Thermo-Calc

85 day(s) more to enjoy this software

SYS:set-log-file

Heading:go data

SYS:go data

... the command in full is GOTO_MODULE

THERMODYNAMIC DATABASE module

Database folder: C:\Program Files\Thermo-Calc\2020b\data

Current database: Steels/Fe-Alloys v9.2

VA /- DEFINED

L12_FCC B2_BCC DICTRA_FCC_A1

REJECTED

TDB_TCFE9:

TDB_TCFE9:def-ele

... the command in full is DEFINE_ELEMENTS

ELEMENTS:C W Mo V Co Cr Fe

C W MO

V CO CR

FE DEFINED

TDB_TCFE9:get

... the command in full is GET_DATA

08:27:01,878 INFO *** Invoking Gibbs Energy System v6 ***

REINITIATING GES .....

ELEMENTS .....

SPECIES ......

PHASES .......

... the command in full is AMEND_PHASE_DESCRIPTION

... the command in full is AMEND_PHASE_DESCRIPTION

Creating a new composition set FCC_A1#2

... the command in full is AMEND_PHASE_DESCRIPTION

Creating a new composition set HCP_A3#2

... the command in full is AMEND_PHASE_DESCRIPTION

... the command in full is AMEND_PHASE_DESCRIPTION

... the command in full is AMEND_PHASE_DESCRIPTION

... the command in full is AMEND_PHASE_DESCRIPTION

Suspending M2O3C as it has net charge

PARAMETERS ...

FUNCTIONS ....

List of references for assessed data

'A. Dinsdale, SGTE Data for Pure Elements, CALPHAD, 15 (1991) 317-425'

'B. Uhrenius, Int. J. Refract. Met. Hard Mater. 12 (1994) 121-127; Molar

volumes'

'X.-G. Lu, Thermo-Calc Software AB, Sweden, 2006; Molar volumes'

'A. Fernandez Guillermet, Int. J. Thermophys., 8 (1987) 481-510; TRITA-MAC

308 (1986); CO'

'X.-G. Lu, M. Selleby and B. Sundman, CALPHAD, 29, 2005, 68-89; Molar

volumes'

'J. Bratberg and B. Sundman, J. Phase Equilib., 24, No. 6, 2003, 495-503;

Co-V'

'N. Saunders, ThermoTech 1996, Unpublished work; Co-Ti'

'W. Golumbfskie, Z.-K. Liu, J. Alloys Compd., 407, 193-200(2006); Co-Y'

'H. Mao, Thermo-Calc Software AB, Sweden, 2012; Molar volumes'

'Unassessed parameter; Linear combination of unary data'

'A. Markstrom, Swerea KIMAB, Sweden; Molar volumes'

'B. Sundman et al., Report EUR 20315, Contract No 7210-PR/050, 2002; New

Sigma model'

'P. Gustafson, TRITA-MAC 342 (1987); CR-FE-W'

'N. Saunders, COST 507 Report (1998); Cr-Ti'

'B.-J. Lee, KRISS, Unpublished research, during 1993-1995'

'Thermo-Calc Software, Sweden, 2014: Volume data updated for TCFE9

database (TCFE v9.0, Jan, 2017).'

'L.F.S. Dumitrescu, M. Hillert and N. Saunders, J. Phase Equilib., 19

(1998) 441-448; Fe-Ti'

'J-O. Andersson, CALPHAD, 12 (1988) 1-8; TRITA 0317 (1986); C-MO'

'J. Bratberg and Karin Frisk, CALPHAD, 26, No. 3, 459-476, 2002; Mo-V-C'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2015; LAVES_PHASE_C14'

'B.-J. Lee, Private communication, (1999); Estimated parameter'

'P. Gustafson, Z. Metallkd., 79 (1988) 397-402; TRITA-MAC 330 (1987); C-MO

-W'

'M. Seiersten, Unpublished work (1989); Al-Fe'

'A. Fernandez Guillermet, Z. Metallkd., 78 (1987) 700-709; TRITA-MAC 333

(1987); C-CO'

'A. Fernandez Guillermet, Z. Metallkd., 79 (1988) 317-329; TRITA-MAC 361

(1987); C-Co-FE'

'A. Fernandez Guillermet, Z. Metallkd., 79 (1988) 524-536, TRITA-MAC 362

(1988); C-CO-NI AND C-CO-FE-NI'

'P. Villars and L.D. Calvert (1985). Pearson`s handbook of

crystallographic data for intermetallic phases. Metals park, Ohio.

American Society for Metals; Molar volumes'

'A. Kusoffsky and B. Jansson, CALPHAD, 21 (1997) 321-33; Co-Cr, Co-Cr-C'

'A. Markstrom, Thermo-Calc software AB, Sweden, 2011'

'A. Fernandez Guillermet and G. Grimvall,J. Phys. Chem. Solids, 1992, 53,

105-125; Molar volumes'

'B. Kaplan, A. Markstrom, A. Blomqvist, S. Norgren, M. Selleby, CALPHAD,

46 (2014) 226-236, C-Co-Cr'

'Thermo-Calc Software, Sweden, 2014: Volume data updated for TCFE8

database (TCFE v8, May, 2015).'

'A.V. Khvan, B. Hallstedt, K. Chang, CALPHAD, 39, 54-61(2012); C-Cr-Nb'

'J-O. Andersson, CALPHAD, 11 (1987) 271-276; TRITA 0314; C-CR'

'J. Bratberg, Z. Metallkd., 96 (2005) 335-344; Fe-Cr-Mo-C'

'B.-J. Lee, CALPHAD, 16 (1992) 121-149; C-Cr-Fe-Ni'

'C. Qiu, ISIJ International, 32 (1992) 1117-1127; C-Cr-Fe-Mo'

'P. Gustafson, Metall. Trans. A, 19A (1988) 2547-2554; TRITA-MAC 348,

(1987); C-CR-FE-W'

'B.-J. Lee, Metall. Trans. A, 24A (1993) 1017-1025; Fe-Cr-Mn-C'

'P. Gustafson, Scan. J. Metall., 14 (1985) 259-267; TRITA 0237 (1984); C-FE'

'P. Franke, Estimated parameter within SGTE, 2007; Fe-C, Ni-C, Mo-C, C-Mn'

'B. Hallstedt, unpublished work (2016); C-Fe-Mn Epsilon martensite.'

'J-O. Andersson, CALPHAD, 12 (1988) 9-23; TRITA 0321 (1986); C-FE-MO'

'B. Hallstedt, D. Djurovic, J. von Appen, R. Dronskowski, A. Dick, F.

Koermann, T. Hickel, J. Neugebauer, CALPHAD, 34, 129-33(2010); Fe-C'

'D. Djurovic, B. Hallstedt, J. von Appen, R. Dronskowski, CALPHAD,

submitted, 2011; Fe-Mn-C'

'H. Du and M. Hillert, TRITA-MAC 435 (1990); C-Fe-N'

'W. Huang, Metall. Trans. A, 21A (1990) 2115-2123; TRITA-MAC 411 (Rev

1989); C-FE-MN'

'J.-H. Shim, C.-S. Oh, D.N. Lee, Metall. Mater. Trans. B. 27 (1996) 955

-966; Ti-Mo-C'

'Thermo-Calc Software, Sweden, 2019: Volume data updated for TCFE9

database (TCFE v9.1, June, 2019).'

'W. Huang, TRITA-MAC 431 (1990); C-V'

'A. Fernandez Guillermet and W. Huang, TRITA-MAC 440 (1990); Mn-V-C'

'B.-J. Lee, TRITA-MAC 475 (1991); C-Cr-Fe-V'

'A. Fernandez Guillermet, Z. Metallkd. 82 (1991) 478-487; Nb-Zr'

'S. Jonsson, PhD Thesis; TRITA-MAC 519 (1993); W-C and Ti-W-C'

'P. Gustafson, Mat. Sci. Tech., 2 (1986) 653-658; TRITA 0212 (1985); C-W'

'P. Gustafson, Metall. Trans. A, 18A (1987) 175-188; TRITA 0257 (1985); C

-FE-W'

'P. Gustafson, Z. Metallkd., 79 (1988) 421-425; TRITA-MAC 331 (1987); C

 -FE-MO-W'

'B. Jansson, IM report (1987); C-CO-CR-W'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2015; Co-Cr and Co-Cr-Fe

SIGMA'

'Thermo-Calc Software, Sweden, 2008: Volume data updated for TCFE6

database (TCFE v6, April, 2008).'

'A. Fernandez Guillermet, CALPHAD, 13 (1989) 1-22; TRITA-MAC 337 (1987);

Co-Fe-Ni'

'A. Davydov and U.R. Kattner, J. Phase Equilib., 20 (1999) 5-16; Co-Mo'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2014; Co-Mo metastable

LAVES_PHASE_C14'

'N. Dupin, Private communication; Introduction of V'

'A. Markstrom, K. Frisk, B. Sundman, J. Phase Equilib. Diffus. 26 (2005)

152-160; C-Co-W'

'A. Fernandez Guillermet, Metall. Trans., 20A (1989) 935-956; TRITA-MAC

371 (1988); C-CO-W'

'I. Isomaki, J. Alloys Compd. 375 (2004) 191-195; Co-Zn'

'B.-J. Lee, CALPHAD, 17 (1993) 251-268; revision of Fe-Cr and Fe-Ni liquid'

'J-O. Andersson and B. Sundman, CALPHAD, 11 (1987) 83-92; TRITA 0270

(1986); CR-FE'

'K. Frisk, Metall. Trans. A, 21A (1990) 2477-2488; TRITA 0409 (1989); CR

-FE-N'

'J-O. Andersson, Metall. Trans. A, 19A (1988) 1385-1394; TRITA 0322 (1986);

CR-FE-MO'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2019; Cr-Fe-Nb'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2014; Cr-Fe-Zn'

'K. Frisk, KTH Report D 60 (1984); CR-MO'

'B. Sundman, Private communication; FCC parameter same as BCC; Cr-Mo'

'J-O. Andersson, TRITA-MAC 323 (1986); C-CR-FE-MO'

'K. Frisk, TRITA-MAC 429 (1990); CR-MO-NI'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2009; Z_PHASE'

'L. Kjellqvist, Thermo-Calc Software AB, Sweden, 2013; Reassessed

solubility of Al, Cr, Fe, Ni in Mn2O3. When Mn2O3 is modelled as the

same phase as cubic Y2O3 (M2O3C).'

'L. Kjellqvist, Thermo-Calc Software AB, Sweden, 2012; Molar volumes'

'B.-J. Lee, TRITA-MAC 474 (1991); Cr-Fe-V'

'H.K. Danielsen and J. Hald, CALPHAD, 31 (2007) 505-514; Z-PHASE'

'P. Gustafson, CALPHAD, 11 (1987) 277-292; TRITA-MAC 320 (1986); CR-NI-W '

'P. Gustafson, TRITA-MAC 354 (1987); C-Cr-Fe-Mo-W'

'A. Fernandez Guillermet, CALPHAD, 6 (1982) 127-140; (sigma phase revised

1986); TRITA-MAC 200 (1982); FE-MO'

'K. Frisk, TRITA-MAC 428 (1990); FE-MO-NI'

'W. Huang, TRITA-MAC 432 (Rev 1989,1990); FE-V'

'J-O. Andersson, CALPHAD, 7 (1983) 305-315 (Parameters revised 1986 due to

new decription of V) TRITA 0201 (1982); FE-V'

'W. Huang, TRITA-MAC 432 (1990); C-Fe-V'

'A.V. Khvan, K. Chang, B. Hallstedt, CALPHAD, 43, 143-48(2013); Fe-Nb-V'

'W. Huang, TRITA-MAC 439 (1990) also in W. Huang, CALPHAD, 15, 195

-208(1991); Mn-V, Fe-Mn-V'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2009; SIGMA and M7C3'

'P. Gustafson, Z. Metallkd., 79 (1988) 388-396; TRITA-MAC 329 (1987); MO-W,

FE-MO-W '

'S. Huang, J. Vleugels, L. Li, O. Van Der Biest, J. Alloys Compd., 395

(2005) 68-74; V-W-C'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2016; C-Co-Cr liquid'

'A. Markstrom, Thermo-Calc Software AB, Sweden, 2015'

'A. Fernandez Guillermet, Z. Metallkd., 80 (1989) 83-94; TRITA-MAC 374

(1988); C-CO-FE-NI-W '

'I.K. Kupalova, V.I. Pavlova, High Speed Steels: Physical Properties,

Prop. Data Updat. 2 (1988) 67-78; Molar volumes'

'A.V. Khvan, B. Hallstedt, C. Broeckmann, CALPHAD, 46, 24-33(2014); Cr-Fe-C'

'J-O. Andersson, Metall. Trans. A, 19A (1988) 627-636 TRITA 0207 (1986); C
 -CR-FE'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2016; FCC Fe-Cr-C and C-Cr-Ni'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2008; Fe-Cr-Mo-V-W-C'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2009; Carbonitrides and

M23C6'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2008; Fe-Cr-V-C'

'S. Nagakura, Transactions of the Iron and Steel Institute of Japan, 8

(1968) 265-294; Molar volumes'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2015; Estimated parameter'

'A. Fernandez Guillermet, Z. Metallkd., 79 (1988) 633-642; TRITA-MAC 372

(1988); Co-Fe-W'

'B. Sundman, Private communication, (2000); Estimated Cr-Ni-Mo'

'B.-J. Lee, Private communication, (2000); Estimated parameter'

'A. Markstrom, Thermo-calc Software AB, Sweden, 2011; SIGMA phase in Cr-Fe

-W'

'J. Bratberg, Thermo-Calc Software AB, Sweden, 2008; Solubilities in M6C'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2016; C-Cr-Fe-V'

'R. Naraghi, Thermo-Calc Software AB, Sweden, 2016; C-Cr-Fe-W'

'P. Gustafson, Inst. Met. Res. (Sweden) (1990); Estimations of C-CR-FE-V,

C-CR-FE-MO-V-W, FE-N-W, FE-MN-N, FE-N-SI, CR-N-V, C-CR-N, FE-MO-N, CR

-N-W, CR-TI-N'

-OK-

TDB_TCFE9:go poly

... the command in full is GOTO_MODULE

POLY version 3.32

POLY:list-cond

... the command in full is LIST_CONDITIONS

DEGREES OF FREEDOM 9

POLY:set-cond n=1 P=1e5 T=1473.15

... the command in full is SET_CONDITION

POLY:list-cond

... the command in full is LIST_CONDITIONS

N=1, P=1E5, T=1473.15

DEGREES OF FREEDOM 6

POLY:set-cond

... the command in full is SET_CONDITION

State variable expression:set-cond

*** ERROR 1661 IN QVFIND: NO SUCH STATE VARIABLE

POLY:set-cond

... the command in full is SET_CONDITION

State variable expression:

Factor:

State variable:

*** ERROR 1032 IN GPAR : PARAMETER VALUE MISSING

POLY:set-cond W(c)=0.0126 W(W)=0.0589 W(Mo)=0.0434 W(V)=0.0387 W(Co)=0.0003

W(Cr)=0.042

... the command in full is SET_CONDITION

POLY:list-cond

... the command in full is LIST_CONDITIONS

N=1, P=1E5, T=1473.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

POLY:com-eq

... the command in full is COMPUTE_EQUILIBRIUM

Using global minimization procedure

Calculated 35382 grid points in 8s

Found the set of lowest grid points in 1s

Calculated POLY solution 5 s, total time 14 s

POLY:list-eq

... the command in full is LIST_EQUILIBRIUM

OUTPUT TO SCREEN OR FILE /SCREEN/:

Options /VWCS/:vxcs

Output from POLY-3, equilibrium = 1, label A0 , database: TCFE9

Conditions:

N=1, P=1E5, T=1473.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

Temperature 1473.15 K ( 1200.00 C), Pressure 1.000000E+05

Number of moles of components 1.00000E+00, Mass in grams 5.62032E+01

Total Gibbs energy -8.32138E+04, Enthalpy 4.15018E+04, Volume 7.35549E-06

Component Moles M-Fraction Activity Potential Ref.stat

C 5.8959E-02 5.8959E-02 9.5121E-03 -5.7019E+04 SER

CO 2.8610E-04 2.8610E-04 2.7667E-07 -1.8496E+05 SER

CR 4.5398E-02 4.5398E-02 2.9776E-04 -9.9448E+04 SER

FE 8.0923E-01 8.0923E-01 1.4731E-03 -7.9865E+04 SER

MO 2.5424E-02 2.5424E-02 1.6340E-04 -1.0680E+05 SER

V 4.2698E-02 4.2698E-02 8.8007E-06 -1.4258E+05 SER

W 1.8006E-02 1.8006E-02 2.2568E-04 -1.0284E+05 SER

FCC_A1#1 Status ENTERED Driving force 0.0000E+00

Moles 8.9299E-01, Mass 5.0045E+01, Volume fraction 8.9979E-01 Mole fractions:

FE 8.83080E-01 C 2.94905E-02 MO 1.54478E-02 CO 3.12659E-04

CR 4.62775E-02 V 1.65859E-02 W 8.80521E-03

M6C Status ENTERED Driving force 0.0000E+00

Moles 4.9220E-02, Mass 3.7894E+00, Volume fraction 5.0454E-02 Mole fractions:

FE 4.03575E-01 W 1.62110E-01 V 6.58912E-02 CO 1.38482E-04

MO 1.78498E-01 C 1.42857E-01 CR 4.69302E-02

FCC_A1#2 Status ENTERED Driving force 0.0000E+00

Moles 5.7792E-02, Mass 2.3689E+00, Volume fraction 4.9760E-02 Mole fractions:

C 4.42852E-01 MO 4.92117E-02 CR 3.05094E-02 CO 1.50969E-06

V 4.26420E-01 W 3.74410E-02 FE 1.35643E-02

POLY:set-cond T=573.15

... the command in full is SET_CONDITION

POLY:com-eq

... the command in full is COMPUTE_EQUILIBRIUM

Using global minimization procedure

Calculated 35382 grid points in 1s

Found the set of lowest grid points in 0s

Creating a new composition set M6C#2

Calculated POLY solution 3 s, total time 4 s

POLY:list-eq

... the command in full is LIST_EQUILIBRIUM

OUTPUT TO SCREEN OR FILE /SCREEN/:

Options /VXCS/:

Output from POLY-3, equilibrium = 1, label A0 , database: TCFE9

Conditions:

N=1, P=1E5, T=573.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

Temperature 573.15 K ( 300.00 C), Pressure 1.000000E+05

Number of moles of components 1.00000E+00, Mass in grams 5.62032E+01

Total Gibbs energy -2.35313E+04, Enthalpy 1.54361E+03, Volume 7.06638E-06

Component Moles M-Fraction Activity Potential Ref.stat

C 5.8959E-02 5.8959E-02 1.0279E-03 -3.2787E+04 SER

CO 2.8610E-04 2.8610E-04 1.6785E-07 -7.4342E+04 SER

CR 4.5398E-02 4.5398E-02 1.8860E-03 -2.9895E+04 SER

FE 8.0923E-01 8.0923E-01 2.1474E-02 -1.8304E+04 SER

MO 2.5424E-02 2.5424E-02 3.1735E-04 -3.8388E+04 SER

V 4.2698E-02 4.2698E-02 5.9953E-09 -9.0221E+04 SER

W 1.8006E-02 1.8006E-02 1.1649E-03 -3.2191E+04 SER

BCC_A2 Status ENTERED Driving force 0.0000E+00

Moles 7.5324E-01, Mass 4.2068E+01, Volume fraction 7.6434E-01 Mole fractions:

FE 9.97766E-01 CO 3.79741E-04 MO 4.65092E-05 C 1.40020E-10

CR 1.73497E-03 W 4.99602E-05 V 2.30839E-05

LAVES_PHASE_C14 Status ENTERED Driving force 0.0000E+00

Moles 5.9127E-02, Mass 4.4694E+00, Volume fraction 6.6500E-02 Mole fractions:

FE 4.88534E-01 CR 1.78120E-01 CO 5.14901E-07 C 0.00000E+00

MO 2.52993E-01 W 8.03516E-02 V 6.97490E-10

M23C6 Status ENTERED Driving force 0.0000E+00

Moles 6.5155E-02, Mass 3.1895E+00, Volume fraction 5.9445E-02 Mole fractions:

CR 5.13364E-01 FE 1.75297E-01 V 1.03643E-03 CO 1.83005E-07

C 2.06897E-01 MO 1.03272E-01 W 1.33614E-04

FCC_A1#2 Status ENTERED Driving force 0.0000E+00

Moles 8.7842E-02, Mass 3.0773E+00, Volume fraction 7.3556E-02 Mole fractions:

V 4.80623E-01 FE 4.23451E-02 CR 1.10855E-03 CO 2.33019E-12

C 4.61412E-01 W 1.35635E-02 MO 9.48330E-04

M6C#1 Status ENTERED Driving force 0.0000E+00

Moles 2.7238E-02, Mass 2.7356E+00, Volume fraction 2.8313E-02 Mole fractions:

FE 4.22329E-01 C 1.42857E-01 V 1.07932E-02 CO 1.98370E-07

W 3.85739E-01 MO 3.80778E-02 CR 2.03521E-04

M6C#2 Status ENTERED Driving force 0.0000E+00

Moles 7.3959E-03, Mass 6.6303E-01, Volume fraction 7.8467E-03 Mole fractions:

MO 3.49041E-01 W 2.04220E-01 V 1.34993E-02 CO 2.52771E-06

FE 2.89189E-01 C 1.42857E-01 CR 1.19090E-03

POLY:set-cond

... the command in full is SET_CONDITION

State variable expression:

Factor:

State variable:

*** ERROR 1032 IN GPAR : PARAMETER VALUE MISSING

POLY:set-cond T=823.15

... the command in full is SET_CONDITION

POLY:com-eq

... the command in full is COMPUTE_EQUILIBRIUM

Using global minimization procedure

Calculated 35382 grid points in 0s

Found the set of lowest grid points in 0s

Calculated POLY solution 1 s, total time 1 s

POLY:list-eq

... the command in full is LIST_EQUILIBRIUM

OUTPUT TO SCREEN OR FILE /SCREEN/:

Options /VXCS/:

Output from POLY-3, equilibrium = 1, label A0 , database: TCFE9

Conditions:

N=1, P=1E5, T=823.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

Temperature 823.15 K ( 550.00 C), Pressure 1.000000E+05

Number of moles of components 1.00000E+00, Mass in grams 5.62032E+01

Total Gibbs energy -3.61406E+04, Enthalpy 1.07248E+04, Volume 7.13026E-06

Component Moles M-Fraction Activity Potential Ref.stat

C 5.8959E-02 5.8959E-02 2.9708E-03 -3.9825E+04 SER

CO 2.8610E-04 2.8610E-04 4.5446E-07 -9.9952E+04 SER

CR 4.5398E-02 4.5398E-02 2.1514E-03 -4.2034E+04 SER

FE 8.0923E-01 8.0923E-01 1.0226E-02 -3.1365E+04 SER

MO 2.5424E-02 2.5424E-02 4.8495E-04 -5.2230E+04 SER

V 4.2698E-02 4.2698E-02 4.7593E-07 -9.9636E+04 SER

W 1.8006E-02 1.8006E-02 7.1817E-04 -4.9543E+04 SER

BCC_A2 Status ENTERED Driving force 0.0000E+00

Moles 7.8465E-01, Mass 4.3872E+01, Volume fraction 7.9878E-01 Mole fractions:

FE 9.80926E-01 MO 1.20450E-03 W 6.41273E-04 C 9.01412E-07

CR 1.59164E-02 V 9.48704E-04 CO 3.61998E-04

M6C#2 Status ENTERED Driving force 0.0000E+00

Moles 7.3270E-02, Mass 6.3392E+00, Volume fraction 7.6740E-02 Mole fractions:

FE 3.29412E-01 W 2.15869E-01 V 5.87314E-02 CO 2.52433E-05

MO 2.40400E-01 C 1.42857E-01 CR 1.27056E-02

M23C6 Status ENTERED Driving force 0.0000E+00

Moles 6.5398E-02, Mass 3.2297E+00, Volume fraction 5.9485E-02 Mole fractions:

CR 4.79607E-01 FE 2.04284E-01 V 8.39188E-03 CO 3.26451E-06

C 2.06897E-01 MO 9.56506E-02 W 5.16602E-03

FCC_A1#2 Status ENTERED Driving force 0.0000E+00

Moles 7.6685E-02, Mass 2.7627E+00, Volume fraction 6.4996E-02 Mole fractions:

V 4.83811E-01 FE 2.67593E-02 CR 7.99780E-03 CO 2.64676E-09

C 4.55900E-01 W 1.75794E-02 MO 7.95237E-03

POLY:set-cond
 ... the command in full is SET_CONDITION

State variable expression:

Factor:

State variable:

*** ERROR 1032 IN GPAR : PARAMETER VALUE MISSING

POLY:set-cond T=923.15

... the command in full is SET_CONDITION

POLY:com-eq

... the command in full is COMPUTE_EQUILIBRIUM

Using global minimization procedure

Calculated 35382 grid points in 0s

Found the set of lowest grid points in 1s

Calculated POLY solution 1 s, total time 2 s

POLY:list-eq

... the command in full is LIST_EQUILIBRIUM

OUTPUT TO SCREEN OR FILE /SCREEN/:

Options /VXCS/:

Output from POLY-3, equilibrium = 1, label A0 , database: TCFE9

Conditions:

N=1, P=1E5, T=923.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

Temperature 923.15 K ( 650.00 C), Pressure 1.000000E+05

Number of moles of components 1.00000E+00, Mass in grams 5.62032E+01

Total Gibbs energy -4.20870E+04, Enthalpy 1.51650E+04, Volume 7.16698E-06

Component Moles M-Fraction Activity Potential Ref.stat

C 5.8959E-02 5.8959E-02 6.1703E-03 -3.9053E+04 SER

CO 2.8610E-04 2.8610E-04 5.3760E-07 -1.1081E+05 SER

CR 4.5398E-02 4.5398E-02 1.6348E-03 -4.9248E+04 SER

FE 8.0923E-01 8.0923E-01 7.5604E-03 -3.7494E+04 SER

MO 2.5424E-02 2.5424E-02 4.2952E-04 -5.9507E+04 SER

V 4.2698E-02 4.2698E-02 7.7663E-07 -1.0798E+05 SER

W 1.8006E-02 1.8006E-02 4.9289E-04 -5.8451E+04 SER

BCC_A2 Status ENTERED Driving force 0.0000E+00

Moles 7.8901E-01, Mass 4.4179E+01, Volume fraction 8.0347E-01 Mole fractions:

FE 9.72165E-01 MO 2.40587E-03 W 1.11374E-03 C 1.32951E-05

CR 2.25896E-02 V 1.35600E-03 CO 3.56793E-04

M6C#2 Status ENTERED Driving force 0.0000E+00

Moles 7.3989E-02, Mass 6.2220E+00, Volume fraction 7.7263E-02 Mole fractions:

FE 3.47974E-01 W 1.97718E-01 V 4.94074E-02 CO 5.62725E-05

MO 2.37837E-01 C 1.42857E-01 CR 2.41505E-02

FCC_A1#2 Status ENTERED Driving force 0.0000E+00

Moles 8.0492E-02, Mass 2.9736E+00, Volume fraction 6.8204E-02 Mole fractions:

V 4.65877E-01 FE 2.60862E-02 MO 1.52057E-02 CO 1.84803E-08

C 4.55803E-01 W 2.19575E-02 CR 1.50705E-02

M23C6 Status ENTERED Driving force 0.0000E+00

Moles 5.6505E-02, Mass 2.8284E+00, Volume fraction 5.1060E-02 Mole fractions:

CR 4.34918E-01 C 2.06897E-01 W 1.29316E-02 CO 7.50537E-06

FE 2.53611E-01 MO 8.32645E-02 V 8.37044E-03

POLY:set-cond T=973.15

... the command in full is SET_CONDITION

POLY:com-eq

... the command in full is COMPUTE_EQUILIBRIUM

Using global minimization procedure

Calculated 35382 grid points in 0s

Found the set of lowest grid points in 0s

Calculated POLY solution 1 s, total time 1 s

POLY:list-eq

... the command in full is LIST_EQUILIBRIUM

OUTPUT TO SCREEN OR FILE /SCREEN/:

Options /VXCS/:

Output from POLY-3, equilibrium = 1, label A0 , database: TCFE9

Conditions:

N=1, P=1E5, T=973.15, W(C)=1.26E-2, W(W)=5.89E-2, W(MO)=4.34E-2,

W(V)=3.87E-2, W(CO)=3E-4, W(CR)=4.2E-2

DEGREES OF FREEDOM 0

Temperature 973.15 K ( 700.00 C), Pressure 1.000000E+05

Number of moles of components 1.00000E+00, Mass in grams 5.62032E+01

Total Gibbs energy -4.52533E+04, Enthalpy 1.76583E+04, Volume 7.18637E-06

Component Moles M-Fraction Activity Potential Ref.stat

C 5.8959E-02 5.8959E-02 8.3499E-03 -3.8721E+04 SER

CO 2.8610E-04 2.8610E-04 5.7280E-07 -1.1629E+05 SER

CR 4.5398E-02 4.5398E-02 1.4086E-03 -5.3120E+04 SER

FE 8.0923E-01 8.0923E-01 6.4939E-03 -4.0755E+04 SER

MO 2.5424E-02 2.5424E-02 3.9571E-04 -6.3394E+04 SER

V 4.2698E-02 4.2698E-02 9.2952E-07 -1.1238E+05 SER

W 1.8006E-02 1.8006E-02 4.1206E-04 -6.3066E+04 SER

BCC_A2 Status ENTERED Driving force 0.0000E+00

Moles 7.9203E-01, Mass 4.4396E+01, Volume fraction 8.0667E-01 Mole fractions:

FE 9.67456E-01 MO 3.21173E-03 W 1.44828E-03 C 4.12219E-05

CR 2.59599E-02 V 1.52944E-03 CO 3.53236E-04

M6C#2 Status ENTERED Driving force 0.0000E+00

Moles 7.3964E-02, Mass 6.1242E+00, Volume fraction 7.7096E-02 Mole fractions:

FE 3.57419E-01 W 1.88170E-01 V 4.47410E-02 CO 7.83219E-05

MO 2.36075E-01 C 1.42857E-01 CR 3.06598E-02

FCC_A1#2 Status ENTERED Driving force 0.0000E+00

Moles 8.2964E-02, Mass 3.1069E+00, Volume fraction 7.0296E-02 Mole fractions:

C 4.55624E-01 FE 2.58863E-02 MO 1.99046E-02 CO 4.29136E-08

V 4.54769E-01 W 2.40862E-02 CR 1.97297E-02

M23C6 Status ENTERED Driving force 0.0000E+00

Moles 5.1040E-02, Mass 2.5765E+00, Volume fraction 4.5936E-02 Mole fractions:

CR 4.10121E-01 C 2.06897E-01 W 1.84674E-02 CO 1.04413E-05

FE 2.81906E-01 MO 7.38269E-02 V 8.77164E-03

POLY: