ASSIGNMENT NO.

- 4

Date of issue: 06/11/2014

Date of Submission: 11/11/2014

Instructions to course students in answering the course assignments:

 ANSWER NEATLY AND LEGIBLY on A4 sheets only and not in sheets torn from a book.
 Sketch diagrams wherever relevant. Explain your notations explicitly and clearly.
 An incomplete assignment is NOT acceptable for submission.
 Once you submit your assignment, you will be expected to answer all the questions
there INDEPENDENTLY. You may be asked to answer any question of the assignment in
the class.
 Leave clear left margin on every sheet.
 On the top of your fist sheet, write your Name, Class, Section, USN, Due Date and Date
of Submission.
 Page number your answer sheets sequentially.
 Staple (do not pin or clip) your sheets cleanly on the left hand top corner.

UNIT – 5
1. State and prove the Inequality of Clausius.
2. Show that entropy is the property of a system.
3. Write short note on Entropy Principle.
4. Show the entropy change of the universe during transfer of heat through a finite
temperature difference.
5. Show that mixing of two fluids is an irreversible process.
6. Find the maximum work obtainable from two finite bodies at temperatures T1
and T2.
7. Find the maximum work obtainable from a finite body and TER.

UNIT – 6

1. Define: (i) pure substance (ii) Saturation state (iii) Triple point
(iv) Critical point (v) Saturation temperature (vi) Saturation pressure
(vii) Quality (viii) Degree of the superheat (ix) Degree of subcooling
(x) Compressed liquid.
 2. Draw phase equilibrium diagram showing various parameters on:
(i) p – v coordinates (ii) T – s coordinates
(iii) p – T coordinates (iv) h – s coordinates
3. What is the main objective of quality measurement?
4. With a neat sketch explain how throttling calorimeter can be used to measure
the dryness fraction of wet vapour.
5. With a neat sketch explain how separating and throttling calorimeter can be used
to measure the dryness fraction of wet vapour.

UNIT – 8

1. Differentiate between : (i) Ideal gas and real gas (ii) Universal gas constant
and particular gas constant (iii) Perfect gas and semi – perfect gas.
2. State and explain Amagat’s law.
3. State Dalton’s law of partial pressures and hence derive an expression for the gas
R of a mixture of gases.
4. Obtain expressions for the constants ‘a’, ‘b’ and ‘R’ in terms of the critical
properties for a Vander Waal’s gas OR derive Vander Waal’s constants in terms of
critical properties.
5. Write short notes on:
i. Compressibility factor
ii. Law of corresponding states
iii. Compressibility chart
iv. Vander Waal’s equation of state
v. Generalized compressibility chart.