SAFETY DATA SHEET

(Safety Data Sheet)

Recorded in the Register

SDS No. 6 3 1 2 1 8 3 9 . 2 4 . 3 9 6 0 8 dated October 12, 2015

Valid before October 12, 2020
Rosstandart
Information and analysis centre
Safety of substances and materials Director signature / A. A. Toporkov/
FGUP VNII SMT L.S.

NAME:
technical (according to a Atren-Light Chemical Filler for Light-Weight Cement Slurries.
regulatory document)
chemical (according to Not available
IUPAC)
Atren-Light Chemical Filler for Light-Weight Cement Slurries.
trade
synonyms Not available
ARCCEO FTCC code:
2 4 5 8 6 0
code: 3 8 2 4 4 0 0 0 0 0
2
Symbol and name of basic standard, technical or information document for products
(GOST, SPECIFICATIONS, OST, STO, (M) SDS etc.)
TS 2458-007-63121839-2010
Atren-Light Chemical Filler for Light-Weight Cement Slurries
HAZARD DESCRIPTION:
Signal word: CAUTION
Short (verbal): It is a low hazardous substance according to the degree of its effect to the human body (haz-
ard class 4 according to GOST 12.1.007). It has irritating effect on the mucous membranes of the eyes. The
product pollutes the environment.
Detailed: in 16 attached sections of the Safety Data Sheet.

BASIC HAZARDOUS MAC w.z., Hazard CAS No. EU No.

COMPONENTS mg/m3 class (if any)

DiSodium Metasilicate (dust containing sili- 6/2 3 6834-92-0 229-912-9

cate; silicates, alumosilicates):
Polyethenol: 10 4 9002-89-5 209-18-33
Aluminum sodium silicate (aluminum silicate): 6 4 1344-00-9 215-684-8
Disodium carbonate: 2 3 497-19-8 207-838-8

APPLICANT: Industrial Chemistry LLC, Kazan

(name of organization) (city)
Applicant type: manufacturer, supplier, seller, exporter, importer
(delete as appropriate)
6 3 1 2 1 8 3 9 +7 (843) 537-23-93
Emergency telephone number:
ARCCEO code:
Head of the applicant organization: _________________ / M. A. Yutyaev /
(signature) clarification of signature
L.S.
page 2 SDS No. 63121839.24. 39608 Atren-Light Chemical Filler for Light-Weight Cement Slur-
of 14 Valid before 12.10.2020 ries according to TS 2458-007-63121839-2010

SAFETY DATA SHEET COMPLIES WITH UN RECOMMENDATIONS

ST/SG/AC.10/30 GHS.

IUPAC – International Union of Pure and Applied Chemistry (International Union

of Theoretical and Applied Chemistry)

GHS – United Nations ST/SG/AC.10/30 recommendations Globally Harmo-

nized System of Classification and Labeling of Chemicals

ARPCC – All-Russian Product Classification Code

ARCCEO – All-Russian Classification Code of Enterprises and Organizations

FTCC – Foreign Trade Commodity Code

CAS No. – Substance number in Chemical Abstracts Service Register

EU No. – Substance number in European Chemicals Agency Register

MAC w.z. – Maximum allowable concentration of chemicals in the working zone,

mg/m3 (maximum single/shift-average)

Safety Data – In Russian: Safety Data Sheet (substance, mixture, material, industrial
Sheet wastes)

Signal word: One of two words Danger or Warning (or Not available) is
specified according to GOST 31340-2007. Precautionary marking of chemicals.
General requirements.
Atren-Light Chemical Filler for Light-Weight Cement Slur- SDS No. 63121839.24. 39608 page 3
ries according to TS 2458-007-63121839-2010 Valid before 12.10.2020 of 14

1. Identification of a chemical product and information on the manufacturer and/or supplier

1.1. Identification of chemicals
1.1.1. Technical name:
1.1.2. Short recommendations for
use:
(including application limitations)
1.2. Data on a manufacturer or supplier
1.2.1. Full official name of the organization:
1.2.2. Address (postal and registered address):
1.2.3. Telephone as well as for emergency consulta- +7 (843) 537-23-93 (from 8.00 to 16.00 Moscow time).
tions and time limits:
1.2.4. Fax:
1.2.5. E-mail:
Atren-Light Chemical Filler for Light-Weight Cement
Slurries. [1]
The product is intended for industrial use in oil industry.
[1]
Industrial Chemicals
Limited Liability Company
ul. Ostrovskogo, d. 84, Kazan, the Republic of Tatarstan,
Russia 420107
420107, Kazan, p.o. box 146.
+7 (843) 537-23-94 (automatic).
Timofeev_a_i@mirrico.com; info@mirrico.com

2. Hazard (hazards) identification

2.1. General hazard level of chemical products: Classification according to GOST 12.1.007: low-hazard
(information on hazard classification in accordance with the substance (hazard class 4). [2,9,29-32]
legislation of the Russian Federation (GOST 12.1.007) and GHS classification: eye damage / irritation, hazard class
GHS)
2B. Specific target toxicity (may cause respiratory irri-
tation), hazard class 3. [2,29-32]
2.2. Information on marking according to GOST
31340-2013
2.2.1 Signal word: Caution. [12]
2.2.2 Hazard pictogram: Exclamation mark. [12]
2.2.3 Hazard statements: Н320 Causes severe eye irritation upon eye contact.
H335: May cause irritation. [12]

3. Composition (information on components)

3.1. General product information No, because the recipe is mixed. [1]
3.1.1. Chemical name: No, because the recipe is mixed. [1]
(according to IUPAC)
3.1.2. Chemical formula: No, because the recipe is mixed. [1]
3.1.3. General description of the composition: The product is a mixture based on sodium salt. [1]
(subject to the brand assortment; production process)
3.2. Components
(Name, CAS and EU numbers, mass fraction (in the amount
100 %), MAC w.z. or SRLI w.z., hazard classes, reference to
data sources). Table No. 1 [3,28-32]
Components Mass Health standards
(name) content, % in air of a working zone
CAS No. EU No.
MAC w. z., Hazard class
mg/m3
1 2 3 4 5 6
DiSodium Metasilicate (dust con- 6/2, F, aerosol 3 6834-92-0 22329-912-9
taining silicate; silicates, alu-
mosilicates):
Polyethenol: 10, aerosol. 4 9002-89-5 209-18-33
page 4 SDS No. 63121839.24. 39608
of 14 Valid before 12.10.2020
1 2
Aluminum sodium silicate (alu-
minum silicate):
Disodium carbonate:
Note: F is strongly fibrogenic aerosols. + special skin and eye protection is required.
4. First aid measures
4.1. Symptoms observed:
4.1.1. In case of inhalation:
4.1.2. In case of skin exposure:
4.1.3. In case of contact to eyes:
4.1.4. If swallowed:
4.2. First-aid rendered to injured persons
4.2.1. In case of inhalation:
4.2.2. In case of skin exposure:
4.2.3. In case of contact to eyes:
4.2.4. In case of inhalation:
4.2.5. Contraindications:
5. Fire-fighting measures
5.1. Information concerning
fire and explosion hazard:
(according to GOST 12.1.004)
5.2. Fire and explosion hazard indices:
(nomenclature of indices according to GOST 12.1.044 and
GOST R 51330.0)
5.3. Products of combustion and/or thermal destruc- If heated, the product can decompose with forming car-
tion and hazard caused by them:
5.4. Recommended extinguishing media:
5.5. Unsuitable extinguishing media:
5.6. Personal protective equipment for fire fighting: Fire-fighting suit complete with a self-rescue device SPI-
(PPE of firefighters)
Atren-Light Chemical Filler for Light-Weight Cement Slurries
according to TS 2458-007-63121839-2010
3 4 5 6
6/2, F, aerosol. 4 1344-00-9 215-684-8
2,+, aerosol 3 497-19-8 207-838-8
Throat irritation, cough, weakness, faintness, de-
creased motor activity, change of respiratory rhythm,
nausea, vomit. [29-32]
Inhalation of strongly fibrogenic aerosols is a cause of
some occupational diseases (dust bronchitis, pneumono-
coniosis and etc.) [33]
The product does not have irritating properties in case of
single exposure. Can cause hyperemia, itch, edema in
case of multiple or prolonged exposure. [2,29-32]
Tearing, cutting, hyperemia, edema. [ 2,29-32]
Throat irritation, cough, abdominal pain, nausea, vomit,
diarrhea. [29-32]
Fresh air, rest and rewarming, put an injured person to
horizontal position, release him off discomfortable
clothes, apply for medical aid if necessary. Artificial
ventilation for indication. [29-32]
Remove substance surplus, take off dirty clothes, wash
skin with water, apply for medical aid if necessary [29-
32].
Wash with running water for 10-15 minutes, if necessary
seek medical help. [29-32]
Wash mouth with water, drink a lot of liquid, absorbent
carbon, saline purge. Provide the injured person with
rest, warming, fresh air, apply for medical aid if neces-
sary. Upon vomit stoop a head to avoid vomit entry into
lungs. [29-32]
Do not cause vomiting in artificial way! Do not use neu-
tralizing solutions. [1,29-32]
Nonflammable substance. [29-32]
Nonflammable substance. [29-32]
bon and sodium oxides affecting the central nervous and
cardiovascular systems, blood, liver, kidneys. [29-32]
According to the main source. [29-32,25]
According to the main source. [29-32,25]
20. [22]
Atren-Light Chemical Filler for Light-Weight Cement Slur-
ries according to TS 2458-007-63121839-2010
5.7. Special fire fighting procedures:
6. Emergency response
6.1. Prevention of hazardous impact on people,
environment, buildings, constructions etc.
in case of emergency
6.1.1. Necessary general actions in case of emer- Suspend work, send away strangers, keep a windward
gency:
6.1.2. Personal protective equipment in emergency All-service protective suit L-1 or L-2 complete with an
situations:
(PPE of emergency crews)
6.2. Emergency response procedure
6.2.1. Spill and leakage management:
(as well as elimination of them and environmental precau-
tions)
6.2.2. Fire response plan:
7.Storage regulations for chemicals and
and handling of them upon loading-unloading operations.
7.1. Safety measures upon handling of chemicals
7.1.1. Systems of engineering safety measures:
SDS No. 63121839.24. 39608 page 5
Valid before 12.10.2020 of 14
According to the main source. [21,23,25,28-32]
side, avoid low places, move the vehicle to a safe place.
Isolate the hazardous zone within a radius of not less than
50 m, correct the specified distance according to results
of chemical survey. Enter the emergency zone with
complete protective clothes on, observe fire safety
measures, do not smoke, and eliminate sources of fire and
sparks. Render first medical aid to injured persons, send
people from the emergency zone for a medical checkup,
call emergency services. [22]
industrial gas mask and cartridges A, B. [22]
Stop work, put on PPE, pump the contents to an empty
proper capacity, collect and forward for disposal to the
landfill of toxic industrial waste. Avoid the product entry
into water basins, sewerage and soil. Observe fire safety
regulations, eliminate sources of fire and sparking. For
spreading (deposition, isolation) of aerosols use sprayed
water. If necessary, make measurements for compliance
with the MAC level, call neutralization specialists. [22]
Call fire protection service, inform surrounding people
about the fire, leave the hazardous zone, tell to firefight-
ers the place and the object of burning when they arrive.
Organize evacuation of people from nearby buildings
subject to a direction of movement of toxic combustion
products. [1,21,22,23]
Hermetic sealing of equipment, communication lines,
containers, avoid spillages, forming of vapor, direct con-
tact to the product. Provide a limited access to the prod-
uct, production control of harmful factors. Use personal
protective equipment, supply and exhaust ventilation.
Control of technological processes and equipment condi-
tion. Comply with the requirements of fire safety ac-
cordi8ng to GOST 12.1.004, ГОСТ12.1.018, provide
firefighting primary means, exits, entries and passes
should be free. Do not use the product near sources of
heat, open flame, or sparks. The facilities shall be
equipped with washstands, medical kits, emergency kits
of personal protective equipment, equipped with a pipe-
page 6 SDS No. 63121839.24. 39608
of 14 Valid before 12.10.2020
7.1.2. Environmental precautions:
7.1.3. Recommendations for safe transfer and car- Continuity and tightness of packs, prevent burning, unau-
riage:
7.2. Storage of chemical products:
7.2.1. Safe storage conditions and terms:
(including storage life; incompatible substances and materials key and under supervision, in tight pack, on pallets, at a
for storage)
7.2.2. Containers and packs:
(including materials they are made of)
7.3. Safety measures and rules of household stor-
age:
8. Exposure controls and personal protective equipment
8.1. Working zone parameters
subject to compulsory control (MACwork. zone or
Atren-Light Chemical Filler for Light-Weight Cement Slurries
according to TS 2458-007-63121839-2010
line and industrial sewage. The floor in the production
facilities should be easily cleaned with water and should
be with slopes and drains. [1,8,12,13,14,21]
Avoid the product entry into the environment. Pressuriza-
tion of equipment, communications, containers. Provide
control of concentration of hazardous substances in the
air of a working zone, sanitary protection zone, industri-
al effluents. Meet requirements to accumulation, collec-
tion, placement, removal and treatment of industrial
waste. Do not discharge the product to municipal sewers,
domestic sewage systems, naturally impounded reser-
voirs, rivers, soil. Do not store containers, in which the
product was or is, directly on the ground, do not burn
waste in earth mounds, do not perform unauthorized
placement of waste. [1,8,12,13,14,21]
thorized access, spillage, entry into the environment. Do
not perform loading-unloading operations with the prod-
uct if containers do not conform to the requirements or
are improper, if there is no marking on them. Do not car-
ry with oxidizers, explosive substances, substances
flammable upon contact to air and water, alkalis and acid-
ic-type materials, compressed and liquefied gases, and
acids. Observe requirements on securing and disposition
of loads. Avoid external mechanical effect, damage to
containers. Do not throw, use hooks. [1,19,20,21,22]
Store in covered, ventilated warehouses under lock and
temperature from minus 35 to 35 0C. Prevent exposure to
direct sunlight, moisture, heat, fire, acids, alkalis and oxi-
dants. Guarantee period of conformity of the product
with specifications is 12 months. Separation of substanc-
es and materials in case of storage shall comply with
GOST 19433, GOST 12.1.004, incompatible materials
are moisture, strong oxidants, acids, alkalis. Do not pile
the bags in a vertical position. Storage premises shall be
equipped with replacement assembly of protective
clothes, fire alarm system, temperature control devices,
industrial medical kit and also fire-fighting equipment.
[1]
The product is packed in polypropylene bags according to
GOST 30090 or in multi-layer paper bags according to
GOST 2226. The other types of containers and packs
providing quality, safety, hermetic sealing of the product
can be used subject to agreement with a consumer. [1]
Not suitable for household use.
Health standards are given with regard to components.
[29]
Atren-Light Chemical Filler for Light-Weight Cement Slur- SDS No. 63121839.24. 39608 page 7
ries according to TS 2458-007-63121839-2010 Valid before 12.10.2020 of 14

SRLIwork. zone) DiSodium Metasilicate: MACw.z.- 6/2 mg/m3, dust

8.2. Exposure controls:
8.3. Personal protective equipment for personnel:
8.3.1. General recommendations:
8.3.2. Respiratory protective equipment (types of
the respiratory protective equipment)
8.3.3. Protective means (material, type):
(special clothes, safety shoes, hand protection, eye protec-
tion):
8.3.4. Personal protective equipment for household Not suitable for household use. [1]
use:
9. Physical and chemical properties
9.1. Form:
(aggregative state, color, odor)
9.2. Parameters specifying ­basic properties of Moisture content of no more than 15%. [1]
chemicals, first of all hazardous properties:
(temperature values, рН, solubility, n-octanol/water index 1% water solution pH is 11,0-13,5 units; [1]
etc.)
containing silicate; silicates, alumosilicates: dust of
glass and construction materials made of glass,
strongly fibrogenic aerosol. [29,3]
- polyethenol: MACw.z. - 10 mg/m3, aerosol, [30,3]
- aluminum sodium silicate: MAC w.z. – 6 mg/m3,
alumosilicate, strongly fibrogenic aerosol. [31,3]
- disodium carbonate: MACw.z.- 2 mg/m3, aerosol,
special skin and eye protection is required. [32,3]
Ventilation efficiency. Provide hermetic sealing of
equipment, containers, avoid forming of dust, high tem-
peratures. Use the product in well-ventilated facilities.
Control of concentration of hazardous substances in air
of a work zone, sanitary and hygienic control of ventila-
tion systems. Laboratory work shall be performed only
in the exhaust fume hood with ventilation switched on,
periodical wet cleaning of premises. [1,8,13,14,21]
Avoid direct contact to the product, forming of dust. Do
not eat, drink and do not smoke in the work zone. Use
personal protective equipment. Make periodical hygienic
cleaning of the personal protective equipment. Availabil-
ity of replacement kits of the personal protective equip-
ment. Observe HSE regulations. Availability of fire-
fighting equipment. Persons aged 18 are allowed to work
by results of medical checkups. Labor protection brief-
ing. [13]
RPG-67A type respirators. [29-32, 17]
I-II type rubber acid and alkali resistant gloves. Special
clothes (cotton suit), rubber gloves, leather boots or rub-
ber boots, protective glasses with side shields. [29-32,17]
White powder, faint smell. [1]
The substance is soluble in water, insoluble in fats. [1]
Bulk density is 1.05-1.50 g/cm3 [1]

10. Stability and reactivity

10.1. Chemical stability: The product is stable (stability in abiotic conditions is 1-
(specify decomposition products for non-stable products) 7 days) if properly stored, used and transported. It does
not form derived toxic substances in air and sewage
with other substances or factors, at ambient temperature.
[29-32]
10.2. Reactivity: The substance reacts with acids and alkalis. [29-32]
10.3. Conditions to avoid: Avoid high temperatures, exposure to moisture, the
(including hazardous effects upon contact to incompatible sources of fire, sparking, heat, direct sunlight, contact to
substances and materials) acids and alkalis. Forming of dust, direct contact to a
page 8 SDS No. 63121839.24. 39608 Atren-Light Chemical Filler for Light-Weight Cement Slurries
of 14 Valid before 12.10.2020 according to TS 2458-007-63121839-2010

man. In case of burning and high temperatures carbon

and sodium oxides are emitted, see Clause 5.3 hereof.
[1,13,21,29-32]
11. Toxicological information
11.1. Information concerning It is a low hazardous substance according to the degree
particular hazards: of its effect to the human body (hazard class 4 accord-
(evaluation of hazard (toxicity) of effect on the body and the ing to GOST 12.1.007). Causes gastrointestinal distress,
most specific displays of hazard) irritates the mucous membrane of the eyes. [2,9,29-32]
11.2. Routes of exposure: Inhalation, in case of contact to skin, mucous mem-
(inhalation, ingestion, contact to skin and eyes) branes of the eyes, oral. [29-32]
11.3. Target human organs, tissues and systems: Nervous and respiratory systems, liver, kidneys, pe-
ripheral blood blood cell composition, gastrointestinal
tract, skin, eyes. [29-32]
11.4. Information on health hazards in case of di- It irritates upper respiratory airway, if inhaled, high
rect contact to the substance as well as the effects dispersiveness of the product particles promotes its long
of these contacts: lasting stay in the form aerosol in dust, air of produc-
(irritation of the upper airways, eyes, skin; skin-resorptive and tion premises, and makes for quick penetration of parti-
sensitizing effects) cles into the respiratory tract. [29-32,33]
Does not have irritate skin in case of single exposure
(1.5 % water solution, Guinea pigs, 4 hours, 14 applica-
tions) - 0 points, no effect [2]
Irritates eye mucosa (1.5 % water solution, single appli-
cation, one drop, rabbit's eye) - 1 point, conjunctival
and corneal vessels are injected.
Sensitizing properties were not identified (according to
the method of Alekseyeva-Petkevich, Guinea pigs). [2]
Disodium carbonate has a sensitizing effect, causes
dermatitis. [32]
Skin-resorptive properties of the product were not stud-
ied. Information on components is not available.
[2,29,32]
11.5. Information on hazardous long-term effects Cumulative properties of the product were not studied,
on a human body: all components have weak cumulative properties. [2,29-
(effect on reproduction function, carcinogenicity, mutagenici- 32]
ty, cumulative and other chronic effects) Long-term adverse health effects of the product on the
body were not studied; additional information is given
according to the components of the substance:
- embryotropic (stillbirth, lactation index), gonadotropic
properties of disodium metasilicate were identified in
animal experiments; [28,29]
- the properties of polyethanol were not studied or were
not established; [28,30]
- the properties of aluminium sodium silicate were not
studied or were not established; [28,31]
- embryotropic (increased preimplantation loss) and ter-
atogenic (fetal development pathology) properties of
disodium carbonate were identified. [28,32]
11.6. Acute toxicity indices: DL50 10000 mg/kg, intragastric route, mice (according
(DL50 (DL50), route of entry (ingestion, contact to skin), ani- to the method of V. B. Prozorovsky). [2]
mal type; CL50 (CL50), exposure time (h), animal type) DL50 more than 2500 mg/kg, epicutaneous, mice. [29-
32]
CL50 is not reached. [29-32]
Atren-Light Chemical Filler for Light-Weight Cement Slur- SDS No. 63121839.24. 39608 page 9
ries according to TS 2458-007-63121839-2010 Valid before 12.10.2020 of 14

12. Information on environmental impact

12.1. General description of impact on objects of Pollutes the air, has negative impact on water biological
ecological interest: resources, pollutes soil, is transformed in the environ-
(atmospheric air, water basins, soils, including observed ef- ment. The product does not belong to the category of
fects) ozone-destroying substance. [28,29-32]
The product changes appearance, smell, taste of water,
it has an impact on sanitary conditions of water basins
and their inhabitants, retards a biological need for oxy-
gen, violates self-cleaning processes, depresses nitrifica-
tion processes. It leads to soil degradation and sup-
presses vegetation, changes their biological composi-
tion, and has a negative effect on soil animals resulting
in their death, deteriorates the appearance of vegetation
cover. [28,29-32]
12.2. Ways of environmental impact: In case of violation of rules of handling, storage, car-
riage, unorganized waste disposal as a result of emer-
gencies and accidents. [1]
12.3. Health standards:
(allowable concentration in atmospheric air, water including
fishery water bodies, soil) Table No. 2 [4,7,29-32]
Components MACatm.air or SLRI- MACwater2 or APLwater, MACfishery3 or MAC or APC
3
atm. air , mg/m mg/l, (LHI, hazard SLRI fishery mg/l, of soil, mg/kg
1
(LHI , hazard class) class) (LHI, hazard (LHI)
class)
SRLImax.sing.: 0,3, so- 30, san.-tox., *, hazard Not established.
Disodium metasilicate **
dium silicate class 3.
0.1 org. foam, hazard 1, org., tox., haz- Not established.
Polyethenol SRLImax.sing.: 0,1
class 4 ard class 4.
Aluminum sodium sili- 0.5, aluminium, san.- Not established.
*** Not established.
cate: tox., hazard class 2
0.15/0.05, res., 200, sodium, san.-tox., Not established.
Disodium carbonate ****
hazard class 3. hazard class 2.

Note * sodium silicate (by SiO3). Since water solutions of the substance are exposed to hydrolysis and have a
highly alkaline reaction, control of pH value in water reservoirs (pH=6.5-8.5) is required. **MACfisher. of sodi-
um is 120.0 mg/l, san.-tox. (environmental) hazard class 4. MACfisher. of potassium silicate is 2 mg/l, tox., haz-
ard class 3, 1.0 mg/l by SiO3. Control of pH value in water reservoirs (pH=6.5-8.5) is required. * * * Daily av-
erage MACair aluminosilicates (zeolites) is 0.03 mg/m3, res. hazard class 2. **** Do not discharge into the res-
ervoir before the hydrolysis process is finished, hazard class 3, MACfisher. of sodium is 120.0 mg/l, san. - tox.,
(environmental) hazard class 4.

12.4.2. Indicators of ecotoxicity:
(CL, EU for fish, Daphnia Magna, algae, etc.)
Acute toxicity to fish, according to the product as a whole
in accordance with the recommendations of the GHS is
CL50 more than 100 mg/l, fishes, 96 h. Chronic toxicity
for fish and bioaccumulation properties in the aquatic en-
vironment, in accordance with the GHS recommendations
were not identified. [26,28,29-32]

1
LHI - limiting harmful index (tox. - toxicologic; s.-t. - sanitary-toxicologic; org. - organoleptic; refl. - reflectory; res. - resorptive;
refl.-res. - reflectory-resorptive, fish.- fishery (change of commercial properties of wild capture aquatic organisms); gen. - general san-
itary).
2
Water of water bodies of household and cultural and general water use
3
Water of water bodies for fishery purpose (including off-shore facilities)
page SDS No. 63121839.24. 39608
10 Valid before 12.10.2020
of 14
12.4.3 Migration and transformation in the envi-
ronment due to biodegradation and other pro-
cesses (oxidation, hydrolysis, etc.):
13. Recommendations for disposal of waste (residues).
13.1. Safe handling of waste generated in the pro- Limitation, recording and profiling of wastes. Collection,
cess of application, storage, transportation:
13.2. Information on places and methods of neu-
tralization, utilization or disposal of waste, includ- inhabited localities. Waste disposal shall be performed in
ing containers (packages):
13.3. Recommendations for disposal of waste
generated in the process of household use of the
products:
Atren-Light Chemical Filler for Light-Weight Cement Slurries
according to TS 2458-007-63121839-2010
Additional information is provided according to the com-
ponents of the composition:
- disodium metasilicate: CL50 is 210 mg/l, Brachydanio
rerio, 96 h [29]
- polyethanol: no information available. [30]
- aluminum sodium silicate: CL50 1800 mg/l, Brachydanio
rerio, 96 h. [31]
- disodium carbonate: CL50 is 300 mg/l, Lepomis macro-
chirus (Bluegill Sunbird), 96 h. [32]
Threshold concentration of the product for the effect on
the organoleptic properties of water were not studied, ad-
ditional information is provided on the components:
- disodium metasilicate TCgen. is 10 mg/l; [29]
- polyethenol: TCorg. foam is 0.5 mg/l, TCorg. smell is 63 mg/l,
TCgen. is 50 mg/l; [30]
- aluminum sodium silicate: no information available;
[31]
- disodium carbonate: no information available. [32]
Biodegradation and biological dissimilation properties are
low. The product is transformed in the environment.
[29-32]
emplacement, removal and disposal in the places ap-
proved in accordance with the established procedure. Se-
lective collection of wastes by hazard types. Use ventila-
tion, PPE, prevent dust generation, exposure to high tem-
peratures, ensure tightness of equipment, packaging, con-
trol the concentration of harmful substances in the air of
the working zone. The waste is transported in vehicles in
accordance with set requirements. To comply with fire
safety regulations see paragraph 7.1.1 Of MSDS. In case
of spillage, collect in a special container and remove to
the places approved in accordance with the established
procedure. [1,13,14,21]
Avoid pollution of the surrounding territory, soil of the
specialized organizations having appropriate license. The
air is purified before emission according to the established
standards of maximum permitted emissions. The water
used for washing of the contaminated equipment, contam-
inated surfaces is collected and transported to the author-
ized treatment facilities. The product waste is buried in
special facilities (landfills). Empty containers may not be
re-used and shall be disposed, before disposal containers
shall be emptied from the residues of the product. Comply
with the requirements for protection of the environment.
See Section 8 of SDS. [1,13,14,21]
Not suitable for household use. [1]
Atren-Light Chemical Filler for Light-Weight Cement Slur- SDS No. 63121839.24. 39608 page
ries according to TS 2458-007-63121839-2010 Valid before 12.10.2020 11
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14. Transportation information

14.1. UN number: N/A. [27]
(in accordance with the UN Recommendations on the
Transport of Dangerous Goods)
14.2. Proper shipping name: Atren-Light Chemical Filler for Light-Weight Cement
Slurries. [1]
14.3. Applied modes of transport: Transported by all modes of ground transport vehicles in
accordance with the shipping rules applicable by this
mode of transport. [1]
14.4. Cargo hazard classification according to the
GOST 19433-88:
 class: The product is not classified as a hazardous cargo. [11]
 subclass:
 classification code (in accordance with
GOST 19433-88 and in case of railway transporta-
tion):
 number(s) of drawing (s) of hazard symbol(s):
14.5 Classification of cargo hazard in accordance
with UNO Recommendations concerning hazard-
ous cargo transportation:
 class or subclass: The product is not classified as a hazardous cargo. [27]
 additional hazard:
 UN packing group:
14.6 Transport marking: Keep away from sunrays; Keep dry; Do not use hooks;
(manipulation signs according to GOST 14192) Temperature limits; Do not throw. [1,11]
14.7. Emergency cards: Not required. [19,20,22]
(for railway, sea and other carriages)

15. Information on national

and international law
15.1. National law
15.1.1. The laws of the Russian Federation: On Public Sanitary and Epidemiologic Well-Being. On
Protection of Environment. On Fire Safety Regulations.
Uniform sanitary and epidemiologic and hygienic re-
quirements in the Customs Union.
15.1.2. Environment and The Product is not subject to obligatory certification
person protection regulations:
15.2 International conventions Not regulated
and agreements:
(regulation of the products by Montreal Protocol, Stockholm
Convention etc.)

16. Additional information

16.1. Information on revision The IB is re-registered upon expiration. Previous MSDS
(re-edition) of SDS: «First edition of the Safety Data No. 63121839.24.24074
Sheet» or “The SDS was reregistered after expiry of validity
period". "Previous SDS No.” or “ Clauses …. were amend­
ed, date of amendment…”)
page SDS No. 63121839.24. 39608 Atren-Light Chemical Filler for Light-Weight Cement Slurries
12 Valid before 12.10.2020 according to TS 2458-007-63121839-2010
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16.2. The list of data sources used for preparation of the SDS
1. TS 2458-007-63121839-2010 Atren-Light Chemical Filler for Light-Weight Cement Slurries
2. Toxicological test report No. 17301.E dated 11.05.2010 The Center of Hygiene and Epidemiology of
the Republic of Tatarstan Federal State healthcare Facility, GSEN.RU.TsOA.043
3. Hygienic regulations 2.2.5.1313-03. Maximum allowable concentrations (MAC) of harmful substances
in the air of the working zone.
4. Hygienic regulations 2.2.5. 2308-07. Safe Reference Level of Impact (SRLI) of harmful substances in
the air of the work zone.
5. Hygienic regulations 2.1.5.1315-03. Maximum allowable concentrations (MAC) of chemical substances
in water of water bodies of household and cultural and general water use.
6. Hygienic regulations 2.1.6.1338-03. Maximum allowable concentrations (MAC) of pollutants in the at-
mospheric air of populated areas.
7. Hygienic regulations 2.1.6.2309-07. Safe Reference Level of Impact (SRLI) of pollutants in the atmos-
pheric air of populated areas.
8. GOST 12.1.005-88. SSBT. General sanitary and hygienic requirements to the air of the working zone.
9. GOST 12.1.007-76. SSBT Hazardous substances. Classification and general safety requirements.
10. GOST 19433-88. Dangerous goods. Classification and marking.
11. GOST 14192-96. Marking of goods.
12. GOST 31340-2013. Safety marking of chemical products. General requirements.
13. SP 2.2.1327-03. Hygienic requirements for arrangement of technological processes, production equip-
ment and working tools.
14. SanPiN 2.1.7.1322-03. Hygienic requirements for disposal and neutralization of production and con-
sumption wastes.
15. The unified list of goods subject to state sanitary and epidemiological surveillance at the customs border
and in the customs territory of the customs union.
16. Decree of the Government of the Russian Federation No. 563 dated 08.05.1996 On Regulation of Im-
port into the Russian Federation and Export from the Russian Federation of Ozone-Depleting Substanc-
es and Products Containing such Substances.
17. Decree of the Ministry of Labor of the Russian Federation dated July 22, 1999 No. 26 On Approval of
Trade Standards of Free Provision of Chemical Production Staff with Special Clothing, Special Foot-
wear and Other Personal Protective Equipment.
18. Safety rules and emergency response procedure for dangerous goods in case of transportation by rail.
19. The rules for transportation of dangerous goods by road.
20. The rules for transportation of dangerous goods by rail.
21. Fire safety rules in the Russian Federation (PPB 01-03).
22. Emergency cards for dangerous goods transported by the railways of the CIS, the Republic of Latvia,
the Republic of Lithuania, and the Republic of Estonia.
23. V. P. Ivannikov, P. P. Klyus Guidebook of a Manager of Fire Extinguishing
24. N. V. Lazarev, Ye. N. Levina Hazardous substances in industry. Reference book for chemists, engineers
and doctors.
25. Fire and explosion hazard of substances and materials, extinguishing agents: reference edition.
26. Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
27. The Recommendations on the Transport of Dangerous Goods Model Regulations.
The 16th revised edition.
28. IUCLID Chemical Data Sheet: http://ecb.jrc.ec.europa.eu/esis/index.php, N-CLASS Database:
http://apps.kemi.se/nclass/default.asp., ESIS: http://ecb.jrc.ec.europa.eu/esis, ICSC:
http://www.safework.ru/ilo/ICSC/, GESTIS Substance Database http://gestis-en.itrust.de.
29. Information card of a potentially hazardous chemical and biological substance. Disodium metasilicate.
Certificate of state registration. Series No. 000458 FBUZ RPOKhBiV.
30. Information card of a potentially hazardous chemical and biological substance. Polyethenol. Certifi-
cate of state registration. Series VT No. 000780, FBUZ RPOKhBiV.
Atren-Light Chemical Filler for Light-Weight Cement Slur- SDS No. 63121839.24. 39608 page
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31. Information card of a potentially hazardous chemical and biological substance. Aluminum sodium sili-
cate: Certificate of state registration. Series No. 002068 FBUZ RPOKhBiV.
32. Information card of a potentially hazardous chemical and biological substance. Disodium carbonate.
Certificate of state registration. Series No. 000443 FBUZ RPOKhBiV.
33. GOST R 54578-2011Air of the working zone. Strongly fibrogenic aerosols. General principles of hy-
gienic control and impact assessment.