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ABSTRACT
From many years practical industrial experience the author has drawn together a list of the key
points to consider when embarking on a large-scale geometallurgical project. Fundamental aspects
which must be considered include (but are not limited to):
understanding the variability of the orebody both laterally and with depth;
comminution properties and variability;
flotation properties, requirements and variability – differing ore zones may have substantially
different requirements for optimal performance;
the role of texture – the consequences of both grain size and distribution and how the circuit
will handle these;
realistic expectation in terms of the financial requirements and time frame results are required
within; and
integration of, and communication between key personnel within the various departments of
the site (mining, geology and processing) is a fundamental aspect of any geometallurgically
based processing system.
An example of a highly complex nickel sulfide ore will be used as the basis of discussion.
INTRODUCTION
It is well established practice to use mineralogical information employed, only a metallurgist with appropriate experience
in conjunction with metallurgical characterisation to assess an may be able to correctly diagnose the problem.
ores amenability to processing; and this is usually undertaken This paper has been written with operations staff in mind
as part of a feasibility study prior to the actual processing of and seeks to provide some insight into how to (or not to)
an ore. This initial set of information then forms the basis conduct a geometallurgical investigation. It is not intended
for an operations budgeting and forecasting of metallurgical
to provide a review of mineralogical analysis methods, or
performance. In the environment of an existing operation, the
even predictive methods used by some major companies and
use of current mineralogical data is often non-existent within
research facilities. Instead, an example will be presented,
the metallurgical environment despite the data existing within
drawn from the authors many years of experience operating
geological models, albeit in a basic form.
flotation plants treating highly complex base metal sulfide
As orebodies are increasingly becoming more complex, ores and the lessons learned from geometallurgical projects
there is a growing necessity within the industry to use detailed conducted on operating sites.
mineralogical information to predict both plant operating
requirements and ore response. Operators need to know
A REAL WORLD EXAMPLE
whether particular ore zones within an orebody will have
significant differences in comminution and flotation (or The example provided here will be based on a flotation
hydrometallurgical) processing requirements such as ore concentrator treating a complex nickel sulfide ore.
hardness, viscosity, kinetics and reagent type and demand.
Knowledge of the ultimate product specifications such as Identifying the problem
overall grade and recovery and the acceptable levels of The scenario is a fairly common one; an existing concentrator is
contaminant minerals are also required for strategic forward required to treat ore from a new ore source. Previous test work
planning. To date there exists no set guideline for predict- conducted on this new ore showed that a saleable concentrate
ing ore performance based on its mineralogy, with most of 18 per cent Ni is able to be achieved at 70 per cent recovery
operations applying a reactive approach to the problem; using the existing circuit configuration, and these figures
when a problem occurs in the plant the ore mineralogy may have formed the basis of forecasting the plants performance
be checked retrospectively to see whether a link can be found on this new ore, as well as concentrate sales contracts. The
with a specific ore property. Even when this approach is current ore being fed to the plant can be broadly described
1. MAusIMM, PhD Candidate, JKMRC, University of Queensland, 40 Isles Road, Indooroopilly Qld 4068. Email: b.newcombe@uq.edu.au
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 139
B NEWCOMBE
as a coarse grained pentlandite-pyrrhotite; whilst the new ore learned are intended to provide some valuable insight for
has been broadly described as a finely disseminated millerite- anyone considering embarking on a geo-metallurgical study,
pyrite. The target metals of interest are nickel and to a lesser particularly at an operating site.
extent cobalt. As with most nickel concentrators, penalties are
applied if arsenic levels are too high or the Fe:MgO ratio is too Question – ‘Is the plant feed material
low. A schematic of the circuit configuration is presented in consistent?’
Figure 1, showing that a flash flotation cell is in use and there
are currently two stages of cleaning applied. Answer
The operating strategy for the existing ore is very well Plant feed material for this new ore source has been classified
established, having been the sole source of production for by the ratio of sulfide to non-sulfide nickel. This classification
many years. When the new ore is treated through the plant, system is summarised in Table 1.
the operating personnel try to maintain the status-quo, with Consideration of Figure 6 shows that the mill feed grade
significant detrimental impacts on every part of the plant. is possibly the only trend in this plant that displays any
As can be seen from Figures 2 - 5, plant performance is quite consistency; the ‘answer’ returned by both the mining
erratic, despite taking ore from a single stockpile on the ROM and geology departments to this question is that the ore is
pad. consistent as delivered and stockpiled on the run-of-mine
It is evident that the plant is not well operated or controlled, (ROM) pad based on the grade guidelines that have been
having major fluctuations in almost all key operating specified... ‘it’s not us, it’s you’.
parameters. Mill stoppages are frequent, occurring up to Given that the plants in-line assay equipment is well
50 times a month, concentrate grade targets (>18 per cent Ni) maintained and operating effectively, a fault finding
are not being met, and although it’s not able to be shown, the investigation into the key operating equipment (control
plants recovery is well below expectation. Trends with similar valves, flow and level indicators, etc) and variables (such as
variability to those presented in Figures 2 - 5 can be produced water and reagent addition) is undertaken, with little effect.
for every section of the plant (crushing through to final product
thickening and filtration) and more specifically for parameters Question – ‘Has any test work previously been
fundamental to flotation performance, including flotation performed on this new ore?’
feed size (p80) and density. No consistent operating strategy
can be applied to maintain the plants stability, with both Answer
recoveries and concentrate grades fluctuating wildly within There is very little information available from feasibility test
a single stockpile feed. Working in this highly unpredictable work performed on this orebody and the relevance of what
operating environment is also placing a significant amount is available is questionable due to the way core samples were
of stress on plant personnel. The following is a succession of blended together and the proximity of these samples to both
questions that were worked through to try and mitigate the the top and centre of the orebody, which represent ore blocks
problem, this scenario is founded in reality and the lessons that have already been processed. The lack of information
Cyclone
overflow to
flotation circuit
Cyclones
Flash
Float
Flash Con
(to final con)
Circuit Feed AG Mill Ball Mill
(from crushing)
Rougher
Final Tail Scavenger
Cleaner
ReCleaner
To Final Con
140 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
LESSONS LEARNED FROM GEOMETALLURGICAL INVESTIGATIONS CARRIED OUT ON A NICKEL SULFIDE FLOTATION PLANT
GrindingCircuitPerformance
HourlyAveragefor7days
90 600
85
550
80
500
75
450
70
MillFeedTonnes
MillPoerkW
65 400
60
350
55
300
50
250
45
40 200
Time(hours)
MillFeed(tph) MillPower(kW)
GrindingCircuitPerformance
6minuteaverageover24hours
90 600
85
550
80
500
75
450
70
MillFeedTonnes
MillPoer(kW)
65 400
60
350
55
300
50
250
45
40 200
Time(sixminaverages)
MillFee(tph) MillPower(kW)
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 141
B NEWCOMBE
FlotationCircuitPerformance
HourlyAveragefor7days
30
25
20
ConcentrateGrade%M
15
10
0
Time(hours)
ConcentrateGrade(%M)
FlotationCircuitPerformance
6minuteaverageover24hours
25
20
ConcentrateGrade%M
15
10
0
Time(sixminaverages)
ConcentrateGrade(%M)
FIG 5 - Twenty-four hour flotation performance (six minute average data) (note that no data was available for the tail grade during this period due to blockages in the
line feeding the in-line analyser).
142 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
LESSONS LEARNED FROM GEOMETALLURGICAL INVESTIGATIONS CARRIED OUT ON A NICKEL SULFIDE FLOTATION PLANT
CircuitFeedGrade
6minuteaverageover24hours
2.5
1.5
M%
0.5
0
Time(sixminaverages)
M%
FIG 6 - Twenty-four hour mill feed grade (six minute average data) (note that periods of flat-line occur when the equipment is being maintained).
distinct ore zones based on sulfide mineral content and grain
size, these are presented in Table 2.
TABLE 1 It is important to note that at this stage the host rock
Current ore classification system. variation has not been considered.
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 143
B NEWCOMBE
144 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
LESSONS LEARNED FROM GEOMETALLURGICAL INVESTIGATIONS CARRIED OUT ON A NICKEL SULFIDE FLOTATION PLANT
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 145
B NEWCOMBE
High
Violarite
zone
Foot-Wall
Ore
Main Hanging
Lode -Wall
Ore
FIG 11 - Plan view of arsenic distribution (ppm). FIG 12 - Plan view of overall ore zones.
Question – ‘Can an operating strategy be of $100 k per ore type, it is decided to proceed with testing
quickly developed to deal with the different the three most prevalent ore types (1, 3 and 4) without any
grinding/hardness characterisation work. The objective of this
ore types?’ work is to provide a basis for forecasting plant performance,
Answer find a preliminary reagent scheme based on the available
A detailed test work program at this stage would be a waste of reagents on site for each ore type and identify the nature of
time and money if the current ore classification system remains the losses that are occurring.
in place. Discussions are held between the geology, mining Samples for this work are taken from the grade control
and metallurgy departments. An understanding is eventually drilling program and are ‘RC’ drill chips. Results of the three-
reached that if (and only if) metallurgical test work shows stage cleaning flotation test work are presented in Table 5 and
that plant performance will be significantly compromised by indicate that not only does each of the ores respond differently,
maintaining the current system, ores will be re-classified by they also have significantly different reagent requirements.
mineral content, new orebody models produced and mining The feed material for each test has been ground to the plant
production and ore separation will be in-line with these new target p80 (75 μm). Table 5 is provided to give an overall
models. review of the performance differences between the ores at
Available funds are limited and results are required quickly. laboratory scale. Please note that the depressant referred to in
As the problem is perceived as largely a flotation issue and this table is used for non-sulfide gangue depression and is not
flotation testing and associated mineralogy will cost in excess targeting the arsenic minerals.
TABLE 2
New ore zone classifications.
TABLE 3
Preliminary test work results under standard conditions.
TABLE 4
Preliminary test work results under optimised conditions.
Ore type Head grade Con grade Recovery
(Ni %) (Ni %) (%)
Ore type Head grade Con grade Recovery
1 1.1 4.9 86 (Ni %) (Ni %) (%)
2 1.2 7.8 56 2 1.2 9.1 66
3 0.7 4.4 60 3 0.7 5.4 66
146 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
LESSONS LEARNED FROM GEOMETALLURGICAL INVESTIGATIONS CARRIED OUT ON A NICKEL SULFIDE FLOTATION PLANT
TABLE 5 TABLE 6
Optimised performance for each ore type from three-cleaner test work. Grind times required to achieve a target p80 of 75 μm.
Feed Ore type Grind time
Ore Con grade Recovery
grade Reagent use
type (Ni%) (%) 1 11 min, 53 sec
(Ni%)
3 16 min, 15 sec
Standard collector and
activator dosages can be 4 12 min, 11 sec
used, but frother addition
1 0.8 17.3 78 should be minimised in the In terms of host rock variability, although no specific
rougher cells. Depressant ore hardness or grinding characterisation work has been
use should be limited to performed, there is an indication that this may also be a
final cleaning only. problem when the lab grind times are considered, as shown in
Increased collector and Table 6. It is also noted that slurry viscosity may be an issue
depressant requirements, when treating ores 3 and 4.
3 0.7 10 62 frother addition should be On the basis of these results, new operating strategies are
minimised, standard dose put into place across site, with ores being re-classified into
of activator. new categories, new block models produced and new ROM
Standard collector, activator stockpiling strategies employed. Reagent strategies within
and frother dosages can the plant are changed to allow online optimisation for each
4 0.7 8.0 67 be used but depressant ore type, along with optimisation of other key operating
addition should be parameters such as air addition, pulp density and froth depth
minimised. for each ore. Ongoing test work is undertaken to find a solution
to viscosity problems and new reagents are tested for each ore
type to seek out better alternatives.
Whilst recovery is considered acceptable for the ore types
tested, the third cleaner concentrate grades indicate that
significant unforeseen difficulties will be encountered to
OVERALL RESULT
reach contract concentrate grades when treating ore types 3 The impact of these changes on day-to-day operation of the
and 4. It is important to note that the circuit treating the ore plant is displayed in Figures 13 to 17. These figures contain
incorporates a flash flotation cell, and no attempt has been data from immediately after the first ore is treated with the
made as part of this test work to determine whether the new classification system in place (some eight months after the
operation of this unit will be beneficial or detrimental in trying initial inception of the project). The most significant change is
to achieve both grade and recovery targets. The test work also that of improved comminution circuit stability, with periods
indicates that in order to get the best results from each ore of several days enjoyed without stoppages and consistent
type, a different reagent addition strategy should be in place feed material. Another beneficial impact is the ability to
for each. stabilise the plant on a single ore type, optimise performance
GrindingCircuitPerformance
HourlyAveragefor7days
90 600
85
550
80
500
75
450
70
MillFeedTonnes
MillPowerkW
65 400
60
350
55
300
50
250
45
40 200
Time(hours)
MillFeed(tph) MillPower(kW)
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 147
B NEWCOMBE
GrindingCircuitPerformance
6minuteaverageover24hours
90 600
85
550
80
500
75
450
70
MillFeedTonnes
MillPowerkW
65 400
60
350
55
300
50
250
45
40 200
Time(sixminaverages)
MillFeed(tph) MillPower(kW)
FlotationCircuitPerformance
HourlyAveragefor7days
25
20
ConcentrateGrade%M
15
10
0
Time(hours)
ConcentrateGrade%M
148 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
LESSONS LEARNED FROM GEOMETALLURGICAL INVESTIGATIONS CARRIED OUT ON A NICKEL SULFIDE FLOTATION PLANT
FlotationCircuitPerformance
6minuteaverageover24hours
20
18
16
14
ConcentrateGrade%M
12
10
0
Time(sixminaverages)
ConcentrateGrade%M
CircuitFeedGrade
6minuteaverageover24hours
0.8
0.7
0.6
0.5
%M
0.4
0.3
0.2
0.1
0
Time(sixminaverages)
MillFeedGrade%M
FIG 17 - Twenty-four hour mill feed grade (six minute average data).
concentrate grades remained low throughout averaging 16.7 Whilst flotation recovery was improved overall, there was an
per cent Ni, well below the target of 18 per cent Ni. Large indication that the residence time of the plant was insufficient
fluctuations in concentrate grade were observed from one for some of the slower floating minerals found in ore types 3, 4
ore type to another, ranging from as low as 12 per cent up to and 5. Flotation test work was continued in order to understand
22 per cent Ni. the varying kinetic responses of the minerals concerned and
A major factor contributing to poor flotation performance perform ongoing flotation optimisation test work.
was ore viscosity, this previously unforeseen problem may
have been identified and mitigated earlier if closer attention LESSONS LEARNED
had been paid to host rock properties (such as fibre and clay
content). The operation of the flash flotation cell also proved The information presented here represents a scenario that
troublesome with this viscous, poorly liberated material; with has been and will continue to be played out at many operating
evidence to suggest that the flash circuit should be bypassed plants all over the world. The key lessons learned by the
whilst on some ores to minimise reduction in final concentrate author, having been through this experience a number of
grades. times can be summarised as thus:
THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 149
B NEWCOMBE
Understanding of the orebody and how it varies both flotation testing and associated mineralogy and reagent
laterally and with depth is a requirement for all persons optimisation test work) was in the order of $500 k.
involved in a geo-metallurgical study. Metallurgists are not, Even after this initial phase of testing, work was still
and should not be expected to have intimate knowledge of ongoing due to the continued issues associated with the
geological models, but through good communication with poor kinetics of some of the ore types and ore viscosity
the site geologists have ready access to overviews of block problems. More thorough planning and testing of the ore
models and their assay and mineralogical content. These in the initial stages of feasibility may have reduced both
are easily printed from the programs the geologists use the overall cost and duration of this particular project,
and provide a visual (usually colour coded) tool for seeing and also saved the operation from having to maintain an
grade and mineral variation. essentially uncontrollable concentrator whilst the work
Understanding key aspects of mineralogical response is was being done.
a fundamental requirement of the metallurgist involved. Communication is a fundamental aspect of this type
Sulfide minerals within a group each have their own of project. Involvement from the geology, mining and
unique processing requirements and response (ie the processing departments on site are required to make
different nickel sulfides have a different response to the such an endeavour a success and the communication
same reagents and chemical conditions). Variations in between these departments must be open and honest.
host rock properties may also require different treatment As with all projects involving teams, selection of the
methods to be employed. Where such knowledge is lacking appropriate people must not only take into consideration
within the site team, it would be advised to involve a their technical ability but also their personality and inter-
consultant (either from within the company or an external personal skills. Technical knowledge can always be drawn
source) with the relevant experience, not only to interpret from sources external to the team as required.
metallurgical data, but also provide high-level training Utilise all available resources; managing a troublesome
and education to the site team on geo-metallurgical issues.
plant as well as conducting major project work stretched
Host rock characteristics and consequent comminution the site metallurgy department to its absolute limits. The
properties are just as important as flotation properties. use of ‘corporate’ metallurgists located elsewhere within
Whilst the comminution circuit in the example provided the company would have significantly eased the load. Good
here is now able to be operated steadily on each ore
relationships with reagent suppliers allowed test work for
type, milling throughput is limited and target p80s are
optimising reagents and tailoring collector and frothers
seldom achieved, affecting both the grade of and recovery
to be performed by external technicians, allowing the site
to final concentrate. Ore viscosity is also an ongoing
team to remain focused on the significant task at hand.
concern. A considerable amount of capital expenditure
would be required to upgrade the comminution circuit
in order to achieve the expected results, upgrading of
ACKNOWLEDGEMENT
pumping equipment for thickeners is also required, along
The author wishes to acknowledge the invaluable assistance
with significant amounts of test work in order to find
of Professor Dee Bradshaw (JKMRC) in the preparation of
suitable flocculants and dispersing agents. All of this was
this document.
unforeseen from the feasibility test work conducted on the
ore; if initial testing had been expanded to more thoroughly
investigate ore properties, systems could have been put REFERENCES
into place to cope with the new ores’ requirements. Ackerman, P K, Harris, G H, Klimpel, R R and Aplan, F F, 1987a.
Evaluation of flotation collectors for copper sulphides and pyrite,
Understanding the role of texture; the consequences of
I, Common sulfhydryl collectors, Interntional Journal of Mineral
both grain size and distribution and how the circuit will
Processing, 21:105-127.
handle these is vital. In the circuit considered here, the
use of a flash flotation cell to treat a finely disseminated, Ackerman, P K, Harris, G H, Klimpel, R R and Aplan, F F, 1987b.
Evaluation of flotation collectors for copper sulphides and pyrite,
slow floating nickel sulfide ore resulted in a very low-grade
III, Effect of xanthate chain length and branching, International
concentrate. The circuit configuration was eventually
Journal of Mineral Processing, 21:141-156
required to be altered to accommodate this type of ore.
This could have been picked up earlier if closer attention Ross, V E, 1991. An investigation of sub-processes in equilibrium
froths (I): The mechanisms of detachment and drainage,
had been paid to the available mineralogical data.
International Journal of Mineral Processing, 31:37-50.
Realistic expectation in terms of time and financial
requirements for such a study should also be outlaid from Senior, G D, Shannon, L K and Trahar, W J, 1994. The flotation of
pentlandite from pyrrhotite with particular reference to the effects
the start of such a project. In the example provided here
of particle size, International Journal of Mineral Processing,
there is eight months between the initial inception of the
42:169-190.
project and the actual changeover to when the first ore was
treated through the plant under the revised classification Smith, L K, Senior, G D, Bruckard, W J and Davey, K J, 2011. The
flotation of millerite – A single mineral study, International
system. The cost of the test work conducted throughout
Journal of Mineral Processing, 99:27-31.
that period (including feed ore characterisation, baseline
150 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011