ANITA LEWIS1

COLLEGE OF MEDICINE AND ALLIED HEALTH SCIENCES

FACULTY'S OF PHARMACEUTICAL SCIENCES
D. PHARM.
Q1 a.Molar mass of Juglone ??

Chemical formula: C10 H6O3.

10 C : 10 × 12.0g = 120g

6 H : 6 × 1.0 g. =6g

3 O : 3 × 16.0 g = 48g

Molar Mass. =174 g

The molar mass of 1 mole of Juglone is 174g.

bi. Moles of Juglone =Mass

Molar mass
Mass= 0.72mg= 0.00072 g
No. moles = 0.00072g ÷ 174g/mol = 4. 1379× 10-6 mol
~=4.14×10-6 mol
ii. 1 mole of Juglone ------> 6. 02 ×1023
4.14 × 10-6 mole of Juglone------> x
X= 6.02×1023 x 4.14 × 10-6
X= (6.02 × 4.14)× 1023-6
X= 2.49 × 1018 molecules of Juglone.

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Therefore, there are 2. 49x1018 molecules of Juglone.

2a. Molar mass of NaCl
1 Na: 1× 23= 23g
1 Cl: 1× 35.5=35.5g
Molar mass= 58.5g/mol
bii. From the no. of moles= mass(g)/Molar mass (gmol-1 )
Mass(g)= no.of moles x molar mass
Mass( g) = 8.55× 58.5 = 500.175g
No. Of moles of NaCl= mass/molar mass= 8.55moles
ii. NaCl -------> Na+ + Cl-
Mass of chlorine ion present.

1 mole NaCl--------> 1 mole of Cl-

8.55 moles NaCl--------> 8.55 mole Cl-
Mass of Cl- = no.of moles x molar mass= 8.55× 35.5= 303.525

molar mass of NaHCO3 = Na + H + 3(O) = 23+ 1+12+3(16)

= 84g/mol
Molar mass of C6H8O7 = 6(12)+8(1)+7(16) =192g/mol
Balanced equation;
3 NaHCO3(aq) + C6H8O7 (aq) -----> 3 CO2( g) + 3H2O + Na3C6H5O7(aq)
1.0×102 mg= 0.1 g

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From the equation;

3 moles of NaHCO3 -----> 1 mole of C6H8O7
3× 84 g/mol of NaHCO3 -----> 1× 192g/mol of C6H8O7
Also, 0.1g NaHCO3 --------------> xg of C6H8O7
==>> 252g = 0.1× 192
X= 19.2/252 = 0.076190mol
Therefore, 0.076 g of Citric acid is used for every 100 mg of NaHCO 3.

b). Also, from the equation.

Molar mass of CO2 = 12+ 2( 16) = 44g

3 NaHCO3 ----------> 3CO2

3 moles 3 moles

3 × 84 g/ mol 3× 44g/mol

252g/ mol of NaHCO3 ---------------------->. 132g/mol CO2

0.1g NaHCO3 ---------------> x g of CO2

252x = 132× 0.1

X= 13.2/252

X= 0.05238 mol

Q4. Balance equation:

C6H10O4(l) + 2NH3(g) + 4H2(g) ---------------------> C6H16N2(l) + 4H2O(l)

Molar mass of C6H10O4 = 6(12)+ 10(1)+4(16)

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=146g/mol

Molar mass of C6H16N2 = 6(12)+ 16(1)+2(14)

= 116g/mol

From the equation;

1 mol of C6H10O4 -----------------------> 1mol of C6H16N2

==>> 146g/ mol of C6H10O4 ---------> 116g/mol of C6H16N2

5×102 g of C6H10O4 -----------------------> x g of C6H16N2

146g/mol x= 5×102 g × 116g/ mol

X= 58000/146 = 397.260274g

X= 397.26 g of C6H10O4

% yield=actual yield/ theoretical yield x 100%

No. Of moles of Adipic acid= 500g/ 146g/mol= 3.425 mol.

Hence, theoretical value= 3.425× 116= 397.26g

% yield= 385g/ 397.26g × 100%= 96.9%

Theoretical yield= No.of moles of Adipic acid x Molar mass of C 6H16N2

15. Symbols of the elements with the following corresponding atomic

numbers for ( See periodic table)

16. Antidote.An antidote is a drug, chelating substance, or a chemical

that counteracts (neutralizes) the effects of another drug or a poison.

Antidote used for Phosphorus poisoning.viz are ;

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 ANITA LEWIS5

a. Astropine

b. Protopam Chloride.

17. Radiopharmaceuticals are compounds used as diagnostic and for

therapeutic purpose.

18. What are diuretic??

Diuretics are class of drugs that increase the flow of urine ( termed
as diuresis).promote diuresis, the increased production of urine.

Example of diuretic ; Hydrochlorothiazide.

19. a. Calculate the molar mass of Aspirin.

Molar mass of Aspirin ( C9H8O4) = 9(C)+8(H)+4(O)

= 9(12)+8(1)+4(16)

=180g/mol

b.Mass = 300mg=300/1000= 0.3g

No.of moles of Aspirin= mass/molar mass

= 0.3g/180g/mol

= 1.6666× 10-3 moles = 1.67× 10-3 mole.

c. How many molecules

From Molecule (N)= no.of moles x Avagadro's number

N= 1.6666× 10-3 x 6.02× 1023 = 1.0032932×1021

Q20. a Molar mass of Aspartame ( C14H18N2O5 )=

14(12)+18(1)+2(14)+5(16)

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= 294g/mol

b. no.of moles of Aspartame= 15g/294g/mol =0.0510 mol

C.Mass in gram of Aspartame= no.of moles× molar mass

= 2.65 mol×294g/mol =779.10 g

d. 7.5mg= 7.5/1000= 7.5×10-3 g

No.of moles = 7.5×10-3 g/294g/mol= 2.5510× 10-5 mol

Molecules number= 2.5510× 10-5 x 6.02×1023 =1.54×1019 molecules

e.number of atoms = no.of moles× Avagadro's number

No.of moles= 2.5g/294g/mol =8.5034×10-6 moles

1 mole of Aspartame= 6.02×1023 atoms

8.5034×10-6 moles = x atom

Cross multiply:

===>> X atom= 6.02×1023 × 8.5034×10-6 = 5.119×1018 atoms.

9/19/2020

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