Chapter-2, Qualitative Chemistry

H-spectrum [part-1]

1. The radius of 4th orbit of electron of H atom 8.45  10−10 m. On this atom in 2nd and 3rd Bohr
shell the energy of an electron is − 5.42  10−12 erg and − 2.41  10−12 erg .

i. Calculate the velocity of the electron in 4th orbital only following the stem data.
ii. As the energy radiated when the electron comes from 3rd shell to 2nd shell, calculate the
wavelength of that energy.

2. Radius of an orbit is 8.5  10−8 cm & velocity of electron is 5.4452  107 cms−1. In which orbit
that electron is rotating.

3. What is the frequency, wave length, wave number and radiation energy of electron, when it
comes 2nd shell from 4th shell?

4. Calculate the velocity and angular velocity of the electron in the last energy shell of Chlorine?
[ S.B-16]

5. Read the stem:

EC = −3.1  10−12 erg

rc = 6.7A

rB = 4.3A
+
A EA = −8.910−12erg
B
C
i. Find the wave length of emissions spectrum due to the transition of an electron from C to A-
shell using the information of given stem.
ii. The velocity of electron will increase with increase of distance between electron and nucleus−
analyze the statement mathematically.

6. Dhaka, Dinajpur, Sylhet, Jashore Board-2018

D
C
B
A

RH = 109678cm–1

What will be the colour of the emitted rays if the electron of the stem transmitted to B-shell?
Analyse mathematically.

7. Cumilla Board-2019

5(E)
4(D)
3(C)
2(B)
1(A)
The wave length of 3rd line of 'B' shell created the colour which will be visible or not. Explain
mathematically.
8. Barishal Board-2019
e E

+ K L M

H-atom
2nd part

The radiation shown in part-2 is used in either medical or testing fake notes ⎯ Analyze.

9. Rajshahi Board-2017
e−
M
L
+ K

The model is applicable to hydrogen atom. Calculate the wavelength of the emitted energy for
the electronic transition shown above.

10. Rajshahi, Cumilla, Chattogram, Barishal Board-2018

Electron

X
Y
Z
In which region of electromagnetic radiation is the emitted wavelength for the transition of electron
of the stem found? Evaluate mathematically.

11. Dinajpur Board–2017, 2016.

•e
• + XY Z

Calculate the absorbed radiation by the electron transition shown in the stem.

12. Barishal Board-2017

M
L

K
e
+

Consider the model as hydrogen atom. Calculate the absorbed energy and its frequency for the
electronic transition shown in the stem.