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Summary Collection Code 165593

Struct. formula K Cl Structure type NaCl

Cell parameter 6.2849(5) 6.2849(5) 6.2849(5) 90 90 90 Space group F m -3 m (225)

Cell volume 248.25 [ų] Z 4
Temperature 290 [K] Pressure atmospheric
Data quality High quality R-value 0.138
Author Cherginets, V.L.; Baumer, V.N.; Galkin, S.S.; Glushkova, Title Solubility of Al2 O3 in some chloride-fluoride melts
L.V.; Rebrova, T.P.; Shtitelman, Z.V.
Reference Inorganic Chemistry (2006) 45, (*) p7367-p7371 DOI 10.1021/ic060181r

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Published Crystal Structure Powder Pattern

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Chemistry

Sum. formula Cl1 K1 Struct. formula K Cl

Molecular weight 74.5500 [u] Z 4

ANX formula AX AB formula AB

Chemical name Potassium chloride

Published Crystal Structure Data

Cell parameter 6.2849(5) 6.2849(5) 6.2849(5) 90 90 90 Space group F m -3 m (225)

Cell volume 248.25 ų Z 4

Crystal system cubic Crystal class m-3m

Laue class m-3m

Structure type NaCl

Pearson symbol cF8 a/b b/c c/a

Wyckoff sequence b a Axis ratios 1.0000 1.0000 1.0000

Calc. density 1.99 [g/cm³]

EL Lbl OxState Wyck Symb X Y Z SOF U

K 1 +1.00 4a 0.00000 0.00000 0.00000 1.000000 0.00735
Cl 1 -1.00 4b 0.50000 0.50000 0.50000 1.000000 0.00466

Standardized Crystal Structure Data

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10/3/2020 ICSD - Details on Search Result

Cell parameter 6.2849 6.2849 6.2849 90.000 90.000 90.000 Space group F m -3 m (225)

Cell volume 248.25 ų Z 4

Crystal system cubic Crystal class m-3m

Laue class m-3m

Structure type NaCl

Pearson symbol cF8 a/b b/c c/a

Wyckoff sequence ba Axis ratios 1.0000 1.0000 1.0000

Transformation info Multiple transformations possible, first one selected

EL Lbl OxState Wyck Symb X Y Z SOF U

K 1 +1.00 4a 0.0000 0.0000 0.0000 1 0.0074
Cl 1 -1.00 4b 0.5000 0.5000 0.5000 1 0.0047

Distances and Angles

Bibliography

Author Cherginets, V.L.; Baumer, V.N.; Galkin, S.S.; Glushkova, Title Solubility of Al2 O3 in some chloride-fluoride melts
L.V.; Rebrova, T.P.; Shtitelman, Z.V.

Reference Inorganic Chemistry (2006) 45, (*) p7367-p7371 DOI 10.1021/ic060181r

Abstract Alumina solubility in chloride-fluoride melts of KCl-NaCl-NaF mixtures with ratios of 0.425:0.425:0.15 (I), 0.38:0.38:0.24 (II), and
0.35:0.35:0.30 (III) (molar fractions) was investigated in the 973-1123 K temperature range using the isothermal saturation method. Al2O3
solubility in the ionic melts studied was shown to be on the order of 0.06 g kg-1 for system I, 0.12 g kg-1 for system II, and 0.14 g kg-1 for
system III at 1073 K. All the ''Al2O3 + melt'' systems were found to demonstrate negative deviations from the ideal solutions. The
solubility of Al2O3 in all the melts increases with the temperature increase; however, the dependences of -log NAl2O3 versus T-1 were
characterized by the slopes (2.6 +- 0.4) x 103 K (I and II) and (2.4 +- 0.6) x 103 K (III), which were considerably less than the slope
predicted by the Shreder-Le Chatelier equation (similar 5.8 x 103).

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Experimental information

Temperature 290 [K] Pressure atmospheric

Radiation type X-Ray Sample type Powder data

R-value 0.138

Remarks Rietveld profile refinement applied Remarks Temperature factors available

Additional information

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Published Crystal Structure Standardized Crystal Structure

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