Physical Chemistry Laboratory I

Experiment 8 Name………………………………………………………

Binary Liquid-Vapor Phase ID……………………………………………………………

Diagram Date………………………………………………………..

1. Collect all your experimental results in the Tables below:

V(c-h)ml V(e-a)ml no n(ch) n(ea) X ( ch)

D=0.78g/ml D=0.9 g/ml Refractive mol mol
MW=84.2 g/mol MW=88.1 index
g/mol
1 10 0 1.4256
0.092637 0 1
2 9 1 1.4175
0.083373 0.010216 0.890845
3 8 2 1.41
0.074109 0.020431 0.783888
4 7 3 1.4043
0.064846 0.030647 0.679064
5 6 4 1.398
0.055582 0.040863 0.57631
6 5 5 1.3927
0.046318 0.051078 0.475564
7 4 6 1.3877
0.037055 0.061294 0.376768
8 3 7 1.3835
0.027791 0.07151 0.279867
9 2 8 1.3785
0.018527 0.081725 0.184806
10 1 9 1.3747
0.009264 0.091941 0.091534
11 0 10 1.371
0 0.102157 0

plot : X ch=m∗no +b
 Physical Chemistry Laboratory I

1.2

1 f(x) = 18.42 x − 25.21

0.8
𝑿(𝒄𝒉)

0.6

0.4

0.2

0
1.36 1.37 1.38 1.39 1.4 1.41 1.42 1.43
𝒏_𝒐
𝑹𝒆𝒇𝒓𝒂𝒄𝒕𝒊𝒗𝒆
𝒊𝒏𝒅𝒆𝒙

  V(ch) V(ea) T n(L) n(V) X(L) X(V)

1 10 0 79 1.4256 1.425 1 1
2 9 1 72 1.4201 1.4132 0.949242 0.822144
3 8 2 69 1.4133 1.4036 0.823986 0.645312
4 7 3 68 1.4049 1.3991 0.669258 0.562422
5 6 4 67 1.3983 1.3959 0.547686 0.503478
6 5 5 66 1.3923 1.3931 0.437166 0.451902
7 4 6 68 1.3867 1.3899 0.334014 0.392958
8 3 7 69 1.382 1.3867 0.24744 0.334014
9 2 8 70 1.3772 1.382 0.159024 0.24744
10 1 9 71 1.3735 1.3776 0.09087 0.166392
11 0 10 74 1.371 1.371 0 0

plot :T =f (X L , X V )
 Physical Chemistry Laboratory I

85

80

75

70
T

X(L)
X(V)
65

60

55
0 0.2 0.4 0.6 0.8 1 1.2
x(L,V)