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Learning about water chemistry is often avoided by most aquarium owners, but by knowing just
the basics of water chemistry, you can greatly improve your success in rearing healthy fish. Most
aquarium owners are aware that the quality of water has a direct impact on the health of their
fish. But many aquarium owners do not understand the basic internal chemistry of their fish's
water, nor do they understand how to correctly or safely adjust it. Until the basics of water
chemistry are mastered and some common water maintenance techniques are learned, it will be
difficult to maintain a healthy and safe environment for the fish in your tank. The water quality is
by far the single most important factor in the health of your fish, and the more you know, the
better job you will do. This article provides a brief overview that is just the bare minimum that
aquarium owners should know and understand.
Fish obtain their basic necessities from the water in which they live. The most
characteristic feature of any aquarium system is therefore the quality of the water it contains.
This water must be obtained from some source, pre-treated to make it suitable for the fish,
delivered to the fish in sufficient quantities and maintained in good condition. Finally, it must be
disposed of. The water supplied to an aquarium is not pure, but contains dissolved and
particulate materials, some are necessary for the well-being of the fish and others are harmful.
Contamination may occur not only at source or form the animals, but often takes place within the
aquarium form the materials used in its construction. The volume of water supplied to an
aquarium may at first sight, seem to restrict the number of fish that can be maintained within it.
However, it is rarely the quantity of water per unit which limits the carrying capacity. The
capacity is usually set by the consumption of dissolved oxygen and the accumulation of toxic
metabolic products.
pH
Every aquarium owner has heard of pH, but many do not understand the importance of
controlling it. pH is the measure of acidity or alkalinity in the water. The pH scale is from 1 to
14. A pH of 7 is neutral, which means the water is not acidic or alkaline. As the scale goes down,
for example 6, the water becomes more acidic. As the pH goes up, for example 8, the water gets
more alkaline. One very important part of the pH scale what most people do not understand is
that it is a logarithmic scale. What this means is that the pH changes at a tenfold level between
each number. For example, a pH of 5 is 10 times more acidic than a pH of 6, and a pH of 4 is
100 times more acidic than a ph of 6. So if your fish are supposed to be at a pH of 7, and the
water level is 8, they are in water that is 10 times more alkaline than what they should be. If the
pH is 9, then they are in water that is 100 times more alkaline than what they need. So it is easy
to see why even a small change in required pH is stressful and potentially fatal to fish.
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Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
These examples really emphasize the importance in matching your fish closely to the
expected pH level of your water and then closely monitoring the pH. Putting a fish that requires a
pH of 8 with a fish that requires a pH of 6 is just not a good idea because one or both will be at a
very unacceptable level of pH and will be under a great deal of stress.
There are several different ways to influence your water's pH. There are chemical
additives that can be added directly to the water that will either raise or lower the pH. More
natural agents can be used to alter water pH as well. Peat in the tank or filter will acidify the
water. Mineral salts like calcium that are found in limestone or in some shells will cause an
increase in alkalinity and pH. There is one important consideration in altering the pH of water
and that relates to the mineral content (hardness) of the water. Remember that fish are very
sensitive to changes in pH, and rapid changes in pH can cause extreme stress and death. Fish
should not be exposed to a change in pH greater than 0.3 in a 24-hour period.
Tap water is usually alkaline. Always test tap water pH prior to making freshwater
aquarium water changes, and adjust as required. Marine aquaria should be maintained at a level
of 8.2 to 8.4.
Dissolved oxygen:
The majority of aquatic organisms need oxygen and must obtain it from the surrounding
water. The oxygenation or aeration of the water is therefore, of fundamental importance in any
aquarium, especially as the oxygen supply is one of the factors which may ultimately limit the
capacity of a particular volume of water for carrying fish.
The oxygen dissolved in water comes from two main sources: the atmosphere and green
plants. The actual content is a function of temperature, salinity and atmospheric pressure. Low
temperature, low salinity and higher atmospheric pressure favours more gas content (thereby
more oxygen) in the solution (water medium).
Aeration: Continuous aeration is very good husbandry since it mixes the water, supplies the
oxygen for the fish, removes carbon dioxide and maintains a constant temperature throughout the
tank. Many cheap air pumps are available in the hobby trade, though they are often noisy, are of
limited power and many frequently fail. If only one or two tanks are required, such vibratory
diaphragm pumps are acceptable, but a spare pump and several replacement diaphragms should
be stocked. The pump should be mounted above the tank level or the air-line fitted with non-
return valve to prevent back-siphoning when the pump is stopped or fails. A loop in the air-line 8
cm (3 inch) vertically above the tank’s water level will also prevent back-siphoning by absorbing
the oscillations when the airflows stops. The air tubes from the pump are connected to air stones
for providing minute air bubbles that diffuses the oxygen in water. Besides that it is also
connected to various types of toys and also for airlift pumping under for under gravel filtration.
For diffusion of more oxygen in water a micro pore air stone gets priority during selection of air
stones.
11
Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
in colour and grasping at the surface layer. Acute toxicity levels = 0.4 ppm NH3. Chronic toxicity
levels = 0.05 ppm. This is common in new aquarium when immediately stoked to full capacity.
Ammonia can damage the gills at a level as small as 0.25 mg/lt. For immediate removal of
ammonia, use ammonia detoxifier such as Kordon's Amquel. Kordon Amquel removes ammonia,
chloramines, chlorine, and many other organic toxins. Completely non-toxic, contains no
formaldehyde, and will not affect dissolved oxygen levels. One teaspoon treats ten gallons.
However, it is best left alone until the bacterial load is sufficient. Note that the bacterial phases
will not take place unless the tank is initially stocked with feeder fish which can be removed
after treatment. Test the water until the ammonia drops to nearly zero. At this time, we should
notice an increase in the nitrite level. When the nitrites are gone, it will be safe to add fish.
The conversion of the more toxic nitrogenous compounds to less toxic compounds is
achieved through organisms residing in water treatment units such as filters. In some aquaria,
algae are also used in nitrogen recycling. The process of combating the effects of nitrogenous
waste products is facilitated by low stock density, a high water turn over, aeration or oxygenation
of the water, frequent cleaning, removal of feces and waste food and by the provision of special
water treatment facilities.
1. First, the waste from fish, plants, and food breaks down and releases ammonia.
2. This ammonia is very toxic to fish and must be converted by bacteria to nitrite.
3. The nitrite is also toxic to fish and must then be converted to nitrate.
4. The nitrate is not nearly as toxic and is taken up by plants or algae and used to help them
grow.
Ammonia is the most toxic product formed in water. Sources of ammonia in aquarium
water are fish respiration and digestion and decaying foods. Freshwater fish begin to be stressed
at levels of 0.50 ppm (parts per million). Marine aquaria levels should be less than 0.05 ppm.
Nitrate, nitrite, and ammonia are also removed through the weekly water changes.
Because high levels of ammonia and nitrite are lethal for fish, it is critical that these products be
efficiently removed or converted to nitrate.
Maintaining a population of bacteria that can convert ammonia and nitrite is an important
part of the water chemistry, and the process is known as biological filtration. Biological filtration
will occur naturally in most tanks that have been up and running for a couple of months. The
better filters often contain a special area or wheel that is made specifically for providing an
optimal habitat for growing these bacteria. While the bacteria will live in a traditional filter and
on rocks etc. in the aquarium, the new filters harbor a much higher number and can therefore do
a better job of removing ammonia and nitrites.
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Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
If a fish tank is overcrowded, or the waste level gets too high through overfeeding or
dead fish etc., even a properly functioning biological filter can be overwhelmed and toxic
conditions can result. Periodically checking the ammonia and nitrite levels in your tank with a
test kit will ensure that your biological filter is working correctly. Tanks that have a healthy plant
population will also aid in the removal of nitrates. Because it takes weeks to months for a tank to
grow a healthy population of bacteria, it is important that a tank be allowed to age before fish are
added. After the tank ages several weeks with only a few hardy fish, more fish can be slowly
added over a couple of months to make sure the biological filter is not overloaded.
High levels of nitrate can be present in the water of wells contaminated from fertilizer,
agricultural runoff, or sewage. These nitrates are dangerous to humans as well as livestock.
Nitrates can be removed by reverse osmosis or specialized nitrate removing chemicals.
Water Temperature:
While not considered chemistry, water temperature needs to be mentioned. Fish are cold
blooded, which means they cannot raise or lower their body temperature and their body
temperature will be the same as the water around them. If a fish is kept outside of their normal
temperature range they will become stressed and become diseased or die. The majority of fish
are tropical, which means they come from tropical climates with water temperatures around
75ºF. Even cold water species such as goldfish cannot handle very cold water or sudden changes
in temperature. Know your species of fish and their temperature requirements.
Temperature is perhaps the most potent of all the environmental factors controlling and
governing the metabolism of animals. Water has a high thermal capacity compared to air; that is,
it can absorb a large amount of heat energy for a small rise in temperature. It, therefore, provides
a thermally stable environment.
In aquarium, fish are largely denied the use of any behavioural regulation, and the
aquarium design and management must compensate for this loss. Sudden change of temperature
in the aquarium should be avoided. Such as thermal shocks are most likely to occur when fish are
transferred from tank to tank or when they first arrive in the aquarium complex. A simple rule is
to float transfer containers plus fish in their new tanks until the temperature has equilibrated or
alternatively to slowly mix the water in the container with that in the tank over half an hour or
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Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
more. Increases in temperatures have the most distressing effect since respiration rate and
excitability increase while the oxygen-carrying capacity of the water decreases. Such
temperature increase in established tanks may result from refrigeration breakdown or thermostat
malfunction. The damage caused by faulty thermostat in a heated system can be minimized by
employing the minimum wattage heaters required for the temperature control or by including a
high temperature cutout in the circuit. This could simply be a second thermostat in series with
the first, but set to a slightly higher temperature so that it is on all the time during normal
operations. Such a thermostat should, however, be serviced regularly to ensure it does not stick
on.
During winter months necessary heating arrangements may be made for tropical
aquarium fish. A water heater of 5-6 watts capacity is required per gallon of water. Heating
equipment of the aquarium is basically an electric heating coil complete with thermostat to
control it both contained in glass tube. This submerged in the aquarium, connected to the
electricity supply and the built-in neon indicator. A thermometer is always kept inside the
aquarium to monitor the temperature. It is placed at the front where it can be easily seen. It is
best arranged heater and thermostat at opposite corners of the tank to get correct temperature
readings of the aquarium water.
Water hardness
Water hardness is often confusing and therefore overlooked by many aquarium owners.
Water hardness is important because it is closely related to pH and, just like pH, fish have certain
levels of water hardness that they thrive in, and if the hardness is too far off, it can cause stress
and death. Water hardness can be most simply described as the level of mineral in the water.
Hard water has a lot of dissolved mineral, and soft water has very little dissolved mineral in the
water. The most common mineral in water is calcium. However, other minerals can also be
present. Most people's tap water is either slightly hard or soft depending on where it comes from.
Well water from areas that have a lot of limestone (calcium) is often hard. Water that comes
from lakes (rainwater) is often devoid of mineral and is soft. It is important that you know the
hardness of the water that you use in your fish tank. Some species of fish require hard water and
others require soft water.
The other reason that hardness is important is that it affects pH. Hard water (high mineral
content) is usually high in pH. Soft water (low mineral) is usually low in pH. The mineral in hard
water will act as a buffer which will reduce the amount of acid in the water. The resulting water
will be more alkaline and higher in pH. The problem arises when we try to lower the pH in hard
water. If we add a commercial pH decreaser to an aquarium that is filled with hard water, the
mineral in the hard water will buffer the water and make it difficult to successfully lower the pH.
We would first have to remove the mineral from the water before we could effectively lower the
pH. The same is true for trying to raise the pH in acidic water that is soft and does not contain
much mineral. Until we add mineral to the water, it will be difficult to successfully alter and
maintain a high pH level. So what do we do? Well, it is not too hard to add mineral in the form
of calcium based rock, so making soft water hard and more alkaline (higher in pH) should not be
too difficult. To soften hard water, you need to take the mineral out with a water softener, reverse
osmosis or a specialized chemical that irreversibly binds up the mineral. Another option is to find
a source of demineralized water for your fish tank (rain water is soft in nature).
Of course the alternative to all of this may be to tailor your fish and plant species around
your existing water source. For beginning aquarist this may be the best solution. There are a wide
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Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
variety of tropical fish available and it is not difficult to find at least a dozen different species for
every different type of water. Any decent book on aquariums and tropical fish will list the
individual pH and hardness requirements of the different fish species. If the water is too hard for
your specific application (such as breeding certain species), simply mix it with deionized water
until the required hardness is obtained. Most hobbyists don’t feel the need to measure this
particular water quality.
Chlorine
Chlorine is commonly added to water supplies to disinfect the water (to kill bacteria) and
can be harmful to fish. It is lethal to fish at 0.2 - 0.3 ppm. It can be removed with chemical
chlorine eliminators (by adding hypo @ 1 g per 5 lit of water) or by aerating the water in a tank
over night.
Phosphates
Phosphate is a salt, commonly found in tap water, which serves as an algae nutrient.
Maximum phosphate levels are 2 - 3 ppm with less than 0.05 ppm being ideal. Reef tanks should
be maintained at less than 0.05 ppm.
Importance of Water quality management in aquarium
Nothing is more important in aquarium keeping than water quality management. There
are many excellent products available out there to assist in water quality management, but there
is still no replacement for water changes, good filtration, and good feeding habits.
Water Changes:
Changing water in more frequent, smaller amounts is preferable to larger less frequent
changes. Make sure the water going in has the right chemistry (pH, etc.) and temperature.
Weekly water changes are probably the most important part of maintaining good water quality.
Weekly water changes of around 15%-20% of the total water volume will correct many potential
problems in water quality. The water changes will bring fresh mineral rich water into the tank.
The fish, plants and bacteria use up the trace minerals in the water and by adding new water
weekly you replace these minerals. By removing water you reduce the amount of nitrate and
ammonia that builds up in the water as well. Weekly water changes also help remove other
toxins or pollutants that can build up in the tank. If a siphon with a gravel cleaner is used the
gravel can be cleaned and uneaten food and fish and plant waste can also be removed. This keeps
the ammonia levels down and the water cleaner. (If you have an under gravel filter or a filter
system that does not have a biological filter you may not want to disrupt the good bacteria by
over cleaning the gravel).
Remember that most tropical fish live in environments where currents or rainfall
regularly bring fresh water and remove waste. By providing weekly water changes we help to
simulate this natural and much needed requirement. An important note about water changes is to
make sure the total does not exceed a third of the water volume. It is also important that the
water that is added is free of chlorine. Otherwise use a declorinator (sodium thiosulfate), if
chlorine or chloramines are present. (Wonder shells remove chlorine, stabilize KH, and add
electrolytes). Water changes are important for Nitrate removal and buildup of toxic organic and
inorganic material.
Routine partial changes of the water are necessary to dilute the build-up of soluble
materials (due to accumulation of fecal and unfed materials). Evaporation losses should be
replaced by suitable water (artificially prepared or natural). The cleaning can be done by hand;
15
Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
the hands should be washed with shop, after the job and not before because of the danger of
introducing soap into the water. Use scraper for algae on glasses. The toys, air stones and other
equipments, which have the algae and other sediment attachment, should also be cleaned. Plants
should be trimmed and decaying leaves should be removed regularly at the time of water
exchange.
Temperature 17-380C
pH 7.0-8.5
CO2 < 5 ppm
Alkalinity 75-250 ppm as Ca CO3
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Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
Hardness 50-200 ppm as Ca CO3
Dissolved oxygen 5.0-10.0 ppm
Free ammonia <0.05 ppm
Ionised ammonia <0.1-0.4 ppm
CAUTION
Adjustment and/or corrections to existing water chemistry MUST be made gradually.
Stability is as important as water quality.
Biological Filtration
Biological filtration is the term used to describe beneficial bacteria, which is established
during the initial cycling of the aquarium. These bacteria break down ammonia and nitrite and
convert them into the less toxic compound nitrate. It is widely acknowledged throughout the
aquatic community that these bacteria require a surface to attach and oxygen rich water.
Biological filtration is essential and needs to be adequately established in every
aquarium.
It is recommended to medicate fish in a separate tank (hospital tank) when using
antibiotics (anti bacteria), as extensive use of these medications will kill the bacteria.
Live rock and sand are by all means biological filtration as well. In theory you could maintain an
aquarium with these alone, however the tanks fish population would be restricted to small
numbers. Always keep in mind, that biological filtration requires oxygen. An inadequate or
interrupted supply will result in the failing of your biological filtration system
Saltwater tanks can be successfully maintained using only a protein skimmer and
biological filtration.
Chemical Filtration
Chemical filtration removes dissolved wastes. The most common type of chemical
filtration is activated carbon. Others, such as Algone absorb ammonia, silicate, phosphates and
so on. Carbon has established itself as “a must have” in the aquarium. Still, be aware that some
carbons leach phosphates. Another media for chemical filtration consists of zeolite, which will
delay or disrupt biological filtration, especially during the cycle.
18
Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
Mechanical Filtration
Mechanical aquarium filtration removes solid particles from the water via the aquarium
filter. It does not remove or convert ammonia, nitrite or nitrate. This filter type actually provides
a means to remove free-floating waste before it decays. Mechanical filtration will only be
beneficial if the filter material is replaced every 2-4 weeks because the waste will still decay
while trapped in the filter material. To save money on replacements, you can also rinse the filters
in use or use an alternative filter such as filter floss, which costs only a fraction of replacement
cartridges.
Common types of filter media are paper cartridges, sponges, and floss. Mechanical
filtration will be ineffective on matter that settled in the gravel. Use a siphon to remove these
particles. Kill two birds with one stone – siphon during water changes! Be aware, that beneficial
bacteria will settle on the filter media. Take this under consideration, and replace part of the
media at a time if it’s possible. Sponges will clog quickly and paper even faster. Filter floss is
very efficient due to small and large openings, which will not clog as easily. Another benefit of
floss is that you can easily do a partial change, reducing the amount of bacterial settlements that
are removed.
AQUARIUM FILTERS
Corner Filter
Water is forced through it. On the inside you would find filter floss or other
media. It is mainly a physical/mechanical filter. Beneficial bacteria settle on the
medium and provided biological filtration. This very inexpensive filter is an
excellent way to set up a hospital tank. Buy one for pennies on the dollar and
use some gravel from your established tank. You will immediately have a
working biological and mechanical filter for your hospital tank.
Canister Filter
Basically an enhanced corner filter. A closed box where water is forced
through filtration media (mechanical and/or chemical). It can be placed inside the
aquarium, or outside (underneath the aquarium or as hang on type). The canister filter
has the most powerful mechanical filtration system, and can be used with messy
eaters. The down side is that it requires frequent cleaning. Bacteria will also settle in
this filter type. Biological filtration can be improved, by placing wet dry wheels at the
outflow of the canister filter.
Power Filter
The very easy to maintain power filter hangs on the back of the aquarium (easy access).
Water is pulled through a mechanical filtration, using floss and insert cartridges. They
also provide enough space for chemical filtration media. Within the last few years a wet
19
Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
dry wheel (biowheel) was developed, to provide an even larger area for bacteria to settle. Wash it
once in a week. Cost: Rs. 400-1000/-
Protein Skimmer
The protein skimmer is a chemical filtration method. It takes out dissolved
biological waste before it can decompose. This is achieved by a tubular design with air
bubbles inside. The waste is attracted to the surface of air bubbles, which then rises to
the water surface. There, a skimmer removes the biological waste. This filtration type
has revolutionized reef tanks. It only works with high pH and salinity. This filter is for
salt-water use only.
Sponge Filter
A sponge filter looks like a tube with a sponge like material inside. As water flows
through, bacteria will colonize the porous foam and establish a biological filtration.
These sponges also serve as a mechanical filter, removing larger particles from the
water. The advanced versions use two sponges, making it easier to preserve bacteria
colonies by replacing the sponges at different times. Using a sponge from an
established aquarium can also jump-start a new tank or quarantine/hospital tank.
Undergravel Filter:
The undergravel filter (UGF) is basically a perforated plate below the gravel.
Water is pumped upward through the gravel by air bubbles, water stream, or a
combination of both. This slow flow of water and oxygen allows the bacteria to
colonize the gravel. The UGF is an aid for biological filtration. It does not remove
larger waste particles. It has to be well maintained, especially through vacuuming of
the gravel. UGF’s are inexpensive, but have a tendency to clog up. It is
recommended to replace this filter as they age. Of course, they can be combined with a power
head as a pre-filter for larger particles.
Wet–Dry Filter:
Also known as trickle filter. This kind of filter was designed with consideration of the
oxygen demand of beneficial bacteria. It consists of a plastic tube with unsubmerged
media (floss, bioballs etc.) over which water trickles – hence “Trickle Filter”. The wet
dry filter provides a large air to water surface. The larger the surface structure of the
20
Enterprenurship Development in Ornamental Fish Breeding and Culture
B. K. Mahapatra, Subhendu Datta, G. H. Pailan, S. Munilkumar and S. K. Mishra
Published by Director, Central Institute of Fisheries Education, Mumbai, India on 25 thAugust, 2012
media gets the better it works. This filter provides no mechanical filtration and works on the
principle of the wet dry wheels.
****
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