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)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
1. A 24. B 47. A
2. C 25. A 48. D
3. B 26. D 49. A
4. ABD 27. ABCD 50. ABC
5. BC 28. ABD 51. BD
6. AC 29. AD 52. ABC
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 2
Physics PART – I
SECTION – A
1. A
Field due to arc A’B’ is equal to field due to side AB at the centre
y
of arc. Similarly it will hold for other pairs also. So the field at the 0,3m A
incentre is zero.
ax bx2 cx3 ay by2 cy3
x= 1 y 1
A'
abc a bc
3 3
B' C' C
x= m, y= m B x
3m,0
2+ 2 2+ 2
2. C
Since water in the smaller vessel is taking heat from the water in the large vessel. It can reach to
a temperature 100C . Since the temperature of water in the large vessel cannot go
beyond 100°C before boiling completely. Hence water in the smaller vessel will not take heat from
the water outside, it will not boil.
3. B
Magnitude of flux
q I I
E2 E1 A 2 1 I ρ1 ρ2
0
q 0 I 1 2
4. ABD
2 1 80 1 16
T+ 200 20 16 T 80 / 3 N and f 10 42 f N
3 2 3 5 3
For maximum value
1 2 2 1 2
of T 400 / 3 20 & T 100 10 5rad / sec
2 3 5
5. BC
e=B0 v0 2 y 4 B0v03/ 2 t
e Bv
i 0 where y 4v0t
2y
B0 v0 2 B02v0 y 4 B02v03/ 2
F 2 y B0 t
2 B 2v 2 y 4 B 2v5/2
p F .v 0 0 0 0 t
6. AC
From monkey frame
v am va vm 40 ˆj m / s
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3 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
40
time= =1sec
40
7. BCD
Taking torque about R.H. side of loop
mg -T1 ibB=0
2
-πnir 2 Bkˆ
8. AD
T/A
where T M x x
2
Y
x/ YA
1
M
2
And ms U
2
YA 1
YA
2ms 1
M 2
9. C
10. B
SECTION – C
11. 4
Sol: For solid sphere under pure rolling motion
5 1
KE translation = KE total = KX 2max
7 2
X max =4cm
12. 1
V2 dT
=4 T-T0 +4
R dt
T dT t dt V2
T0 V 2 0 C T T0
4R
1 et N 1
4 T T0
R
13. 2
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 4
Sol. 1
Hence dm d F
2
Hence radial component of tension, O dθ
d
2 F sin Fd F
2
nd 2 m 2 R
Fd RF
2 2 F dθ
increment in radius is R so elongation in length of
2
ring
2 R R 2 R 2R
O dθ
R
Strain Y strain
2 R R strain Y
2 2
R m R F
R N 2
R Y 2 AY
14. 6
Consider the object as two portion ‘A uniform rod’ and ‘A frustum’ with thermal resistance R1 and
R 2 respectively then
1
R1
k1 A1 k r 2
And R2 2
k2 A2 2k r1r2 4 k r 2
Equivalent thermal resistance Req R1 R2
5
Req ....................... 1
4k r 2
Now if we consider the same lamina with equivalent thermal conductivity K eq , then
keq
3
Req R1 R2 ........ 2
keq 2 r 2keq r
2 2 2
keq r
By equating the terms of Req from eqn. (1) & (2), we get
5 3
2
4 k r 2keq r 2
6k
k eq
5
N 6
15. 4
As initial angle of approach with horizontal is 45° whereas
the river velocity is zero then =45°
At point B, v S / G along the perpendicular to line AB is zero
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5 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
16. 3
p 2 m 2 m v0
r same T T
qB qB qB
As T 3T they will meet at / 2 +
T 6 m 3
Time is 750 s 250 3 s 3v 0
4 4qB
17. 5
Let v1 and v 2 the speed just before collision. Using COAM about point O on the ground
+Q m -2Q
2m
A B
O
2 v 2 v 42
0 mv1 R mR 2 1 2mv2 R 2mR 2 2 v1 v2
3 R 5 R 25
2
1 12 v 1 5
K A mv12 mR 2 12 .mv12
2 23 R 2 3
1 2 1 14
K B 2mv22 1 mv22
2 5 2 5
K B 42 v22 25
K A 25 v12 42
18. 2
x=u x t 1
1 2
h u y t gt 2
2
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 6
uy ux
Eliminating t and using sin and cos = and θ
u u
substituting in equation (1) and (2) h
gx 2
h 1 cos 2 2 x sin 2
u x
Differentiating w.r.t.
x 2u 2 u2
for maximum value of x tan 2 x h
h g 2g
So maximum Area = x 2 209000m2 0.2km2
19. 1
1 100
X L wL 100 X C 100
wc
i3
100 100 100 1H
i1 = =1A i 2 1A i3 1A
100 100 100
From phasor diagram i2
100μF
i1
i i1
i3
i2
100V,100 rad/sec
So i i3 1A
20. 4
Using WET from a frame moving with velocity 8 ˆj m / s
X max 1 2
0
qv0 B0 x dx cos180 m v0 2
2
X max 4 meter
SECTION – D
21. 00000.73
Impulse due to ‘N’ would act at the centre of the colliding parts
L-x
2
x N
2
Applying Impulse momentum theorem
N .dt M v v0 (1)
& Applying Angular impulse, angular momentum theorem
Lx ML2
N
2 .dt (2)
12
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7 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
L x
v
2
Also e (3)
v0
From (1), (2) & (3)
2
L x L x 2
v 1 3 v0 3 e
2 L2
for v 0
e
x L 1
3
For inequality to hold true for all ‘e’
1
x L 1
3
or x
3 1 , xmax 0.732
22. 00008.89
Power absorbed by shell
P×2π 1-cos37
4π
P
10
For equilibrium
P
3 R 2 T 4
10
P 2400
T 4 2
8.89
30 R 30 9
23. 00056.56
Applying conservation of angular momentum w. r. t. the centre of earth,
4 R mv0 sin 30 mvR, v 2v0
Applying energy conservation
1 2 GMm GMm 1 2
m 2 v0 mv0
2 R 4R 2
GM 64 106
v0 40 2 100m / s
2R 2
x 40 2 56.56
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 8
Chemistry PART – II
SECTION – A
24. B
Sol.
O
O
O
*
* *
H Cl O
: O: O Cl
Cl
25. A
Octanol and water are insoluble.
26. D
H
N (I)
'X' NO 2 CH3
N
(II)
First step is EAS and in 2 step N(I) is better nucleophile than other N(II) .
nd
27. ABCD
O O
N N diamagnetic because no unpaired electron
O O
N
paramagnetic due to presence of unpaired electron.
O O
O O
N N
O O O
HNO3, H2SO4 etc. are responsible for acid rain
28. ABD
E0Cr3+ /Cr2+ <E 0Fe3+ /Fe2+ <E Co
0
3+
/Co2+
29. AD
Hydrolysis requires a galactosidase, showing that galactose and mannose are linked by a
galactosidic linkage. For sugar to be reducing, one of the hexoses must have free
hemiacetal form.
The methylation /hydrolysis procedure shows the point of attachment of the glycosidic bond to
mannose. C1 is anomeric carbon on mannose ring and both forms satisfy the above
conditions.
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9 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
30. ABC
2+ 3.2×10-11
Step-I: Mg = 3 =2×10-4 M
4
2+ -4
Step-II: Mg =2×10 M
2+ -4 100
Step-III: Mg =2×10 × = 3.33 10-5 M
100+500
Step-IV:
Mg(OH) 2 (25ml of 2×10-4 M or 0.005 mmole) is mixed with MgCl2 (225ml of 0.06M or 13.5 mmole)
13.5
so Mg 2+ mainly from MgCl M
2 250
31. ABCD
Na/EtOH Li / NH3
N H3C N CH3 H3C N CH3
H H
P Q
H 2 O/H +
H3C N CH3
H
H 2O
OH
H3C O H3C N
NH2 CH3
H
Tautomerism
O
NH
H 3O +
O
O
R
OH
Aldol reaction
O
CH3
S
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 10
32. C
O O
A= B=
33. A
O
O O +
S
S H 5C 6
H5 C6 -
F= (E)= O
O or
H
CH=CH2
CH=CH2 CH=CH2
SECTION – C
34. 4
K a2 K a1
G RT ln K a
ΔG1° >ΔG °2 ,ΔG 1° and ΔG °2 are both +ve due to K a <1
ΔG10 ΔH10 TΔS10 and ΔG 2 0 ΔH 2 0 TΔS2 0
ΔH10 ΔH 2 0
ΔS10 is more negative than ΔS2 0 .
ΔS10 and ΔS2 0 both are negative because water is more organised due to hydration.
35. 2
N2 2 NH 3
3H 2
t 0 4 16
t teq. 4 a 16 3a 2a
P 1 20 R T
9
P 1 20 2a R T a 1
10
On adding 'x' moles of inert gas at constant volume, equilibrium composition does not change
9
P 1 18 R T
10
P 1 18 x RT
x2
36. 7
CFSE Eligand field Esymmetric field
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11 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
0.6 0
0.4 0
-2 3
= 5× Δ 0 + 2× Δ 0 +2P -2P
5 5
4
= 0
5
4
87.5 x 70
5
x
7
10
37. 9
Λ m =Λ m0 -A C
For KCl
120=150-A 0.0625
A 120
'A' will remains same for KCl and NaCl (1:1 electrolyte)
For NaCl
x
90=126-120
100
x9
38. 5
ClF3 , XeF2 , SF4 , SbF4 , XeOF2 are having lone pairs at equitorial position.
39. 4
degenerate states are
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 12
40. 2
CCl2
CHCl3 +OH -
H
CCl Cl
2
C OH
Cl
Cl
CCl
2
Cl
OH - C
Cl Cl Cl
Cl
It has two plane of symmetry
41. 3
LiCN,Na 2CO3 ,NaHCO3
42. 6
Chalcocite Cu2S, Argentite Ag2S, Horn silver AgCl, Siderite FeCO3,
Azurite 2CuCO3 .Cu OH 2 , Limestone CaCO3. MgCO3, Magnesite MgCO3, Kieserite
MgSO4.H2O
43. 9
A and B are same
α obs.
αsp.rot. =
c(g/ml)×l(dm)
α
60= obs.
1.5
×1
10
α obs. =90
SECTION – D
44. 02806.28
10CO2 g 4 H 2O
C10 H 8 s 12O2 g
14000×2
For 1 mole Napthalene, heat liberated = =28×105 J/mole
0.01
ΔU=-28×105 J/mol
U at 300 K 28 105 10 2 35 4 75 2
but here product and reactant both are at 300K
28 105 1300 J
2800 1.3 kJ 2801.3 kJ
H U n g RT
2801.3 2 8.3 300 103
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13 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
2801.3 4.98
2806.28 KJ/mol
45. 00001.02
The rate of change of pH with the volume of alkali added is maximum at equivalence point.
So volume required to neutralisation = 25.5ml
25.5×2×0.2=M×1×10
So, M=1.02
46. 00001.48
Z=4×0.999
4×0.999×40
d= 3
gm/cm3
1/3
6×1023 0.18 ×10-7
3
=1.48g/cm
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 14
SECTION – A
47. A
2 tan 1 sec 2 x & sin 1 x 3 x 2 x 2
2 2
3 2 2
Equality holds if x x x 2 1 & sec x 1
x 3 x 2 x 1 0, x n, n N but equation has no integral roots.
48. D
Sol. Factor of W 24.32.51 5 3 2 30
2 8 4 2
Factor of W 2 .3 .5 9 5 3 135
1 66 W 66 W2
Hence 66 28 38
49. A
Sol.
S1 : sphere
0, 0,0
O
M P
S 2 : circle
Plane:x y z 1
Let OM be distance from ‘O’ to plane
1 1
OM
12 12 12 3
OP 1 given
OMP is a right angled triangle
1 2
MP 1
3 3
The required curve is the cone with S2 as circular base and vertex at O 0,0,0
2
1 1 2 1
V r 2 h
3 3 3 3
2 2 3
9 3 27
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15 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
50. ABC
Sol.
0 x 1
1 1 x 1
0 1 x 2
2
x 1
1 2 x 3
2 3x2
3 x2
0 x 1
x 1 x 0
x 0 x 1
x x 2 1 0 1 x 2
x 2x 3
2 x 3 x2
3x x2
x x 1
x 1 1 x 0
x 1 0 x 1
x x 2 1 x 1 x 2
x 1 2x 3
x 2 3x2
x 3 x2
1/ 2 0 1/ 2
1
f x g x dx 2 x 1 dx 2 x 1 dx 2
1/ 2 1/ 2 0
51. BD
Sol. Divide S in 7 partition of form 7k r r 0,.....,6 we can choose a element from partition of
form 7k r . We cannot use 7 k 1 r.r 1,.....,6 and we can select 1 element from
partition of form 7 k .
52. ABC
2
Let Q x x 2 bx c, Q P x P x bP x c as P x | Q P x c 0 and
Q x P x b
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 16
53. ACD
c b
B a C
D A
D A case-I case-II
b a c
E B F C E B b F C
case-I
sin C c b
Let a b c , b2 ac
sin B b a
case-II
sin A b a
Let a b c , b 2 ac
sin B c b
2
Let a , b, c c , c , c as triangle is
2 2 1 5
formed b c a 1 0
1 5 2
54. ABCD
2
16 sin
4
x cos 2 x f x 4sin 2 x cos x dx
0
2
f x 4sin 2 x cos x
0
f x 4sin 2 x cos x
55. B
56. D
Sol. (55 – 56)
Y
B
C ,1
0,1 E
x y 1
P
x, y
O A X
D
, 0
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17 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
x y
1
1
AM GM
x y
1 xy
2 1
1
xy
4
1
xy
16
2
Region traced by point P is y x 1 4 x
1
1
Area x 1 2 x dx
0
6
SECTION – C
57. 8
1 2ei
Sol. f i tan i ei f i 2
f i sin 2 i
4 1
ei f i 8
i 1 f i
58. 9
Sol. 2 1, , is the ordered triplet which satisfy first two equations so it must satisfy third
2 2 2
equation & 2 1 must be minimum which happens
1 1 1 1
at so , , , , which satisfies third equation, i.e.
3 3 3 3
1 1 1
a a b 6 1
3 3 3
b 3& a R
59. 5
14
17 k
Sol. Coeff. of x14 in 1 x 1 2 x 3x 2 ....... 15 x14 ......... is 1 15 k 17
Ck .
k 0
15
Which is same as coeff. of x14 in 1 x 15 C14 15
60. 5
th th th
Sol. Let r , r 2 , r 6 terms be a, a 2d , a 6d respectively.
2
a 2 d a a 6d a 2 d .
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 18
1
Terms are 2d ,4d ,8d so common ratio of G.P is .
2
u u u
Let u , , 2 ,...... 2 p are 2 p 1 terms in p,2018 p
2 2 2
i.e.
u
u 2018 p & p
22 p
p.2 2 p u 2018 p
4 p 2018
p5
61. 2
Sol. f x x2 x R 1
f f x f 2 x x R 1,0
2
f f x f 2 x x2 x R 1, 0
f f f x f 2 f x f 4 x x8 x R 1
f f f x x 8
has solution only at x 1
62. 0
2 1
sin x 4 4 sin x 4
Sol. min f t
1
4 sin x
4
4 sin x
/2
/2
I1 4 sin x dx 4 x cos x
0
0
I1 2 1
/2 1
I 2 min t 2 sin x t sin x 4 dx
0 4
/2
1 2
min t cos x t cos x 4 x
4 0
1
min 2 t 2 t
4
1 2
min 2 t 2 1
4
I 2 2 1
I1 I 2 0
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19 AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18
63. 3
x 2 2 x 3 p n
Case 1: One of the factors is 1 which is possible only when x 2, 3
Case 2: Let x 2 p & 2x 3 ps
r
p s 2 p r s 1 7
p 7&x 5
64. 1
Sol. a2 bc b2 ca c2 ab ab bc ca
So given expression reduces to
2 2 2 2
ab bc ca
ab bc ca 2abc a b c
2 2
ab bc ca ab bc ca
1
65. 2
cos x 1 cos x 1 cos x
3
k k k
cos x cos
2 3 0
k k
k 6
k 6
cos 4 8
3
66. 5
1
Let chosen points be 1 , 1 & 2 , 2 . The area of the triangle 1 2 2 1 must be
2
integer.
2 64 16 .16 5
1 2 2 1 is even integer. Total probability 1
64 64 8
SECTION – D
67. 00102.01
dv Adh
A A
dt dt
0 t
dh dt
15.7 0
15.7 t
dv 2 dh
10.1
dt dt
0 t
2
10.1
15.7
dh dt
0
2
t 10.1 15.7
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AITS-FT-VIII (Paper-2)-PCM (Sol.)-JEE(Advanced)/18 20
2
10.1 15.7 15.7 10.1
2
As t is same in both case
68. 03600.00
As z1 z2 z3 0 z1 , z2 , z3 are vertices of an equilateral triangle and z4 , z5 are end points of
2
diameter. So zi z j 3r 2 if
2 2
i, j 1, 2,3 ; zi z j 4r 2 if i 1, 2, 3 & j 4, 5 & z4 z5 4r 2
2
z z i j 25r 2 3600
1 i j 5
69. 00007.75
Let A denotes the probability that every box have three balls each. B is the probability that each
box has balls of the colour as that of the box.
Required probability =P B/A =1 P B/A
Cases: R B, B G, G R or R G, B R, G B
1 1 1 1 1 1
P A . . . .
2 2 2 2 2 2
1 1 1 1 1
P A B . . . .
2 2 4 2 4
1 1
.
1
So P B / A 8 16
1 1 32
8 8
31
P B / A
32
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