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HINTS & SOLUTIONS (PRACTICE PAPER-2)

ANSWER KEY
Que s. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. A D A D C C B C C B B C A D B
Que s. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. C A A D A D C B D C D A C B B
Que s. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. C A B D B D C D A D D B B B A
Que s. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B A A C A D C B D A B A D B B
Que s. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. A C A A D B C B C B A C B B C
Que s. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. B A B C B B A A D D D C C C A
Que s. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. B A C B A C D B D D D C B A A
Que s. 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. B A A D A D D B A C A B D A C

PART-I (1 Mark)
MATHEMATICS

1. The equation z2 = z , where z is a complex number, has


(A*) 4 solution (B) 2 solution
(C) no solution (D) infinitely many solutions
Sol. z = a + ib

z = a – ib
It is given : z2 = z
(a + ib)2 = a – ib
a2 – b2 + i 2ab = a – ib
 a2 – b2 = a and 2ab = – b
2ab + b = 0
b(2a + 1) = 0

1
b = 0 or a =
2
When b = 0, a2 – b2 = a
a2 – 0 = a
a (a – 1) = 0
So, a = 0, or a = 1
2
1   1  1
When a = ,   – b2 =
2  2  2

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1 1
– b2 =
4 2

1 1 3
b2 = + =
4 2 4

3
b=±
2
 z = 0 + 0i or 1 + 0i
1 3 1 3
 z= +i. or –i
2 2 2 2
 There will be four solutions possible.

10
 x 1 x 1 
2.  2/3  
x  x  1 x  x 1/ 2 
1/ 3

10
 ( x1/ 3  1)( x 2 / 3  x1 / 3  1) ( x1/ 2  1)( x1/ 2  1) 
  
 ( x 2 / 3  x1/ 3  1) x1/ 2 ( x1/ 2  1) 

1/ 3 10
(x  1)  (1  x 1 / 2 ) 
1/ 3 10
x  x 1 / 2 
General Term Tr + 1 = (– 1)r 10 Cr (x1/3)10 – r (x-1/2)r
10 r r

= (– 1)r 10 Cr x 3 2

10  r r
For the independent term  =0
3 2
10  r r

3 2
20 – 2r = 3r
5r = 20
r = 4.
10!
So, independent term = (– 1)4 10 C4 = 4!6! = 210.

a a2 a3  1
b b2 b3  1
3. =0
c c2 c3 1

a a2 a3 a a2 1
2 3 2
b b b b b 1
2 3
+ 2
=0
c c c c c 1

1 a a2 a a2 1
1 b b2 b b2 1
abc –1 =0
1 c c2 c c2 1

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1 a a2 a 1 a2
2
1 b b b 1 b2
abc +1 =0
1 c c2 c 1 c2

1 a a2 1 a a2
2
1 b b 1 b b2
abc –1 =0
1 c c2 1 c c2

1 a a2
1 b b2
(abc – 1) = 0
1 c c2

 abc = 1.

4. ax2 – 6xy + y2 = 0
2h
m1 + m2 =
b
6
m1 + m2 =
1
a
m 1m 2 =
b
a
m 1m 2 = =a
1
Given : m2 = m12
m 12 + m 1 – 6 = 0
(m1 + 3) (m1 – 2) = 0
m1 = – 3 and m1 = 2
and m 1m 2 = a
m1 × m12 = a
m 13 = a
a is positive, so a = (2)3 = 8.
5. x2 + 4y2 =1 ....(i)
2 2
4x + y = 4
y2 = 4 – 4x2
put in (i)
x2 + 4(4 – 4x2) = 1
x2 + 16 – 16x2 = 1
16 – 1 = 15x2
15 = 15x2
x2 = 1
x=±1
y2 = 4 – 4x2
= 4 – 4(1)
y2 = 0
y=0
 (1, 0) and (– 1, 0) are two common point.

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6. Diameter = major axis = 2a
radius = a b 2 2
(0, b) y= a a –x
Area of circle = a2
x2 y2 (– a, 0) (0, 0) (a, 0)
Let the equation of the ellipse be   1.
a2 b2
b
y= a2  x 2
a (0, – b)

1 2 a b
Area of ellipse = a = 4 ×  a 2  x 2 dx
3 0 a
a
b x 1 x
=4×  a 2  x 2  a 2 sin 1 
a 2 2 a 0

2
1 2 b  a 
a = 4 ×  
3 a  4 

b 1

a 3

2 2
b  1 8 2 2
e= 1   = 1   = = .
a 3 9 3

PA  PB 18  2 B
7. PD = = =9
PC 4
N
1 18 O
BN = AB = 10 4 P 9
2 C 2 D
M
1 13 A
MC = CD =
2 2
PM = MC – PC
13 5
= –4=
2 2
5
ON = PM =
2
In ONB
2
5 25 425 5 17
OB = 10 2    = 100  = =
2 4 4 2

5 17
Diameter = 2 × OB = × 2 = 5 17 cm.
2
8. cos 175 = cos (180 – 5) = – cos 5
cos 185 = cos (180 + 5) = – cos 5
cos 355 = cos(360 – 5) = cos 5
 cos 5 + cos 10 + cos 15 + ......+ cos 355
= cos5 + cos 10 + .....+ cos 85 + cos 90º + cos(180º – 85) + cos (180º – 80º)
+ .......+ cos (180º – 5) + cos 180º + cos (180º + 5) + cos(180º+ 10)
+ .......+ cos (180º + 85) + cos 270 + cos(360 – 85) + ......+ cos(360 – 5)
= cos 5 + cos 10 + .......+ cos 85 + 0 – cos 85 – cos 80 – ..........– cos 5 – 1
– cos 5 – cos 10 – cos 85 + 0 + cos 85 + cos 80 + ...........+ cos 5
=–1

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9. By AA similarity
y Q a– y
QCP ~ PBA D C
3 a–x
ay ax 3
= = 5 P
x a 4
4 x
ax 3
= A a B
a 4

a
x=
4

ay 3
=
x 4

ay 3
=
a/4 4

13a
y=
16
In PAB
42 = x2 + a2
2
a
16 =   + a2
4

17a 2
16 =
16

16  16 256
a2 = =
17 17

256
Area of square ABCD = a2 = .
17

10. By Angle bisector theorem A

x 2
4

2
x=

= x=4
2 1
B C
3 2  4 2  22 9  16  4 21 7 2 D 1
cos B = = = = .
23 4 24 24 8

18 x  6
11. s= = 9x + 3
2

s= (9 x  3)( 2)(3 x  1)( 6 x )

= 6 (3 x  1)( 3 x  1)( x )

= 6(3x + 1) x
x is a perfect square, so in 1 to 20, 4 perfect square i.e. possible values are {1, 4, 9, 16}.

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f (1  h)
12. f(1) = 0 as lim exists.
h0 h
f (1  h)  f (1)
 lim f ‘(1) exists.
h 0 h
So, f is differentiable at 1.

13. Statement I is true that the derivative of an odd differentiable function is always even and statement II is
also true that If f(x) is differentiable at a point x0 and g(x) is not differentiable at x0, then f(x) g(x) is not
differentiable at x0.
0, 0  x 1
14. x   
 1,  1  x  0

 sin( 1)
  sin1,  1  x  0
f(x) =   1
 0, 0  x 1

lim f ( x )  sin1
x 0 

and xlim
0 
f (x)  0

 lim f ( x ) does not exists.


x 0

15. x– x > 0 for all x > 1.


and – x + 4 x > 0 for all x < 0
So, range of f is [0, ).
x
t
16. f(x) =  e (t  1)(t  2) dt
0

f’(x) = ex(x – 1)(x – 2)


For decreasing
f’(x) < 0
ex(x – 1)(x – 2) < 0
(x – 1)(x – 2) < 0 [ ex > 0]
x  (1, 2).

1
17.  x | x |3 / 2 dx
1

0 1
=  x(  x )3 / 2 dx +  x( x )3 / 2 dx
1 0

0 1
=  x 5 / 2 ( 1)3 / 2 dx +  x 5 / 2 dx
1 0

0 1
 x7 / 2   x7 / 2 
3/2
= (– 1)   +  
 7 / 2  –1  7 / 2  0

2 2
= (– 1)3/2 [0 – (– 1)7/2] + [1 – 0]
7 7

2 2 2 2 4
= – (– 1)5 + = + = .
7 7 7 7 7

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18.  x f ( x)f (x)......f
1 2 10 ( x ) 1 dx
Let f11(x) = t
dx
x f1( x )f2 ( x )......f10 ( x ) = dt

 1.dt =t+C
= f11(x) + C.
19. Applying AM and GM condition :
x1  2x 2  3 x 3
 6 x1x 2 x 3 1 / 3
3

4
 6 x1x 2 x 3 1/ 3
3
Cubing both sides
64
 6 x1x 2 x 3
27

32
x1x 2 x 3 
81

2 2 2
x1  x 2  x 3 2 2 2 1/ 3
Now also
3
 x1 x 2 x 3  
2 2 2 2/3
x1  x 2  x 3  32 
 
3  81 

1/ 3
2 2
 210 2

x1 + x2 + x3  3 
 38 
 

1/ 3
2 2 2
38  2
x1 + x2 + x3   
9 9

24
x 12 + x 22 + x 32   0 .6
9
x 12 + x 22 + x 32  1 . 6
So, according options least value is 2.

20. 12 3 4 5 6 7
at each position two posibility i.e. either H or T
So total posible outcomes = 27
As we want three tails is sequence and it happened at 7th turn. So at position 5, 6, 7 we have tails and
position 4 must have head otherwise our requirement is fullfilled at position 6.
So, the position 1, 2, 3 can have anything i.e. H/T = 23
To get tail at 1, 2,3 position we have only one probability.
So, total favourable cases = 23 – 1 = 7
7 7
required probability = = .
27 128

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PHYSICS
22. PV = nRT
PdV + VdP = 0
1 dv 1
–  
V dP P
 = P–1 (Answer is C)

1
23. E for point charge
r2
Force solid sphere
1
Inside the sphere E  r and out side the sphere E 
r2

L
24. =
r 4
L
So,  =
r 4

25. Angular momentum,  = mvr



Magnetic moment,  = IA = nqr2 = qr 2
2
v 2 vqr
 = 2r qr  2

 vqr q
or   (Answer is C)
 2mvr 2m

2  2 1/ 2
26.
kT
=
ML T  = [M0L0T0]
1 1/ 2
c m 2T M
Which dimensionally ratisfies
f 1 kT
= (Answer is D)
f c m
1
27. Average power, <P> = vA2w2
2
 Av2 (Answer is A)

d 0.2  6  103
28. Wave length,  =  = 0.5 × 10–4 m
D 24
 = 5 × 10–5 cm
 = 500 nm (Answer is B)
29. (B)

30. By angular momentum conservation


m1v1r1 = m2v2r2 ( m1 = m2 )

5.6  10 4  9  1010
So, v2 = = 900 m/s (Answer is B)
5.6  1012

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31. y = y1 + y2
= 2A cos (2Kx) cos(2cost)
x = 0, y = 0
  20m (Ans. C)
32. A  m (some as x)

1
  sec–1
t

1
  sec–1
t
 = angle(dimensionless) (Answer is A)

33. KE = 0.01864 × 931 = 17.4 Mev


KEf – KEi = 17.4 Mev
As proton is at rest (B) option is correct

mv 2 kq1q2
34.  2
r r

kq1q2
v=
mr

9  10 9
v = 1.6 × 10–19
9.11 10 31  0.53  10 10
v = 2.24 × 106 m/s (Answer is D)

I
35. F
F

0 1 2
F= 
2d

4  10 7  4000  4000  60  10 2
F=
2  1.5  10 2
F = 128N repulsion (Answer is B)

37. (C)

38. Phase different between VR and VC is 90º

so, VR2  VC2 = 220 (Answer is D)

39. Distance between to consecutive destructive interference is 1.7cm, so total number of points of
destructive interference on the line PQ is 4. (Answer is A)

40. (D)

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CHEMISTRY

41. The ionization energy or enthalpy of Na is greater than that of Li but the hydration enthalpy of Li is higher
than that of Na. Difference between ionization enthalpy of both is less than difference between their
hydration enthalpy so overall oxidation potential of Li is greater than Na. Therefore Li metal is a better
reducing agent than Na metal.

1
42. Compressibility K =
P
1 1
 Kx – Ky = –
1 2
= 0.5 atm–1

OH

43.
CO2H

44.

conc. NaOH
2CH3 CHO CH3 CH2OH + CH3 COOH

Cannizzarro reaction

45. On heating solution becomes unsaturated


 solubility and conductance both are increase.

46. According to graph, segment BC represents isobaric process. It means pressure is constant so accord-
ing to Charle’s law V  T [on constant pressure]
From B to C volume decreases so temperature will also decreases.

H H
6 4 3 1

47.
7 5
2 OH

when same groups present in same side of the double bond then geometrical isomer is known as
Z – isomer.

48. Due to back donation electron defficiency of [B] almost neutral.

+ +
/////////////////////////

+
Cl Cl Cl
Cl Cl
49. en Co en en Co Co en

Cl
en en
cis/d
trans

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10
50. xH2S + 2NaNO3 +2HCl  yS + zNO + k NaCl + 4H2O
Put the following value of variables in above equation
x = 3, y = 3, z = 2, k = 2
3H2S + 2NaNO3 + 2HCl  3S + 2NO + 2NaCl + 4H2O

51.  R = k [X]1/3 [Y]2/3


1 2
order of reaction = + =1
3 3
52. Because Zn has higher oxidation potential than Cu. so Zn loses its electrons at an anode and convert in
Zn2+ ions and come into the solution. These electrons flow externally from zinc to Cu by wire.

53. Because ideal mixture of benzene and toluene follows Raoult’s law
according to Raoult’s law
Pmix = PA + PB

Pmix = XAPAº + XBPBº

Pmix = XAPAº + (1 – XA) PBº

Pmix = XA(PAº – PBº) + PBº

This is a linear equation, by comparing with y = mx + c


y = Pmix
x = XA
m = PAº – PBº
c = PBº
according to above data graph will be like following -

PBº
Pmix

PAº

XA = 0 XA XA = 1
molefraction (benzene )

54. sp3d2 hybridization explains the bonding of complex which has C.N. (co-ordination number) 6 so answer
may be either [Fe(CN)6]3– or [Fe(H2O)6]2+. But H2O is a weak ligand and CN– is a strong ligand.
Because weak ligand form an outer orbital complex with metal ion and this is possible when sp3d2
hybridization takes place.

55. 2NaCl + H2SO4  Na2SO4 + 2HCl

MnO2 + 4HCl  MnCl2 + 2H2O + Cl2

1
56. Bond order = [N – Na]
2 b

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11
1
 B.O. of O2+ = [10 – 5] = 2.5 Nb = no. of electron present in BMO
2
1
B.O. of O2– = [10 – 7] = 1.5 Na = no. of electron present in ABMO
2
1
B.O. of O22– = [10 – 8] = 1
2
1
 Inter atomic distance 
B.O
 order of inter atomic distance ; O22– > O2– > O2+

57. amylose [it is a part of starch]

0.693
58 t1/ 2 =
K
0.693
t/12 =
6.93  10 – 3
t1/2 = 100 s
59. Because unit cell has six faces and every facial atom is a part of two unit cell. It means only half part of
one facial atom belongs to one unit cell.
1
so, total no. of facial atoms in fcc unit cell = 6 × =3
2

T1 – T2 W
60. = =
T1 Q1

800 – 200 W
 
800 100
W = 75 J
PART-II (2 Mark)
MATHEMATICS
81. a=A– d
b=A
c=A+d
3
a + b + c = 3A =
2
1
A= =b
2
3
 a+b+c=
2
3 3 1
a+c= –b= – =1 ....(i)
2 2 2
b2 = a 2c 2
2
 1
  = ± ac
2

1
When ac =
4
1
c= ...(ii)
4a

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12
From (i) & (ii)
1
a+ =1
4a
4a2 – 4a + 1 = 0
(2a – 1)2 = 0
2a – 1 = 0
1
a=
2
By this we get
a=b=c
But a < b < c, so we take
1
When – ac =
4
1
c= ....(iii)
4a
from (i) & (iii)

1
a– =1
4a
4a2 – 4a – 1 = 0

4  16  16
a=
8

44 2 1 2
= =
8 2
as b > a

1 2
 a=
2

82. g’(x) is changing its slope from positive to negative as it passes through g(2). So, g(2) is largest.

92
83. B =   × 180º = 140º D
 9 

180 º 140 º x
1 = 2 = = 20º z
2
3
3 = 140 – 2 = 120º C
2
y
In ACD x
1
A
x B
y 2  x 2  z2
cos 120º =
2xy

1 y 2  x 2  z2
=
2 2xy

– xy = y2 + x2 – z2
z2 = x 2 + y2 + xy

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13
0 * *  * 
 
* 0 *  *
* * 0  *
84. AA =       
T

 
 * * *  0
As the diagonal element of resulting matrix are zero.
 multiplication R1 of A and C1 of AT (i.e. = R1 of A) = 0
It is possible only when all element in R1 of A is zero
In the same way we can say that element of all 10 rown of A is zero so for the above condition we can
formm only 1 matrix i.e. A = null matrix.

(0, b) C

E
(0, 0)
(– a, 0) A (–ae, 0) O B
85. F
D (0, – b)

(i) As line DE and AC are  so product of there slope = – 1.


b  0 b
× =–1
0  ae a
b b
× =–1
ae a
2
b
e=  
a
(ii) and line CF and AD are also 
b0 b  0
 × =–1
0  ae 0a
b b
× =–1
ae a
2
b
e=  
a
(iii) and line AO is  to CD
00 2b
 × –1
0a 0
2
b
From (i) & (ii) case e =  
a
But in (iii) case ‘e’ cannot be determined. So, we can not determined uniquely.

 1 2 3
86.  [ x ]e  x dx =  0e
x
dx +  (1) e  x dx +  2e
x
dx + ......
0 0 1 2

2 x 3
= 0 +  e x   +  2e  + .........
1 2
= – (e–2 – e–1) – 2(e–3 – e–2) – 3(e–4 – e–3) .........
= e–1 + e– 2 + e–3 ............
1
1 1 1 e 1
= + + + ..........  S = = .
e1 e2 e3 1 e 1
1
e

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 /2   /2 
87.   cos1003 xdx    cos1004 xdx 
 0   0 

 (1002  1000  998 .....2) (1003  1001  .....1)


= × 
2 1003  1001  ....... 1 1004  1002  ....... 2

=
2  1004

=
2008

x
88. lim g( x )  e f ( t ) f ( x ) dt
x 0

x
g( x )  e f ( t ) dt
= 0
lim f(x)
x e
x
g' ( x )  e f ( t )  g( x )e f ( x )
= 0
lim
x f ' ( x )e f ( x )

g( x )
= lim 0 
x  f ' (x)

3 x 3  .....
= lim 0 
x 16 x 3  ....
3
= .
16
dy
89. = sin(x + y) + cos(x + y)
dx
let x + y = u
Differentiating wrt x
dy du
1+ =
dx dx
dy du
= –1
dx dx
dy
 = sin(x + y) + cos(x + y)
dx
du
– 1 = sinu + cosu
dx
du
= sinu + cosu + 1
dx
du
 dx
sin u  cos u  1
Integrating both sides
du
 sin u  cos u  1   dx

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du
  dx

2 tan u / 2 1  tan 2 u / 2
2
 2
1
1  tan u / 2 1  tan u / 2

sec 2 (u / 2)du
 2 tan u / 2  1  tan 2
 dx

u / 2  1  tan 2 u / 2

sec 2 (u / 2)du
  dx 
2 tan u / 2  2

sec 2 (u / 2)du
  dx 
2(tan u / 2  1)

Put 1+ tanu/2 = t
(1/2)sec2u/2du = dt

dt
  dx 
t

log |t| = x + c
log |1+ tanu/2| = x + c

(x  y)
log 1  tan =x+c
2

It passes through origin.


 log1 = 0 + c
c = 0.

(x  y)
So, log 1  tan = x.
2

90. Total mappings of bijection is 6 !.


for self inverse

6! 4! 6 C 4 6
2! 2! 2! 3! + C2  1
 2! 2! 2! +   = 76
  4 going to their own value
2 pairing 2 going to their own value

76 19
P= = .
720 180

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PHYSICS

d
91. M1 M2
r1 r2

M1r1 = M2r2 and r1 + r2 = d

M2 d
so r1 = M  M ........(i)
1 2

2r1
T = v ........(ii)
1

Here

GM1M2 M1v12
=
d2 r1

GM2r1
or v1 =
d

From (ii)
2r1d
T= GM2r1

2d r1
T=
GM2

2d M2d
T= M1  M2
GM2

2d3 / 2
T= (Answer is B)
G(M1  M2 )

92. a = r = 20 × 0.5 = 10 m/s2

93. For min


hc
 min = K.E.

hc
min =
K.E.

6.6  10 34  3  10 8
min = 30  10 3  1.6  10 19 = 4.14 × 10–111 m

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 V  V0   340  9 
94. App. frequency, N =  V  V  N   340  9   90
 S   
N = 94.9 kHz

  18  (3.96 )2  0.92
95. Mass of water, m = kg
10 3
m =  × 18×10–2 × (3.96)2 × 10–4 × 0.92 ×103
KA (1  2 ) t mL f 
mLf = t = KA (   )
 1 2

  18(3.96)2  0.92  333  103  10 3


t = t = 9.2 s (Answer is A)
103  400    (3.96)2  15

96. Range, R = 2 (H  h) h
(i) h = H/4

 HH 3
X1 = 2  H   3H/4
 44
H/2 2
3
X1 = H
2
(ii) h = H/2 H/4
X2 = H 1
(iii) h = 3H/4
3 X2
X3 = H
2
X1= x3
X2 > X1 = X3 (Answer is C)

CHEMISTRY

101. Xe contains 8 electrons in its outermost shell or valence shell. In XeF2, Xe uses 2 electrons for  bonds so
it contains 3 lp. In XeF4., Xe uses 4 electrons for  bonds, so it contains 2 lp.

102. N2 + 3H2 2NH3


initial moles 4 16 0
at equilibrium

[according to question ammonia gas is produced = 4 mol]


 2 = 4
put the value of  = 2
4–2 16 – 3 × 2 2×2
moles at 2 10 4
equilibrium
concentration 2 10 4
at equilibrium V V V

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[NH3 ]2
KC =
[N2 ][H2 ]3

2
4
 
V
=  2  10 3
  
 V  V 

42
= × V2
2  10 3
8
= × (10)2 (V = 10L]
10 3
= 0.8 mol–2 lit2

Kw 0
103.  Depression in freezing point TF = m W
0
In given two cases m0, W and K are constants
so TF  w0
( TF )1 ( w 0 )1
( TF )2 = ( w 0 )2

5.5 – 4 2.9
=
5.5 – 2.5 2.9  x
1.5 2.9
=
3 2.9  x
x = 2.9 g

I OH
II ' III '
2 5
2R and 5R
105. III II
OH
I '

106. Zn + 2Ag+ (0.0001M)  Zn2+ (0.1M) + 2Ag


by nernst equation

0.059 [ Zn2  ][ Ag]2


Ecell = Eº – log10
n [ Ag ]2 [ Zn]
 [Ag] = [Zn] = 1

0.059 [ Zn2  ]
 Ecell = Eº – log10
2 [ Ag ]2

0.059 (0.1)
 Ecell = 1.56 – log10
2 ( 0 .0001)2
 Ecell = 1.56 – 0.2065

 Ecell  1.35 V

Cu(Y)
107. 2CH3Cl + Si 
(CH3)2SiCl2
(X)
SiCl4 + 2CH3MgBr  (CH3)2SiCl2 + 2Mg(Br)Cl
(Z)

Pre-foundation Career Care Programmes (PCCP) Division


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108. according to Arrhenius theory
E

K = Ae RT

according to question K is same in both cases, so

E1 E2
RT1 = RT2

E1 and T1 are activation energy and temp. in absence of catalyst


500 400
= E2 and T2 are activation energy and temp. in presence of catalyst
625 T2

T2 = 600K

109. 28
Ni  [Ar]3d84s24p0

Ni2+  [Ar]3d8 4s0 4p0


[Ar]
because CN– is a strong ligand w.r.t. Ni2+ ion, so pairing of electrons takes place.

[Ar]
dsp2 hybridization

[Ar]
2
dsp hybridized Unhybridized
orbitals orbitals

In dsp2 hybridization geometry of complex is square planar.

238 206
110. 92 U  82 Pb  x 24He  y –01e
by balancing of mass no.
238 = 206 + 4x + 0y
x=8
by balancing of nuclear charge
92 = 82 + 2x – 1y
92 = 82 + 2 × 8 – y
y=6

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