  G12 

2

1,3- DIOXOLANO 2-PROPANOL ln  2  x12  12 
x xG 
  x

  2 1 12  1
A 71.018 73.032
B -6400.8 -7215.9
C -7.0388 -7.1145
D 6.02E-07 4.62E-06 G12  exp(  12 12 )
E 2 2
P(KPA) 101.3
α 0.262
A12 75.76 82.53

X1 X2 T(K) Pvp1 Pvp2 τ12

0 1 225.669652 0.0938135242 0.0154528329 0.3357119546
0.2 0.8 341.488377 79.605940459 56.326161217 0.221852353
0.6 0.4 345.313576 90.730832559 66.561153804 0.2193947914
0.8 0.2 343.394611 85.00772522 61.24528521 0.2206208182
1 0 342.368294 82.064920005 58.553364556 0.2212821728

x y
0 0
1 1

1.2

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1
   G12 
2
 21G21 
x12  12 
x xG 
   x  x G 2 

  2 1 12  1 2 21 
  2

 G 21   12 G12
ln  1  x 22  21 
x x G 
  

  1 2 21   x2  x1G12 
2


G 21  exp(   12 21 )
exp(  12 12 )

τ21 G12 G21 ϒ1 ϒ2 y1 y2

0.3657115577 0.9158006838 0.0958164281 2.6286398702 6558.3394767 0 1.000443474
0.2416773323 0.9435316999 0.0633194611 1.3127384743 1.7850429672 0.20632138 0.7940344952
0.2390001601 0.9441394178 0.062618042 1.2254593502 1.2992083684 0.6585604 0.3414681462
0.2403357461 0.943836191 0.0629679655 1.2288362557 1.4481525729 0.82496012 0.1751086226
0.2410562002 0.943672662 0.0631567244 1.2344903924 1.7238778633 1.00008248 0

Column M
Column D

0.6 0.8 1 1.2

2
 12 G12 
 
 x2  x1G12 
2



y1+y2
1.00044347
1.00035588
1.00002854
1.00006874
1.00008248