Inverse of T (T^-1) :

 S11 S 22 S 22 
 S 21  S S12 
In matrix form: inv(T )   12

  11 S 1 
 S12 S12 

m - code:
clc, clear all, close all
syms s11 s12 s21 s22;
syms T iT;
T=[1/s21 -s22/s21; s11/s21 (s12*s21-s11*s22)/s21]
iT=inv(T)
det(T)

S of T relationships:

For case a2=0 (No excit. on 2nd port ) <=> 10 cases in S&T param above def (eguations
1 _ S ,  2 _ S , 1 _ T ,  2 _ T  ) → and from:
.....1ST 
1
1TS => S 21 
T11
___________________________________________________________________________________

..... 2ST 
T21
2TS => S11  T21 S 21 and 1ST => S11 
T11

For case a1=0 (No excit. on 1st port ) <=> 20 cases in S&T param above def (eguations
 3 _ S ,  4 _ S ,  3 _ T ,  4 _ T  ) → and from:

 T12
3TS => S 22  T12 S 21 and 1ST => S 22  .....3ST 
T11
___________________________________________________________________________________

.....3ST 
S11 S 22 T12T21
4TS => S12  T22  and from: (1ST) (2ST) (3ST) => S12  T22 
S 21 T11
  T21 T12T21 
T 
 S11 S12   T11 22
T11 
In matrix form: S    ……………………………. (MST)
 21 S 22   1  T12 
 T11 T 11 

% T2S:

clc, clear all, close all

syms a1 b1
syms a2 b2
syms T11 T21 T12 T22
eqns = [a1 == T11*b2+T12*a2, b1 == T21*b2+T22*a2];
vars = [b1 b2];
[b1, b2] = solve(eqns, vars)