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Long-Term Control of Paraffin Deposition: SPE Members
Long-Term Control of Paraffin Deposition: SPE Members
SPE 13126
This paper was presented at the 59th Annual Technical Conference and Exhibition held in Houston, Texas, September 16-19, 1984. The material is sub-ject to
correction by the author. Permission to copy is restricted to an abstract of not more than 300 words. Write SPE, 6200 North Central Expressway, Drawer 64706,
Dallas, Texas 75206 USA. Telex 730989 SPEDAL.
A second method for removing paraffin involves thermal compares the long-term effectiveness of both inhibitors in the same
1 9 field. In a second field evaluation, the blend of crystal modifiers was
methods. ' The thermal methods used include bottomhole heaters; used in two wells to successfully control paraffin deposition. Samples
circulation of hot oil, water or steam; and the use of heat-liberating of crudes from these wells were monitored periodically for paraffin
chemicals. Magnesium bars followed by hydrochloric acid produce a content and paraffin deposition.
chemical reaction resulting in the release of heat. The heat melts the
paraffin, facilitating its removal. However, in order to prevent further
deposition, th~ temperature of the crude must be maintained above the
melting point of the paraffin. Bottomhole heaters require special TEST PROCEDURES
equipment and added power consumption. In addition, hot fluids can be
dangerous and normally involve equipment service costs. Asphaltene and Paraffin Content Determination
If the crude is sampled from a well previously treated with Paraffin deposition tests were performed with Paraffin
paraffin inhibitor, 510 g of the crude is weighed into a one liter Inhibitor A (ethylene-vinyl acetate copolymer) and Paraffin
mason jar. A lid is placed on the jar, substituting aluminum foil for Inhibitor B (controlled-release blend of crystal modifiers) in nine
the snap cap and the jar placed into a 150°F waterbath overnight. A different crudes. The test results are listed in Table I. Long-term
sample from an off-set well not treated with paraffin inhibitor is weight loss tests using Paraffin Inhibitors A and B were performed
used as a control. If the crude is sampled from a well not treated at 100° and 150°F. Long-term weight loss tests using the inert
with paraffin inhibitor, 510 g of the crude is weighed into a one carrier component in Paraffin Inhibitor B were also performed at
liter mason jar. The appropriate amount of paraffin inhibitor to be 100° and 150°F. The results of these tests may be found in Tables
evaluated is added to the jar and the jar placed in a 150°F waterbath II and III.
overnight. A sample with no paraffin inhibitor is used as a control.
Laboratory Evaluation
Paraffin Inhibitor B remained in the pellet after 20 after the third month up until the time of the hot
weeks. oil treatment. The wells treated with Paraffin
Inhibitor B showed an even paraffin deposition
Long-term weight loss tests were also performed during the production history.
with the inert carrier of Inhibitor B in the Dean In summary, well 8 had 305 days of production
Sand crude at 100° and 150°F. The test results
after 20 weeks of exposure revealed that less than 1 without a paraffin-related problem. Wells 9 and 10
percent of the carrier was dissolved in the 100°F are still producing without a paraffin-related
test and less then 10 percent in the 150°F test. problem after 347 and 315 days, respectively. A
production history up-date will be given during the
Field Evaluation I oral presentation of this paper.
ACKNOWLEDGMENTS
REFERENCES
OF (°F- 32)/1.8
lbm X 4.535924 E-01
ft X 3.048* E-01
gal X 3.785412 E-03
All tests were conducted with 300 PPH active ingredient(s) of each paraffin inhibitor.
Table II
Exposure To Dean
Sand Crude, weeks Inhibitor A Inhibitor B Inhibitor A Inhibitor B
1 100 10 100 13
2 28 34
4 30 40
8 34 40
20 38 50
Table Ill
1 <1 <1
2 <1 <1
4 <1
8 <1 4
16 <1 7
20 <1 6
Table IV
* As of 6/18/84
Table V
Inhibitor A Inhibitor B
Elapsed Time Since
Stimulation Treatment, months Well 8 Well 9 Well 10
5.6 5. 6
4.4 5.3
5.0 5. 8 4. 8
5.4 8.8
1.6
10 3. 8
Table VI
% DeEosition*
Inhibitor A Inhibitor B
Elapsed Time Since
Stimulation Treatment, months Well 8 Well 9 Well 10
56 60
47 48
17 59 45
51 45 47
50 52
3 26
7 25
8 54
Table VIII
Date of First
Well Date Stimulated Paraffin Inhibitor Reported Paraffin Problem Time Produced, days
* As of 6/18/84
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Fig. 1-Laboratory apparatus used for paraffin deposition test.