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ANSWER KEY
Que s. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. A D A D C C B C C B B C A D B
Que s. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. C A A D A D C B D C D A C B B
Que s. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. C A B D B D C D A D D B B B A
Que s. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B A A C A D C B D A B A D B B
Que s. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. A C A A D B C B C B A C B B C
Que s. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. B A B C B B A A D D D C C C A
Que s. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. B A C B A C D B D D D C B A A
Que s. 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. B A A D A D D B A C A B D A C
PART-I (1 Mark)
MATHEMATICS
z = a – ib
It is given : z2 = z
(a + ib)2 = a – ib
a2 – b2 + i 2ab = a – ib
a2 – b2 = a and 2ab = – b
2ab + b = 0
b(2a + 1) = 0
1
b = 0 or a =
2
When b = 0, a2 – b2 = a
a2 – 0 = a
a (a – 1) = 0
So, a = 0, or a = 1
2
1 1 1
When a = , – b2 =
2 2 2
1 1 3
b2 = + =
4 2 4
3
b=±
2
z = 0 + 0i or 1 + 0i
1 3 1 3
z= +i. or –i
2 2 2 2
There will be four solutions possible.
10
x 1 x 1
2. 2/3
x x 1 x x 1/ 2
1/ 3
10
( x1/ 3 1)( x 2 / 3 x1 / 3 1) ( x1/ 2 1)( x1/ 2 1)
( x 2 / 3 x1/ 3 1) x1/ 2 ( x1/ 2 1)
1/ 3 10
(x 1) (1 x 1 / 2 )
1/ 3 10
x x 1 / 2
General Term Tr + 1 = (– 1)r 10 Cr (x1/3)10 – r (x-1/2)r
10 r r
= (– 1)r 10 Cr x 3 2
10 r r
For the independent term =0
3 2
10 r r
3 2
20 – 2r = 3r
5r = 20
r = 4.
10!
So, independent term = (– 1)4 10 C4 = 4!6! = 210.
a a2 a3 1
b b2 b3 1
3. =0
c c2 c3 1
a a2 a3 a a2 1
2 3 2
b b b b b 1
2 3
+ 2
=0
c c c c c 1
1 a a2 a a2 1
1 b b2 b b2 1
abc –1 =0
1 c c2 c c2 1
1 a a2 1 a a2
2
1 b b 1 b b2
abc –1 =0
1 c c2 1 c c2
1 a a2
1 b b2
(abc – 1) = 0
1 c c2
abc = 1.
4. ax2 – 6xy + y2 = 0
2h
m1 + m2 =
b
6
m1 + m2 =
1
a
m 1m 2 =
b
a
m 1m 2 = =a
1
Given : m2 = m12
m 12 + m 1 – 6 = 0
(m1 + 3) (m1 – 2) = 0
m1 = – 3 and m1 = 2
and m 1m 2 = a
m1 × m12 = a
m 13 = a
a is positive, so a = (2)3 = 8.
5. x2 + 4y2 =1 ....(i)
2 2
4x + y = 4
y2 = 4 – 4x2
put in (i)
x2 + 4(4 – 4x2) = 1
x2 + 16 – 16x2 = 1
16 – 1 = 15x2
15 = 15x2
x2 = 1
x=±1
y2 = 4 – 4x2
= 4 – 4(1)
y2 = 0
y=0
(1, 0) and (– 1, 0) are two common point.
1 2 a b
Area of ellipse = a = 4 × a 2 x 2 dx
3 0 a
a
b x 1 x
=4× a 2 x 2 a 2 sin 1
a 2 2 a 0
2
1 2 b a
a = 4 ×
3 a 4
b 1
a 3
2 2
b 1 8 2 2
e= 1 = 1 = = .
a 3 9 3
PA PB 18 2 B
7. PD = = =9
PC 4
N
1 18 O
BN = AB = 10 4 P 9
2 C 2 D
M
1 13 A
MC = CD =
2 2
PM = MC – PC
13 5
= –4=
2 2
5
ON = PM =
2
In ONB
2
5 25 425 5 17
OB = 10 2 = 100 = =
2 4 4 2
5 17
Diameter = 2 × OB = × 2 = 5 17 cm.
2
8. cos 175 = cos (180 – 5) = – cos 5
cos 185 = cos (180 + 5) = – cos 5
cos 355 = cos(360 – 5) = cos 5
cos 5 + cos 10 + cos 15 + ......+ cos 355
= cos5 + cos 10 + .....+ cos 85 + cos 90º + cos(180º – 85) + cos (180º – 80º)
+ .......+ cos (180º – 5) + cos 180º + cos (180º + 5) + cos(180º+ 10)
+ .......+ cos (180º + 85) + cos 270 + cos(360 – 85) + ......+ cos(360 – 5)
= cos 5 + cos 10 + .......+ cos 85 + 0 – cos 85 – cos 80 – ..........– cos 5 – 1
– cos 5 – cos 10 – cos 85 + 0 + cos 85 + cos 80 + ...........+ cos 5
=–1
a
x=
4
ay 3
=
x 4
ay 3
=
a/4 4
13a
y=
16
In PAB
42 = x2 + a2
2
a
16 = + a2
4
17a 2
16 =
16
16 16 256
a2 = =
17 17
256
Area of square ABCD = a2 = .
17
x 2
4
2
x=
= x=4
2 1
B C
3 2 4 2 22 9 16 4 21 7 2 D 1
cos B = = = = .
23 4 24 24 8
18 x 6
11. s= = 9x + 3
2
= 6 (3 x 1)( 3 x 1)( x )
= 6(3x + 1) x
x is a perfect square, so in 1 to 20, 4 perfect square i.e. possible values are {1, 4, 9, 16}.
13. Statement I is true that the derivative of an odd differentiable function is always even and statement II is
also true that If f(x) is differentiable at a point x0 and g(x) is not differentiable at x0, then f(x) g(x) is not
differentiable at x0.
0, 0 x 1
14. x
1, 1 x 0
sin( 1)
sin1, 1 x 0
f(x) = 1
0, 0 x 1
lim f ( x ) sin1
x 0
and xlim
0
f (x) 0
1
17. x | x |3 / 2 dx
1
0 1
= x( x )3 / 2 dx + x( x )3 / 2 dx
1 0
0 1
= x 5 / 2 ( 1)3 / 2 dx + x 5 / 2 dx
1 0
0 1
x7 / 2 x7 / 2
3/2
= (– 1) +
7 / 2 –1 7 / 2 0
2 2
= (– 1)3/2 [0 – (– 1)7/2] + [1 – 0]
7 7
2 2 2 2 4
= – (– 1)5 + = + = .
7 7 7 7 7
1.dt =t+C
= f11(x) + C.
19. Applying AM and GM condition :
x1 2x 2 3 x 3
6 x1x 2 x 3 1 / 3
3
4
6 x1x 2 x 3 1/ 3
3
Cubing both sides
64
6 x1x 2 x 3
27
32
x1x 2 x 3
81
2 2 2
x1 x 2 x 3 2 2 2 1/ 3
Now also
3
x1 x 2 x 3
2 2 2 2/3
x1 x 2 x 3 32
3 81
1/ 3
2 2
210 2
x1 + x2 + x3 3
38
1/ 3
2 2 2
38 2
x1 + x2 + x3
9 9
24
x 12 + x 22 + x 32 0 .6
9
x 12 + x 22 + x 32 1 . 6
So, according options least value is 2.
20. 12 3 4 5 6 7
at each position two posibility i.e. either H or T
So total posible outcomes = 27
As we want three tails is sequence and it happened at 7th turn. So at position 5, 6, 7 we have tails and
position 4 must have head otherwise our requirement is fullfilled at position 6.
So, the position 1, 2, 3 can have anything i.e. H/T = 23
To get tail at 1, 2,3 position we have only one probability.
So, total favourable cases = 23 – 1 = 7
7 7
required probability = = .
27 128
1
23. E for point charge
r2
Force solid sphere
1
Inside the sphere E r and out side the sphere E
r2
L
24. =
r 4
L
So, =
r 4
vqr q
or (Answer is C)
2mvr 2m
2 2 1/ 2
26.
kT
=
ML T = [M0L0T0]
1 1/ 2
c m 2T M
Which dimensionally ratisfies
f 1 kT
= (Answer is D)
f c m
1
27. Average power, <P> = vA2w2
2
Av2 (Answer is A)
d 0.2 6 103
28. Wave length, = = 0.5 × 10–4 m
D 24
= 5 × 10–5 cm
= 500 nm (Answer is B)
29. (B)
5.6 10 4 9 1010
So, v2 = = 900 m/s (Answer is B)
5.6 1012
1
sec–1
t
1
sec–1
t
= angle(dimensionless) (Answer is A)
mv 2 kq1q2
34. 2
r r
kq1q2
v=
mr
9 10 9
v = 1.6 × 10–19
9.11 10 31 0.53 10 10
v = 2.24 × 106 m/s (Answer is D)
I
35. F
F
0 1 2
F=
2d
4 10 7 4000 4000 60 10 2
F=
2 1.5 10 2
F = 128N repulsion (Answer is B)
37. (C)
39. Distance between to consecutive destructive interference is 1.7cm, so total number of points of
destructive interference on the line PQ is 4. (Answer is A)
40. (D)
41. The ionization energy or enthalpy of Na is greater than that of Li but the hydration enthalpy of Li is higher
than that of Na. Difference between ionization enthalpy of both is less than difference between their
hydration enthalpy so overall oxidation potential of Li is greater than Na. Therefore Li metal is a better
reducing agent than Na metal.
1
42. Compressibility K =
P
1 1
Kx – Ky = –
1 2
= 0.5 atm–1
OH
43.
CO2H
44.
conc. NaOH
2CH3 CHO CH3 CH2OH + CH3 COOH
Cannizzarro reaction
46. According to graph, segment BC represents isobaric process. It means pressure is constant so accord-
ing to Charle’s law V T [on constant pressure]
From B to C volume decreases so temperature will also decreases.
H H
6 4 3 1
47.
7 5
2 OH
when same groups present in same side of the double bond then geometrical isomer is known as
Z – isomer.
+ +
/////////////////////////
+
Cl Cl Cl
Cl Cl
49. en Co en en Co Co en
Cl
en en
cis/d
trans
53. Because ideal mixture of benzene and toluene follows Raoult’s law
according to Raoult’s law
Pmix = PA + PB
PBº
Pmix
PAº
XA = 0 XA XA = 1
molefraction (benzene )
54. sp3d2 hybridization explains the bonding of complex which has C.N. (co-ordination number) 6 so answer
may be either [Fe(CN)6]3– or [Fe(H2O)6]2+. But H2O is a weak ligand and CN– is a strong ligand.
Because weak ligand form an outer orbital complex with metal ion and this is possible when sp3d2
hybridization takes place.
1
56. Bond order = [N – Na]
2 b
0.693
58 t1/ 2 =
K
0.693
t/12 =
6.93 10 – 3
t1/2 = 100 s
59. Because unit cell has six faces and every facial atom is a part of two unit cell. It means only half part of
one facial atom belongs to one unit cell.
1
so, total no. of facial atoms in fcc unit cell = 6 × =3
2
T1 – T2 W
60. = =
T1 Q1
800 – 200 W
800 100
W = 75 J
PART-II (2 Mark)
MATHEMATICS
81. a=A– d
b=A
c=A+d
3
a + b + c = 3A =
2
1
A= =b
2
3
a+b+c=
2
3 3 1
a+c= –b= – =1 ....(i)
2 2 2
b2 = a 2c 2
2
1
= ± ac
2
1
When ac =
4
1
c= ...(ii)
4a
1
a– =1
4a
4a2 – 4a – 1 = 0
4 16 16
a=
8
44 2 1 2
= =
8 2
as b > a
1 2
a=
2
82. g’(x) is changing its slope from positive to negative as it passes through g(2). So, g(2) is largest.
92
83. B = × 180º = 140º D
9
180 º 140 º x
1 = 2 = = 20º z
2
3
3 = 140 – 2 = 120º C
2
y
In ACD x
1
A
x B
y 2 x 2 z2
cos 120º =
2xy
1 y 2 x 2 z2
=
2 2xy
– xy = y2 + x2 – z2
z2 = x 2 + y2 + xy
* * * 0
As the diagonal element of resulting matrix are zero.
multiplication R1 of A and C1 of AT (i.e. = R1 of A) = 0
It is possible only when all element in R1 of A is zero
In the same way we can say that element of all 10 rown of A is zero so for the above condition we can
formm only 1 matrix i.e. A = null matrix.
(0, b) C
E
(0, 0)
(– a, 0) A (–ae, 0) O B
85. F
D (0, – b)
1 2 3
86. [ x ]e x dx = 0e
x
dx + (1) e x dx + 2e
x
dx + ......
0 0 1 2
2 x 3
= 0 + e x + 2e + .........
1 2
= – (e–2 – e–1) – 2(e–3 – e–2) – 3(e–4 – e–3) .........
= e–1 + e– 2 + e–3 ............
1
1 1 1 e 1
= + + + .......... S = = .
e1 e2 e3 1 e 1
1
e
x
88. lim g( x ) e f ( t ) f ( x ) dt
x 0
x
g( x ) e f ( t ) dt
= 0
lim f(x)
x e
x
g' ( x ) e f ( t ) g( x )e f ( x )
= 0
lim
x f ' ( x )e f ( x )
g( x )
= lim 0
x f ' (x)
3 x 3 .....
= lim 0
x 16 x 3 ....
3
= .
16
dy
89. = sin(x + y) + cos(x + y)
dx
let x + y = u
Differentiating wrt x
dy du
1+ =
dx dx
dy du
= –1
dx dx
dy
= sin(x + y) + cos(x + y)
dx
du
– 1 = sinu + cosu
dx
du
= sinu + cosu + 1
dx
du
dx
sin u cos u 1
Integrating both sides
du
sin u cos u 1 dx
sec 2 (u / 2)du
2 tan u / 2 1 tan 2
dx
u / 2 1 tan 2 u / 2
sec 2 (u / 2)du
dx
2 tan u / 2 2
sec 2 (u / 2)du
dx
2(tan u / 2 1)
Put 1+ tanu/2 = t
(1/2)sec2u/2du = dt
dt
dx
t
log |t| = x + c
log |1+ tanu/2| = x + c
(x y)
log 1 tan =x+c
2
(x y)
So, log 1 tan = x.
2
6! 4! 6 C 4 6
2! 2! 2! 3! + C2 1
2! 2! 2! + = 76
4 going to their own value
2 pairing 2 going to their own value
76 19
P= = .
720 180
d
91. M1 M2
r1 r2
M2 d
so r1 = M M ........(i)
1 2
2r1
T = v ........(ii)
1
Here
GM1M2 M1v12
=
d2 r1
GM2r1
or v1 =
d
From (ii)
2r1d
T= GM2r1
2d r1
T=
GM2
2d M2d
T= M1 M2
GM2
2d3 / 2
T= (Answer is B)
G(M1 M2 )
hc
min =
K.E.
6.6 10 34 3 10 8
min = 30 10 3 1.6 10 19 = 4.14 × 10–111 m
18 (3.96 )2 0.92
95. Mass of water, m = kg
10 3
m = × 18×10–2 × (3.96)2 × 10–4 × 0.92 ×103
KA (1 2 ) t mL f
mLf = t = KA ( )
1 2
96. Range, R = 2 (H h) h
(i) h = H/4
HH 3
X1 = 2 H 3H/4
44
H/2 2
3
X1 = H
2
(ii) h = H/2 H/4
X2 = H 1
(iii) h = 3H/4
3 X2
X3 = H
2
X1= x3
X2 > X1 = X3 (Answer is C)
CHEMISTRY
101. Xe contains 8 electrons in its outermost shell or valence shell. In XeF2, Xe uses 2 electrons for bonds so
it contains 3 lp. In XeF4., Xe uses 4 electrons for bonds, so it contains 2 lp.
2
4
V
= 2 10 3
V V
42
= × V2
2 10 3
8
= × (10)2 (V = 10L]
10 3
= 0.8 mol–2 lit2
Kw 0
103. Depression in freezing point TF = m W
0
In given two cases m0, W and K are constants
so TF w0
( TF )1 ( w 0 )1
( TF )2 = ( w 0 )2
5.5 – 4 2.9
=
5.5 – 2.5 2.9 x
1.5 2.9
=
3 2.9 x
x = 2.9 g
I OH
II ' III '
2 5
2R and 5R
105. III II
OH
I '
0.059 [ Zn2 ]
Ecell = Eº – log10
2 [ Ag ]2
0.059 (0.1)
Ecell = 1.56 – log10
2 ( 0 .0001)2
Ecell = 1.56 – 0.2065
Ecell 1.35 V
Cu(Y)
107. 2CH3Cl + Si
(CH3)2SiCl2
(X)
SiCl4 + 2CH3MgBr (CH3)2SiCl2 + 2Mg(Br)Cl
(Z)
E1 E2
RT1 = RT2
T2 = 600K
109. 28
Ni [Ar]3d84s24p0
[Ar]
dsp2 hybridization
[Ar]
2
dsp hybridized Unhybridized
orbitals orbitals
238 206
110. 92 U 82 Pb x 24He y –01e
by balancing of mass no.
238 = 206 + 4x + 0y
x=8
by balancing of nuclear charge
92 = 82 + 2x – 1y
92 = 82 + 2 × 8 – y
y=6