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Answer:

(a)

 P 
 
The derivative  V  S can be written as:

 P   P   T 
     
 V  S  T  S  V  S …… (1)

Use the below mentioned Maxwell relations in equation (1).

 P   S 
   
 T  S  V  P
 T   P 
    
 V  S  S V

Simplify equation (1) as shown below.

 P   P   T 
     
 V  S  T  S  V  S
 P   S    P  
      
 V  S  V  P   S V 
 P   S   P 
      
 V  S  V  P  S V
 P   S T   P T 
        
 V  S  T V  P  T S V
 P   S   T   P   T 
           ...... (2)
 V  S  T  P  V  P  T V  S V

Again, use the below mentioned Maxwell relations in equation (2).

 T   P 
    
 V  P  S T
 P   S 
   
 T V  V T

Simplify equation (2) as shown below:

 P   S   T   P   T 
          
 V  S  T  P  V  P  T V  S V
 P   S    P     S    T 
           
 V  S  T  P   S T    V T   S V
 P   S    P   S    T 
         
 V  S  T  P   S T  V T   S V
 P   S   P   T 
        ...... (3)
 V  S  T  P  V T  S V

 S   P   T 
  ,  , and  
Now,  T  P  V T  S V can be defined as:

 S  CP
  
 T  P T
 P  1
  
 V T T V
 T  T
  
 S V CV

Use the above definitions in equation (3) as:

 P   S   P   T 
       
 V  S  T  P  V T  S V
 P   CP   1  T 
      
 V  S  T   T V   CV 
 P  CP
  
 V  S  T CV V

(b)

Entropy can be written as a function of P and T such that,

S  S  P, T 

Take partial derivative of above expression as:

  S   S 
dS    dP    dT
 P T  T  P …… (4)

Now, at constant volume, divide equation (4) by P such that,

 S   S   P   S   T 
         
 P V  P T  P V  T  P  P V
 S   S   S   T 
        ...... (5)
 P V  P T  T  P  P V

 S   S   T 
  ,  , and  
Now,  P T  T  P  P V can be defined as:

 S 
   V
 P T
 S  CP
  
 T  P T
 T   V 
   
 P V  S T

Use the above definitions in equation (5) as:

 S   S   S   T 
       
 P V  P T  T  P  P V
 S   CP   V 
   V    
 P V  T   S T
 S   CP   V P 
   V     
 P V  T   P S T
 S   CP   V   P 
   V       ...... (6)
 P V  T   P T  S T

 V   P 
  and  
 P T  S T are defined as:

 V 
   T V
 P T
 P  1
  
 S T V

Use the above definitions in equation (6) as:

 S   CP   V   P 
   V      
 P V  T   P T  S T
 S   CP   1 
   V     T V    
 P V  T   V 
 S    T CP 
   V   
 P V  T 
 S  T CP
    V
 P V T