – s) ; (D – r)
DPP No. # A2
21. 4 22. 2 23. 3 24. 2 25. 29 k Cal
DPP No. # A3
6. 01 7. 02 8. 5 9. 6 10. 4
11. 4 12. [A – p,q,r,s] ; [B – q, r] ; [C – q, s] ; [D – p].
DPP No. # A4
17. 6 18. 9 19. 2 20. 6 21. 5
DPP No. # A5
11. 06 12. 0 13. 2
14. [A - p,q,s]; [B - q]; [C - r]; [D - q]
DPP No. # A6
17. 85% 18. 2% 19. 7 20. 14 g 21. 6
DPP No. # A7
4. 4 5. 4 6. 2 7. 7
8. (a) Sodium pentacyanido-C-nitrosoniumferrate(II) (Sodium nitroprusside-diamagnetic)

(b) Bis (dimethylglyoximato) nickel (II)
(c) Ammonium dinitrosyltetrathiocyanato-S chromate (III)
(d) Diaquadiiodidodinitrito-O palladium (IV)
(e) Tetraamminechloridothiocyanato-N cobalt (III) ion
PAGE NO.-93
(f) Potassium tetraoxidoferrate (IV)

(g) Potassium tetraazidocobaltate (II) [N3¯ is azide]
(h) Dichloridobis(triphenylphosphine) nickel (II)
(i) Tris(acetylacetonato)chromium (III) [(acac)¯ is ]
(j) Tetrakis(pyridine)platinum(II) tetrachloridoplatinate (II)
9. (a) Fe2+ + 6H2O + Cl¯  [Fe(H2O)6]2+ Cl¯

Cation is a complex ion and carries + 2 charge, hence its structure is [FeII(H2O)6]Cl2
Oxidation state of the metal ion has been given in the structure. Students may omit it.

(b) K + Ag3+ + 4F¯  K+ [AgF4]¯ anion is a complex K+ [AgIIIF4]¯
cation
(c) [TiIICl5]3– (d) [CoIII(NH3)4Cl2]Cl (e) [AgI(CN)2]¯ (f) [Ni(NH3)2Cl4]2–
(g) [CuII(en)3]SO4 (h) Na[AllII(H2O)2(OH)4] (i) [CrIII(NH3)Cl(en)2]SO4 (j) K2[ZnII(CN)4]
10. (A) – p,q,r ; (B) – p,r ; (C) – p,q,r ; (D) – p,q,s,t
DPP No. # A8
17. 6 18. 3 19. 8 20. 22 m mol 21. 12
DPP No. # A9
6. 6 7. 3 8. 00 9. 8 10. 5
11. 9 12. 5 13. 5
14. [A - r]; [B - p]; [C - p,q,s]; [D - q,p].
DPP No. # A10
21. 6 22. 2 23. 6 kJ 24. 8 25. 8
15. 34 16. 6 17. 09 (i, ii, iii, v, vi, vii, viii, ix, x) 18. 2
DPP No. # A12
7. 20 8. 03 9. 05 10. 2 11. 8
12. 8 13. [A – p,q,r]; [B – p]; [C – p,r]; [D – s,r]
PAGE NO.-94
DPP No. # A13
7. 02 8. 07 9. 21 10. 8 11. 2
12. 34 13. (A) q,r ; (B) p,s ; (C) q ; (D) q,r
DPP No. # A14
17. 6 18. 3 19. 5 20. 22.0 kcal 21. 6
DPP No. # A15
8. 1 9. 6 10. 83.9 11. 5 12. 90.00
13. 7 14. 24 15. 81 16. 02
DPP No. # A16
7. 3 8. 5 9. 90 10. 5 11. 1
12. 67.20 13. (A)  p, r ; (B)  q, s ; (C)  p, r ; (D)  q, s
DPP No. # A17
21. 3 22. 3 23. 7 24. 4 25. 6
DPP No. # A18
9. 1 10. 5 11. 3 12. 5
13. (A)  q, r ; (B)  p, s ; (C)  q ; (D)  q, r
DPP No. # A19
18. 9 19. 5 20. 3 21. 6 22. 1
DPP No. # A20
5. 27 6. 8 × 10–3 lt. 7. 6.4 × 10–4 cm 8. 1 9. 7
10. 38 11. 6 12. 6
13. (A - p, r); (B - r); (C - q, s); (D - p, q, r, s).
PAGE NO.-95
ORGANIC CHEMISTRY
DPP No. # A1
21. 1 22. 3 23. 5 24. 2 25. 4
DPP No. # A2
10. 6 (2, 3, 4, 5, 6, 8) 11. 3 12. 36
13. (A)  (q, r, s); (B)  (q, r); (C)  (q, r, s); (D) (s)
DPP No. # A3
17. 5 18. 5 19. 2 20. 8 21. 0
DPP No. # A4
8. 6 9. 4 10. 6 11. 4
12. (A)  p,q ; (B)  p,q ; (C)  p, r, s ; (D)  p,r
DPP No. # A5
17. 8 18. 4 19. 2 20. 8 21. 2
DPP No. # A6
19. 2 20. 60 21. 6 22. 2
DPP No. # A7
9. 2 2 10. 08 11. 2 12. 7
13. (A – p,t) ; (B – q,s) (C – p,t) ; (D – q,r)
14. (A)  (p, q) ; (B)  (p, s) ; (C)  (p, r) ; (D)  (p, s)
DPP No. # A8
21. 3 22. 8 23. 4 24. 6 25. 5
PAGE NO.-96
DPP No. # A9
17. 4 18. 4 19. 7 20. 3 21. 6
DPP No. # A10
9. 4 10. 9 12. (A – q , s) ; (B – p, q) ; (C – q) ; (D – p, r)
DPP No. # A11

17. 03 18. 94 19. 3 20. 3 21. 1
DPP No. # A12
7. 3 8. 7 9. 5
DPP No. # A13
9. 4 10. 4 11. 1
DPP No. # A14
21. 5 22. 2 23. 1 24. 5 25. 2
PAGE NO.-97

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DPPs BOOKLET-1 | VIJETA (01&02JPB & 01&02JPAB) |

JEE(Main+Advanced). It is a collection of problems (Physics, Chemistry & Mathematics in

the target exam.

are welcome at smdd@resonance.ac.in.

S. No. Particulars Page No.

ORGANIC CHEMISTRY DPPS

S. No. Particulars Page No.

1. DPP No. A1 053 – 055

2. DPP No. A2 055 – 057

3. DPP No. A3 057 – 061

4. DPP No. A4 061 – 062

5. DPP No. A5 063 – 066

6. DPP No. A6 066 – 070

7. DPP No. A7 070 – 072

8. DPP No. A8 073 – 074

9. DPP No. A9 075 – 078

10. DPP No. A10 079 – 083

11. DPP No. A11 084 – 087

12. DPP No. A12 087 – 091

13. DPP No. A13 091 – 094

14. DPP No. A-14 094 – 097

ANSWER KEY 098 – 101

DPP No. # A1 (JEE-ADVANCED)

(A) SAB izØe ds izdkj ij fuHkZj ugha djrkA

ChemINFO Solution & Colligative Properties

DPP No. # A2 (JEE-MAIN)

3. lgh fodYi @ fodYiksa dk p;u dhft, %

7. fuEu esa ls dkSulk yo.k dk _.k&vk;fud ty vi?kVu n'kkZrk gSA

(A) (B) (C) (D)

23. 0.1 M RCOOH (Ka = 10–5) ds tyh; foy;u dk pH gS %

DPP No. # A3 (JEE-ADVANCED)

3. fuEu esa ls dkSulk@dkSuls flfydkWuksa ds fy, lR; gS@gSa \

ChemINFO Solution & Colligative Properties

,d 'kq) inkFkZ ds voLFkk vkjs[k ds dqN egRoiw.kZ vfHky{k.k%

CO2 dk voLFkk vkjs[k%

DPP No. # A4 (JEE MAIN)

(A) (B) (C) (D)

6. mikip;h vfHkfØ;k MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O ds fy,

9. tc cksjsDl dks ty esa ?kksyk tkrk gS] rks %

10. fuEu esa ls dkSulk dFku xyr gS &

11. fuEu esa ls dkSulk yo.k ty eas U;wure foys; gksrk gS \

ChemINFO Solution & Colligative Properties

(iii) fefJr djus ij ;gk¡ vk;ru esa deh gksrh gS o

22. og feJ.k igpkfu;s tks _.kkRed fopyu dk foy;u n'kkZrk gS %

DPP No. # A5 (JEE-ADVANCED)

ChemINFO Solution & Colligative Properties

DPP No. # A6 (JEE-MAIN)

16. og vkWDlkbM tks fd vipk;d ugha gS] fuEu gS %

ChemINFO Solution & Colligative Properties

,ye ds mnkgj.k % lksMk ,ye : NaAl(SO4)2·12H2O

DPP No. # A7 (JEE-ADVANCED)

10. dkWye–I esa lwph c) fyxs.Mksa dks

ChemINFO Coordination Compounds

VªsVk,DokdksckYV (III)-m-,ekbMks-mgkbMªksDlkbMksVªsVk,ehuØksfe;e (III) lYQsV

m-,ekbMks-m-gkbMªksDlkbMksfcl (fcl(,FkkbyhuMkbZ,Eehu)dksckYV(III)) lYQsV

11. dk lgh uke D;k gS\

(A) -,ekbMks--gkbMªksDlkbMksfcl (VªsVk,EehudksckYV (III)) vk;u

14. fcl ¼,FkkbyhuMkbZ,ehu½dksckYV(III)--bekbMks--gkbMªksDlkbMksfcl¼,FkkbyhuMkbZ,ehu½ dksckYV (III) DyksjkbM vk;uksa

DPP No. # A8 (JEE-MAIN)

13. CO2 ds lEHkou dh ekud eksyj ,UFkSYih fdlds cjkcj gS -

ChemINFO Coordination Compounds

DPP No. # A9 (JEE-ADVANCED)

(A) PV (B) PV (C) PV (D) PV