Professional Documents
Culture Documents
INSTRUCTOR: Assoc. Prof Dr Alina Abdul Rahim Faculty of Science & Technology
Abstract
The widespread fortification of flour with the flour treatment agents is not a new issue worldwide. The flour is
fortified with 90 mg/kg of L-cysteine that acts as a dough conditioner to reduce the mixing time and resulting in a
dough with improved pan flow while 50 mg/kg of benzoyl peroxide is used to whiten the yellowish flour as
demanded by the consumers. Enrichment and fortification of the nutrients will be conducted to compensate the
nutritional loss of the flour after the milling processes. Even though these additives are used to maintain the
desirable characteristics of the flour, the halal status and the wholesomeness of the flour are still doubtful since the
source of these additives may derived from unknown sources and can cause health problems to the consumers.
Therefore, this article offers the understanding of flour treatment agents in terms of its properties, characteristics,
usage and benefits. This paper also included future explanation on the Halal status and wholesomeness of flour
usage in food in Islam.
Keywords: Flour treatment agents, Flour, L-Cysteine, Benzoyl peroxide, Halal, Wholesome (toyyib)
Most fast product are made from white flour that may
Benzoyl peroxide has a long history of use in food contains deadly toxic chemicals. The health official
industry as bleaching agent added for flour. A premix has been warning the general public about the dangers
of 32% benzoyl peroxide and 68% cornstarch is used that will take place due to the consumption of white
in bleaching flour. The maximum amount used as flour products.
flour bleaching agent is 50 mg/kg of the flour[18].
The by-product of bleaching process which is alloxan
This bleaching agent has the advantage over gaseous may cause potential diabetes to the consumers who
agent that only a simple feeder is required, and storage consume white flour product regularly. Upon the
of chemicals present no hazard. The treated flour intake of alloxan, the free radicals will be generated in
contains traces of benzoic acid, but objection has not the body and destroy the Beta cell of the pancrease.
been raised[19]. As a result, the Beta cell cannot operate normally and
fail to produce insulin. This will then cause the
The bleaching process using benzoyl peroxide does
not affect the baking process to any marked degree. consumers to be affected with insulin-dependent
However, it has the disadvantage that the reagent used diabetes[23]. Unfortunately, the Food and Drug
(benzoyl peroxide) is mixed with the flour in such Administration (FDA) still allows companies to use it
minute amount that even distribution throughout the in the foods we eat.
flour mass is difficult to obtain[20].
In other occasion, people might want to be aware that The flour also has to be fortified with iron since it is
the concentration of benzoyl peroxide varies with eliminated during the milling and bleaching process.
other countries. As mention above, the concentration The iron used in the fortification should be derived
of benzoyl peroxide in Japan is 300 mg/kg which from appropriate source. The source of iron may be
exceeds the permitted amount (50 mg/kg). The flour derived from encapsulated iron salt, Iron EDTA and
used in Japan might become toxic as the benzoyl elemental iron powder. Each of these iron source will
peroxide concentration is very high and may lead to show different bioavailability or the degree to which
the toxicity of flour. We must be careful in choosing the body can absorb and utilize a particular mineral
our flour that is free from toxic, wholesome and source[26]. The sources of iron for flour fortification
considered safe for consumption. is summarized in Table 3.
Extraction from Human hair and -Extraction of cysteine via -Low yield -Commercially [9], [10]
protein hydrolysate animal feather electrolysis from keratin used in food
-unpleasant odour industry especially
-Decolourizing of mixture in China
with activated charcoal -waste treatment is
necessary -May impose
-Filtration and Halal issue
concentrating the filtrate
-Crystallization at proper
temperature
Fermentation of Direct fermentation There have been two Cysteine -SAT that is less [12]
glucose from glucose approaches to obtaining an degradation in sensitive to
SAT that is less sensitive to media feedback
feedback inhibition: The inhibition is used
engineering of SAT from E. in this study
coli through site directed or
random. The use of the -May also impose
natural SAT, which is halal issue if the
desentisized from higher culture medium
plants contains enzyme
from unlawful
animal.
.
TABLE 2: Isolation and Purification Process of Cysteine. Adapted from Boehm [17]
Process/Method Detail procedure Drawback/weakness
Isolation of soluble cystine in purified L-cysteine is reduced from complex Complicated and cysteine must
form mixture or appropriate fermenter be prepared in two- stage
broth to give L-cysteine via electrolysis process via intermediate cystine
Direct isolation of cysteine from a -Cystine and inorganic salt are Limited to the solution that
solution containing cysteine, cystine, crystallized at 20°C by adding hydrogen contained serine, cysteine,
serine and inorganic salt chloride and removed by filtration. cystine and inorganic salt.
-Remaining solution contains cysteine Low yield and low purity
Ion exchange chromatography -Fermenter broth comprises of an Simple, cost effective and
oxidizing agent, cysteine binding to an applicable for industrial
ion exchanger and form ion exchange application
as an eluent
Encapsulated iron -There are coated -Have fat coating -The product may have Thoyyib
salts forms of ferrous that protect them large particle size
sulfate and from chemically causing them to be
ferrous fumarate reacting with removed from flour
available unsaturated fat. during the final sifting.
Iron EDTA -The iron is -Prevents the iron -High tendency to Thoyyib
chelated with from being bound to cause colour change in
EDTA phytic acid and food.
maximize the
absorption of iron. -More expensive
compared to other
-Does not promote source of iron
lipid oxidation. fortificant.
Elemental Iron -Most common -Low cost -May damage the flour Less thoyyib
powders used as source of due to the presence of
iron fortificant. tramp iron
-Can be detected
by magnets and
metal detector
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