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Flame Test Test on solid

Li +¿¿- Red  Clean the Nichrome Nitrate


Na+¿¿- Yellow wire with concentrated Observation Inferences
K +¿¿ - Lilac HCl
-Bubbles -Sodium or potassium
Ca2+¿ ¿- Red  Dip nichrome wire in
Relight glowing nitrate
Sr 2+¿¿ - Red sample
splinter -Lithium nitrate or
Ba2+¿¿- Green  Put it into the blue
-Brown gas group 2 nitrate
flame of the Bunsen
burner
Additional of acid : test for carbonate and Carbonate
hydrogencarbonate Observation Inferences
Observation Interference Turns limewater milky
o Bubbles o G1 – It is a -Drops of water -Group 1
 Turns carbonate or condense on upper hydrogencarbonate
limewater hydrogencarbona part of the tube
milky te -No water produced -Group 2 carbonate or
 G2 - It is a Lithium carbonate
carbonate

Observation
Relight is glowing splinter
Ignites with a ‘pop’ sound

Test for an OH group Observation Interference


Add a small piece of sodium to the unknown in  Bubbles  It contain
an evaporating basin.  Sodium OH group
disappear/Na
Add PCl5 disappears
o Steamy fume
o Litmus goes red
Oxidation Alcohol
Test Observation Inferences
 Add dilute sulphuric acid o The Orange solution  Primary to
 Aqueous Potassium Dichromate turns Green secondary
(VI) o The solution remain alcohol
 Warm the mixture in a beaker of Orange  Tertiary alcohol
hot water
Tests for halogenoalkanes
Test Observation Inferences
Shake a few drops of unknown Two layers form
with water
Dilute nitric acid White precipitate H contains C-Cl group
Sliver nitrate Cream precipitate H contains C-Br group
Yellow precipitate H contains C-I group

Adding ammonia solution to The precipitate Soluble in dilute AgCl – chloroalkane


precipitate ammonia AgBr -bromoalkane
Insoluble in dilute ammonia but AgI - iodoalkane
Soluble in concentrate
ammonia
Not soluble in concentrated
ammonia

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