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SYNOPSIS
The distribution of gold loaded ont.o carbon particles from a carbon-illi>ulp operation was measured by neutron-
activation analysis. The nature of the distribution is examined, and the implications for operating plants and CIP
simulators are discussed.
SAMEVATTlNG
Die verspreiding van die goud wat in 'n koolstof-in-pulpbewerking op koolstofpartikels ~el.aai !s, i~ de~r
neutronaktiveringsanalise gemeet. Die aard van die verspreiding word ondersoek en die Imphkasles Vir
bedryfsaanlegte en KIP-simuleerders word bespreek.
Journal of the South African Ins~tute of Mining and Metallurgy JULY 1992 177
8 hours, the transfer being regulated mainly by the TableI
requirement to maintain the target carbon concentration in Size and m.1 dll1rlbutlonl of carbon particles
each contactor. Regenerated carbon is added when its Size (D) Mass (m) Mass fraction Comment
preparation is complete-ideally before the loaded carbon mm mg smaller than
has been removed. The addition takes about half an hour. Dorm
178 JULY 1992 Journal of the South African Institute of Mining and Metallurgy
0,99
,
0,9 0,93 I
0,8 0,95
It
0,7 0,9
V
!:I 0,8
V
S'~
~~ 0,8
...~ . 0,5 Sd
... rot 0,4
~.
;~~g 0,3 ..~
~:=:
0,7
0,6
0'" ~i
jj 11'2
0,4
.
0,1
~e. 0,3
.-
"'A.
.
:I
0,05'
0,02
i
0,2
0,1
0,01
. free-.. U_M. 0,05
A tree .0., 1..\1'andy.h
0,01 0,02
0,6 0,8 1 3 5 6 7 8
The distribution results are presented in Figure 6 in a way particles that is highly loaded in a sample of loaded carbon.
that indicates the proportion of highly loaded particles. The (Highly loaded particles are any that have a loading greater
diagram indicates, for example, that about 30 per cent of than twice the mean.) The loading, y, on a particle
the gold is found on particles that have a loading greater influences the rate of adsorption, ra, through expressions
than 5000 g/t. To complement this information, the with forms similar to that of equation [2]. The rate of
distribution of particle mass according to gold loading is elution is the negative of the adsorption rate. Other
also shown in the diagram. From this curve, it can be seen expressions for adsorption and elution rates are given
that particles with loadings of more than 5000 g!t constitute elsewhere8-11.
about 11 per cent of the mass of the carbon.
rg = k (c - (yla)b), [2]
SIGNIFICANCE OF THE FINDINGS where c is the gold concentration in solution, and a, band k
are constants.
Adsorption and Elution Equation [2] illustrates a common feature of adsorption
The distribution results are of interest from a practical expressions namely, that the higher the gold loading on the
point of view in that they indicate the proportion of the carbon, the slower is the rate of adsorption. However, high
8,0
7.5 2.~
7,0
6,5
.-
r
~ 6,0
::
50S
.
.(.:.- 2 I
5,0
. - GI
N
m 4,S
.!I 4,0
, t
01
.a-' . ..'....
...",.~ ..
Po Po
2,5
2,0 ....
. 410..
1.5
.,s
1,0
~5
0,0
J'.. ~
.. I .\ '.,... -
.."~~".,.,~
~..~~ .-". .: :-' -.-:... .
.,.., ..: . -
.
.
I':S
I0,8
0,6
0 2500 sooo 7'100 10000 I~OO 11000
Gold loading (g/t)
Agure 2- The distribution of gold Ioadings on the particles of a sample of loaded carbon
Journal of the South African Ins6tute of Mining and Metallurgy JULY 1992 179
Ma.. d8naity (maa. f~ction p8r g/t interval) z 10'
loadings favour rapid elution.
400
A second factor that is important in the influence of gold
loading on the rates of adsorption and elution is intra-
particle diffusion. The value of the mass-transfer
""
200 I
I~ ~ coefficient associated with intra-particle diffusion is likely
to decrease as a greater proportion of the loaded gold is
found in the more inaccessible pores and adsorption sites
within the carbon particles. The greater the gold loading on
100 i
I
I
H~ '- --
the particles, the higher is this proportion likely to be. This
means that, in adsorption circuits, the adsorption rate on
/ *
~---;---,--, very highly loaded particles is likely to be inhibited both by
0 the magnitude of the gold loading and by a reduced mass-
2 3 4 5 6 7 8 9
°
C:Old Loading (kg/t)
transfer coefficient. In elution circuits, the elution rate from
such particles is likely to be inhibited by the reduced mass-
transfer coefficient.
Figure 4-Dlstrlbutlon density of gold Ioadlngs on a loaded The implication of these observations is that the
carbon proportion and size of the particles that are highly loaded is
likely to have some impact on the adsorption and elution
rates. Figure 6 shows that the proportion of highly loaded
carbon is significant, and that a considerable proportion of
Ma.. r~ction the gold is loaded on such particles. The diagram shows
that about 30 per cent of the gold was loaded on 11 per cent
Ma.. fn..U... of vold
~.--~- of the carbon in particles that were highly loaded; that is,
;/~ with loadings greater than twice the mean.
0,8 00 parti.h. with 81.. < 0 /
/
/
/ Figure 6 also shows that fully 22 per cent of the carbon
/
0,6 / particles have loadings that are less than half the mean
/
/
..
loading. The extent to which these particles are under-
/
/
/ utilized can be appreciated when it is seen that they account
0,4
/ for only 7 per cent of the gold.
{/
Figure 7 shows the size distributions of carbon particles
0,2
,/< with high and low loadings. This indicates that all the
..-" Ma.. frocU of parUcl.. ..1th .10. < 0
~.~ highly loaded particles were smaller than 1,54 mm,
0
0,5 0,7
whereas 40 per cent of the particles with low loadings were
0,9 1~1 1!3. 1!5 1,7 1,9 ~1 2,3 2,5
larger than that. No particles larger than 1,84 mm were
Particl. Bb. (ilia)
highly loaded; 16,3 per cent of the carbon fell into this
category and had a mean loading of 1930 g/t.
Figure 5-Dlstrlbutlon of gold and carbon particles according Influence of Operating Practice on Distribution
to particle size Stange and King! simulated the effect of the amount of
carbon transferred on the distribution of gold loadings in a
particular CIP adsorption circuit. Figure 8 shows, for three
0,8
'"\
\
\ -
Dis1ributlon
Geld
01
-
-E-
loading> 5303 g/t
lDodIng ..1326 g!t
'\ - 0- Parlid8s 0,8
\
\
0,6 \
\
j. 0,6
,
\,
0,4 , -
0.,4
".'
0,2 """;-".-
------.--- 0,2
--.--------
0
0 2 3 4 5 6 7 8 0
C:Old Loading c; (ltg/t) 0,4 M 0,8 1,2 1,4 1,6 1,B 2
Particl. Bb. D (-)
180 JULY 1992 Journal of lie South Amcan Institute of Mining and MetaRurgy
Ma.. d8l18ity (ma.. fraction per 'lItloadinq intarval) Maa. denaity (maa. fraction per 'lItinterval) ..106
400
i\
',022 \
I
8,G20
G,DIt 300
1 \\
, I
ot carbon inventory transterred
D,tll
- ,00& / \
G,D14
200 I \
0,012
). \
\
D,tlD /\ \
G,DOI
i
! 100 \\
G.DDI
D,DDI
I
I
i
I
\,
0
~'-- -"---...
-
,
0,1101 i -\:~-- ,...~---- 0 2 4 6 8 10
I "","--"" ---~,-----
G.ooo
,
L/ "'--"-"' ._-:~-~~_:~.:~:::::-;::::.",~- Gold Loadinq (kq/t)
1000 2000 JOOO
.~
A
Journal of the South African Institute of Mining and Metallurgy JULY 1992 181
CONCLUSIONS REFERENCES
The gold loading on a sample of loaded carbon taken 1. STANGB, W., and KING, RP. A population balance approach to the
from a typical South African CIP operation, as measured by modelling of the CIP process. Proceedings of APCOM87. The 20th
International Symposium on the Application of Computers and
neutron-activation analysis, was 2582 g/t. The values for Mathematics in the Minerals Industries. King, R.P., and Barker, LJ.
individual particles was found to vary by factors of (eds.). Johannesburg, 1987. vol. 2, pp. 209-221.
between 0,18 and 5,4 of the mean. The results showed how 2. F'LHMING,C.A., and NI(x)L, MJ. The adsorption of gold cyanide onto
the gold loading on particles varied from one to another, activated carbon. Ill. Factors influencing the rate of loading and equi-
the distribution being essentially un i-modal and of log- librium capacity. J. S. Afr.lnst. Min. Metall.. vol. 84, no. 4. 1984. pp.
normal form. The expected inverse relationship between 85-93.
loading and particle size was conf1ll1ledand quantified. In 3. Ltm1!RMAN, RD., QUON, J.E., and GBMMBL,R.S. Fihn transport coef-
addition, the way in which the gold was distributed ficient in agitated suspensions of activated carbon. J. Water Pollution
Control Federation. vol. 46, no. 11. 1974. pp. 2536-2546.
according to particle size was established, as well as the
4. STOCH, H. Manual of the analytical methods used at Mintek.
fraction of the loaded gold that is found on particles with Johannesburg, Mintek, 1986.
given loadings.
5. CASHION, J.D., McGRATH, A.C., VOLZ, P., and HALL, J.S. Direct
From the results it is possible to assess how much of the analysis of gold species on activated carbon by Mossbauer spec-
gold occurs in small highly loaded particles that could troscopy. Trans.lnstnMin. Metall., Sep. 1988. pp. CI29-CI33.
impair the oerformance of the adsorption and elution 6. JONES, M.H., MAcRAB, c.M., SPARROW, G.J., and WOODCOCK, IT.
processes. Such particles would have lower than expected Distribution of organics and gold on the external and internal surfaces
adsorption rates before they are removed from the of activated carbons from CIP plants. Aus IMM Bul and Proc.. vol.
293, no. 6.1988. pp. 121-126.
adsorption circuit. In addition, some fraction of the gold in
these particles is likely to be found in the smaller pores of 7. ERASMUs, C.S., SBlLSCHOP, J.P.F., and WATIERSON, ]l.W. Newevi-
dence on the composition of mineral grains of native gold. Nucl.
the carbon and so may be less accessible to elution. What is Geophys., voU, no. I, 1987. pp. 1-23.
revealed is that, for the sample analysed, about 11 per cent
8. WooLLACOIT, LC., STANGB,W., and KINo, RP. Towards more effec-
of the carbon containing 30 per cent of the gold falls into tive simulation of CIP and ClL processes. 1. The modelling of adsorp-
this category. The adsorption and elution kinetics would be tion and leaching. J. S. Afr. Inst. Min. Metall.. vol. 90, no. 10. 1990.
improved if the operating practices were modified so as to pp. 275-282.
reduce the proportion of carbon that is loaded in this way. 9. V AN DBVBNTBR, J.S.J. Kinetic model for the adsorption of metal
The influence of the transfer scheme on this proportion and cyanides on activated carbon. Ph.D. thesis, University of
Stellenbosch, 1984.
on the distribution of gold loadings is best assessed by
simulation. The measured results were not inconsistent with 10. LE Roux, J.D., BRYSON, A.W., and YoUNo, B.D. A comparison of
several kinetic models for the adsorption of gold cyanide onto activat-
the simulator predictions reported by Stange and King, and
ed carbon. J. S. AIr. Inst. Min. Metall.. vol. 91, no. 3. 1991. pp. 95-
lend some qualitative support to their approach. It therefore 103.
seems reasonable to use their technique as a means of 11. VAN DBR MBRWB, P.F, and V AN DBVBNTBR,J.S.J. Generalized simula-
exploring how a given carbon-transfer scheme can be tion of Zadra and AARL elution columns. Proceedings 14th CM!
modified to improve the gold-loading distribution. Conference, Edinburgh, Jul. 1990.
182 JULY 1992 Journal of /he South African Institute of Mining and MetallulflY