STD-ASTM DLL4YL-ENGL 1998 MM 0759520 Ob35702 517 mi qq] Designation: D 1141 - 98" uae sooreyton ese wa ures Meboriecrdy tora es arta ae aaa oa aor Standard Practice for the Preparation of Substitute Ocean Water’ ‘This sand i sued under he fed designation D 1241; the nur namely following the designation ince the yea of ‘ign adoption in the case of revision the yer of ast eision. A mambo in paenteve indicates the year st eaova A supenerpt pitn indices an ei change since the at evnon ot teapprova ‘This standard nas been approve for ase by agencies of he Deparment of Deen ff Nowe—The ie of ik standard was edtrally comestd in February 1999, 1, Seope 1.1 This practice covers the preparation of solutions con- taining inorganic salts in proportions and concentrations rep- resentative of ocean water [Note 1—Since the concentrations of ocean water varies with sampling location, the gross concentration employed herein isan average of many reliable individual analyses. Trace elements, occurring naturally in con: cenations below 0.005 mg/ are not inched. 1.2 This practice provides three stock solutions, each rela- tively concentrated but stable in storage. For preparation of substitute ocean water, aliquots of the first two stock solutions with added salt are combined in larger volume, An added refinement in adjustment of heavy metal concentration is provided by the addition of a small aliquot of the third stock solution to the previous solution, 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsiblity of the user of this standard to establish appro- priate safety and health practices and determine the applica bility of regulatory limitations prior to use. 2. Referenced Documents 241 ASTM Standards: D 1129 Terminology Relating to Water’ 1D 1193 Specification for Reagent Water? E200 Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis* "This pati suerte jrston of ASTM Comite B19 on Water ans ‘se esonsbliy of Subcommiee D10.02 on Gener! Specifications, Teal Resources sn Saisie Methods. Current eon approve Sep 10,1958, Pbished November 1998, Originally published es D 1181 50". Las previous eon D I1s1-90 (1996), Ts practice is based wpm the flling sts May and Black, “Synthetic Osean Wate” Naw Reseurch Lathoniory Report 1.2002, Ragas 1946, May, Pad Alexandes A. Li "Spray Testing with Natal and Syntee Sea Winter, Pat I-Comosion Characteristics inthe Testing of Metal” Proceeding ASTM, Vol 50 1950. ‘Aleve, A Land May. TP. “Spay Teng with Natl and Syatc Sea Wats, Pat I-A Study of Onc Cotings,” Preceding, ASTM, Vl 30,1950, " Anual Bonk of ASTM Standards, No 11.01 Anal Bok of ASTM Stands N15.05, 3. Terminology 3.1. Definitions —For definitions of terms used in this prac: tice, refer to Terminology D 1129. 43.2 Definition Of Term Specific to This Standard: 3.2.1 chlorinity, .n—the weight of silver ion (g) required to completely precipitate the halides in 0.3285 kg of water (gikg). 4. Significance and Use 4.1 This substitute ocean water may be used for laboratory testing where a reproducible solution simulating sea water is required. Examples are for tests on oil contamination, deter- gency evaluation, and corrosion testing. Nore 2—The lack of organic matter, suspended matter and marin life i this solution does not permit unqualified acceptance of test results 4 representing perlormance in actual ocean water. Where corrosion i involved, the resus obtained from Iuboratory Tess may not approximate those secured under natural testing conditions that differ greatly from those of the laboratory, and especially where effects of veleeity salt stmoyphees, or organic constituents are involved. Iso the rapid depletion ‘of reacting elements present in lowe concentrations suggests caution in direct application of results 5. Reagents and Materials 5.1 Purity of Reagents—Reagent grade chemicals shall be used in all tests. Unless otherwise indicated, it is intended that all reagents shall conform to the specifications of the Commit. tee on Analytical Reagents of the American Chemical Society,® Other grades may be used, provided itis first ascertained that the reagent is of sulficiently high purity to permit its use without lessening the accuracy of the determination, 5.2 Purity of Water—Unless otherwise indicated, references {to water shall be understood to mean reagent water conforming. to Specification D 1193, Type I. 5.3 Sodium Hydroxide, Solution, Standard (0.10 N)— Pre- pare and standardize as directed in Practice E 200. 54 Stock Solution No. J—Dissolve the indicated amounts of the following salts in water and dilute to a total volume of * Reagent Chemicals, American Chemical Society Soecifcations. American CChemicl Soci, Washington, DC. Fr sussetion on the tein eens a lged by the American Chemical Sciey, se Anolur Sten fr Leretrs CChemicls, BDH Lid. Pole, Dove, U.K, a the Unie State Pharma pei and Narional Formulary. US. Pharscopial Convention i, (USPC), Rockeile MD,STD-ASTM DLB4L-ENGL 2598 MH O759510 0635703 453 mm qh D141 7.0 L. Store in well stoppered glass containers. Mao 64,0 3889.09 ( ach larryeroue) 20589( SeysHo saag(=21 gt) 5.5 Stock Solution No. 2—Dissolve the indicated amounts of the following salts in water and dilute to a total volume of 7.0 Lor a convenient volume. Store in well stoppered amber alass containers. Ke 4282 9(+ 09501) NaHoo, 4407 9(= 201 gt) RB 7049 (= 10091) Hye, 1909(-27 a1) Nar Biat 03 ah) 5.6 Stock Solution No, 3—Dissolve the indicated amounts, of the following salts in water and dilute to a total volume of 10.0 Lor a convenient volume. Store in well stoppered amber glass containers BatNOs)e ase4g MeN), 88,0 oseg cumoslectjo 03969 riNo)e6H0 181g POINOsIe 00669 AgNos 004099 Nore 3—To make the addition of AgNO, in the above solution, dissolve 0049 g of AgNO, in water and dite to 1L. Add! 100 mL of this solution 10 Stock Solution No.3 before diluting to 10.0 L, 6. Preparation of Substitute Ocean Water 6.1 To prepare 10.0 L of substitute ocean water, dissolve 245.34 g of sodium chloride and 40.94 g of anhydrous sodium sulfate in 8 to 9 L of water. Add 200 mL. of Stock Solution No. I slowly with vigorous stirring and then 100 mL of Stock Solution No. 2, Dilute to 10.0 L. Adjust the pH to 8.2 with 0.1 NV sodium hydroxide solution. Only a few millilitres of NaOH. solution should be required. [Note 4—Prepare the solution and adjust the pH immediately prior to 7. Preparation of Substitute Ocean Water with Heavy Metals 7.1 Add 10 mL of Stock Solution No. 3 slowly and with, vigorous stirring to 10.0 L of the substitute ocean water prepared as described in Section 6. 8. Keywords 8.1 substitute brine; substitute ocean water; substitute salt water; substitute seawater APPENDIX (Nonmandatory Information) XI. COMPOSITION OF SUBSTITUTE OCEAN WATER X1.1 The substitute ocean water prepared in accordance 2 6 will have the composition shown above the line in Table X1.1 (upper half of the table). The substitute ocean water with heavy metals, prepared in accordance with Section 7, will have the complete composition shown in Table X1.1 TABLE X1.1_ Chemical Composition of Substitute Ocean Water * Compound ‘Concantaion, rr] — Base MgCl, 520 Nass, 408 cat, 16 Ke 095 NaH©0, o20t ker 0301 1605 oer SC 0.005, NaF 0.008 Ban, ‘o.oo00888 MiNOite ‘.0000540 cans 0000808, ZnO). ‘0000086, DINOS), 0000086 AgNO, ‘100000048 Achlriny of ie eubaut oosan waters 7038. The pH afer asustest wth 01 N NGOH salute) is 82STD-ASTM DLLYL-ENGL 1998 MM 0759510 Ob35704 397 me jy D 1141 ‘The macan Soke for Testing and Mattias takes ro poston respecting he vay of ay ten! gh asserted n connection wih ary tem mentioned in Wis standard. User ofthe standard are express advced that determination of he vahy of any such Patent rights, and tbe risk of nengoment of such ngs, re ently Me own responsby, ‘This stand is sujet revision a anytime by he response tect commitoe and must be reviewed every fv years and ‘trot revised eter reapproved or win Your comments are tied ether reson Ps standart adfera aaa {and shouts be adored to ASTM Heacauaters. Your conents wil acive cael consideration ata moot othe responsi ‘eohnialcommitee, whic you may attend you fee! hat your comments have nol eceved a fa earn you shou make fut views known othe ASTM Commitee on Standars, 100 Bar arbor Div, West Conshohocson, PA T6428