Professional Documents
Culture Documents
Chapter 40
Pressure, Temperature, Quality
and Flow Measurement
Pressure measurement
The pressure gauge is probably the earliest instru-
ment used in boiler operation. Today, with complex
control systems in operation and more than one hun-
dred thirty years after the first water tube safety
boiler, a pressure gauge is still used to determine steam
drum pressure. The Bourdon tube pressure gauge is
shown in Fig. 1. Although improvements have been
made in construction and accuracy, its basic principle
of operation remains unchanged. A closed end oval
tube in a semicircular shape straightens with inter-
nal pressure. The movement of the closed end is con-
verted to an indication (needle position).
Pressure measuring instruments take various forms,
depending on the magnitude of the pressure, the ac- Fig. 2 Inclined differential manometer (courtesy of Dwyer Instru-
curacy desired and the application. ments, Inc.).
Fig. 4 Opposed bellows gauge (courtesy of ITT Barton, a unit of ITT Industries, Inc.).
used in control systems, but the more common designs der certain circumstances a through the wall pressure
use electrical circuitry to sense the changing position connection may not be representative. It may be nec-
of basic mechanical motion and to produce an electri- essary to use a probe incorporating a tip configura-
cal output signal to be transmitted. These are readily tion that minimizes the effects of the flowing fluid to
adaptable to computer based systems. Some transduc- obtain a representative static pressure measurement.
ers use a piezoelectric crystal which changes electri- Connecting lines to instruments should be as short
cal resistance as the element is deformed under pres- and direct as possible and must be leak-free. For differ-
sure. Other pressure transmitter designs use a dia- ential pressure readings, it is preferable to use a differ-
phragm with strain gauges attached; minor changes ential pressure measuring device rather than to calcu-
in diaphragm strain are transferred to the strain late the difference between the readings on two instru-
gauges, which change resistance. Electrical circuits ments. Particular attention should be paid to the place-
recognize the resistance change in the crystal or strain ment of the instrument, the potential for condensation
gauges and produce an indication of pressure. Ad- in the impulse lines, and the accumulation of debris or
vanced applications have used an optic glass fiber non-condensable gases in the completed installation.
embedded in a metal diaphragm, with pressure mea-
surement determined as a change in the light beam
traversing the fiber. Pressure transducers incorporat- Temperature measurement
ing electrical components have the advantage of fewer Today, the Fahrenheit and Celsius (formerly centi-
mechanical parts for improved durability. However, grade) scales are the most common and firmly estab-
this may restrict the installation location due to tem- lished temperature scales.
perature limitations of the electrical components. In- The Fahrenheit scale is fixed at the freezing point
struments configured to generate electric signals have (32F) and the boiling point (212F) of pure water at
been adapted to incorporate computing capability to atmospheric pressure, with 180 equal degrees between
assist in calibration. Pressure transmitters and trans- the two points. The centigrade scale was originally based
ducers have been readily adapted for power plant on the same freezing (0C) and boiling (100C) points of
computer data acquisition and control systems. water at standard atmospheric pressure, using the con-
venient 100 degree interval of the decimal system.
In 1960, the General Conference of Weights and
Instrument corrections Measures changed the defining fixed point from the
In recording and reporting pressure readings, cor- freezing point to the triple point (0.0C) of water. The
rections may be necessary for water leg and for con- triple point is the condition under which the three
version to absolute pressure by adding atmospheric phases of matter (solid, liquid and vapor) coexist in
pressure. Effective water leg is the added pressure equilibrium. This point is more easily and accurately
imposed on the gauge by the leg of water standing reproduced than the freezing point. At standard at-
above the gauge. Fig. 5 illustrates a water leg correc- mospheric pressure the interval between the triple
tion to a pressure gauge reading. The density of the point for water and steam on the centigrade scale
water in the leg may change with ambient tempera- became 99.99C instead of 100C.
ture and, for precise measurement, the water leg tem- In 1990, temperature standards were further re-
perature should be monitored. On some gauges it may fined by the International Temperature Scale 1990
be possible to zero the gauge at zero operating pres-
sure with the water leg completely filled to compen-
sate for the water leg static head. Care must be taken
in performing water leg adjustments as this may af-
fect the instrument calibration over the operating
range. Differential pressure measurements require a
water leg correction for both sides of the measuring
instrument. For some liquid level devices, the differ-
ential pressure measurements from two water legs of
different elevations are used to provide the indication
of liquid level. Differential pressure measurements
across orifices, nozzles or pitot tubes to measure flow
are described below.
reading, portable instrument. Low precision thermom- Within the visible range, two types of temperature
eters are inexpensive and instruments of moderate measuring instruments, the optical pyrometer and the
precision are available for laboratory use. This ther- radiation pyrometer, sense the emitted radiation to
mometer features a reservoir of liquid in a glass bulb indicate temperature.
that is connected directly to a glass capillary tube with Optical pyrometers The optical pyrometer visually
graduated markings. Mercury, the most common liq- compares the brightness of an object to a reference
uid, is satisfactory from –40F (–40C), just above its freez- source of radiation. The typical internal calibration
ing point, to about 600F (316C) if the capillary space source is an electrically heated tungsten filament. A
above the mercury is evacuated. The upper temperature red filter may also be used to restrict this visual com-
limit may be 900F (482C) or higher if this space is filled parison to a particular wavelength. This instrument
with pressurized nitrogen or carbon dioxide (CO2). measures the temperature of surfaces with an emis-
The use of unprotected glass thermometers is re- sivity of 1.0, which is equivalent to that of a black-
stricted to laboratory or research applications. For body. By definition, a blackbody absorbs all radiation
more severe service there are various designs of in- incident upon it, reflecting and transmitting none.
dustrial thermometers with the bulb and stem pro- When calibrated and used properly, the pyrometer
tected by a metal casing and usually arranged in a yields excellent results above 1500F (816C). Tempera-
thermometer well. Response to rapid temperature ture measurement of the interior surface of a uni-
changes is slower than with the unprotected labora- formly heated enclosure, such as a muffle furnace, is
tory type instrument. a typical application. When used to measure the tem-
Solids The expansion of solids when heated is rec- perature of an object outside a furnace, the optical py-
ognized in thermometers using a bimetallic strip. Flat rometer always reads low. The error is small [20F
ribbons of two metals with different coefficients of (11C)] for high emissivity bodies, such as steel ingots,
thermal expansion are joined face to face by riveting and large [200 to 300F (111 to 167C)] for unoxidized
or welding to form a bimetallic strip. When the strip liquid steel or iron surfaces.
is heated, the expansion is greater for one metal than The optical pyrometer is widely used for measuring
for the other. A flat strip bends, or changes curvature objects in furnaces at steel mills and iron foundries. It
if it was initially in a spiral form. Bimetallic strips are is not applicable for measuring gas temperature be-
seldom used in power plant thermometers but are cause clean gases do not radiate in the visible range.
widely used in inexpensive thermometers, household
Radiation pyrometers In one type of radiation py-
thermostats and other temperature control and regu-
rometer, all radiation from the hot body, regardless of
lating equipment. They are particularly useful for
wavelength, is absorbed by the instrument. The heat
automatic temperature compensation in other instru-
absorption is measured by the temperature rise of a
ment mechanisms.
delicate thermocouple (TC) within the instrument. The
Radiation properties thermocouple is calibrated to indicate the temperature
All solid bodies emit radiation. The amount is very of the hot surface at which the pyrometer is sighted,
small at low temperatures and larger at high tempera- on the assumption that the surface emissivity equals
tures. The quantity of radiation may be calculated by 1.0. The hot surface must fill the instrument’s entire
the Stefan-Boltzman formula: field of view.
This type of radiation pyrometer has high sensitiv-
q/S = σ ε T4 (2) ity and precision over a wide range of temperatures.
The instrument gives good results above 1000F (538C)
where when used to measure temperatures of high emissiv-
q =
radiant energy per unit time, Btu/h ity bodies, such as the interiors of uniformly heated
S =
surface area, ft2 enclosures. Because operation of the instrument does
σ =
Stefan-Boltzman constant, 1.71× 10–9 Btu/h ft2 R4 not require visual comparison, radiation pyrometers
ε =
emissivity of the surface, dimensionless (usu- may be used as remotely operated temperature indi-
ally between 0.80 and 0.95 for boiler materials) cators. Errors in temperature measurements of hot
T = absolute temperature, R = F + 460 bodies with emissivities of less than 1.0, especially if
they are in the open, are extremely large.
At low temperatures the radiation is primarily in Radiation pyrometers sensitive to selective wave-
the invisible infrared range. As the temperature rises, lengths in the infrared band give good results when
an increasing proportion of the radiation is in shorter measuring temperatures of bodies or flames. One de-
wavelengths, becoming visible as a dull red glow at sign uses a system of lenses, a lead sulfide cell and
about 1000F (538C) and passing through yellow to- electronic circuitry to produce a measurement.
ward white at higher temperatures. The temperature An advancement of the single band pyrometer is
of hot metals [above 1000F (538C)] can be estimated by the two color pyrometer, which measures the intensi-
color. For iron or steel, the approximate color scale is: ties of two selected wave bands of the visible spectrum
dark red 1000F (538C) emitted by a heated object. This unit computes the total
medium cherry red 1250F (677C) of the emitted energies and converts it into a tempera-
orange 1650F (899C) ture indication. As with the optical pyrometer, indications
yellow 1850F (1010C) depend on sighting visible rays and therefore its mini-
white 2200F (1204C) mum temperature measurement is 1000F (538C).
Other properties
Other material properties that vary with tempera-
ture are also used as the basis for temperature mea-
suring instruments. By flowing gas through two ori-
fices in series, a method has been developed for mea-
suring gas temperatures up to 2000F (1093C) com-
mercially and up to 4500F (2482C) in the laboratory.
Temperatures ranging from absolute zero to 5000F
(2760C) have been accurately determined by using a
laboratory instrument that measures electron motions.
High temperature research has been stimulated by
gas turbine and jet propulsion applications, and fur-
ther development of new and improved temperature
measuring instruments is expected.
Table 1
Types of Thermocouples in General Use
Type of Useful Temperature Maximum Millivolts at 500F Magnetic
Thermocouple (Note 1) Range, F (C) Temperature, F (C) (260C) (Note 2) Wire
(+) Copper to constantan (−) −300 to 650 (−184 to 343) 1100 (593) 13.24 −
(+) Iron to constantan (−) 0 to 1400 (−18 to 760) 1800 (982) 15.01 Iron (+)
(+) Chromel to constantan (−) −300 to 1600 (−184 to 871) 1800 (982) 17.94 −
(+) Chromel to alumel (−) 0 to 2300 (−18 to 1260) 2500 (1371) 11.24 Alumel (−)
(+) 90% Pt 10% Rh to
platinum (−) 900 to 2600 (482 to 1427) 3190 (1754) (Note 3) 2.048 −
Notes:
1. Nominal composition: constantan, 55% Cu, 45% Ni; chromel, 90% Ni, 10% Cr; alumel, 95% Ni, 5% Al, Si and Mn
combined.
2. Reference junction 0F (−18.0C).
3. Melting point.
Fig. 12 Application of pad-type thermocouple. Fig. 14 Thermocouple elements and hot junctions.
tion contact points are subject to thermal conduction Temperature of fluids inside pipes
in the wires. Where this type of error is significant,
precautions should be taken to prevent temperature The temperature of a fluid (liquid, gas or vapor)
gradients in the wires. Drilled holes for the wire ends flowing under pressure through a pipe is usually
should allow a snug fit before peening. For installa- measured by a glass thermometer, an electrical resis-
tions requiring a significant number of thermocouples, tance thermometer, or a thermocouple. Each thermom-
there are portable spot welding machines available to eter is inserted into a well, or thermowell, projecting
join the ends of the wire directly to a steel surface. into the fluid. The thermowell is preferred but a ther-
mocouple properly attached to the outside of a pipe
Millivolt potentiometer wall can provide good results. The thermowell provides
The temperature-emf relationships of standardized
thermocouple wires, as established and published by
the manufacturer, should be used to convert the po-
tentiometer readings to equivalent temperature val-
ues. These tabulated values represent the net emf
impressed in the potentiometer terminals when the
reference junction is at 0F (–18C) and the measuring
junction is at the temperature listed. The millivolt
potentiometer may be used with any type of thermo-
couple. It is frequently used when several different
thermocouple types are installed.
It is usually impractical to maintain the reference
junction at 0F (–18C) while taking readings. Correc-
tion for any reference junction temperature can be
made by adding to each observed emf reading the emf
value corresponding to the reference junction tem-
perature. The temperature of the measuring junction
can then be determined. Most millivolt potentiometers
are equipped with a compensator, which should be
used to correct for the reference junction temperature.
Direct millivolt readings then correspond to the actual
thermocouple temperature.
Direct reading potentiometer
A potentiometer may be graduated to read the hot
junction temperature directly instead of in millivolts.
When calibrated for use with a specific type of ther- Fig. 16 Thermocouple well installation.
To assure a close comparison, the thermocouple tem- Limitations of gradient thermocouples The gradient
peratures should always be read with the calibrated thermocouple method of measuring heat flow
equipment and under operating conditions close to through tube walls is a guide rather than an abso-
those existing during the original setup. An accumu- lute measure. Relatively small dimensions and small
lation of internal deposits in the thermocouple zone is differential temperatures exist between surface ther-
marked by an increased temperature difference from mocouple and depth thermocouple locations. Also, any
inner surface to saturation. small error in determining temperatures or in metal
When the average of the surface and depth tem- thickness between thermocouples usually represents
peratures approaches the limit for the tube metal, the a large percentage of this small difference.
boiler should be shut down and the inside tube sur- The effectiveness of the gradient temperature plot
faces inspected. Sufficient allowance should be made as an internal scale detector is also dependent on the
for tube to tube temperature variations. nature of the scale. Certain types of scale, such as
carbonate or silica deposits, accumulate uniformly,
while iron oxide deposits can accumulate irregularly.
The location of nonuniform deposits is uncertain and
the gradient thermocouple method is not reliable for
detecting such accumulations.
For a quick determination of internal tube deposit
changes, the difference between surface and depth
temperature readings can be plotted against the dif-
ference between surface and fluid temperature read-
ings. With a clean tube, points should fall along a straight
line over a range of inputs. As deposits form, the differ-
ence between surface and fluid temperature increases
for an unchanging surface and depth temperature dif-
ference. Fig. 22 shows a typical plot of such conditions.
tubes and by the fusing characteristics of ash and slag fer to the thermocouple by convection is proportional
from the current or expected fuel. The overall complex- to the gas mass velocity and the temperature differ-
ity of combustion and heat transfer relationships pre- ence between gas and thermocouple, the junction tem-
vents exact calculation and accurate measurement of perature may be brought closer to the true tempera-
the gas temperatures provides information to confirm ture of the gas by increasing the rate of mass velocity
calculation methods. and convection heat transfer at the thermocouple while
The optical pyrometer and radiation pyrometer are shielding the junction from radiation.
not designed to measure gas temperature. Excessive A special high velocity thermocouple probe for mea-
error is also encountered when gas temperatures in suring high gas temperatures in boilers is illustrated
the furnace and superheater areas are measured with in Fig. 25. This portable assembly is primarily used
a bare thermocouple. for making test traverses in high duty zones by in-
The high velocity and multiple-shield high veloc- sertion through inspection doors or other test open-
ity thermocouples (HVT and MHVT), developed to ings in the setting.
correct for radiation effects, are the best instruments This thermocouple is supported by a water-cooled
available for measuring high gas temperatures in probe. The measuring junction is surrounded by a
cooler surroundings or low gas temperatures in hot- tubular porcelain radiation shield through which gas
ter surroundings. Cross-sections through single and flow is induced at high velocity by an attached aspi-
multiple-shield high velocity thermocouples developed rator. The gas aspiration rate over the thermocouple
for use in boiler testing are shown in Fig. 24. can be checked by an orifice incorporated with the
The surfaces (water-cooled walls, or superheater or aspirator and connected to the probe by a flexible hose.
boiler tube banks) surrounding the usual location of The gas mass velocity (or mass flux) over the thermo-
a gas traverse are cooler than the gases. Consequently, couple junction should be at least 15,000 lb/h ft2 (20.34
the readings from a bare unshielded thermocouple kg/m2 s). Convection heat transfer to the junction and
indicate lower temperatures than those obtained with shield is simultaneous and both approach the tempera-
an HVT. For the same reason, an HVT generally in- ture of the gas stream. Radiation transfer at the junc-
dicates lower values than an MHVT. A comparison be- tion is diminished by the shield. Because the shield is
tween bare thermocouple, HVT and MHVT results in exposed to the radiation effect of the surroundings, it
typical boiler furnaces and cavities is given in Fig. 23. may gain or lose heat and its temperature may be
MHVT measurements closely approach true gas slightly different from the junction temperature.
temperatures. In this design, the thermocouple junc- With the increasing size of steam generators, han-
tion is surrounded by multiple shields, all of which dling long HVT probes has become more difficult but,
receive heat by convection induced by the high gas
flow rate. In this manner, the heat transfer by radia-
tion is so reduced that there is virtually no heat ex-
change between the junction and the innermost shield.
Because of the small flow areas that rapidly become
clogged by ash, use of the MHVT is limited to clean gas
conditions. Where traverses are taken in dust- or slag-
laden gases, it is usually necessary to use the HVT. The
readings are corrected by comparison with results ob-
tained under clean gas conditions from an MHVT.
For temperatures exceeding 2200F (1204C), noble
metal thermocouples are required and it is important
to protect the thermocouple from contamination by the
gases or entrained ash. Various coverings, shown in
Fig. 24, provide some protection for the wires, espe-
cially when fouling occurs from molten slag at tem-
peratures above 2400F (1316C). When platinum ther-
mocouples are used in gas above 2600F (1427C), ap-
preciable calibration drift may occur even while tak-
ing measurements requiring only several minutes of
exposure time. The thermocouple elements should be
checked before and after use with corrections applied
to the observed readings. When the error (∆T) reaches
40 to 60F (22 to 33C), the contaminated end of the ther-
mocouple should be removed and a new hot junction
should be made using the sound portion of the wire.
Because heat transfer by radiation is proportional
to the surface area, emissivity, and difference of the
source and receiver absolute temperatures, the effects
of radiation increase as the temperature difference
between the thermocouple hot junction and the sur- Fig. 24 Shield assemblies for high velocity thermocouple (HVT) and
rounding surfaces increases. Also, because heat trans- multiple-shield, high velocity thermocouple (MHVT).
Fig. 25 Rugged, water-cooled, high velocity thermocouple (HVT) for determining high gas temperatures.
to date, no acceptable point by point measurement of and insert these thermocouples using a sootblower
high temperature gases has been fully developed. carriage. The remotely insertable thermocouple is
called a thermoprobe.
Measurement evaluations
Large boilers may have significant variation in ac- Insulation and casing temperature
tual measurements at a particular measurement
plane. Where significant data variation exists, data Outer surfaces
reduction may require mathematical methods to The measurement method should be carefully se-
weight-average individual measured values during lected to avoid significant errors in measuring
the data reduction process. uncased insulation surface temperature. Portable con-
Flue gas temperature measurements at the econo- tact thermocouple instruments designed to be pressed
mizer outlet during performance tests are an example against a surface are unsatisfactory on insulated sur-
of a large number of data points which require reduc- faces because the instrument cools the surface at the
tion to a single representative temperature. point of contact, and the low rate of heat transfer
A weighted average temperature becomes time con- through the insulating material prevents adequate
suming and the need for such accuracy must be justi- heat flow from surrounding areas to the contact point.
fied. An average of the individual temperature mea- Thermocouple attachment to the insulation surface
surements is usually acceptable if a sufficient num- must not appreciably alter the normal rate of heat
ber of points are obtained. The average gas tempera- transmission through the insulation and from the
ture may be approached by increasing the number of surface to the surroundings. Fine wires can be at-
points or by instrument design to satisfy a particular tached and maintained at the surface temperature
requirement. For example, in a heat loss efficiency test, more easily than heavy wires. If the insulation is plas-
multiple measuring locations are used to indicate flue tic at the time of application, press the thermocouple
gas exit temperatures for determining dry gas loss. The junction and several feet of lead wire into the surface
number of points required by the ASME Performance of the insulation; the thermocouple will adhere when
Test Code permits efficiency accuracies within 0.05%. the insulation hardens. If the insulation is hard and
Under certain circumstances, the maximum, rather dry, the junction and lead wires may be cemented to
than average, gas temperature may be required for the surface using a minimum of cement. Fastening the
equipment protection. A moveable probe with one or wires to the surface with staples introduces conduc-
two thermocouples may be used to determine the lo- tion errors. Covering the wires with tape changes the
cation of this high temperature. For instance, during heat transfer characteristics of the surface and imposes
boiler pressurization and before steam is flowing an undesirable insulation layer between the wire and
through the superheater or reheater tubes, a bare the ambient air.
thermocouple temporarily installed in the gas stream
immediately before the tubes may be used to indicate Steel casings
the highest temperature to prevent tube overheating. The temperature of steel boiler casings may be ac-
These thermocouples are normally removed after curately measured with portable contact thermocouple
steam flow is adequate for cooling. On units designed instruments, because lateral heat flow from adjoining
for remote operation, it is possible to remotely retract metal areas quickly compensates for the small quan-
tity of heat drawn by the instrument at the contact The four steam quality measurement methods may
point. Thermocouple wires may be peened into or be summarized as follows:
fused onto the metal surface to form the hot junction.
1. The sodium tracer method, with continuous re-
Thermal contact between the lead wires and the sur-
cording of total dissolved solids in steam, is used
face should be maintained for several feet. The wire
for the highest accuracy.
installation should minimize any disturbance of heat
2. The conductivity method is useful within certain
transfer from the surface to the surrounding air. Ap-
limitations but is less accurate.
proximate surface temperatures may be conveniently
3. The calorimeter method is not suitable for measur-
measured with fusion paints or crayons.
ing extremely small quantities of carryover and
Thermometers are sometimes fastened to metal
at pressures exceeding 600 psi (4.14 MPa).
surfaces with putty. This method gives an approximate
4. Gravimetric analyses require large samples and
surface temperature indication if the metal is massive
do not detect carryover peaks.
and near ambient temperature. It is not recommended
for boiler casing temperature measurement and is
completely unsatisfactory for measuring insulation Obtaining the steam sample
surface temperature.
Through-steel components, such as metal ribs im- If the steam quality results are to be accurate, the
bedded in insulation and studs or door frames extend- instruments must be supplied with a representative
ing through insulation, cause considerable local up- steam sample. The method of obtaining a steam
sets in surface temperatures and their influence may sample and the operation of the boiler during testing
spread laterally along a metal casing. These effects are fundamentally the same for each testing method.
must be considered in planning and interpreting sur- The sampling nozzle design should be as recom-
face temperature measurement. mended by ASME Performance Test Code 19.11. It
Infrared cameras may be used to measure surface should be located after a run of straight pipe equal to
temperatures. These instruments can minimize the need at least ten diameters. Locations in the order of pref-
for complex thermocouple installations, especially if large erence are:
surface areas are to be measured. Improved equipment 1. vertical pipe, downward flow,
permits recording for further review. 2. vertical pipe, upward flow,
3. horizontal pipe, vertical insertion, and
Measurement of steam quality 4. horizontal pipe, horizontal insertion.
and purity The nozzle should be installed in the saturated steam
pipe in the plane of a preceding bend and in a position
The most common methods of field testing for steam that ensures the sampling ports directly face the steam
quality or purity are: flow. On boilers with multiple superheater supply tubes,
1. sodium tracer (flame photometry), sampling nozzles should be located in tubes spaced across
2. electrical conductivity (for dissolved solids), the width of the drum. These sampling points should be
3. throttling calorimeter (for direct determination of at no greater than 5 ft (1.52 m) intervals.
steam quality), and When a calorimeter is used the connection from the
4. gravimetric (for total solids). sampling nozzle to the calorimeter must be short and
well insulated to minimize radiation losses. Connections
Each of these methods is described in ASME Per- must be steam-tight so the insulation remains dry.
formance Test Code 19.11, Water and Steam in the When steam purity is tested by conductivity or so-
Power Cycle. The throttling calorimeter determines dium tracer methods, the tubing from the sampling
steam quality directly, whereas the other methods nozzles to the condenser should be steel (preferably
determine the steam solids content. stainless), with an inside diameter not exceeding 0.25
Most of the solids content of steam comes from the boiler in. (6.4 mm). It should be of minimal length to reduce
water, largely in the carryover of water droplets. (See also the storage capacity of the line. Multiple connections
Chapter 5.) It is customary to relate steam quality and can be run to a common line and then to the condenser.
solids content of steam by the following equation: However, these connections should be valved so that
each one can be sampled individually to isolate pos-
solids in steam × 100 sible selective carryover. Cooling coils, or condensers,
x = 100 − (6)
solids in boiler water should be located close to the sampling nozzles to mini-
mize settling of solids in the sample line.
where x equals % steam quality in percent by weight
and solids are expressed as equivalent parts per mil- Sodium tracer method
lion (ppm) (by weight) of steam or water. The sodium tracer technique permits measuring
By the use of Equation 6, steam quality can be de- dissolved solids impurities (carryover) in steam con-
termined if the solids content is known. This relation- densate to as low as 0.001 ppm.
ship is subject to error resulting from carryover of sol- Sodium is present in all boiler water where chemi-
ids in solution in the steam or in vaporized form. This cal treatment is in the form of solids. The ratio of the
effect occurs principally with silica at pressures above total dissolved solids in the steam condensate to the
2000 psi (13.79 MPa). total dissolved solids in the boiler water is proportional
to the ratio of the sodium in the steam condensate to adjusts the position of the prism. The selected wave-
the sodium in the boiler water. By determining the length is directed back to the plane mirror where it is
sodium content of the steam condensate and boiler reflected through the adjustable exit slit and lens. The
water and the total dissolved solids in the boiler wa- light impinges on the photomultiplier tube, causing a
ter, the solids content of the steam and the percent current gain which registers on the meter. The amount
moisture carryover may be calculated. The sodium of sodium in the sample is obtained by comparing the
content of steam condensate and water is usually de- emission from the water sample to emissions obtained
termined by using a flame photometer. The effect of from solutions of known sodium concentration.
any change in boiler operating conditions on carryover
is promptly indicated, facilitating problem analysis. Conductivity method
The operation of a flame photometer is illustrated
in Fig. 26. The condensed steam sample is aspirated Electric conductivity can be used to determine steam
through a small tube in the burner into the oxygen- purity in certain boilers. This method is applicable to
hydrogen flame. The flame, at 3000 to 3500F (1649 units operating with significant solids concentration
to 1927C), vaporizes the water and excites the sodium in the boiler water and with a total steam solids con-
atoms, which emit a characteristic yellow light hav- tent in excess of 0.5 ppm.
ing a definite wavelength. The intensity of the emitted The conductivity method is based on the fact that
yellow light is a measure of the sodium in the sample. dissolved solids, whether acids, bases or salts, are com-
The intensity of the light is measured with a spectropho- pletely ionized in dilute solution and, therefore, con-
tometer equipped with a photomultiplier attachment. duct electricity in proportion to the total solids dis-
The light from the flame is focused by the condens- solved. On the basis of solids normally present in boiler
ing mirror and is directed to the diagonal entrance water, the solids content in parts per million equals
mirror. The entrance mirror deflects the light through the electrical conductivity of the sample in micromho
the entrance slit and into the monochromator to the per mm times 0.055.
plane mirror. Light striking the plane mirror is reflected The condensed sample should ideally be free from
to the fiery prism where it is dispersed into its compo- dissolved gases, especially ammonia (NH3) and CO2,
nent wavelengths. The desired light wavelength is which contribute nothing to the solids content of the
obtained by rotating a wavelength selector which steam but have a significant effect on conductivity.
Fig. 27 Throttling calorimeter showing sampling tube in steam pipe. Fig. 28 Percent moisture in steam versus calorimeter temperature.
of condensed steam to complete dryness and weigh- Y = compressibility factor, dimensionless, equals
ing the residual. This can be done on a batch basis or 1.0 for most liquids and for gases where the
by a continuous sample system. pressure drop across the device is less than
While a gravimetric analysis provides an accurate 20% of the initial pressure
measure of total solids in water, its main disadvantage A = cross-sectional area of throat, ft2
is that it requires a relatively large quantity of water g c = proportionality constant, 32.17 lbm ft/lbf s2
obtained over an extended period of time. It therefore P1 = upstream static pressure, lb/ft2
does not localize carryover peaks when they occur. P2 = downstream static pressure, lb/ft2
Time lag in other methods of steam purity measure- β = ratio of throat diameter to pipe diameter, di-
ment is usually small enough to permit attributing mensionless
peaks of carryover to periods of high water level, high ρ 1 = density at upstream temperature and pres-
boiler water solids, or other operating upsets. sure, lb/ft3
Details of primary element sizing, fabrication and
Flow measurement flow calculations can be obtained from the ASME pub-
lication Fluid Meters, Their Theory and Application.
Fluid flow includes water, steam, air and gas flow.
Table 2 is extracted from the ASME Performance Test
While there are many means of measuring flow, the
Code 19.5, Section 4, Flow Measurement, to show the
basic methods for the accuracy required by the ASME
advantages and disadvantages of the three primary
Performance Test Code use the orifice, flow nozzle (flow
element types. The throat tap nozzle has the highest
tube), or venturi tubes as primary elements. The pres-
accuracy of the primary flow measuring devices.
sure drop or differential pressure created by these
The primary elements listed should be fabricated
restrictions can be converted into a flow rate.
of erosion and corrosion resistant materials. The ori-
The flow of any fluid through an orifice, nozzle or
fice and flow nozzles are shown in Fig. 29; the ven-
venturi tube may be determined by the equation:
turi tube is shown in Fig. 30.
Even though these elements can be sized with con-
2 gc ρ1 ( P1 − P2 ) siderable accuracy by calculation, they should be labo-
= Cq YA
m (7)
1 − β4 ratory calibrated prior to precision testing. Calibration
where is usually by weighed water tests using scales. For
commercial use, calculated flow rates or rates based
m = flow rate, lb/s on prototype testing or calibration are adequate.
Cq = coefficient of discharge, dimensionless, depen- Certain important factors of the primary element
dent on the device used, its dimensions and installation should be considered for accurate mea-
installation surement. These include:
Table 2
Advantages and Disadvantages of Various Types of Primary Elements
Advantages Disadvantages
Orifice
1. Lowest cost 1. High nonrecoverable head loss
2. Easily installed and/or replaced 2. Suspended matter may build up at the inlet side of
3. Well established coefficient of discharge horizontally installed pipe unless eccentric or
4. Will not wiredraw or wear in service during test period segmental types of orifices are used with the hole
5. Sharp edge will not foul with scale or other suspended flush with the bottom of the pipe
matter 3. Low capacity
4. Requires pipeline flanges, unless of special
construction
Flow Nozzle
1. Can be used where no pipeline flanges exist 1. Higher cost than orifice
2. Costs less than venturi tubes and capable of handling 2. Same head loss as orifice for same capacity
same capacities 3. Inlet pressure connections and throat taps when used
must be made very carefully
Venturi Tube
1. Lowest head loss 1. Highest cost
2. Has integral pressure connections 2. Greatest weight and largest size for a given size line
3. Requires shortest length of straight pipe on inlet side
4. Will not obstruct flow of suspended matter
5. Can be used where no pipeline flanges exist
6. Coefficient of discharge well established
1. location in the piping in relation to bends or For example, the draft loss across the gas side of an
changes in cross-section, air heater may be used as an index of the flue gas flow.
2. possible need for approach straightening vanes, Because pressure differentials vary with a change in
3. location and type of pressure taps, surface cleanliness, these are not highly reliable meth-
4. dimensions and condition of surface or piping be- ods. The use of orifices, flow nozzles, venturi air foils,
fore and after the element, or impact suction tubes in areas free of entrained dust
5. position of the element relative to direction of fluid and at relatively stable temperatures prove more sat-
flow, and isfactory. Fig. 31 illustrates two types of venturi sec-
6. type and arrangement of piping from primary ele- tions used in air ducts for measuring combustion air
ment to differential pressure measuring instrument. flow. Fig. 32 illustrates an impact suction pitot tube
Details of these requirements for precision testing are arrangement for metering primary air flow to a pul-
also covered in the ASME publication Fluid Meters, Their verizer. For a dependable determination of air flow,
Theory and Application. These devices produce a differ- the primary element should be calibrated at normal
ential pressure across the element and a differential pres- operating pressure and temperature. Test connections,
sure gauge should be used for the flow measurement. or sampling points, for this purpose are located at a
Flow measurement of combustion air or flue gas zone in the duct or pipe where good flow characteris-
generally does not require a high degree of precision. tics are obtainable, and the calibrating flow measure-
Orifices, flow nozzles, or venturis are also used, but ments are made using a hand held pitot tube or
the rigid requirements of construction and location are equivalent probe. The pitot tube, when inserted fac-
usually not possible because of space limitations. As a ing the air or gas flow stream, measures velocity pres-
substitute, a component of the steam generator, located sure, that is, the difference between total and static pres-
in the flow path, can create a suitable pressure dif- sure. The velocity pressure measurement can be con-
ferential, which is used to obtain a flow measurement. verted into a velocity reading for English units only by:
Fig. 30 Dimensional proportions of classical (Herschel) venturi tubes with a rough-cast, convergent inlet cone. (Source: ASME, Fluid Meters,
Their Theory and Application, Sixth Edition, 1971.)
Fig. 31 Venturi sections for air ducts. Fig. 32 Averaging pitot tubes.
References
1. Tower, J.R., “Staring PtSi IR cameras: More diversity, 3. Weiss, J., and Esselman, W., Electric Power Research
more applications,” Photonics Spectra, (USPS 448870), Institute and R. Lee Foster-Miller Inc., “Assess fiberoptic
Laurin Publishing Company, Pittsfield, Massachusetts, sensors for key power plant measurements,” Power, p. 55,
February, 1991. October, 1990.
2. Kaplan, H., “What’s new in IR thermal imagers,”
Photonics Spectra, (USPS 448870), Laurin Publishing
Company, Pittsfield, Massachusetts, February, 1991.
Bibliography
1986 Digital Systems Techniques, Instruments and Ap- The OMEGA Temperature Handbook and Encyclopedia,
paratus, Supplement to ASME Performance Test Codes, Vol. MMV, Fifth Ed., Omega Engineering, Inc., 2004.
ANSI/ASME PTC 19.22, American National Standards Temperature Measurement Designer’s Guide, Thermo
Institute/American Society of Mechanical Engineers, New Electric Company Inc., Saddle Brook, New Jersey, 1986.
York, New York, 1986. Also available online at www.thermo-electric-direct.com.
Manual on the Use of Thermocouples in Temperature
Measurement, ASTM Special Technical Publication 470B,
American Society for Testing and Materials, Philadelphia,
Pennsylvania, 1981.
Virtually all areas of a power plant are continually monitored to ensure efficient and reliable daily operation.