Performance Report Creation Time: 2019-08-06 11:51

Instrument: iCAP OES

Operator: ICP-OES-PC\admin

Sensitivity Test Results Result: Failed

End Time: 2019-08-06 11:45

The sensitivity test has failed, please check the following items:

- The test solution used is correct

- The sample capillary tubing is not kinked or blocked
- The peri pump tubing is in good condition
- The pump tension is correctly adjusted
- The nebulizer is not blocked
- The nebulizer is correctly positioned in the spraychamber
- The correct center tube is fitted, 1.5mm for Radial instruments and 2mm for Duo instruments
- A Torch Alignment routine has been run if the torch has been removed and replaced

Nebulizer Gas Flow 0.50 L/Min

Element Wavelength Order Result

Ba 455.403 74 Failed

Signal: 7849.9 cps Background: 3480.552 cps View: Radial

Minimum Limit: 9000.000 cps Sbr: 2.255 Slit: Visible

Cu 324.754 104 Failed

Signal: 901.1 cps Background: 367.837 cps View: Radial

Minimum Limit: 1000.000 cps Sbr: 2.450 Slit: Visible

K 766.49 44 Passed

Signal: 2919.9 cps Background: 10389.202 cps View: Radial

Minimum Limit: 2379.000 cps Sbr: 0.281 Slit: Visible

Mn 257.61 131 Failed

Signal: 4523.9 cps Background: 148.873 cps View: Radial

Minimum Limit: 6986.000 cps Sbr: 30.388 Slit: Visible

Ba 455.403 74 Passed

Signal: 194408.8 cps Background: 13300.361 cps View: Axial

Minimum Limit: 9000.000 cps Sbr: 14.617 Slit: Visible

Ca 317.933 106 Passed

6053.5 cps
Performance Report Creation Time: 2019-08-06 11:51
Instrument: iCAP OES
Operator: ICP-OES-PC\admin

Signal: 6053.5 cps Background: 2106.299 cps View: Axial

Minimum Limit: 4815.000 cps Sbr: 2.874 Slit: Visible

Cu 324.754 104 Failed

Signal: 22999.0 cps Background: 1838.498 cps View: Axial

Minimum Limit: 24786.000 cps Sbr: 12.510 Slit: Visible

K 766.49 44 Passed

Signal: 466914.4 cps Background: 34401.700 cps View: Axial

Minimum Limit: 371070.000 cps Sbr: 13.572 Slit: Visible

Mn 257.61 131 Passed

Signal: 91426.5 cps Background: 936.333 cps View: Axial

Minimum Limit: 7000.000 cps Sbr: 97.643 Slit: Visible

Al 167.079 502 Failed

Signal: 382.2 cps Background: 22.264 cps View: Axial

Minimum Limit: 800.000 cps Sbr: 17.168 Slit: UltraViolet

Ni 221.647 452 Passed

Signal: 52592.1 cps Background: 629.535 cps View: Axial

Minimum Limit: 40707.000 cps Sbr: 83.541 Slit: UltraViolet

P 177.495 490 Failed

Signal: 3847.0 cps Background: 61.673 cps View: Axial

Minimum Limit: 5202.000 cps Sbr: 62.378 Slit: UltraViolet

Zn 213.856 458 Passed

Signal: 5096.2 cps Background: 314.122 cps View: Axial

Minimum Limit: 3870.000 cps Sbr: 16.224 Slit: UltraViolet

Geomean
SensitivityResult
Test Results Result:
Result: Failed Calculated Geomean: 3109.097 cps
Performance Report Creation Time: 2019-08-06 11:51
Instrument: iCAP OES
Operator: ICP-OES-PC\admin

View: Radial Lower Limit: 4023.000 cps

Geomean
SensitivityResult
Test Results Result:
Result: Failed Calculated Geomean: 19741.103 cps

View: Axial Lower Limit: 22037.000 cps

Relative
Sensitivity
Standard
Test Results
Deviation Test Result: Passed
End Time: 2019-08-06 11:45
The RSD test has passed

Nebulizer Gas Flow 0.50 L/Min

Element Wavelength Order Result

Ba 455.403 74 true
Passed

Calculated RSD: 0.851 % View: Axial

Upper Limit: 2.000 % Slit: Visible

Ca 317.933 106 true

Passed

Calculated RSD: 1.764 % View: Axial

Upper Limit: 2.000 % Slit: Visible

Cu 324.754 104 true

Passed

Calculated RSD: 0.236 % View: Axial

Upper Limit: 2.000 % Slit: Visible

K 766.49 44 true
Passed

Calculated RSD: 1.211 % View: Axial

Upper Limit: 2.000 % Slit: Visible

Mn 257.61 131 true

Passed

Calculated RSD: 0.185 % View: Axial

Upper Limit: 2.000 % Slit: Visible
Performance Report Creation Time: 2019-08-06 11:51
Instrument: iCAP OES
Operator: ICP-OES-PC\admin

Al 167.079 502 true

Passed

Calculated RSD: 2.437 % View: Axial

Upper Limit: 4.000 % Slit: UltraViolet

Ni 221.647 452 true

Passed

Calculated RSD: 0.229 % View: Axial

Upper Limit: 2.000 % Slit: UltraViolet

P 177.495 490 true

Passed

Calculated RSD: 1.237 % View: Axial

Upper Limit: 3.000 % Slit: UltraViolet

Zn 213.856 458 true

Passed

Calculated RSD: 0.555 % View: Axial

Upper Limit: 2.000 % Slit: UltraViolet

Relative
DetectionStandard
Limit Test
Deviation Test
Result: Failed
End Time: 2019-08-06 11:51
The detection limit test has failed, please check the following items:

- The test solution used is correct

- The blank solution is not contaminated
- The spraychamber was thoroughly rinsed before measuring the blank
- The peri pump tubing is in good condition
- The pump tension is correctly adjusted
- The nebulizer is not blocked
- The nebulizer is correctly positioned in the spraychamber
- The correct center tube is fitted, 1.5mm for Radial instruments and 2mm for Duo instruments
- A Torch Alignment routine has been run if the torch has been removed and replaced

Nebulizer Gas Flow 0.50 L/Min

Element Wavelength Order Result

Ba 455.403 74 Failed
false

Signal: 194408.8 cps Standard Deviation: 1411.984 cps View: Axial

Upper Limit: 0.300 ppb Concentration: 200 ppb Slit: Visible
Detection Limit: 4.358 ppb
Performance Report Creation Time: 2019-08-06 11:51
Instrument: iCAP OES
Operator: ICP-OES-PC\admin

Detection Limit: 4.358 ppb

Ca 317.933 106 Failed

false

Signal: 6053.5 cps Standard Deviation: 24.400 cps View: Axial

Upper Limit: 1.700 ppb Concentration: 200 ppb Slit: Visible
Detection Limit: 2.418 ppb

Cu 324.754 104 Failed

false

Signal: 22999.0 cps Standard Deviation: 87.669 cps View: Axial

Upper Limit: 1.900 ppb Concentration: 1000 ppb Slit: Visible
Detection Limit: 11.436 ppb

K 766.49 44 Failed
false

Signal: 466914.4 cps Standard Deviation: 5081.668 cps View: Axial

Upper Limit: 3.200 ppb Concentration: 5000 ppb Slit: Visible
Detection Limit: 163.253 ppb

Mn 257.61 131 Failed

false

Signal: 91426.5 cps Standard Deviation: 249.574 cps View: Axial

Upper Limit: 0.500 ppb Concentration: 1000 ppb Slit: Visible
Detection Limit: 8.189 ppb

Al 167.079 502 Failed

false

Signal: 382.2 cps Standard Deviation: 8.014 cps View: Axial

Upper Limit: 0.600 ppb Concentration: 2000 ppb Slit: UltraViolet
Detection Limit: 125.803 ppb

Ni 221.647 452 Failed

false

Signal: 52592.1 cps Standard Deviation: 101.670 cps View: Axial

Upper Limit: 1.200 ppb Concentration: 5000 ppb Slit: UltraViolet
Detection Limit: 28.998 ppb
Performance Report Creation Time: 2019-08-06 11:51
Instrument: iCAP OES
Operator: ICP-OES-PC\admin

P 177.495 490 Failed

false

Signal: 3847.0 cps Standard Deviation: 38.269 cps View: Axial

Upper Limit: 8.800 ppb Concentration: 10000 ppb Slit: UltraViolet
Detection Limit: 298.432 ppb

Relative
GeomeanStandard Deviation Test
Result: Failed
Calculated Geomean: 25.439 ppb View: Axial

Upper Limit: 1.500 ppb