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When the opposite happens, an oil-in-
water emulsion is formed. Emulsions may
be tight (difficult to break) or loose (easy to
break) depending on the type and amount
of emulsifying agent present.
Emulsifying Agents
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Emulsion Stability An emulsion should be tested frequently.
No two emulsions are alike. Even the
A stable emulsion is one which will not emulsion from a single weli changes over
break down or separate without some time thereby requiring changes in the
form of treating. The stability of an treatment process. The treating process
emulsion is dependent on several factors : must be monitored carefully since revenue
is affected by the gravity of oil. Natural gas
• Emulsifying agent. The effect also generates considerable revenue for
depends on the type of agent and our company and must be monitored
conditions under which the emulsion closely to ensure maximum yield and
is produced. The formation of a stable minimal waste.
emulsion would be very difficult Treating emulsions may include one or
without an emulsifying agent. more of the following procedures: allowing
settling time, applying heat, injecting
• Viscosity of oil. Oil with a high chemicals, using electricity, or operating
viscosity (resistance to flow) tends to mechanical devices.
keep water droplets in suspension
creating a more stable emulsion.
• A.P.I. gravity of oil. Oil with a low
A.P.I. gravity tends to keep water
dropiets in suspension creating a
more stable emulsion.
• Water percentage. Generally, a
smaller percentage of water in an
emulsion means greater stability.
• Agitation. Increased agitation
means greater dispersement of water
and greater stability.
• Droplet size. Emulsions containing
small water droplets are more stable
because small droplets are lighter and
will not settle out as easily.
• Age of emulsion. The longer an
emulsion remains untreated, the
harder it is to break. Settling Time
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Settling rate is also affected by the size of Adding Chemicals
the water droplets. Smaller droplets are
lighter and take longer to separate through Emulsion breaking chemicals are injected
settling. into the well stream ahead of the
If the difference in A.P.I. gravity between electrostatic treater. They react with the
water and oil (the gravity differential) is film around water droplets, destroying or
small, separa-tion is slow. However, water neutralizing the film, thereby al-lowing the
weighs more than oil and will eventually droplets to coalesce (combine) and
settle to the bottom of a vessel. Some separate from the oil.
emulsions can be adequately treated with There must be sufficient agitation to allow
settling alone. Others need additional the chemical to come into contact with
treatment procedures which are designed each water droplet. The amount and type
to speed up the settling process. of chemical required directly affects how
well the emulsion breaks and the time
needed for settling. Also, the warmer the
Applying Heat emulsion, the less chemical is needed.
Chemicals must be applied only as
The ideal way to treat oil is without heat; needed because too much chemical is
however, treatment frequently requires wasteful and could cause an oil-in-water
heat to speed up separation. Heat by itself emulsion to form. This would allow oil to
will not break an emulsion, but it aids in leave the vessel through the water outlets,
several ways: (1) Heat causes water resulting in lost revenue\and
droplets to move faster and strike each environmental pollution.
other with greater frequency and force.
When the droplets collide, the film of
emulsifying agent ruptures, and larger, Using Electricity
heavier droplets form. They then yield to
gravity differential and settle out; (2) Heat Electricity, usually used in conjunction with
lowers the viscosity of oil and allows the heat and chemicals, will separate oil and
water droplets to settle out more easily; water. The vessel used to do this is called
and (3) Heat speeds up chemical action. an electrostatic treater and will be
Chemicals make the fiim of emulsifying discussed in sections two and three of this
agent around water droplets rigid. When module.
heat is applied, the water droplets expand
and break the film. The droplets can then Using Mechanical Devices
merge into larger ones and settle out.
Heat must be applied only as needed Devices such as gun barrels and free-
because too much heat will waste energy water knockouts are used in the treatment
(fuel) and cause greater wear on the of emulsions. A gun barrel is basically a
equipment. Also, excessive heat can cook settling tank used to separate oil and water
off the lighter ends of crude oil in the field. After emulsified oil has been
which will change the oil's gravity and heated and treated with chemicals, it is
result in lost revenue. pumped to the gun barrel where water and
oil separate by gravity setting. Gun barrels
are largely being replaced by heater
treaters or electrostatic treaters but are still
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common, especially in older fields. particles of oil that may be entrained in the
A free-water knockout is a gravity-type free water as it passes through the filter.
separator used to remove excessive water The free water is drained off and only
from the produced fluid ahead of the emulsion passes on to the treating unit.
treating unit. Sometimes a filter or This device prevents over-loading of the
excelsior, called hay, is used to catch treating vessel and saves fuel.
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External Components
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the gas outlet. Some treaters have a • Make-up Gas Line (not
gas dome which is designed to shown). Some treaters may have a
remove any liquid particles entrained make-up gas line with a regulator to
in the gas stream prior to leaving the maintain proper operating pressure of
vessel. the unit.
• Gas Back-Pressure Valve (not • Free Water Outlet. Free water,
shown). This valve, located on the which has settled out of the emulsion,
gas outlet line, maintains sufficient leaves the unit through this outlet
pressure in the vessel to dump located on the bottom of the treater.
liquids. • Free Water Level Controller. This
• Safety Device. The safety device device maintains the free water level
may be a relief valve, rupture disc or in the treater.
both. They are designed to open or • Free Water Dump Valve. This
burst if too much pressure builds up valve is located on the free water
in the treater. outlet line. It allows free water to
leave the vessel.
• Oil Outlet. Oil leaves the treater dump valve allows clean oil to leave
and enters the oil outlet line through the treater and is controlled by a level
the oil outlet. controller.
• Oil Dump Valve. This valve is • Treated Water Outlet. Treated
located on the oil outlet line. The oil water, which has settled out of the
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oil, leaves the unit through this outlet the high-voltage electrostatic field in
located on the bottom of the treater. the treater.
• Treated Water Dump Valve. This • Sight Glasses. These devices
valve is located on the treated water enable a pumper to see the water/oil
outlet line. It allows treated water to interface levels in the treater. They
leave the vessel. help him to determine abnormal fluid
• Treated Water Level levels (upset condition).
Controller. This device maintains the • Gas/Air Supply Lines. These lines
treated water level in the treater. provide gas or compressed air to the
• Drains. On the bottom of the level controllers so they can work
treater are drains to empty the vessel properly. Gas/air supply lines usually
for repairs or to remove accumulated contain a regulator, drip trap, and
solids, e.g., sand, clay, etc. filter to help supply clean, dry gas or
compressed air to the level
• Transformer. The transformer
controllers
steps up incoming voltage to create
• .
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Internal Sections
The internal sections are arranged in the • Baffle. The baffle separates the
following order from fire boxes to gas separation area from the heating
opposite end of the treater: inlet section, area of the inlet section. It helps to
surge section, and treating section. divert incoming emulsion to the
bottom of the treater.
Inlet Section. The inlet section, which is
• U-Shaped Hood or
the first section to receive emulsion,
serves two purposes. Entrained gas Downcomer. This device covers the
separates and leaves through the gas firetubes in the gas separation area. It
outlet thus preventing agitation of the diverts incoming emulsion to the
emulsion later. Also, free water which has bottom of the treater.
separated upon entry to the treater and • Water Wash. In this area of the
after being heated by the firetubes, falls inlet section, the emulsion gives up
to the bottom where it is drained from the free water. Water washing is the
unit. process where large water droplets
coalesce with small water droplets
and settle out
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• Flow Spreader. The flow spreader header with the oil outlet located near
disperses emulsion along the length the bottom of the surge section.
of the firetubes to ensure maximum Some units do not have an internal
use of the heating area by using the distribution pipe and oil is removed
total surface area of the firetubes. from the top of the treater.
Treating Section. Final treating and
• Firetubes. The firetubes supply settling of the emulsion takes place in this
heat to the emulsion causing oil section.
viscosity to be lowered so water
droplets can settle out. • Flow Spreader. The flow spreader
• Weir. This is a dam-like device receives emulsion from the surge
over which emulsion from the inlet section and disperses it along the
section flows into the surge section. length of the treating section to
ensure uniform distribution over the
Surge Section. The surge section is the electrical grids.
middle section which serves to keep the • Electrical Grids. There are two
treating section "fluid-packed," that is, electrical grids made of steel rods.
liquid completely filling the treating The lower grid is electrically charged
section with no gas on top. while the upper grid is grounded.
Grids are suspended from the vessel
• Clean Oil Distribution Pipe. This shell with insulated hanger rods.
pipe connects the clean oil collection
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• Clean Oil Collection Header. This pressure is usually at or below the
header runs horizontally across the maximum safe working pressure of
top of the treating section and is used the treater.
to skim off clean oil for removal from • Sight Glasses. Sight glasses or
the vessel. gauge glasses are not safety devices
themselves, but they have safety
features built in. They are the best
way for the pumper to see if the
Monitoring and Safety Devices. treater is doing its job. If the sight
In order to operate properly and safely, glass is broken, a safety feature of
every electrostatic treater is equipped the sight glass valve will cause a steel
with safety devices and monitoring ball to seat and shut off the flow.
features. However, if the sight glass valve is
not wide open, the ball will not seat.
• Fiame Arrestors. Flame arrestors
• Low Level Controller. The low
fit on the front of fire boxes. They level controller is a safety device
have a series of aluminum vanes
installed on an electrostatic treater to
placed very closely together so heat ensure that the firetubes are always
generated in fire boxes is dispersed covered with liquid. It is designed to
in the air before it can cause a fire shutdown the burners if liquid level
outside the vessel. Flame arrestors falls below the desired level. Shutting
should be used on any fired emulsion down the burners keeps the firetubes
treater. from overheating, which results in
• Fuel Gas Scrubber. The fuel gas tube failure and a safety hazard.
scrubber prevents entrained liquids • Indicator Light. The indicator
from "going to the burners with the light, located on the transformer,
fuel gas. If the scrubber fills with remains on as long as the electrical
liquid, a float rises and shuts off a grids are functioning properly or
valve which stops gas from flowing to unless power has been lost to the
the burners, preventing the possibility treater.
of a fire. The scrubber has a drain
valve that the pumper should open • Voltmeter. The voltmeter
each day to drain off liquids collected measures the voltage of incoming
in it. electricity to the treater. It should
read 220 or 440 volts during normal
• Safety Relief Valve. A safety relief
operation depending on the electrical
valve is a pressure-relieving device power source.
designed to open at a pre-set
pressure to relieve excessive • Circuit Breaker. A circuit breaker,
pressure within a vessel or line. It located between the power source
may also be called a pop valve. and the transformer, protects the
transformer from power surges.
• Rupture Disc. A rupture disc is a
fail-safe pressure relief device made • Ammeter. Some electrostatic
of metal that is designed to burst at a treaters have an ammeter to measure
pre-set pressure. The pre-set the strength of electric current across
the grids.
•
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Electrostatic Treater Operation
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Inlet Section.
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No clean oil leaves the treating section completed between the upper and lower
unless an equal amount of fluid enters the grids where water droplets coalesce and
surge section. This is controlled by a float settle out.
in the surge section which is mechanically
linked to the oil dump valve. heated emulsion rises through the
electrostatic field, water droplets are given
Treating Section. an electrical charge, which causes them to
become elongated and polarized. When a
water droplet becomes polarized, it
acquires a positive ( + ) charge on one end
and a negative (-) charge on the other end.
Alternating current on the lower electrical
grid GRIDS causes it to reverse polarity
(change from positive to negative) 120
times per second or 60 cycles per second.
This causes the water droplets to move
around rapidly and collide with each other
with enough force to break the thin film
surrounding each droplet.
Electrical System.
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open, which allows oil to leave the vessel.
The electrical system consists of a step-up When the emulsion returns to the pre-set
transformer and two electrical grids level, the dump valve closes and allows oil
(electrodes). Step-up transformers to accumulate in the treating section.
increase the incoming voltage to a higher
level, e.g., most electrostatic treaters are Free water and treated water levels in the
supplied by 440 volts which is then treater are maintained by water dump
stepped-up to 15,000-20,000 volts to valves. As with the oil dump valve, water
produce the electrostatic field around the dump valves open to remove water when
grids. the interfaces rise above pre-set levels and
close when the interfaces return to pre-set
The two grids are suspended one above levels.
the other in the treating section. The upper
grid is grounded to the vessel shell and is Both water dump valves operate by means
adjustable so that the electrostatic field of Interface level controllers which use gas
can be regulated to meet varying or compressed air to open and close the
coalescing requirements. The lower grid is dump valves. This is achieved by the level
not grounded and receives the electrical controller diverting gas or compressed air
output from the transformer. Both grids to the diaphragm of the dump valve. Gas
are suspended from the top of the vessel or compressed air pressure offsets the
shell by insulated hanger rods. All spring tension holding the diaphragm in
components of the electrical system are the closed position. This action lifts the
designed for high voltage service. diaphragm and allows water to flow
through the dump valve. When the
The transformer is the heart of the interface returns to its pre-set level, the
electrical system. Most electrostatic level controller vents the gas or
treaters have a reac-tance type compressed air and allows the diaphragm
transformer which has a reactor to protect to seat, closing the dump valve.
the transformer from power surges and
high voltage dispersion. These Some electrostatic treaters are designed
transformers are oil-immersed and meet to allow water in the inlet section to join
all reasonable electrical safety water in the treating seciion before being
requirements. A circuit breaker, located removed from the treater. This
between the power source and the arrangement utilizes one dump valve and
transformer, protects the transformer from level controller to maintain water ievels in
electrical power failures. A fused the treater. Mechanically operated oil
disconnect at the power source is dump valves and gas-operated water
recommended for maximum safety. dump valves have been discussed in this
manual. Other types of oil and water dump
Fluid Levels. valves may be used on electrostatic
treaters.
Oil level in the treating section is
maintained by the oil dump valve, which is Operating Temperature.
operated by a float in the surge section.
When emulsion rises above a pre-set level Operating temperature is important and
in the surge section, the float rises with the will vary from lease to lease. The lowest
emulsion and causes the dump valve to possible temperature to adequately treat
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the emulsion should be used. In warmer gravity, and oil volume will be decreased
climates, heating may be necessary only in resulting in lost revenue.
colder months.
Operating Pressure.
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have enough capacity to protect the changed and a different chemical is
treater if pressure increases. required.
• Free Water in the Lease Tank. If
Gas leaving at the top of the treater is the water outlet lines are plugged or
controlled by a gas back-pressure valve the water dump valves do not open,
which controls the pressure in the treater. water has nowhere to go except out
The inlet and surge sections are held at a the oil outlet into the lease tank. If the
slightly higher pressure than the treating valves are operating properly, it may
section. When there is not enough be that the treater simply cannot
entrained gas in the incoming fluid to handle the amount of free water
maintain necessary pressure, a make-up produced, and a free- water knockout
gas line is usually connected to the gas unit should be installed upstream of
equalizer. the treater.
• Oil in the Water Disposal System.
There are several reasons why a higher
pressure is maintained in the first two This can happen if the oil outlet is
sections. plugged, the oil dump valve is stuck
closed, or the water dump valves are
• The differential pressure assures a stuck open. Sometimes when the oil
positive flow of fluid from the surge outlet on a treater is below the oil inlet
section to the treating section. on the lease tank and the back-
• The treating section must be fluid- pressure valve fails to hold a positive
packed. pressure on the treater, oil will go
• There must be enough differential through the water outlets into the
pressure to move the clean oil to water disposal system.
storage tanks.
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5. Adjust torch position to ignite pilot. 9. Drain the fuel gas scrubber.
y6. Open main supply valve. 10. Check chemical pump and
6. Slowly open pilot valve. chemical surge tank.
7. Open burner valve after pilot is • Weekly
lighted and torch removed. 1. Open the bottom drains on the
8. Adjust gas and air mixture to obtain treater briefly. This will prevent build-
proper flame. up of sediment and help prevent drain
9. Set fuel pressure as low as possible clogging.
to maintain proper temperature. 2. Sight glass valves should be
checked to prevent clogging. Sight
MAINTENANCE CHECKS glasses should be cleaned if needed.
3. Take inlet and outlet samples to
For smooth operation, the following check BS&W content.
maintenance checks should be performed • Monthly
as indicated :
1. Check the burners and pilots for
good performance. Clean if
STEPS :
necessary.
2. Check the burners to make sure
• Daily
they remain centered in the firetubes.
1. Check indicator light on
3. Check the flame arrestors to make
transformer. It should always be on
sure they are not clogged. Clean if
and bright.
necessary.
2. Check the voltmeter. It should read
• Yearly
220 or 440 volts depending on
electrical power source. 1. Inspect and clean entire vessel.
Use proper safety procedures for
3. Check free and treated water levels
confined space entry.
using sight glasses. Adjust levels if
necessary. 2. Inspect the firetubes, remove from
vessel and check for heat stress and
4. Check gas back-pressure valve for
cracks.
correct vessel pressure. Adjust
pressure if necessary.^ 3. Inspect the fuel gas scrubber float
to make sure it works.
5. Check the oil dump valve linkage.
4. Inspect dump valves. Clean and
6. Check the water dump valves for
repair if necessary.
condensation or accumulation of
liquids in the gas/air supply lines by
opening the bleed valves provided. WATER LEVEL CHECKS
7. Drain the drip traps that supply
gas/air to the water dump valves. Water levels are pre-set. When the water
level changes, these checks can be done
8. Check treater temperature to make to restore it to the pre-set condition :
sure fires aren't out and the
• PROBLEM : Low Water Level
thermostat is operating in the right
POSSIBLE CAUSE : Emulsion build-
range. Adjust temperature if
up at the interface. Increased weight
necessary.
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of emulsion on the water will cause • Emulsifying Agent : The substance
the level to drop. which determines the stability of an
• PROBLEM : No Water Level emulsion; it forms a film around the
POSSIBLE CAUSE : Low gas suspended droplets.
pressure. Back-pressure valve may • Emulsion : Mixture of liquids which
be leaking or set too low. Safety relief can only be separated by a treating
valves may be leaking. process.
An oil valve stuck in the closed • Emulsion Stability : Measured by
position. This would force all liquid the degree of difficulty in breaking the
out the water dumps or the gas emulsion; affected by several factors.
outlet.
• Fluid-Packed : Condition when a
Circulating pump rate is too high.
vessel or section of a vessel is
More volume than the treater can
completely full of liquid with no gas on
handle.
top.
Leaking water dump valves. This
would cause loss of the fluid seal and • Free Water : Water which readily
low gas pressure. separates from other fluids.
• PROBLEM : High Water Level • Interface : The point at which the oil
POSSIBLE CAUSE : Plugged water and water meet.
dump lines. Usually caused by scale • Loose Emulsion : An emulsion
build up. which is easy to break.
There are many problems that can occur • Polarized : When a substance
with electrostatic treaters. If you observe acquires a positive ( + ) charge on one
unusual conditions, check with your field end and a negative (-) charge on the
foreman. other end.
• Settling Time : Time it takes for
GLOSSARY water to separate from oil.
• Sight Glass : Device located on the
outside of a vessel used for monitoring
• Alternating Current : (A.C.) liquid levels.
Electrical current which reverses flow
• Three-Phase Separation :
at regular intervals, usually 120
reversals per second or 60 cycles per Separating gas, oil, and water.
second. • Tight Emulsion : An emulsion
• A.P.I. Gravity : Specific gravity as
which is difficult to break.
defined by the American Petroleum • Treated Water : : Water which
Institute. separates from other fluids only after
• BS&W : Basic sediment and water.
treating with heat, chemicals, etc.
• Two-Phase Separation :
• Coalesce : Combining water
droplets into larger droplets so they Separating natural gas from liquids.
will settle out of oil. • Viscosity : Thickness of oil;
• Direct Current : (D.C.) Electrical
resistance to flow.
current which flows continuously in • Weir : A dam-like device which
one direction. controls liquid level and flow through
the electrostatic treate
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