Sampel Kue LC MS –ESI pos ion

Vol injection 10 ul Date : 11.00 20/2/18

Flow 0.3 ml/min

Eluent : Acetonitril + Ultra water

Operating by : Lab Analisis Farmasi UNG

Quarsetin 25 ppm
Quarsetin c 25 1: TOF MS ES+
3.13 TIC
100 1648312 7.72e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin b 25 1: TOF MS ES+
3.13 TIC
100 1642852 7.72e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin 25 1: TOF MS ES+
3.21 TIC
98 1642018 6.11e6
Area
%

-2 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

25 ppm 3.214 6209521 1642017.875 2.909 3.552

25 ppm 3.129 7667662 1642852.375 2.909 3.417

25 ppm 3.129 7554424 1648312.250 2.943 3.417

Quersetin 20 ppm

Quarsetin c 20 1: TOF MS ES+

3.16 TIC
100 1553128 6.91e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin b 20 1: TOF MS ES+
3.15 TIC
100 1551708 7.33e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin a 20 1: TOF MS ES+
3.15 TIC
100 1550887 7.13e6
Area
%

-0 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

20 ppm 3.146 7109070 1550887.125 2.943 3.366

20 ppm 3.146 7092346 1551707.625 2.926 3.400

20 ppm 3.163 6817189 1553128.125 2.943 3.451

Quarsetin 15 ppm
Quarsetin c 15 1: TOF MS ES+
3.16 TIC
100 1414158 6.32e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin b 15 1: TOF MS ES+
3.16 TIC
100 1412582 6.22e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin a 15 1: TOF MS ES+
3.16 TIC
100 1414165 6.70e6
Area
%

-0 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

15 ppm 3.163 6449927 1414165.000 2.960 3.417

15 ppm 3.163 6185863 1412582.250 2.909 3.451

15 ppm 3.163 6161573 1414158.000 2.943 3.434

Quarsetin 10 ppm
Quarsetin c 10 1: TOF MS ES+
3.18 TIC
100 1335226 5.67e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin b 10 1: TOF MS ES+
3.18 TIC
100 1333893 5.79e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin a 10 1: TOF MS ES+
3.18 TIC
100 1331231 6.03e6
Area
%

-0 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

10 ppm 3.180 5866925 1331231.250 2.943 3.434

10 ppm 3.180 5753895 1333893.250 2.926 3.485

10 ppm 3.180 5616945 1335226.375 2.893 3.468

Quarsetin 5 ppm
Quarsetin c 5 1: TOF MS ES+
3.20 TIC
100 1236589 5.34e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin b 5 1: TOF MS ES+
3.20 TIC
100 1237982 5.27e6
Area
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin a 5 1: TOF MS ES+
3.20 TIC
100 1238274 5.53e6
Area
%

-0 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

5 ppm 3.197 5372871 1238274.250 2.960 3.451

5 ppm 3.197 5188961 1237982.000 2.960 3.485

5 ppm 3.197 5227434 1236588.500 2.960 3.485

Kue A3
Kue A3 a 25 1: TOF MS ES+
3.26;1351246 TIC
96 3.85e6
Area
%

-4
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A3 b 25 1: TOF MS ES+
3.18 TIC
97 1350952 4.25e6
Area
%

-3
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A3 c 25 1: TOF MS ES+
3.20;1350539 TIC
97 4.18e6
Area
%

-3 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

25 ppm 3.197 4278518 1350539.375 2.859 3.569

25 ppm 3.180 4333939 1350951.875 2.825 3.518

25 ppm 3.265 3970343 1351246.250 2.926 3.637

Kue A2
Kue A2 c 25 1: TOF MS ES+
3.20 TIC
99 1239948 5.06e6
Area
%

-1
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A2 b 25 1: TOF MS ES+
3.20 TIC
99 1238455 5.04e6
Area
%

-1
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A2 a 25 1: TOF MS ES+
3.18 TIC
99 1239866 5.21e6
Area
%

-1 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

25 ppm 3.180 5171012 1239866.250 2.893 3.468

25 ppm 3.197 5064539 1238454.750 2.808 3.518

25 ppm 3.197 5089619 1239947.875 2.893 3.518

Kue A1
Kue A1 c 25 1: TOF MS ES+
3.20 TIC
99 1178112 4.86e6
Area
%

-1
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A1 b 25 1: TOF MS ES+
3.20 TIC
99 1179150 4.90e6
Area
%

-1
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A1 a 25 1: TOF MS ES+
3.20 TIC
100 1177397 4.98e6
Area
%

-0 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

25 ppm 3.197 4919909 1177397.250 2.909 3.468

25 ppm 3.197 4897519 1179150.000 2.893 3.501

25 ppm 3.197 4880298 1178112.375 2.859 3.501

Kue A 0
Kue A0 c 25 1: TOF MS ES+
6.31 TIC
2.40e6
%

1.69
94
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A0 b 25 1: TOF MS ES+
6.31 TIC
2.39e6
%

1.69
95
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A0 a 25 1: TOF MS ES+
6.31 TIC
2.51e6
%

1.69
95 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Quarsetin 25 1: TOF MS ES+
3.21 TIC
98 6.11e6
%

-2
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A3 b 25 1: TOF MS ES+
3.18 TIC
98 4.79e6
%

-2
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A2 a 25 1: TOF MS ES+
3.18 TIC
99
5.21e6
%

-1
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A1 a 25 1: TOF MS ES+
3.20 TIC
100
4.98e6
%

-0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80
Kue A0 a 25 1: TOF MS ES+
6.31 TIC
2.51e6
%

1.69
95 Time
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80

Index Time Height Area Lower Bound Upper Bound

Quarsetin 25 ppm 3.214 6209521 1642017.875 2.909 3.552

Kue A3 25 ppm 3.180 4333939 1350951.875 2.825 3.518

Kue A2 25 ppm 3.180 5171012 1239866.250 2.893 3.468

Kue A1 25 ppm 3.197 4919909 1177397.250 2.909 3.468

Kue A0 25 ppm - - - - -