FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

A 12
ln γ 1 =
x 1 A 12
(
( 1+
x 2 A 21
)2
)
T(ªC) = 60 A 12 A 21
x 1 A 12 x2 A 2
T(K) = 333.15

γ 1 =e
( 1+
( x 2 A 21 )
)2
γ 2 =e
(
( 1+
x1 A 1

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

T x1 x2 A 12= A 21 =
A 12= 0.4262 333.15 0.001 0.999 0.4262 0.4394
333.15 0.1 0.9 0.4262 0.4394
A 21 = 0.4394 333.15 0.2 0.8 0.4262 0.4394
333.15 0.3 0.7 0.4262 0.4394
333.15 0.4 0.6 0.4262 0.4394
333.15 0.5 0.5 0.4262 0.4394
333.15 0.6 0.4 0.4262 0.4394
333.15 0.7 0.3 0.4262 0.4394
333.15 0.8 0.2 0.4262 0.4394
333.15 0.9 0.1 0.4262 0.4394
333.15 0.999 0.001 0.4262 0.4394

CALCULO DE LAS PRESIONES DE VAPOR:

Metil Aceta

1
METIL ACETATO METANOL 0.9
VP_A= -8.05406 VP_A= -8.54796
0.8
VP_B= 2.56375 VP_B= 0.76982
0.7
VP_C= -5.12994 VP_C= -3.1085
Y1

VP_D= 0.16125 VP_D= 1.54481 0.6

Pc= 46.9 Pc= 80.9 0.5
Tc= 506.8 Tc= 512.6 0.4
T= 333.15 T= 333.15 0.3
x= 0.34264009 x= 0.350078034 0.2
0.1
DIAGONAL 0
0 0.1 0.2 0.3 0.4 0.
X1
 0.4
0.3
0.2
0.1
0
0 0 0 0.1 0.2 0.3 0.4 0.
0.2 0.2
X1
0.4 0.4
0.6 0.6
0.8 0.8
1 1
oseph Christian Cruz Huanca

A 21
ln γ 2 =
x 2 A21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21

γ2 =e
( ( 1+
x 1 A 12 )
)2

γ 1= γ 2= Pvp1 Pvp2 P y1 y2
1.530161956 1.00000041 1.1259659 0.846540765 0.84741748 0.00203313 0.99796687
1.415249081 1.00416758 1.1259659 0.846540765 0.92441413 0.17238185 0.82761815
1.317947317 1.01687721 1.1259659 0.846540765 0.98545515 0.30117327 0.69882673
1.236956246 1.03861229 1.1259659 0.846540765 1.03329051 0.4043695 0.5956305
1.170214355 1.07011078 1.1259659 0.846540765 1.07058402 0.49230006 0.50769994
1.11608213 1.11240598 1.1259659 0.846540765 1.09918372 0.57163803 0.42836197
1.073278907 1.16688325 1.1259659 0.846540765 1.12021097 0.64727564 0.35272436
1.040835325 1.23535711 1.1259659 0.846540765 1.1340956 0.72336191 0.27663809
1.018059065 1.32017492 1.1259659 0.846540765 1.14055621 0.80402862 0.19597138
1.004512307 1.4243557 1.1259659 0.846540765 1.13851946 0.8940927 0.1059073
1.000000453 1.55037134 1.1259659 0.846540765 1.1261529 0.99883457 0.00116543

Metil Acetato (1) - Metanól (2) Metil Acetato (1)

1 1.2
0.9
0.8 1
0.7
0.8
Y1

0.6 VAN LAAR

P

0.5 DIAGONA
0.6
L
0.4
0.3 0.4
0.2
0.2
0.1
0 -1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1 X-Y
 L
0.4
0.3 0.4
0.2
0.2
0.1
0 -1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1 X-Y
 y1+y2
1
1
1
1
1
1
1
1
1
1
1

Metil Acetato (1) - Metanól (2)

1.2

0.8
Xvs P
0.6 Y vs P

0.4

0.2

-1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
 0.4

0.2

-1.66533453693773E-16
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

A 12
ln γ 1 =
x 1 A 12
(
( 1+
x 2 A 21
)2
)
A 12 A 21
x 1 A 12 x2 A
P (bar) = 1

γ 1 =e
( 1+
( x 2 A 21 )
)2
γ 2 =e
(
( 1+
x1 A

Parámetros de Van Laar: Cálculo del coeficiente de actividad:

Presion T x1 x2
A 12= 0.4262 1 337.2891981 0.001 0.999
1 319.0608738 0.1 0.9
A 21 = 0.4394 1 315.7886142 0.2 0.8
1 316.7261775 0.3 0.7
1 317.798954 0.4 0.6
1 318.8957644 0.5 0.5
1 320.0858628 0.6 0.4
1 321.3120116 0.7 0.3
1 322.6289676 0.8 0.2
1 324.0635178 0.9 0.1
1 325.633086 0.999 0.001

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6

VP_A VP_B VP_C VP_D Pc Tc x

-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.334472774
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3704402648
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3768969729
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3750470057
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3729302407
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3707660528
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3684177925
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3659983986
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3633998271
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.3605692229
-8.05406 2.56375 -3.1085 0.16125 46.9 506.8 0.357472206
oseph Christian Cruz Huanca

A 21
ln γ 2 =
x 2 A21
(
( 1+
x 1 A12
)2
)
A 21
x 2 A 21

γ2 =e
( ( 1+
x 1 A 12
)2
)

A 12= A 21 = γ 1= γ 2= Pvp1 Pvp2 y1

0.4262 0.4394 1.530161956 1.000000413 1.29354083545 0.999065293 0.00197932697
0.4262 0.4394 1.415249081 1.004167576 0.67943966536 0.999065293 0.09615763619
0.4262 0.4394 1.317947317 1.016877206 0.71321609426 0.999065293 0.18799624759
0.4262 0.4394 1.236956246 1.038612286 0.73724302621 0.999065293 0.27358120984
0.4262 0.4394 1.170214355 1.070110779 0.76552672572 0.999065293 0.35833214532
0.4262 0.4394 1.11608213 1.112405983 0.79533617092 0.999065293 0.4438302439
0.4262 0.4394 1.073278907 1.166883252 0.82872458062 0.999065293 0.53367156736
0.4262 0.4394 1.040835325 1.235357109 0.86428715453 0.999065293 0.62970642068
0.4262 0.4394 1.018059065 1.320174924 0.90383049157 0.999065293 0.73612225984
0.4262 0.4394 1.004512307 1.424355699 0.94853378252 0.999065293 0.85753247265
0.4262 0.4394 1.000000453 1.550371342 0.99944507473 0.999065293 0.99844608194

METIL ACETATO (1) - METANOL (2) METIL ACETATO (1) - METANOL

1 340
0.9
335
0.8
0.7 330
0.6 325
T
y

VAN
0.5 LAAR
0.4 320
0.3 315
0.2
310
0.1
0 305
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 -0.8 0.2
x X-Y

VP_A VP_B VP_C VP_D Pc Tc

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
 DIAGONAL:
0 1
0.2 1.2
0.4 1.4
0.6 1.6
0.8 1.8
1 2

y2 y1+y2
0.99806664 1.000045967
0.902906076 0.999063712
0.812741379 1.000737626
0.726349041 0.999930251
0.641466323 0.999798469
0.555683105 0.999513349
0.466317023 0.99998859
0.370260724 0.999967144
0.263788189 0.999910449
0.142302434 0.999834907
0.001548922 0.999995004

METIL ACETATO (1) - METANOL (2)

340

335

330

325 X vs
T
320

315

310

305
0.2 1.2
X-Y

x
0.342003125
0.377563648
0.3839473
0.382118265
0.380025451
0.37788575
0.37556406
0.373172041
0.370602872
0.367804296
0.364742322
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Λ12 Λ21
ln γ 1 =−ln ( x1 + Λ12 x2 ) +x 2
[ −
x1 + Λ12 x2 Λ21 x 1 + x2 ]
Volúmenes:

Λ12 Λ21
v 1=

v 2=
79.84

40.73
ln γ 2 =−ln ( x2 + Λ21 x1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ]
Parámetros de Wilson:
v2 λ12
λ12 = -31.19 Λ 12 =
v1
exp −
RT ( )
λ21 = 813.18

Isoterma a la temperatura de: R T (K) x1 x2

1.987 333.15 0.001 0.999
T ( ºC )= 60 1.987 333.15 0.1 0.9
1.987 333.15 0.2 0.8
T ( K )= 333.15 1.987 333.15 0.3 0.7
1.987 333.15 0.4 0.6
La contante sera: 1.987 333.15 0.5 0.5
1.987 333.15 0.6 0.4
R= 1.987 1.987 333.15 0.7 0.3
1.987 333.15 0.8 0.2
1.987 333.15 0.9 0.1
1.987 333.15 0.999 0.001

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6
T= 333.15 T= 333.15
x= 0.342640095 x= 0.3500780336
oseph Christian Cruz Huanca

Λ12 Λ21
−
x1 + Λ12 x2 Λ21 x 1 + x2 ] [
γ 1 =exp −ln ( x1 + Λ12 x2 ) + x 2
[ Λ 12
x1 + Λ12 x2
−
Λ21
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ] [
γ 2 =exp −ln ( x 2 + Λ21 x 1 ) −x1
Λ12
[ −
Λ21
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]
λ12
(
p −
RT ) Λ 21 =
v1
v2
exp −
λ21
RT ( )
v 1= v 2= λ12 = λ21 = Λ12= Λ21= γ 1=
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.856714343
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 2.295664146
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.906163501
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.629974553
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.42954109
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.282210923
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.17389711
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.095743458
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.042323858
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.010695634
79.84 40.73 -31.19 813.18 0.5347570733 0.5738620162 1.000001099

Metil Acetato (1) - Metanól(2)

0.8
Y1

0.6 WILSON
DIAGONAL
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 0.8

Y1
0.6 WILSON
DIAGONAL
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

Λ 12 Λ21
x1 + Λ12 x2
−
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.000001205 1.1259659 0.846540765 0.848911806 0.003789043 0.996210957 1
1.01155895 1.1259659 0.846540765 1.029177253 0.251155915 0.748844085 1
1.045178823 1.1259659 0.846540765 1.137084205 0.377505042 0.622494958 1
1.101058185 1.1259659 0.846540765 1.203052176 0.457659892 0.542340108 1
1.181582589 1.1259659 0.846540765 1.244000505 0.517560729 0.482439271 1
1.291499437 1.1259659 0.846540765 1.268516349 0.569060768 0.430939232 1
1.438593361 1.1259659 0.846540765 1.280192039 0.619485862 0.380514138 1
1.635031523 1.1259659 0.846540765 1.278875089 0.675311331 0.324688669 1
1.899803695 1.1259659 0.846540765 1.260549151 0.744831644 0.255168356 1
2.263152181 1.1259659 0.846540765 1.215792995 0.842419673 0.157580327 1
2.768793696 1.1259659 0.846540765 1.127185067 0.997920575 0.002079425 1

Metil Acetato (1) - Metanól (2)

1.4
1.2
1
WILSON
P

0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
 1.2
1
WILSON

P
0.8 X1 vs
DIAGONAL P
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
P
X1 vs
P
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

etanol agua
Λ12 Λ21
v
Λ
57.141
0.6848
18.06
0.3781
ln γ 1 =−ln ( x1 + Λ12 x2 ) +x 2
[ −
x1 + Λ12 x2 Λ21 x 1 + x2 ]
λ 382.3 955.45
A 8.04494 7.96681
B 1554.3 1668.21 Λ12 Λ21
C
Presión(mmHg)=
222.65
520
228 ln γ 2 =−ln ( x2 + Λ21 x1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 +x 2 ]
t 60
T 333.15
v2 λ12
R 1.987
Λ12 =
v1
exp −
RT ( )
T(ºC) T (K) x1 x2 v 1= v 2= λ12 =
60 333.15 0.001 0.999 57.141 18.06 382.3
60 333.15 0.1 0.9 57.141 18.06 382.3
60 333.15 0.2 0.8 57.141 18.06 382.3
60 333.15 0.3 0.7 57.141 18.06 382.3
60 333.15 0.4 0.6 57.141 18.06 382.3
60 333.15 0.5 0.5 57.141 18.06 382.3
60 333.15 0.6 0.4 57.141 18.06 382.3
60 333.15 0.7 0.3 57.141 18.06 382.3
60 333.15 0.8 0.2 57.141 18.06 382.3
60 333.15 0.9 0.1 57.141 18.06 382.3
60 333.15 0.999 0.001 57.141 18.06 382.3

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6
 VP_A VP_B VP_C VP_D Pc Tc x
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.3426400947
ph Christian Cruz Huanca

Λ21
−
Λ21 x 1 + x2 ] [
γ 1 =exp −ln ( x1 + Λ12 x2 ) + x 2
[ Λ 12
x1 + Λ12 x2
−
Λ21
Λ21 x 1 + x2 ]]
Λ12 Λ21
−
Λ21
Λ 21 x 1 +x 2 ] [
γ 2 =exp −ln ( x 2 + Λ21 x 1 ) −x1
[ −
x 1 + Λ 12 x 2 Λ 21 x 1 + x 2 ]]
λ12 v1 λ
RT ) Λ 21 =
v2
exp − 21
RT ( )
λ21 = Λ12= Λ21= γ 1= γ 2= Pvp1 Pvp2
955.45 0.1774011375 0.7471247729 7.18890029538 1.0000048365 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 3.57299327897 1.0345258985 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 2.36010583792 1.1112840282 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.79396897393 1.2164845876 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.47964415783 1.3485143586 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.28772661981 1.5100382386 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.16474414412 1.7063660887 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.08513933381 1.9453118748 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.03551168202 2.2376687186 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.00848084168 2.5981517782 351.48996844 149.4218698
955.45 0.1774011375 0.7471247729 1.00000082292 3.0418838665 351.48996844 149.4218698
 VP_A VP_B VP_C VP_D Pc Tc
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

X i γ i PSat
i
.
=Y i PT

y1 y2 y1+y2
0.0048592814 0.2870637882 0.2919230697
0.2415137106 0.2675436821 0.5090573927
0.3190590486 0.2554617498 0.5745207985
0.3637858258 0.2446895792 0.6084754049
0.4000615987 0.232497158 0.6325587567
0.4352144125 0.2169545549 0.6521689673
0.4723798644 0.1961295473 0.6685094117
0.5134440637 0.167695464 0.6811395278
0.5599568745 0.1285987092 0.6885555837
0.6135073256 0.0746578263 0.6881651519
0.6752668604 0.0008740846 0.676140945
 x
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
0.3500780336
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

2
G 21 2
τ 12 G
γ 1 =exp( (x 2 ) (τ 21 .( )+
x 1 + x 2 G 21 ( x 2 + x1

2
G 12 2
τ 21 G
γ 2 =exp(( x1 ) (τ 12 . ( )+
Volúmenes: x 2 + x 1 G 12 ( x 1 +x 2
v1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp ( ¿α12 . τ 12 )
Parámetros del NRTL: Λ12 = g ¿ Λ 21 = g ¿

Λ12= 381.46

Λ21= 346.54

α 12 = 0.2965 Cálculo del coeficiente de actividad:

Asumimos la temperatura de:

T (K) x1 x2 v1= v 2=
T ( ºC )= 60 333.15 0.001 0.999 79.84 40.73
333.15 0.1 0.9 79.84 40.73
T ( K )= 333.15 333.15 0.2 0.8 79.84 40.73
333.15 0.3 0.7 79.84 40.73
La constante será: 333.15 0.4 0.6 79.84 40.73
333.15 0.5 0.5 79.84 40.73
R= 1.987 333.15 0.6 0.4 79.84 40.73
333.15 0.7 0.3 79.84 40.73
333.15 0.8 0.2 79.84 40.73
333.15 0.9 0.1 79.84 40.73
333.15 0.999 0.001 79.84 40.73

CALCULO DE LAS PRESIONES DE VAPOR:

0.8
Y1

0.6
METIL ACETATO METANOL 1
VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982 0.8
VP_C= -5.12994 VP_C= -3.1085

Y1
0.6
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9 0.4
Tc= 506.8 Tc= 512.6
T= 333.15 T= 333.15 0.2
x= 0.342640095 x= 0.350078034
0
0 0.1
 tian Cruz Huanca

2
τ 12 G 12
)+ 2
))
G 21 (x 2 + x1 G 12 )

2
τ 21 G 21
)+ 2
))
G 12 ( x 1 + x 2 G 21 )
=exp ( ¿α12 . τ 12 ) G21=exp ( ¿α12 .τ 21 )

Λ12= Λ21= α 12 = τ 12 = τ 21 = G 12= G 21= γ 1=

381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 2.737933438
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 2.262012338
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.905965907
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.639901713
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.439912523
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.289691195
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.178050889
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.097362338
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.042570606
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.010594821
381.46 346.54 0.2965 0.576250506 0.523498795 0.842941031 0.856229019 1.000001067

Metil Acetato (1) - Metanól (2) Metil Acet

1 1.4
1.2
0.8
1
Y1

0.6 NRTL
P

DIAGONA 0.8
 Metil Acetato (1) - Metanól (2) Metil Acet

1 1.4
1.2
0.8
1
Y1

0.6 NRTL

P
DIAGONA 0.8
L 0.6
0.4
0.4
0.2
0.2
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.2 0.4
X1
 Diagonal
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.000001021 1.1259659 0.846540765 0.848777907 0.003632069 0.996367931 1
1.010191581 1.1259659 0.846540765 1.024346394 0.248641355 0.751358645 1
1.041175471 1.1259659 0.846540765 1.134328507 0.378382912 0.621617088 1
1.094677865 1.1259659 0.846540765 1.202624629 0.460610908 0.539389092 1
1.174084106 1.1259659 0.846540765 1.244862994 0.520954485 0.479045515 1
1.284852486 1.1259659 0.846540765 1.269914157 0.571750578 0.428249422 1
1.435234461 1.1259659 0.846540765 1.281860869 0.620868533 0.379131467 1
1.637450393 1.1259659 0.846540765 1.280765353 0.675310898 0.324689102 1
1.909583328 1.1259659 0.846540765 1.262427187 0.743899664 0.256100336 1
2.278649864 1.1259659 0.846540765 1.217002776 0.841498307 0.158501693 1
2.779724517 1.1259659 0.846540765 1.127194284 0.997912383 0.002087617 1

Metil Acetato (1) - Metanól (2)

4
2
1
8 X1 vs
 Metil Acetato (1) - Metanól (2)

4
2
1
8 X1 vs
P
6
4
2
0
0 0.2 0.4 0.6 0.8 1 1.2
X-Y
 FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre"TORRES DE LA CRUZ JHYNO

2
G21 2
τ1
γ 1 =exp((x 2 ) (τ 21 .( )+
x 1 + x 2 G 21 (x 2 +
Presion(bar)= 1.013
2
G12 2
τ2
γ 2 =exp( ( x1 ) (τ 12 . ( )+
Volúmenes: x 2 + x 1 G 12 ( x 1+
v1= 79.84
Λ 12 Λ 21
v 2= 40.73
τ 12 =
R.T
τ 21 =
R.T
G12=exp ( −α12 .τ 12 )
Parámetros del NRTL: Λ12 = g ¿ Λ 21 = g ¿

Λ12= 206.7

Λ21= 5270.3

α 12 = 0.4
Cálculo del coeficiente de actividad:
Asumimos la temperatura de:
R Presion T (K) x1
T ( ºC )= 60 8.314 101.3 372.808115 0.001
8.314 101.3 358.8013361 0.1
T ( K )= 333.15 8.314 101.3 355.6426474 0.2
8.314 101.3 354.2923113 0.3
La constante será: 8.314 101.3 353.3782637 0.4
8.314 101.3 352.6084888 0.5
R= 8.314 8.314 101.3 352.0147078 0.6
8.314 101.3 351.561963 0.7
8.314 101.3 351.3038864 0.8
8.314 101.3 351.2688406 0.9
8.314 101.3 351.4651792 0.999

CALCULO DE LAS PRESIONES DE VAPOR:

METIL ACETATO METANOL

VP_A= -8.05406 VP_A= -8.54796
VP_B= 2.56375 VP_B= 0.76982
VP_C= -5.12994 VP_C= -3.1085
VP_D= 0.16125 VP_D= 1.54481
Pc= 46.9 Pc= 80.9
Tc= 506.8 Tc= 512.6

VP_A VP_B VP_C VP_D Pc Tc x

-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.264388092
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.292025777
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.298258391
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.300922827
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.302726394
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.304245286
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.305416914
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.306310255
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.306819482
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.306888633
-8.05406 2.56375 -5.12994 0.16125 46.9 506.8 0.306501225
ORRES DE LA CRUZ JHYNO

G21 2
τ 12 G12
)+ 2
))
x 1 + x 2 G 21 (x 2 + x1 G12 )
G 12 2
τ 21 G21
)+ 2
))
x 2 + x 1 G 12 ( x 1 + x 2 G 21 )
G12=exp ( −α12 .τ 12 ) G21=exp ( −α12 .τ 21 )

x2 Λ12 = Λ21 = α 12 = τ 12 = τ 21 = G 12=

0.999 206.7 5270.3 0.4 0.0666876017 1.7003563979 0.973677596
0.9 206.7 5270.3 0.4 0.0692909323 1.7667344006 0.972664202
0.8 206.7 5270.3 0.4 0.0699063492 1.7824258932 0.972424793
0.7 206.7 5270.3 0.4 0.0701727876 1.7892193626 0.972321162
0.6 206.7 5270.3 0.4 0.0703542964 1.7938473543 0.972250571
0.5 206.7 5270.3 0.4 0.0705078859 1.7977634786 0.972190842
0.4 206.7 5270.3 0.4 0.0706268191 1.8007959594 0.972144593
0.3 206.7 5270.3 0.4 0.070717773 1.8031150416 0.972109225
0.2 206.7 5270.3 0.4 0.070769724 1.8044396549 0.972089025
0.1 206.7 5270.3 0.4 0.0707767847 1.804619682 0.972086279
0.001 206.7 5270.3 0.4 0.0707372467 1.8036115692 0.972101653
 VP_A VP_B VP_C VP_D Pc Tc
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6
 Diagonal
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

POTENCIA(10;(B$13-(B$14/(B$15+A28))))

G 21= γ 1= γ 2= Pvp1 Pvp2 y1 y2

0.506544775 5.803855413 1.000003413 223.1401275 100.100293846 0.01278453146 0.98717211155
0.493272381 3.446712849 1.03057138 134.4908078 59.2041987378 0.45760236453 0.54208033063
0.490186005 2.306352312 1.107765584 119.226626 52.2543535001 0.54289951549 0.45714175269
0.488855788 1.741351227 1.217677699 113.1570433 49.5001927189 0.58355228874 0.41651230532
0.487951657 1.432357312 1.353498398 109.1965793 47.7061294264 0.61760520744 0.38244917922
0.487187904 1.250970865 1.51154961 105.9516002 46.2380386631 0.65420713205 0.34497082591
0.486597307 1.139948925 1.689484564 103.5038837 45.1317850229 0.69884979865 0.30108372811
0.486146132 1.07111231 1.885918215 101.6694513 44.303363846 0.75251313523 0.24744083178
0.485888618 1.029537527 2.099896691 100.6359876 43.8369080716 0.81823120046 0.18174329363
0.48585363 1.007143049 2.330929774 100.4963268 43.7738859784 0.89923750587 0.10072443646
0.486049588 1.000000717 2.576376706 101.2808481 44.1279456861 0.99881184448 0.00112231206

Metil Acetato (1) - Metanól (2)

0.9

0.8

0.7

0.6
Y1

NRTL
DIAGONA
 Metil Acetato (1) - Metanól (2)

0.9

0.8

0.7

0.6

Y1
NRTL
0.5 DIAGONA
x L
0.272711442 0.4
0.30003641
0.306198503 0.3
0.308832791 0.2
0.310615951
0.312117657 0.1
0.313276028
0
0.314159261 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.314662727
X1
0.314731095
0.31434807
 COMPONENTE 1 CONPONENTE2
y1+y2 A 7.28781 7.19621
0.999956643
0.999682695 B 1623.22 1730.63
1.000041268
1.000064594 C -44.17 -39.724
1.000054387
0.999177958
0.999933527
0.999953967
0.999974494
0.999961942
0.999934157

Metil Acetato (1) - Metanól (2)

375

370

365

NRTL 360
T

X1 vs
DIAGONA
 Metil Acetato (1) - Metanól (2)

375

370

365

NRTL T 360
X1 vs
DIAGONA
T
L
355

350

345

340
1 0 0.2 0.4 0.6 0.8 1 1.2
X-Y
X1 vs
X1 vs
T
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Presion Total 1

DATOS EXPERIMENTALES:
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340 Presion T x1
0.03 0.333 335.15 1 345.7995517 0.001
0.0505 0.445 332.55 1 321.9016854 0.1
0.107 0.49 330.35 1 324.0167872 0.2
0.124 0.5 330.1 1 325.0375458 0.3
0.248 0.522 329.4 1 325.426516 0.4
0.401 0.5365 328.95 1 325.5164608 0.5
0.505 0.5483 328.85 1 325.5160035 0.6
0.55 0.552 328.8 1 325.7511579 0.7
0.603 0.561 328.85 1 326.7186232 0.8
0.727 0.595 329.15 1 329.5135658 0.9
1 1 337.85 1 337.1684589 0.999

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )
+ q 1 ln
x1 2 Φ1( ) ( )
+Φ 2 l 1 − l 2 −q 1 ln ( θ 1 +θ 2 τ 21 ) +θ 2 q1
r2 ( −
θ1 +θ 2 τ 21 θ 2 +θ1 τ 12 )
Φ2 z θ r τ 12 τ 21
ln γ 2 =ln
( )
x2 2 Φ2 ( ) ( r1 )
+ q2 ln 2 +Φ 1 l 2− 2 l 1 −q2 ln ( θ 2 +θ 1 τ 12 ) +θ 1 q 2
(
−
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 )
−a 12

z Φi =
r i xi qi x i
τ 12 =exp ( )
T
θi =
li= ( r i−q i ) −( r i−1 ) NC NC
−a
=exp (
T )
2 ∑
j
rj x j ∑ qj xj
j
τ 21 21

r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
a12 = -29.64

z= 10

l1 l2 Φ1 Φ2 θ1 θ2 τ 12
 l1 l2 Φ1 Φ2 θ1 θ2 τ 12
-0.43 0.22 0.000429675 0.999570325 0.000507342 0.999492658 1.089495121
-0.43 0.22 0.045541401 0.954458599 0.053338307 0.946661693 1.096450126
-0.43 0.22 0.096949153 0.903050847 0.112509835 0.887490165 1.09579129
-0.43 0.22 0.155434783 0.844565217 0.178526841 0.821473159 1.09547654
-0.43 0.22 0.222568093 0.777431907 0.252650177 0.747349823 1.095357145
-0.43 0.22 0.300420168 0.699579832 0.336470588 0.663529412 1.095329579
-0.43 0.22 0.391780822 0.608219178 0.432024169 0.567975831 1.095329719
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.095257724
-0.43 0.22 0.632044199 0.367955801 0.669789227 0.330210773 1.094962663
-0.43 0.22 0.794444444 0.205555556 0.820267686 0.179732314 1.094120422
-0.43 0.22 0.997674419 0.002325581 0.998029887 0.001970113 1.091888296

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4

VP_A VP_B VP_C VP_D Pc Tc x

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.325400797
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.372021683
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.36789546
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.365904124
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.365145306
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.364969838
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.364970731
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.364511982
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.362624613
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.357172131
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.342238668
oseph Christian Cruz Huanca

x2 ln γ 1 = ln γ 2 = γ 1= γ 2= Pvp1 Pvp2
0.999 4.3196057214 1.78004E-05 75.15898887 1.000017801 1.385109266 0.896786026
0.9 2.44357009283 0.093025438 11.51407377 1.097489653 0.52682858 0.398632486
0.8 1.5833902672 0.238401396 4.871443341 1.26921855 0.577589438 0.430749685
0.7 1.07622785133 0.404551198 2.933592706 1.498629761 0.603520627 0.446971577
0.6 0.73126734426 0.588747283 2.077712116 1.801729944 0.613655939 0.453279807
0.5 0.48207205698 0.791707434 1.619426472 2.207161794 0.616019848 0.454748568
0.4 0.29847082254 1.015481212 1.347796211 2.760691554 0.61600781 0.454741091
0.3 0.16488894625 1.262988446 1.17926215 3.535972778 0.622224138 0.45859895
0.2 0.07293002191 1.538173578 1.075655262 4.656078537 0.648356167 0.474746205
0.1 0.01838004486 1.846378474 1.018549998 6.336828928 0.729076 0.523951315
0.001 1.8806835E-06 2.191647234 1.000001881 8.949943633 0.994313101 0.679683927

METANOL (1) - TETRACLORURO DE CARBONO

τ 21 τ 12
q1
( −
θ1 +θ 2 τ 21 θ 2 +θ1 τ 12 ) 0.9
1

0.8
τ 12 τ 21
q2
( −
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 ) 0.7
Y1

0.6
0.5
−a 12
τ 12 =exp
T( ) 0.4

−a 0.3
=exp (
T )
21
τ 21
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1

τ 21
 τ 21
0.038317032
0.030076228
0.030772102
0.031110357
0.031239665
0.031269599
0.031269446
0.031347762
0.031670835
0.032611964
0.035247511

VP_A VP_B VP_C VP_D Pc Tc

-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4
 DIAGONAL:
0 0
0.2 0.2
0.4 0.4
0.6 0.6
0.8 0.8
1 1

y1 y2 y1+y2
0.10410341194 0.895905187 1.000008599
0.60659431362 0.393745526 1.00033984
0.56273884463 0.437372393 1.000111238
0.53114511264 0.468891436 1.000036548
0.51000015175 0.49001268 1.000012832
0.49879942473 0.501851833 1.000651258
0.49815179581 0.502159956 1.000311752
0.51363576224 0.486478021 1.000113783
0.5579261778 0.442091123 1.0000173
0.66834032259 0.332018985 1.000359308
0.99332065557 0.006083133 0.999403788

ACLORURO DE CARBONO (2) METANOL (1) - TETRACLORURO DE CA

355
350
345
340
UNIQUAC 335
T

DAT. EXP.
330
DIAGONAL
325
320
315
310
305
0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
1 X-Y
 x
0.37850547868
0.42145635255
0.41765494745
0.41582037063
0.41512128693
0.41495963193
0.41496045381
0.41453781829
0.41279902378
0.40777576245
0.39401786682
1) - TETRACLORURO DE CARBONO (2)

X1 vs T
(CALC.)
Y1 vs T
(CALC.)
X1 vs T (EXP.)

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X-Y
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Temperatura 328

DATOS EXPERIMENTALES:

x y P(bar) x1 x2 ln γ 1 =
0.005587 0.0514 0.43427 0.001 0.999 4.572531345
0.0234 0.3692 0.75861 0.1 0.9 2.446826149
0.0343 0.3926 0.79019 0.2 0.8 1.59334703
0.0525 0.4326 0.85891 0.3 0.7 1.085663334
0.1734 0.5084 0.96216 0.4 0.6 0.739189221
0.545 0.5535 0.99515 0.5 0.5 0.488301086
0.8699 0.6724 0.91647 0.6 0.4 0.30299331
0.7 0.3 0.167770557
0.8 0.2 0.074361866
0.9 0.1 0.018762579
0.999 0.001 1.9154E-06

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Φ1 z θ1 r1 τ 21 τ 12
ln γ 1 =ln
( )+ q 1 ln
x1 2 Φ1( ) ( )
+Φ 2 l 1 − l 2 −q 1 ln ( θ 1 +θ 2 τ 21 ) +θ 2 q1
r2 ( −
θ1 +θ 2 τ 21 θ 2 +θ1 τ 12 )
Φ2 z θ2 r2 τ 12 τ 21
ln γ 2 =ln
( )+ q2 ln
x2 2 Φ2 ( ) ( )
+Φ 1 l 2− l 1 −q2 ln ( θ 2 +θ 1 τ 12 ) +θ 1 q 2
r1 ( −
θ2 +θ1 τ 12 θ 1 +θ 2 τ 21 )
−a 12

z Φi =
r i xi qi x i
τ 12 =exp ( )
T
θi =
li= ( r i−q i ) −( r i−1 ) NC NC
−a
=exp (
T )
2 ∑
j
rj x j ∑ qj xj
j
τ 21 21

r1= 1.43
r2= 3.33
q1= 1.43
q2= 2.82
a21 = 1127.95
 a12 = -29.64

z= 10

l1 l2 Φ1 Φ2 θ1 θ2 τ 12 τ 21
-0.43 0.22 0.000429675 0.999570325 0.000507342 0.999492658 1.084608955 0.032100876
-0.43 0.22 0.045541401 0.954458599 0.053338307 0.946661693 1.084608955 0.032100876
-0.43 0.22 0.096949153 0.903050847 0.112509835 0.887490165 1.084608955 0.032100876
-0.43 0.22 0.155434783 0.844565217 0.178526841 0.821473159 1.084608955 0.032100876
-0.43 0.22 0.222568093 0.777431907 0.252650177 0.747349823 1.084608955 0.032100876
-0.43 0.22 0.300420168 0.699579832 0.336470588 0.663529412 1.084608955 0.032100876
-0.43 0.22 0.391780822 0.608219178 0.432024169 0.567975831 1.084608955 0.032100876
-0.43 0.22 0.5005 0.4995 0.541959935 0.458040065 1.084608955 0.032100876
-0.43 0.22 0.632044199 0.367955801 0.669789227 0.330210773 1.084608955 0.032100876
-0.43 0.22 0.794444444 0.205555556 0.820267686 0.179732314 1.084608955 0.032100876
-0.43 0.22 0.997674419 0.002325581 0.998029887 0.001970113 1.084608955 0.032100876

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4
T= 328 T= 328
x= 0.360124854 x= 0.410496046
tian Cruz Huanca

ln γ 2 = γ 1= γ 2= Pvp1 Pvp2 P y1
2.137181E-05 96.78880578 1.000021372 0.68437917 0.496826262 0.562580285 0.11774362567
0.09075665113 11.55162534 1.095002505 0.68437917 0.496826262 1.280192577 0.61753925939
0.23642186959 4.920189419 1.266708583 0.68437917 0.496826262 1.176922302 0.57221706889
0.40345348206 2.961403567 1.496985594 0.68437917 0.496826262 1.128636104 0.53871825678
0.58873302543 2.094236862 1.801704255 0.68437917 0.496826262 1.110381228 0.51630991202
0.79314541856 1.62954541 2.210337942 0.68437917 0.496826262 1.106690436 0.50385676917
1.01901914371 1.353905407 2.770475992 0.68437917 0.496826262 1.106528887 0.50242772838
1.26971482904 1.182665225 3.559837255 0.68437917 0.496826262 1.097160202 0.51640044023
1.54969911507 1.077196536 4.710052785 0.68437917 0.496826262 1.05778428 0.5575510127
1.86486575052 1.018939702 6.455069238 0.68437917 0.496826262 0.948311788 0.66181503194
2.21931448401 1.000001915 9.201021256 0.68437917 0.496826262 0.688267409 0.99335823703

τ 12
21
−
θ 2 +θ1 τ 12 )
METANOL (1) - TETRACLORURO DE CARBONO
τ 21
−
12 θ 1 +θ 2 τ 21
)
1
0.9
0.8
0.7
Y1

0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1
 DIAGONAL:
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
y2 y1+y2 1 1
0.88225637433 1
0.38246074061 1
0.42778293111 1
0.46128174322 1
0.48369008798 1
0.49614323083 1
0.49757227162 1
0.48359955977 1
0.4424489873 1
0.33818496806 1
0.00664176297 1

ACLORURO DE CARBONO (2) METANOL (1) - TETRACLORURO DE CAR

1.4

1.2

0.8
P

UNIQUAC
DAT.EXP.
DIAGONAL 0.6

0.4

0.2

0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
 DAT.EXP.
DIAGONAL 0.6

0.4

0.2

0
.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 X-Y
ACLORURO DE CARBONO (2)

X1 vs P
(CALC.)
Y1 vs P(CALC)
X1 vs P (EXP)
Y1 vs P (EXP)

0.6 0.7 0.8 0.9 1

 Y1 vs P(CALC)
X1 vs P (EXP)
Y1 vs P (EXP)

0.6 0.7 0.8 0.9 1

FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

DATOS EXPERIMENTALES
x y T (K)
0 0 349.85
0.002 0.02 349.25
0.002 0.027 349
0.004 0.12 345.5
0.013 0.2415 340.75
0.017 0.264 340
0.03 0.333 335.15
0.0505 0.445 332.55
0.107 0.49 330.35 T x1 x2 γ 1=
0.124 0.5 330.1 348.3160334 0.001 0.999 20.27130067
0.248 0.522 329.4 328.3428421 0.1 0.9 7.505293705
0.401 0.5365 328.95 327.9782059 0.2 0.8 3.866465684
0.505 0.5483 328.85 328.2441135 0.3 0.7 2.51258245
0.55 0.552 328.8 328.3297906 0.4 0.6 1.858673253
0.603 0.561 328.85 328.3144127 0.5 0.5 1.494498073
0.727 0.595 329.15 328.3578238 0.6 0.4 1.275432079
1 1 337.85 328.6979679 0.7 0.3 1.139720569
329.7157587 0.8 0.2 1.057595363
332.0831504 0.9 0.1 1.01367919
337.2209776 0.999 0.001 1.000001331

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Grupos funcionales:
Me tan ol=CH 3 OH . .. . .. . . .. . . .. . . .. . . .. . . .. Un∗subgrupoCH 3 OH
Tetracloruro . . de . .Carbono=CCl4 . .. . . .. Un∗subgrupoCCl4
Sub-Grupo k Rk Qk v k 1 ( me tan ol ) v k 2 (tertracloruro)
CH 3 OH 1 1.4311 1.432 1 0
CCl4 2 3.39 2.91 0 1

R1= 1.4311 Q1= 1.432 v 11 = 1 v 12= 0

R2= 3.39 Q2= 2.91 v 21 = 0 v 22 = 1

Parámetros de interaccion Binaria:

Sub-Grupo CH 3OH CCl4

Grup. funcional 6 24
CH 3OH 6 0 -67.8
 CH 3OH
CCl4 24 860.1 0

a11 = 0 a12 = -67.8

a21 = 860.1 a22 = 0

NSG NSG r i xi qi x i
Φi = θi =
Parte combinatorial: NC
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC
∑ rj x ∑ qj xj
j
k k j j

r1= 1.4311 q1= 1.432

r2= 3.39 q2= 2.91

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL TETRACLORURO DE CARBONO

VP_A= -8.54796 VP_A= -7.07139
VP_B= 0.76982 VP_B= 1.71497
VP_C= -3.1085 VP_C= -2.8993
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6
Tc= 512.6 Tc= 556.4
T= 343.6 T= 343.6
x= 0.329691767 x= 0.382458663

VP_A VP_B VP_C VP_D Pc Tc x

-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.320491546
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359456024
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.360167371
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359648628
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359481485
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359511485
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.359426797
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.358763231
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.356777685
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.352159285
-8.54796 0.76982 -3.1085 1.54481 80.9 512.6 0.342136212
n Cruz Huanca

γ 2= Pvp1 Pvp2 y1 y2 y1+y2

1.0000072887 1.520398107 0.969326945 0.030820447 0.968364676 0.999185123
1.058225204 0.694296882 0.50287031 0.521090201 0.478935033 1.000025235
1.1866319017 0.683752745 0.49644401 0.528741305 0.471277039 1.000018345
1.3674838929 0.691428599 0.501123837 0.521181409 0.479695142 1.000876551
1.6066440307 0.693917136 0.502639157 0.515906088 0.48453732 1.000443408
1.9189478557 0.693469924 0.502366908 0.518194733 0.482007951 1.000202683
2.3275230408 0.694733002 0.503135754 0.531650855 0.468424024 1.000074878
2.8660156414 0.704696624 0.50919241 0.562210066 0.437806024 1.00001609
3.5830337777 0.735227831 0.527662198 0.622058836 0.378126296 1.000185132
4.5502135073 0.810549137 0.572683956 0.739473114 0.260583427 1.000056541
5.8639327576 0.996377876 0.680865738 0.995382823 0.003992551 0.999375374

METANOL (1) - TETRACLORURO DE CARBONO(2)

1
0.9
0.8
0.7
0.6 UNIFAC
y1

0.5 DAT. EXP.

DIAGONAL
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
 0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1

z Φi z θi Φi NC
qi x i li  (ri  q i )  ( ri  1) ln γ Ci =ln ( )+ q ln ( )+l ¿ ) ∑ x j l j
θi = NC 2 xi 2 i Φi xi j
∑ qj xj
j
Φ1 = Φ2 = θ1 = θ2 = l1 = l2=
0.000422397 0.999577603 0.000492346 0.999507654 -0.4356 0.01
0.044804343 0.955195657 0.051842734 0.948157266 -0.4356 0.01
0.095463308 0.904536692 0.109547124 0.890452876 -0.4356 0.01
0.153204655 0.846795345 0.174166869 0.825833131 -0.4356 0.01
0.219625236 0.780374764 0.247024323 0.752975677 -0.4356 0.01
0.29684097 0.70315903 0.329801935 0.670198065 -0.4356 0.01
0.387716399 0.612283601 0.424673784 0.575326216 -0.4356 0.01
0.496227901 0.503772099 0.534499307 0.465500693 -0.4356 0.01
0.62806109 0.37193891 0.663116462 0.336883538 -0.4356 0.01
0.791639777 0.208360223 0.815799468 0.184200532 -0.4356 0.01
0.997634431 0.002365569 0.997969972 0.002030028 -0.4356 0.01

VP_A VP_B VP_C VP_D Pc Tc x

-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.37398268613
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40987986678
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.41053521592
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.41005730866
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40990332386
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40993096213
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40985294066
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.4092416105
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40741236756
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.40315752976
-7.07139 1.71497 -2.8993 -2.49466 45.6 556.4 0.39392347657
DIAGONAL:
x y
0 0
0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

METANOL (1) - TETRACLORURO DE CARBONO (2)

355

350

345

340 X1 vs T (CALC)
Y1 vs T (CALC)
T

335 X1 vs T (EXP)
330 Y1 vs T (EXP)

325

320

315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
 320

315
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y

X .Q Θmi Ψ
Φi
xi
NC
)∑ x j l j
j
v mi
X mi= NSG
∑ v ni
n
Θ mi= NSG mi m
∑ X ni . Qn
n
Ψ mn =EXP
−a mn
( )
T [
Ln Γ ki=Q k 1−Ln ∑ Θmi Ψ mk −∑
( m ) m (∑
n
Θn

ln γ C
1=
C
ln γ 2 = Ψ 11 = Ψ 12 = Ψ 21 = Ψ 22 = Ln Γ 11= Ln Γ 12=
-0.204277755 -1.3145327E-07 1 1.214886693 0.084643307 1 0 3.228333088
-0.178267174 -0.00140816381 1 1.229357262 0.072837959 1 0 3.422710241
-0.152102161 -0.00605876979 1 1.229639519 0.072626141 1 0 3.426476464
-0.126253854 -0.0147194679 1 1.229433618 0.072780593 1 0 3.423729164
-0.101007992 -0.02837487165 1 1.229367353 0.072830375 1 0 3.422844904
-0.076758575 -0.04830303347 1 1.229379244 0.072821439 1 0 3.423003584
-0.05405332 -0.07618489491 1 1.22934568 0.072846665 1 0 3.422555677
-0.033661692 -0.11426350284 1 1.229083031 0.073044392 1 0 3.419050192
-0.016678554 -0.16557924387 1 1.228300693 0.073636789 1 0 3.408603687
-0.004684877 -0.2343216312 1 1.226501409 0.075018992 1 0 3.384549992
-5.30312E-07 -0.32529605197 1 1.22269215 0.078038493 1 0 3.333496839
X 11 = 1 Θ 11= 1
X 12 = 0 Θ 12= 0
Θ 21 =
 X 21 = 0 Θ 21
21
= 0
X 22 = 1 Θ 22 = 1

Θmi Ψ km ∑ x j v nj x m .Q m
( ∑ )]
Θm Ψ km
∑ Θmi Ψ mk −∑
( m ) m
n
Θni Ψ nm X m= j

∑ ∑ x j v nj
n j
Θ m=
∑ x n Qn
n
[
Ln Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m (∑ )]
n
Θn Ψ nm

Ln Γ 21= Ln Γ 22= X 1= X 2= Θ1 = Θ2 = Ln Γ 1= Ln Γ 2=
2.097254103 0 0.001 0.999 0.000492346 0.999507654 3.213483881 7.4201255E-06
2.097151327 0 0.1 0.9 0.051842734 0.948157266 2.193875773 0.05800133283
2.097099665 0 0.2 0.8 0.109547124 0.890452876 1.504442991 0.17717772923
2.097137528 0 0.3 0.7 0.174166869 0.825833131 1.047564943 0.32769194461
2.097149511 0 0.4 0.6 0.247024323 0.752975677 0.720870921 0.50252242216
2.097147368 0 0.5 0.5 0.329801935 0.670198065 0.478548988 0.7000800775
2.097153409 0 0.6 0.4 0.424673784 0.575326216 0.297338326 0.92098952439
2.09719981 0 0.7 0.3 0.534499307 0.465500693 0.164444809 1.16718628981
2.097328803 0 0.8 0.2 0.663116462 0.336883538 0.07267636 1.44178910937
2.097572449 0 0.9 0.1 0.815799468 0.184200532 0.018271351 1.74949578773
2.097837621 0 0.999 0.001 0.997969972 0.002030028 1.86139E-06 2.0941165495
 Θm Ψ km
∑ Θm Ψ mk )−∑
m (∑ )]
n
Θn Ψ nm
R
Lnγ i =∑ v kj ( Ln Γ k −Ln Γ kj )
k
C
Lnγ i=Lnγ i +Ln γi
R

Ln γ R
1= Ln γ R
2=
Ln γ 1= Ln γ 2= γ 1= γ 2=
3.213483881 7.4201255E-06 3.009206126 7.2886723E-06 20.27130067 1.000007289
2.193875773 0.05800133283 2.015608599 0.05659316902 7.505293705 1.058225204
1.504442991 0.17717772923 1.35234083 0.17111895944 3.866465684 1.186631902
1.047564943 0.32769194461 0.921311089 0.31297247672 2.51258245 1.367483893
0.720870921 0.50252242216 0.619862928 0.47414755051 1.858673253 1.606644031
0.478548988 0.7000800775 0.401790414 0.65177704403 1.494498073 1.918947856
0.297338326 0.92098952439 0.243285007 0.84480462948 1.275432079 2.327523041
0.164444809 1.16718628981 0.130783118 1.05292278697 1.139720569 2.866015641
0.07267636 1.44178910937 0.055997806 1.2762098655 1.057595363 3.583033778
0.018271351 1.74949578773 0.013586475 1.51517415653 1.01367919 4.550213507
1.86139E-06 2.0941165495 1.33108E-06 1.76882049753 1.000001331 5.863932758
FIQ-UNCP "Termodinámica de los Procesos Quimicos II - VI Semestre" Joseph Christian Cruz Huanca

Temperatura 328

DATOS EXPERIMENTALES:

x y P(bar) T x1 x2 γ 1=
0.005587 0.0514 0.43427 328 0.001 0.999 24.6412256
0.0234 0.3692 0.75861 328 0.1 0.9 7.512383307
0.0343 0.3926 0.79019 328 0.2 0.8 3.866403286
0.0525 0.4326 0.85891 328 0.3 0.7 2.512614806
0.1734 0.5084 0.96216 328 0.4 0.6 1.858559129
0.545 0.5535 0.99515 328 0.5 0.5 1.494384994
0.8699 0.6724 0.91647 328 0.6 0.4 1.27533507
328 0.7 0.3 1.139601485
328 0.8 0.2 1.057450636
328 0.9 0.1 1.013582496
328 0.999 0.001 1.000001306

CALCULO DE LOS COEFICIENTES DE ACTIVIDAD:

Grupos funcionales:

Me tan ol=CH 3 OH . .. . .. . . .. . . .. . . .. . . .. . . .. Un∗subgrupoCH 3 OH

Tetracloruro. . de . .Carbono=CCl4 . .. . . .. Un∗subgrupoCCl4
Sub-Grupo k Rk Qk v k 1 ( me tan ol ) v k 2 (tertracloruro)
CH 3 OH 1 1.4311 1.432 1 0
CCl4 2 3.39 2.91 0 1

R1= 1.4311 Q1= 1.432 v 11 = 1 v 12= 0

R2= 3.39 Q2= 2.91 v 21 = 0 v 22 = 1

Parámetros de interaccion Binaria:

Sub-Grupo CH 3OH CCl4

Grup. funcional 6 24
CH 3OH 6 0 -67.8
 CH 3OH
CCl4 24 860.1 0

a11 = 0 a12 = -67.8

a21 = 860.1 a22 = 0

NSG NSG r i xi qi x i
Parte combinatorial: Φi = θi =
r i= ∑ v ki . R k qi = ∑ v ki . Q k NC
∑ rj x j
NC
∑ qj xj
k k j j

r1= 1.4311 q1= 1.432

r2= 3.39 q2= 2.91

CALCULO DE LAS PRESIONES DE VAPOR:

METANOL (1
METANOL TETRACLORURO DE CARBONO
VP_A= -8.54796 VP_A= -7.07139 1
VP_B= 0.76982 VP_B= 1.71497 0.9
VP_C= -3.1085 VP_C= -2.8993
0.8
VP_D= 1.54481 VP_D= -2.49466
Pc= 80.9 Pc= 45.6 0.7
Y1

Tc= 512.6 Tc= 556.4 0.6

T= 328 T= 328
x= 0.360124854 x= 0.410496046 0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0
tian Cruz Huanca DIAGONAL:
0
0.2
0.4
0.6
0.8
1

γ 2= Pvp1 Pvp2 P y1 y2 y1+y2

1.000008637 0.68437917 0.496826262 0.513197664 0.032860519 0.967139481 1
1.058335512 0.68437917 0.496826262 0.987359853 0.520713763 0.479286237 1
1.186615442 0.68437917 0.496826262 1.000850546 0.528767433 0.471232567 1
1.367770008 0.68437917 0.496826262 0.991555212 0.520267923 0.479732077 1
1.607164019 0.68437917 0.496826262 0.987872436 0.515029717 0.484970283 1
1.919565029 0.68437917 0.496826262 0.988208139 0.517464854 0.482535146 1
2.328344481 0.68437917 0.496826262 0.986400728 0.530907611 0.469092389 1
2.867753107 0.68437917 0.496826262 0.973376179 0.560876334 0.439123666 1
3.587095229 0.68437917 0.496826262 0.935390373 0.618947733 0.381052267 1
4.556697511 0.68437917 0.496826262 0.850695971 0.733878252 0.266121748 1
5.859916216 0.68437917 0.496826262 0.686607044 0.995759787 0.004240213 1

R1 R2 Q1 Q2 v 11 = v 12= v 21 =
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0
 1.4311 3.39 1.432 2.91 1 0 0
1.4311 3.39 1.432 2.91 1 0 0

z Φi z θi Φi NC
qi x i li  (ri  q i )  ( ri  1) ln γ Ci =ln ( )+ q ln ( )+l ¿ ) ∑ x j l j
θi = NC 2 xi 2 i Φi xi j
∑ qj xj
j Φ1 = Φ2 = θ1 = θ2 = l1 = l2 =
0.000422397 0.999577603 0.000492346 0.999507654 -0.4356 0.01
0.044804343 0.955195657 0.051842734 0.948157266 -0.4356 0.01
0.095463308 0.904536692 0.109547124 0.890452876 -0.4356 0.01
0.153204655 0.846795345 0.174166869 0.825833131 -0.4356 0.01
0.219625236 0.780374764 0.247024323 0.752975677 -0.4356 0.01
0.29684097 0.70315903 0.329801935 0.670198065 -0.4356 0.01
0.387716399 0.612283601 0.424673784 0.575326216 -0.4356 0.01
0.496227901 0.503772099 0.534499307 0.465500693 -0.4356 0.01
0.62806109 0.37193891 0.663116462 0.336883538 -0.4356 0.01
0.791639777 0.208360223 0.815799468 0.184200532 -0.4356 0.01
0.997634431 0.002365569 0.997969972 0.002030028 -0.4356 0.01

METANOL (1) - TETRACLORURO DE CARBONO (2) METANOL (1)

1 1.2
0.9
1
0.8
0.7
0.8
Y1

0.6 UNIFAC
P

DAT. EXP. 0.6

0.5
DIAGONAL
0.4
0.4
0.3
0.2
0.2
0.1
0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3
X1
 0
0.2
0.4
0.6
0.8
1

v 22 = r1 r2 q1 q2 X 11 = X 12 = X 21 =
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0
 1 1.4311 3.39 1.432 2.91 1 0 0
1 1.4311 3.39 1.432 2.91 1 0 0

X .Q Θmi Ψ
Φi
xi
NC
)∑ x j l j
j
v mi
X mi= NSG
∑ v ni
n
Θ mi= NSG mi m
∑ X ni . Qn
n
Ψ mn =EXP
−a mn
( )
T [
LnΓ ki=Q k 1−Ln ∑ Θmi Ψ mk −∑
( m ) m (∑
n
Θn

ln γ C
1=
C
ln γ 2 = Ψ 11 = Ψ 12 = Ψ 21= Ψ 22 = Ln Γ 11= Ln Γ 12=
-0.204277755 -1.3145327E-07 1 1.22962263 0.072638798 1 0 3.426251126
-0.178267174 -0.00140816381 1 1.22962263 0.072638798 1 0 3.426251126
-0.152102161 -0.00605876979 1 1.22962263 0.072638798 1 0 3.426251126
-0.126253854 -0.0147194679 1 1.22962263 0.072638798 1 0 3.426251126
-0.101007992 -0.02837487165 1 1.22962263 0.072638798 1 0 3.426251126
-0.076758575 -0.04830303347 1 1.22962263 0.072638798 1 0 3.426251126
-0.05405332 -0.07618489491 1 1.22962263 0.072638798 1 0 3.426251126
-0.033661692 -0.11426350284 1 1.22962263 0.072638798 1 0 3.426251126
-0.016678554 -0.16557924387 1 1.22962263 0.072638798 1 0 3.426251126
-0.004684877 -0.2343216312 1 1.22962263 0.072638798 1 0 3.426251126
-5.30312E-07 -0.32529605197 1 1.22962263 0.072638798 1 0 3.426251126

METANOL (1) - TETRACLORURO DE CARBONO (2)

1.2

0.8 X1 vs P (CALC.)
P

Y1 vs P (CALC.)
0.6 X1 vs P (EXP.)
Y1 vs P (EXP.)
0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y
X 22 = Θ 11= Θ 12 = Θ 21 = Θ 22 = a11 = a12 = a21 =
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1
 1 1 0 0 1 0 -67.8 860.1
1 1 0 0 1 0 -67.8 860.1

Θmi Ψ km ∑ x j v nj x m .Q m
( ∑ )]
Θm Ψ km
∑ Θmi Ψ mk −∑
( m ) m
n
Θni Ψ nm X m= j

∑ ∑ x j v nj
n j
Θ m=
∑ x n Qn
n
[
Ln Γ k =Qk 1−Ln
(∑ Θm Ψ mk )−∑
m m (∑ )]
n
Θn Ψ nm

Ln Γ 21= Ln Γ 22 = X 1= X 2= Θ1 = Θ2 = Ln Γ 1= Ln Γ 2=
2.097102806 0 0.001 0.999 0.000492346 0.999507654 3.408698633 8.7688366E-06
2.097102806 0 0.1 0.9 0.051842734 0.948157266 2.194819941 0.05810556597
2.097102806 0 0.2 0.8 0.109547124 0.890452876 1.504426852 0.17716385854
2.097102806 0 0.3 0.7 0.174166869 0.825833131 1.04757782 0.32790115042
2.097102806 0 0.4 0.6 0.247024323 0.752975677 0.720809518 0.50284601866
2.097102806 0 0.5 0.5 0.329801935 0.670198065 0.478473322 0.70040164646
2.097102806 0 0.6 0.4 0.424673784 0.575326216 0.297262264 0.92134238661
2.097102806 0 0.7 0.3 0.534499307 0.465500693 0.164340318 1.16779233652
2.097102806 0 0.8 0.2 0.663116462 0.336883538 0.072539504 1.44292199038
2.097102806 0 0.9 0.1 0.815799468 0.184200532 0.018175957 1.75091976239
2.097102806 0 0.999 0.001 0.997969972 0.002030028 1.83658E-06 2.09343135778
a22 =
0
0
0
0
0
0
0
0
0
 0
0

Θm Ψ km
∑ Θm Ψ mk )−∑
m (∑ )]
n
Θn Ψ nm
R
Lnγ i =∑ v kj ( Ln Γ k −Ln Γ kj )
k
C
Lnγ i=Lnγ i +Ln γi
R

Ln γ R
1= Ln γ R
2=
Ln γ 1= Ln γ 2= γ 1= γ 2=
3.408698633 8.7688366E-06 3.204420878 8.63738E-06 24.6412256 1.000008637
2.194819941 0.05810556597 2.016552767 0.056697402 7.512383307 1.058335512
1.504426852 0.17716385854 1.352324691 0.171105089 3.866403286 1.186615442
1.04757782 0.32790115042 0.921323966 0.313181683 2.512614806 1.367770008
0.720809518 0.50284601866 0.619801526 0.474471147 1.858559129 1.607164019
0.478473322 0.70040164646 0.401714747 0.652098613 1.494384994 1.919565029
0.297262264 0.92134238661 0.243208944 0.845157492 1.27533507 2.328344481
0.164340318 1.16779233652 0.130678627 1.053528834 1.139601485 2.867753107
0.072539504 1.44292199038 0.055860951 1.277342747 1.057450636 3.587095229
0.018175957 1.75091976239 0.013491081 1.516598131 1.013582496 4.556697511
1.83658E-06 2.09343135778 1.30626E-06 1.768135306 1.000001306 5.859916216