INORGANIC CHEMISTRY

Daily Assignment
Home Work DPP

Thermodynamics (1)

1. What is limitation of first law of the thermodynamics

(a) Does not predict about the direction of flow of heat
(b) Does not tell whether the reaction is feasible or not
(c) a and b both
(d) None of these
2. Entropy is
(1) It is the degree of disorder of randomness in a system
(2) Entropy is a state function and mixing is always positive
(3) Entropy is a intensive property
(4) Entropy of solid is minimum and gases is maximum
(5) Entropy increase with temperature, and complexity and atomicity
CHEM ACADEMY
Right statement is
(a) 1, 2, 3, 4 (b) 1, 2, 4, 5 (c) 2, 3, 4 (d) 1, 3, 5
3. 64 gram oxygen is compressed adiabatically and reversibility at 25ºC from 1 atmosphere until 2
atmosphere Assume that CP = 29.33 J/K for oxygen and Assume ideally determine the dU and V2?
Respectively
(a) 2.717 KJ, 29.74 L (b) 27.17 KJ, 29.74 L
(c) 27.717 KJ, 2.974 L (d) 27.17 KJ, 2.974 L
4. 2 mole of CH4 is expanded adiabatic and reversible until triple volume the temperature declines
from 298 K to 213 K Calculate work done is
(a) +4616 (b) +2308 J (c) –2308 J (d) –4616 J
5. For which of the following pairs choose the substances with the higher entropy per mole at a given
temperature
(i) O2 gas at 5 atm or O2 gas at 0.5 atm (ii) Br2(l) or Br2(g)
(a) O2 gas at 5 atm (ii) Br2(l) (b) O2 gas at 0.5 atm (ii) Br2(l)
(c) O2 gas at 5 atm (ii) Br2 gas (d) O2 gas at 0.5 atm (iii) Br2 gas
6. For which of the following process will Sº system be the most positive
(a) 2SO2(g) + O2(g)  2SO3(g) (b) 2NH3(g)  N2(g) + 3H2(g)
(c) Hg(l)  Hg(s) (d) 4Fe(s) + 3O2(g)  2Fe2O3(s)
7. The molar heat of vaporization for ethanol is 37.4 KJ/mole if the boiling point of ethanol is 78.0ºC
calculate S in J/K for the vaporization of 0.500 mole ethanol.
(a) 53.3 (b) 107 (c) 0.053 (d) 240

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8. If the Entropy for C2H2 gas is 230 then what is the absolute molar Entropy for this
(a) 230 J/K mole (b) 115 J/K mole
(c) 57.5 J/K mole (d) cannot predict (data not sufficient)

 P 
9. For the gaseous substance  T  = ?
 v

(a)  /  (b)  /  (c)  /  (d)  / 

10. For a gaseous substances Cp – Cv =

 P   V   P   V   T   V   T   T 
(a) V  T   T  (b) T  T   T  (c) T  P   T  (d) T  P   V 
 v  p  v  p  v  p  v  p

11. Among the following the system require higher amount of thermal energy to giving the temperature
80ºC
(a) 200 gm at 40ºC (b) 100 gm at 20ºC (c) 150 gm at 50ºC (d) 300 gm at 30ºC
12. What is the internal pressure for 4 mole of Vandar walls gas.

a 4a 16a
(a) zero (b) (c) (d)
V2 V2 V2
13. Which relation is correct in this equation
(1) P – 1V – 
(a) 1, 2, 3
CHEM ACADEMY
(2) T – 1 V 1 – 
(b) 1, 2
(3) P1 –  T – 
(c) 1, 3 (d) 2, 3
14. Which statement is correct
(1) Piso > Padia (2) Viso > Vadia (3) qrev < qirren (4) wiso > wadia
(a) 1, 2, 4 (b) 1, 2, 3, 4 (c) 2, 3 (d) 1, 4, 3
15. µJT for ideal and Vander walls gases respectively

1  2a  1  2a  1  2a 
(a) 0, 0 (b) O, C  RT  b  (c) P, C  RT  b  (d) O, C  RT  b 
P   P   V  
16. Match the following
(1) 2a / Rb (A) Ti
(2) a / Rb (B) TB
(3) 8a / 27 Rb (C) TC
1 2 3
(a) B C A
(b) A B C
(c) C B A
(d) A C B
17. dU for Isothermal Process for Vander walls gas and Ideal gas respectively

2  1 1 
(a) n a  2  1  ,O(zero) (b) O(Zero), O(Zero)
V V 
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 2  1 1  2  1 1 
(c) n a  2  1  , O Zero (d) n a  1  2  , T
V V  V V 
18. For an irreversible isothermal expansion of a perfect gas from Vi to Vf, the change in entropy of the
gas is
(a) NR ln(Vf / Vi) (b) Zero (c) less than zero (d) greater than zero
19. For the reaction
N2(g) + 3H2(g)  2NH3(g)
Compute the entropy change (in J / Kl / mol) for the process comment on the sign of the property.
Data : Species NH3(g) N2(g) H2(g)
S  (J/K/mol) 192.3 191.5 130.6
(a) Sº = –37.65 J/k/mol, negative sign indicates that there a decrease in the gaseous species during
the reaction.
(b) Sº = –198.7 J/k/mol, negative sign indicates that there a decrease in the gaseous species during
the reaction.
(c) Sº = –31.25 J/K/mol, negative sign indicates that there a decrease in the gaseous species
during the reaction.
(d) Sº = +31.25 J/K/mol, the positive sign indicates that there reaction is spontaneous.
20. Match the following:
 U 
P.
 CHEM ACADEMY
 S 
V
 U 
1. A

Q.  V  2. S
 S
 G 
R.  P  3. P
 T
 G 
S.  T  4. P
 P
5. H
6. V
(a) P – 3, Q – 4, R – 6, S – 2 (b) P – 3, Q – 1, R – 2, S – 5
(c) P – 1, Q – 3, R – 5, S – 2 (d) P – 4, Q – 3, R – 6, S – 5
21. Standard entropy of crystalline carbon monoxide (in KJ/mol) at 0  K is around.
(a) 0.03 (b) 2.50 (c) zero (d) 5.76

(C P  C V )
22. If a gas obeys the equation of state P(v – nB) = nRT the ratio (C  C ) is
P V ideal

(a) > 1 (b) < 1 (c) 1 (d) (1 – b)

23. Two moles of a monatomic perfect gas initially 4.0 bar and 47  C under goes reversible expansion
in an insulated container. The temperature at which the presser reduces to 3.0 bar is.
(a) 200 K (b) 285 K (c) 310 K (d) 320 K

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24. Choose the correct criterion of spontaneity in terms of the proporties of the system alone.
(a) (dS)U, V > 0 (b) (dS)T, P > 0 (c) (dS)H, P < 0 (d) (dG)T, V < 0
25. A diabatic reversible expansion of a monatomic gas (M) and a diatomic gas (D) at an initial tem-
perature i, has been carried out independently from initial volume to final volume V2. The final
temperature (TM for monatomic and TD for diatomic) attained will be
(a) TM = TD > Ti (b) TM < TD < Ti (c) TM > TD > Ti (d) TM = TD = Ti
26. For the reaction
2Cl(g)  Cl2(g)
The thermodynamic properties
(a) G, H and S are positive (b) G, H and S are negative
(c) G and H are negative and S is positive
(d) G is negative and H and S are positive
27. The change in entropy when one mole of an ideal gas is compressed to one fourth of its initial
volume and simultaneously heated to twice its initial temperature is
(a) (CV – R) ln4 (b) (CV – 2R) ln2 (c) (CV – 2R) ln4 (d) (CV + 2R) ln2
 P 
28. The internal pressure, T  T  T   P for one mole a vanderwalls gas is
 V
a a  RT  RT
(a) (b)   (c) Zero (d)

29.
V2
CHEM ACADEMY V2  V  b 
Consider the following P-V diagram for an ideal gas that follows the diagonal path from A to B
Vb

(T = 300 K)
B D
20
Pressure (atm)

1 C A (T = 300 K)

0.5(L) 10(L)
Volume(L)
The work done (in atm-L) on the gas in the process is
(a) 9.5 (b) 99.75 (c) 190 (d) 10 ln 20
–1 –1
30. One mole of an ideal gas (CP = 29.234 JK mol ) is expanded reversibly and adiabatically from 1
dm3 to 10 dm3. The initial temperature is 750 K, the final temperature will be
(a) 1000 K (b) 750 K (c) 300 K (d) 100 K
31. The relationship between volume change in an isothermal process (Vi) and an adiabatic process.
(Va) for a pressure change from P1 to P2 is
(a) Vi > Va (b) Vi < Va (c) Vi = Va (d) Vi = Va = 0
32. Using Joule – Thomson effect, find the current expression for T:
(H / P)T (H / T)P
(a) T   CP
(P) (b) T  
CP
(P)

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 (U / V)T (U / T)V
(c) T   CV
(P) (d) T   CV
(P)

33. An adiabatic process is an

(a) isobaric process (b) isochoric process (c) isenthalpic process(d) isentropic process
 S 
34. For one mole of an ideal gas,  V  is equal to
 T
(a) P/T (a) T/P (c) PT (d) P/V
35. Which one of the following relations is correct
 T   P   T   V   P   S   S   V 
(a)  V    S  (b)   P    S  (c)  T    V  (d)  P    T 
 S  V  S  P  V  T  T  P
 H 
36. The change in enthalpy with respect to change in pressure at constant temperature  P  is
 T
 V   V   V   V 
(a) T  T   V (b) T  T   V (c) T  T   V (d) T  T   V
 P  P  P  P
 CP 
37. Find the value of  P 
 T
  2V    2V   2 P    2P 
(a) T  T 2  (b) T  T3  (c) T  V 2  (d) T  T 2 
 P  P  T  V
38. If a gas obey ideal gas behavior then find the value of TE2V
i.e. CHEM ACADEMY
TE2V = ?
stress
Hind elasticity 
strain
(a) –R (b) R (c) P (d) –P
39. The change in entropy when three moles of argon gas are heated at constant volume from 200 K to
300 K is
(a) 15.16 JK–1 mol–1 (b) –15.16 JK–1 mol–1 (c) –5.05 JK–1 mol–1 (d) 5.05 JK– mol–1
40. For a system of constant composition, the pressure P is given by
 U   U   V   U 
(a)   S  (b)   V  (c)   S  (d)  V 
 V  S  T  T
41. Calculate the coefficient of performance () of an engine operating between 110ºC and 25ºC. (The
efficiency of carwat engine is 22.2%)
(a) 3.5 (b) 0.222 (c) 0.778 (d) 0.1556
42. H and U for the reaction
Fe2O3(s) + 3H2(g)  2Fe(s) + 3H2O(l)
at constant temperature are related as
(a) H = U (b) H = U + RT (c) H = U + 3RT (d) H = E – 3RT

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