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2012/2011

Secondary School
.
E xarmna tion
Papers
"(
5. eco11dary Four Exp,·eys
Science (PltJ sic�Y-IClteniistJJ�
Pa11er 1 & 2

I Gag EngSeng Scboo1l S.A1


1 Ahmad lb rahim Second.ary Scbool SJ\l
3, Dun.ieam. Secon.dary Scboo1l SA1
4 St. Gabriel'sSeconid.ar. y Scbool SA1
5 Chij St Jo,seph's Con1rent
1 SA1
6 Xinmtin Seconid.ary Scbool SA1
7 Karanj. iSeco1ndary Scbool SA1
8 _. ew T1own. Secondary Scboo1l SA1
9 l\laris St,ella High School SA1

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101 Nan ChiauHighSchool
1 SA1
Ill Tanj ong Katong Girls'School
1 1 SA1
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AHMAD IBRAHIM SECONDARY SCHOO[···-- · · ,, . :}
GCE "0" LEVEL PRELIMINARY EXAMINATION 2012
· SCIEN9E {CHEMISTRY)
(ANSWER SCHEME)

Sec 4 Express/ 5 Normal (Academic)

PAPER1 Date: Au_gust2012

Multiple-Choice Questions (20 marks)

01) C Q6) B 011) A Q16) D •.


l
i
!;
02) C Q7) A 012) C 017) A I
I
i
b
I

03) 0 Q8) 013) B Q18) D i

I
04) D Q9) A 014) C -Q19) D I
I
I
010) A 015) A 020) D i
Q5) B· !
Ii
PAPER3 Date� August 2012 Ii
Section A: Structured Questions (45 ,:narks).
I
Qn.
1 (a) R
Suggested Answer Remarks
Award 1 m�rk for
each correct answer
Il
{b} T ,. ii
i
(c) S !

(d) PandO
t·,f
.
t":.......
2 (a) Argon Award 1 mark for i'
(b) _Sulfur dioxide
each correct answer !I

Ii
i

(c) Ethene
(d) Lead (II) nitrate
II
i •,
l>

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3 {a} W:Groupl · Award 1 mark for. I
each correct answer. l
X: GroupV ! ..
No marks awarded if
Y: Group Ill the group number is
written as 1, 2, 3 ·.:.
Z: Group VII
l
3 {b) {i) All these elements have onlt one outer shell electron I
'
I
j

[1], thus they are placed in Group l. ·.


55
I
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·-• .. -...... ·�.
i
!
I
�· . -
Duneam Secondary School
· C9mbined Science Chemistry ·
preiirns · Examil)a.tit>n 2012 .. •
l
Answer Scheme

panP-r 1
21 C 31 a
'
22 b 32 b
23 C 33 d
.24 d 34 C
.25 d 35 d .!
26. a 36· b
27 C 37 b
28 b 38 C
29 b 39 a
30 d 40 .b
..

Paper3

Section A

1a X {1]
1b to maximize the effects of cooling [1]
1c colorless (1J
1d the substances heated are volatile and flammable [1]
I
i
l
ii.
!
[1] no marks given for name
'
!i·: -.,


2a Na20 ..
2b sulfur dioxide [1] no marks given for formula
2c S02 or Cli() · [1) no marks given for names · i
2d correctly shown valence shell electrons [1] Ii
correct brackets and charges shown [1]
legend [1.]

·r-?�.

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I.
3a an· atom that has same number of protons but different number of neutrons [ 1]
3b (0.62x38) + (0.38x40) = 38. 76
[1] [1] [1]

3c chemical properties are dependent on valence shell electrons [1]
isotopes have the same number of valence electrons [1]

79
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St. Gabiief's· Secondary Sehool . .
�12 Pr�liminary Examinations Sec 4E5N Scienc�(Chemistry) Marking Scheme

P1 _.J;-.. ..

'21;. 22 ·. 23: 24 ZS. -28 27 �-�2� ....::,29··


A D C B A C B A B D
31 32 . 33 ·34 35. _3� 37 38 39 .· .40
A D B D D A C C D B·

P3
Section·A
1 a Methane/ carbon dioxide ·[1]
Most got this
, . correct.
b argon [1]
Most got this
correct.
C aluminium oxide [1]
Some wrote
calcium oxide.
d ammonium chloride . [1].
Quite a
riumberof
'.
,;
students got
this wrong.
They wrote.
· lead{ll) nitrate
instead.
:
e calciurri oxide [1]
Quite a
number of
students
wrote
. ammonium
chloride.
i .·
2 a They have the same number of valence electrons. [1]
. Most got this !
;·.
correct
- However,
there were a
fewwho
identified the
halogens as
having one

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valence
: electro11-
b Fluorine. chlorine, bromine. iodine [1)
Quite a
: number of
students
wrongly spelt
·nuorine· as
·t1ourine•. 1
103
mark was
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4Exp/5N{A)i 5NA(IT) Science(Chemistry)2012
Prelim Paper 3 Mark S.cheme

CHEMISTRY P1 ANS:
1 A. 6 A 11 C 16 D
2 D 7 C 12 C 17 .B
3 B 8 8 13 D 18 C
4 o 9 A 14 B ·19 A
5 C 10 D 15 D 20 B

Section A

Q Answer Marks
1 (a) (i) iron 1
(ii) hydrogen 1
(iii) iron(lf) chloride 1
(iv) - sodium chloride 1

1 (b) Fe + 2HGI 7 FeCl2 + H2 2


(1tn ..,. correct formulae; 1 m - correct balancing)

1(c) Fe +{aq) + 20H"(aq) � F�(OH)2 (s) 1

2(a) Covalent bond; Covalent substances _have low melting point and boiling 1
point

2(c) sulfur 1

2{d) 1m: 2 double bond 2


1m: all electrons
accounted for

y 0
0

2(b) Store in oir-lt is very reactive_ 1

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2(e) When XZ is dissolved in water or in molten state, their ions are mobile 1
and hence there is a conduction of electricity_

3(a) coke 1

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Xinmin Secondary School
Chemistry
Paper 1

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Xinmin Secondary School
Chemistry
Paper 3

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2012 4E/5N Prelim Exam 5116 S"cience (Chemistry) Answer Scheme
P;aper 1 ·:�
' - . ..
21. il' ·26. C 31: A '3tt·: .C
22 A 27. D 32. D 37.
..
i- ••
.•, .:

23. C 28. D' 33. C 3g: A


24. D 29. 8 34. B 3�. B
25� B 30. A 35� C 40. A

PaperJ
No Yz marks awarded for this paper.
A1 compound symbol of symbol of formula
Positive ion neoativeion
sodium chloride Na
+
er NaCJ
calcium oxide. Ca;,:+ o;,: CaO
...
..
lead(II) iodide PbL+ ,- Pblz

. .aluminium hydroxide ·Ai'·+ OH- !V(OHh

ammonium sulfate ·NH/. so/- (NH4)2S04

'i
. !
Award 1 · mark for each correct answer.
[fotal: 5 marks]

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Karanji Secondary School
Chemistry
Paper 1

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Karanji Secondary School
Chemistry
Paper 3

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'. ·._,--:

·Answer Key for 2012 4 Exp Science {Chemistry) 5116 Prelim 2


MCQ (20 marks)
"• ·-

Question 021 Q22 023 024 Q25 Q26 027 Q28 ·Q29 Q30

Answer D D B A B D B C B A
i
034 i
·Question 031 032 Q33 Q35 Q36 Q37 Q38 Q3� Q40 l
ii
i
Answer A B C C B D A B C D (
I
l

Section A (45 marks)

Ala Helium 1
b Pen�ene 1
c. Ammonia l
d Crud�·o,1•· l

A2 To a beaker ofwaim hydrochloric acid, add excess iron metal/ iron(II) carbonate/
iron(H) oxide l iron(ll) hydroxide a,nd stir till no more of it dissolves. I
Filter the mixture to obtain iron(ll) chloride solution as the filtrate. l
Gently heat the filtrate till satu�ion and Jet it cool for crystals to form. t
Filter off the irori(H) chloride crystals and dry them between two pieces offilter I
papers.

A3a 100°c I
b X at bottom ofthe flask I
C Check the melting point/ boiling point of the water obtained. I
lfthe water melts at O °C or boils at I 00 °C, then water is pure. OR
If the water melts/ boils over a.range of temperature, then the water i$ impure. I
..

A4a Correct drawing ofNF3 molecuJe w1th sharing of electrons I


Legend for electrons + Ratio of atoms I
b NF3 does not conduct electricity in any state I
due to absence of free mobile electrons or ions. l
C Higher boiling point 1 j···-..
1 · •. :
-· I

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as more energy is needed to overcome the stronger intermolecular forces of attractiQn
in NBr3, which is a larger molecule than NF3
d 2NF3 + 6HC/ � N2'+3C/i + 6HF I l
A5a Both atoms contain same number of3 protons, I
but lithiurn-6 contains only 3 neutrons 1
while lithium-? contains 4 neutrons. I

18
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New Town Secondary School
Chemistry
Paper 1

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New Town Secondary School
Chemistry
Paper 3

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Mark Scheme
4Exp Science. Chemistty .
End of Year 2012

Paper1
Multiple-choice questions

21 B 31 B
22 C 32 D
23 D 33 A
24 B 34 D
25 B 35 A
26 A 36 C
27 A 37 A
28 B 38 s-
29 D . 39 D
30 C 40 D

Paper3
[
Structured i
!
Section A

1. sublimation [1]
attractive forces between molecules d�crease from very strong in dry
ice to very weak in carbon· dioxide. [1]
the movement of molecules increases from rotate and vibrate in a fixed
position in dry ice to move randomly at high speed in carbon dioxide i
gas[1] I
;
i
2.
Either an element or a
Substance Element Compound
"
Mixture
compound
Solid p
PowderQ- " !
l ·."
'
Liquid R -.J

Liquid S .-,J

GasT v
1 mark each

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3. (a} H2S04 [1]
(b) Corrosive/aborbwater easily [11
(c) sodium oxide[1J, aluminium oxide[1]
(d) (i} zinc carbonate/zinc/zinc oxide[1]
(e) (ii) ZnC03(s) + H_zS04(aq) 7 Zn$Q4(aq) + C02{g) + H20(I}
Balanced chemical e quation [1}, correct state symbol (1]
4. (ci) alkali metals[1]
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201 t Prenm 1 scteoce{Gtiem.is!ry) f,.ilsvter Scheme-� ·
.. : -· . ·-.. _. ...

P.aper 1
.. C ·-' 3.:_.._ . D ::
. · .. '. . .4 · A ·B
.1 :. .2 C 5
. ·8 . o·· . . 9. · 10. ·8·;.:_.:
6 ··o 7 D'. o
12 0 . .1:, -
: .c - = · - 14. s 1s. c.:r·:.-.....
c
11 0
_. .
·. :.-. . ·15 17.-.. B·i ._: .
.· ..
·, .
.Pal)e!2
-.· �-":.

·
A1. (a) lt_is usually soluble in or�nlc�oiyents·bµt_ . �pt_il) �ter. .- ·
.
. . .. :.... . .
::. -. ::· :·. -..·
__ . - .
[1}

. (bl�. ·SodiLJm sulfide is-an ionic comoound,witb giant ionic lattice structure. 1n. (11
.. aqueous �nd molten statei lhe·Joos: are :mobile hence able to_ conduct
· :· · · ·. · ·
electricity;�,:.
.
" -·Carbon stllfide is a covalent moJeeule with simp!e mofecular structure. that · [1 J
·
taas mobile ions:pres�rit·soi can119(condu.ct �rectricity. .
oQ· - . ·. . .
-· . _: ..
.

(c) The� in sodium sulfide:a.,:e)1,et�::bY:';;tcoog-e!edrostatic forces of [1)'


. attractjoil�h!c.if (eqVi(�:ilar@@roouotof� hea(;to:eyer me - .
co : . · . •. -·. ,:· .
The moieci.ite� iii qirbon �sulfi�-�re :flek(by:W�1{1ntermoiecutar forcesof. [1] ·
. attraction yvhicil requir�
·. . �-_. �smai1 of . lo .
amOl[li heat ·overcome.
.
- : . .. � - ..
(11
.

A2 (a) . Vofu1,e=of gas/ ·


cm ·
3

· ·....:. -= ··.;.._ _;.:. __· .Time/


-'--�--�-...;.·-· - . mi_n .
(b) No: of motes;of CaC03 .. . .·• • f · ·· ·, ·; f. · - · . -�.: . mass -: : . (1]-
. - =--=----=
. , ·o. o.mo1es· o . a· 00·-.3·-. -,
N
. . . .
c
. ·. . Molarm4ss ·
. ·. .
:: . .·: :_ -:··:Jis_ :_· .... . .
·. '. :- .- 40.+Ji=-t .
·
· ){ °
16) . ::
. - ·
. - ·. - .�:0.3���--:�'·: - .�-:. ..· .: ._ .
- • ..---. .
.. ·: .. . . - :
_; __

. . Pl.-
. :.· . : :. . . 1: _. ·
. _- : · · . 1 . . -'
: . :: . '032-5,no/ . . . . 0.325mol. ..
No. of mOl!;!S of CO2 . . . -·... :. .. .. . . : .. .. ..
.
.. .
Volume of C<?2· ·. VorofC02'==JlJOhc�4dm�.· . - .

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. :

- -: --- - -----���-�_.3_2__5 x_2_��m-�·--


3

-
1 J'�
[ -
����
�7.8dm3 ·
· � - -'�-

. L_·����
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2\. 'll. 21 24. 25.
B C B A D

-
25.. '21. 2a. 29. 30.
B B 0 B
.
C
:n 35..
.·.o.
31,.. :,z. 3<.
8 B 0 A
. 40.
c
"7•• 39.
.B C D B.

:::.i:r-..._,.�!'·�--·l"ocij,ilde..albo
Sal lm:psiscail>o�- • . 1

- l•
1 ·l ..
b> ·- � • · 21«H• C>Cl,•·ttp•COt, - ----· -- . "; • •
N�of!"ola'!l!�=ll.2:a.,�011000.
cl) j1
•• . • 0.0133? mcl
j
ii) 1moloolC:aCC:. Wilruc1....,2n,alesolHCI.
...... • •. 1 ·-
-···-- ... z ........ J>O.olll'Cloiol�•0.013l211.•(ll)()666mol
• !L
t
Ill lotl<od(l).-�
m-· •• - -
M... ol eaco.
! 0.00&110 t40 • il + 16 s 3)
1--+--- ·__:c1l@q
I .
PbZIIIC-\e"

.
Qiseo{>Pef
H N · 0 H

' - �·. cQv·


·". '..
R lshyifn>O"'II'"
Sls:rinGhydlO>l,Je
:nicoppoftll)O•illO
Ulsa,ppotllij i:.lfolc
. . :

o- °'°""""
.1-dcdn>noff\ilrO(I<!' .
. : .
ol h)'drogon �,
7•1

2•1
2M(s) • lH'°'[I � 2M!?ll(aq) .. Ha (g)
. �af��---.:.--RNI.• <><>CRd,,,;..O -""'>' 11
<)

ld)
I ·
�-It dedran to
• �,a M; IOII. n lr.J.nslc,s oJ e� to a
·•
I 1o ,orrn Mtl.-

Whatl pidide :i2;t G.ct•��s.. :he sude� aiN. inaea:os..

==.:..en::t:'io�'O���
1Hs inctoasu VM. .uo:1 ol conlo1dttdwoan.r� �.11..

i :::::::'a£G"'i'wo cases ..ar.d the &p eedd

.-.�--=-F1-i:::
CDIS�_":' .

iea;i n,.,,...-,,.,.,.. ::- . ··!k\


·-
.Lo
l

!
Sbntlo<OffOS......... .,....... 1.
"ijj
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.:-·- ·<--;'-' .. - -

iI'.
i

···"-
)JI\ OUII to ttSOUIUa l>ec9US• of toilllh dcm:and. .
ill Sna•• lt:Z.l'

.
.0:2.G .1
2Cl b

- __ ._-___-
3_+;;SnCl.
::::.�
• c.,.�--,-==·-·-:,,-:,--,-�--�---
Sn= c,,::::,

r") - r.,,.,,....
,;.,

Ian•"'
the oaicfatlor\$b!c cat Sn rcdul:01 r.o. • •·eoo-1� • l,;IJliurla � gn..,0��valence ckcflft so aq,gftt *-' h
:- PJ


ore,., lo albln U- :bt>le )::rucllni.ol .a nobf• 51�- 3
Tho CN.icio Snet. lo&• �Ill> ..... cHotine p,.-
--��... ond..;I_,
. • ft bec:Gr:le$ a p: sl&ve laiiof chet1;• 1•. ·. .JOIA,ol4
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nolla1P<.
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b),1 \.,. t"..clSOISh�xldiifta�lcr.. tS�dS

I
2. Add,-a.gpt�l�nabsa�lrr�oneSUJI , ..:4
oxide I cot1*'(1l) .clllbon,14• I� o.ddc WI uc.o.ss : -4,e,iA of S

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wdoalo1,cao1ch:ches.. -3


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co.-»c.:t.? t:J:.k i: d�l'd I..QPQ .£ IV-b:t buna.

247
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Ta�jong Katong·�in$' sthi>ol··
Prelimlnary �fuation 2010
�ence ( Cl)an_1�tiv ):51-16/5118 ·· ..
.. .. - . .:· �. --
'

.-·..·= . - ..•. - :·- .... :,'1l}


..;-� .-:.. : ....._ •...-.. _ .·•·..... .- ...
:5118/1: tc�rn1a·1oj.
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