Professional Documents
Culture Documents
THEORETICAL CHEMISTRY
VOLUME XVI
Pt and General Index, Completing the Series
BY THE SAME AUTHOR
Hg.
With 232 Diagrams.
Vol. V. B, Al, Ga, In, Tl, Sc, Ce, and Rare
Vol. VII. Ti, Zr, Hf, Th, Ge, Sn, Pb, Inert Gases.
Vol. VIII. N, P.
With I 56 Diagrams.
ON
BY
WITH 94 DIAGRAMS
V
CONTENTS
CHAPTER LXXIV
PLATINUM
� 1. The History of the Platinum Metals (1) ; � 2. The Occurrence of the Platinum
Metals
VU
AB BRE VIATIONS
� aq. -� aqueous
atm. = atmospheric or atmosphere (s)
at. vol. = atomic volume(s)
at. -wt. = atomic weight(s)
0K
-�>(8)-{S�!e^B)
sat. � saturated
temp. �= temperature(s)
vap. �� vapour
In the CPOSS references the first number in clarendon type is the number of the
volume ; the second number refers to the chapter; and the succeeding number refers
to the
" �," section. Thus 5. 88, 24 refers to � 24, chapter 38, volume 5.
ix
ABBREVIATIONS
triangle represent the single components A1 B1 and C1 the sides of the triangle
represent binary
mixtures of A and B1 B and C1 or C and A ; and points within the triangle, ternary
mixtures.
The compositions of the mixtures can be represented in percentages, or referred to
unity, 10,
etc. In Fig. I1 pure A will be represented by a point at the apex marked A. If 1OO
be the
Fia. 1.
standard of reference, the point A represents 100 per cent, of A and nothing else;
mixtures
containing 8O per cent, of A are represented by a point on the line 88, 60 per
cent, of A by a
point on the line GG1 etc. Similarly with B and C�Figs. 3 and 2 respectively.
Combine
Figs. 1, 2, and 3 into one diagram by superposition, and Fig 4 results. Any point
in this
diagram, Fig. 4, thus represents a ternary mixture. For instance, the point M
represents a
mixture containing 20 per cent, of A1 20 per cent, of B, and GO per cent, of C.
CHAPTER LXXIV
PLATINUM
PLATINUM is one member of a family of six elements called the platinum metals.
They usually occur together so that before the discovery of the companion elements,
the term platinum was applied to an alloy with platinum as the dominant metal.
The same thing is often done to-day. The platinum metals, with their sp. gr.,
are as follow :
IOSMTIJM (22-47)
Platinum metals
[PALLADIUM (11-9O)
\^ RUTHENIUM (12-26)
F. Hoefer, and C. de Paravey suggested that the " heavy black pebbles "
contained platinum presumably because of their weight, but Pliny's ideas of
specific gravity were very vague, and in one place he even said that lead is
heavier
than gold. H. Kopp, and E. IJ. Schubarth very rightly considered that these
far-fetched allusions have no connection at all with platinum. In the sixteenth
century, J. C. Scaliger,2 writing against G. Cardanus' dictum that all metals are
fusible, said that there is a metallic substance in the mines of Mexico and Darian
(Panama) which cannot be melted in the Spanish furnaces. It is considered that
this metallic substance was probably that which was afterwards called platinum
because platinum is now known to occur in these very districts. A. N. von Scherer
also said that from a reference in B. A. Balbin's Epitome it appears as if platinum
was known to the Bohemian Jesuits at the end of the sixteenth century. Towards
the middle of the eighteenth century, A. de Ulloa accompanied the expedition sent
from France to measure the arc of the meridian at the equator, and in his account
VOL. xvi. 1 B
INORGANIC AND THEORETICAL CHEMISTRY
America, there is an unworkable, metallic stone called platina which makes even
gold ores useless if it is associated with them in large proportions. The South
metal. Other specimens from Spanish America found their way into Europe about
1*. J. Macquer and A. Baumc, P. Bergsoe, etc. Some of the early descriptions
were based on the properties of the crude mineral, and did not apply to platinum
per se.
Somo of tlio early spofimons of platina. were contaminatod with, minute globules of
mercury because the' mineral had been previously ground with mercury in mills with
the
object of dissolving out the gold. LTntil assayers had learned to deal with the
alloy of
Xilatinum and gold m cupcllation processes, gold could be adulterated with platina
-without
being detected by the sp. gr. tests, or by cupcllation processes then available. W.
Lewis
reported that some bars of gold had been received from some Spaniards in payment
for
goods, and that the bars were very brittle, and could not be refined so that they
were
** qui to useless " ; and also, on this account, the Dutch refiners at Dort are
said to have
called platina <lialtolt4M melallorutn. It was also said that the King of Spain had
ordered
the mines that afford the platina to be closed in order to prevent the fraudulent
adulteration
of gold ; O. IJ. JBerthollot and 15. "I'elIetier said that the Spanish Government,
for a similar
reason, had ordered a consignment of platinum or gold debased by platinum to be
thrown
into the sea.
The term platina is the diminutive form of the Spanish plafa, silver, and it was
applied in allusion to the silvery colour of the metal. T. Scheffer called it aurum
river Pinto was one of the tributaries of the San Juan. The term platinum
ultimately crystallized from all these appellations.
E. Milly said that platinum is not an element, but rather an alloy of gold,
iron, and mercury ; and G. G. L. de Buff on, that it is an alloy of gold and iron.
These hypotheses were not acceptable to M. Blondeau, and L. JS. G. de Morveau.
The observations of W. Lewis, T. Scheffer, A. Cronstedt, A. S. Marggraf,
P. J. Macquer and A. Baume, T. Bergman, T. Willis, C. von Sickinger, L. Crell,
C. L. Berthollet and B. Pelletier, A. von Mussin-Puschkin, L. B. G. de Morveau,
and J. L. Proust showed that platinum was entitled to rank as an elemental
metal, sui generis, even though investigators at a later period separated platinum
into a group of elements previously unknown.
There have been some erroneous, and some unverified reports of other elements in
platina. Thus, G. Osann said that platinum ore from the Urals contains three new
metals :
and titania. C. F. Chandler reported a white metal in native platinum from Oregon
which
PLATINUM
resembled the white metal found by Jf. A. Genth in some Calif ornian gold ores. The
metal
was unnamed, and the reports unverified. S. Item reported the disco vex-y of a new
element
in some platinum residues, and he named it davyum, but J. W. Mallet showed that
davyum
is a mixture of iridium, rhodium, and iron. T. "WiIm reported a new element in
platinum
ores, but he did not assign to it a name, and A. Guyard reported an element
ourali'uyrh in
Russian platinum, but both reports are unconfirmed. A. del Campo y Cerdan and S. P.
do
Rubies could detect no new element in the platiniferous minerals from the Urals.
ore which is insoluble in aqua regia ; and in 1804, S. Tennant showed that the
residues
contained two distinct metals, one was named iridium�from iris, the rainbow�on
account of the varying colours of its salts, and the other, osmium�from 6<rfj,rj, a
REFERENCES .
W. Noddack's estimates are indicated below, and for a later estimate, they gave
5-0 X 1O-8. The subject was discussed by G. Berg, W. Vernadsky, F. Bernauer,
A. B. Fersmann, I. and W. Noddack and O. Berg, P. Niggli, E. Herlinger,
V. M. Goldschmidt and C. Peters, G. Tammann, O. E. ZvyagintzefT, and P. Vinassa.
Platinum has been reported from extra-terrestrial sources. Thus, J. M. Davison 2
observed platinum and iridium in the meteoric iron of Coahuila, and Toluca,
Mexico ;
C. Claus, P. Collier, H. St. C. Deville and H. Debray, L.. Duparc and co-workers,
R. A. Farquharsen, A. Frenzel, F. A. Genth, A. Hadding, G. C. Hoffmann,
E. Hussak, J. F. Kemp, S. Kern, I. Koifman, N. von Kokscharoff, M. M. Kositzky,
A. Kromeyer, P. Krusch, J. J. Kyle, A. Leplay, W. J. Martin, G. Osann, S. P. de
Rubies, S. F. Shemtschushny, Ii. F. Svanberg, A. Terreil, G. Tschernik,
H. N. Warren, and F. Weil. The following is a selection :
Pt Pd .Rh Ir (Ir.Os)
Colombia . 76-82-86-20 0-50-1-66 1-22- 3-46 0-85-2-52 0-95- 7-98
California . 76-50-90-24 O-10-1-95 0-65- 3-39 0-85-4-29 0-68-22-55
Canada . . 68-19-78-43 0-09-0-26 1-70- 3-IO 1-04-1-21 3-77-14-62
Urals . . 68-72 86-5O O-14-1-87 0-30 11-07 0-83 5-32 0-57-3-85
Atxstralia . 59-80-61-40 1-50-1-80 1-50- 1-85 1-10-2-20 25O - 26-O
The iron ranged from 2-3O to 9-78 ; the copper, from 0-21 to 5-20 ; the gold, from
0-3O to 315 ; and the osmium, from 0-19 to 1-13. S. P. de Rubies observed 0-1
per cent, of nickel and cobalt, in some platinum from Kitlim, Urals ; and
Gold Au Ag Pd Pt Ir Rh
Palladie 86-0-91-1 O to 4-2 8-2-11-6
o-01
3O-4 �
found in the auriferous gravels and sands, and are doubtless fragments worn away
from the rock in which the metals were originally deposited. In the majority of
cases, the mother rock, the original home of the platinum, consists of basic- or
ultra-basic igneous rocks including the peridotites, pyroxenites, and dunites.
The peridotites and pyroxenites are composed of iron magnesium silicates,
pyroxene, and augite, with hornblende, olivine, chromite, ilmenite, and magnetite ;
whilst the dunites consist principally of olivine with some chromite. These rocks
have been more or less altered to serpentine. Examples have been quoted by
R- P- Greg and W. G. Lettsom 1X reported that the presence of platinum has been
recognized
auriferous sands of Wieklow, Ireland. Platinum is not worked in France, but there
are a
PLATINUM
few places where its presence has been reported. Gt. A. Itenngott i a announced its
presence
at St. Arey, Dept. Isere ; and E. Gueymard, at Chapeau in the Vallee du Drac, at
Rousses
in Oisans ; and near Presles in Savoy. �T. J. Ebelmen, and E. Gueymard noted that
platinum is associated -with many of the minerals in the Alps. P. Berthier and
platinum has been reported in the auriferous sands of the Ilhine by L. Hopff, and
J. W. Dobereiner ; in the silver of Commern and Mochernich, by M. R-ossler ; in the
gold
of Wilhelmshiitte, by J. J. Herzelius ; and near Tilkerode, and Zorge in the Marz,
by
F". Wrede, J. C. L. Zinckon, and O. Luedecke. According to P. Krusch, platinum
occurs
finely disseminated in the slates and graywackes of Westphalia�Ereudenberg, Siegen,
Ekaterinburg, and declared a state monopoly. About 1014, Russia was producing about
93 per cent, of the world's supply of platinum. The metal was derive* 1 from the
extensive deposits of alluvial sands in the Ural Mountains. According to C. Claus.
development of the JNTizhni-Tagilsk deposits began itx 1824, and in 1825, the metal
was
also found in Goroblagodat. The most prolific producing districts are south-west of
Nizhni-Tagilsk, north-west of Nizhni-Turinsk, and the Isoff district, near
Goroblagodat.
The whole of tho platinum is derived from gravel deposits which are usually
auriferous
and associated with dunite. According to N. K. Wyssotsky, and A. D. Lumb:
The platiniferous belt of the Urals consists of four parallel bands striking,
roughly,
north and south ; the westernmost of those, made up of crystalline schists, forms
tho watershed between Europe and Asia. The next band to tho east comprises
olivine- and mica-gabbros, diallage-peridotites, diontes and altered syenites�all
of which have been erupted from a great depth. The third band is made up of Lower
Devonian sedimentary rocks, shattered and buried in places by diabasic eruptive
rocks. Tho eastern portion of this band is formed of eruptive rocks of deep-seated
origin which may be gneissose granites. The fourth, or most easterly band, is
composed
of ancient rocks, which have boon eroded by the advancing sea of Lower
Tertiary age. The area emerged from the waves as early as the Carboniferous
period ;
consequently the accumulation of platinum, and in some localities of gold, m the
INORGANIC AND THEORETICAL. CHEMISTRY
surface-deposits, wore not swept away. They were concentrated later on in the
alluvia�perhaps at the time of the most intense glaciation, probably in the
Pleistocene.
The basic igneous rocks, from which the platinum is derived, are exposed in the
form of discontinuous elliptical outcrops near the summits of the Urals,
particularly
on the western side of the mountains. These outcrops attain larger dimensions in
the northern and central TJrals than farther south. The process of concentration of
platinum in the gravels has clearly extended over a very long period of time, and
it is probable that the richer gravels have been reconcontrated, perhaps several
times.
worked on the tributaries of the Rivers Tagil, Salda, Imiaura, and Tura. In the
Nizhni -
Tagilsk district, the richest placers are iix the valleys of the Rivers Visim,
Martian, Sisim,
Chaush, and Cherna, and farther south, along with gold, in the gravels of Nevian,
Verkhne-
Isot, 13ilonibaov, Alapaov, Sysert. Kyshtym, and Mias, and in the Rivers Tanalyk,
Sakmar,
and Urtazym. There are smaller deposits in Nikolae-Pavdinsk, Rastos, and Systersk.
The placer deposits are derived from country rock made up of serpentine gabbro,
diallage,
and olivenite and the associated minerals are chiefly quartz, zircon, ilmenite,
chromite,
magnetite, spinel, and native gold and palladium. The crude platinum usually
includes
iridium, rhodium, ruthenium, and iron. A. A. Losch, A. Karpinsky, and A.
Jvrassnopolsky
discussed the occurrence of platinum in Bissersk, -where a 2-kgrm. nugget of
platinum was
found. In addition to what has been previously stated, the Ural deposits were
discussed
by C. Blomoke, G. Rose, A. Inostranzeff, I. Koifman, A. G. Betochtin, V. P. Mishin,
J. H. Li. Vogt,*8 and G. Lunde and M. Johnson also described the presence of traces
of
platinum in the nickel ores of Norway ; and G. vom Rath, in the silver of
Konigsberg.
J. PT. Vogel 19 roportod traces of platinum in Portugal. According to L. N.
Vauquelni,^0
platinum occurs in Spain in the silver mines of Guadalcanal, Estremadura, although
J. J. Berzolius had doubts on this subject. A. Orio reported traces of platinum to
be
associated with the pyrites of Asturia. According to A. D. Lumb, the metal lias
also been
noted at Ronda, Malaga, in the alluvial deposits along the Rivers Verde and
Guadaiza.
The deposits are derived from serpentine and peridotite rocks. The pay gravels
contain
8 grms. of platinum per ton. The metal has also been reported in the other parts
but
not in payable quantities. It occurs principally in the northern districts, and in
the
Rivers Minho, Luna, SiI, Orbigo, Gallego, Cinea, Darro, and lower Jenil, where it
occurs
in the concentrate sands accompanied by magnetite, ilmenite, zircon, and frequently
gold.
S. P. de Rubies, K. Rubio, L. Duparc and A. Grosset, T. C. Earl, F. Gillman, and D.
y Orueta
and S. P. de Rubies discussed the occurrence of platinum in Spain.
Asia.�The Uralian deposits in Asia have been indicated in connection witli the
Russian deposits. R. Helmhackor 21 reported the presence of platinum in the
auriferous
sands of Altai ; and it has also been reported in Armenia�Batum and Sasun�by L. do
Launay,82 but none was found by A. G. Betochtin in the peridotites of Gokoha. J. P.
Kemp,
and N. Nakovnik reported it in Siberia�in Baikal, Balkash, and Jenissei. K. Jimbo,
and
T. Wada observed that in Japan, the metal occurs in the auriferous sands of the
province of
Ishakari, and the Yubari River of Iburi ; in the Rivers Yubari-garva, Pechau, and
other
rivers in the province of Hokkaido where gold and iridosmium are associated with
the
platinum. It is also found in the gold and iron sands of the Nishi-Mikawa, in the
province
of Sado. E. de Hautpiek mentioned the occurrence of platinum in the auriferous
gravels
in the Uryanchai district of Mongolia, on the Russian border of China. L. de Launay
found that the metal also occurs in the auriferous sands of Rigal, in the
Philippines. Traces
PLATINUM
of platinum have been noticed associated -with the gold obtained from native
workings at
Bonai, in India.28 Platinum, and iridioplatinum were discovered in Burma, in 1831,
in the auriferous sands of the Ava. The occurrence was described by J. Prinsep, A.
Faber,
It. Romania, and H. Burney ; and M. F. Heddle proposed to call the metal from this
locality avaite. Platinum occurs associated with gold in the Irawaddy River, and it
has
been obtained commercially at Myitkyina ; and it has been located in the iridosmium
in
the auriferous gravels of the rivers draining the Patkoi Ranges on both the Assam
and the
Burma sides. Platinum was also discovered in south-eastern Borneo in 1831, Jn the
gravels
of Gunung Lawack ; and, according to T. Posewitz,24 it is now obtained as a by-
product
of the gold-washing in the province of Tanah-Laut. The platinum is here associated
with
osmiridium, and gold. The mineral laurite, (RU,OB)S2, occurs in these deposits. L.
Hundeshagen
also described the occurrence of platinum in the diamond placers, "west and
southeast
of Borneo. The Borneo platinum was examined by M. Bocking. According to
been also reported in the auriferous gravels of Fenerive, Marolambo, and Vandrozo,
in
Madagascar. The subject was discussed by L. Duparc, and L. Duparc and co-workers.
The
gold-platinum deposits at Ru we, in Katanga, were described by P. V. Brande.
A. E. V. Zealley *� located platinum in the conglomerates and gravels of the
Soinabuba
Fields, near Gwelo, in Rhodesia. The country rock is serpentinized dunite. The
deposit
is capped by a ferruginous, siliceous gossan. The ore yields 3 ozs. 12 cwts. of
platinum
per ton, and 7 ozs. of osmiridium per ton. B. Lightfoot, and H. B. Maufe also noted
gold
and platinum in a reef in the great dyke of norite at the head of the valley
drained by the
River Umtebekwe. The platinum is found only in notable quantities in those areas of
the dyke where felspar-rich norite is present. According to P. A. Wagner, there are
large reserves of platinum in. South Africa, principally in the Transvaal. The
platinum
metals occur in the most diverse circumstances, and in rocks ranging in geological
age
from the most ancient to the most recent. W. Bettel noted the metal in the black
sands
from the battery " clean-ups " on the Rand at KIerksdorp, and other gold-mining
districts,
and in the residual slimes at the Rietfontem mines. A. Hall and W. A. Humphrey
observed
that samples of chrotnite from Kromdaal, near Rustenburg, and from the
Secoeoeniland
deposits may contain 1 to 1 � dwt. of platinum per ton. The platinum metals in the
Transvaal occur in the ultra-basic and basic rocks about Uitkomst, Freezburg, and
Messina ;
in the auriferous conglomerates of Witwatersrand, and the Black Reef in JKlerksdorp
district; m the norite zone of the Bushveld; and m the igneous complex�a vast body
of
plutonic and volcanic rocks in the central part of the Transvaal. According to P.
A. Wagner,
the platinum here occurs in
1. Oreumotectic deposits formed by segregation from the parent norite magma,
and occurring in the acid quartz-bearing differentiates of the norite magma.
11. Orthoteetic deposits formed by direct segregation from the parent norite
magma.
A. Deposits in which platinum is associated with magmatic nickel-copper-iron
sulphides in norite, pyroxenite, and harzburgite.
(a) In the upper part of the norite zone, e.g. (i) Deposits of the Blaauwbank
type in which the ore-bearer is quartz-bearing anorthositic
norite. (ii) Deposits of the Stulpoort Park type in which the
ore-bearer is a medium grained, spotted norite rich in felspar,
(iii) Deposits of the Minsk's Claims type, Lydenburg District,
in which the ore-bearer is a rather coarse-grained diallage norite
rich in felspar,
(o) In the lower part of the norite zone, e.g. (iv) Deposits of the
Merensky Horizon tyj>e occurring above and below the main
horizon in the Lydenburg District. (v) Deposits of the
Merensky Horizon type as developed in the Rustenburg, Pretoria,
Lydenburg, Pietersburg, and Potgietersrust districts ; the ore
bearers are pseudo-porphyritic pyroxenitic diallage-norite,
felspathic, pyroxenite, felspathic harzburgite and ehromitite.
(vi) Deposits of the Tweenfontain type, Potgieterscrust District
in which the ore-bearer is a fine-grained pyroxenitic diallagenorite
emerging into coarse-grained felspathic bronzitite and
bronzitite. (vii) Deposits of the VaIk fontein type, Rustenburg
District, in which the ore-bearer is bronzitite.
B.�Chromitite deposits.
INORGANIC AND THEORETICAL CHEMISTRY
B. D. Longyear found a moan content of 0-0068 oz. of platinum, 0-022 oz. of gold,
0-223 oz.
of silver, per ton JTI addition to 1*95 per cent, of nickel, and 1*11 per cent, of
copper. The
subject was discussed by F. W. Clarke and C. Catlett, A. P. Coleman, H. J. L. Vogt,
and
J. W. Dickson. Platinum has been also reported from the vicinity of Star Lake, and
Le
Pas district in Mamtoba. G. C. Hoffmann reported platinum in the sands of the North
wide area in placer deposits. The platinum is found in auriferous sands from
streams rising
in the belt of serpentine rocks in the Siskyou, Butta, Calaveras, Stanislaus,
Trinity, Yuba,
Kern, Humboldt, Plumas, Sierra, Placer, Shasta, and El Dorado Countries. The
platinum
in the foothills of the Sierra Nevada was in old stream channels on the western
slopes of the
mountains. Platinum occurs in the beach deposits on the Pacific coast in the
counties
of Coos, Curry, Josephine, Oregon, and Del Morte. There is some alluvial platinum
near
Placervillc. The Californian platinum contains 25 to 45 per cent, of iridium, and
it is believed
to originate in the serpentine and olivine rocks of Sierra Nevada, etc. J. D. Dana
mentioned
the occurrence of platinum in the Klamath region ; and F. A. Gonth, at Capo
Blanco. Platinum was reported by J. F. Kemp to occur m Colorado, in the black sands
of Clear Creek ; in the gold gravels of Como ; and in a vein near Villa Grove. J.
F. Kemp
also reported platinum to occur in the Lumpkin county in Georgia ; and J. F. Kemp,
and
T. H. Hite, in the auriferous sands of Snake River from Baskerville to Lewiston in
Idaho.
In JMontana, J. F. Kemp noted the occurrence of platinum at Miles City ; and W.
Browne,
in the auriferous sands of Warm Springs near Helena. In Nevada, J. L. Beeler
mentioned
the occurrence of platinum in the silver ore at Austin ; and W. W. Attwood in the
gold
of the Comstock Lode. Platinum is associated with the copper-nickel- and cobalt-
sulphide
ores from Key West, and the Great Eastern Mines near Bunkerville, Lincoln Co.
According
to F. A. Hale, and A. Knopf, platinum is extracted with the copper and gold ores of
the
Boss Gold Mine, and the Oro Amigo Mine, near Goodsprings, Clark Co. In New York
State, P. Collier noted that platinum occurs at St. Lawrence near Plattsburgh ; and
Coyapas. Xho deposits are of no groat economic importance, and operations are
mainly
confined to native -washings. A. Damour, and E. I>. Levat reported that platinum is
In 1801, J. Vieira do Couta 3* reported that platinum occurs in Brazil in the sands
of
the Lages River, near Concei�?ao, Minas Graes ; and E. Hussak observed that the
platinum
is confined to the alluvium of the rivers having their rise on the eastern slope of
the Serra
do Espinhaco the Rio Xanque, Rio Itambe, Rio Peixe, Rio Antonio, and Rio Gyanhacs ;
were made in the first half of the last century on the Brazilian platinum by A. "F.
Gehlen,
A. ID. Lumb ; the metal also occurs in the beach sands on the coastal border of New
South
Wales and Queensland near Ballina, at Fvans Head, and at Currumbim. J. C. H.
Mingaye,
and J. B. Jaquet described the occurrence in the Broken Hill district at Little
Darling
and Mulga Springs Creek. Here the deposits resemble those of Sudbury, Canada. B.
Dunstan,
and L. K. Ball described the occurrences of platinum in Queensland, -where it
occurs
it\ the beach deposits between Southport and Currumbin ; in the Coopooroo and
Wairmaba
Creeks, near Tnnisfail ; in the Lucknow and Alma reefs of the Gympio goldfield ; in
the
auriferous, alluvial deposits of Brickfield Gully ; and at the head of the Don
River, Central
Queensland. A. D. Lumb, and A. M. Howitt described the occurrence of platinum in
Victoria, at the Walhalla Copper Mine, and in the Thompson River Copper Mino.
According
to B. Beck, and A. D. Lumb, platinum and irjdosrnium occur in Tasmania in the
Bald Hill district near Waratah ; in the placer deposits of the Nineteen Mile Creek
and its
tributaries�Linger-and-Die, MeGinty's and Barren Creeks ; in the rivers Heezleword,
Whytc. Castray, Huskisson, "Wilson, Boyes, and Savage, and at the Badger gold
diggings,
west of Savage River, and at the Salisbury goldfield, near Beaconsfield. l3latinum
has
been reported near BooJcoomatta in South A-itstralia ; and also in Papua in the
Lakekamu
district, and in the Yodda Valley.
Platinum is obtained in New Zealand from the Orepriki district in Southland. The
subject lias been discussed by Ii. A. Farquharson, J. A. Bond, L. do Launay, B.
Beck, and
A. D. Lumb. The presence of platinum has also been reported in quartz bodies near
the
Thames River, and in n pyritic body near the Taramekan River in West land ; in the
Taraka and George Rivers flowing into Awarua Bay ; in the beach sands of the east
coast
of Otago ; in the Clutha River ; in the Nelson gold district ; and in the Parapara
district.
The world's production of platinum 3 6 is about 9 tons per annum, and when
averaged per annum for the six years ending December 31, 1914, and expressed
in troy ounces, it was as follows :
Borneo
Russia, Colombia Australasia United States Sumatra Burma Canada
The Russian industry was so disorganized during the war and the revolution that
the output from the Urals dropped from 210,0CKJ troy ozs. in 1912 to 55CX) troy
ozs.
in 1921. Colombia and Canada accordingly increased their outputs, and South
Africa started producing the metal. The Uralian output is recovering its place,
for it again leads, with Colombia, and South Africa respectively, in the second
and. third, ranks. The "world's production approximated :
Australia
1015
43
31)19
162
1925
436
3 920
Canada
Colombia
475
18,749
69O
32,236
8,698
56,0OO
9,521
55,0OO
Russia
South Africa
United States
1 04,000
�
3,19O
39,425
10,460
94,8OO
4,325
92,70O
4,951
4,923
Total 219,933 72,513 164,259 167,50O
Minimum Maximum
Russia. 7,115,482 10,128,303
Colombia 700,000 735,000
Borneo 175,0OO 200,000
United States 10,000 12,000
Canada 9,000 10,000
Other Countries 9,000 10,000
metal. Nearly 50,0OO troy ozs. were so treated in the United States in 1927.
J. M. Hill estimated that the world's production up to June, 1917, totalled about
T>,000}000 troy ozs., and he supposed this to be distributed as follows :
Chemical and Physical apparatus 1,000,000
Kleetrioal plant 250,000
Catalyst . . . . . 500,000
Dental work . . . . 1,000,000
.Jewellery . . . . 1,000,000
Minor uses and hoarded motal . 1,250,000
The market value of platinum fluctuates from year to year, but there is a
general tendency for it to rise. An agreement amongst the dealers enables them
to control outputs, and to maintain
prices without individual com270
petition. In 188O, the price of 200 \T\
platinum was between 12.v. Gd. and 790
13*. per oz. troy; in 189O, it had T
risen to about 25s. ; and in 1900, 780
Z,730
-^= 720 �
335 ^L JJO
538 467
in this
7I
P. A. Wagner, H. B. Kosmann, 70
C. Li. Henning, etc. 60
r
�K
H 1
188O to KU 5.
troy. Osmium sells at about 24Os. per oz. troy ; rhodium, 225s. per oz. troy ; and
ruthenium, 195s. per oz. troy. The price of these three metals is negotiable, being
INORGANIC AND THEORETICAL CHEMISTRY
REFERENCES.
Platinous sands and gravels are washed in the same way as auriferous sands�
3. 23, 2�in order to concentrate the metal. The gold is removed from the residue
by treatment with mercury. Compact platinum does not amalgamate with
mercury in the cold. The residue contains the grains of platinum - alloyed with
the other platinum metals, iron, copper, silver, etc.� mixed with grains of
osmiridium, titaniferous iron, chromite, spinel, zircon, quartz, and may be some
gold amalgam. The washing is sometimes done by hand, sometimes by machines.
The process of washing, flotation, and. modifications which have been introduced
to suit particular cases were discussed by P. von Tunner,1 C. Schnabel, C.
Zcrenner,
H. !Louis, A. von Ernst, A. Laurent, K. P. Rothwell, F. W. Horton, I). T. Day and
R. H. Richards, J. Noad, L. Perret, etc.
The extraction of platinum from sulphide ores.�According to P. Wagner,2
the South African deposits in the Lydenburg, Potgietersrust, and Rustenburg
districts are mined by underground shafts. T. K. Prentice and R. Murdoch have
described the process used at Onverwacht. The platinum occurs in the metallic
state, but by simple gravity concentration the crushed dunite gave a very low grade
operations. At the Maandagshoek plant, good results were obtained with the
dunite ores by repeating the concentration of the ore along with an acid treatment.
centrates, 90 per cent, of the platinum metals as well as the nickel and copper
can be collected in a concentrate containing 6 to 8 ozs. of platinum metals per
ton.
With oxidized ores, there is only a 65 to 70 per cent, recovery of the platinum
metals,
and nearly all the copper and nickel is lost. As recommended by P. Trotzig, the
concentrate is therefore smelted to a nickel-iron-copper matte, and this is re-
smelted
to produce a higher grade matte containing approximately 65 ozs. of platinum
metals per ton, and 25-5 per cent, of nickel and 15-5 per cent, of copper. The
enriched matte is then roasted, and afterwards leached with sulphuric acid to
Blake Crusher I Stamp Mill I Trap for Metallics _ 4 O verflow Metallics 4 Cone
4 13all Tube M1Il Trap for Metal lies t t Me tallies-James and 4 Curvelinoar Tables
Overflow I Wilfley Tables {_ 'I 4 H eacls Middlings and ail infss H eads Tailings 4
James and Corduroy Tables i i I Amalgamation Barrel � 4 Hand-panning Tailings H ea<
1� ! i
'Platinum Amalgam �I I ! Retort Acid Treatment 4, I
Retort Sponge 4-4 Tailings Hand-panning and Crude coarse Platinum
dissolve the nickel, copper, and iron. These metals can be recovered by
precipitation
from the soln. The sludge remaining after the leaching process is smelted to
furnish a mass containing 60 per cent, of platinum metals. With about two-thirds
sulphide ore, and one-third oxidized ore, this process is said to recover 78 per
cent,
of the platinum metals ; and with sulphide ore alone, 85 per cent, of platinum
metals, and 80 per cent, of the nickel and copper in the ore. At Sudbury, where
in the extraction of nickel by the Canadian Copper Co., the platinum metals follow
the nickel matte, it was found that 56,405 tons of matte produced in 1916
contained 0-10 troy oz. per ton of platinum and 0-15 troy oz. per ton of palladium.
INORGANIC AND THEORETICAL. CHEMISTRY
Actually the company recovered 1093 troy ozs. of palladium and platinum, and
257 troy ozs. of other platinum metals�mainly rhodium and iridium.
earth. On cooling, the free metal crystallized in coarse crystals from the matte ;
and on exposure to the air, the matte disintegrated. The product was then
crushed, and the free metal crystals separated by a mechanical process such as a
magnetic separator or a shaking table, and then treated for the recovery of the
platinum metals. K. Wagenmann discussed the extraction of platinum from
sulphide ores.
The method employed in recovering platinum from the Sudbury copper-nickel
sulphide ores, described by D. McDonald, M. A. Mosher, R. IJ. Peek, and C. Langer
and S. and C Johnson, depends on whether the crude nickel is purified by
electrolysis
or by the Mond process. In the former process, the copper-nickel matte
is smelted with nitre cake and coke, and after a repetition of the process, the
bottom
matte, containing the platinum metals along with about 1 -5 per cent, of copper
and 72 per cent., is broken up, washed with water to remove sodium sulphide, and
with dil. acid to remove iron. The washed sulphide is then treated by one of the
two following methods :
(i) Roasted with 15 per cent, of sodium chloride between. 600� and 1200� ;
the copper chlorides are leached out ; and the soln. led over scrap copper to
cement
any platinum metals which may pass into soln. The insoluble " green nickel oxide *'
is then mixed with 20 per cent, of soda ash, and calcined over 1200� ; and washed
free from sodium salts when " black nickel oxide " with 77*8 per cent, of nickel
remains. This is roasted to remove the last traces of sulphur ; smelted with coal
in an open-hearth furnace, and cast into anodes�about 4 cwt. in weight. The
anodes are used for the electrolysis of a soln. of nickel sulphate which is
circulated
at a greater rate than the migration velocities of the iron and copper, so as to
hinder
the deposition of iron and copper on the cathode, where nickel is deposited. The
cathodes are* protected by canvas bags. The anode slimes are dried, melted to
metal, cast into anodes which are bagged, and again used in the electrolysis of
nickel sulphate in separate cells. The secondary .anode slimes so obtained contain
about 2 per cent, of platinum metals, and they are concentrated to 40 to 60 per
cent, platinum metals by a chemical process.
(ii) Instead of the chloridizing roast, the washed sulphide is finely-ground,
roasted, leached with dil. sulphuric acid, and the residual nickel oxide reduced by
with litharge and soda ash to form a lead bullion which is then cupelled, and
granulated. The granulations arc boiled in cone, sulphuric acid, the palladiferous
silver sulphate diluted and precipitated as chloride which is then reduced to
metal,
cast into anodes, and electrolyzed.
The insoluble material from the sulphuric acid treatment is united with the
rich concentrate from the 40 to 60 per cent, concentrate from the electrolytic
nickel
anode slimes, and digested with aqua regia. The gold is precipitated, cast into
anodes and electrolyzed ; the palladium is precipitated as palladous
diamminochloride
; and the platinum as ammonium chloroplatinate.
the electric smelting of the concentrates has not proved satisfactory because
platinum absorbs carbon from the carbon electrodes of the furnace as thus loses
most of the properties that make platinum of value in the arts.
The lead-platinum alloy can also be cupelled at a high temp. J. L. Byers studied
the effect of platinum on ordinary gold-assay beads. Rhodium and iridium remain
J. W. Mellor suggested extracting the platinum metals from dunite and norite
ores by blowing the dry, powdered ore through a deep bath of molten lead along
with the flue gases previously passed over heated coke. The platinum metals
are dissolved by the lead�any forms of platinum not attacked by the molten lead
accumulate at the bottom of the bath. When the lead shows signs of " stiffening "
by the dissolved metals, it is cupelled, or otherwise treated to recover the
platinum.
L. D. Hooper, and W. Gunther proposed treating the platiniferous ore with carbon
monoxide so as to convert the platinum metals into carbonyls, as in the analogous
process for nickel. The carbonyls are separated from the ore by volatilization, or
by washing with a suitable solvent�like carbon tetrachloride. The carbonyls
INORGANIC AND THEORETICAL CHEMISTRY
aqua regia.�In most of the wet processes which have tried for isolating platinum,
the native metal is first opened up by dissolving it in warm, cone, aqua regia.
This was done by IJ. N. Vauquclin,4 and W. H. Wollaston, who recommended a
preliminary treatment with a magnet to remove iron ore, and cold, dil. aqua regia
to extract gold, mercury, and iron. L. Gmelin also recommended a preliminary
treatment with cone, hydrochloric acid on a water-bath for several days.
JL. N. Vauquelin introduced the dried ore into a retort fitted with a receiver,
and added 4 times its weight of aqua regia made from a mixture of 2 parts of
hydrochloric acid, of sp. gr. 1*18 with 1 part of fuming nitric acid of sp. gr.
1*48.
Another more common mixture is made from 4 vols, of hydrochloric acid, sp. gr.
1-18 ; 1 vol. of nitric acid, sp. gr. 1-42 ; and 1 vol. of water. The object of the
retort
is to confine the poisonous fumes of osmic acid, but W. Lasch added that this
precaution is usually unnecessary, although A. Laugier observed that some osmic
acid may collect in the acid distillate. To avoid an undue loss of chlorine,
open vessels on a sand-bath with lO�15 times its weight of aqua regia are
necessary.
E. !Barruel recommended acting on the ore first with dil. and then with cone, aqua
regia. H. Dullo, and W. C. Heraeus observed that the process of dissolution is
hastened if the pressure of the air in the vessel is augmented. TI. V. Collet-
Uescotils,
and H. Hess also found that the operation is hastened if the ore be previously
fused
with 2 to 4 times its weight of zinc. The soln. contains platinum, palladium, gold,
iridium, rhodium, ruthenium, base metals, and silver chloride dissolved in the
acid liquor ; the osmium which is present escapes as volatile tetroxide during
the dissolution of the ore. The residue not dissolved by the aqua regia contains
the osmiridium with osmium and iridium as the principal constituents with smaller
proportions of rhodium, ruthenium, platinum, iron, and copper ; the residue also
contains sand, chromite, titanite, zircon, etc.
(i) The precipitation of the platinum by ammonium chloride.-�The platinum
metals have now to be recovered from the aqua regia soln. which contains platinum,
iridium, rhodium, palladium, iron, copper, and a small proportion of osmium
and ruthenium chlorides. H. St. C. Deville and H. Debray evaporated the liquid
to dryness, heated the product to redness, when the platinum salts are converted
to the metal and the salts of base metals are converted into oxides which can be
removed by levigation in water. The residual platinum metals are melted in
the oxy-hydrogen furnace. The usual process is to precipitate the platinum as
ammonium chloroplatinate, (NH4)2PtCl6, from the soln. by the addition of
ammonium chloride. In the process devised by W. H. Wollaston, the precipitation
of iridium is hindered in the presence of an excess of acid. The ammonium
chloroplatinate
so obtained was washed, dried, and strongly heated in order to convert
it into platinum sponge, which was afterwards compressed and hammered whilst
red-hot into bars or rolled into sheets. The first washings from the ammonium
chloroplatinate were evaporated to about one-twelfth the original volume to obtain
a
PLATINUM
mixed iridium and platinum salt ; and the second part of the wash-water was
evaporated to dryness, heated -to redness, and added to a fresh portion of ore.
Palladium, rhodium, ruthenium, osmium, and iridium are obtained from the
residues which do not dissolve in the aqua regia, and the mother-liquors after
precipitation.
whilst the rhodium and the greater part of the iridium remain in the nitrate. To
prevent the precipitation of iridium, J. J. Berzelius recommended adding some
nitric acid to the soln. H. V. Collet-Descotils, J. Cloud, L. N. Vauquelin, and
W. von Schneider discussed the process. F. Wyatt treated the aqua regia soln.
with ammonium chloride to precipitate the platinum ; then with sodium hydroxide
and mercuric cyanide to precipitate the palladium�the rhodium remains in soln.
The residue insoluble in aqua regia is heated in a current of air "when osmium is
converted into volatile osmium tetroxide, and rhodium oxide is deposited in the
hotter parts of the tube. The residue is heated with salt in a current of
chlorine when sodium chloroiridate is formed which can be dissolved in boiling
water.
(ii) The precipitation of the platinum by other reagents.�Instead of using
ammonium chloride as precipitant for the platinum, the precipitation by potassium
chloride was discussed by J. J. Berzelius, C. Bullman, and H. Pirngruber.
V. A. Jacquelain tried a mixed soln. of ammonium and potassium chlorides as
j>recipitant. J. W. Dobereiner treated the aqua soln. with lime-water in darkness,
but the process does not give a satisfactory separation of iridium and platinum.
It was discussed by C. Claus, W. von Schneider, and H. St. C. Deville and H.
Bebray.
After removing most of the platinum as ammonium chloroplatinate, the metals
remaining in soln. can be precipitated by iron or zinc, although iridium is reduced
very slowly. The washed material is treated with aqua regia (HCl 4 vols., and
HNO3 1 vol.) diluted with 4 vols, of water. Gold and palladium are quickly
dissolved, the platinum is dissolved a little more slowly, but very little iridium,
rhodium, and ruthenium pass into soln. The platinum can be precipitated from
the soln. as ammonium chloroplatinate ; the gold, if present, by ferrous sulphate ;
and the palladium can then be precipitated, as indicated above. These precipitates
contain more or less iridium, rhodium, and ruthenium. The remaining metals are
28 INORGANIC AND THEORETICAL CHEMISTRY
recovered by precipitation with zinc in a soln. from which most of the nitric
acid has been removed by evaporation.
L.. Duparc said that the process employed in some references for the recovery
of all the precious metals in crude platinum involves the following operations :
(i) The treatment of the mineral with aqua regia with the separation of the
insoluble
osmiridium and sand, etc.
(ii) The precipitation of the platinum as ammonium chloroplatmate and subsequent
calcination of the precipitate to produce platinum sponge.
(iii) The separation of iridium as ammonium chloroiridate from the mother-liquor by
as stated) with iron, or with zinc, to separate in the metallic state other metals
of the
platinum group (together with any small quantities of platinum not previously
separated)
which are deposited as a fine black precipitate called "' first blacks."
Drying and roasting of the " blacks " and treatment with dilute sulphuric acid to
remove
copper and other base metals.
(v) Treatment of the cleaned " blacks " with dilute aqua regia to obtain a solution
�S. 23, 4�and in the refining of silver by B. Mobius' electrolytic process�3. 22,
3.
A. I. Bochkoff discussed the subject.
(2) Opening up the native platinum with halogens.�H. Prasch 6 proposed to
extract platinum from sands with a very small proportion of platinum by treating
them with chlorine-water which dissolves the metal. K. L. Graham developed a
chlorination process for the extraction of platinum from flotation concentrates of
PLATINUM
sulphide ores. The dried ore is roasted for 6 hrs. at a dull red-heat to eliminate
sulphur, and oxidize thoroughly all the base metals. The product is then mixed
with salt and kept at 500� to 600� for about 5 hrs., and at the same time chlorine
is passed over the surface of the heated materials so as to convert the metals of
the
platinum group, copper, and nickel into soluble chlorides. The product is treated
with acidified water. The soln. is agitated with powdered limestone to precipitate
the copper as carbonate. Only a small proportion of platinum is removed by this
process, and it can be recovered from the copper by subsequent smelting and
electrolysis. The platinum metals are precipitated as a black powder by agitation
with zinc dust. The dried powder is roasted at a red-heat for a few minutes and
contains over 70 per cent, of the metals of the platinum group. The residual soln.
is treated with sodium hydroxide or bleaching powder. The residue left after the
chlorination treatment is treated with cyanide to extract the gold since it is not
attacked by the chlorination process owing to the temp, exceeding the dissociation
temp, of gold chloride ; at the same time, 4 to 5 per cent, of platinum metals are
also recovered. About 90 per cent, of the platinum metals and gold are extracted
from the concentrate by this treatment. The subject was discussed by T. TJ. Kapp,
and Tt. A. Cooper and F. W. Watson.
subjected the finely-powdered ore to the action of steam under pressure in the
presence of silicic or boric acid and a soln. of chloride of sodium, calcium, or
magnesium. If the ore is not sufficiently silicious, silica or boric acid is added
to it. For such platinum concentrates, sodium chloride and nitrate are employed,
and the nascent chlorine produced is particularly active in converting the metals
into a soluble form. If the platinum ore is poor, it should be first treated with a
soln. of potassium ferrocyanide through which air is blown, and the product is
afterwards treated under pressure in an autoclave. W. Gunther exposed the ore to
carbonyl chloride under press, so as to convert the platinum into a carbonyl
derivative
of the chloride, and then leached the ore with a suitable solvent.
The extraction of platinum from residues insoluble in aqua regia.�H. St. C.
Deville and H. Debray 8 recommended fusing the residues rich in platinum with
enough lead oxide to make an alloy of lead with 25 per cent, of platinum, along
with sand, and carbon ; with residues with but a small proportion of platinum, in
addition to the lead oxide, some glass, lime, and fluorspar were also employed.
The resulting alloy was then fused with galena, sand, and an iron silicate sand to
isolate the platinum. W. Savelsberg discussed the subject. For F. Wyatt's
observations, vide supra. R. Gilchrist melted the ore -with lead ; B. G. KarpofF,
with bismuth ; and E. Leidie and Li. Quennessen, with zinc.
A. Guyard fused the platiniferous residue, insoluble in aqua regia, with 3 times
its weight of a mixture of equal parts of sodium hydroxide and nitrate, at a bright
red-heat, in a thick wrought-iron crucible, for about an hour. The mixture should
be well stirred with an iron spoon during the last 20 minutes, and finally poured
into an ingot mould. The product is boiled with water, and the soln. contains
sodium
osmate. The washed residue is treated with aqua regia, when osmiridium remains
undissolved. The soln. contains iron, copper, lead, iridium, rhodium, ruthenium,
and platinum. The excess of aqua regia is removed by evaporation, adding some
water and hydrochloric acid every now and again to remove the nitrogen oxides.
The soln. is then acidified with hydrochloric acid and treated with hydrogen
sulphide,
at a temp, of 70�, for about 15 hrs. If the mother-liquor is coloured only a pale
yellow by the dissolved iridium sulphide, it is filtered, and the precipitate is
treated
with cone, sulphuric acid which converts the sulphur, and the sulphides of copper
and lead into sulphur dioxide and soluble sulphates. The mixture is digested with
INORGANIC AND THEORETICAL CHEMISTRY
3O
water, filtered, and washed until the washings are free from copper and iron.
Nitric acid is first added to the precipitated sulphides of the platinum metals,
and
then hydrochloric acid. The soln. is boiled, and the lead chloride filtered from
the
cold liquid- The soln. is then treated with ammonium chloride in the usual way.
E. Wichers and co-workers observed that the residue contains mainly rhodium,
iridium, ruthenium, and osmiridium, and can be treated by one of the following
processes : (i) If rhodium is predominant, the dried residue can be intimately
mixed with 2*5 times its weight of sodium chloride, and heated to dull redness in
a current of chlorine. This converts rhodium into a soluble sodium rhodium
chloride, and some of the iridium is likewise converted into a soluble double
chloride,
but iridium is less readily attacked than rhodium, (ii) If iridium is predominant,
the residue is fused at 600� to 700� with 3 parts of sodium hydroxide and 1 part
of sodium dioxide in a silver, nickel, or iron dish. Some iridium forms a basic
iridate, but most remains insoluble in water, but soluble in hot, cone,
hydrochloric
acid. The ruthenium remains in the aq. soln. of the fused mass. Rhodium is
not rapidly attacked by the alkali fusion, and that treatment may be alternated
with the sodium chloride and chlorine method until all the insoluble material is
converted into a soluble form. The mixed soln. of iridium, ruthenium, and osmium
can be neutralized with hydrochloric or sulphuric acid and boiled with a little
alcohol, and the small amount of metal remaining in soln. can be recovered by the
hydrochloric acid-zinc reduction.
When the mixed iridium and rhodium chlorides contain more iridium than
rhodium, the soln. is treated with chlorine to oxidize tervalent iridium to the
quadrivalent stage, and concentrated by evaporation until over 50 grms. of the
two metals are present per litre. Enough ammonium chloride is added to precipitate
ammonium chloroiridate, which may also contain rhodium. A large excess of
ammonium chloride subsequently interferes with the precipitation of rhodium.
The iridium still present in the mother-liquor can be recovered by evaporating the
soln. to dryness, to eliminate an excess of acid which would interfere with the
subsequent separation of rhodium. The residue is extracted with water, and
filtered from the impure ammonium chloroiridate. The filtrate containing not
more than 50 grms. of rhodium per litre is boiled and treated with sodium nitrite.
This reagent first neutralizes the acid present and reacts with ammonium chloride
to form ammonium nitrite, which decomposes in the hot solution. Rhodium and
the other platinum metals, as well as certain base metals, are converted to soluble
double nitrites, while other base metals, notably iron and tin, are precipitated as
hydroxides. Heating is continued and more sodium nitrite added until the colour
of the solution becomes yellow or light brown. The precipitate is filtered oft* and
treated for the recovery of the small amounts of platinum metals which it may
contain. Ammonium chloride is added to the well-cooled filtrate to precipitate
ammonium rhodium nitrite. The granular, white or yellowish salt is separated
by filtration, washed with water and dried, or dissolved in hydrochloric acid for
further purification. It is not suitable for direct ignition to sponge. Residual
metals are recovered from the filtrate by means of hydrogen sulphide.
dry sodium carbonate (4 parts), and powdered glass (2 parts), and added in small
portions
at a time to a red-hot crucible. The button of lead which is formed collects the
platinum
metals and gold. The lead alloy is dissolved in hot aqua regia, and the soln. is
heated on
a sand-bath to drive off the nitric acid. The cold soln. is filtered and the
precipitated lead
and silver are washed with water. The gold is precipitated by ferrous chloride or
sulphate ;
PLATINUM
and the filtrate is treated with iron to precipitate the platinum. The precipitate
is boiled
with nitric acid, dissolved in aqua regia, and the platinum precipitated by
ammonium
E. Friwoznik used zinc as a collector for the precious metals. Here the gold
containing platinum is melted with about 3 times its weight of zinc, and the
granulated alloy treated with sulphuric acid to dissolve out the zinc. The washed
product is then treated with nitric acid of sp. gr. 1-199 to extract the silver,
and
again washed. The residual gold-platinum alloy is dissolved in aqua regia, first
at ordinary temp., and afterwards warmed. Platinum alone remains undissolved.
The soln. containing gold with a small proportion of platinum is mixed with
hydrochloric acid, and evaporated in a dish to drive off nitrous fumes. The
product is dissolved in water, and the platinum precipitated with ammonium
chloride ; and the nitrate is treated with ferrous sulphate to precipitate gold.
The separation of platinum and gold has been also discussed by J. P. J. d'Arcet,
F. Mylius and R. Dietz gave a plan in -which the mixed chlorides are boiled in a
distilling flask 'with dil. nitric acid and the distillate collected in a soln. of
sodium
hydroxide. If osmium is present, the liquid becomes yellow since osmium tetroxide
distils over -with the steam. The residual liquid is shaken with ether to extract
any gold chloride which collects in the ethereal layer. The liquid is then boiled
with ammonium acetate and formic acid for several hours in a flask fitted with a
reflux condenser, and the black precipitate is washed, dried, and heated to redness
in hydrogen. The residue is washed with hydrochloric acid, mixed with sodium
chloride, and ignited in chlorine. The product is dissolved in water and treated
withruthenfiltrates
ammoniumium, whilst
to right) :
chloride,
palladium
a precipitate contains
and rhodium remain
the
in s
platinum,
oln. (precip
iridium,
itates to
and
left,
Treat soln. with NH4 Cl
1 ...
Add hydroxylamine to the hot aq. soln. Jilvaporate to dryness with excess NH4Cl ;
of precipitate and then NH4Cl extract with warm NH4Cl and cool
J. _ � I
Platinum Evaporate ; reduce dry Rhodium Palladium
residue in H 2 ; fuse with
KOH -h KNO3 ; extract
with water
4, I
Iridium Ruthenium
Plans were also given by N". A. Tananaeff and K. A. Dolgoff, S. IT. Schemtschuschny
present as chlorides in dil. hydrochloric acid (7 to 8 c.c. HCl per 1OO c.c. of
soln.) :
4r I
Palladium, as Add excess 2 per cent, alcoholic soln. ot-furilPd(
C4H7O8Na)2 dioxime ; add alcohol IO per cent, of total
volume ; boil ; and filter
Rhodium, as
K8Rh(ISTO2).
Ruthenium, as
Ru 2O s.3HjO
Reject
Osmium Reject
For confirmatory tests of the different metals vide the analytical reactions of
the different metals, and Table I. In the older process for the recognition of the
platinum metals, hydrogen sulphide is passed into a hot, acidified soln. of the
Colour
Amm. sulphide .
Kthyl mercnptan
(1 : 100).
Warm NH4OH .
Alkali lye .
Soln. KI (1 : 1OtK))
Soln. HgCJy2
Soln. N2H4-HCl
(1 : IOOO)
Soln. dimethylglyoxime
HCl aoln. cobaltic
luteoohlorido
yellow
No pp. No pp. Brown pp.
Yellow pp.
decoloriza-tion
tion
in excess
Violet cryst. Red cryst. Red cryst.
pp. pp.
Nil Nil Dark pp.
Nil Nil
Reddish
colour
Osmium
Oold-yellow
No pp.
Black
Dark brown
pp.; insoluble]
in excess
Nf) change
Yellowish
brown pp.
Red pp.
Brownishred
pp.
Brown
cryst. pp.
Nil
Nil
Nil
Black
Nil
Nil
Nil
METALS
Iridium Platinum
No. pp.
Slow
deeolorization
Black pp. Yellow pp.
Brownish-Yellow pp.
red pp.
Nil Nil
Decoloriza-Intense
tion yellow
Yellow Nil
Nil Nil
Brownish Nil
colour
acid to remove tin ; boil the residue with nitric and tartaric acids to
remove antimony (filtered solids to left, filtrates to right) :
Fuse insoluble part with KO H -f-KlClO3 ; After the removal of Sb, As, and Sn heat
the
extract with water ; filter residue to redness ; digest with dil. aqua regia
The methods available for the determination of the platinum metals when
associated with one another in ore, or in alloy, are somewhat complicated. The
pioneer work was done by W. H. Wollaston, L. N. Vauquelin, A. Laugier, L�. R. von
Fellenberg, H. Hess, H. V. Collet-Descotils, F. Dobereiner and F. Weiss, J. Persoz,
Fuse residue with borax and silver ; Boil to remove HNO a ; add Cl2-water ;
digest button of metal with nitric evaporate at low temp, to dryness ;
acid. There remains undissolved digest with water; add excess NH4Cl
i I
Osmiridium [ ]
Ignite and weigh as Pt 4- Ir ; Boil with dime thy lglyoxime
digest with aqua regia I
j }
INORGANIC AND THEORETICAL CHEMISTRY
Platinum
Zn-f HCl
�r
Palladium
Iron
Rhodium
4-4Ruthenium
Osmium
Insoluble contains Add NH4Cl to Digest pre- Evaporate soln. to dryness
Rh + Ir. fuse with precipitate trace cipitate with with HNO3; ignite; wash
KHSO4 ; extract of Pd and l3t. HCl out iron and nickel with
with -water and dil. Ignite HCl ; ignite residue for
H8SO4 4-Au+ Rh
Platinum
Insoluble contains Ir and Boil with Na2CO8 trace Rh. Dissolve in aqua acidify with
HCl
regia ; evaporate to drydry,
and ignite
ness at 120� ; dissolve in The precipitate The soln.
water ; precipitate with of K 2l*dCl4 con- contains
Mg ; ignite ; extract -with tains 4dil.
H8SO4, then with dil. 4- Copper
�ir
Iridium
Rhodium Gold
PLATINUM
sodium dioxide ; the cold cake can be dissolved in hydrochloric acid, and the two
soln. mixed. The following metals may be present : ruthenium, rhodium,
palladium, osmium, iridium, and platinum, as well as gold, copper, and iron along
Acidify soln. Add NaNO3 Add HCl; the ruthenium forms RuCl3.
and saturate with NH4Cl Alcoholic soda lye reduces the osmium
to form sodium osmate
with NH4Cl
I 4, I
Iridium Rhodium Platinum Palladium
F. Mylius and A. Mazzucchelli obtained good results in test analyses with the
following scheme (precipitation to left, soln. to right) :
Saturate soln. with NH4Cl
I
Ir
Iridium
4 ~~ "I I I 4-4r
Iron,
Iridium Evaporate with NH4Cl Extract with ether Blue filtrate Rhodium
Zinc,
M 1 I � 4-Nickel,
{, J Gold Copper Cobalt
Platinum Add HgCy8 for
Palladium
4:0 INORGANIC AND THEORETICAL, CHEMISTRY
In order to obtain platinum of a higher degree of purity, J. J. Berzelius
*neutralized
a soln. of platinum in aqua regia by means of lime, or ammonia,
saturated the liquid with hydrogen sulphide, and allowed it to stand for a few
days in a closed flask. The liquid was filtered from the osmium sulphide, and then
treated with potassium chloride. The precipitate was washed with a soln. of
potassium chloride until the washings were free from iron chloride. The dry
precipitate was heated with twice its weight of potassium carbonate until it began
to fuse. The cold product was washed with water, and then with dil. hydrochloric
acid. The mixture of platinum and iridium oxide was collected on a filter-paper,
washed, and dried. The greater part of the platinum was extracted from the
mixture by warm, dil. aqua regia, and the remainder of the platinum was taken
up with cone, aqua regia, containing a little sodium chloride to prevent the
reduction
of the platinic chloride during the evaporation. The soln. was treated with
potassium chloride, and the dry precipitate so obtained was gently heated with
dry sodium carbonate until the mass blackened and began to fuse. The product
containing metallic platinum and the oxides of rhodium and iridium, was washed
first with water, and then with dil. hydrochloric acid. The platinum was extracted
from the product by aqua regia, and precipitated from the soln. by ammonium
chloride.
E. Wichers and co-workers have pointed out that the repeated precipitation
of ammonium chloroplatinate is the most important method of purifying platinum.
The salt is relatively insoluble. It may be readily precipitated in a form that is
easily filtered and washed, and it may be directly converted to metallic platinum
by ignition. Any desired degree of purity may be attained by a sufficient number
of reprecipitations. All the platinum metals except rhodium can exist in the
quadrivalent state and in this condition form relatively insoluble salts analogous
to ammonium chloroplatinate and isomorphous with it. However, because of the
usual course of previous separations, osmium and ruthenium are seldom present
with platinum except in very small amounts. Palladium is readily reduced from
the quadrivalent state to the bivalent state by heating the solution. It is
probably
true that iridium also is reduced in part, at least, from the quadrivalent state to
the trivalent state by heating, especially if the temperature reached 140� to 150�
C.
The double chlorides of bivalent palladium and trivalent iridium with ammonium
chloride are much more soluble than ammonium chloroplatinate and not isomorphous
with it. Rhodium, iridium, and palladium display remarkable persistence
in contaminating the platinum salt. Platinum containing 0-7 per cent, of rhodium
was found to contain 0-2 per cent, after the first precipitation and 0*04 per cent,
present, may persist for a few precipitations because of the solubility of silver
chloride in cone. soln. of chlorides. E. Wieners and co-workers recommend the
following procedure :
Crude spongy platinum contained in a porcelain dish with a cover glass to prevent
loss by the spray is dissolved in aqua regia�3OO to 35 vols, of hydrochloric acid
of sp. gr.
1-18, 75 to 1OO vols, of water, and 6O to 7O vols, of nitric acid of sp. gr. 1-42.
The temp.
is raised rather slowly to avoid too vigorous a reaction. In some cases more aqua
regia
is required for complete solution. The soln. is evaporated fairly rapidly without
previous
filtration until the temp, reaches 140� to 150� unless the residue becomes pasty
before this temp, is attained, in which case the evaporation must be stopped to
avoid
local overheating. If no large amount of base metal or alkali impurities were
present in
the sponge, the soln. will be fluid at 150�. A small amount of water is then added,
which
causes a lively boiling and the evolution of nitrous fumes. In this process any
nitrous
compounds of platinum are decomposed. L. Duparc and M. N. Tikonowiteh state that
if the nitrous compounds formed during the treatment -with aqua regia are not
decomposed,
a considerable amount of platinum will escape precipitation with ammonium chloride.
More -water is added to cool the solution below 100�. After digesting a few minutes
some
hydrochloric acid is added and"the evaporation repeated. This whole process can be
repeated three or four times, insuring the elimination of nitrous compounds and
presumably
promoting the reduction of quadrivalent iridium to the trivalent state. After
the last evaporation �water only is added and the soln. diluted so as to contain
not less than
50 grms. and not more than IOO grms. of platinum in 1 litre. It is set aside to
allow settling
of insoluble matter and then decanted or filtered from any residue. The residue may
E. Wichers and co-workers also found that good work can be done with alkaline
reagents. The reaction is slow in the cold, and to hasten the process, the soln.
should be boiled for a few minutes. A reaction between the chloroplatinate and
the alkaline soln. tends to make the soln. sufficiently acidic to hinder the
complete
precipitation of impurities, or to redissolve some of the precipitate. They found
that the presence of a bromate retards the hydrolysis of the chloroplatinate. The
base metals are readily precipitated in the alkaline soln. ; palladium, rhodium,
and
iridium appear to precipitate very nearly completely ; osmium and ruthenium
probably precipitate, except for the portion of the ruthenium that is present as
nitrosochloride and the osmium and ruthenium that may be oxidized to the
tetroxides by the action of the bromate, if the soln. at any time becomes acidic
enough to liberate bromine ; silver is likely to remain in the soln. as dissolved
silver chloride and gold is divided between the precipitate and the soln. However,
gold may be eliminated by adding sufficient ferrous sulphate to precipitate it as
metal
before the addition of sodium hydrocarbonate. The iron from this reagent, of
course, is precipitated with the other impurities and may in fact be helpful in
collecting small amounts of other precipitated compounds. Some platinum�
rarely over 5 per cent.�"will appear in the precipitate. E. Wichers and co-workers,
42
The soln. of impure platinum in aqua regia is evaporated once or twice to eliminate
nitric acid. Enough sodium chloride is added to form sodium chloroplatmate and
similar
salts of the other metals. The soln. is evaporated and the residue thoroughly dried
to
remove as much as possible of the hydrochloric acid. The residue is dissolved in
water
and the soln. diluted so as to contain about 50 grms. of platinum per litre. If
gold is thought
to be present, ferrous sulphate soln. is added in small portions until no further
precipitation
of gold occurs. The soln. is decanted from the residue and heated nearly to
boiling, after
which sodium hydrocarbon ate is added in small portions to neutralize most of the
remaining
hydrochloric acid. When the soln. is nearly neutral, as may be judged by
diminishing
effervescence, 10 to 12 grms. of sodium bromate for each 1OO grms. of platinum are
added,
only a little being added at first to determine whether the soln. is nearly enough
neutral
not to decompose the bromate. If bromine is evolved, more sodium hydrocarbonate is
added until the addition of a little sodium bromate causes no further evolution of
bromine.
The remaining sodium bromate is then added and the addition of small portions of
sodium
hydrocarbonate continued until the soln. just turns sensitive litmus paper blue.
The
soln. is now brought rapidly to boiling and again tested with litmus paper. If it
is acid
a little more sodium hydrocarbonate is added and the soln. is then boiled for 3 to
5 minutes.
It is finally tested once more, and if not alkaline another small portion of sodium
hydrocarbonate
is added and the boiling continued for a minute* The soln. is then cooled rapidly
in running water. After the precipitate settles, the supernatant soln. is siphoned
off
and passed through a filter to collect the suspended precipitate. If observations
or tests
indicate that the reaction has not been successful, the soln. is acidified with
hydrochloric
acid, evaporated down and the whole process repeated, after adding a little
aluminium
chloride. The aluminium salt is added so as to produce a precipitate which will
collect
smaller amounts of precipitated compounds. This is also done when practically pure
platinum is being treated. If the separation of impurities appears to have been
successful,
the soln. is digested -with hydrochloric acid to decompose the bromate and the
platinum
is preoi pita ted with ammonium chloride. The ammonium chloroplatinato precipitated
from this soln. will carry down considerable sodium chloride, most of which may be
removed by leacliing with water after the salt has been ignited to sponge.
P. Bergsoe based a process for preparing platinum free from iridium on the
conversion of the platinum in soln. into barium platinocyanide, and purifying the
salt by re-crystallization�ICX) parts of boiling water dissolve 25 to 33 parts of
the salt, and 100 parts of cold water, 3*33 parts of salt.
An aqua regia soln. of 40 grms. of platinum containing traces of iridium, mixed
with
another 0*25 grm. of iridium, was treated with the theoretical proportion of barium
hydroxide, and with hydrogen cyanide. The warm mixture was treated with sulphurous
acid until it became colourless, and after removing the precipitated barium
sulphate.
PLATINUM
by filtration of the hot soln., it was allowed to cool to allow the barium
platinocyanide to
crystallize out. The latter salt is almost insoluble in a soln. of barium chloride.
The
barium platinocyanide was re-crystallized 3 times from water, and the mother-
liquors
evaporated to about one-third or one-fourth their vol. and the further separations
mixed
with the main product. The yield was 75 per cent, of platinum free from iridium.
The
mother-liquors contained 7*015 grms. of platinum, and 0-281 grm. of iridium. It is
believed that this method of purification gives a better product than the sodium
chloroplatinate
process. Traces of osmium, ruthenium, and rhodium follow the iridium, but
palladium, which forms a double cyanide, isomorphous -with that of platinum, cannot
be
removed by this treatment, but it can be expeditiously removed by other processes�
vide supra.
A number of processes for separating iridium and platinum are based on the
reduction of iridium tetrachloride to the trichloride by reducing agents which do
not affect the platinum tetrachloride. This prevents the formation of a precipitate
of the double salt of iridium when the soln. is treated with ammonium or potassium
chloride. Thus, C. Krug reduced the iridium salt with ferric chloride.
The metal was dissolved in aqua regia ; the nitrogen oxides were removed as
before ;
ammonium chloride was added to the soln. ; the impure ammonium chloroplatinate was
dissolved in hot water ; ferrous chloride -was added to the boiling soln., until it
no longer
became paler ; and on cooling iridium-free ammonium chloroplatinate separated out,
but the lower chloride of iridium remained in soln. The calcined precipitate was
again
dissolved in aqua regia as before, and the soln. treated with sodium chloride to
precipitate
sodium chloroplatinate. The precipitate -was dissolved in alcohol, and the soln.
filtered
from the rhodium, palladium, and ruthenium. The soln. was evaporated to dryness,
and
the product heated in an atm. of coal gas. The residue was -washed with water,
dried,
and fused on wood charcoal in the oxy-hydrogen flame.
quite free from other metals. After cooling and separation of this salt, the liquid
is again heated and further quantities of nitrite are added. Suddenly, and
especially
if the liquid is stirred, the crystalline double rhodium compound separates,
carrying
with it lead, bismuth, and tin, and small quantities of copper. If the liquid is
allowed to cool, the separation of the rhodium becomes complete, provided that a
moderately large quantity of potassium chloride is present. Should iron and copper
be present, the addition of the nitrite is continued until the liquid becomes
alkaline,
and, on boiling, the iron and copper are precipitated, whilst platinum and
palladium
remain in soln.
M. C. Lea reduced the iridium salt with oxalic acid. The mixed chloroplatinate
and chloroiridate were dissolved in just enough hot water for the purpose, and the
soln. was treated with crystals of oxalic acid until no more bubbling occurred ; it
was boiled for 2 or 3 minutes, half saturated -with ammonium chloride, and cooled.
The platinum was precipitated as chloroplatinate, and iridium trichloride remained
in soln. M. Vezes separated the platinum by precipitation as potassium platinous
oxalato-dinitrite, K2[Pt(C204)(N02)2].H20. According to C. Claus, the mixed
ammonium chloroplatinate and chloroiridate can be treated with a little water,
and then with an aq. soln. of hydrogen sulphide. Sulphur, and platinum sulphide
are precipitated, but iridium sulphide is precipitated only when the hydrogen
sulphide is in great excess. The precipitate of platinum sulphide also contains
some ammonium chloroplatinate and it yields platinum when calcined. The
INORGANIC AND THEORETICAL CHEMISTRY
C. Claus said that here the potassium cyanide reduces the iridium tetrachloride
far more rapidly than is the case with the platinum salt.
According to C. Claus, the mixed soln. of iridium and platinum can be treated
with 1 part of sulphuric acid to 3 parts of platinum, and evaporated to dryness.
The yellowish-brown mass can be digested with water, filtered, and treated with
ammonium chloride to precipitate the platinum. Most of the iridium is transformed
into sulphate by this treatment, and only a small proportion of the platinum
is affected, the sulphates are not precipitated by the ammonium chloride. C.
Birnbaum
observed that a mixture of the hydroxides of iridium and platinum can be
dissolved in a soln. of potassium sulphite or carbonate," saturated with sulphur
dioxide, and boiled with the addition of water until all the sulphur dioxide is
expelled, the whole of the iridium is precipitated as sulphite, Ir(S03)2 ; the
filtrate
contains the platinum which is recovered by evaporation to dryness, and roasting
the product.
J. IT. Gladstone and A. Tribe treated a soln. of the platinum salt with alkali
formate, washed the precipitated metal with cone, nitric acid and then with water.
T. WiIm, however, showed that the base metals cannot be removed from metals of
the platinum group by reducing agents, since some of the base metals always
accompanies the platinum metals�contact action, surface adsorption, or chemical
action.
The Reparation of platinum from copper was discussed by W. H. Swanger and
F. Mylius and F. Forster added that platinum prepared by the aqua regia process
PLATINUM 45
is not likely to contain that element ; and in samples of commercial " platinum,"
and '* pure " platinum, they found, respectively :
Pt Ir Rh Pd Ru Pe Cu
96-9O 2-56 0-20 Trace 0-02 0-20 99-58
99-28 0-32 O-13 � 0-04 0-06 007�99-9O
H. St. C. Deville and H. Debray analyzed a number of samples and found : platinum,
90-50 to 3-30 per cent. ; iridium, 2-10 to 7-90 per cent. ; and rhodium, 0-30 to 3-
30
per cent. O. J. Broch and co-workers found that purified samples contained :
99*890 to 99-892 per cent., platinum ; 0-065 to 0-070, rhodium ; and 0-023 to 0-
029,
iridium. K. Kraut noted the contamination of platinum with barium ; A. Vogei
and co-workers, with chromium ; E. Reichardt, with silicon; A. Villiers and
F. Borg, with zinc; H. N. Warren, with thallium ; A. Classen, with iron ; and
G. C. Hoffmann, and E. Hussak, with copper. W. N. Hartley noted the presence
of carbon and phosphorus in a specimen of brittle platinum ; E. Reichardt found
silicon in another sample of brittle platinum. T. WiIm said that platinum crucibles
become brittle with use if rhodium and palladium are present, because those Jmetals
are attacked by the carbon of the coal-gas name. H. Moser discussed the subject.
O. ZvjaginstseiT and co-workers did not find dvi-manganese in native platinum.
REFERENCES .
of a dull grey, soft, �pongy powder. To convert this product into malleable
platinum the metal must be either fused or welded together. The metal itself
fuses at so high a temp, that the manufacture of vessels, or of sheet platinum from
ingots cast from the molten metal was impracticable. At first, that is, towards
the end of the eighteenth century, attempts were made to reduce the fusibility of
the metal by alloying it with a volatile metal, thus F. C Achard,1 and M. Jeannety
The plates cast from these alloys were heated to drive off the volatile element,
and the resulting product hammered together so as to close the pores. The results
is also a narrow groove to facilitate the pouring of the molten metal into ingots
moulds when the furnace "is tilted. It is said that a kilogram of platinum requires
for fusion 6O to 100 litres of oxygen�dependent on the purity of the metal. The
hydrogen is now usually replaced by coal gas, and improved burners are employed
The subject was discussed by J. B. Dumas, E. Matthey, and H. Violette. Furnaces
PLATINUM
H. Pellet added that purified hydrogen, freed from all traces of arsenic, does
not reduce platinum salts in aq. soln. The slow reduction of platinum salts by
hydr iodic acid was studied by R. Silliman ; by potassium, iodide, by H. Rose, and
J. L. Lassaigne ; by sulphur, hydrogen sulphide, and alkaline sulphides, by Mrs.
Fulhame
; and by lead or copper sulphide, by W. Skey. N. W. Fischer found that
platinum salts are not reduced by selenium, but that they are reduced by tellurium.
C. A. Tibbals found that platinum salts are reduced by sodium telluride ; V. Meyer
and J. Locher, and W. C. Lossen, by hydroxylamine and hydrogen ; A. Gutbier
and G. Hofmeier, by hydrazine hydrate ; N. Tarugi, by hydrazine sulphate in
alkaline
soln., but, according to P. Jannasch and O. von Mayr, not in acidic soln. ; Mrs.
Fulhame,
and R. Bottger, by phosphorus ; Mrs. Fulhame, by phosphine ; N. W. Fischer,
by arsenic, antimony, and bismuth ; T. Polleck, by sodium dioxide and a silver
salt ; D. Vitali, by silver oxide ; and C. Claus, W. Hempel, W. Skey, and L.
Kessler,
t>yferrous sulphate. P. Pascal added that unlike soln. of salts of gold and silver,
platinum salts are not reduced in the cold by ferrous pyrophosphate. Many
other " reducing " salts precipitate metallic platinum�vid e infra, colloidal
platinum.
Mrs. Fulhame, F. W. O. de Coninck, and W. Heintz noted that soln. of platinum
salts are reduced by animal charcoal; and H. Fresenius and P. H. M. P. Brinton,
by over 8O per cent, alcohol. The reducing action of alcohol was studied by
Gr. Vulpius ; of glycerol, by F. Bullnheimer ; of ether, by C. W. G. Kastner ; of
formaldehyde, by N. Awerkijeff, A. Bach, F. Jean and A. Trillat, S. Rothenfusser,
and R. E. Liesegang ; of sodium formate, by J. J. Berzelius, J. W. Dobereiner,
E Dreyfuss. The reduction does not occur, according to R. Brandes, with alkali
oxalates, citrates, or benzoates. The reducing action of potassium ferrous oxalate
was studied by J. M. Eder ; of alkali tartrates, by R. Phillips ; of orgamc acids,
by P. Cazeneuve ; of benzene, petroleum, and naphtha, by G. Gore ; of tertiary
amines, by Li. TschugaefE ; and of sugars, by D. J. Stern and J. Friinkel ; and of
glycerol, by R. Zdrawkowitsch.
B. Geddes discussed the term Platimoor. E. Davy said that the platinum black
which he prepared soiled any surface on which it was rubbed, and J. von Liebig
added that, by pressure, it acquired a white colour, and a metallic lustre.
Platinum
black is a powerful catalytic agent. E. Davy at first thought it to be a nitrite
of platinum, but J. von Liebig showed that platinum black is platinum in a fine
state of subdivision. The metal, however, is more or less contaminated by
impurities
absorbed or adsorbed from the system in which it is prepared. Platinum
black was obtained by R. Blondlot by passing an electric current in nitrogen for
3 hrs. between two discs, one of copper and one of platinum, 3 to 4 mm. apart, and
heated to bright redness. The black powder on the platinum disc was digested in
hot nitric acid to remove the copper, and a residue of platinum black remained.
When alloys of platinum with zinc are treated "with acids which attack zinc and not
grains of the powder, and G. von Hevesy and T. Somiya, the preparation of
platinum-black with a little lead ; the lattice measurements show that the lead is
not in solid soln., and measurements of the grain-size, and of the electrolytic
polari
PLATINUM
zation "were made. O. Loew recommended tlie following method for preparing
platinum black of great catalytic activity :
An �q. soln. (50 to 6O c.c.) of platinic chloride (50 grms.) is mixed, with 4O to
45 per
cent, of formaldehyde solution (7O c.c.)* the mixture cooled well, and then sodium
hvdroxide (5O grms.) dissolved in water (5O grms.) gradually added ; after keeping
for
] 2 hrs. the soln. is filtered. A yellow liquid, from which a small quantity of
platinum is
deposited on boiling, first passes through the filter, but as soon as most of the
salts have
been washed out of the residue, the filtrate assumes a deep black colour. The
process is
interrupted at this stage for several hrs. because the residue soon absorbs oxygon,
the temp,
rising to 36� to 40�, and the washings then pass through colourless. As soon as
oxidation
is complete, the residue is washed until completely free from sodium chloride,
pressed,
and dried over sulphuric acid.
that a fresh surface is exposed. The grains of platinum are estimated to be more
than 15 A.�or 4 unit cell cubes�and less than 30 A.�or 8 unit cell cubes�in
thickness. Platinized pumice is obtained by the same process as that employed
for platinized asbestos. J. Stenhouse, and M. Figuier likewise prepared platinized
carbon. E. V. Alexeevsky and I. D. Makaroff soaked the charcoal, previously
ignited at 950�, in a soln. of chloroplatinic acid, dried the product at 100�, and
reduced it at 120� to 150� with electrolytic hydrogen containing formaldehyde.
VOL. XVI. E
5O INORGANIC AND THEORETICAL, CHEMISTRY
to form sheets and foil. Platinum sponge is obtained by igniting dried ammonium
chloroplatinate, preferably in hydrogen. W. H. Wollaston 8 emphasized the need
for igniting the chloroplatinate at as low a temp, as possible, to prevent
agglomeration,
which makes the process a slow one. The preparation of spongy platinum
was described by R. Bottger, J. W. Dobereiner, M. Faraday, K. A. Hirschberg,
�whichagain causes the formation of coarse particles which can now be washed as
required
without showing any tendency to pass into the colloidal state. The metal is finally
filtered
and dried in a vacuum over sulphuric acid. Great caution must be observed in the
subsequent
admission of air into the desiccator as the metal readily becomes incandescent
owing
to absorption of oxygen. Previous to use, it is advisable to grind and wash it once
more.
The plating of metals, say copper or brass, with platinum has been effected by
spreading fine spongy platinum on the metal, then platinum foil, and afterwards
rolling at ordinary temp., and at a red-heat. Processes were described by
C. Bromeis,9 M. Labonte and J. Dupuis, and M. Savard. E. Melly was not successful
in platinizing metals with thin platinum films by using platinum amalgam by
the process employed for gilding with gold amalgam, but he did obtain good results
by dipping the clean metal in a dil. neutral or alkaline soln. of platinum
tetrachloride,
and then heating it to 60� ; R. Bottger recommended a mixture of 8 parts of sodium
chloride with a soln. of 1 part of platinic chloride in 100 parts of water ; or a
mixture of 1 part of ammonium chloroplatinate with 8 parts of ammonium chloride.
Methods were also described by A. P. Gr. Daumesnil, A. Gawalowsky, J. Stodart,
J. H. Johnson, J. A. Paterson, and C. Wilde. For the electrodeposition of platinum,
vide infra.
platinio chloride dissolves in the oil ; and when this mixture is painted on
pottery
glazes, and fired in a muffle at a dull red-heat, the so-called platinum lustre is
produced. Thin films of platinum on porcelain and glass were also obtained by
,
54 INORGANIC AND THEORETICAL, CHEMISTRY
Mrs. Fulhame,1 in lier study of the action of reducing agents on metallic salts
in 1794, observed phenomena which would now be interpreted as effects due to the
presence of colloidal metals ; and the same remark applies to phenomena observed
by J. W. Dobereiner, and by A. Schmidt. G. Bredig prepared a colloidal solution
of platinum, as a hydrosol, by spluttering platinum electrodes immersed in jce-cold
water�3. 23, 10. The process was also employed by G. Bredig and R. Muller
von Berneck, A. de Gregorio y Rocasolano, R. Furth, S. Miyamoto, A. Voet, and
C. Ernst. According to E. Muller, the hydrosol is not very stable unless water
of the highest degree of purity is employed. M. Kimura observed that when a
platinum wire is heated to incandescence, and then plunged into distilled water,
the presence of colloidal platinum can be detected by ultra-microscopic
examination.
H. Kuzel prepared the colloid by bringing the element into a fine state of
subdivision
by grinding, cathodic spluttering, etc., and then treating it for long periods
alternately with dil. acidic soln. and dil. alkaline or neutral soln. under the
influence
of moderate heat, and violent agitation. After each treatment the material is
washed with distilled water or other solvent until it is free from the reagent
employed.
S. Miyamoto used the silent discharge, E. Jirsa observed that in some cases
the colloidal particles are probably oxides.
When a very dil. soln. of a platinum salt, say hydrochloroplatinic acid, is treated
with a reducing agent, the platinum which is formed may be in colloidal soln., or
a precipitate may be formed, which, when washed with distilled water, is peptized
as the associated salts are washed away. K. Regel observed that if potassium
chloroplatinate precipitates are treated with magnesium and hydrochloric acid,
colloidal platinum is formed. O. Loew, Kalle and Co., H. Schulze, E. C. Auerswald,
alcohol, and methyl alcohol. The stability is not dependent on the dielectric
constants of the media. J. Billitzer obtained colloidal soln. in alcohol, and in
chloroform ; J. Lindeman and T. Svedberg, in alcohol and ether ; and T. Svedberg,
and E. F. Burton, in ethyl malonate. E. C. H. Davies and V. Sivertz studied the
rhythmic precipitation of platinum on silica gel. H. P. Walmsley studied the
aerosol of platinum.
B. Delachanal and A. Mermet found that the red colour�red colloidal platinum�
produced when soln. of platinum salts are treated with stannous chloride is due
to the presence of colloidal metallic platinum in a very fine state of subdivision,
and that the formation of this in place of the more usual brown colloidal metal
is due to the action of stannic chloride and its products of hydrolysis as
protective
colloids. The red colloid is also formed when the reduction of platinum salts is
effected by means of a soln. of phosphorus in ether, if gelatin is added as a
protective
colloid. The identity of the two red substances has been established by
spectroscopic
observations. If the colloidal soln. obtained by reduction with stannous
chloride is shaken up -with ethyl ether or ethyl acetate, the organic solvents take
up the red colour, and this is found to be connected -with the solubility of
stannic
chloride in these media, in which it plays the part of protective colloid. When the
aq. soln. is diluted with a large volume of water, or when the ethyl acetate soln.
is poured into water, a chocolate-brown precipitate is obtained. According to
colloidal stannic acid. The properties of the purple of Cassius, and red colloidal
platinum are similar.
J. Duclaux found that the osmotic press, of the soln. is less than 2 cm. of water.
C. Thomas said that the change to white of the colour of the ultramicroscopic
particles marks the beginning of coagulation. P. LaI and P. B. Ganguly observed
that the colloid is coagulated by exposure to ultra-violet light. E. Miiller
studied
the polarization, and extinctive coeff. of the colloidal soln. ; A. T. Williams,
and
O. Scarpa, the spectra of colloidal soln. of platinum ; E. B. Spear and co-workers,
the coagulation of the sol in ultra-violet light ; and E. B. Spear and K. D. Kahn,
the precipitation of the colloid on metallic surfaces. H. Freundlich observed that
the hydrosol of platinum shows anodic convection like arsenic sulphide sol.
S. W. Pennycuick studied the cataphoretic velocity. L. Holla found that the
velocity of migration of the colloidal particles in an electric field with a drop
of
potential of 1 volt per cm. is 24 O X 1O-5 cm. per second ; T. Svedberg gave for
the
lower limit 7*6 x K)-3 cm. per second; and E. F. Burton, 2-3xl0 -5 cm. per second
for the speed of colloidal soln. in ethyl malonate. The subject was discussed by
A. Einstein, F. Evers, J. J. Bikermann, N. Bach and N. Balaschowa, W. Biltz,
and W. R. Whitney and J. C. Blake.
According to L. Liebermann, reddish-brown, colloidal soln. of platinum become
dark brown when hydrogen is passed through the liquid. The colloidal soln. of
platinum dissolves hydrogen gas roughly in proportion to the concentration.
hydrogen is oxidized to "water. G. Bredig and R. Muller von Berneck studied the
catalytic decomposition of hydrogen dioxide by colloidal platinum ; the activity
diminishes with increasing proportions of protective colloid which may be present.
Thus, J. Groh found the effect of increasing the percentage proportion of gelatin
on the relative times required to decompose 50 per cent, of hydrogen peroxide :
According to G. Bredig and IC. Ikeda, and T. S. Price and J. A. N. Friend, the
activity of the colloid is decreased by hydrogen sulphide or cyanide which are
metaphorically said to poison the reaction. C. J. Farmer and F. Parker observed
that the activity of the colloid is increased by a short exposure to ultra-violet
light,
but is decreased with a long exposure until it finally ceases as a black,
flocculent
precipitate is formed. T. S. Price and J. A. N. Friend observed that the presence
of colloidal platinum favours the reaction between hydrogen dioxide and
permonosulphuric
acid ; and J. A. N. Friend, the reaction between hydrogen dioxide and
potassium persulphate. G. L. Clark studied the subject.
chloride, 0-058 ; uranyl nitrate, 0-065 ; lead nitrate, O-Oll ; barium hydroxide,
0-058 ; and aluminium sulphate, 0-007. S. W. Pennycuick studied the exchange of
ions at the surface of colloidal platinum. W. Biltz found that a trace of ferric,
aluminium, cerium, zirconium, or chromium hydroxide precipitates the colloidal
platinum from 1 or 2 c.c. of the sol. N. Pappada found that a 4 per cent. soln. of
mercuric chloride does not precipitate the colloidal soln. unless it bo warmed ;
soln.
of potassium cyanide or hydrocyanic acid change colloidal platinum chemically ;
there is also a chemical reaction with the halogens�e.g. chlorine or iodine ; 0-
12Vsoln.
of non-ionized, organic substances�e.g. methyl or ethyl alcohol, glucose, and
saccharose�coagulate the sol, but N- and more cone. soln. do not do so ; 2 c.c.
of 0-liV-soln. of hydrochloric, nitric, and sulphuric acids coagulate the sol,
likewise
also with 1 c.c. of 2V-CsCl ; 1-5 c.c. of iV-RbCl�incompletely, and likewise so
with
2V-KC1, 2V-NaCl, and N-IACl ; coagulation occurs with 3 c.c. of 22V-KC1 ; 1 c.c.
of 012V-BaCl2, 0-IiV-SrCl2, and 0-IiV-CaCl2 ; and with 5 drops of 0-12V-Al2(SO4)3,
and 0-12V-Cr2(SO4J3 ; no coagulation occurred with OliV-soln. of CsCl, RbCl,
KCl, NaCl, or LiCl, or with the corresponding bromides, iodides, sulphates, or
nitrates. The coagulation of the sols was studied by S. W. Pennycuick and
R. J. Best, A. Voet, P. C. L. Thorne and co-workers, W. D. Bancroft, Wo. Ostwald,
and A. Ivanitzkaja and co-workers. E. B. Spear and K. D. Kahn observed that
colloidal soln. of platinum are coagulated by metal plates ; and M. Annetts, by
cathode rays. The plates are more active if roughened. The order of decreasing
activity is : zinc, steel, nickel, tin, and copper. A. de Gregorio y Rocasolano
studied the ageing of the sol. Y. Shibata and H. Kaneko studied influence of the
sol on the rate of oxidation of pyrogallol.
INORGANIC AND THEORETICAL, CHEMISTRY
ItEFEEENCES.
R. J. Haiiy x first suggested that the crystals belong to the cubic system. He
said : la forme de petits cristaux de platine m'a paru Stre celle du cube ; A.
Breithaupt
confirmed this with crystals of platinum from Russia ; and F. Mohs said that the
crystals are hexahedral. G. B. Sowerby found native platinum with a laminated
structure. Platinum usually occurs in grains or scales, occasionally in lumps or
nuggets -weighing up to 21 lbs.�vide supra. The structure of these grains was
discussed by R. Beck, H. O. H. Carpenter and S. Tamura, B. von Cotta, A. Daubree,
M. Ginsburg, E. Hussak, A. Inostranzeff, B. O. Karpoff, A. Liversidge, S. Meunier,
J. Orcel, V. Poschl, J. W. Retgers, F. Rinne, S. F. Schemtschuschny, and
G. H. Stanley and P. A. Wagner. Well-formed crystals are comparatively rare.
Cubes or distorted cubes are the most common crystalline forms. P. V. Jeremejeff
described some crystals which he said were usually hexahedral, rarely octahedral.
No cleavage was observed, but there is some twinning about the (lll)-plane.
Octahedral forms were also observed by E. Hussak, G. B. Sowerby, and F. Limmer.
J. Orcel obtained octahedral and tetrahedral crystals by volatilization. The colour
and streak of platinum are whitish steel-grey. F. Mylius and R. Dietz noted that
the fracture of platinum is crystalline ; native platinum has a hackly fracture.
A. Jedele studied the corrosion figures. R. Gans and R. Calatroni discussed the
nature of the ultra-microscopic particles of platinum. M. Berek discussed the
microdetection
of platinum in ores.
J. J.Ebelmen obtained, by chance, during the fusion of some silicates, octahedral,
and cubo-octahedral crystals of platinum ; and J. JoIy obtained small octahedral
or cubo-octahedral crystals by heating platinum in contact with quartz, or topaz.
G. T. Beilby observed that the polished metal has a transparent, glass-like skin
which may pass into minute scales or granules. A. Guntz and H. Bassett observed
that in high temp, electric furnaces, where platinum is near its m.p., the metal
may be sublimed to form small crystals 00085 to 0-014 mm. in size. These crystals
may be cubic or octahedral, or a combination of these forms, or a combination of
cubic and tetrahedral forms. G. T. Beilby, and H. Zahn and J. Kramer noted
that amorphous layers are converted into the crystalline metal at a definite temp.
G. D. Preston studied the twinning of the crystals. G. A. Hulett and H. W. Berger,
and H. Moissan observed that small crystals are formed as a dusty sublimate when
platinum is heated in the electric furnace ; G. P. Thomson and co-workers, the
crystalline structure of thin films ; and W. Crookes, that platinum sublimed at
1300� furnishes hexagonal plates with a metallic lustre. F. W. Constant observed
mosaic crystals.
W. Campbell found that by suitably cooling platinum, a dendritic structure
could be developed in the metal. Dendrites, represented by the so-called platinum
tree, were obtained by G. F. Wach by the action of zinc on a dil. soln. of platinic
chloride ; and W. Holtz wrapped a zinc-rod (1 mm. thick and 1*5 mm. in width
at the bottom, and 3 mm. in width at the top) in paper, and when this was
immersed in a soln. of platinic chloride, a platinum tree with many branches was
developed. The tree had a metallic lustre and was hard enough to permit of filing.
J. W. Mallet observed that the etching with aqua regia of platinum which has
been fused showed up the crystalline structure ; and T. L.. Phipson observed that
the metal etched by aqua regia exhibits octahedral and tetrahedral forms , and
6 0 INORGANIC AND THEORETICAL CHEMISTRY
T. Andrews. F. Bran showed the crystalline structure of the metal which had
been exposed to anodic attack in hydrochloric acid. T. Andrews said that the
general microstructure of platinum is allotrimorphic in character and derived
from a system of interfering cubes and octahedra, the cubic and hexagonal form
being frequently noticeable. The size of the larger crystal grains varies from
0*002
inch to 0-04 inch in size, and the smaller crystals range from about 0-0002 inch
to about 0-007 inch. J. Orcel, K. Gebhard and H. J. Wiester, O. Feussner,
E. Schmid, and F. W. Constant studied the subject. S. Kalischer found that
platinum wire which showed no signs of crystallization became distinctly
crystalline
after being heated to redness. M. Soceze noted that platinum which had been
heated for a few days in the vicinity of its m.p., acquired a crystalline structure
showing cubic and octahedral forms. L. Holborn and co-workers observed that
chemically pure platinum after being heated to 1670� was distinctly crystalline.
S. Dembinska found that deposits several w*/x thick show no crystal structure until
they have been heated beyond a critical temp., 250� to 300�. O. Feussner showed
that platinum does not crystallize on annealing below a certain temp, limit. The
representing the annealing
curve
900� temP
I 60 3
: 52-8
42-2
Percentage work
burner. J. F. Daniell, and W. N.
O. Kottig, and O. L. Erdmann observed that octahedral crystals are formed when
platinum is heated at bright redness for some hours in contact with potassium
nitrate ; and F. Limmer obtained well-formed crystals by heating the platinum
sponge in contact with cupric chloride. H. Moissan obtained crystals of platinum
PLATINUM
the mass, under the influence of the strain, develop innumerable fine stress bands
or slip-bands indicating crystalline slip.
The area, enclosed, by the main, lines of disruption roughly approximate to the
size
of the large crystal grains. The distances between the extremely fine lines or slip
bands
coincide approximately with the size of the minute crystals forming the mass, the
finer
slip bands indicate that the crystalline slip has taken place along the facets of
the smaller
crystals. The direction of the main lines of crystalline disruption do not always
coincide
with the intercrystalline facet junctions of the large crystal grains. The lines of
least
resistance or greatest crystalline slip develop chiefly at an approximate angle of
45� to the
pressure linos, but the line of greatest weakness in the mass structure of the
metal is not
always at that angle with the line of the disruptive force.
M. Chabaneau, 24-O, and J. Cloud, 23-5�all three values are too high ; P. Berthier
also gave some high values along with 21-47 and 21-53 ; J. J. Berzelius gave
21*45 ; M. J. Brisson gave 19-5 for the metal which has been fused ; 20-3 for the
hammered metal, and 21-O for the wire ; M. Faraday and J. Stodart gave 21-3 for
the sp. gr. ; D. Prechtl, 17-7 for the fused metal ; W. H. Wollaston gave 21-16 for
wire, 21-25 for malleable platinum, and 21-4 for the wire drawn from the same
metal; B. Scholz gave 21-345 ; P. T. Meissner, 21-359 ; C. von Sickingen, 21-061 ;
R. F. Marchand, 21-2668 to 21-3092 at 0� ; C. Schumacher, 21-1878 to 20-212 ;
C. Barus, 21-31 ; R. Hare gave 21-16 to 21-31 for the hammered metal.
O. J. Broch said that the mean value of the earlier determinations is 21-49.
Collections
of data were made by R. F. Marchand, R. Bottger, and F. W. Clarke, and
observations on the subject were made by G. Osann. H. St. C. Deville and
H. Debray gave 21-15 for purified metal not hardened ; and the highest value for
the purified metal was 21-504 at 17-8�/17-6�. The lower values were attributed
to the presence of sealed pores. W. A. Tilden gave 21-323 at 3 8�'18� ;
T. W. Richards, 21-31 at 20� ; P. W. Bridgman, 21-34 at 20� ; W. Schlett, 21-1296
to 21-4802 ; G. Wertheim, 20-513 to 20-518 at 30� to 15� ; J. Y. Buchanan, 21-5 ;
E. Gruneisen, 21-39 to 21-44; T. W. Richards, 21-31; W. Gaede, 21-407;
C). J. Broch and co-workers obtained 21-463 for purified strongly hammered metal ;
and for the best representative value for a number of samples, they gave 21-49 at
0�/4� ; F. Mylius and R. Dietz gave 21-4 for the purified metal. A. W. Hull, and
W. P. Davey gave 21-23 for the sp. gr. calculated from the X-radiogram data ;
and W. P. Davey, 21-51.
G. W. A. Kahlbaum and E. Sturm obtained 21-4316 to 21-4327 at 20�/4� for
annealed wire, and 21-4152 to 21-4133 for cold-drawn wire ; and G. W. A. Kahlbaum,
21-4 at 200/20� for the rolled or wire-drawn metal, and 21-1 to 21-3 for the
compressed metal. The change in sp. gr. with mechanical work was further discussed
by W. Schlett, and F. C. A. H. Lantsberry. T. M. Lowry and R. G. Parker
gave 21-3351 for the sp. gr. of the massive metal, and 21-3705 for the filings.
G. W. A. Kahlbaum and E. Sturm obtained 21-3985 to 21-4312 for the purified
metal, 21-4112, at 20�/4�, after torsion, and 2-4284 after annealing. G. Wertheim
gave for the hammered metal subjected to a tensile stress before elongation 21-166
to 21-275, and after cracking, 20*987 ; and with another sample, 20-753 to 21-207
before elongation, and 21-029 after cracking�all at 12� to 13��vide infra, elastic
modulus. J. A. Groshans studied the density relations of the different elements.
A. Sayno discussed some relations between the sp. gr., at. wt., m.p., and torsion
modulus. G. Quincke gave 18-915 for the sp. gr. of the molten metal.
T. Thomson gave 21-47 for the sp. gr. of spongy platinum ; G. Rose, 16-6340 ;
L. Playfair and J. P. Joule, 21-169 to 21-243 ; E. H. Archibald, 21-16 at 24�/4� ;
A. W. Warrington gave 21-45 at O0, and added, v=^o(l-f-O-OOOO2660). B. Scholz
gave 17-894 for the sp. gr. of platinum black ; J. von Liebig, 15-8O to 17-572 ;
and G. Rose, gave 20-7732 to 20-9815 ; and Ii. Playfair and J. P. Joule, 17-766,
but T. Sexl observed that sub-microscopic particles do not have a much lower
density than massive platinum. C. Benedicks gave 1-37 X 1O-8 cm. for the atomic
radius ; V. M. Goldschmidt, 1-38O A. W. Biltz and K. Meisel, W. Hulme-Rothery,
E. H. Westling, J. C. Slater, M. X�. Huggins, and G. Hagg discussed the packing
density ; and G. Destriau, the atomic volume in the solid and liquid states.
H. St. C. Deville and L. Troost 2 discussed the porosity of platinum. H. St. C.
Deville and H. Debray 3 said that platinum is nearly as hard as copper, and it is
readily polished ; and W. H. Wollaston observed that in compact masses, platinum
is harder than copper, and softer than iron. T. Turner found the hardness of
platinum on Mohs' scale to be 4 to 5 ; and J. R. Rydberg, 4 to 4-5. S. Bottone
observed the relative hardness of platinum to be 0-1107 when that of copper is
0-1360 ; and F. C. Calvert and R. Johnson gave iron, 1000 ; lead, 16 ; and
platinum, 375. C. A. Edwards gave 44 for Brmell's hardness ; and F. E. Carter
INORGANIC AND THEORETICAL CHEMISTRY
gave for cast, hard, and annealed platinum, respectively, 50, 97, and 47 ; and for
the scleroscopic hardness of hard and annealed platinum, respectively, 21, and 7.
Observations were made by P. Rehbinder, C. Johnson, and A. T. Grigorieff.
O. J. Broch and co-workers found that a wire supported at its two ends soon
acquires
a permanent sag. G. T. Beilby observed that the metal is readily hardened and
softened. G. Tammann and co-workers studied the effect of cold work on the
hardness.
W. II. Wollaston 4 remarked on the high tenacity of platinum wires and found
that the metal is very ductile, for it can be drawn out into very thin wires�alone
the metal can be drawn to a thickness of IOVd;th inch ; and when enclosed in silver
and A. Baudriinont made a similar observation, and added that the tensile strength
of a wire 0-410 mm. in diameter was 22-625 grms. per sq. mm. at 0� ; 19-284 at
100� ; and 17-277 at 200�. D. H. Ingall gave 14-27 tons or 32,000 lbs. per sq. in.
at 15�. W. Geibol found a wire 1 mm. in diameter broke with a load of 24 kgrms.
E. Steinmann studied the effect of annealing�vide infra, platinum-iridium alloys.
Y. E. Carter gave for <)-5 mm. wire, for hard and annealed platinum, respectively,
34 and 15 kgrrns. per sq. mm., and percentage elongations in 2 inches, respectively
0-8 and 32. A. GaifFe noted how dust on the wires during the drawing may interfere
with their tenacity. According to P. Phillips, the tenacity, with slow elongation
under the action of a constant load, can be represented by se=a-|-6 log t, where t
is the time, and a and b are constants. With a load of 50O kgrms. per sq. cm.,
the value of b is zero, and with increasing loads, the value of b increases. The
time / indicates how long the load is acting before elongation begins :
Ijoad firm or>4 771 854 952 1050 1247 1455 156O
fox IO* O 2-265 3-22 5-39 6-73 26-4O 138-O
Fracture
The results are plotted in Fig. 5 with the corresponding values for copper, silver,
and gold. The wires were 0-0506 cm. diameter, and were annealed 5 mins. by a
current of 8-5 amperes. F. A. and C. 1^. Lindemann found at the absolute temp.
20-4�, 81�, and 290� K., that the tensile
1200 strengths of platinum were, respectively,
8600, 7251, and 5080 kgrms. per sq. cm.
lbs. per sq. in., elongation, 30 per cent, in 2 ins., and reduction in area 93 per
F. Kohlrausch gave 17,020 kgrms. per sq. mm. for the elastic modulus or
Young9s modulus of platinum ; E. Edlund gave 16,275 kgrms. per sq. mm. ;
C. Schaefer, 16,029 kgrms. per sq. mm. ; and E. Griineisen obtained two samples]
PLATINUM
respectively, 17,021, and 17,080 kgrms. per sq. mm. G. Wertheim found the
elastic moduli, JE kgrms. per sq. mm., of drawn and annealed wires to be :
Sp. gr. .
For drawn platinum wire, N. Katzenelsohn gave 17,187 kgrms. per sq. mm. ;
Sg 5000 s
H. Tomlinson gave for Young's modulus, 149OxIO6 grms. per sq. cm.; and
A. Mallock, 1-27 for the ratio of Young's modulus at �273� and at 0�. P. Lasareff
5/3
found the elastic limit is proportional to n , where n is the number of atoms per
c.c.
E. Griineisen gave 1-0014 for the ratio of the adiabatic to the isothermal elastic
modulus ; and 0-368 to 0-387 for Foisson's ratio, i.e. the ratio of the lateral
contraction
to the longitudinal extension ; C. Schaefer gave 0-22 ; F. E. Carter, 0-387 ;
and H. Tomlinson 0-076. Gr. M. F. Sayre studied the elastic after-effect ; and
G. Tammann, the effect of cold-work on the physical properties.
C. Schaefer found the rigidity or torsion modulus to be 6593-6 kgrms. per sq.
mm. ; E. Griineisen gave 6220 kgrms. per sq. mm. at 18� ; W. Sutherland gave
650O ; H. Tomlinson, 6620 ; F. Horton, 6585 ; G. Pisati, 6280 ; A. T. Kupffer,
6370 ; and B. Gutenberg and H. Schlechtweg gave 6-8 X 1022 dynes per sq. cm.
K. R. Koch and C. Dannecker observed that the effect of temp, on the torsion
modulus T kgrms. per sq. mm., and the damping coeff., K9 of wires 1-507 mm. in
diameter, and 372-0 mm. in length is small, being
0�, 200� 400� 600� 800� 1000� 1200� 1400� 1600� 1700�
T . 724O 724O 7200 694O 574O 471O 413O 36OO 3300 286O
K . l-OOl l-OOl l-OOl 1024 1108 1-1Ol 1-13 11 7 1-27 1-5
F. E. Carter gave 6*10 dynes per sq. cm. for the rigidity ; and H. Tomlinson,
692-7 XlO6 grms. per sq. cm. Observations were made by R. H. M. Bosanquet,
J. Konigsberger, A. G. Grigorieff, K. Iokibe and S. Sakai, and G. Wertheim.
P. W. Bridgman observed that the rigidity increases under press. 2-4 per cent,
per 10,000 kgrms. per sq. cm. ; and that there are no breaks in the curves of
shearing
stress and pressure. The subject was discussed by L. H. Adams. The elastic
VOL. XVI. F
INORGANIC AND THEORETICAL CHEMISTRY
H. Sieglerschmidt studied the relation between the elastic modulus and the thermal
expansion ; O. Forster, the relation between the elastic modulus, the sp. ht.,
and the at. wt. ; L. P. Sieg, the relation between the elastic modulus and the m.p.
;
H. Jeffreys, the relation between the tensile strength and the m.p. ; A. H. Stuart,
and J. Kleiber, the relation between the elastic constants and the sp. ht. ; and
A. Sayno between the sp. gr., the at. wt., the m.p., and torsion modulus. W.
Sutherland
gave e/E=l�O-S230/Tmt where e denotes Young's modulus at 0�, and E9
at absolute zero ; and T9n is the m.p. of the metal. The relation is imperfect
because it gives a finite value for the modulus at the m.p. whereas it ought to
give
a zero value. Otherwise the observed values are approximately in accord with the
expression. A. Jacquerod and H. Mugeli gave for the bending elasticity of
platinum 19,90O kgrms. per sq. mm. at 0�, and 0-000075 for the temp, coeff. between
0� and 100�. F. E. Carter gave for the volume elasticity 24-7 dynes per sq. cm. ;
and for Ericsen's ductility test of hard and annealed platinum, respectively, 7*8
and 12-2 mm. K. Iokibe and S. Sakai gave for the rigidity and logarithmic
decrement,
for periods of about 10 seconds :
27� 191� 369� 604� 743�
Rigidity x 10-" 6-41 6-33 61 8 5-8O 5 04
26� 191" 385� 604� 690�
Log. doer. 0-0,25 0O835 0-0,97 00220 O0500
and for the viscosity w=l-75xl08 at 15�. The subject was investigated by
T. Kikuta, and G. Subrahmaniam.
per sq. in. JS. Gruneisen gave 0-04 X IO-1 2 c.g.s. units for the cubic
compressibility
of platinum, and 0-39 X 10 "6 to 0-40 x 1O-6 for the coeff. of cubical
compressibility ;
he found the effect of temp, on the coeff. of cubic compressibility j3, to be :
� 189� 16-8� 133� 164�
)3x 10� U-374 0-392 0-401 0-404
The compressibility thus increases with rise or temp., whereas the coeff. of
thermal
expansion decreases with a rise of temp. The results with a few metals are
illustrated by the curves, Fig. 7. IJ. H. Adams gave 0-3 X 1O-6 to 0-37x10 �
megabars. P. W. Bridgman gave for wire at 30�
/fir
B. Gutenberg and H. Schlechtweg gave 1-7 XlO8 c.g.s. units at ordinary temp.
CE . Guye and S. Mintz studied the effect of temp, on the viscosity, and found
that in passing from a high to a low temp, the original logarithmic decrements
are not obtained. These differences are smaller the higher is the temp. S. Virtel
studied the resistance law for the motion of sub-microscopical particles through
gases ; and F. Hirata, through viscous liquids. M. Born and O. F. Bollnow
calculated the cohesive force of the atoms in the space lattice to be 5'62XlO1 1
dynes per sq. cm.
T. W. Richards fl calculated for the internal pressure 347,00O megabars at 20� ;
and this value is exceeded only by tungsten. J. H. Hildebrand and co-workers,
and Jt. H. Mehl studied the cohesive press.
D. V. Gogate and D. S. Kothari 7 gave 1819 for the surface tension of platinum
at 2000�. G. Quincke calculated the capillarity coeff. of hard, drawn platinum to
be 3025 grms.; annealed platinum, 2388 grms.; and molten platinum, 1 69-04 mgrms.
P. Palladino said that methylene bromide gives a concave meniscus with platinum ;
S. Hi. Bigelow and F. W. Hunter studied the effect of platinum "walls on the
capillarity
of water, and of benzene ; and E. Warburg and T. Ihmori, the effect on the
capillarity of water. E. Degen discussed the wetting of platinum by water ; and
F. E. Bartell and M. A. Miller, the adhesion of water to the metal.
The diffusion of various gases, etc., in platinum -was studied by C. Matteucci,8
and G. Moreau, and the subject is discussed in connection with the chemical
properties of the metal. W. Kettembeil, and A. Coehn and W. Kettembeil
observed that mercury does not diffuse in platinum, but N. T. M. Wilsmore found
that platinum amalgam will make platinum swell. W. C. Roberts-Austen observed
that platinum diffuses more rapidly in bismuth than it does in lead. The diffusion
coeff. for platinum in lead is 1-69 per sq. cm. per day, at 492�.
O. D. Chwolson 9 gave 2700 metres per second for the velocity of sound in
platinum ; A. Masson gave 2792-1 metres per second ; and G. Wertheim gave
2684*9 metres per second for drawn wires, and 2733-4 metres per second for annealed
wires. J. Kleiber found that the velocity of sound in metals is proportional to the
sq. root of the product of the sp. ht. and the linear coeff. of expansion. Relative
values were calculated by G. Wertheim on the assumption that the velocity in air
is unity :
Thin wiies Medium wires Thick wires
* * *�
at 20�, 0-05899 at 40�, and for the metal with 10 per cent, of iridium, 005884.
A. Matthiessen observed for the coeff. of cubical expansion between 7-52� and 97�,
^==�o(l -hO-O425540+O-O7lO402). Observations were made by M. Thiesen,
E. L. Nichols, and W. D. Flower. R. Benoit obtained values for the coeff. of linear
7O
H. Ie Chatelier gave for purified platinum, Ct=OO4113, and for platinum with
iridium 0O4IOS between 0� and 1000� ; and T. Seliwanoff, ct=0-05975 between 0�
and about 1600��a increases rapidly up to 150�.. and thereafter, slowly.
H. O. Dorsey gave <x=0-05815 between 20� and �180� ; G. Shinoda, 9-9xl0~�
between 15� and 1000� ; and I,. J. Terneden :
100� 200� 300� 400� 500� 600� 700� 800�
E. Gruneisen gave :
�150� � IOO" 0� 100� 87f>�
and S. Valentiner and J. Wallot gave the following results, plotted in Fig. 8, for
the average temp. :
IJ. Holborn and A. L. Day found that a rod of unit length at 0� becomes I
at temp., 0�, between 0� and 1000�, where I=-(88680+1 -32402) x io~9, or
I Z0(M CK)588f>80~f 0-O8132402) . K. Scheel gave for 0� between 16� and 56�,
Z^Z0(I+O-O588O604-0-O819502) ; between 16�
and �190�, I=I0(J +0-0586150+0-O837O02) ;J between 100� and �190�, Z=7O(1+O-O587490
900 �
^ soo
/tin
that the changes in length of metre rods of
*"^20(f -/00� o� 100� platinum, and platinum with 2O per cent, of
KJO. 8. -The Kffoct of Heat on tli� iridium, at 16�, were, respectively, �3-649
Coefficient of Thormal Expansion (o). mm. and �1*553 mm. at �191�; +2-158
E. A. Owen and E. TJ. Yates measured the thermal expansion of the spacelattice
of platinum up to 600�, and obtained for the coefT. of expansion at 0�,
a---<zo(l+O-O479O80+O-O8381702-O-O11794503+O-O14294304) which is in close agreement
at 100�.
W. Swientoslawsky and S. Bakowsky 3 studied the evaporation of liquids from
platinum surfaces. P. JL. Dulong and A. T. Petit gave O-0335 for the specific
heat of platinum between 0� and 100�, and 0-0335 between 0� and 300�.
H. V. Regnault obtained 003197 and 003294 between about 11� and 99� ; H. Kopp
gave 0-0325 between 20� and 52� ; H. Tomlinson, gave between 0� and 100�,
0-031980+O-O56302 ; R. Bunsen, 0-03234 and 0-032672 between 0� and 100� ;
J. JoIy, 00328 between 14� and 100� ; L.. Schuz, 0-03037 and 0-03295 between 15�
and 100� ; and A. Bartoli and E. Stracciati, 0-032238 between 16� and 100�.
Observations were made by E. Terres and H. Biederbeek ; and K. Schulz compiled
a bibliography on the sp. hts. of the metals. J. Violle obtained for the mean sp.
ht. between 0� and
100� 200� 400� 600� 800� 1000� 1200�
or, sp. ht.-=O-O317~|-O-OOOOOO60. U. BeIm gave for the purified metal, 0-0311
between 18� and �79�, and 00293 between 18� and �186� ; W. Jager and
H. Diesselhorst, 0-0326 between 17� and 100� ; W. A. Tilden, 0-0292 between 15�
and �182�, and 0-03147 between 15� and 100�, 00338 between 15� and 435�,
0-0377 between 0� and 1000�, and 0-0388 between 0� and 1177�. L.. Kunz obtained
00359 between 0� and 930� ; 0-0377 between 0� and 946� ; 00377 between 0�
and 960� ; and 0-0378 between 0� and 1018�. A. Wigand working between 0�
and the following temp, obtained 0-03145 at 32� ; 003181 at 54� ; 003204 at 97� ;
003216 at 133� ; 0-03223 at 162� ; and 0-03230 at 199� ; similarly with W. Schlett,
and E. Gruneisen :
O. M. Corbino measured the sp. ht. at constant vol. ; and !L. Fabaro gave
Cjt^=Ct>{\ +0*0463(T-f-273)}. E. Gruneisen said that the ratio of the sp. ht. at
constant press, to that at constant vol. is 1-019 at 18�. W. Weber gave 0-0259 for
the sp. ht. at constant vol., and he added that the temp, rises or falls by 100� if
to 0-03168 : a cast specimen had a sp. ht. of 0*03168, when hammered to 2 mm. the
value was 6*03134, and when cold-drawn to 0-5 mm., 0-03150 ; a specimen of cast
platinum had a sp. ht. of 0*03188, and after annealing for 30 minutes at a white
heat, 0*03145. F. M. Jager and co-workers found the sp. ht. of annealed platinum
to be 2 per cent, higher than that of the unannealed metal. E. Gruneisen found
that the mean sp. ht., cv, of platinum is increased by 0-O619 per kgrm. per sq. cm.
S. Ridwell studied the relation between the sp. ht., the electrical resistance, and
W. Nasse 4 could not melt it in the hard-porcelain oven, but L. Eisner melted
platinum black into small, metallic beads, and J. J. Prechtl did succeed in melting
with a high chimney. The carbon, etc., here present would, according to
J. B. Dumas, lower the m.p. of the metal. The metal does not melt in the strongest
heat of a forge, although M. Faraday and J. Stodart obtained imperfect fusion ;
if, however, the fuel be in contact with the platinum fusion may occur owing to
the formation of silicides and carbides of platinum. The metal was fused in the
oxy-hydrogen flame by E. D. Clarke, W. Maugham, A. Marcet, E. F. Diirre, and
R. Hare. R. Hare melted 28 ozs. of platinum on a block of lime heated by the
oxyhydrogen
flame ; and H. St. C. Deville, and H. St. C. Deville and H. Debray
modified R. Hare's procedure and were able to melt a kilogram of metal with the
consumption of 60 to IOO litres of oxygen. F. Reich melted platinum on a block
PLATINUM
W. Skey melted pointed wires in the ordinary blowpipe flame ; C. Fery melted
thin wires in a bunsen burner. C. Fery and C. Cheneveau found that a horizontal
wire heated electrically broke at 1690�, rather below the true m.p., a vertical
wire
similarly heated fused to a drop at 1710� ; a wire held vertically in the flame of
a
meker burner fused to a bead at 1740�, and in the oxy-coal gas flame, the fusion
temp, was between 1700� and 1750� according as an oxidizing or reducing flame
was employed. This shows that the m.p. of platinum, like that of silver, depends
on the nature of the atmosphere in which the fusion occurs. The subject was
discussed by C. W. Waidner and G. K. Burgess. R. C. Smith observed the sintering
of precipitated platinum-black occurs at about 500�. J. G. Children, P. Riess,
and C Despretz melted platinum wires heated by the passage of an electric current,
and, as previously indicated, C. W. von Siemens and A. K. Huntington, and
others melted the metal in an electric furnace. M. Rabinovitsch studied the glow
on heating the finely-divided metal ; R. Wright and R. C. Smith, the sintering of
the finely-divided metal ; and J. A. M. van Liempt and J. A. de Vriend, the time
of melting thin wires.
The methods available for measuring high temp, were very unsatisfactory
throughout the greater part of the nineteenth century ; and consequently the
cylinders of the metals with plane surfaces of contact are subjected to press, for
4 to 8 hrs. at 400�, all the metals tried, with the exception of platinum and
antimony,
were welded so thoroughly that if the piece be broken the fracture does not take
place at the original surfaces of separation.
J. A. Harker obtained 1710� for the m.p. of platinum, but this datum is too low ;
L. Holborn and S. Valentiner gave 1789�, but this value is rather larger than that
obtained by other investigators ; L. Holborn and W. Wien gave 1780� ; and
L. Holborn and F. Henning, 1710�. F. Doerinckel, 1744� ; O. Goecke, 1745� to
1755� ; K. R. Koch and C. Dannecker, 1750� ; A. L,. Day and R. B. Sosman, 1755� ;
W. Nernst and H. von Wartenberg, 1745� ; W. Holman and co-workers, 1760 �;
C. W. Waidner and G. K. Burgess gave 1753� ; H. E. Ives, 1764� ; F. Hoffmann,
1771� ; F. E. Carter, 1755�. G. Ribaud and P. Mohr gave 1762� ; L. D. Morris
and S. R. Scholes, 1773� ; W. F. Roeser and co-workers, 1773-5� ; F. H. Schofield,
1773-3� ; and F. Hoffmann and C. Tingwaldt, 1773-8� for the f.p. Observations
�were made by O. Ruff. The temp, determinations also depend on the values
assigned to the constant in the equation employed in standardizing the pyrometers.
H. St. C. Deville and H. Debray, and W. Heraeus noted the spitting of molten
platinum during cooling owing to the liberation of absorbed gases as the metal
solidifies. C. E. Mendenhall and Ii. R. Ingersoll found that platinum may be
supercooled 370�, and that when the metal solidifies there is a momentary flash
of light. J. IJ. Byers discussed the behaviour of platinum on cupellation.
74 INORGANIC AND THEORETICAL CHEMISTRY
Calculations of the m.p. from empirical equations have been made, and
calculated that the raising of the atm. press. 1 atmosphere lowers the m.p.,
and that at a press, of 46,0OO atm. platinum would accordingly melt at 27��that
is, of course, if something else did not happen. C. T. Heycock and F. H. Neville
measured the lowering of the f.p. of cadmium, thallium, lead, and bismuth by
about a gram-atom of platinum in 1OO gram-atoms of metal. P. W. Robertson,
and W. Crossley discussed the relation between the at. vol. and the m.p. ; J.
Johnston,
the effect of press, on the m.p. ; A. Stein, the relation between the electrical
resistance, the at. vol., and the m.p. ; T. Carnelley, and E. M. Lemeray, the
relation
between the m.p. and the coeff. of thermal expansion ; L. P. Sieg, the relation
between the m.p. and the elastic modulus ; W. Braunbek, the lattice energy of
melting ; Ii. Jeffreys, the relation between the m.p. and the tensile strength ;
W. Tlerz, the relation between the m.p. and its vibration frequency ; W. Widder,
and N. F. Deerr, the relation between the m.p. and the latent heat of fusion ; and
W. Sutherland, the relation between the m.p. and the elastic constants. J. Johnston
observed that if D be the density of the substance at the m.p., T, the absolute
m.p.,
and Q, the heat of fusion per gram, then the press, required to melt platinum at
27� is \Ky\QD log (7727), or 46,0OO atm.
H. Moissan 5 found that the volatilization of platinum readily occurs in the
electric arc furnace, indeed, the metal boils and distils as readily as water does
at
1(K)�. O. J. Broch and H. St. C. Deville observed no volatilization when melted
in oxygen gas ; W. N. Hartley observed none in the oxy-hydrogen flame ; and
F. Mylius and F. Forster, and R. W. Hall found no evidence of volatilization at
high temp. If the rate of volatilization of osmium at 1300� is 1000, that of
platinum
is 2. On the other hand, A. Knocke observed that in vacuo platinum volatilizes
at 540�, but not at 538�. W. Crookes observed that an electrically heated wire
volatilizes nearly half as rapidly as gold ; and at 1300�, platinum lost in 2 hrs.
0-019 per cent, and in 30 hrs., 0-245 per cent., although no loss was observed at
900� ; he first thought that the volatility is due to the formation and
decomposition
of unstable, volatile oxides, but later gave up the hypothesis. R. W. Hall said
that the behaviour of platinum when heated is best explained by the hypothesis
that an oxide is formed which is stable at high and low temp., but unstable at
intermediate temp.�vid e infra, action of oxygen on platinum. F. E. Carter said
that an appreciable volatilization occurs at 1000�. H. St. C. Deville also said
that
the metal volatilizes rapidly at a temp, a little above its m.p, ; and C. Zengelis,
but no perceptible loss occurred during 20 hrs.' heating at 900�. I. Langmuir and
Gr. M. J. MacKay estimated the rate of evaporation of platinum, m grms. per sq.
cm. per second, at different temp, on the absolute scale, T� K., and found log m
==14-0�27800T-1�1-76 log T9 or :
F. Beilstein said that the loss in weight with crucibles becomes less and less with
iridium from the alloy. R. W. Hall found the loss in some cases to be greater
PLATINUM
after the twentieth ignition than after the first ; in some cases, the crucible
after
a month's use ceases to lose weight. H. A. Jones and co-workers found the rate
of evaporation, m grms. per sq. cm. per second, and the vap. press, p bars, to be :
to gain in weight owing to the diffusion of the metal to the surface, and there
oxidizing�vide infra, action of iron oxides on platinum. G. K. Burgess and
P. D. Sale found that rhodium like iridium stiffens platinum, and reduces the
volatilization of platinum above 900�. Observations were made by J. Strong,
F. Mohr, E. Sonstadt, A. K. Boldyreff, G. A. Hulett and H. W. Berger, and E.
Goldstein.
G. C. Wittstein referred the loss to osmium, but F. Stolba pointed out that
the loss in weight is greater than the amount of osmium in the platinum.
O. Li. Erdmann thought that the grey film produced on platinum heated in a
non-reducing bunsen flame is due to an allotropic change because he could detect
no variation in weight, but A. Remont showed that the film can be produced by
heating the metal in a reducing flame and is then due to the formation and
subsequent
decomposition of a carbide, and in the case of burning gas, it is produced
not by carbon suspended in the flame, but rather by one or more gaseous
constituents
of the flame. F. Stolba discussed this subject. Li. Troost and P. Hautefeuille,
Li. Pigeon, and F. Seelheim noted that platinum volatilizes at a yellow heat
in chlorine, and V. Meyer found that platinum so lost 1 per cent, in weight when
heated in a current of dry chlorine at 1750��presumably, in this case, an
intermediate
volatile chloride is formed. J. Strong studied the vaporization of platinum
in vacuo from a tungsten filament ; and O. Goche, the cathodic evaporation of
platinum in a magnetic field.
P. Ricss noted that when platinum wires are heated electrically material
particles or dust are given off by the metal, and analogous observations were made
by A. Berliner, T. A. Edison, J. Elster and H. Geitel, F. Emich, F. Fischer and
H. Marx, W. L). Flower, H. Goldschmeid, F. Henning and L*. Austin, L. Holborn
and F. Henning, G. A. Hulett and W. Berger, S. Kalandyk, H. Kayser, V. Kohlschutter
eliminated with continuous heating, and they are produced by the evolution of
the gases occluded by the wires. The properties of the nuclei are as follow :�
They are emitted by the wire at comparatively low temp. The minimum temp,
required to produce them is lower the less the press, of the surrounding gas. They
alter
in size and disappear very soon after their liberation, but last longer if water-
vapour has
been caused to condense upon them. The ability of the wire to emit them is
temporarily
lost after an omission, but is slowly regained after the lapse of time. The wire
immediately
regains the ability to produce them when hydrogen is brought into contact with it ;
air,
oxygon, and nitrogen do not produce this effect. If the wire has been kept at a
white-heat
in a vacuum for a very long time, the admission and withdrawal of pure hydrogen
does not
revive the power to emit nuclei in a vacuum.
The second set is dependent on the presence of oxygen about the heated wire,�
these nuclei are never obtained below a certain temperature, and about this temp,
they are always formed in the presence, but never in the absence of oxygen. The
properties of the second set of nuclei indicate that an unstable, endothermal, and
volatile platinum oxide is formed as indicated above, and this is in agreement with
The second sot of nuclei aro not formed in nitrogen, hydrogen, or a vacuum, but
pnly
in the presence of oxygen. The rate of loss of weight of the metal is zero in
nitrogen,
hydrogen, or a vacuum. For platinum and rhodium the rate of disintegration at a
given
temperature is roughly proportional to the oxygen pressure ; for iridium, which is
very
oxidizablo, the rate of disintegration increases much more rapidly than the oxygen
pressure.
The disintegration of palladium is of a different nature and will be considered
later. At
low pressures of oxygen the nuclei aro very small. The nuclei begin to be formed
(that
is, the disintegration begins) at a fairly definite temperature. The nuclei are
very persistent
and do not alter in size ; thoy are unaffected by light or by an electric field.
�1-26 log Tt or :
?7� K. .
jy .
1000�
324x10-2�
1250�
891OxIO-1 6
1500�
3160xlO~1 2
17/50�
13OO XlO"9
2000�
49-5xlO-�
4180�
76O mm.
J. A. M. van Liiempt studied the vap. press, curves.
metal solidifies it emits a momentary glow owing to the liberation of the heat of
fusion. J. Violle gave 27-18 CaIs. per gram or 5-3 CaIs. per gram-atom for the
latent heat of fusion ; G. Pionchon gave 27-17 CaIs. ; and J. W. Richards computed
27-8 cals. per gram, J. A. M. van Liempt calculated 530O cals. per gram-atom.
N. F. Mott studied the relation between the latent heat, the m.p., and the
electrical
conductivity. N. von Raschevsky, and N. F. Deerr made some observations on the
relation between the m.p. and the heat of fusion. I. Langmuir and G. M. J. MacKay
represented the latent heat of vaporization by (128,000�2-5T) cals. per gram-atom.
F. S. Mortimer also studied the vapour pressure. A. Jouniaux said that Trouton's
rule did not apply to platinum. C. M. Guldberg estimated the critical temperature
of platinum to be 7000� when that of mercury is 1000�. J. J. van Laar, and
M. Thiesen discussed the equation of state of platinum. J. Thomsen studied
the thermochemistry of the platinum compounds. G. N. Lewis and co-workers,
R. C. Tolman, and E. C. Eastman gave 10-0 for the entropy of platinum at 25� ;
W. M. Latimer gave 0-41 for the change of entropy between 200� and 900�. The
internal energy and entropy were studied by K. K. Kelley, R. D. Kleeman, W. Herz,
B. Bruzs, R. von D. Wegener, and E. Kordes. E. D. Eastman and co-workers
discussed the thermal energy of the electrons in platinum.
PLATINUM
According to II. St. C. Deville and H.Debray,1 the Colour of platinum prepared
by fusion is a more silvery white than is the case with the hammered metal.
A. W. Wright said that the colour of thin films by transmitted light is grey with a
have a dark brown colour�vide supra, colloidal platinum. W. L*. Dudley said
that the incandescent vapour of platinum is blue. A. Kundt observed no dichroism
in the colour of platinum.
K. Forsterling and V. Freedericksz 2 found the light absorption, k, and the
index of refraction, fx, for light of -wave-length A, to be :
A . . .10 0 1-52 1-97 3-29 3-41 4-65/u
k . 1-83 1-76 1-65 1-62 1-56 1-41
E. Hagen and R. Rubens gave for the extinction coeff., k in /=/0.10~*'d, where d
denotes the thickness, and I0 and /, the intensities of the incident and emergent
rays of light of wave-length A:
A O-326 O-3 85 0-45 O-55 0-65 0-8 1-2 2 O 2-5^i
R 77 81
� � 83 86 88 89 per cent.
and A. Partszch and W. Hallwachs gave for the reflecting power of electrolytic
platinum, H1, and for a film prepared by spluttering, R2 :
in the reflecting power with increasing age. C. Fery said that a surface of
platinum black at 100� reflects 18 per cent, of the incident rays ; K. J. Angstrom
obtained only 0-82 to 1*25 per cent, for different regions of the spectrum ; and
T. Royds gave for platinum black deposited in 15 and in 3 mins., respectively,
JF?i and R% :
A 0-8 8-7 25-5 51fx
R1 . . . 0-17 0-59 0-93 1-1 per cent.
2?a . . . 1-3O 5-70 7-08 7-4
F. Limmer said that crystals of platinum obtained by the action of cupric chloride
on spongy platinum had an unusually strong reflecting power. P. Desains studied
the reflection of heat rays from polished platinum ; the selective reflection 1WaS
studied by H. Rubens ; the changes of phase in the reflected light, by H. Kath,
and J. Patterson ; and the relation between the electrode potential and the optical
constants, by V. Freedericksz.
K. Forsterling and V. Freedericksz gave for the index of refraction, for light
of wave-length A :
A . . . 1OO 1-52 1-97 3-29 3-41 4-65/z
ft . . . 3-42 4-71 5-92 7-5O 8-82 10-9O
and W. Meier :
909. E. Hagen and H. Rubens found the emissivity of platinum at 170� for
wave-length 4/x, is 8-5 per cent., and for wave-lengths 8/J,, 12/Lt, and 25-5/x,
respeepectively,
4-6, 3-5, and 2-82 per cent. For wave-length 25-5/*, the emissivities at
different temp, are :
Kmissivity
170�
3-49
220�
3*68
300�
40 4
600�
5-4O
900�
6-86
1200�
8-34
1600�
9-84
The change in the emissivity for wave-lengths 26/c and 8-85/u, with temp, is
greater
than the value calculated from the electrical behaviour. C. Davisson and
J. R. Weeks studied the relation between the emissivity and the electrical
resistance.
W. W. Coblentz's results for the isochromatic radiation energy of platinum are
summarized in Fig. 9. E. Bauer and M. Moulin found the emissivity, for angles
less than 40�, is nearly constant, but it increases for greater angles.
Observations
were also made by M. Czerny, H. A. Erickson, E. Furthmann, W. Giess, M. S. Glass,
E. Hagen and H. Rubens, A. L.. Helfgott, F. Hoffmann, M. Kahanowioz, G. Liiebmann,
L. TJ. Lockrow, F. Paschen, F. Rossetti,
R. W. Sears and J. A. Becker, V. A. Suydam,
A. M. Tyndall, W. von Uljanin, and
A. G. Worthing. H. Cassel and E. Gltickauf,
and T. B. Rymer studied the effect of oxygen
on the thermionic emission.
M. Geiseler noticed that platinum glows
when heated in the oxy-hydrogen name, and
A. Crova, and E. Becquerel, that glowing
platinum radiates energy like carbon, lime,
and porcelain. A. Smithells, and V. B. Lewes
observed that the glow of platinum is not
exceeded by the glow of the carbon particles
in hydrocarbon flames. G. Fletcher found
that an electrically-heated platinum wire
glows more strongly in air containing hydrocarbons
than in air alone. P. Desains and
5 Watts P. Curie, and J. Meunier found that platinum
Fia. 9.-�The Isochromatic Kmissivity can be maintained incandescent in a current
Curves of !Platinum. of coal-gas and air even though no flame is
present ; he also showed that the property
depends on the composition of the mixture. If a platinum wire is first cleaned
with hydrochloric acid and then heated, it loses the property of remaining
incandescent
; if, however, it is passed between the fingers it regains that particular
property because it takes up saline matter from them. This saline matter
can be removed from the fingers by washing them in acidified distilled water,
but not with soap and water. Thus, platinum itself is not responsible for the
incandescence, but rather the saline matter which is on its surface. C. Braun
noted that during the slow cooling of incandescent platinum, it retains its glow
more intensely than does porcelain. C. Killing observed that a trace of platinum
in thorium gas-mantles favours the incandescence as in the case of a trace of
ceria.
H. F. Weber observed that platinum emits a grey glow at about 360� ; R. Emden
said that with impure platinum the glow begins at about 404�, and with the purified
E. Ii. Nichols investigated the character and intensity of the rays from platinum
glowing at different temp., and found the intensities of the spectral lines of the
emitted light, on Kirchoff's scale, to be :
1294� 1238� 1188� 1081� 901�
The results are plotted in Fig. IO along with those of J. Stefan, H. F. Weber, and
if anything, the positive emission. The decay with time of the positive currents
at different temperatures showed the existence of two sources of ions, the first
source decaying according to an exponential law, and the second increasing to a
maximum before decaying. A. M. Tyndall and G. C. Grindley found that the
electrons emitted by an incandescent platinum wire, when removed from the
vicinity of the particles, attach themselves to molecules and give rise to normal
ions of the same mobility as those produced by polonium. The positive emission
is complex, and although the greater number have mobility of 1*4 cm. per sec. per
volt per cm. the mean value is of the order of 1*1. It is concluded that positive
ions are emitted either as small metallic clusters or as atoms, many of which
cluster
before Teaching the observation chamber, that the uncharged particles are metallic
clusters ranging from atomic size to metallic dust, and that their growth and
subsequent coagulation are responsible for the blackening of filament lamps.
W. H. Crew studied the effect of light. The thermionic emission of positive ions
was studied by F. Horton, !L. Weissmann, H. A. Erikson, H. A. Wilson, C. Grieb,
and Li. Li. Barnes ; and G. I. Finch and A. W. Ikin found that the catalytic
activity
of films of platinum is connected with electrical activity. The thermionic emission
illustrated in Fig. 11. The spark spectrum was also examined by W. E. Adeney,
f-r�i�i�r-�T�r-*-i 1 1 r"�i"- "t�*T r-"�J H 1 1 1�� 1 *� W ��, , ___ ^
6500 6000 5500 '5000 4500 40Q}
the lines M&N&, 4-407 ; M3N3, 5-484 ; j8", 6011 ; 0�, 6030 ; ct", 6-223 ; M1N19
6-250 ; M3N79 6-663 ; M1N5, 8012 ; al9 6049 ; 0l9 5-831 ; �3, 5-649 ; yx, 5-329 ;
y2, 4-733 ; andy3, 4-623. E. Dershem, E. Hjalmar, F. L. Hunt, A. J. M. Johnson,
metal in two forms, first, condensed on the surface, and, secondly, dissolved in
the
interior, the sudden diminution of the ionization by heating corresponding with the
abolition of the surface layer and the further gradual diminution to the
progressive
removal of the dissolved gas. The temporary restoration of the surface by the
electric discharge is attributed to a surface " double layer." V. Kohlschutter
found that when exposed to the canal rays, platinum splutters similarly to what
it does when used as cathode in the discharge tube, and the action is greater in
air
than it is in hydrogen. A. J. Dempster, and K. P. Jakovleff studied the absorption
of canal rays by platinum. S. C. Roy, J. T. Tate, and K. S. Woodcock studied
the emission of electrons by platinum. N. Piltschikoff studied the Moser rays ;
S. Matthes, the 8-radiation of platinum. The action of the so-called n-rays was
studied by E. Bichat, R. Blondlot, and J. Meyer ; and H. Mayer, alkali ions.
A. Remele noted that a heated platinum wire emits rays which will pass through
paper and affect a photographic plate. J. A. Ie Bel studied the radiations from a
heated platinum wire.
According to F. Paschen,9 and K. Siegl, when platinum is exposed to radium
rays it furnishes a secondary radiation. When small quantities of platinum are
dissolved in cone. soln. of uranium nitrate, or a radium salt, and the platinum is
separated by chemical means, it has acquired a radioactivity�induced radioactivity
�which gradually disappears. The phenomenon with radium was studied by
effect caused by the emergent beam. Thus, the ratio of the emergent photoelectric
effect to the incident photoelectric effect is greater than unity if the films are
thin enough, and with platinum the ratio is constant, 1-14 ; but for thicker films,
the ratio is less than unity. The results were confirmed by R. D. Kleeman.
J. Robinson showed that the dissymmetry is the result of two effects : (i) the
velocities of the electrons emitted, and (ii) the actual numbers of electrons
emitted.
The dissymmetry is not so marked for velocities as it is for currents. As the
thickness of the film increases through 1O-7 cm., the photoelectric effect suddenly
PLATINUM
increases ; but for films thinner than 10~7, the rate is constant, and begins to
diminish after the sudden increase in current has set in. The sudden rise in the
photoelectric effect is attributed to the increase in the energy until it is
sufficient
to ionize the molecules of platinum. The thickness of film which gives the sudden
rise in current is the same for slow and quick moving electrons. The orientation
of the plane of polarization of the light has no influence on the dissymmetry.
W. Frese noted that any treatment "which renders the metal passive reduces the
photoelectric sensitiveness. T. Pavolini discussed the subject. A. Coehn and
K. Sperling studied the action on a photographic plate. IJ. A. du Bridge, C. del
Rosario, and XJ. A. du Bridge and W. W. Roehr gave for the thermionic work
function 4*99 volts, and for the true work function 4*97 volts for photoelectric
currents excited by monochromatic light. The photoelectric threshold is 2486 A.
O. Stuhlmann studied the subject. W. H. Crew, W. Espe, and Xi. T. Jones and
V. Duran observed the emission of electrons from a platinum tube through which
hydrogen is passing ; and H. P. Walmsley, the emission of positive ions by hot
platinum. C. Davisson and L. H. Germer, R. H. !Fowler, O. Koppuis, and
H. XJ. van Velzer studied the thermionic constants ; E. D. Eastman, thermoelectric
effects, and heat capacity of electrons ; and R. Hamer gave A=2782 for
the limiting frequency of the photoelectric effect ; R. Suhrmann found the
intensity of the photoelectric current is i=l-34 x 106T2e�53610T^ j) X. Webster
studied the critical potentials ; J. B. Austin, the characteristic frequency ;
W. Bennewitz, G. Bethe, K. Herrmann, J. Kluge, K. Reger, and M. Sende and
H. Simon, the effect of adsorbed hydrogen ; B. Abendroth, and A. X. Brewer, the
effect of adsorbed hydrogen, nitrogen, ammonia, helium, and of temp. ; H. Leupold,
the effect of adsorbed ammonia ; and A. E. Woodruff, and R. F. Hanstock, the effect
of cold work on the photoelectric effect. C. Cha studied the relation between the
incident and emergent velocities of photoelectrons emitted by thin platinum films.
According to R. Ruer and E. Scharff, an anode of platinum polarized in sulphuric
acid is sensitive to light. In one case, in darkness, the e.m.f. was constant
at 0-913 volt, and after half-an-hour's exposure to daylight, 0*956 volt. G. Grube
and L. Baumeister observed that with the light from a mercury vapour lamp, using
platinized-platinum electrodes, anodically polarized, and dipping in 2iV-H2SO^,
* the nobler the initial potential, the greater was the fall in potential. This
continued
in the same direction for 15 mins. after the light had been turned off,
after which it rose again. Smooth platinum, coated with a golden-yellow oxide
by superposition of alternating current on direct current, also showed an initial
reduction of potential on exposure to light. On continued illumination, the
potential rose until it was higher than the initial value and after four successive
illuminations the total rise in potential was 0*179 volt. An electrode which had
been strongly oxidized and kept in the dark showed no decrease in potential on
exposure to light, but only a positive effect. The sensitivity of the electrode to
light is weak in potassium cyanide and still weaker in sodium hydroxide. The
action of X-rays is similar to that of light. V. Bjerkness studied the resonance
and absorptive power of platinum for electric waves ; T. Argyropoulos, and
A. Wehnelt, the oscillations of a white-hot platinum wire with a repeated makeand-
break ; X. Arons, the electric polarization of platinum films ; B. Eginitis,
voltaluminescence ; and J. W. Dobereiner, Nobili's rings. J. N. Frers studied
the combinations Pt^CuBr ; Pt-Ag2S ; Pt-Cu2S ; Pt-PbS ; Pt-MoS2 ; Pt-FeS2;
and Pt-ZnO as radio-detectors.
According to R. Nahrwold,11 air in the vicinity of a glowing platinum wire
increases in electrical conductivity; and J. Elster and H. Geitel found that in
this
way> air, coal-gas, carbon dioxide, and oxygen become positively electrified ; and
a wire heated to redness in air or oxygen becomes negatively charged. H. A. Wilson
observed that the emission of electrified particles is greater in hydrogen than it
is in air. The emission of electrified particles by hot platinum was found by
A. Wehnelt to be the same if the metal is covered with calcium or barium oxide.
INORGANIC AND THEORETICAL, CHEMISTRY
The subject was studied by M. S. Glass. G. H. Martin found that a hydrogen atm.
favours the discharge. J. A. McClelland observed that the emission of positive
ions continues up to a certain temp., and above that, at a white heat, negative
ions
are given off. Negative ions were found by A. Occhialini to be given off in intense
electrical fields. J. A. Harker and G. W. C. Kaye found that positive ions are
emitted up to 1100�, and above that temp., negative ions ; the negative ionization
in nitrogen at 40 mm. press, increases at first slowly and then more rapidly as the
temp, rises from 1350� to 1550� ; and at 1460�, by increasing the press, from O to
800 mm., the negative ionization increases at first quickly, and then more slowly.
Observations on the subject were also made by H. A: Wilson, O. W. Richardson,
K. Becquerel gave 855 when that of mercury is 100 : and with silver�100,
K. Becquerel gave 8-042 ; P. Riess, 10-4 ; A. Matthiessen, 10-53 ; and L.. Weiller,
Quite a number of formulae has been devised to represent the observed results.
The variation of the resistance with temp, was discussed by C. Barus, R. Benoit,
G. Niccolai obtained a linear relation for the resistance at temp, between �189�
and 400�, but IJ. Holborn and W. Wein found that there is a bend in the curve,
Fig. 12, corresponding with a parabolic formula. E. Hagen and H. Rubens gave
JK=O-154(l+O-OO240-f O-O5330�); CW . von Siemens, R-=^ 0034369T*+000210407T
�0-2413; H. L,. Callendar, #=0-03771T*+0-002520T�0-2450 ; F. Henning and
W. House, R=R0(I -+ 0-003969520�O-O6644O802_OO1151716504) ; R. Holm and R.
Stormer, R -0-00001048(1 +0-003695(0 �15)�O-O6598(0�15)2+O-O1O525(0 �15)3} ;
and E. Griincisen expressed his results in terms of P. Debye's function�1. 13, 16.
W. Tuijn, II. Moser, H. Rolnick, A. T. Grigorieff, G. Bainter, and J. T.
MacGregor230O
OU1UUUi
270O
190O\ g-. 40,000
X \
1700
S 1500 S 30.000\
1300
1100 SI
20.000\ \ ._.
900
� \
/ \
70O
500 / \
V^
300 Y� �
10 2OfIfL
FJO. 12. The Effect of Tempera- Fia. 13. The Resistance of Thin
ture on the !Resistance. Films of Platinum.
According to F. Streintz, the sp. resistance of platinum black of sp. gr. 11-6 is
jR=O*92(l-|--O-OO1450), a value about six and a half times as great as that of
solid
platinum, whereas the temp, coeff. is less than half of that of the solid metal. J.
Mooser
observed that the sp. resistance of samples of spluttered platinum -was 11-3, 23-1,
and 82-3 times greater than the platinum en masse, presumably owing to the
formation of oxidized films on the surfaces of the granules. J. Kramer found the
conductivity of thin films, produced by cathode spluttering or by vaporization, is
about a millionth part of that of the normal metal. R. Deaglio, H. Kahler,
decreases from /tx/x downwards. B. Pogany confirmed this, and his results are
summarized in Fig. 13. A. Riede represented the conductivity, K mhos, of films
of thickness x mgrms. per sq. cm. by K=(I-QTx--0-0005)-|-(O-13:r�0-0085).
The subject was investigated by E. Bose, R. Pohl, A. C. Longden, and J. Patterson.
H. K. Onnes gave for the ratio of the resistance, R, at T� K., to that, R0,
at 27309� K.
0K. 27309� 20-2� 14-2� 4-3� 2-3� 1-49�
HIRo � 1 00171 00135 00119 00119 OOH9
W. Tuijn, and W. Tuijn and H. K. Onnes found that platinum did not show
superconductivity
at low temp. The indications point to a zero conductivity for the
pure metal at absolute zero ; and the small constant value observed below 4-3� K.
is attributed to the presence of an impurity. The subject was discussed by
C A. Crommelin, W. J. de Haas and J. de Boer, and W. Meissner and B. Voigt.
As a rule, the temp, coeff. of the electrical conductivity of a metal is greater
the
higher the degree of purity. R. Suhrmann found that with platinum foil between
400� and 1600�, in vacuo, the resistance increases as the gas is pumped ofF, it
then
passes through a maximum and afterwards decreases. Thus, at 926�, the resistance
of platinum rose from 0-4315 to 0-4345 ohm when the metal was soaked in hydrogen,
and as the gas was pumped off, the resistance passed
successively through the stages 0-4498, 0-4506,0-4494, 07
0-4430, and 0-4280 ohm. The relation between the
� �y
r /
and Franz's rule ; F. W. Reynolds, and H. Dobrets-0-2
berger, the effect of absorbed hydrogen, nitrogen, Fia. 14.�Tho !Effect of Ocand
carbon dioxide on the high frequency resistance ; cluded Hydrogen on the
!Resistance of Platinum at
O. Feussner observed that the temp, coeff. of platinum wire generally decreases
by an amount almost within the limits of experimental error when it is subject
to mechanical stress. When a wire is passed through a drawing-plate to reduce
its cross-sectional area, a very large decrease in the temp, coeff. occurs.
P. W. Bridgman reported that the temp, coeff. between 0� and 100� of a sample
of purified platinum was 0-003905, and after being subjected to a press, of 12,000
kgrms. per sq. cm., 0*003868. P. Cohn found that the resistance of platinum wire
decreases with heating, and this the more rapidly the higher the temp., as
indicated
1OO INORGANIC AND THEORETICAL CHEMISTRY
in Fig. 15, and by increasing the drawing velocity the resistance is increased by
about 0-1 per cent. In Fig. 15, the resistance is represented by the ordinates and
the logarithm of the time, by the abscissa*. W. H. Johnson showed that an annealed
metal wire should conduct electricity better than
ISvslow
K^.
^G?
700*1
0 998 annealing at a red-heat ; E. Becquerel similarly NN. N observed the ratio 100
: 101-3 ; and O. Chwolson
\ 140� found the change with a feeble heating to be �5-3
�� 0 996
per cent., and with a strong heating +5-8 per cent. 1 Gr. W. A. Kahlbaum and E.
Sturm also showed
.so
<� 0 994
� I
^b ^ 0-98150, and after annealing at a red-heat, 0-97555,
a decrease of 0-61 per cent. A. Heintz emphasized
0 992
1 2 3 Log t
M. Ascoli observed that the resistance increased as the elastic modulus increased,
and H. Tomlinson found that the increase of resistance per unit caused by a stress
of a gram per sq. cm. is 2285 X 10~12 ; and he also studied the effect of torsion
on
the resistance ; and O. Feussner, and H. Rolnick, the effect of tension. S. Lussana
found that the resistance, R ohms, decreased with an increase of pressure, p atm.,
on the metal, so that if SR denotes the change of the resistance :
p . 1 KK) 190 3OO 39O 5OO 595 680 750
R . 5-94565 5-94422 5-94295 5-9418O 5-94093 5-94016 5-93964 5-93920 5-94886
SR . 006240 00s237 006176 005166 0O6I 18 0-Oa92 00587 OOfi82
K. Honda and co-workers studied the subject. E. D. Williamson found the ratio
of the electrical resistance at 1 kgrm. and 12,000 kgrms. per sq. cm. press, is 0-
9776.
P. W. Bridgman obtained for the press, coeff. at 0�, �78-4�, and �182-9�, and 7000
kgrms. per sq. cm. press., the respective values �0-05193, �0-05197, and �0-05234.
A. Lafay gave 8R/R= � 0-05186; E. Lissell, �005827^+0-01041j92. ana g. Lussana,
�0-O5156j0+O-Olo521j02. A. Michels and P. Geels found that at lower press, the
coeff. varies more than it does with temp. P. W. Bridgman showed that the
samples here employed -were probably contaminated with iridium. P. W. Bridgman
also gave for the fractional change in the longitudinal resistance of platinum,
1-78 XlO""6 per kgrm. per sq. cm., and for the fractional change in the transverse
resistance 0-34 X 10~6 per kgrm. per sq. cm. The press, coeff. of the sp.
resistance
found by E. Gruneisen is �0-05179 ; by P. W. Bridgman, �0-05207 ; and by
B. Beckman, 0-05150. P. W. Bridgman obtained for platinum of a high degree of
purity, with press, up to 12,000 kgrms. per sq. cm. :
0� 25� 50� 75� 100�
R l-OOOO 1-0967 1-1934 1-2901 1-3868
rms
S. Bidwell studied the relation between the resistance, R, and the thermal
expansion ; and A. Stein, the relation between the resistance and the melting-
point.
According to E. L. Nichols, if I denotes the length of platinum at temp, up to
near the m.p., then taking the values of R and I at 0�, as unity, the corresponding
than �1*140 volt. W. E. Ayrton and J. Perry observed the e.m.f. against distilled
water is �0-285 to �0-345 volt at 16-5� ; against a cone. soln. of alum, 0-246 volt
;
PLATINUM 103
against a soln. of sodium chloride of sp. gr., 1-18, �0-856 volt at 15-5� ; against
a cone. soln. of ammonium chloride, �0*057 volt ; against cone, sulphuric acid,
1-300 to 1-6OO volt ; and against cone, nitric acid, 0-672 volt. F. Bergius
observed
that the potential of copper, silver, or zinc against platinum in fuming sulphuric
acid decreases as water is added, and finally attains a constant value. KL.
Horovitz
studied the effect of the acidity of H'-ion cone, of the soln. ; and G. Tammann
and K. Bochow, the effect of adsorbed hydrogen. F. Vies and A. Ugo measured
the effect of the acidity of the soln.
�15. 68, 6, Fig. 41. F. Giordani and B. Focaccia studied the cathodic and anodic
potentials of smooth platinum in 30 per cent. soln. of potassium hydroxide.
S. B. Christy observed for 2V-, 0-12V-, and 0012V-KCy, respectively �0-40, �0-46,
and �0-50 volt ; B. Neumann, for soln. of potassium dichromate, �1-063 volt ;
dichromic acid, �1-397 volt ; sodium hydrosulphate, �0-662 volt ; potassium
ferrocyanide, �0-593 volt ; nitric acid, �1-259 volt ; and neutral ferrous
sulphate,
�0-635 volt ; and E. F. Burton, for ethyl malonate, �0054 volt ; G. Hoist, in
hydrazine ; and J. Sambussy, in nitrobenzene. P. Bechtereff observed that the
electrode potential of platinum in molten sodium hydroxide at 330� to 650� is the
same as that of iron, cobalt, nickel, gold, silver, copper, constantan, or
magnetite.
According to W. D. Bancroft, the potential of normal soln. of some depolarizers
is as follows : potassium permanganate, 1-76 volts ; chlorine in potassium
chloride,
1-67 volts; manganese dioxide in potassium chloride, 1-63 volts; bromine in
potassium bromide, 1-43 volts ; chloric acid, 1-42 volts ; dichromic acid, 1-40
volts ;
bromine in potassium hydroxide, 1-32 volts ; perchloric acid, 1-27 volts ; nitric
acid, 1-26 volts ; ferric chloride, 1-24 volts ; chlorine in potassium hydroxide,
1-19
volts ; potassium nitrate, 1-14 volts ; potassium dichromate, 1-06 volts ; and
iodine
in potassium iodide, 0-89 volts.
S. J. French and LL. Kahlenberg found that the potential of platinum in 2V-KC1
in hydrogen becomes more basic reaching a maximum and then falling off ; in
nitrogen, the potential becomes more basic, reaching a maximum, and then falling
off ; and in oxygen, the potential changes very little. Carbon monoxide, and
methane alter the potential, but helium has very little effect. B. Kamiensky
studied the potential in contact with an aq. soln. of potassium chloride and an
emulsion of potassium xanthate and turpineol. Li. Kahlenberg and J. V. Steinle
104 INORGANIC AND THEORETICAL, CHEMISTRY
to be sensitive to sound.
According to C. Fredenhagen, platinum electrodes in some oxidizing soln.
show a constant potential immediately after immersion, whilst in others it is
variable, and this indicates that the velocity of reaction of the ions of the
oxidizing
soln. with the gases absorbed by the platinum is very variable. Tn oxidation
elements, the platinum electrodes always become charged with gases ; in some
cases, the potential measured is entirely due to this gas charge, and is in no way
conditioned by the giving up of electrons from the ion of the solution to the
electrode.
The magnitude of the gas charge is dependent on the H "-ion cone, in the liquid,
but
the potential of the oxidizing agent is absolutely independent of this. N. E.
Loomis
and S. F. Acree prepared platinum electrodes for use as hydrogen electrodes in
0-1 HCl in determining the H"-ion concentration in reacting systems, in which the
deviation from the mean is less than O-l millivolt. H. D. Kirschman and co-workers,
not affected by the reaction in the cell, and this does not support the hypothesis
that an alloy is formed. H. V. Tartar and H. K. McClain referred the electrode
potential to adsorbed films ; R. D. Kleeman and co-workers, the sign of the
electrical
layer of a soln. in contact with platinum. E. R. Smith found that the e.m.f. of a
cell with the electrode reaction PtCl4"+2Cl'-PtCl6"4-2e shows reversibility ;
PLATINUM
and hydrogen from zinc and sulphuric acid, give the same value for the e.m.f. ;
and a similar result is obtained with electrolytic and chemically prepared oxygen.
The e.m.f. of an oxygen cell is diminished by the addition of platinum sulphate to
the soln., whilst that of the hydrogen cell increases�the sum of the two remaining
constant. The e.m.f. is independent of the density and temp., up to 70�, of the
gas. F. Forster observed that the potential communicated by oxygen to platinum
is characteristic of a chemical compound�a platinum oxide ; and that the e.m.f.
of hydrogen towards oxygen between platinized electrodes depends on the electrode
material. G. N. Lewis showed that the e.m.f. of the gas cell is less than
corresponds
with the formation of the water, and hence the value 1-14 volt observed
by N. T. M. Wilsmore, V. Czepinsky, and E. Bose at 25� and 1 atm. press, is too
high. The subject was discussed by R. Abegg and J. F. Spencer, K. Bennewitz
and W. Schieferdecker, S. J. French and L.. Kahlenberg, G. Grube and H. Reinharat,
charged with oxygen give a somewhat lower value, whilst a charge of hydrogen
raises the oxidation potential. The increase produced by hydrogen soon passes
away, and the electrode regains its normal value. The electrode can be freed from
either oxygen or hydrogen by a mixture of ferrous or ferric salts. The ozone gas
cells were studied by A. Brand, O. Mumm, S. Jahn, and L. Grafenberg ; oxidizing
gas cells by C. Fredcnhagen ; and the Volta effect in water vapour by E. Dubois.
According to W. R. Grove, the sequence of the e.m.ff. of platinum foil charged
with different gases, so arranged in the series that platinum charged with a given
gas is positive towards platinum charged with one of the preceding gases in the
series is : chlorine, bromine, iodine, oxygen, nitric oxide, carbon dioxide,
nitrogen,
camphor, ethereal oils, ethylene, ether, alcohol, sulphur, phosphorus, carbon
monoxide, and hydrogen. B. O. Peirce observed that the nature of the liquid
has a great influence on the e m.f. of any combination of two gases in the gas
cell.
At ordinary temp, tho relative e.m.f. with water and hydrogen and oxygen is O-874 ;
nitrous oxido, 0-790 ,- carbon diaxi<lo, 0-981 ; nitric oxide, 0-933 ; air, 0-807 ;
water,
0-807 ; and carbon monoxide, 0-404 ; with dil. sulphuric acid, and hydrogen and
oxygen,
0-926 ; hydrogen and carbon dioxide, 0-892 ; and hydrogen and nitric oxide, 0-768 ;
with
hydrogen and oxygen and a soln. of sodium sulphate, 0-698 ; in a soln. of potassium
sulphate,
0-698 ; with a soln. of zinc sulphate, and hydrogen and oxygen, 0-771 ; hydrogen
and carbon dioxide, 0-82O ; and hydrogen and nitric oxide, 0-860 ; with water and
iodine
and bromine, O-335 ; with a soln. of sodium bromide, and hydrogen and bromine, 1-
252 ;
with a soln. of potassium bromide, and hydrogen and bromine, 1-253 ; and oxygen and
bromine, O-5OO ; a soln. of potassium iodide, and oxygen and iodine, 0-057, and
hydrogen
and iodine, 0-861 ; with dil. hydrochloric acid, and hydrogen and nitric oxide, 0-
765 ;
hydrogen and oxygen, 0-855 ; and hydrogen and chlorine, 1-360 ; with a soln. of
potassium
chloride, and hydrogen and chlorine, 1-39O ; and with a soln. of sodium chloride,
and
hydrogen and chlorine, 1-390 ; oxygen, 0-760 ; carbon dioxide, 0-846 ; and nitric
oxide,
0'7SO. At a temp, between 75� and 80�, with water, and hydrogen and oxygen, 0-828 ;
nitric oxide, 0-945 ; carbon dioxide, 0-875 ; nitrous oxide, 0-780 ; and water, 0-
954.
PLATINUM
soln. of potassium chlorate, 3*5 volts, the same soln. -with sulphuric acid (13 :
6),
3-6 volts, and the same soln. with fuming hydrochloric acid (1 : 1), 3-6 volts ;
cone. soln. of potassium dichromate with sulphuric acid (10 : 3), 3*8 volts ;
fuming
nitric acid, 3*8 volts ; cone. soln. of potassium permanganate, 4*0 volts, the same
108 INORGANIC AND THEORETICAL CHEMISTRY
with sulphuric acid (10 : 3), 4-5 volts, or (55 : 50), 4-5 volts. Observations were
made by G. Oesterfeld.
rhodamine-B.
A few cases have been examined when molten compounds have been employed
as electrolyte : thus, H. Davy � employed molten lead oxide with zinc and platinum
electrodes ; M. Faraday, molten potassium chlorate or nitrate, sodium sulphate or
phosphate, lead oxide or iodide, and bismuth oxide with platinum and copper
electrodes, and molten silver nitrate or chloride with platinum and iron
electrodes.
and 0-438 for the Na-cation. A. Miolati gave 61-5 for the speed of migration
of ^[PtCl4(OH)2]" ; and P. Walden, 53-4 for [Pt(CyS)6I.
F. Haber gave 10_14� to 1O-150 for the electrolytic solution pressure of platinum;
and "B. Neumann gave 4 X 10~36 atm. F. Glaser also remarked on the high soln.
press, of platinum in soln. of potassium cyanide. E. Bose discussed the equilibrium
001 volt ; A. Thiel and E. Breuning, up to 0-0001 volt ; and J. Tafel, 007 volt
with
a current of 1 ampere. G. Carrara observed 0-02 to 0-04 volt in JV-H2SO4 and
01 volt in iV-KOH, and 010 volt in .ZV-H2SO4 in methyl alcohol, and 0-05 volt
in ethyl alcohol. F. P. Bowden and E. K. Rideal, A. Slygin and co-workers,
E. l^iebreich and W. Wiederholt, N. Koboseff and N. I. Nekrassoff, I. Zlotowsky,
A. L. Ferguson and G. M. Chen, J. A. V. Butler and G. Armstrong, F. T. Chang
and H. Wick, A. L. Ferguson and G. M. Chen, A. L. Ferguson and G. Dubpernell,
A. Frumkin and A. Schligin, S. Glasstone, W. I>. Harkins and H. 8. Adams,
G. R. Hood and F. C. Krauskoff, V. V. Ipateeff and co-workers, M. Knobel,
E. Licbreich and W. Wiederholt, F. Meunier, T. Onoda, P. P. Porfiroff,
P. Sederholm and C. Benedicks, A. Smits, and P. S. Tutundzic studied the
subject. F. Kaufler showed that the cathode at which there is an overvoltage
of hydrogen must be locally heated more than is the case with no hydrogen
overvoltage, and the superior reducing power of the former may be due to
the elevated temp. He found that benzophenone and acetophenone were not
reduced if no heating current be employed, but it did occur with a heating
current. The potential of the heated electrode is rather lower than that of the
unheated one. C. Marie studied the effect of the viscosity of the electrolyte on
the
overvoltage of hydrogen. P. Sederholm and C. Benedicks studied the effect of
curvature on the overvoltage ; H. T. Beans and L.. P. Hammett, the hydrogen
electrode ; I. Slendyk and P. Herasymenko, the separation of hydrogen from
platinum cathodes ; and P. Herasymenko and I. Slendyk studied the effect of
INORGANIC AND THEORETICAL, CHEMISTRY
no
connected with the formation of platinum oxides or hydroxides, and not with
passivity. G. Armstrong and co-workers studied the subject. K. Bornemann
found that platinum electrodes in A^H2SO4 with hydrogen dioxide furnish a
curve with a break at 1-20 to 1*22 volts, and with electrodes which have been
heated to redness, at 1-06 to 1-08 volts. A. Mazzucchelli and C. Barbero also
investigated
the potential with soln. of hydrogen dioxide ; and O. Mumm, and F. Forster,
the potential of ozone formation. The decomposition voltage curve of hydrochloric
acid was discussed by E. Miijler, R. Luther and F. J. Brislee, and E. Bose.
According
to G. Pfleiderer, when a dil. soln. of hydrochloric acid is electrolyzed with
fresh platinum anodes, and the current is kept constant, the potential rises
gradually
from 1-4 volts to about 1-9 volts, when oxygen is given off freely. The oxidation
of the platinum may be due to the influence of hypochlorous acid formed by the
action of chlorine on the water. Both oxygen and chlorine are formed, and the
formation of oxygen can be regarded as a secondary phenomenon : 2Cl2*-f-2H20
�4ClH-J-O2 ; and D. Macaluso also studied the behaviour of platinum in a soln.
PLATINUM
of chlorine in hydrochloric acid. A. Coehn and Y. Osaka found that with a soln. of
potassium hydroxide, cooled by a freezing mixture, much ozone is evolved with a
platinum anode at 3 volts. W. Kettembeil observed a break in the decomposition
curve at 1*32 volts. G. Armstrong and co-workers studied the subject. A. Coehn
and St. Jahn studied the phenomenon with soln. sat. with carbon dioxide ;
According to H. Draper, the polarization increases about 1 per cent, for a rise of
temperature of 4�. The subject was investigated by T. R. Robinson, R. Abegg,
F. Exner, A. Bartoli, A. de la Rive, W. Beetz, J. C. Poggendorff, and F. M. Raoult.
R. Tholdte found that the polarization decreases as the size of the electrodes is
reduced
until it attains a constant value. The subject was studied by A. Bartoli, E. Lenz,
W. Andauer, and C. Fromme. The effect of the concentration of the electrolyte was
examined by E. Bouty, C. Fromme, and J. M. Gaugain ; and the rate of the reaction
with hydrogen on the cathode, by L. P. Uammett. E. Lenz observed that with the
same current density, the polarization decreased with increasing cone, of sulphuric
acid ; and A. Bartoli, that the addition of glycerol lessened the polarization.
The nature of the surface of the electrodes was found by J. C. Poggendorff to be
such that with smooth platinum electrodes, the maximum polarization was 2-12
to 2*33 volts, and with platinized platinum, 1*83 to 1-85 volts. The subject was
studied by C. Fromme, J. Roszkowsky, E. E. Zimmerman, J. Tafel, E. Brunner,
and A. Friessner. H. J. T. Ellingham discussed the behaviour of nitric acid at a
platinum cathode.
C. F. Schonbein noted that in the electrolysis of water with an anode of smooth
platinum and a cathode of platinized platinum gas is developed less vigorously
than when the electrodes are reversed. R. Luther noted that with ozone, the
oxidation
potential with plain electrodes is larger than it is with platinized electrodes.
The subject was discussed by F. Forster, and F. Forster and E. Muller. The
comparison of the two electrodes in the electrolysis of alkali chloride soln. was
made by F. Haber, H. Wohlwill, R. Lorenz and H. Wehrlin, F. Forster and
E. Muller, E. Muller, F. Winteler, W. Oechsli, and A. Biiltemann ; the
electrooxidation
of ammonium sulphate was studied by A. Biiltemann ; the reduction of
formaldehyde alkaline soln., by A. Bringhenti ; the electrolysis of formic acid, by
V. V. Pitcheta said that the potential at platinum anodes during the passage of a
current depends on the formation of a film of mol. oxygen, or suboxide. When
the current is broken, the potential depends on the accumulation of at. oxygen.
The behaviour of an anode depends on its previous history, and reproducible results
can be obtained only under strictly uniform conditions. The subject was discussed
by L. Arons, A. Bartoli, W. Beetz, M. Ie Blanc, E. du Bois-Reymond, F. P. Bowden,
J. A. V. Butler and G. Armstrong, J. Daniel, H. Dufour, F. Exner, C Fromme,
W. L. Hildburgh, T. P. Hoar, H. Luggin, D. Macaluso, C. Matteucci, G. Meissner,
T. A. L. du Moncel, J. L. R. Morgan and co-workers, E. Muller, E. Muller and
F. Spitzer, W. Nernst and A. M. Scott, K. Ochs, N. Piltschikoff, J. C. Poggendorff,
not 0*4 to 0*6 as observed by F. Forster. The results are explained by the
interaction
of the surface of the electrode with the gas generated in the process of
electrolysis, the metal suffering a change from which it recovers only after some
time ; the question of whether an oxide of platinum or a solid soln. of the gas in
platinum is formed is an open one. J. A. V. Butler and G. Drever observed that
platinum is anodically polarized in acidic and alkaline soln., and an adsorbed
layer
of oxygen is formed prior to the establishment of the oxygen overvoltage, but, as
in the case of iridium, there is no evidence of a slow formation of oxides of a
peroxidic character such as occurs with palladium and rhodium.
electrically active, but has a smaller oxygen press, than the gas itself. The
passivity
of platinum was discussed by G. Grube, R. Ruer, V. V. Picheta, W. J. Muller and
O. Hering, G. C. Schmidt, E. Grave, F. Forster and J. Yamaski, J. Steiner and
VOL. xvi. i
11 4 INORGANIC AND THEORETICAL. CHEMISTRY
^/
r
r
0-25 \HCI �with the flat part of the wire. R. Luther and
Cl2"-ions are present in the soln. and that these Ii 0 20 HCI __ ^y ions are in
equilibrium with the Cl'-ions, and
the exhaustion of these ions is responsible for
the constant value of the current strength.
The condition of the platinum anode is the
iv T
k
k
O 10 HCI _
// ^y
Kio. 16.�Anodic Potential�Cur- strength may fall away rapidly almost to zero,
rent Curves of Tiydrorvhlorio Acid. the electrode having become ** passive." If,
curve cannot now be obtained. This passive condition is due to a superficial change
of the platinum anode, and has nothing to do with the solution. It disappears
allowed to fall below 1�6 volts, a passive electrode becomes spontaneously active.
the passive condition does not set in. There are thus three states of the platinum
surface. The production of the passive condition does not depend on the presence
of Cl'-ions, but begins in acid solutions at about 1*9 volts and vanishes at about
1-6 volts.
but rather of a platinum oxide ; and C. M.Gordon and F. E. Clark,that the capacity
of a platinum electrode is conditioned by a film of oxide. G. Lippmann said that
the discharge of hydrogen or oxygen from a platinum plate in electrolysis does not
PLATINUM
and O. M. Lammert studied the quinhydrone electrode with platinum and platinum
alloys.
A. P. SokolofF. F. Giordani and B. Focaecia, and P. Schoop found that with soln.
of calcium chloride the electrode acquires cracks and pores, but when the platinum
is alloyed with 10 per cent, of iridium, the metal is stable. R. Ruer observed the
disintegrations of platinum electrodes in the electrolysis of nitric acid by an
alternating
current, owing to the alternate oxidation and reduction of the metal. The
subject was discussed by P. Burger. W. D. Bancroft and J. E. Magoffin studied
the energy changes in the electrolysis of sulphuric acid.
The attack of platinum anodes in the direct current electrolysis of dil. sulphuric
acid was observed by K. Arndt,1 6 G. Grube and co-workers, A. Brochet and J. Petit,
M. Margules, J. Tafel and B. Emmert, and G. Senter ; hydrochloric acid, and soln.
of chlorides, by W. H. Wahl, F. Haber, F. Bran, II. C. P. Weber, C. Marie,
"E. H. Archibald, M. Margules, F. Schulz, and A. Nobis ; ammonia, ammonium
salts, and potash lye, by E. Reichel ; ammoniacal nitrate soln., by A. Thiel ;
nitric
acid, by M. Margules ; soln. of sulphides, by W. Schulte, F. W. Durkee, W.
Klapproth,
and H. Ost and W. Klapproth ; soln. of cyanides, by T. WiIm, F. Reichel,
A. Fischer, L.. Eisner, R. Ruer, F. Glaser, A. Brochet and J. Petit, and F. M.
Perkin ;
soln. of ammonium acetate and chrome-alum, by C Engels ; phosphoric acid,
formic acid, and acetic acids, but not oxalic acid, by M. Margules ; and alkali
hydroxides, by G. Janeczek, M. Margules, P. BechterefF, and E. A. Bourgoin ;
molten potassium nitrate, by W. Hittorf; molten potassium carbonate, by T. Gross;
molten lead chloride, by M. Faraday ; and molten potassium uranium hexachloride,
by J. Aloy. The attack of platinum electrodes in the alternating current
electrolysis
of dil. sulphuric acid was studied by R. Ruer, A. Brochet and J. Petit, M.
Margules,
and W. J. Muller ; in hydrochloric acid, by P. Burger, and M. Margules ; in nitric
acid, by H. J. T. Ellingham, M. Margules, and P. Burger ; in soln. of alkali
hydroxides, by M. Margules ; in sodium phosphate soln., and phosphoric acid, by
M. Margules, and E. Drechsel ; in soln. of sulphides, by F. W. Durkee ; and in
soln. of ammonium carbonate and carbamate, by E. Drechsel, and B. Gerdes ;
and A. Brochet and J. Petit, in soln. of cyanides.
The electrolysis of sulphuric acid by alternating currents with platinum
electrodes, was studied by P. Burger, F. Kruger, and D. Reichinstein ; and of
nitric acid, by T. Gross, and H. Danneel ; and the polarization of electrodes with
alternating currents, by S. Glasstone, and N. Isgarischeft and S. Berkmann.
Rotating platinum electrodes were used by F. Fischer and co-workers in the
preparation of ozone.
Platinum electrodes "were used in the formation of ammonia by E. Briner and
at 20� and 60�, respectively, 0-68 to 0-53 volt and 0-69 to 0-59 volt and current
density 8 X 10~~4 amp. per sq. cm. C. W. Keitel used a bath of a 10 per cent. soln.
of ammonium sulphate or nitrate with 5 per cent, free ammonia, and 2 per cent,
of platinous diamminonitrite, replenishing the ammonia and nitrate as required.
The bath is operated at 95�, with 2-2 volts. C. W. Keitel and H. E. Zschiegner used
a bath prepared by boiling platinous chloride with sodium nitrite until the soln.
is
yellow or colourless, and then adding an excess of ammonia. T. Erdey-Gruz and
H. Wick, and C. Marie and N. Thon made observations on the subject. F. Kohlrausch
found that chlorine is given off at the anode, and both hydrogen and platinum
appear at the cathode. It is, however, doubtful if platinum is the primary product
of the electrolysis. An aq. soln. of platinic chloride gave on electrolysis with
weak
currents, hydrogen alone at the cathode, no platinum separating, and at the anode
oxygen was obtained. With stronger currents, a deposit of platinum appears on the
cathode and oxygen at the anode. The author regards the depositions of platinum
in the last case as due to secondary action, and suggests that platinic chloride
exists
in solution as H2PtCl4O, 'with the ions H2 and PtCl4O. The secondary deposition
of platinum may be due to the reaction 2H2+3H2PtCl4O=Pt+2H2PtCl6+3H2O as
the solution gradually changes to one of hydrogen platinochloride. The platinum
cathode becomes bent during the passage of the current, perhaps owing to occlusion
of the hydrogen taking place with contraction in volume. G. Grube and co-workers
observed fine-grained deposits of platinum are produced when a soln. of O-IMH2PtCl2
per sq. cm., and the current yield is 60 to 7O per cent. At the anode, dissolution
of platinum begins at E�\ volt ; chlorine begins to be evolved at 1*2 to 1*4 volts.
W. Hittorf said that the platinum deposited electrolytically from a soln. of alkali
T. Yoshida, and the Platinum Plating Co. used a bath of alkali phosphatoplatinate
�say G. Nikolaus' recipe : where the electrolyte is a boiling soln. of 4 grms. of
platinic chloride, 2O grms. of ammonium phosphate ; 90 grms. of sodium phosphate ;
and 5 grms. of sodium chloride per litre. The article to be plated should be kept
in motion, and a potential difference of 6 to 8 volts employed. P. Jewreinoff, and
W. H. Wahl employed a bath of alkali oxalatoplatinate ; T. WiIm, F. Glaser,
A. Fischer, and H. Freudenberg employed a bath containing cyanide soln. ; and
R. Bottger, and W. C. Arzen, a soln. of ammonium chloroplatinate and sodium
citrate. The subject was discussed by M. Baum, R. Bottger, A. Church, D. Clerk
and C. A. Fawsitt, J. B. A. Dode, H. Elkington, L. l'Hote, T. Howse, J. H. Johnson,
precipitate, after filtering and washing, in more ammonia. The bath is made up
by dissolving 1OO grms. of ammonium nitrate or sulphate in a litre of distilled
water
containing 5 per cent, of ammonia, adding 2O grms. of the solid plating salt, and
heating. It is worked at 95� and is quite stable. It is kept ammoniacal, and
more salt is added as is necessary. H. S. Booth and M. Merlub-Sobel deposited
platinum from soln. of salts in liquid ammonia. R. H. Atkinson studied the
electrolytic transfer of the metal using fused chlorides as electrolytes ; G. G
rube
and co-workers discussed the subject. In the electrolysis of soln. of platinum
chloride containing cerous chloride, A. B. Schiotz found that platinum alone is
deposited. M. Prasad and N. B. Choksey studied the effect of a magnetic field.
C. Sandonnini and V. N. Borghello observed no action occurred on electrolyzing
carbon tetrachloride with IO per cent, sulphuric acid and a platinum anode, but
with a lead anode dehalogenization occurred.
J. Plticker 1 8 noted the spluttering of platinum from the cathode in a discharge
118 INORGANJC AND THEORETICAL, CHEMISTRY
tube ; and G. Granquist found that at 0*6 mm. press., platinum splutters more
easily than gold. The loss in weight is independent of the temp. W. Crookes
observed that the loss in weight from an electrode weighing 10-1940 grms. was
2*0370 grms. in 24 hrs. ; F. Ehrenhaft said that the radius of the spluttered
particles
is 4*4 XlO-6 to 14-7 X 10~6 cm. With a pressure approximating 0*4 mm., and a
current of 0-0006 amp., and voltage JS, L. Holborn and L. Austin found the losses
in weight in 30 mins., under comparable conditions, to be :
Air Hydrogen
, * , , * ,
R. Defregger, in helium, 168 volts with platinized platinum, and 160 volts with
smooth platinum; by H. Dember, 165 volts in helium with a highly polished platinum
wire, and 163 volts in argon ; by J. W. Capstick, 369 volts in oxygen ; and by
G. Bode, 320 to 340 volts in chlorine ; 376 to 414 volts in bromine ; and 38O to
430 volts in iodine. Observations were made by H. Rohmann, O. Klemperer,
C. A. Skinner, W. Matthies, F. Miiller, O. W. Richardson, H. P. Waran, F.
Deininger,
and J. A. Cunningham. C. del Rosario investigated the low press, discharge.
F. W. Aston discussed the effect of platinum on Crookes' dark space ; L. Tonks,
anchoring the cathode spot ; and A. Janitzky, the effect o, occluded gas in the
anode.
According to W. R. Grove,20 after silver and gold, the arc discharge of platinum
furnishes the shortest and darkest arc-light of all the metals tried. E. Leccher
found that between horizontal platinum electrodes, 5 mm. in diameter, and 2 mm.
apart, the difference of potential is 35 volts. L. Arons gave 30 volts for a
current
of 4*5 amps, in nitrogen at atm. press, with the electrodes 1*5 mm. apart.
V. Li. Chrisler studied the platinum arc in air ; A. J. Dempster, the emission of
positive ions ; and S. Virtel, the properties of particles from the electric arc.
Observations were made by C. E. Guye and co-workers, W. B. Nottingham,
H. W. Malcom and H. T. Simon, H. E. Ives, and J. Stark. According to A. Simek
and H. Kadlcova, drops of molten tellurium dioxide move from the negative to
the positive pole on the surface of hot platinum.
T. J. Seebeck2 1 represented platinum in the thermoelectric series between
palladium and rhodium, and J. P. Emmet observed that a current flows from warm
PLATINUM 119
platinum to the cold metal when in contact with antimony, arsenic, platinum,
copper, silver, lead, tin, zinc, mercury, iron, nickel, gold, and bismuth.
Observations
on the subject were made by J. Gumming, W. G. Hankel, P. O. C. Vorssel-
mann-de-Heer, H. Rohmann, W. Rollmann, A. Abt, J. M. Gaugain, N. F. Mott, and
and an unstretched wire, a current flows through the hot junction from the
stretched to the unstretched wire�Lord Kelvin added that this occurs only if the
stretching is permanent ; and E. Wagner found that a compressed wire gives a
thermoelectric force against an uncompressed wire, amounting at 58�, and a
press, of a kgrm. per sq. cm., to 0-010186 volt per degree. P. W. Bridgman observed
and the results with one sample of purified platinum against lead were E X10�
= �30920�00133402 volts; and with another specimen, E X10� �� 1*7880
�G-Ol7302 +O-O4420a volts. K. Tsuruta studied the effect of longitudinal tension ;
G. Tammann, and G. Tammann and G. Bandel, the effect of cold work. V. B. Lewes
observed that molten platinum heated in the oxy-hydrogen flame gives a greater
thermoelectric current than does the molten metal near the m.p. C G. Knott,
and J. Monckman observed that a thermoelectric current flows through the hot
junction from non-hydrogenized to hydrogenized platinum. W. Ende, and G. Meyer
studied the effect of striction ; and J. L. Hoorweg, the effect of different kinds
of
platinum. J. Wiirschmidt, and G. K. Burgess and P. 13. Sale determined the purity
of the platinum by determinations of its thermoelectric force. R. M. Holmes
measured the thermoelectric force of these couples. F. Jenkin observed a
thermoelectric
current between platinum and platinum covered with copper oxide ; and
R. Bunsen, with platinum and pyrolusite, or platinum and copper pyrites.
E. Heiber measured the thermoelectric force of platinum against the solid
alkali metals�Li, Na, K, Rb, and Cs. H. C. Barker found that for a temp, difference
W. Jager and H. Diesselhorst gave 0*38 millivolt at 100� for the thermoelectric
force of the platinum-aluminium couple ; J. Dewar and J. A. Fleming gave 0-40 ;
PLATINUM 121
100� ; J. Dewar and J. A. Fleming, 0-45 ; K. Noll, 0-40 ; W. H. Steele, 0-41 ; and
E. Wagner, 0-44 millivolt. Lord Kelvin gave 44� for the neutral point. A. V.
Tidblom
measured the thermoelectric force of some tin-zinc alloys against platinum.
For the platinum-lead couple, W. Jager and H. Diesselhorst gave 041 millivolt ;
J. Dewar and J. A. Fleming, 0-44 millivolt ; K. Noll, 0-41 ; and E. Wagner, 0-46
millivolt. J. Buchanan gave �85� for the neutral point ; and M. Avanarius gave
J0=O-O85(0i� 02)+O-OO46(0;i�O2)*. Lord Kelvin gave 36� for the neutral point.
Observations on lead were also made by P. G. Tait, G. G. de Metz, E. Becquerel,
and A. V. Tidblom, and on some lead-zinc and lead-tin alloys by A. V. Tidblom,
J. Dewar and J. A. Fleming gave for lead for temp, between 0� and 0�, in c.g.s.
units ;
0 . 99-9� 33-2� 11-6� -j-21-9� �90-2� �135-1� �181� -205-6�
E . �29,630 �6,83O � 2,080 +2,8OO �3,52O �4,15O �19,22() � 30,930
W. H. Steele gave 4-70 millivolts at 100� for the thermoelectric force of the
'platinum-antimony couple; and observations were made by A. V. Tidblom.
W. Jager and H. Diesselhorst gave �6*52 millivolts at 100� for the platinum-bismuth
and for the thermoelectric force of platinum against the other platinum metals,
vide infra.
A. Walcker, and L. Nobili observed that in cold water hot platinum is positive
against cold platinum, also in sulphuric acid (1 : 2), in soln. of sodium chloride
(1 : 10 and 1 : 100), but negative in soda lye. F. C. Henrici said that the hot
metal
is positive in soln. of sulphuric or nitric acid, ammonium chloride, potassium
iodide,
cupric chloride, mercuric nitrate, stannic chloride, and ferric chloride or
sulphate ;
and negative in "water, hydrochloric acid, potassium hydroxide, chlorate, carbonate
sulphate, acetic acid, oxalic acid, very dil. soln. of sulphuric or nitric acid,
barium
chloride, mercuric chloride, manganous chloride, and potassium ferrocyanide.
Observations were made by M. Faraday, A. Voller, H. Wild, A. C. Becquerel, Gr.
Gore,
B. Kaniewsky, and R. Kremann and co-workers. E. Bouty studied the thermoelectric
force of platinum against platinic chloride. The thermoelectric force against
some fused salts and glass "was studied by R. Bottger, T. Andrews, and W. G.
Hankel.
The Peltier effect was studied by E. Edlund,2 2 and H. Jahn. A. E. Caswell
gave 0-85. P. W. Bridgman measured the Peltier effect, JP X 106 joules per coulomb,
with platinum, uncompressed metal and metal compressed at p kgrms. per sq. cm.,
and found :
and nitric acids, and soln. of sodium chloride and potassium bromide and sulphate.
According to O. Berg, the Thomson effect is negative, and changes only a little
with temp., and he found that crXl06=8-79 to 9-69. Lord Kelvin observed that
the heat flows from the warmer to the colder parts in the direction of the current.
H. Alterthum found that the curve representing the Hall effect at different temp,
has a minimum between 83� and 194�. H. B. Peacock obtained for thin films
�0-000130 at 18�. Observations were made by P. Raethjen, A. Riede, A. K. Chapman,
M. Cantone, and E. Bossa. H. Zahn gave �21 X 10-� for Lieduc's effect, and
A. K. Chapman studied the Carbino effect.
PLATINUM 123
Ordinary platinum contains much occluded gas which is very difficult to remove.
A. Berliner 3 estimated that the metal contains roughly 80 vols, of occluded gas.
Platinum freed from occluded gases can be readily recharged with gas. L. Mond
and co-workers found that platinum foil at ordinary temp, gives off very little
gas, but at dull redness it gives up 0-4 times its vol. of gas�chiefly carbon
dioxide.
33. Delachanal observed :
H8 CH4 CO CO2 N2
144 grms. I*t . 3-65 0-47 4-05 O-7O 1-31�10-20 c.c
146 grms. Pt-Ir 8-65 0-87 3-60 0-60 108 9-80 o.c
150 grms. of platinum black occluded 17 c.c. of gas�15*3 c.c. were absorbed by
potash lye, and the remainder was incombustible. D. Tommasi gave for the
absorption coefr. 1*75 for hydrogen, 9-35 for oxygen, 9-42 for sulphur dioxide,
and 65-00 for carbon monoxide. J. L�. Smith found that air condenses on smooth
platinum as a film which can be removed by polishing. C. Zengelis observed
that when hydrogen is passed into a liquid in which platinum is immersed, the
metal adsorbs hydrogen.
o-ooo
These results compared with those for nickel are represented by the curves in
Fig. 17. T. Graham observed that at a red-heat platinum absorbs hydrogen and
drogen
sorbs m
M. von Pirani and A. R. Meyer found drawn platinum does not take up hydrogen
at a red-heat. When platinum is heated to a high temp, in hydrogen, the m.p. is
depressed 250� to 300�, and the metal becomes brittle. The effect is not due to
the occlusion of hydrogen but rather to the presence of a small quantity of a
carbonaceous impurity in the hydrogen from which, at or near its m.p., the metal
takes carbon. A. Si everts and W. Krumbhaar showed that molten platinum probably
dissolves hydrogen.
T. Graham also found that when platinum is used as the cathode in the electrolysis
of water, it can take up as much as 2-19 vols, of hydrogen which is given up
at a red-heat in vacuo, or when the hydrogenized metal is used as anode in the
electrolytic cell. F. Winteler observed that when spongy platinum is used as
cathode, some of the absorbed gas is given off when the circuit is broken. The
absorption of electrolytic hydrogen was studied by H. Schlesinger, L. Cailletet
and E. Collardeau, A. E. Freeman, E. Root, J. Eggert, M. A. Schirmann, and
J. R. Partington.
According to A. Sieverts and E. Jurisch, the absorption of hydrogen by compact
platinum at a high temp, is probably a case of simple dissolution, but in the case
of platinum black, chemical changes supervene. M. W. Travers, and W. Heald
studied the absorption of hydrogen by platinum obtained by cathodic spluttering,
and R. Burstein and A. Frumkin, by platinized charcoal. G. Neumann and
F. Streintz observed that platinum black takes up 49-3O times its vol. of hydrogen,
and G. Neumann, 63-14 to 77-14 vols. L. Mond and co-workers found that under
reduced press, platinum black absorbs a certain vol. of hydrogen, and more is
absorbed as the press, is raised to 200 or 30O mm., and a further increase of
press,
is almost without effect since by increasing the press, from 1 atm. to 4� atm.,
only one more vol. of hydrogen is absorbed. About 310 vols, of hydrogen are
absorbed per unit vol. of platinum black, and of this, 200 vols, are converted by
the absorbed oxygen into water, so that only 110 vols, are really occluded by the
platinum. Part of the hydrogen can be removed at ordinary temp, in vacuo, and
by far the larger proportion at about 250� to 300�, but a red-heat is necessary for
its
complete removal. The amount of hydrogen absorbed by platinum is very largely
influenced by slight traces of impurity. E. Muller and K. Schwabe observed that
the quantity of occluded hydrogen depends on the temp, of formation of the metal
from its oxide ; on the method of preparing the oxide, and on the rate at which
the hydrogen is brought in contact with the metal. The freshly-prepared metal
can absorb more hydrogen than is the case with the metal which has been kept
for some time. L. Mond and co-workers also observed that platinum sponge
obtained by heating platinum black to redness has a greater absorption power
than platinum sponge made by heating ammonium chloroplatinate. A. do Hemptinne
also noted that platinum black which has been heated to 180� suffers a reduction
of absorptive power. H. S. Taylor and R. M. Burns found that the number
of vols, of hydrogen taken up by 1 vol. of
25� 110� 218�
A. F. Benton said that it was here assumed that the absorbed hydrogen is all
removed at 110� in vacuo ; actually, more than half the absorbed hydrogen is
retained by the metal under these conditions. He gave 36*7 vols, as the average
absorption by 1 vol. of platinum black at 25� and 1 atm. press. H. S. Taylor
and R. M. Burns noted that the absorption power depends on the mode of preparation
and is less pronounced the higher the temp, of preparation. R. Burstein and
A. Frumkin studied the absorption of hydrogen by platinized charcoal. E. Muller
and K. Schwabe observed that the platinum can adsorb initially more hydrogen than
is the case if the metal has been degassed before it is allowed to re-adsorb the
gas.
E. B. Maxted's results on the effect of age on the absorption are summarized in
PLATINUM
Fig. 18. A. Sieverts and H. Bruning's curve for the speed of absorption of hydrogen
40.000
30.000
20,000
)c~~
Y/ 6
70,000
Cals. Li. Mond and co-workers could not confirm this result. The decrease in the
values is connected with the union of the hydrogen with the oxygen already
occluded by the metal. They gave 68-8 Cals. per gram of hydrogen, or 137-6 Cals.
per mol of hydrogen. According to E. B. Maxted, the differential heat of adsorption
rises from a low value to a maximum, and finally decreases with further
adsorption. The results for two specimens are summarized in Fig. 19. II. S. Taylor
22\
S
~%>20
g 18 II �
M ,7
�
_ P*
"_'-nf
� �
�
-_ � J
790\
20 40 6O 80 8 10 18
Fio. 19.
Time
Rates
in
of
minutes
Absorption of Fio. 2O.
Temp. 0~7x JOO
Rates of Approach to
Hydrogen. E qui I i br ium.
and IX. M. Burns obtained curves which exhibited no maximum, but gradually
decreased with an increase in the adsorption concentration ; and E. 13. Maxted
and N. Hassid found that the differential heat of adsorption on platinum is
nearly constant between 13,300 and 17,50O cals. ; the heat of desorption also was
nearly constant between �15,0OO and �19,1OO cals. G. B. Taylor and co-workers
gave 20,(XX) cals. (approx.) for the heat of adsorption of hydrogen. The subject
was studied by E. W. Flosdorf and G. B. Kistiakowsky, P. A. Favre, and
A. Montier.
A. de Hemptinne found that platinum black absorbs less hydrogen at �78�
than it does at 15�, and if the absorption tube at �78� be allowed to regain a
higher
temp., a marked absorption of gas occurs at about �40�. Freshly-prepared
platinum black has a great absorptive power even at the temp, of liquid air�it
can induce the union of hydrogen and oxygen at �190�. A. Gutbier observed a
small maximum in the absorption curve at 0�. E. Harbeck and G. Lunge said
that when platinum black saturated with hydrogen is cooled from 250�, it takes
up the same amount of hydrogen as was given off in raising the temp. H. Baerwald
found platinized asbestos absorbs more hydrogen at the temp, of liquid air than it
does at room temp. F. H. Pollard also made some observations on the absorptive
power of platinized asbestos. The gas molecules which bombard the metal are
partly absorbed and partly reflected. The molecules which make non-elastic
3 40 INORGANIC AND THEORETICAL, CHEMISTRY
collision will be adsorbed if the energy developed does not exceed that of the
attraction force of the surface molecules. M. Knudsen, and F. Soddy and
A. J. Berry measured what has been called the accommodation coeff. or the energy
of exchange between hydrogen and platinum and obtained 0*24 at room temp., and
0-25 at �75�. H. H. Rowley and K. F. Bonhoffer obtained 0-22 at room temp.,
and 0*37 at �163�. The result with parahydrogen was 10 per cent, smaller at
�133�, and at �93�, 15 per cent, smaller than for ordinary hydrogen.
N. L. Koboseff and W. L. Anochin studied the subject. A. Sieverts and H. Briining
observed that 2*017 grms. of platinum black, prepared by reduction with
formaldehyde,
and occupying 0-094 c.c, at 752 mm., absorbed, at 20�, the vols, of hydrogen
per vol. of platinum black indicated in Fig. 21. The results with platinum black,
45 32
3O ^*N
S43 I"
^39
GO ^ \
\ g 22
-5 20 \
18
\ \ I
33
obtained by reduction with magnesium, for lower temp., are represented by the
upper curve, Fig. 22, and there is a break in the curve at about 0�. The lower
curve was obtained on a rising temp, with platinum black, obtained by reduction
with magnesium, and degasified in vacuo at 200�, and hydrogen introduced at
�120��first under reduced press, and finally at atm. press. The temp, was
then slowly raised 20� every half-hour up to 100�, and then cooled again to �120�.
The absorption curve obtained is indicated in Fig. 23. The absorption isotherms
were studied by W. G. Palmer.
i" 27
r
0 31
� ^. �
I"�
�s W
s,
^23 e �-2\
U�5?n 11�*
I
S 19
;^� J i 0-1
% ,
UM
^ /7|-/
I jg[c (aye
15
8
A. F. Benton observed that for pressures, p mm., the vol. of gas, c.c. at n.p. 0,
absorbed by 4-269 of grms. of platinum black :
11 23-5 67-8 162-4 393-4 577 768 mm. Vol. H 8 606 6-36 6-83 6-97 712 7-21 7-35 c.c.
A. Sieverts and H. Bruning's results for the effect of press, on the absorption at
different temp, are summarized by the curves, Fig. 25, with platinum reduced by
magnesium ; the dotted curves represent the results with platinum black reduced
PLATINUM
per 16 grms. oxygen, from which it may be deduced that 1 grm. of hydrogen
142 INORGANIC AND THEORETICAL CHEMISTRY
absorbed by spongy platinum and capable of being oxidized in the cold by free
oxygen, evolves 9-5 CaIs. Platinum black prepared by reducing a soln. of a platinum
salt with formic acid, does not evolve any gas when heated to 500� or 600� in
vacuo, 62-255 grms. of the platinu mblack absorbed 0-0342 grm. hydrogen in the
cold, with evolution of 14-2 cals. per grm. of hydrogen absorbed, and formation
of two hydrides : in vacuo this loses 23 c.c. or 0-02 grm. hydrogen, and on passing
oxygen over it, the increase of weight is 0*0765 grm. with development of 51-6
Cals.
hydride, which is not oxidized by oxygen in the cold. This hydride is decomposed
by gradually heating it to the temp, at which glass softens. The heat of formation
of the less stable hydride is -f-8-7 Cals., H= I grm., that of the more stable
being
nearly double, or +17 Cals. The proportion of the total weight of hydrogen
oxygen possibly as suboxide. The hydrogen absorbed is used partly in the reduc
tion'of the oxide, partly in the formation of hydride. The absorption of hydrogen
in this case is attended with the evolution of -f-12 Cals. per grm. of gas
absorbed,
but a small quantity of water is formed at the same time. Of the hydrogen absorbed,
of absorption were made by P. A. Favre, but E. Rothe did not think the results
were accurate. H. S. Taylor, E. Waldburger, L. P. Hammett and A. E. Loreh,
platinum, and hence inferred that the platinum black had a surface area of 1*3 X
IO6
sq. cm. per c.c, or 6-0 sq. metres per gram. The subject was discussed by A.
Eucken,
and M. Polanyi. E. Muller and K. Schwabe observed that of the hydrogen adsorbed
by reduced platinum, 53 to 69 per cent, is irreversibly absorbed (indicating
chemical
combination) and the remainder is reversibly absorbed (indicating molecular
penetration in the lattice or simple soln.). P. Anderson showed that hydrogen
just removed from hydrogenized platinum is more chemically active than ordinary
hydrogen in reducing copper oxide, and sulphur. S. Roginsky, and C. Y. Meng
and co-workers studied the ionization of hydrogen gas in contact with platinum ;
formation of larger metal crystals, a loosening of the texture of the metal, and a
diminution in contact between the individual crystal surfaces. II. Damianovich
noted the change in the microstructure of platinum after exposure to the electric
discharge in hydrogen. K. F. Bonhoeffer and co-workers, and P. H. Emmett and
or is previously " fixed '* by means of hydrogen, the platinum is poisoned and
desorption of acid is incomplete. Reduction of adsorbed oxygen by means of
hydrogen is also inhibited under similar conditions. Mercuric chloride influences
only slightly the development of a hydrogen potential by oxygen-free charcoal.
144 INORGANIC AND THEORETICAL CHEMISTRY
R. !Lucas said that purified platinum does not absorb oxygen, but platinum
containing
iridium does not do so with activated oxygen. R. Schwarz and W. Kunzer
found that an oxide is formed. F. E. Carter said that the finely-divided metal,
in oxygen, begins to form black platinum monoxide at 450�, that this oxide at
500� forms platinum and its dioxide, and that the dioxide at 500� furnishes
platinum and oxygen. According to E. K. Rideal and O. H. W. Jones, the loss in
weight of a platinum wire heated electrically, to 1400� K. to 1900� K., in a glass
bulb immersed in liquid air, is greater in oxygen than in vacuo. This is in
agreement
with the observations of R. Nahrwold, G. Owen, W. Stewart, and J. Elster
and H. Geitel. E. K. Rideal and O. H. W. Jones infer that two reactions are
involved : (i) a surface reaction between the platinum and oxygen at a rate which
is directly proportional to the press., pt of the oxygen ; and (ii) a reaction
which
occurs simultaneously between the platinum vapour and the oxygen. The combined
effect is represented by the equation�dp/dt=a-\-bp, where a and b are constants.
Below 1700� K., and above that temp, when p is less than 5O bars, the second
reaction : Pt+O2=^ PtO2, predominates. I. Liangmuir suggested that the alteration
in the speed of the reaction at high press, and temp, is due to the concentration
of
ozone, or of oxygen atoms, but E. K. Rideal and O. H. W. Jones consider this
to be less likely than the hypothesis of a surface reaction. H. H. Rowley and
of platinum sponge at a red-heat absorbed respectively 2-4, and 0-5 vol. of oxygen.
found that 1 vol. of platinum sponge absorbed 1*90, 2*80, and 4*30 vols, of oxygen,
respectively, at 25�, 110�, and 218� ; and platinum black, 26*50 and 26-10 vols.
PLATIlTOM
O 35 65 8O 96 1IO minutes
Time
C. Paal and C. Amberger observed that colloidal platinum readily takes up oxygen
from the air, and the elementary hydrosol is not regenerated when the sol is
treated
with hydrogen.
W. W. Randall found that oxygen does not diffuse through heated platinum ;
but. A. Li. Ferguson and G. Dubpernell discussed the transfer of electrolytic
oxygen
IUVl
1 90
770i
�^
80
70 I rrrr. S
�I 60 /
^ 50 /
� 4O
S 30
1~
.a io
� tI\/
L \
I � � 1
100 200� 300" 400� 500� 600� 70(
Fm. 26.--THe Rate of Approach, to FIG. 27. The Evolution of Oxygen from
Kquilibrium.
through the metal. J. Thomsen observed that the affinity of platinum for oxygen
is small. According to I. Langmuir, a platinum filament at temperatures above
1600� K. gradually causes the removal of oxygen at low pressures. The oxygen
combines with the platinum atoms as fast as they evaporate from the filament,
and forms the dioxide, which collects on the bulb as a brown deposit. G. B. Taylor
and co-workers gave approximately 65,000 cals. for the heat of adsorption ;
and E. B. Maxted and N. J. Hassid, 60,0OO cals. per gram mol. of oxygen.
H. St. C. Deville and H. Debray said that platinum is never found as a mineral
associated with oxygen ; T. WiIm noted that platinum obtained by the ignition
of the ammines or ammonium salts at a red-heat in air is not oxidized ; and no
sign of oxidation occurs when platinum sponge is heated to redness in air.
H. Ie Chatelier added that under suitable conditions of temp, or press., the metal
may be oxidized. Y. Okayama studied the subject. W. Skey noted that the
surface of the metal exposed to air liberates iodine from a dil. soln. of potassium
iodide in dil. sulphuric acid ; J. L. Smith also noted the condensation of air on
the
surfaces of platinum crucibles. According to W. Skey, platinum whieh has been
" in contact for a short time with distilled water, ammoniated water, or with
aq. soln. of the alkalies, carbonates or chlorides," will not amalgamate. Acids,
on heating to about 200�, restore the amalgamable condition ; and G. Mcissner,
H. Humpelt, and B. Dessau showed that a film can be detected optically on
platinum heated in air or oxygen�vide supra, the volatilization of platinum.
H. Damianovich noted a change in the microstructure of platinum after exposure
to the electric discharge in oxygen. A. Fery studied the effect of adsorbed oxygen
on the electrical resistance.
VOL,, xvi. i*
146 INORGANIC AND THEORETICAL, CHEMISTRY
The heat developed during the occlusion of oxygen by platinum was found by
L. Mond and co-workers to be ll-O cals. per gram of oxygen, and since this is
almost
the same as the value given by J. Thomsen for the heat of formation of platinous
hydroxide, the two phenomena may be related, the necessary water being present
in platinum black dried in vacuo. They finally concluded that the occlusion of
oxygen by platinum or palladium is a true oxidation phenomenon. According
to Ja. Wohler, and C. Engler and L. Wohler, platinum black containing occluded
oxygen turns potassium iodide starch solution blue ; it is somewhat soluble in
dilute hydrochloric acid, the weight of platinum in solution is less than the
weight
of platinum black dissolved, and if the difference be attributed to oxygen it is
found that the ratio of platinum to oxygen agrees well with PtO ; the amount of
oxide present in the platinum sponge depends on the state of division. It does not
easily amalgamate, and the amalgam formed becomes covered with a film of the
black oxide ; hydrogen dioxide does not reduce it in the cold, but on boiling,
complete
reduction takes place, and it is also reduced by alcohol, ether, and other
organic substances ; in absence of air, it oxidizes arsenious to arsenic acid, and
the
residue loses its spongy character and becomes granular. It is further shown that
the properties of active platinum sponge closely resemble those of platinous oxide,
R. Vondracek also inferred that platinum black contains a very labile compound
of platinum and oxygen ; and E. Goldstein, that in the electrical discharge in
oxygen with platinum electrodes, a compound of platinum and oxygen is formed,
that the absorption of oxygen is very rapid if the electrodes are at a high temp.,
and that the faculty of platinum to form these oxides is connected with its
catalytic
activities. P. Lafntte and P. Grandadam found that platinum is oxidized when
heated between 300� and 500� at 50 to 200 kilogrms. per sq. cm. press. At the
optimum temp., 455�, spongy platinum at 4 atm. press, increased in weight
2-1 per cent. ; and at 150 atm. press., 7*37 per cent., and platinum black
increased
13*96 per cent. The product is a mixture of platinum monoxide and dioxide.
F. C. Phillips also noted that the order of the oxidizability of the platinum
metals is connected with their faculty of burning hydrogen�namely, osmium,
palladium, platinum, and iridium.
Platinum black containing occluded oxygen was found by J. W. Ddbereiner 5
to exert an action on hydrogen and other combustible gases or vapours whereby
the metal may be heated to redness, and if air has access, the gases may be set
on fire. If air or oxygen has not access, the oxidation ceases as soon as the
occluded
oxygen is consumed, but if air or oxygen has access, the platinum black takes up
more oxygen, and transfers it to the combustible body so that the process is
continuous.
The subject was discussed by A. Adie, W. Artus, A. Baudrimont,
A. C. Becquerel, M. Berthelot, M. Bodenstein, R. Bottger, M. C. Boswell and
C. H. Bayley, C. Brunner, G. L. Cabot, H. Courcot and J. Meunier, W. Davies,
J. W. Dobereiner, F. P. DuIk, P. L,. Dulong and L.. T. Thenard, A. Fyfe,
L,. W. Gilbert, F. Gill, C. A. Gruel, G. F. Hanle, H. Karmarsch, W. Klinkerfues,
W. Knop, J. von Liebig, G. Merryweather, G. Merz, C. F. Mohr, F. Parmentier,
C. H. Pfaff, M. V. Poljakoff and co-workers, P. W. Schmidt, C. F. Schonbein,
J. S. C. Schweigger, H. A. von Vogel, A. Wagner, E. O. Wiig, and T. WiIm.
A. Osawa found that the arrangement of the atoms in the lattice of platinum black
is not changed by the adsorption of oxygen, but there is a linear expansion of
2-9 per cent. The inflammation of hydrogen was described by A. Garden,
C. G. Gmelin, W. Herapath, and A. Pleischl ; of alcohol, or ether vapour, by
S. F. Dana, K. Fuchs, H. B. Miller, and G. Schiibler ; and the self-ignition of
coal
PLATINUM
and O. F. F. Nicola.
The oxide theory of catalysis assumes that the platinum forms an unstable
oxide which is alternately reduced and re-oxidized ^Pt-J-O2-PtnO2 ;
PtwOa-r-2H2==2H20-f-wPt ; or PtnO2H-H2=PtnH-H2O2, and PtnO2H 2H2O2
=wPt-|-2H2 H-SO2, M. Traube8 supposed that ^Pt +WH 2O2=PtnO^+ mH20~
is followed by PtnOTO+mH202===nPt-|-mH2OH-m02, and E. Oliveri-Mandala
said that M. Traube's hypothesis does not explain the catalysis of ammonium
nitrite, hydrazine, hydrazoic acid, and hydroxylamine ; and he assumed that
the catalyst reacts with water, forming an oxide, and hydrogen. The subject was
discussed by F. D. Aguirreche, T. Bayley, B. Batscha, G. Bodliinder, J. Boeseken
and co-workers, E. Bose, M. C. Boswell and R. R. McLaughlin, G. Bredig and
co-workers, J. W. Dobereiner, J. Elster and H. Geitel, T. J. Fairley, W. French,
A. de Gregorio y Rocasolano, that the activity of the sol increases with age to a
maximum and then decreases. W. Spring noted that polished platinum decomposes
hydrogen dioxide, and R. C. Smith found that washing the surface with alcohol
and water, or the presence of a film of grease, inhibits the decomposition. The
change in the surface from amorphous to crystalline also decreases the catalytic
activity, as in the case observed by Gr. Vavon. The catalytic effect with compact
platinum was studied by A. von Bayer and V. Villiger, K. Bornemann, H. Damianovich
and O. F. F. Nicola, T. S. Glikman, A. de Gregorio y Rocasolano, F. Haber
and S. Grindberg, V. Henri, H. Heymann, A. Kailan, G. R. Levi, E. B. Maxtcd
and co-workers, A. R. Miro and N. G. Morales, E. Oliveri-Mandala, M. V. PolyakofT
and co-workers, F. Richarz, A. Rius, V. A. Roiter and M. G. Leperson, R. Schwarz
and W. Friedrich, I. I. Shukoff and co-workers, A. Sieverts and H. Briining,
J. Sirkin and V. G. Vassileeff, R. C. Smith, S. Tanatar, J. Teletoff, M. Traube,
I. I. Tschukoff and co-workers,F. Weigert, R. Wolff, and R. Wright and R. C. Smith;
with platinum black, and spongy platinum, by H. von Euler, M. A. Heath and
J. TT. Walton, A. Sieverts and J. F. Miiller, J. Weiss, and L. Wohler ; -with
colloidal
platinum, by G. Bredig and co-workers, Y. K. Suirkin and I. N. Godneff,
A. Lebedew, N. E. Ditman, L. Licbermann and W.von Genersich, and E. B.Spear�
O. Paal and C. Amberger placed the colloids in the decreasing order of activity :
Os, Pd, Pt, and Ir ; the poisoning of the catalytic activity was studied by
G. Bredig and co-workers, F. Bock, 13. Gernez, A. S. Loevenhart and J. H. Kastle,
O. H. Neil son and O. H. Brown, H. V. Tartar and N. K. Schaffer, G. Bredig and
W. Reinders, C. Engler and L. Wohler, J. H. Kastle and C. R. Smith, A. S.
Loevenhart
and J. H. Kastle, T. S. Price and co-workers, C. F. Schonbein, and L. Wohler.
acts on spongy platinum to form platinous chloride, and the reaction was studied
by Li. Pigeon. C. Nogareda found that chlorine forms a unimolecular adsorption
layer, and that the attack by chlorine molecules between 600� and 850� furnishes
PtCl4 ; above 1200�, the attack is by chlorine atoms. G. Gore observed that when
silver chloride is melted in a platinum crucible in an atmosphere of chlorine, the
metal is attacked ; and H. Erdmann and O. Hauser found that platinum is attacked
when heated with chlorides of the alkalies or alkaline earths in a bunsen flame.
For G. Gore's observations on the action of chlorine and silver fluoride, vide
supra.
C. F. Schonbein also observed that aq. soln. of chlorine attack the metal
liberating
oxygen ; and that platinum black decomposes chlorine water catalytically with
the evolution of oxygen. S. Cooke noted that platinum charged with hydrogen
acts on chlorine to form hydrogen chloride ; O. Ruff and H. Krug observed no
action with the metal in contact with chlorine trifluoride.
W. R. Hodgkinson and F. K. S. Lowndes observed that a red-hot platinum
wire in hydrogen chloride is attacked ; and W. L. Dudley showed that hydrogen
chloride in the presence of air or oxygen readily attacks platinum. P. Perotti,
and H. SohifT noted that platinum favours the union of hydrogen and chlorine
electrolytic gas ; and the thermal decomposition of hydrogen chloride in the
presence of platinum was discussed by W. Weldon ; M. Berthelot observed no
action at 550� ; and M. G. Levi and O. Garavini observed that the decomposition
occurs at 800� to 1100� in the presence of platinum, and at 1500�, without
platinum.
According to F. C. Carter, platinum is not attacked by hot or cold cone,
hydrochloric
acid, but T. WiIm, W. L. Dudley, and H. St. C. Deville and J. S. Stas found
that precipitated platinum is soluble in hot, cone, hydrochloric acid in the
presence
of air ; and C. Engler and L. Wohler found that dil. hydrochloric acid partially
dissolves platinum black in the absence of air, but if the metal is freed from
occluded
oxygen, it no longer dissolves. L. Wohler found that finely-divided platinum, in
an atmosphere of carbon dioxide freed from air, is slightly soluble in cone,
hydrochloric
acid when heated in a sealed tube at 200�. M. Berthelot found that fuming
hydrochloric acid does not attack platinum in darkness, but the metal is attacked
if exposed to light, and in the presence of manganese dioxide, twice as much
platinum is dissolved as in its absence. H. Kinder observed that when iron is
deposited electrolytically on platinum, and treated with hydrochloric acid, some
platinum passes into soln. with the iron. J. W. Mallet, and C. Matignon found
that the metal is slowly attacked by hydrochloric acid in the presence of air,
forming, according to A. M. Vasileff, hydrochloroplatinic acid ; E. Salkowsky
found that the attack is favoured by hydrogen dioxide. According to P. Rudnick
and R. D. Cooke, unignited platinum black dissolves in cone, hydrochloric acid in
the presence of hydrogen dioxide yielding hydrochloroplatinic acid free from
nitrogen
compounds. H. E. Patten could detect no appreciable action of a soln. of
hydrogen chloride in chloroform, carbon tetrachloride, ethyl chloride, benzene,
silicon tetrachloride, stannic chloride, phosphorus trichloride, antimony
pentachloride,
sulphur monochloride, and thionyl chloride, and with the soln. in arsenic
trichloride no greater action was observed than with arsenic trichloride alone.
According to C. A. Peters, when a soln. of sodium chloride rests on mercury
with a platinum wire connecting both liquids, mercurous chloride and sodium
hydroxide are produced. C. Marie observed that an acidic soln. of potassium
chlorate slowly attacks platinum. CF . Schonbein found that in the presence of
platinum black, hypochlorous acid decomposes with the evolution of oxygen, and
F. Forster and E. Miiller represented the reaction : HC10=HCl-f-0, accompanied
by 3HClO =HC103+2HC1, and by HClOH-HCl=H2O-f-Cl2. E. Schaer noted that
the oxidation of some organic substances by this acid is favoured by the presence
of colloidal platinum. S. Cooke observed that hydrogenized platinum reduces
soln. of potassium hypochlorite to the chloride. W. C. Bray found that platinized
platinum favours the decomposition of chlorine dioxide : 6ClO2+3H2O=SHClO8
4-HC1. C. F. Schonbein observed that a soln. of indigo-blue is decolorized by
PLATINUM
aq. soln. of chloric add in the presence of platinum black, and similarly with an
aq. soln. of perchloric acid. E. V. Zappi recommended a mixture of chloric acid
and cone, hydrochloric acid as a solvent for platinum�the activity of the mixture
is due to the liberation of chlorine : HClO3-J-5HC1=3Cl2 -4-3H2O. According to
of the press. ; and the term bp is due to the formation of PtI2 by the attack of
the phosphorus layer by iodine atoms at a rate proportional to the press, of
the iodine vapour. The rate of formation of PtI2 rapidly becomes negligible
in comparison with that of PtI. Below a certain critical press, the surface of
the metal is bare, and the formation of PtI becomes a reaction of the first
order. The reaction was studied by L. Jacobs and H. K. Whalley, C. Nogareda,
Cr. E. Pringle and G. van Praagh, and G. van Praagh. L. Wohler, and C. Engler
152 INORGANIC AND THEORETICAL, CHEMISTRY
and Li. Wohler noted that a small quantity of iodine is absorbed by platinum
black from O012V-soln. of iodine. W. R. Hodgkinson and F. K. S. Lowndes
observed that with a red-hot platinum wire in the vapour of iodine chloride,
platinous chloride, and traces of the iodide are formed. W. Engelhardt found
no action occurs between colloidal platinum and iodine. W. Pullinger observed
that platinum is attacked by a soln. of iodine. For G. Gore's observations on
the action of iodine and silver fluoride, vide supra. M. Bodenstein and V. Meyer
noted the union of hydrogen and iodine is favoured by hot platinized asbestos.
liberates iodine in the presence of platinous black, but not so with neutral soln.
of
potassium iodide ; on the other hand, L. Wohler observed that in air, on a
waterbath,
iodine is slowly liberated by platinum black from a neutral soln. of potassium
iodide. The platinum black loses this property if it has been preheated to a high
temp. If the platinum black is freed from occluded gases it has no action on soln.
of potassium iodide, but it becomes active if it be exposed to air anew. W. Skey
noted that platinum loses its power of liberating iodide from potassium iodide
soln.
by calcination, or by washing with ammonia or alkaline soln., and it becomes
active again if it be exposed to air, or digested with hydrochloric or sulphuric
acid�hot or cold. G. Just observed that platinum foil which has been dipped in
a soln. of potassium ferricyanide and thoroughly washed, can liberate iodine from
a soln. of potassium iodide. H. Danneel observed that if a soln. of hydriodic acid
be shaken with finely-divided platinum and silver, in an atmosphere of hydrogen,
silver iodide is formed. The reaction is reversible. H. S. Taylor studied the
decomposition
of potassium iodide on platinum surfaces. A. Connell observed that
iodic acid has no action on platinum, and C. F. Schonbein found that a soln. of
indigo-blue is decolorized by iodic acid or by a soln. of potassium iodate in the
presence of platinum black at ordinary temp., and O. Loew and K. Aso, that
potassium iodate is reduced to iodide by glucose and platinum black. G. Lemoine
studied the catalytic effect of platinum on the reaction between iodic and oxalic
acids. E. Schaer noted that the oxidation of some organic substances by the iodates
salts.
T. Graham (1868) thought it possible that when a metal adsorbs a film of gas,
the gas molecules are orientated in such a way that the same parts of the molecules
are all in direct contact with the metal, and the other parts are exposed to the
gas.
According to I. Langmuir (1916), the adsorbed layer is unimolecular in thickness,
and generally orientated. The poisoning of a solid catalyst is then due to the
formation of films of molecules of the " poison gas " on the catalyst, which
prevent
the adsorption of gases which would otherwise react on the surface of the catalyst.
so that the atoms of the molecule are loosened or partially separated ; and (ii),
in the atomic distortion theory, the affinity is supposed to be weakened by the
disturbing
effect of the catalyst on the intra-atomic, electronic orbits of the atoms.
The adsorption of one or both the reacting gases by the catalyst may occur
in different ways�e.g. a diatomic gas may be adsorbed so that it forms a molecular
or an atomic layer or both. The molecular distortion may mean that the
molecule is attached (adsorbed) at more than one point on the catalyst, so that the
A catalyst may exert a very specific action so that the catalyst directs the
reaction in one direction in preference to another. This is exemplified by
-^ H2O-I-CO
Ethyl alcohol in the presence of nickel decomposes into acetaldehyde and hydrogen ;
O 2U 6OIi^ 0 3 ^ C2H4H-H2O
presence of a mixture of zinc and chromium oxides at 300� to 358� ; and chiefly
(Cu H.COH
CO + wHjJ ' Cr2O3
(Ni CH4-HH2O
Again, the presence of "water vapour favours the oxidation of carbon monoxide ;
the union of hydrogen and oxygen ; the union of the hydrogen and chlorine ; and
the union of hydrogen chloride and ammonia. In fact, if these gases be intensely
dried, the reactions may not occur under ^conditions where the moist gases readily
combine. The catalyst is here supposed to act by a cycle or chain of reactions,
say : CO-J-H2O=CO2+H2 ; followed by : 2H2 + 02=2H20. At high temperatures,
the reaction : 2CO+O2 = 2CO2, may proceed directly. On the other
hand, a catalyst may retard the progress of a reaction, and it is then called a
negative catalyst. Thus, K. Than (1864) found that the presence of water vapour
retards the decomposition of ammonia ; W. A. Shenstone (1887), that dry ozone
at 0� decomposes 30 times as rapidly as the moist gas at 26-4� ; and H. G. van de
Stadt (1893), that moisture retards the oxidation of phosphorus.
The presence of certain impurities may reduce the chemical activity of the
catalyst resulting in what is metaphorically called a poisoning of the catalyst.
E. Turner (1823), M. Faraday (1834), and W. C. Henry (1836), for example, noticed
that finely-divided platinum becomes less active in stimulating the reaction
between
hydrogen and oxygen if certain foreign gases are present�the presence of carbon
monoxide, and ethylene act as inhibitors of the reaction. Again, the oxidation of
sulphur dioxide in the presence of a catalyst was not successful commercially until
it was found that the reacting gases must first be freed from arsenical compounds
which poison the catalyst ; sulphur compounds also act as poisons in the synthesis
of ammonia, and in hydrogenation processes. The poison is thought to act by
being preferentially adsorbed on the surface of the catalyst.
In some cases, the activity of a catalyst is enhanced by admixture with another
catalyst so that the activity of the mixture is greater than the sum of the
activities
of the individual constituents. This is the so-called promotor action. For example,
mediate compound formed by the catalyst, or the catalyst may favour the
decomposition
of the intermediate compound formed by the promotor.
A. Orlowsky 1 3 found that the affinity of sulphur for platinum is quite small.
C. Ridolfi observed that no sulphide is formed by the direct action of sulphur.
E. Davy observed that some platinum sulphide is formed when the metal is heated
with sulphur ; and G. Preuner observed that the action is not particularly strong
even between 950� and 1240�. A. Wigand found that the metal acquires a dark
brown film in boiling sulphur. W. C. Heraeus and W. Geibel, and W. R. Hodgkinson
and F. K. S. Lowndes, observed that sulphur vapour had no perceptible action on
an electrically heated platinum wire. A. Jedele observed that sulphur has a
limited solubility in platinum, and that the effect of sulphur on the yield point
and fracture, in kgrms. per sq. mm., and the percentage elongation at room
temp., and at 850�, are indicated in Table II. J. Milbauer found that platinum
TABLE II.�THE EITBCT OF STTI/PHTJIC ON TITE TENACITY OF PLATINUM.
and there is a very slight corrosion after many hours' exposure at 150�, but after
many days' heating at this temp., crystals of platinic chloride are formed.
H. St. C. Deville and J. S. Stas observed that platinum black, precipitated by
formic acid, is fairly soluble in boiling sulphuric acid, and M. Delepine, that
some
platinum vessels are attacked by boiling sulphuric acid, whilst others are not
attacked unless the acid contains nitrous fumes in soln. According to F. C. Carter,
platinum is attacked by hot sulphuric acid but not by the cold acid. A. Scheurer-
Kestner showed that the dissolution of platinum in boiling sulphuric acid is a
true solution process, and is not dependent on oxidation. Under similar conditions,
1000 kgrms. The solubility was greater if the sulphuric acid contained nitrous
fumes in soln. ; and if the metal was alloyed with iridium, the resistance to
attack
was greater. E. Hartmann and F. Benker discussed this subject. C. Marie observed
that the presence of potassium sulphate accelerates the attack by sulphuric acid ;
L. R. W. McCay, that the presence of sulphurous acid or of antimony trioxide
or arsenic trioxide, retards the attack ; and A. H. Allen, that sulphuric acid
containing
potassium permanganate does not attack platinum. Owing to the reducing
action of ammonium sulphate, M. Delepine found that platinum does not lose
weight when boiled in sulphuric acid containing ammonium compounds, and the
contrary result by J. T. Conroy was obtained at a lower temp. The reducing
action is symbolized : 4H2S04-f-Pt=Pt(S04)2H-2S02-h4H20 ; and 3Pt(S04)2
+2(NH4)2S04=2N2+3Pt+8H2S04. L. Wohler found that dil. sulphuric acid
dissolves the minutest trace of platinum black, but leaves spongy platinum
untouched ; W. C. Heraeus gave for the solubility of platinum in 94 per cent,
acid, 0-6 grm. per ton, and in 97 per cent, acid, 2-O grms. per ton. The time the
metal is exposed to the acid and the surface area of the metal should be stated.
J. T. Conroy found that in 28 hrs. 0*04 grm. was dissolved by 95 per cent,
sulphuric
acid at 250� to 260�. R. H. Adie observed no formation of sulphur dioxide or
hydrogen sulphide with warm (200�) or cold, cone, sulphuric acid. According
to M. Delepine, 1 sq. dm. of platinum foil, lOyx to 20/x thick, during an hour's
PLATINUM
exposure to sulphuric acid containing potassium sulphate lost weight at the rate
of 0-008 to 0-012 grm. per hour. At 350� to 355�, and a mixture of 5O grms.
sulphuric
acid and 10 grms. of potassium sulphate, the loss is 0-04 to 0-05 grm. ; and
with a mixture of 50 grms. of sulphuric acid and 2O grms. of potassium sulphate,
the loss at 365� to 370� amounted to 0-12 to 0-13 grm. With sulphuric acid
containing
in soln.
extent as the more dilute acid in the presence of oxygen. Expressing solubilities
in grams of metal dissolved per sq. decimetre per hour, 94 per cent, sulphuric
acid,
and commercial platinum 0-001 grm. in vacuo, and 0-124 grm. in oxygen ; "with
purified platinum, the data were, respectively, 0-0006 and O-0227 grm. ; and
sulphuric acid with 2 per cent, of free sulphur trioxide dissolves 0-0265 grm. of
platinum in vacuo. E. Salkowsky observed no acceleration in the attack by dil.
sulphuric acid in the presence of hydrogen dioxide. K. W. Frolieh observed that
whilst platinum is rarer than gold when it is in contact with sulphuric acid at
ordinary temp., the case is reversed above 200�, as
illustrated in Eig. 28, which gives the e.m.f. of the 350%
millivolts against the Hg2Cl2 | Hg electrode at dif300\
ferent
temp. H. St. C. Deville and H. Debray 250
observed that cast platinum vessels resist boiling 200\� \ ---f> -sulphuric
acid better than those made from malleable I '
156 f/
,5
in Concentrated Sulphuric
W. W. Randall said that nitrogen does not diffuse through heated platinum.
E. J. B. Willey studied the activation of nitrogen in the presence of platinum.
F. Wolfers found that nitrogen in the presence of nickel forms nickel nitride,
which
then attacks the platinum between 300� and 600�, and makes the metal brittle.
H. Damianovich and G. Berraz studied the action of nitrogen at a low press,
and exposed to an electric discharge. B. Delachanal observed that commercial
platinum occludes 0-36 to G-91 c.c. of nitrogen per 100 grms. of metal ; H.
Dobretsberger,
the effect of absorbed nitrogen on the high-frequency resistance of
platinum ; A. Fery, the effect of nitrogen on the electrical resistance ; and
H. Damianovich, the action on the rate of dissolution in aqua regia. S. H. Bastow
said that in the absorption of nitrogen by films of platinum, where the metal is
presumed to be in the atomic state of subdivision, as the temp, is raised, the
nitrogen is given off. The adsorbed nitrogen reacts with hydrogen or water to
form ammonia, so that it is assumed that PtN2 is formed. F. Wolfers observed
that nitrogen acts on platinum in the presence of nickel, presumably a volatile
nickel nitride is formed at about 300�, and that then attacks platinum at 600�
making it brittle. Hence nickel-platinum thermocouples should not be used above
500�. Li. Wohler, O. Loew, and E. J. Russell and N. Smith discussed the oxidation
of atm. nitrogen in air in the presence of alkaline soln. and platinum black to
form
nitrous acid or ammonium nitrite. G. T. Beilby and G. G. Henderson found that
if platinum be heated in ammonia to 800�, the surface of the metal is darkened,
and dulled, and under the microscope has a bubbly appearance. The surface film
can be rubbed off with filter paper ; the frictional electricity of the metal is
reduced ;
and the electrical resistance is increased. W. C. Heraeus observed no perceptible
change in a platinum wire heated in ammonia for half an hour at 1500�. The
formation of ammonia by passing a mixture of hydrogen and nitrogen over
spongy platinum at a dull red-heat, and in other ways, was discussed by
L. Brunei and P. Woog, J. K. Dixon, G. S. Johnson, P. Jolibois and F. Olmer,
F. Kuhlmann, O. Loew, W. Nernst and F. Jost, H. S. Taylor, L. Wohler,
L. T. Wright, and J. Y. Yee and P. H. Emmett�vide 8. 49, 15 ; the retarding
or poisoning effects of acetylene, phosphine, and hydrogen sulphide were studied
by J. Y. Yee and P. H. Emmett ; the oxidation of ammonia by the action of
oxygen in the presence of spongy platinum or platinum black, by L. E. Adaduroff
and co-workers, E. A. Arnold and R. E. Burk, V. I. Atroshchenko,
G. T. Beilby and G. G. Henderson, A. K. Brewer, E. Decarriere, J. W. Dobereiner,
L�. Duparc and co-workers, W. Frankenberger and co-workers, S. L. Handforth
and J. N. Tilley, W. Hennel, W. Henry, A. Klages, K. Kraut, A. !Luyckx,
D. Meneghini, L. Mond and co-workers, A. A. Noyes and G. V. Sammet, W. Ostwald
and E. Bauer, J. R. Partington, P. Pascal and E. Decarriere, N. A. Figurovsky,
W. Reinders and A. Cats, O. Schmidt and R. Bocker, C. F. Schonbein,
PLATINUM
acid, and of alkali and ammonium nitrites, by platinum black was studied by
A. A. Blanchard, S. Cooke, O. Flaschner, O. Loew, J. Meyer and E. Triitzner, and
H. N. Warren. R. Vondracek suggested that the decomposition of ammonium
nitrite by platinum black proceeds in two stages : firstly, the platinum black,
which, to begin with, contains oxygen, oxidizes the ammonium nitrite, thus :
2NH4N02+5cPtOn-fyH20=N2-f-2HN02+a;Pt+(2/-|-3)H20, and, secondly, the
nitrous acid formed in the first stage is reduced by the platinum, which is now
oxygen-free, thus : 2nHN02-hasPt=nN2+^H2O H-Pt^On. L. Wohler found that
nitric acid does not dissolve platinum black. C. Marie observed that warm, cone.
160 INORGANIC AND THEORETICAL CHEMISTRY
nitric acid slowly attacks platinum, and F. M. Gavrilofif studied the solubility of
platinum alloyed with silver in this acid. T. Gross noted that platinum is attacked
in a platinum crucible. The reduction of nitric acid, and of alkali and ammonium
nitrates, was studied by S. Cooke, J. H. Gladstone, J. H. K as tie and E. EIv ove,
A. Muckle and F. Wohler found that aqua regia does not dissolve all the platinum
from an iridium-platinum alloy�much remains associated with undissolved
iridium ; and J. W. Mallet also observed that platinum-iridium alloys strongly
resist the action of aqua regia. C. Claus found that of the platinum metals,
palladium
dissolves most readily in aqua regia and platinum comes next. The other
metals in a compact state do not dissolve in this acid. C. Reinhardt said that in
these cases it is best to alloy the metal with zinc, digest the alloy in cold
hydrochloric
acid of sp. gr. 1-142, and dissolve the residue in aqua regia.
According to E. Davy,1 7 phosphorus combines -with spongy platinum in an
evacuated tube considerably below a red-heat ; the union is attended by flame
and vivid incandescence, and platinum phosphide is formed which F. W. Clarke
and O. T. Joslin represent by Pt3P5. A. Granger observed that the vapour of
phosphorus
attacks finely-divided platinum at 500� ; W. C. Heraeus gave 600� for
the temp, of formation of phosphide with compact platinum ; and W. R. Hodgkinson
and F. K. S. Lowndes found that a red-hot platinum wire is immediately
destroyed by phosphorus vapour. W. Biltz and co-workers studied the equilibrium
diagram, with the compounds PtP2 and Pt20IV A. Jedele observed that the
platinum phosphides�Pt2P, PtP, and Pt3P5�are very sparingly soluble in the
metal, and the effect of phosphorus on the yield point and fracture in kgrms. per
sq. mm., and the percentage elongation at room temp., and at 850� are indicated
in Table III. H. W. Melville and E. B. Ludlam studied the catalytic effect of
platinum on the oxidation of phosphorus. H. Ie Chatelier noted that platinum
thermocouples are spoilt by the vapours of phosphorus. C. F. Schonbein found
platinum black makes dry phosphorus at �5� luminesce ; and H. W. Melville and
JEJ. B. Ludlam studied the catalytic oxidation of the vapour of phosphorus by plati
PLATINUM
r
per cent.
Yield Fracture Elongation Yield Fracture TCluiigatioii
0-26 21-4 2R-9 4-75
0-105 16-8 23-5 11-3 � 0-
025 16-3 21-4 19-4 -0-
005 13-9 20-9 11-9
0-003 10-4 13-9 14-2 3-6 4-2 6-2
0-001 12-2 14-9 24-9 6-2 7-9 6 1
O-0OO 8-7 14-8 27 1 5-1 6-9 OO
represented the reaction with compact platinum POl5 +Pt ^-POl3+Pt Cl2
observed that in a mixture of hydrogen and carbon monoxide, the former gas is
oxidized in the presence of platinum black more rapidly than the latter. The
subject was studied by W. Davies. H. B. Dixon found that dry carbon monoxide
is completely oxidized in the presence of dry oxygen and a glowing platinum
wire. M. Traube noted that some hydrogen dioxide is formed when moist carbon
monoxide is oxidized in the presence of platinum. J. J. Coquillion studied the
action of platinum on a mixture of water vapour and carbon monoxide. E. von
Meyer, and M. Faraday noted that carbon monoxide retards the activity of
platinum on a mixture of hydrogen and oxygen. P. Sabatier and J. B. Senderens
observed that platinum below 420� does not induce the hydrogenization
of carbon monoxide to methane. The reaction was studied by E. F. Armstrong
and T. P. Hilditch. G. O. Kemp observed that in the presence of platinum,
carbon monoxide is oxidized by nitrous oxide forming nitrogen and carbon
dioxide. A. BaikofE found that the platinum thermocouple, in a gas flame,
disturbs the equilibrium of the gases. F. Fischer and co-workers compared the
activity of the platinum metals in the hydrogenation of carbon monoxide to
methane ; and V. Voorhees and R. Adams, the platinum oxides with platinum
black. A. Gutbier and W. Schieferdecker studied the action of hydrogen on
carbon dioxide in the presence of platinum. According to P. Schiitzenberger, and
with platinum black, respectively, 7*70 and 6-00 vols, of gas per vol. of metal are
absorbed. M. Faraday noted that, like carbon monoxide, ethylene retards the
activity of platinum in a mixture of hydrogen and oxygen. V. N. Morris and
164 INORGANIC AND THEORETICAL, CHEMISTRY
Ja. H. Reyerson, and Li. H. Reyerson and L. E. Swearingen studied the adsorption
20, C2H4 and in C6H6 at 80�, but not at room temp. The increase in weight which
occurs when platinum crucibles are heated in coal-gas was observed by T. WiIm,
F. Mylius and C. Huttner, and A. Remont ; and observations on the subject were
also made by S. Kern, P. Schutzenberger and A. Colson, A. Colson, C. L. Berthollet,
H. JDebray observed that when potassium cyanide is heated with platinum black,
at 500� to 600�, the main reaction is symbolized : 4KCy+2H 2O+Pt=K 2PtCy 4
+2KOH+H 2 ; and a boiling, cone. soln. of potassium cyanide attacks the metal,
forming the same complex salt. H. Rossler observed no action with aq. soln. of
potassium cyanide on platinum ; and A. Brochet and J. Petit observed that in
the cold the solubility of platinum is nil, but dissolution commences at about
100�. According to F. Glaser, the dissolution of platinum does not occur when
mercury is being electrodeposited from potassium cyanide soln. containing
sulphuric acid, potassium sulphate, hydrocyanic acid or ammonium cyanide when
the temp, is low, say 15� to 20�, and the current is weak. The dissolution of
platinum
in soln. of potassium cyanide occurs at a higher temp., say 25� to 30�. Platinum
dissolves in soln. of potassium cyanide in the absence of oxygen, and hydrogen
is evolved. The solubility is very small in the cold, but is increased by a rise of
temp., or by the presence of sodium or potassium amalgam. L�. Wohler observed
that with platinum black the solubility is favoured by oxygen, or hydrogen dioxide.
H. St. C. Deville and H. Debray found that mercury is not precipitated by platinum
from a boiling aq. soln. of mercuric cyanide, but if a little potassium cyanide is
X>resent, mercury is deposited and it combines with the platinum. C. Marie observed
cally oxidized in the presence of platinum. Water retards the activity of the
catalyst on the alkoxides. An e.m.f. is developed when electrodes of platinized
and smooth platinum are dipped in an alcoholic soln. of sodium alkoxide. M. Tauber
studied the voltaic potential of platinum during hydrogenations, and R. Koppen,
the effect of the substance supporting the platinum on its catalytic action.
citraconic acids. B. Bruns and co-workers studied the formation of acid oxides
on the surface of platinized charcoal ; E. B. Maxted and V. Stone, the poisoning
of the catalyst. W. E. Grove and A. S. Loevenhaut said that the supposed hydrolysis
to assume the colloidal state. A. Trillat found that a trace of platinum favours
the catalytic activity of copper. R. Engel noted the favourable action of platinum
on the dissolution of copper in hydrochloric acid ; and W. Nernst, on the
dissolution
of copper in a soln. of potassium cyanide. A platinum plate is "without
action on the hydrosol of silver. F. Vies and M. Get studied the effect of platinum
on silver sols. F. C. Carter observed that platinum absorbs calcium when heated
electrically in lime ; M. Ballo, a trace of platinum favours the reducing action of
by molten alkali carbonates, and this the more if manganese is present owing to
the formation of alkali manganates ; R. W. Mahon noticed that the action is also
favoured by the presence of iron compounds. T. Gross observed an attack during
the electrolysis of the fused carbonate�vid e supra. J. J. Berzelius, L. Troost,
and W. Dittmar also showed that lithium carbonate attacks platinum in air,
presumably owing to the formation of lithium dioxide since, W. Dittmar showed
that in nitrogen, the metal is not attacked. C. Kellner found that alkalies are
adsorbed by platinum black ; and W. Skey, that contact with alkalies or alkali
carbonates affects platinum so that it does not amalgamate with mercury.
and the charcoal then absorbs only acid independently of the atmosphere. Spongy
platinum adsorbs alkali from a soln. of sodium sulphate ; but spongy platinum
which absorbs acid and liberates alkali in the presence of oxygen could not be
prepared. J. Persoz, F. C. Carter, and W. F. Hillebrand found that molten potassium
found that soln. of eerie salts are reduced by platinized platinum with the
evolution
of oxygen. W- R. Hodgkinson and F. K. S. Lowndes found that a red-hot platinum
wire in the vapour of mercuric chloride furnishes some platinous chloride- H. Ley
said that when a soln. of mercuric chloride is shaken with platinum, there is
probably
some reduction. R. Peters observed that when a soln. of sodium chloride is
allowed to stand over mercury and a platinum wire is present, some mercuric
chloride and sodium hydroxide are formed, and W. Skey observed a similar result
with hydrochloric acid. E. Schaer noted that the presence of colloidal platinum
favoured the oxidation of some organic substances by mercuric chloride. According
to E. Alexander, platinum does not reduce a soln. of mercuric chloride in ethyl
acetate. S. Cooke noted that mercuric salts are rapidly reduced by hydrogenized
platinum. J. J. Berzelius noted the attack of platinum crucibles by vanadium
salts. L. Pissarjewsky noted the catalytic reduction by platinum of the vanadium
salt K8V5O2G t� KVO4. J. C. G. de Marignac noted that platinum is attacked by
fused potassium columbium fluoride. F. W. Tschirch observed that osmium
OCtofluoride tarnishes platinum. E. Schaer noted that the presence of colloidal
platinum favoured the oxidation of some organic substances by chromic acid.
attacks platinum. S. Cooke found that acidic soln. of potassium dichromate are
rapidly reduced by hydrogen in the presence of platinum. C. E. Schonbein noted
that soln. of potassium chromate in the presence of platinum black colour blue a
soln. of starch and potassium iodide. M. Soller, and E. Muller and M. Soller found
that -with a smooth platinum anode, a soln. of chrome alum in 2V-H2SO4 is not
appreciably oxidized to chromic acid, and with a platinized platinum anode, the
oxidation proceeds about one-third as far as it does with an anode of lead dioxide.
to prepare spongy platinum in presence of oxygen which adsorbs acid and liberates
alkali. Charcoal treated with platinum and activated in air adsorbs acid from
potassium chloride soln. and liberates alkali, whereas the opposite effect is
observed
in an atm. of hydrogen. Addition of thiocarbamide to the potassium chloride soln.
poisons the platinum, and the charcoal then adsorbs only acid independently of
the gaseous atm. I. M. KolthofF and T. Kameda also observed that
platinizedplatinum,
in an atm. of hydrogen, adsorbs the cation from a neutral salt soln.,
and an eq. amount of free acid is formed in the soln. Zinc sulphate soln., in an
atm. of hydrogen, increased in acidity to an extent eq. to the amount of zinc
adsorbed by the platinum. Ammonium chloride likewise became slightly acid,
but in oxygen such soln. became very distinctly acid, and the acidity increased
the longer the oxygen was passed. This is attributed to the formation of
hexaaquoplatinic
acid, which reacts with the ammonium ions present : H2Pt(OlI)6
+2NH4->(NIT4)2Pt(OH)6H-2H. Similar results were obtained with trimethylammonium
and potassium chlorides. No acid adsorption from hydrochloric acid
occurs in a hydrogen atm., but in an oxygen atm. there is eq. adsorption of
hydrogen
and chlorine ions. Sodium hydroxide is strongly adsorbed in a hydrogen atm. ;
maximum adsorption occurs at a concentration of 00007iV. This adsorption is
increased by addition of sodium chloride, and in presence of large amounts of the
latter the maximum disappears. In the presence of oxygen the nexa-aquoj>latinic
acid formed neutralises some of the alkali, and only apparent adsorption of the
latter, therefore, takes place. F. Todt observed that the hydrolytic adsorption in
phosphate buffer soln. containing potassium chloride, at a platinized-platinum
surface, gives rise to acid in amount sufficient to account for the hydrogen effect
observed by L. Wolff. H. Gall and W. Manchot studied the reducing action of
with cone. soln. at 90�, but not at 15� to 18� ; with dil. soln., colloidal
sulphide
is formed. H. Reinsch observed no precipitation in soln. of one part of platinic
chloride in 1OO parts of water and 25 parts of hydrochloric acid ; and N. W.
Fischer
added that the precipitate is soluble in hydrochloric acid. Actually the
precipitated
sulphide is insoluble in mineral acids, but readily soluble in aqua regia ; it is
slowly
dissolved by alkali sulphides, but is more readily soluble in alkali polysulphides
from
which soln. it is precipitated by acids. A soln. of ammonium sulphide precipitates
platinum sulphide ; if ammonium polysulphide is employed the precipitation is
slow in the cold, but faster with warm soln. Complete precipitation is attained
with difficulty.
160,000 parts of liquid, a rose colour is produced in a few minutes ; and with
320,000 parts of liquid, a scarcely perceptible rose colour appears after some
time.
F. Emich and J. Donau said the sensitiveness is such as to detect 0*000005 grm. of
platinum. G. G. Aquilina recommended iodic acid as a test for detecting platinum.
O. Brunck found that sodium hyposulphite reduces platinic to platinous chloride
with the precipitation of sulphur. R. Doht precipitated platinum by boiling the
soln. with hypophosphorous acid. Unlike gold soln., metallic platinum is not
precipitated from hydrochloroplatinic acid by sulphurous acid, acetylene,
hydroxylamine, and hydrogen dioxide in alkaline soln. ; and metallic platinum
is precipitated from the hot soln. by formic acid, by formaldehyde, by glycerol
and sodium hydroxide, by hydrazine, by magnesium, and by zinc. W. N. Ivanoff
observed that soln. of platinum salts give a precipitate with thiocyanate. When
platinum salts are boiled with pyrocatechol or pyrogallol, a blood-red soln. is
produced which changes to dark brownish-red ; and when a platinum salt soln.
is made alkaline with ammonia, the same coloration is produced with resorcinol
(S. C. Ogbum). W. Singleton recommended as tests for platinum, ammoniacal
PLATINUM
found that -with very dil. soln. of hydrochloroplatinic acid, benzidine in acetic
acid soln. gives a flocculent bluish precipitate. The sensitiveness is equal to
0-0000125 part of platinum. V. G. Chlopin said that platinous salts give no
precipitate,
and cone. soln. of platinic salts, a rose-red precipitate. M. Wunder and
the mucous membrane of the stomach was found to be pale except for a patch of
brownish-yellow staining on the posterior wall; the spleen was enlarged and the
kidneys, highly congested, displayed punctiform haemorrhages ; a chronic
intussusception
was found which possibly had something to do with the fatal termination.
Platinum was found in the stomach and intestines. J. A. Blake studied
the relation between the valency and the biological action of platinum salts ; and
F. Hofmeister found that increasing the number of NH3-groups in the platinum
ammines favours the development of the toxicity, but differences in constitution
and valency had no appreciable effect. J. Dunin-Borkowsky and Z. Szymanowsky
observed no connection between the agglutinating and hemolyzing power of salts
of the heavy metals and the valency or chemical relationships of the metals.
C Foa and A. Aggazzotti observed that intravenous injections of colloidal
platinum had no perceptible effect on dogs. A. Robin and G. Bardet found that the
colloid increased the separation of urea, uric acid and indoxyl, and raised the
respiratory quotient. M. Ascoli and G. Izar showed that when administered to
man hypodermically and intravenously, there is an increase in the output of
nitrogenous compounds. W. Chonstein studied the effect of subcutaneous or
intravenous injection of sodium chloroplatinate on the elimination of nitrogen
compounds. According to J. Jiitt, oxyhemoglobin readily forms compounds with
salts and double salts of the heavy metals ; the compounds thus obtained are very
sparingly soluble in blood, especially in the presence of sodium chloride. The
metallic compounds are obtained by the replacement of five hydrogen atoms in
oxyhemoglobin by five atoms of a metal, the valency of the metal appearing to be
without influence. The main action of heavy metals as poisons is that the formation
of the metallic compounds with the oxyhasmoglobin renders the blood incapable
of acting as an oxygen carrier. The physiological action of platinic chloride was
studied by A. W. Pell. J. Feigl and A. Rollet found that the colloid has a specific
observed that in some infectious maladies, the colloid promoted oxidation of the
tissues, and the cure of the disease. C. Levaditi and co-workers found the double
thiosulphate of platinum and sodium to be less active than the corresponding
salt of gold in its trypanocidal action on rabbits.
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190 INOKGANIC AND THEORETICAL CHEMISTRY
Platinum forms the two chlorides�PtCl2 and PtCl4�where the metal is respectively
bivalent and quadrivalent. This is confirmed by the two oxides, PtO, and
PtO2. Platinum is univalent in the platinum monochloride studied by S. Streicher,1
were between 2 and 3, and Li. Holborn and Li. Austin obtained a similar conclusion
from observations on the cathodic spluttering of platinum. The platinum chlorides,
nitrites, etc., exhibit a strong tendency to form complex molecules so that the
platinum in potassium nitritoplatinite, K2Pt(N02)4, and in potassium
chloroplatinite,
K2PtCl4, behaves as if it were sexivalent ; and in potassium chloroplatinate,
K2PtCl6, as if it were octovalent. The constitution of these salts, and
of the ammines has been discussed by I. I. Tscherniaeff, A. A. Frinberg, C. W.
Blomstrand,
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1835. The primary valency of platinum in the chloroplatinates is four. The
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of the type : 2RCLPtCI4 are isomorphous with the analogous complex fluorides of
tin, titanium, zirconium, and silicon, and the analogous chlorostannates ; and
I. Bellucci and N. Parravano showed that the potassium salts of plumbic, stannic,
and platinic acids are isomorphous. H. Reihlen and W. Hiihn discussed the
optical activity of some ammino-salts. There are also the hydrochloroplatinous
acids described by JL. Wohler and F. Martin�tetrachloroplatinous acid, H2PtCl4 ;
the doubtful pentachloroplatinous acid, H2PtCl5, thought to be a derivative of
PtCl3-platinum tervalent ; and hexachloroplatinic acid, H2PtCl6 ; and platinic
acid, H2PtO4�a derivative of platinum trioxide. F. Martin, and JL. Wohler and
F. Martin showed that in the trioxide platinum is probably sexivalent. P. C. Ray
and S. C. R. Gupta suggested that the mercaptidochloride, PtCl(C2H5)2S2, contains
quinquevalent platinum :
C2H6 C2H6
S -S
Cl�Pt Pt-Cl
Il Il
C2H6�S
II
C2H6�S
S�C2H6
I
S-C2 H5
Cl
PLATINUM
and examples were also given by P. C. Ray and N. N. Ghosh. W. Pullinger suggested
that platinum is octovalent in the compound PtCl2.2COCl2 :
o-P"=<<g ci<J-pt<^
Platinum sexivalent Platinum octovalent
J. S. Stas emphasized the difficulty involved in removing the last traces of water
from this salt.
The atomic weights obtained by J. J. Berzelius, and T. Andrews are far too
high, and they are generally rejected from the computation of average values.
In 1881, K. Seubert showed that the value is nearer 195 than 197, for he calculated
195-13 from the ratio (NH4)2PtCl6 : Pt ; 197-22 from (NH4)2PtCl6 : 6AgCl; 194-83
from K2PtCl6 : Pt ; 195-06 from K2PtCl6 : 2KCl ; and 195-31 from K2PtCl6 : 4AgCl.
These results were confirmed by those of W. Halberstadt, who obtained 194-65
from the ratio PtBr4 : Pt ; 194-87 from (NH4)^PtBr6 : Pt ; 195-08 from
K2PtBr6 : Pt ; 195-78 from K2PtBr6 : 2KBr ; 195 Ol from (NH4)oPtCl6 : Pt ;
194-75 from K2PtCl6 : Pt ; and 195-29 from K2PtCl6 : 2KCl. The analyses of
potassium chloroplatinate by W. Dittmar and J. McArthur involve corrections for
some hydroxyl replacing chlorine, and hydrogen replacing potassium, and they
calculated 195-5O from the ratio 2KCl : Pt. F. Schulz obtained 194-5 from five
analyses of ammonium chloroplatinate.
195-245 from 6AgCl : (NII4J2PtCl6 ; 195-213 from 6Ag : Pt ; and 195-241 from
6Ag : (NH4)2PtBr6 ; 195-220 from 6Ag : Pt; and 195244 from 6Ag : (NH4)2PtBr6.
The international standard for the best representative value of the atomic
weight of platinum for 1931 is 3 95-2, and representative values were discussed by
F. W. Clarke, L,- Meyer and K. Seubert, J. I). von der Plaats, W. M. Watts,
T. W. Richards, W. A. Noyes, G. D. Hinrichs, and A. Vurtheim.
C. T. Heycock and F. H. Neville 4 discussed the molecular state of platinum
in alloys with cadmium, lead, and bismuth ; and E. O. von Lippmann estimated
30 to 4O atoms per molecule. W. C Roberts-Austen added that experiments on
the diffusion of platinum suggested that the molecules are more complex than those
of silver, or gold. The relations between the elements and their at. wts. were
discussed
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by J. Johnston ; and the relations between the at. wts. and the colour of the
elements, by M. C. Lea.
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the relative abundances, for the 192, 194, 195, and 196 isotopes are, respectively,
6, 6, 8) for the N-shell ; (2, 2, 4, 4, 4) for the O-shell ; and (2) for the P-
shell.
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Phys. Rev., (2), 45. 847, 1934 ; N. Bohr, Nature, 112. Suppl., 1923 ; E. Bose,
Phys. Zeit., 7.
374, 1906 ; J. Chad wick, Phil. Mag., (6), 40. 734, 1920 ; J. Chadwick and C. D.
Ellis, Radiation
from Radioactive Substances, Cambridge, 1930 ; J. M. Cork and E. O. Lawrence, Phys.
Rev.,
(2), 49. 788, 1936 ; J. A. Crowther, Proc. Roy. Soc., 84. A, 239, 1910; F.
Deininger, Ann.
Physik, (4), 25. 306, 1908 ; A. J. Dempster, Nature, 135. 993, 1935 ; H. Eyring and
A. Sherman,
Journ. Ghem. Phys., 1. 345, 1933 ; P. D. Foote, Trans. Amer. Inst. Min. Eng., 78.
628, 1926 ;
B. Fuchs and H. Kopfermann, Naturtviss., 28. 372, 1935 ; B. Jaeckel, Zeit. Physik,
100. 513,
1936 ; B. Jaeckel and H. Kopfermann, ib., 99. 492, 1936 ; M. Kahonovicz, Atti
Accad. Lincei,
(6), 8. 584, 1928 ; S. Kato, Bull. Inst. Chem. Research Tokyo, 13. 53, 1930 ; G.
Kirsch, Natururiss.,
21. 332, 1933 ; H. Kopfermann and K. Krebs, Zeit. Physik, 101. 193, 1936 ; A.
Matzner,
Sitzber. Akad. Wien, 148. 579, 1935; W. Meier, Ann. Physik, (4), 31. 1049, 1910;
Untersuchungen
uber Dispersion und Absorption bet Metallen fur das sichtbare und ultraviolette
Spektrum,
Gottingen, 191O ; B. V. Nekrasoff, Bull. Soc. CMm., (5), 8. 151, 1936 ; C. D.
Niven, Phil. Mag.,
(7), 3. 1314, 1927 ; J. Patterson, ib., (G), 3. 655, 1902 ; H. Perlitz,
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Wien, 184. 491, 1925 ; R. Pohl, Phys. Zeit., 7. 501, 1906 ; G. I. Pokrovsky, Zeit.
Physik, 57. 560 ,
1929; P. Ray, Zeit. anorg. Chem., 174. 187, 1928; O. W. Richardson, Proc. Roy.
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217, 1930 ;
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and L. Sibaiya, Proc. Indian Acad. Science, 1. 955, 1935 ; 2. 101, 1935 ; H. J.
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Proc. Roy. Soc, 82.
A, 72, 1909.
� 16. Intermetallic Compounds, and Alloys of Platinum
J. Dewar and A. Scott * observed that platinum is very strongly attacked by
the vapour of the alkali metals. According to H. Davy, platinum-potassium alloys
are readily formed since the two metals when heated together unite with
incandescence,
forming a brittle, shining mass. H. Davy observed that the alloy of
potassium and platinum burns when heated in air, forming a yellow powder which
gives off oxygen when heated, and is decomposed by water. K. A. IJofmann and
H. Hiendlmaier observed that if potassium is melted with platinum in air, the
product passes into soln. as potassium platinate. H. Davy likewise prepared
platinum-sodium alloys. C. T. Heycock and F. H. Neville observed that platinum
is insoluble in molten sodium. J. Dewar and A. Scott noted that platinum is
attacked by the vapour of sodium, and V. Meyer added that sodium vapour, in
nitrogen, begins to attack platinum at a red-heat, and the attack is greater, the
higher the temp. F. Haber and M. Sack, and M. Sack observed that platinum
takes up sodium when heated to redness in the vapour of the alkali metal, and when
the metal is afterwards treated with water, it becomes loose and porous on the
surface. According to A. Brester, a sodium-platinum alloy is formed by the
electrolysis of sodium sulphate with a platinum cathode. P. G. Ehrhardt found
that platinum-lithium alloys are harder than platinum itself.
According to A. F. Gehlen,2 platinum-COpper alloys are readily formed at a
white-heat ; and E. D. Clarke obtained the alloy by melting equal weights of the
two metals in the oxyhydrogen flame. H. Ie Chatelier observed that at its m.p.,
copper gives off sufficient vapour to corrode platinum. Alloys were also made
by C. S. Brainin, C. Winkler, J. Murray, C Barus, and F. Doerinckel. According
to C. Krug, the two metals form alloys in all proportions. E. M. Wise and coworkers
studied the use of the platinum-copper alloys for dental purposes. B. N. Sen
discussed the diffusion of copper into platinum. The f.p. curve, Fig. 29, falls
continuously from the m.p. of platinum to that of copper, and there is therefore a
continuous series of solid soln. As pointed out by G. Tammann, no compound
appears on the curve although C. Krug was under the impression that a platinum
cupxide, PtCu, is formed. The subject was discussed by K. Bornemann, E. Janecke,
PLATINUM 195
� 174^
-1750�\ -^
~^
1500'
1250
1400 1000r �
PtCu^
-750" U�
� J 500�
250� -J
no8oD
WOO o"
20 40 60 80 20 40 60 80
of the hardness (Fig. 31), conductivity, and temp. coefE. of the conductivity
(Fig. 32) of re-heated and tempered alloys. H. Rohl discussed the clastic
properties
of the Ou3Pt alloy.
wo
20 40 60 80 100
20 40 60 80 TOO
Atomic per cent.. Platinum Atomic per cent of platinum
Fia. 32.
A. F. Gehlen said that the alloy with 3-7 per cent, of platinum had a fine-grained
structure. H. Behrens observed that when polished surfaces are etched with
nitric acid, deep furrows are cut between cushion-like crystals. W. Lewis found
the sp. gr. of alloys with platinum and
Copper . 0969 66-7 8O 83-3 88-9 92-3 96-15 1OO per cent.
8-830
W. Biltz and F. Weibka studied the at. vol. F. Doerinckel said that the alloys
are soft and tough ; and that the hardness is between 3 and 4 on Mohs* scale.
F. E. Carter's values for Brinell's hardness of workable alloys are given in Table
IV.
TABLE IV.�BBINELL'S HARDNESS OF PLATINUM ALLOYS.
Percentage amount
Alloy
5 10 16 20
Ir . 80 105 140 175
Os 117 175 �
Pr! 65 70 73 75
R h 67 73 77 8O
R u 105 158
A u 102 148
A g 8O 125 17O 172
Cu 110 135 142 145
Ni 138 195 236 27O
A. F. Gehlen said that the alloy with 3*7 per cent, of platinum is malleable, and
E. D. Clarke that the 50 : 50-alloy has a sp. gr. like gold, is malleable, and
easily
filed. F. E. Carter said that with up to 10 per cent, of copper, the alloys do not
blacken on heating, but with more copper they do blacken and become difficult
to -work. Alloys with up to 30 per cent, of copper may be hot rolled, but beyond
that, the alloys are hard and brittle. C. Krug observed that alloys with over
10 per cent, of platinum are liable to " spitting " when they solidify. C. H.
Johansson
and J. O. Linde examined the X-ray spectrum. H. J. Seemann, and C. Barus,
and E. Sedstrom measured the sp. resistance and its temp. coefF. F. E. Carter
said that the addition of copper to platinum raises the electrical resistance very
markedly ; the resistance R ohms, the temp. coefE. a per c.c, and the thermal
e.m.f. against platinum at 1100�, are :
Copper . 5 10 15 20 25 30 per cent.
of the alloys.
A. Sieverts and co-workers observed that platinum raises the solubility of
hydrogen in molten copper. E. D. Clarke said that the 50 : 50-alloy is tarnished
in air ; and C. Krug noted that the alloys generally resist atmospheric corrosion
very well. A. Sieverts and E. Bergner found that platinum lowers the solubility
of sulphur dioxide in copper. F. Doerinckel, and H. Behrens noted that alloys
with up to 50 per cent, of platinum are etched by nitric acid. According to
C. Winkler, alloys with [Cu] per cent, of copper, yield [Pt] per cent, of platinum
when treated with nitric acid :
HNO3 sp. gr. 1-398 1-298 1-190 1-298 (fuming)
* " � � * * 4 * o t * N
[Cu] . . 90-24 99-OO 89-89 98-85 90-61 99-00 89-80 94-78 per cent.
[Pt] . 45-60 5200 26-57 41-27 1119 37-03 5116 40-81
C. Krug said that the solubility of platinum is not influenced by the concentration
form alloys in all proportions, but F. E. Carter said that the alloys do not form a
continuous series of solid soln. as in the case of platinum alloyed with gold, or
palladium with silver. The metals do not readily dissolve in one another, and they
tend to separate on cooling. J. Prinsep attempted to measure the m.p. of
silverplatinum
alloys by a gold air thermometer ; and to use the alloys as pyroscopes.
C. T. Heycock and F. JH. Neville observed that adding 3*55 per cent, of platinum
to silver raised the f.p. to 990�. F. Doerinckel found that a series of solid soln.
larities in the solvent action of nitric acid ; and for similar reasons A. von der
Ropp suggested that platinum, hemitriargentide, Pt2Ag3, is formed. G. Tammann
added that no evidence of any compound of the two elements appears on the f.p.
curve. N. S. Kurnakoff and W. A. Nemiloff's correction of F. Doerinckels curve
is shown in Fig. 33, where A represents a solid soln. of platinum in silver ; B, a
198 INORGANIC AND THEORETICAL CHEMISTRY
solid soln. of silver in platinum ; and A +-B, a mixture of the two solid soln.
Observations
on the subject were made by W. Guertler, G. Natta, K. Bornemann, and
280\
i 240
200 44,
oS95F
160
720
>NA
�Tenacity
-S^-03 80
nQ Sf \
^\
SZ d
40
0 20 40 60 80 100
20 40 80 80 100
KiO. 35.�The Lattice Constants FIG. 36. The Hardness and Tenacity of Platinumof
the Platinum-Silver Alloys. Silver Alloys.
refer to solid soln. The alloys for up to about 30 per cent, platinum were quenched
from 75()� to 850�, and those above 50 at. per cent, platinum were quenched from
1150�. The X-radiograms were studied by J. Weerts. The sp. gr. referred to
water at 4� is :
Platinum
Sp. gr.
0
10-61
10-39
11-17
20-59
11-8O
31-46
12-57
37-89
13*19
57-05 per cent.
14-25
W. Lie wis gave for the sp. gr. of alloys with
Silver
Sp. gr.
5O
13-535
6G-7
12-452
75
11-790
87-5
10-867
100 per cent.
10-980
W. Biltz and F. Weibka studied the at. vol. J. P. J. d'Arcet observed that the
alloys of platinum with silver are less white, less malleable, and less hard than
silver, and when quietly fused, an alloy richer in platinum collects at the bottom.
A. Matthiessen found the linear thermal expansion of alloys with 66 per cent,
of silver to be Z=Z0(I+O-O414150+O-O71O70*) ; and the cubic expansion
V=V0(14-OO442460-}-OO732202). F. A. Schulze gave for the thermal conductivity, k,
Platinum . 0" 10 25 30 33 per cent.
k 1-08 0-98 0-38 0-31 0-3O
J. F. Thompson and E. H. Miller noted that alloys with over 40 per cent, of silver
do not spit perceptibly on solidification. E. Hagen and H. Rubens measured the
emissivity of the alloys ; and H. Weisz found that platinum acts as a nucleus for
the solarization of silver bromide films in photography.
A. Matthiessen and O. Vogt found that the curve for the electrical conductivity
has a break for alloys with 33 per cent, of platinum. The conductivity
33& Pt __.
Pt
^55
25% Pt _s~ \
^S so
^s
\\
-SJ 40
^ 35
30 -n_ 5_ � 20 40 60 80 100
Atomic per cent . Platinum
Platinum-Silver Alloys.
of an alloy with 66*6 per cent, of silver, or 16-95 vols, per cent, of platinum, is
6-696
when that of silver alone is 100 ; and at 0�, 6-696�OOO2210+OO5139302.
A. Matthiessen and C. Vogt also gave for alloys with 5-5 vols, per cent, of
platinum,
18031�0-013950H-O-O5118202; and 2-51 vols, per cent, of platinum 31-640
�0-039360-j-O-O5364202. Measurements were also made by C. Barus, D. A. Gr.
Bruggeman,
and W. Geibel ; and J. F. Thompson and E. H. Miller gave for the resistance
in ohms, It,
Platinum O 10-39 20-59 31-46 37-89 por cent.
R 00217 0-0918 01814 0-2914 0-31I0
J. Dewar and J. A. Fleming gave for an alloy with 66 per cent, of silver,
99-3� 18-35� -80� � ioo� � 182�
R 00427400 00426905 0-0426824 00426311 00426108 00425537
a comparison of the ratio of the thermal, Jc, and the electrical, K, conductivities
at 25�, by F. A. Schulze.
k/JCxlO7 69 77 9O 95 106
Platinum-Silver Alloys.
A small trace of platinum is inclined to dissolve with the silver, but by diluting
the acid, this may be prevented. The subject was also studied by H. Carmichael ;
\
\\
\\ 1
\ /
\ V S /
and A. Steinmann recommended the use of a soln. of 100 vols, of acid and 22 vols,
of water for dissolving out the silver, the operation being twice repeated at 240�.
PLATINUM
K. Hradecky observed that selenic acid dissolves silver from these alloys yielding
a residue of platinum.
F. Doerinckel observed that dil. nitric acid attacks the alloys with increasing
difficulty as the proportion of platinum increases ; and when 50 per cent, of
platinum
is present the alloy is etched only slightly. An alloy with 60 per cent,
of platinum, and rapidly cooled from the molten state, is readily attacked by cone,
nitric acid, but if the alloy has been annealed for 6 hrs. at 1180�, it is much
more
resistant. C. von Sickingen, and J. P. J. d'Arcet observed that although platinum
is not attacked by nitric acid, yet it dissolves slightly when its alloys with
silver
are treated with that acid. H. How, and E. Priwoznik considered the solubility
of the platinum to be connected with the formation of a silver nitritoplatinite.
The solubility of the platinum in nitric acid was also observed by H. Debray,
J. E. Herberger, P. Johnson, J. W. Mallet, H. Miller, A. D. van Riemsdyk,
W. J. Sharwood, and H. N. Warren. C. Winkler, and A. von der Ropp showed
that the cone, of the acid is of importance. According to J. Spiller, nitric acid
of
sp. gr. 1*4:2 will dissolve 0-75 to 1*25 per cent, of platinum from its alloy with
12
times its "weight of silver, whilst treatment with a more cone, acid is attended by
the separation of platinum black. A less cone, acid dissolves less platinum.
J. F. Thompson and E. H. Miller observed that alloys with less than 20 per cent,
of silver furnish a colloidal, dark brown sol of platinum, which, after standing
several days, flocculates and deposits the platinum as a black powder in a very
fine state of subdivision, and leaves a colourless soln of the silver salt.
According
to A. von der Ropp, the residual platinum explodes when dried on a filter, and
heated to about 200�. C. Winkler found that |_PtJ per cent, of platinum is
dissolved
from alloys with [AgJ per cent, of silver :
HNO3 sp. gr. . 1-398 1-298 1-19O 1-298
J. F. Thompson and E. H. Miller found that with nitric acid of sp. gr. 1*10, the
following proportions of platinum passed into soln. from 100 parts of alloy :
f Alloy . . 10-39 20-59 31-46 37-89 5705 per cent.
Platinum^ Residue . 3-59 6-77 24-50 35-49 52-97
(^Dissolved 6-80 13-82 6-96 2-4O 4-08
The results are irregular, but they are taken to prove that, in assaying, platinum
cannot be satisfactorily separated by nitric acid from its alloy with silver. 1.
Koifrnan
obtained analogous results with alloys, containing 0-219 to 5-162 per cent, of
platinum. J. E. Herberger observed that aqua regia
extracts the platinum from the alloys and converts the
silver into chloride. G. Tammann's study of the action
of gold chloride, nitric acid sp. gr. 1-44, fuming hydrochloric
acid, ferric chloride, and ammonium sulphide
indicated a limit of reactivity with up to 35 per cent, of
platinum. J. W. Mallet found that an alloy with 31-09
per cent, of platinum, at ordinary temp., gradually
absorbs five times its weight of mercury and becomes
very brittle. E. Janecke constructed the diagram, p^ QU
Fig. 42, for platinum-silver-copper alloys, showing the Flo 42 The Tornary
eutectic line, and the region of solid soln. System : Pt-Ag-Cu.
and J. T. Eash, and H. Bush recommended the alloys for artificial teeth ; and
dental alloys of these two metals were studied by E. M. Wise and co-workers.
platinum ; and A -\-B, a mixture of the two solid soln. G. Tammann said that no
1800
1700c
-"*'
~~~ A
1600c
7500� ._ _
14Od s?_
� �
_.
13OO
>129O /
8
1200 /
A + B
1100 ._ . -1000
toes CA
20 40 60 wo wo
Per cent, of Platinum Atomic per cent, of platinum
�* IU
I 4 02
same as that of platinum. C Hatchett said that
the alloy of 1 part of platinum and 11 of gold is
"I 3-98
0 20 40 60 80 100
Atomic per cent of platinum that the alloy with 1 part of platinum to 9*6 of
Fio. 45.�The Lattice Constants gold is almost the colour of gold. T. Erhard and
of the Gold-Platinum Alloys. A. Schertel observed that rapidly cooled alloys have
a fine crystalline structure, and, slowly cooled alloys,
a coarse crystalline structure. C. H. Johansson and J. O. Linde's results for the
lattice-constants are summarized in Fig. 45. The alloys with 40 to 100 at. per
cent, of platinum were quenched from 1200�, and those with O to 32 at. per ce"nt.
PLATINUM 203
of platinum, from 1000�. The results represented by the dotted lines were with
samples quenched at 800�. W. Stenzel and J. Weerts found that the lattice parameter
W. Lewis gave for the sp. gr. of the binary alloys from platinum of sp. gr. 19-
285 :
Gold 66-7 75-0 83-3 91-67 93-75 95-8 97 0 98-O 99-0
Sp. gr. . 18-378 18-613 18-812 18-835 18-918 19-089 19128 19-262 19-273
F. Doerinckel found that the hardness of an alloy with IO per cent, of platinum
is very like that of gold ; with 20 to 30 per cent, of platinum, the same as that
of
platinum, and with over 50 per cent, of platinum, about the same as that of
calcite.
The following is a selection from A. T. Grigoreeff's measurements of .Brineirs
hardness, H, of the cast alloys and of annealed alloys :
"Platinum 5 IO 20 40 6O 80 9O 1OO
27-4 33-8 38-2 83-O 127-3 155-3 99-5
M\
300} fAKA J
C. Hatchett found that the alloy with 91*67 per
S3 /
I'250
O \
If
�
hardens platinum, and that the limit of workability
I^ p^
O 20 40 60 80 100
The elastic modulus of an alloy with 77-8 per cent, of gold was found by G.
Wertheim
to be 9844 kgrms. per sq. mm., and the tensile strength to be 7-12 kgrms. per
sq. mm. ; he also found the velocity of sound in the alloy to be 6-848 when that
in air is unity. F. A. Schulze gave for the thermal conductivity, k,
C H. Johansson and J. O. Linde's results for the thermal conductivity of the alloys
are summarized in Fig. 47. F. E. Carter gave for BrinelFs hardness H ; Ericson's
ductility test in mm. ; and the resistance R ohms :
Annealed
F. Doerinckel's values for the m.p. are indicated in Fig. 43. T. Erhard and
A. Schertel gave :
Pt O 5 IO 2O 4O 6O 8O 1OO per cent.
M.p. 1075� 1100� 1130� 1190� 1320� 1460� 1610� 1775�
Observations on a few isolated alloys were made by P. Silow, Y. Shimizu, J.
Prinsep,
and A. Heintz. T. Erhard and A. Schertel found that alloys with 15 to 40 per
cent, of platinum are inclined to segregation, and similar results were obtained by
50 """1
2� SOrer
40
�S�
L� �
�0
30\ ^*
X
I ^
�
20 GHK ^l
55
eg? \f -J
0 I 1 1 1 1 1 1 � -I��J 1�
0 20 40 60 80 100
0 20 4O 60 80 JOO
where the ratios of the thermal and electrical conductivities are by F. A. Schulze.
-8 /A mer studied the chemical potentials of A A liquid and solid solutions of Ag-
Pt alloys.
V / W. Geibel found that the thermoelectric
g -12 force of the alloys against platinum is
iS
20 40 60 80 IOO
susceptibility, in Fig. 50. Y. Shimizu studied the effect of stress on the magnetic
susceptibility.
P. Johnson found that nitric acid dissolves not only gold but some platinum
from the alloys. K. W. Frohlich discussed the error involved in the determination
of platinum -when alloys with gold and silver are treated with hot sulphuric acid.
Some platinum passes into soln. J. Weineck observed that cone, sulphuric acid,
and molten potassium hydroxide with or without potassium nitrate, and molten
potassium hydrosulphate have no marked action on the alloy. F. Doerinckel found
that the alloys resist cold aqua regia very 1WeIl ; soln. of potassium cyanide
rapidly
attack alloys with a low proportion of platinum ; the action is slower with
increasing
proportions of platinum ; and "when 6O per cent, of platinum is present, the attack
is slow with boiling soln. A.G. Norddeutsche Amnerie found that the alloys
dissolve anodically in hydrochloroauric acid ; and F. Haber found that 11 per
cent, hydrochloric acid, at the b.p., attacks platinum anodes as vigorously as a
36 per cent. soln. at ordinary temp. ; but an 8 per cent, soln., at the b.p.,
leaves
the platinum intact, and a soln. below 3O per cent, hydrochloric acid does not
attack the metal at ordinary temp. Li. Quennessen studied the attack by caustic
alkalies. P. Nicolardot and J. Boudet found that crucibles made with gold alloyed
with 12-5 to 25 per cent, of platinum are badly attacked during the electrolysis of
both series of alloys. E. B. Craft and J. W. Harris said that the alloy with 67*5
to
7O per cent, of gold, 25 per cent, of silver, and 5 to 7-5 per cent, of platinum,
is
harder than platinum ; and F. A. Bolley used the alloy 8 parts of platinum, 1 part
of silver, and 3 parts of gold for dental work. L. N. Vauquelin, and H. Debray
noted that nitric acid completely dissolves the alloy with 1 part of platinum,
IO parts of gold, and 30 parts or more of silver. A. von der Ropp noted that nitric
acid dissolves most of the silver and gold, but leaves some platinum alloy
undissolved
; press, increased the solubility of the platinum. E. Matthey noted that
castings of the quaternary platinum-gold-silver-copper alloys are not homogeneous.
R. B. Graf used the 45 : 15 : 25 : 15-alloy for electric contacts. Ii. Nowack
studied the platillium-gold-zinc alloys. N. H. Furman studied an application of
the amalgam�gold-platinum-mercury alloy�in electrometric titrations.
According to M. Tarugi,5 when platinum salts are heated with calcium carbide,
a platinum-calcium alloy is formed, and it is easily decomposed by water.
F. E. Carter said that when the platinum is melted under reducing conditions in a
lime-crucible, it takes up calcium to form an alloy. E. D. Clarke observed that a
platinum-barium alloy is formed by melting a mixture of the two elements in
the oxyhydrogen flame. The bronze-coloured alloy disintegrates to a reddish
powder in 24 hrs. A. Matthiessen found that in the electrolysis of molten barium
chloride with a platinum cathode, a yellow, brittle alloy is formed, and it is
slowly
206 INORGANIC AND THEORETICAL, CHEMISTRY
obtained surface films of alloys with alkaline earth metals by heating platinum
wires in the vapour of the metal. The product was tried as a lamp filament.
heated with platinum in hydrogen, for some hours, a friable alloy corresponding
may take up magnesium to the extent of 3 per cent. M. Balbo noted the reduction
with 1-5 to 2 parts of zinc, at a temp, below redness, producing a vivid combustion
H. Debray observed that platinum dissolves in molten zinc, and alloys were made
by C. Barus, C. Winkler, and CT . Heycock and F. H. Neville by fusing a mixture
of the two elements ; W. R. E. Hodgkinson and co-workers, and A. Pospieloff, by
the action of the vapour of zinc on platinum ; F. Mylius and O. Fromm, C. A. Kohn
and J. Woodgate, T. S. Price, and V. Engelhardt, by the electrodeposition of
zinc on platinum ; J. W. Dobereiner, by the action of platinum on zinc-sodium
alloys ; and F. Mylius and O. Fromm, by the action of zinc on soln. of platinum
salts.
Some compounds have been reported, but the evidence in support of their
chemical individuality is equivocal�e.g. W. R. E. Hodgkinson and co-workers
reported crystalline platinum zincide, PtZn to be formed by strongly heating
platinum dizincide, PtZn2, which is said to be formed by heating platinum for
5 hrs. in the vapour of zinc. H. St. C. Deville and H. Debray obtained the
dizincide
by treating a platinum-zinc alloy, containing an excess of zinc, with hydrochloric
acid, and H. Behrens, by treating the alloy with dil. sulphuric acid. H. Behrens
said that the crystalline powder consists of brownish crystals�probably hexagonal.
C. T. Heycock and F. H. Neville observed that molten zinc dissolves 4 per cent,
of platinum without altering appreciably its f.p., and they obtained a product
corresponding with platinum hemitrizincide, Pt2Zn3, with a m.p. "which W. Guertler
supposed corresponds with a eutectic temp. A. Westgren, U. Dehlinger, and
W. E. Schmid studied the X-radiograms of the Pt5Zn21-alloy.
A. F. Gehlen, and R. W. Fox said that the alloys arc bluish-white. H. Behrens
observed that polished surfaces of alloys with 10 per cent, platinum, etched with
dil. sulphuric acid, show the presence of rod- and needle-like crystals. A. J.
Bradley
discussed the X-radiograms. A. F. Gehlen, and R. W. Fox observed that platinum
is rendered brittle when alloyed with 0-25 part of zinc, and zinc is rendered
brittle
by alloying with 0*05 part of platinum. C. Winkler also found that alloys with
90 to 99 per cent, of zinc are very brittle. C. Barus measured the electrical
resistance,
and its temp, coeff. R. W. Fox observed that the platinum-zinc alloys lose
the greater part of their zinc by oxidation when they are heated in air. G. Tammann
cent, of zinc. These residues were also studied by H. Debray, and H. St. C. Deville
[Zn] . . . 90-0O 98-71 90-46 98-87 98-84 98-83 9O-79 96-74 per cent.
[Pt] . . 10-29 19-67 10-70 31-66 19-40 3714 4-86 10-76
PLATINUM 207
volatilizes from the alloy at a red-heat. When digested with nitric acid, some
platinum passes into soln. along with the cadmium. All the alloys with over
6 per cent, of platinum were found by K. W. Ray to be very brittle, and harder
than either metal component. The cadmium is dissolved out by hydrochloric or
sulphuric acid, leaving spongy platinum behind.
B. Wood noted the brittleness of these alloys. C. T. Heycock and F. H. Neville
observed that the f.p. of cadmium is lowered about 4*5� by the addition of 1 at.
per cent, of platinum. K. W. Ray found that platinum dissolves in molten cadmium,
forming white alloys having a low m.p. The f.p. curve shows that platinum
dicadmide, PtCd2, and platinum hemienneacadmide, Pt2Cd9, are formed. The
hemienneacadmide decomposes at 615� into cadmium and the dicadmide, which
melts at 725�. The eutectic with 2 per cent, of cadmium and the hemienneacarbide
melts at 315�. Cadmium volatilizes rapidly during the preparation of alloys with
over 50 per cent, of platinum, and the pasty mass can be melted only under press.
C. Barus made some measurements of the electrical resistance, and of its temp,
coeff. Gr. Tammann and W. Wiederholt studied the polarization of the alloy.
F. Mylius and O. Fromm found that hydrogen is given off turbulently when the
alloy is treated with hydrochloric acid.
J. F. Danielle R. Bottger, E. Melly, I. N. Plaksin and S. M. Schtamova, and
C.Engler and Li. Wohler prepared platinum-mercury alloys, or platinum amalgams
by triturating spongy platinum with mercury. R. Bottger used a warm mortar,
and J. F. Daniell found that the amalgamation is facilitated if 'water acidified
with
acetic acid is also present. C. Engler and Li. Wohler observed that owing to
occluded oxygen, and oxidation films, platinum black amalgamates with difficulty ;
and M. Tarugi, that the grey mercury which separates when magnesium is added
to a soln. of mercury salt, does not amalgamate platinum black by trituration.
A. Tribe observed that platinum black which has been treated with hydrogen
readily amalgamates with mercury in a few hours. T. Ihmori showed that platinum
black absorbs mercury vapour; and C. Hockin and H. A. Taylor, that platinum
rapidly amalgamates with mercury boiling in an evacuated vessel.
J. F. Daniell observed that compact platinum does not take up mercury at
ordinary temp, even when kept in contact with it for 6 years, but if the mercury
be heated�to 200�, according to F. E. Carter�the metal acquires a film of mercury
which can easily be wiped off ; and J. M. Crafts added that a small proportion of
mercury is taken up by the metal. E. N. Horsford also noted that compact platinum
does not take up mercury at ordinary temp. M. Krouchkoll emphasized that for
amalgamation, the surface of the compact metal should be thoroughly cleaned,
and he recommended dipping the platinum in boiling nitric acid, and heating it
to redness many times. W. Skey showed that the contact of platinum with aq.
ammonia or alkali-lye prevents amalgamation by oxidizing the surface of the
metal, but the metal amalgamates if in contact with mineral acids. G. McP. Smith
208 INORGANIC AND THEORETICAL CHEMISTRY
and H. C. Bennett said that amalgams, not mercury, alone " wet " the surface of
platinum in consequence of their surface tension. E. Englisch observed that
mercuryattacks
platinum at 400� ; and C. Hockin and H. A. Taylor, that an amalgam is
formed when red-hot platinum is plunged into mercury. F. E. Carter said that
sodium amalgam attacks platinum, and there is a process for removing platinum
from its crushed ore which is based on this reaction.
gas ; and also the oxidation of carbon monoxide ; and the reduction of
nitrobenzene,
have been studied.
The amalgam may appear as a viscid mass, which when heated boils up, loses
its mercury, and leaves behind a finely-divided, black powder, or a grey, coherent
mass of mercury. If pressure is applied during the ignition, A. von Mussin-Puschkin
said that the product is fit for working into malleable platinum. E. Melly, and
the dull black powder obtained by heating the amalgam over a spirit lamp still
retains xV^1 0^ it a weight of mercury. Boiling the residue with cone, nitric acid
for 24 hours extracts only a trace of mercury, and the washed and dried residue
has a vigorous catalytic action on hydrogen gas and alcohol. If the amalgam be
heated to a higher temp., all the mercury is expelled, and grey, coherent platinum
remains which no longer inflames a jet of hydrogen. If, instead of heating the
platinum amalgam, it is digested with nitric acid, frequently renewed, the black
powder which remains is mixed with a few shining particles of platinum. It does
not ignite a mixture of hydrogen and air at ordinary temp., but does so if heated.
C. H. Latham studied the adsorption of water vapour by platinum amalgam.
According to R. Sabine, if a drop of dil. sulphuric, hydrochloric, oxalic, or
acetic
acid be placed on the clean surface of a rich amalgam of a metal positive to
mercury
�e.g. copper, zinc, antimony, tin, or lead�the drop does not remain still as it
would
do on purified mercury, but sets itself into an irregular jerky motion ; but with
the amalgam of a metal negative to mercury�e.g. silver, gold, or platinum�the
drop of acid remains quite still. The movement is attributed to alternate oxidation
PLATINUM 209
of a portion of the surface of the amalgam by air outside the drop, and deoxidation
of the amalgam.
According to H. Moissan, when platinum amalgam is shaken with water for
15 seconds or less, it forms an emulsion of a buttery consistency and having five
times the vol. of the original amalgam. The product is stable and not affected
by being heated to 100� or cooled to �80�. A section made at the latter temp,
reveals small drops of water disseminated throughout the amalgam, giving the
latter a cellular appearance. When exposed in a vacuum, it diminishes in vol., a
little water and a small quantity of gas separating. The emulsion is also produced
by shaking 2 c.c. of pure mercury with 12 c.c. of water to which some drops of a
IO per cent, platinic chloride soln. have been added, and when platinum amalgam
is shaken with water, similarly treated, the increase in vol. is greater than with
pure water. Platinum amalgam emulsifies similarly when shaken with sulphuric
acid, aqueous ammonia, aq. or ammoniacal ammonium chloride soln., sodium
chloride soln., glycerol, acetone, anhydrous alcohol, ether, oil of turpentine,
carbon
tetrachloride, or chloroform, and forms stable emulsions. Benzene is inactive.
Platinum amalgam, to which sodium has been added, also increases in volume
and emulsifies when shaken with water. P. Lebeau added that the property of
forming emulsions is not exhibited by the other metals of the platinum group,
and with platinum amalgam, the property is shown when only 0-038 per cent,
of platinum is present. The platinum amalgam loses its property by admixture
with amalgams of zinc, calcium, lead, or tin. The volume of the mass formed is
dependent not only on the nature of the liquid, but also on the state of the
platinum
from which the amalgam was made, being much greater when the latter is
finelydivided,
although even in this case the effect is diminished if the metal be strongly
heated before the amalgam is made. Microscopic examination of sections cut from
the mass, obtained by shaking platinum amalgam with a soln. of gelatin and then
cooling to the f.p. of mercury, show that it had a structure similar to that of
soap
lather, so that it is probably due entirely to surface tension. G. Michaud observed
7800,
7764^X
1600 � -�'
7200 h
.... _ .
787 �
639 Q^
600 -"
when digested with hydrochloric acid, they
furnish a bronze-coloured crystalline powder ;
400 alloys with 80 to 9O per cent, of platinum are
20 40 60 80 700
said that the alloy with 70-4 per cent, of aluminium, Al3Pt, is hard and brittle ;
those with less than 9 per cent, of platinum are soft, malleable, and white ; above
this, the alloys are harder, and yellow. C. Barus made some observations on the
electrical resistance and of its temp, coeff. K. Helouis did not detect any change
with the introduction of a small proportion of platinum. J. H. Gladstone and
does not exceed that of thallium until the proportion of platinum attains 10 per
cent., and as the proportion reaches 48*8 per cent., the m.p. rises to 685�. With
increasing proportions of platinum, the m.p. at first falls slightly, but then
rises
continuously up to 855� for 65 per cent, of platinum. The m.p. goes on rising as
more platinum is added. The maximum at 685� corresponds with the m.p. of
platinum thallide, PtTl. Alloys rich in thallium contain brilliant white crystals
PLATINUM 211
�which are easily polished, and they are surrounded by a dark soft eutectic. When
48*8 per cent, of platinum is present, these crystals constitute the entire alloy.
Alloys richer in platinum are susceptible of a high polish, their surface appears
homogeneous, but their composite character is shown by oxidation in a bunsen
flame. Platinum thallide forms steel-grey, prismatic needles, and it is obtained
by the slow action of 10 per cent, nitric acid on alloys "with less than 10 per
cent,
of platinum. It has a sp. gr. 15-65 at 14�, its hardness is 3 on Mohs' scale ; and
its sp. ht. is 0-045O. It loses a little thallium on continued heating above the
m.p.,
but does not give pure platinum even on prolonged fusion in the oxyhydrogen
flame. The alloy is attacked by the halogens, and dissolved by warm aqua regia ;
the latter on boiling, however, gives the insoluble thallium chloroplatinate. It is
alkali carbonates, and is only very slowly attacked by sodium dioxide. It dissolves
easily in fused zinc, lead, or silver. Its quantitative analysis, rendered very
difficult by its properties, was effected by cupellation with four times its weight
of silver and three times its weight of lead. The compound PtTl is very similar,
especially in its physical properties, to the alloy PtPb. TJ. IIackspill prepared
a platinum-thallium-silver alloy by dissolving silver in the platinum-thallium
alloy ; and a platinum-thallium-zinc alloy by dissolving zinc in the
platinumthallium
alloy. Mercury below its b.p. forms a platinum-thallium-mercury
alloy, or a platinum-thallium amalgam.
C. Winkler1 1 observed that platinum germanium alloys can be readily obtained
by adding platinum to molten germanium. According to H. JCellermann, platinum
dissolves in molten cerium at about 800�. Much heat is developed during the
formation of the platinum-cerium alloys. An alloy with 25 per cent, of platinum
is hard and brittle, and it makes a good pyrophorie metal. The alloys were also
examined by A. Hirsch.
A. F. Gehlen 12 prepared a platinum-tin alloy by heating together a mixture
of spongy platinum with twice its weight of tin filings ; and E. D. Clarke, and
J. Murray noted that when tinfoil is rolled up with fine platinum foil, and heated
before the blowpipe flame, combination occurs attended by a kind of explosion.
H. Goldschmidt observed that the metals alloy below the m.p. ; and II. Debray,
and F. Doerinckel prepared alloys by melting mixtures of the two metals. An
alloy was obtained by B. Delachanal and
1800i
0 20 40 60 80 100
hexagonal crystals, and is very brittle. I. Oftedal gave for the lattice dimensions
�=-4103 A., c=5-428 A., and a : c= l : 1-323. Whilst F. Doerinckel gave 1281� for
the m.p., N. Podkopajeff gave 1324�. According to F.-Doerinckel, the components
of the eutectic at 1181� are platinum stannide and platinum tritastannide, Pt3Sn ;
212 INORGANIC AND THEORETICAL CHEMISTRY
this compound is stable only below 1364�, decomposing at that temp, into crystals
of platinum, and a fused mass containing about 80 per cent, of that metal. M.
Podkopajeff
gave 1266� for the m.p. of this compound. According to F. Doerinckel,
the break in the curve at 846� represents the interaction of platinum stannide and
the fused alloy to form what is probably platinum hemitristannide, Pt2Sn8.
H. St. C. Deville and H. Debray obtained this same compound by slowly cooling an
alloy of platinum with six times its "weight of tin, and then treating the product
with hydrochloric acid ; and P. Schutzenberger, by the action of hydrogen on
Pt2Sn3O2(OH)2, or on Pt2(SnO)2SnO2. The greyish-white powder contains cubic
or rhombohedral crystals. F. Doerinckel said that it exists in two allotropic
forms, one stable below 738�, and the other stable between 738� and 846�.
P. Schutzenberger observed that when oxidized in air, it forms Pt2(SnO)3 ; and
when heated in chlorine, stannous chloride distils off. F. Doerinckel observed that
the f.p. curve at 538� has a break corresponding with a reaction between the
hemitristannide
and the fused alloy, to form what is probably platinum tritaoctostannide,
Pt3Sn8. The compound forms long needles, and it decomposes when
melted. The diagram was discussed by W. Guertler, and K. Bornemann.
Three other compounds have been reported although the f.p. curve does
not indicate their existence. M. Levy and Xi. Bourgeois observed that when
PtO2.4SnO2 is reduced by hydrogen at a red-heat, and the product is treated with
hydrochloric acid, platinum tetritatristannide, Pt4Sn3, is formed in lustrous
plates with a black reflex. J. W. Mallet reported platinum distannide, PtSn2,
or Pt4Sn7, to be formed as a hard brittle mass which is easily pulverized. The
sp. gr. is 10-72. Mercury amalgamated with a little sodium attacks this product.
If an alloy with 2 per cent, of platinum is treated with very dil. hydrochloric
acid, lustrous plates appear on the surface, and these are easily detached by a
glass
rod. A more cone, acid, or the application of heat, destroys the crystals. The
analysis corresponds with platinum tetrastannide, PtSn4. N. Podkopajeff also
prepared this compound. With sodium chloride and chlorine at a red-heat, there
is formed sodium chloroplatinate, and volatile stannous chloride ; and at a
redheat,
hydrogen chloride removes all the tin as stannous chloride. Gr. Tammann
studied the subject.
A. F. Gehlen said that the alloy is tin-white, brittle, and with a laminated
texture. F. Doerinckel observed that alloys with up to 20 per cent, of platinum
arc coarsely crystalline, and tin-white ; alloys with 30 per cent, of platinum have
a finer structure and are pale grey ; alloys with between 40 and 55 per cent, of
platinum have a fine crystalline structure, and are somewhat darker in colour ;
alloys with about 62-5 per cent, of platinum have a more lustrous fracture with
with the same texture and colour ; and with more platinum, the lustre decreases,
and the colour becomes darker. According to F. M. Jager and J. A. Bottema, the
crystals of the monostannide, PtSn, are hexagonal with the same type of structure
as NiAs, and the lattice has two mols. of PtSn per cell. The lattice parameters are
a=4-103 A., and c==5-428 A. The calculated sp. gr. is 13-9. W. Lewis gave for
the sp. gr. of the tin-platinum alloys :
Tin . . 50-4 66-3 8OO 88-9 92-3 96 1OO per cent.
Sp. gr. . 10-827 8-972 7-794 7-705 7-613 7-471 7-180
F. Doerinckel found that the alloys with up to 30 per cent, of platinum are
scarcely
harder than their components, but beyond this point, the hardness rapidly
increases,
and attains a maximum with 80 per cent, of platinum. G. Wertheim found that
an alloy with the proportions Sn : Pt=50*l, has a sp. gr. 7*578 ; an elasticity
coeff.
of 5309 kgrms. per sq. mm., a tensile strength of 4-75 kgrms. per sq. mm. ; and
the velocity of sound 7-89O (air unity). F. M. Jager and J. A. Bottema gave 1281�
to 1330� for the limits of the m.p. ; this estimate is based on F. Doerinekel's
1281� ; and N. Podkopajeff's, 1330�. The heat capacity, Q cals., between B and 0�
is :
0 . . 189-74� 221-88� 418-67� 644-90� 718-30� 80206� 1044-80�
Q . . 7-3728 8-6419 16-5282 25-8917 28-9991 32-5927 43-4606
PLATINUM 213
observations on the electrical resistance and its temp, coeff. C. Hockin and
form platinum plumbide, PtPb, which was also prepared by A. Bauer by fusing
platinum with a small excess of lead, under borax, and dissolving out the excess
of lead by acetic acid. N. A. Puschin and P. N. Laschtschenko observed that the
According to A. F. Gehlen, the alloy, with platinum and 2-7 times its weight
of lead, has the colour of bismuth, splits under the hammer, and has a fibrous
fracture
; the 50 : 50-alloy has a purple colour, and striated surface, and it is hard
and brittle, and exhibits a granular fracture. "W. Lewis found the sp. gr. of some
alloys to be :
Pb . . 49-2 65-8 8OO 88-9 92-3 96-O 1OO per cent.
Sp. gr. . 14-029 12-925 12-404 11-947 11-774 11-575 11-386
F. Doerinckel said that the hardness of these alloys increases gradually as the
proportion of platinum rises to 45 per cent. ; with from 45 to 85 per cent, of
platinum, the alloys are rather harder than fluorite. Alloys containing 5 to 30 per
cent, of platinum are readily fractured by pressure. The fracture of alloys with
5 to 3O per cent, of platinum is very coarsely crystalline ; with 4O to 50 per
cent,
of platinum, the fracture is less coarsely crystalline, and reddish ; with 60 per
cent, of platinum, the fracture and colour resemble hardened steel. G. Wertheim
found the coeff. of elasticity for an alloy with the at. proportion Pb : Pt=85 : 1,
and sp. gr. 11*473, is 2684 kgrms. per sq. mm., and with alloys 6 : 1 and sp. gr.
12-207, 3107-5 kgrms. per sq. mm. ; the elastic limit of the 85 : 1 alloy is 0-4 to
0-6 kgrm. per sq. mm. ; the tensile strength is 1-65 kgrms. per sq. mm. The
velocity of sound with the 85 : 1-alloy is 4-560 (air unity), and with the 6 : 1-
alloy,
4*756. A. Matthiessen found the electric conductivity of an alloy with the at.
proportion Pb : Pt= I : 0-1 to be 5-18 (silver IOO) at 21-4�. C. Barus measured
f-he electrical resistance and its temp, coeff. According to N. A. Puschin and
P. N. Laschtschenko, the e.m.f. of the alloys against lead in JV-Pb(N03)2 soln.
furnishes a curve with two breaks, corresponding respectively with platinum
plumbide, and diplumbide. For alloys with up to 33 at. per cent, of lead, the
e.m.f. is the same as for lead ; there is then a sudden drop corresponding with
PtPb2 ; and there is a second fall with 50 at. per cent, of lead corresponding with
by exposure to air ; and H. St. C. Deville found that the lead of alloys with only
a small proportion of platinum slowly passes into carbonate. F. Doerinckel
showed that the grey, freshly fractured surfaces of alloys with 5 to 30 per cent,
of
platinum oxidize rapidly on exposure to air ; the alloy with 2*5 per cent, of
platinum
oxidizes rapidly on exposure to air ; the alloy with 2-5 per cent, of platinum
oxidizes
more rapidly than lead ; air acts very slowly on alloys with 40 to 5O per cent, of
platinum, and not at all on alloys with more platinum. A. F. Gehlen found that
when the alloys are heated to redness in air, only part of the lead separates from
the platinum ; and that the separation continues only so long as the alloy remains
fusible ; the subject was studied by H. St. C. Deville and H. Debray. A. Bauer
and P. von Mertens showed that sulphuric acid decomposes an alloy with
IO per cent, of platinum slowly and incompletely ; and an alloy with 2 per cent,
of platinum suddenly and completely at 260� to 280�. According to A. von der
Ropp, nitric acid attacks all alloys with up to 50 per cent, of lead rather
rapidly,
and the attack with alloys containing more platinum was found by F. Doerinckel
to be slower. H. Senn discussed the residues, and H. Debray, the explosive residues
�vide zinc. Some platinum passes into soln. along with the lead. C. Winkler
found that with alloys containing [Pb] per cent, of lead, [Pt] per cent, of
platinum
passes into soln. :
y*
by melting a mixture of the two metals in an oxyhydrogen
furnace. W. Guertler made some obser2000
ls r
1/777*
1600
are magnetic with a maximum at 10 per cent, of chromium ; the magnetic transition
point is 390� to 400�. E. Janecke discussed the ternary systems involving
platinum-chromium-copper alloys, also the platinum-chromium-silver alloys,
and the platinum-cnromium-gold alloys.
W. C. Roberts-Austen showed that at 4:92� 1-69 grms. diffuse per sq. cm. per
day, or 1*96 X 10~5 grm. per second in iron. M. G. Korsunsky said that solid
PLATINUM 217
soln. are formed. E. Isaac and G. Tammann observed that the two metals at a
high temp, form a continuous series of solid soln., Fig. 56, but as the temp,
falls, this
decomposes into two other series of solid soln. extending from 0 to 50 per cent,
platinum,
and from 60 to 100 per cent, platinum.
20 40 60 80 100
Plrttinum-lron Alloys.
According to E. Isaac and G. Tammann, the colour of the alloys becomes paler
as the proportion of platinum increases. The structure of the alloys with about
88 per cent, of platinum is very similar to that of native ferroplatinum.
G. H. Billings added that the fracture of alloys with 1 per cent, of platinum is
not
essentially different from that of iron, but the grain is rather finer, resembling
more or less closely the fracture of a 0-3 per cent, carbon steel. W. A. Nemiloff
discussed the microstructure of the alloys. The sp. gr. of an alloy with 0-82 per
cent, of platinum, and 008 per cent, of carbon is 7-861. W. Lewis gave for the
sp. gr. of the platinum-iron alloys :
Iron . 56-4 76-9 83-7 90-9 92-3 1OO per oent.
Sp. gr. . 9-9Ol 8-7OO 8-202 7-862 7-800 7-1OO
E. Isaac and G. Tammann said that the hardness of the alloys decreases with a
proportion of platinum up to 5 per cent., and the hardness then gradually rises as
the proportion of platinum increases up to 40 per cent, of platinum ; beyond that
point up to 9O per cent, platinum, the hardness remains constant. The brittleness
of the alloys reaches a maximum at 50 per cent, platinum. W. A. Nemiloff observed
BrinelFs hardness for the annealed (A) and quenched (Q) alloys and obtained for
alloys with :
96-32% wt.
Pt
100-81
INORGANIC AND THEORETICAL, CHEMISTRY
The results are summarized in Fig. 57. In the quenched samples two solid, soln.
are indicated with 0 to 40 at. per cent, of platinum, and 35 to 1OO at. per cent,
with the annealed samples, the first maximum corresponds with the formation of
a platinum ferride, PtFe. G. H. Billings said that platinum makes iron harder,
but less so than does the same proportion of carbon. E. Jiinecke observed that the
lowest m.p., 1500�, occurs with alloys having 7 at. per cent, of platinum. W. Wien
0 20 40 GO 80 Job � 20 40 60 80 70�
Fro. 57. TheAtom per cent. Pt
Hardness of the IronFia.
Atom per cent. Pt
58. The Temperature Coefficient of the
Platinum Alloys. Electrical !Resistance of the Fe-Pt Alloys.
studied the optical properties of an alloy of iron and platinum. C. Barus measured
the electrical resistance and its temp, coeff. L. AV. Haase studied the
oxygen depolarization current ; and J. Wiirschmidt, the thermoelectric force.
H. St. C. Devillc and H. Debray said that alloys with 17 and 20 per cent, of iron
are magnetic. A. Daubree found that an alloy with 16-87 per cent, of iron
exhibits magnetic polarity, but an alloy with 11 per cent, of iron is only feebly
magnetic. F. Aallot studied the Curie point, and the magnetic moment.
W. Jellinghaus studied the coercive force.
C. F. Schonbein observed that an alloy with 1 per cent, of platinum is not
attacked by nitric acid, and this was confirmed by JP. Monnartz. The alloys are
soluble in aqua regia. According to J. B. J. D. Boussingault, if the pyrophoric
alloy, just mentioned, be placed in hydrochloric acid, without coming in contact
with air, part of the iron dissolves with, the evolution of hydrogen. The heavy,
black powder which remains as a residue after washing contains about 20 per cent,
of iron which may be dissolved out with nitric acid, and it also contains a trace
of
moisture but no hydrogen. The residue takes fire in air below a red-heat, and
burns with the emission of sparks. Sometimes the combustion begins at the
hottest part, and spreads throughout the mass with a red light, as in the burning
of tinder. The powder, after combustion, gains 1 per cent, in weight.
J. Murray did not obtain alloys of platinum and steel at the temp, of an alcohol
flame. W. Lewis said that platinum forms with cast iron a dark, malleable, very
hard alloy ; G. H. Billings prepared an alloy with 4 per cent, platinum with cast
iron containing 2 per cent, of carbon, and found that it could be hammered and
rolled though showing signs of red-shortness. J. Stodart and M. Faraday described
the following platinum-steel alloys : 9 : 2-alloy : perfect alloy, sp. gr. 15-88,
does
not tarnish in air ; 1 : 1-alloy : crystalline structure, sp. gr. 9-862, takes high
polish, does not tarnish in air ; 1 : 8-alloy : finely damasced alloy ; 1 : 10-
alloy :
sp. gr. 8-1 ; 1 : 67-alloy : best adapted for cutting instruments ; and 1 : 100-
alloy :
uniform surface, fine fracture, not so hard as silver-steel, but is much tougher.
J. R. Breant, and H. Bush found that the 1 : 200 alloy can be damasced very well
and is adapted for razors. H. Remy and H. Gonnington studied the catalytic effect
in the hydrogen-oxygen reaction. J. Stodart and M. Faraday found that steel
PLATINTJM
alloyed with a small proportion of platinum dissolves in dil. sulphuric acid more
quickly than with steel without the platinum ; the acceleration can be detected
with 0*0025 part, and is most marked with 0-005 to 0-01 part ; with 0-025 part,
the solubility is perceptibly slower, and steel with 0-5 part does not dissolve
more
quickly than steel alone ; an alloy of 2 parts of steel with 9 of platinum is not
affected by dil. sulphuric acid. These alloys behave in an analogous way with
other acids. When 100 parts of steel are alloyed with 1 part of platinum, or any
other metal insoluble in nitric acid, and treated with dil. sulphuric acid, and the
W. Jellinghaus measured the coercive force of the alloys. H. Remy and H. Gonnington
studied the catalytic effect of the alloy in the hydrogen-oxygen reaction.
E. Janecke studied the ternary systems involving the platinum-cobalt-copper
alloys ; the platinum-cobalt-silver alloys ; and the platinum-cobalt-iron alloys.
The association of nickel with native platinum was observed by A. Terreil,20
and A. Daubree. W. A. Lampadius prepared a platinum-nickel alloy by heating
a mixture of equal parts of the two metals on charcoal burning in oxygen ; and
C. Barus melted the metals in the oxy hydrogen flame. L. Nowack discussed the
so-called white gold alloys. The alloy with 5 per cent, of nickel is used as the
heating
filament in radio tubes. The alloys were studied by J. Cournot, W. Guertler, and
L. Nowack. According to M. G. Korsunsky, solid soln. are formed. W. A. Lampa
22O INORGANIC AND THEORETICAL CHEMISTRY
dius said that the pale yellowish-white alloy is quite malleable, takes a high
polish,
and is equal to copper in fusibility, and to nickel in magnetic power.
1700 [
20 40 GO 80 100
Curves of the Ni-Pt Alloys. and J. Wurschmidt measured the thermoelectric force ;
that the reactions are limited with alloys having up to 25 per cent, of platinum.
0 20 40 60 80 100 20 40 60 80 100
Atomic per cent of platinum Atomic per cent, of platinum
Fio. 60.�The Hardness of the Fio. 61. The Electrical Resistance and TemNi-
Pt Alloys. perature Coefficient of the Ni-Pt Alloys.
platinum-ruthenium alloy, 90 : 10, against platinum, and found that with the cold
joint at 0�, the thermoelectric force, E millivolts at :
..
300\
-�5.**
1600Y I 260 ^J
T^Z $220
�=rr*
\&p
1400 *� 180
��^
I. 140 � 1200
20 40 60 80 100 0 20
40 60 80 100
Atom per cent Pt
2000 2000'
Z1
Z1
/flflff" 1970"
moo�\ mod
1800c 180d
\1773-t
11771�
1700�\ I . .. nod
20 40 60 80 100
0 20 40 BO 80 100
*, 4 0O
� 3-8O [��-
G. K. Burgess and co-workers observed that the presence of rhodium reduces the
loss in weight of platinum by volatilization at temp, exceeding 900�, so that best
quality platinum crucibles might have 3 to 5 per cent, of rhodium and be free from
iron, iridium, and other impurities. The sp. gr. of the alloys by J. S. Acken are
222 INORGANIC AND THEORETICAL, CHEMISTRY
summarized in Fig. 67, and their hardness, in the same diagram. W. A. Nemiloff
and N. M. Voronoff found the Brinell's hardness of the alloy to be :
Rhodium 7O 20 40 60 80 90 100 at. per cent.
��
0-005r
�--1
wo\-
Rochwnll
80 25
J20 IL
CJ
=* 60
^*^
40
20 40 60 80 100
20 40 60 80 100 Per cent, (by weight) of Rhodium
20 Fio. 68.�Tho Electrical .Resistance arid
Rhodium-Platinum Alloys.
the Rhodium-Platinum Alloys.
can be worked, but those with higher percentages work with difficulty. Rhodium
does not harden platinum so much as ruthenium, or iridium, but it hardens the
metal more than palladium. The Brinell's hardness, U, the tensile strength in
kgrms. per sq. mm., the resistance R ohms per million ft., and the temp, coeff.
a per degree between 0� and 1200�, are :
Annealed J1 2Q0�
6k 9O 107 138
103 HO 125 134
R . r
0-00195 0-00135 O-00120
the alloys observed by J. S. Acken, are indicated in Fig. 69. W. A. Nemiloff and
N. M. Voronoff found the sp. resistance, UxIO 6, to be, at 25� and 100� :
Rhodium 0 IO 20 30 40 50 60 1OO at. %
10-88 16-97 19-69 20-40 19-83 17-95 16-35 602
13-79 19-64 2203 22-42 22-07 19-70 18-09
A. TJ. Day and R. B. Sosman found the thermoelectric force, E millivolts, of the
alloys against platinum to be :
Pt : Rh . o� 200� 400� 600� 800� 1000� 1200� 1400� 1600�
95 : 5 O 0-55 2-53 3-92 5-33 6-79 8-20 9-82 11-31
9O : IO 0 0-64 3-25 5-23 7-33 9-57 11-93 14-34 16-75
85 : 15 0 0-65 3-45 5-71 8-23 10-96 13-87 16-89 19-94
--,
rature
0-298
10()� 0-020 0-180 O-643 O-621 0-651 0-676 0-672 0-623 0-696
200� 0-042 0-372 1-436 1-443 1-515 1-592 1-59O 1-492 1-606
400� 0-087 0-758 3-249 3-5OO 3-7OO 3-914 3-92O 3-77O 3-915
600� O-130 1-128 5-221 5-936 6 356 6-732 6-747 6-602 6-772
800� 0-171 1-489 7-331 8-702 9-446 9-996 10028 9-931 10-158
1 O00� 0-213 1-852 9-57O 11-771 12-96O 13-714 13-776 13-745 14-050
1200� 0-254 2-218 11-922 15121 16-876 17-863 17-986 18024 18-432
L. Holborn and F. Helming found that the loss in weight of the thermocouple
near the m.p. is less with platinum-rhodium alloys than it is with platinum-iridium
Gr. R. Levi found that the presence of 10 per cent, of rhodium diminished
the catalytic activity of platinum in hydrogen dioxide. A rhodium-platinum
gauze has been recommended as a catalyst in the oxidation of ammonia.
platinum. G. Tammann and H. J. Rocha observed that alloys -with less than
30 per cent, of palladium have a granular structure and those with more than
40 percent, of palladium have a dendritic structure. E. R. Thews discussed some
uses of the alloys. There appears to be a continuous series of solid soln. T. Barth
and G. Liunde studied the lattice constant of the alloys. G. Tammann and
0 20 40 60 80 100 20 40 60 80 100
Atom per cent. Platinum Atom per cent. Platinum
FiG. 09. The Tensile Strength Fio. 70.�The Kleetrical Properties of the
Alloys.
The values for the electrical conductivity XlO-4 at 0� and its temp, coeff. between
0� and 160� are indicated in Fig. 70; and the thermoelectric force of the alloys
against platinum, expressed in millivolts, are summarized in Fig. 71. C. Barus
made observations on the electrical resistance of the alloys. L. Holborn and
X X 10� 108 112 1-32 1-41 1-60 219 2-55 4-25 5-20
wo
to the square root of the press., and it increases with rise of temp. The results
are
summarized in Fig. 72. G. Borelius and S. Lindblom studied the passage of
hydrogen through the alloy. G. Tammann and
Hydrogen in Platinum-Pal
2� times the hardening effect of iridium on platinum, and it also increases the
electrical resistance 2� times as quickly. An alloy with over 10 per cent, of
osmium
is difficult to -work owing to its hardness and lack of ductility�vide Table IV.
The annealing must be done under reducing conditions or the osmium burns off.
can be cold-worked, and that it is hard, and is only slightly affected by aqua
regia.
O. J. Broch and co-workers, and H. St. C. Deville and H. Debray described the
preparation of the platinum-iridium standard measure for the Comite International
des Poids et Mesures. F. E. Carter noted iridium can be worked at high temp.,
but a little platinum induces brittleness. Iridium is employed to harden platinum
to enable it to be used in chemical ware, electric work, and jewellery. In medium
hard jewellery, the platinum contains 5 per cent, of iridium, and in hard
jewellery,
10 per cent. The limit of workability is 30 to 35 per cent, of iridium. The alloys
are solid soln., and any coring in the crystal grains can be rectified by
annealing.
Segregation does not usually occur. F. Korn, and E. A. Smith discussed the
application of the alloys in the jewellery trade, etc. H. St. C. Deville and H.
Debray
found the sp. gr. of alloys with 10, 15, 33*3, and 95 per cent, of iridium to be
respectively
21-615, 21-618, 21-874, and 22-384. T. Barratt and R. M. Winter gave for
the thermal conductivity of alloys :
17� ibo�
Per cent, iridium . . . io 15 20 10 15 2O
CaIs. per cm. per sec. per degree . 0074 0-056 0042 0075 0-059 0042
O. Feussner and L. Miiller, and L. Muller measured the f.p. of alloys of the two
metals, and the results are summarized in Fig. 73. F. E. Carter said that the
alloys do not oxidize above 1150�, but iridium slowly volatilizes from them ; a
film of oxide forms when the alloy is cooled in the range 1150� to 900�. K.
Friederich
studied the magnetic properties of the alloys. They darken superficially when
heated within the range 900� to 1100�, presumably owing to the formation of an
oxide ; at a higher temp., the oxide is decomposed and the surface regains its
colour. Iridium itself acquires a bluish film under similar conditions. The alloys
begin to lose weight above 900� owing to the volatilization of the iridium oxide.
Hence for high temp, gravimetric work iridium is objectionable in platinum
crucibles, and in thermocouple work. E. Haber studied the resistance of
platinumiridium
electrodes in the electrolysis of hydrochloric acid; and J. Liike and R. Fricke,
the decomposition of nitrous oxide by glowing wires of the alloy. B. S. Srikantan
studied the reaction H2-I-CO2^CO-I-H2C) on platinum-iridium alloys ; H. Remy'
PL.ATINUM 227
2400
?34<f\
2300� 300
C/
/ ^^2�
/ 7/ "J
2000 ^ 30
Ff/
150 *
I / /
/
c
1800� 10 \/�\ 50
\l770�
1700
20 40 60 100
0 20 40 BO 8O Wf)
Per cent of Iridium
KiG. 73. The Liquidus KiG. 74. The Tensile Strength and Hardness of
Curvn of !Platinurn-Platinurn-Iridium Alloys.
lridium Alloys.
hardness are summarized in Fig. 74, and the same diagram gives the tensile strength
of the alloys in kgrms. per sq. mm.�vide Table IV. �,4 00, 1
J. Weerts obtained the dimensions a of the parameters
of the face-centred cubic lattice of the alloys shown in ' 3-90
Ar_
Fig. 75. F. Goldberger and O. Kienberger studied the � 3-8O1
20 40 60 80 100
W. Geibel observed that alloys made into wires 1 mm. FIG. 75. The I-attice
Paradiameter,
had a breaking load, in kilograms, of meter of the Ir-Pt Alloys.
Iridium O 5 IO 15 2O 25 3O 35 per cent
K. Steinmann's results for the effect of annealing on the tensile strength are
summarized
in Fig. 76. K. B. Thews gave 40 kgrms. per sq. mm. for a 5 per cent,
iridium alloy, and 100 kgrms. per sq.
mm. for a 25 per cent, iridium alloy.
E. M. Wise and J. T. Eash gave for
the alloy with 20 per cent, iridium,
reduced 50 per cent, by cold drawing,
the ultimate strength 140,500
lbs. per sq. in., proportional limit
101,000 lbs. per sq. in., elongation
2-5 per cent, in 2 in., a reduction
in area of 85 per cent. ; after a
softening anneal at 1400�, the ultimate
strength was 93,500 lbs. per sq.
in. ; proportional limit, 59,5CX) lbs.
per sq. in. ; elongation, 20 per cent,
in 2 ins., and reduction of area, 88 0� 200� 400" 600� 800� 1000T 1200 1400
Fio. 76. The Effect of the Annealing Tempera
uoo�
The ductility data show that with increasing iridium content, higher annealing
temp, are required. The hard-worked alloys do not show a very marked difference
in ductility until over 20 per cent, is attained, when there is a decrease. F.
Korn,
and N. S. Kurnakoff studied the subject.
Iridium
The results at 25�, and the temp, coeff. of the binary alloys between 25� and 100�
are indicated in Fig. 77. L. Guillet and M. Ballay observed a slight increase in
the resistance when the alloy is cold-worked and annealed at 950�. J. Obata
studied the effect of a magnetic field, and J. L. R. Morgan and co-workers, the
0 004
40-^
^30\
? -
00
003 �=
002
Ca
#20Ct:
I
oooi Ji
"^ l
IO
20 40I
60 80 100 �0� 200� 400� 600� 8006 1000*1200�
Fia. 77.�The
Per cent of Iridium
Electrical "Resistance
Iridium Alloys.
of the Platinum FIG.
78. The Thermoelectric
Force of the Platinum-iridium
Alloys.
hydrochloric acid, and the alloy with 20 per cent, is not attacked at all. G. R.
Levi
observed that the presence of 10 per cent, of iridium decreased the catalytic
activity
of platinum on hydrogen dioxide. M. Delepine noted the dissolution of the
platinum-iridium alloy in sulphuric acid at the rate of 0*10 grm. per hour per
sq. dm. at 265�.
H. St. C. Deville and H. Debray discussed the platinum-iridium-rhodium
alloy which occurs as " a triple alloy of an invariable composition " ; and they
prepared the quaternary platinum-iridium-rhodium-tin alloy. F. E. Carter said
that the platinum-iridium-rhodium alloys are used for radio tubes. The
platinumiridium-
osmium alloys are used for sparking plugs. C. O. Bannister and E. A. du
Vergier discussed the analyses of the platinum-iridium alloys.
PLATINUM 229
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234 INORGANIC AND THEORETICAL, CHEMISTRY
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PLATINUM 235
W. F. .Bruce discussed the subject. J. J. Uerzelius said that the hydrate can be
deprived of its water by a gentle heat ; and C. Engler and L. Wohler added that the
water is difficult to drive off, and requires a temp, of at least 300�. L. Wohler
found that the expulsion of the water is attended by some decomposition of the
oxide so that the pure oxide free from hydrate cannot be so prepared.
J. W. Dobereiner heated calcium chloroplatinate, Ca2Pt2O5Cl2.7H2O, in a covered
crucible, and obtained a violet powder which becomes very hot when treated with
water ; the lime and calcium chloride can be removed by water and dil. nitric
acid, and there remains platinous oxide.
J. W. Dobereiner's product is a violet powder ; J. J. Berzelius' product is a
grey powder ; and L. Wohler's, velvety black. P. Laffitte and P. Grandadam
gave 14-9 for the sp. gr. at 15�. H. G. Howell and G. 33. Rochester studied the
band spectrum. Li. Wohler said that platinous oxide is perceptibly decomposed
at 430� ; P. Laffitte and P. Grandadam said that it decomposes at 560� ; and,
according to J.J . Berzelius, the oxide is completely decomposed at a red-heat so
that the product of the operation above cited by L. Gmelin is not likely to have
been the monoxide. J. J. Berzelius also observed that when the monoxide is
mixed with powdered charcoal, and heated to redness, there is a strong detonation.
L. Wohler observed that the oxide very slowly dissolves in boiling hydrochloric
236 INORGANIC AND THEORETICAL, CHEMISTRY
acid, and that the rate of dissolution is catalytically increased in the presence
of
a trace of platinous chloride, or of a soln. of platinous hydroxide in hydrochloric
As indicated above, L. Wohler showed that the oxygen associated with ordinary
platinum black is in part present as hydrated platinous oxide, Pt0.nH20.
in 30O mols of water with 2 mols of a dil. soln. of sodium hydroxide, and
washed the black precipitate first by decantation, and afterwards on a
filter� L. Mond and co-workers observed that the product is always contaminated
with chlorides, and L. Wohler, that it has a tendency to oxidize unless it is
washed
in an atm. of an inert gas�say carbon dioxide�and dried in a desiccator first
filled with carbon dioxide, and afterwards evacuated. F. Martin, and L. Wohler
and F. Martin prepared the hydrated oxide by dropping a soln. of sodium carbonate
into one of potassium chloroplatinite�or of a soln. of hydrochloroplatinie acid
which has been treated with sulphur dioxide�and boiling the liquid in an atm. of
carbon dioxide until the black, hydrated oxide is precipitated ; the product is
again
boiled with a soln. of sodium carbonate to remove the chlorides from the
precipitate
which is then washed and dried as before.
The hydrated monoxide is a black powder which, according to L. Wohler, has
the composition of a tnouohydrate, or platinous hydroxide, Pt(OH)2, if it has been
dried for a sufficient length of time at 100�. L. Wohler and F. Martin considered
this hydrate to be platinous acid, H2PtO2, which forms salts, platinites. J.
Thomsen
obtained the hydroxide by boiling a dil. aq. soln. of potassium chloroplatinite
with
the proper proportion of soda-lye ; and L. Wohler and W. Frey, by boiling in an
atm. of carbon dioxide a soln. of potassium chloroplatinite mixed with the
calculated
quantity of sodium hydroxide, boiling the precipitate several days in water,
and drying in an atm. of carbon dioxide for 48 hrs. at 120� to 150�. The
precipitate
obtained at ordinary temp, approximates to the dihydrate, Pt0.2H2O.
out of contact with air, potassium platinite is formed, and it yields a dark soln.
in water. Likewise when platinous chloride is decomposed by potash-lye, a dark
green soln. of potassium platinite is formed. L. N. Vauquelin obtained what was
regarded as sodium platinite by decomposing a soln. of platinous chloride with an
excess of soda-lye.
Kalle and Co. prepared colloidal platinous hydroxide by mixing a dil. soln.
of sodium protalbinate and sodium carbonate with a dil. soln. of platinous chloride
and sodium acetate, and warming the mixture on a water-bath at 70� to 80�.
The dialyzed soln. on evaporation furnishes dark green plates which form a
colloidal
soln. with water. A. Skita and W. A. Meyer used gum arabic as protective colloid.
PLATINUM 237
IJ. Mond and co-workers observed that hydrated platinous oxide loses the
greater proportion of its water at 200� to 250� ; and C. Engler and TLt. Wohler
added that the last traces of water are driven off with difficulty, and a temp.
over 300� is required. Li. Wohler observed that after heating 2 days on a
waterbath,
the hydrate contained 13-4 per cent, of water, and 8-5 per cent, of oxygen ;
after heating 14 days at
The calculated oxygen for PtO is 7*6, and the calculated H2O for Pt(OH)2 is
6*3 per cent. L. Mond and co-workers found that oxygen is lost between 237�
and 360�, and that after removing water, the platinous oxide gives off water very
slowly at 380� ; and at 440� the greater part of the oxygen can be gradually pumped
off, but a red-heat is necessary to remove all the oxygen. The subject was studied
by J. Thomsen. JL. Wohler found that in vacuo, or in an atm. of carbon dioxide,
decomposition begins at 400�, but no decomposition is perceptible at 365�. The
velocity of decomposition decreases with decreasing proportions of water. Platinum
monoxide decomposes when heated into platinum and platinum dioxide, which
dissolves in the monoxide lowering its dissociation press. Thus, a sample of
monoxide at 510� gave a dissociation press, of 752 mm. ^ "which in 4O hrs.
decreased
to 203 mm. J. Thomsen gave for the heat of formation : 2Pt4-O2-J-2H2O
=-2Pt(OH)2-[-38*44 CaIs. M. Ie Blanc and H. Saehse said that the conductivity
of the oxide is small.
concurrent reactions progresses more rapidly than the second. J. Thomsen noted
that the hydrated oxide is freely soluble in hydrobromJc acid ; and L.. Wohler,
and J. Thomsen found that platinum monoxide oxidizes hydriodic acid. W. Pluddemann,
-with the hydrated oxide dried in a desiccator, but when dried at 110�, it is
soluble
in fuming sulphuric acid at 200�. The dry or moist hydrated oxide is virtually
insoluble in nitric acid. It transforms arsenic trioxide into the pentoxide. C.
Engler
and L. Wohler found that carbon monoxide reduces platinous oxide to platinum ;
and E. von Meyer observed that it oxidizes carbon monoxide at ordinary temp,
more readily than does platinum dioxide. P. V. McKinney and co-workers studied
the reaction. J. Thomsen observed that formic acid reduces the oxide to metal
with the evolution of carbon dioxide. E. Bullnheimer observed that platinum
oxide is reduced to the metal by glycerol. Li. Wohler observed that the
freshlyprecipitated
and moist hydrated oxide is virtually insoluble in dil. or cone, acetic
acid. Boiling soln. of acetic acid, oxalic acid, and other organic acids are
oxidized
by the hydrated monoxide with the evolution of carbon dioxide. A boiling soln. of
glucose is similarly oxidized. The hydrated oxide is soluble in a soln. of
potassium
cyanide. C. Engler and L. Wohler noted that tincture of guaiacum, and diphenylamine
Derivatives of the three types of ammines have been obtained, namely, the
di-, tri-, and tetra-ammines. J. Reiset 3 prepared platinous tetramminohydroxide,
[Pt(NH4J4](OH)2, by adding the theoretical proportion of baryta -water to a soln.
of platinous tetramminosulphate, evaporating the nitrate out of contact with air,
and finally in vacuo over sulphuric acid until it solidifies. The mass of white,
acicular crystals is deliquescent in air. It melts at 110� and loses with
intumescence
2 mols. of ammonia and 1 mol. of water so that Pt(NH3J2O remains. J. Thomsen
gave for the heats of neutralization of 2 eq. of an aq. soln. with sulphuric acid
be 30-84 CaIs., and with hydrochloric acid, 27*29 CaIs. The mol. conductivities of
a mol jof the compound in 500, IOOO, and 20OO litres were found by A. Werner and
A. Miolati to be, respectively, 247-6, 260-8, and 267-2. G. Bredig gave 74-1 for
the
speed of migration of the �[Pt(NH3)4]--ion. J. Reiset said that the aq. soln. has
an
alkaline, and caustic taste, and does not give off ammonia when boiled ; the aq.
soln. absorbs carbon dioxide from the .atmosphere, and, like a soln. of potassium
hydroxide, it decomposes starch-sugar ; and like a soln. of potassium hydroxide,
it precipitates silver oxide from a soln. of silver nitrate. M. Peyrone observed
that
the compound is slightly soluble in alcohol. It forms salts when treated with
acids. It has been called Reisers first base, when [Pt(NHg)2J(OH)2 represents
Reiset's second base. The constitution was discussed by C. W. Blomstrand,
H. and A. Euler, C. Gerhardt, W. Odling, C. Weltzein, and A. Werner.
W. Odling prepared platinous dihydroxydiammine, [Pt(NHa)2(OH)2], by the
action of baryta water on the corresponding sulphate. The salt crystallizes easily,
decomposes at 100� ; and R. Uhlenhut, that it darkens at 169�, and explodes about
173�. H. Alexander, and R. Uhlenhut found that the salt is insoluble in hot or cold
water ; easily soluble in mineral acids, but it requires warm sulphuric acid for
dissolution, and it is decomposed by the cone. acid. The base is insoluble in
alcohol, and ether ; it is soluble in formic and acetic acids ; and the
hydrochloric
acid soln. reduces Fehling's soln. and also gold chloride soln. in the cold. The
base forms salts with acids. The constitution was discussed by A. Werner.
P. Klason, and W. Odling obtained the cis- and trans-forms of this base. P. T.
Cleve
prepared platinous tetramminodihydroxide, Pt2(NH3)4(OH)2, by the action of a
boiling soln. of sodium hydroxide on platinous c*�s-dichlorodiammine, and drying
the washed product at 100�; the dirty white powder explodes above 100�. It is
insoluble in water and is converted by acids into salts. F. Hoffmann prepared
platinous dihydroxylaminediamminohydroxide, [Pt(NH3)2(NH2OH)2](OH)2, from
the corresponding chloride ; he also prepared platinous
dihydroxylaminebispyridinehydroxide,
TPt(NH2OH)2(C5H5N)2I(OH)2, as a double salt with
platinous chloride. A. Werner obtained platinous bispropylenediaminehydroxide,
rPt{C3H6(NH2)2}2](OH)2. H. Wolfram, H. Alexander, and F. Hoffmann prepared
cis- and trans-forms of platinous dihydroxydihydroxylamine, [Pt(NH2OH)2(OH)2J;
H. Wolfram also prepared platinous oxyhydroxylaminoethylamineoxide,
2[Pt(NH2OH)2O][Pt(NH2OH)(C2H5NH2)O].
S. G. Hedin prepared platinous quaterpyridinehydroxide, [Pt(C6H6N)4](OH)2 ; be also
as well as the dihydrate and the decahydrate. This compound in its a- and /3-forms
bistbiocarbamidebispyrldinehydroxide, [Pt(C5H5N)2{CS(NHa)2}2](OH)2 ; O.
Quesneville,
[Pt(Na3PO3)O].
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Monit. Scient., (3), 6. 667, 1876 ; J. Reiset, Ann. Chim. Phys., (3), 11. 423, 1844
;
Liebig's Ann., 52. 262, 1844; Journ. prakt. Chem., (1), 33. 321, 1844*; Compt.
Rend., 11. 711,
1840; 18. HOO, 1844; C. Rudelius, Lunds Arsskr., (2), 22. 19, 1887; M. G. Saillard,
Compt.
Rend., 74. 1527, 1872 ; Bull. Soc Chim., (2), 18. 254, 1872 ; P. Schutzenberger,
Bull. Soc
Chim., (2), 17. 53O, 1872 ; P. Schutzenberger and C. Fontaine, ib., (2), 18. 101,
1872 ;
P. Schutzenberger and M. G. Saillard, ib., (2), 18. 112, 1872 ; N. Tarugi, Oazz.
Chim. MUd., 33.
ii, 451, 1903 ; J. Thomsen, Journ. prakt. Chem., (2), 13. 247, 1876 ; R. TJhlenhut.
Liebig^s Ann.,
311. 121, 1900; 312. 235, 1900; C. Woltzien, Liebig's Ann., 97. 27, 1856 ; A.
Werner, Nenere
Anschauungen auf dent Oebiete der anorganischen Chemie, Braunschweig, 1923 ; Zeit.
anorg.
Chem., 3. 303, 1893 ; 21. 235, 1899 ; A. Werner and A. Miolati, Zeit. phys. Chem.,
12. 5O, 1893 ;
14. 507, 1894 ; H. Wolfram, Ueber aethylaminhaltige Platinbasen, Konigsberg, 1900.
� 18. Intermediate Oxides
of hydrates, as !L. Wohler also showed this to be the case with the alleged
hydrated
platinosic oxide.
According to "VV. Li. Dudley,2 when spongy platinum is fused with sodium
dioxide, and the product washed with water, a yellow substance is obtained which
it is supposed to be a sodium salt of platinum sesquioxide, Pt2O3.2Na2O ; when
the alkali of this salt is neutralized with acid, and the product washed, there
remains platinum sesquioxide or platinum hemitrioxide, Pt2O3.2H2O. When this
dihydrate is heated to 100�, it loses no "water ; at 385�, it loses 5*22 per cent,
of
water ; and at 450�, it forms a dark brown, amorphous powder of the anhydride,
Pt2O3. J. J. Berzelius supposed that this oxide is formed when powdered platinum
is heated with a mixture of potassium nitrate and hydroxide. W. L. Dudley
represented
the formation of the compound by 2Pt+3Na202== Pt2O3.2Na2OH-Na2O ;
followed by Pt2O3.2Na2O+4CH3COOH=Pt2O3.2H2O 4-4NaC2H3O2, or else
Pt2O3.2Na2O+4H2O=Pt2O3.2H2O+4NaOH. M. Blondel obtained the dihydrate,
by heating the trihydrate to 100� to 105�. L. Wohler found that the product
always retains about 2 per cent, of Na2O very tenaciously, and it behaves like a
mixture of sodium platinate and platinic hydroxide. W. L. Dudley observed that
the dihydrate is reduced to platinum black by boiling sodium hydroxide and
alcohol ; it is insoluble in nitric acid, sulphuric acid, and cold, dil.
hydrochloric
acid, but it is dissolved by hot, cone, hydrochloric acid, in the presence of air,
with
the formation of platinic chloride.
1 S. M. Jorgensen, Journ. prakt. Chetn., (2), 16. 344, 1877 ; L. "Wohler, ZeAt.
anorg. Chem.,
platinic chloride ; C. Marie, that the hydrate is formed by the action of oxidizing
M. Blondel, and H. Topsoe found that the tetrahydrate loses 2 mols. of water
slowly at 100� and becomes yellowish-brown ; at 120�, another mol. of water is
given
off; and at 150�,it darkens in colour owing to reduction. These results do not
agree
with the observations of L. Wohler, who found that when the white hydrate
precipitated
from a cold soln. is dried in air, it is coloured straw-yellow or nankeenyellow,
and it contains 4 mols. of water ; if precipitated from boiling soln., the
product is ochre-yellow, and it contains 3 mols. of water, and the same results
are obtained if the product is dried a short time over calcium chloride ; if dried
for a long time over cone, sulphuric acid, or a short time on a water-bath, the
product is rose-yellow or amber-brown, and contains 2 mols. of water ; and if
dried for a long time at 100�, the colour is dark brown or deep black, and it
contains
1 mol. of water. The last mol. of water is difficult to remove, for after 10 days
at 180�, the product contained 6*3 per cent, of water ; after 8 days at 250�, 4-6
per
cent. ; after 24 hrs. at 410� to 450�, 3 per cent. ; after heating in oxygen at
400�,
2*6 per cent. ; and it decomposes into its elements when heated in oxygen above
510�. F. Becker was unable to dehydrate the hydrated dioxide without some
decomposition. C. Marie also noted that the oxide is decomposed at a dull red-heat.
As just indicated, Li. Wohler obtained the monohydrate, PtO2.H2O, from a higher
hydrate ; and E. von Meyer, by evaporating a mixed soln. of platinic chloride and
an excess of sodium carbonate, to dryness, -washing the residue with hot water,
digesting the solid with dil. acetic acid, and then washing with hot water. The
product is black. M. Blondel reported the polymer, (PtO2-H2O)5, to be formed by
the action of boiling water for 14 days on (Pt02)6.2HC1.9H20, and drying the
product at 100� to 105�. E. von Meyer reported the hemilrihydrate, PtO2-I^H2O,
to be formed by drying at 110� the product of the action of sodium carbonate on
platinic chloride. H. Topsoe prepared the dihydrate, PtO2.2H2O, by heating the
higher hydrate at 100�, and it was obtained by L. Wohler by drying the higher
hydrate for a long time over cone, sulphuric acid. J. J. Berzelius observed that
alkalies precipitate basic double salts from soln. of most platinic salts, but with
platinic nitrate and potash-lye, the hydrate is first precipitated, and, after
that,
the double salt. L. Pigeon heated a mixture of platinic chloride and sodium
hydroxide in a sealed tube for many hours at 180�, and after washing the
precipitate
with water, dried it in vacuo at ordinary temp. H. Topsoe evaporated a
soln. of platinic chloride mixed with an excess of sodium carbonate to dryness on
a water-bath, washed the product with water, then -with acetic acid, and finally
with hot water. G. C. Wittstein obtained the dihydrate by adding calcium carbonate
to a soln. of platinic sulphate, and washing the excess of calcium carbonate
from the precipitate by acetic acid, and the calcium sulphate, by water.
obtained the trihydrate, PtO2.3H2O, from the higher hydrate as a precipitate from
boiling soln. ; E. Prost, by adding water to a soln. of platinic nitrate ; but Li.
Wohler
always found the product to contain some basic nitrate, as was also the case with
the anodic deposit obtained in the electrolysis of a soln. of platinic nitrate in
nitric acid. The colour of the trihydrate ranges from ochre-yellow to
nankeenyellow.
E. Fremy obtained the tetrahydrate, PtO2.4H2O, by boiling a soln. of
platinic chloride for a long time with an excess of sodium hydroxide, and
precipitating
the hydrate -with acetic acid. L. Wohler, and, I. Bellucci employed a
similar process. I. Bellucci dissolved the dihydrate in molten potassium or sodium
hydroxide, and neutralized the product "with acetic acid ; and he also neutralized
Li. Wohler observed that hydrogen does not reduce the monohydrate perceptibly
at ordinary temp., but when feebly warmed the reduction proceeds vigorously,
and if some platinous oxide is present, such as occurs if the hydrate has been
preheated to 400�, the reduction proceeds rapidly at ordinary temp., until it is
retarded by the protective action of the platinum formed on the surfaces of the
grains. The hydrates lower than the dihydrate make electrolytic gas explode, but
the trihydrate only glows in the gas. The decomposition of hydrogen dioxide
proceeds
slowly in the presence of the hydrated dioxide, and this even in acidic or
alkaline boiling soln. when stirred. The freshly-precipitated hydrate was found by
and, better still, potassium hydroxide dissolve the hydrate at ordinary temp.
IJ. Wohler found that the hydra ted dioxide accelerates the decomposition of hot
soln. of potassium permanganate, and when boiled with a cone. soln. of platinic
chloride in the presence of acetic acid, the hydrated dioxide is reduced to metal.
liquid. The white hexagonal plates are sparingly soluble in water ; the soln. has
an alkaline reaction ; it decomposes ammonium salts ; absorbs carbon dioxide
from the air to form a carbonate ; and forms salts with acids.
C. Gerhardt prepared platinic tetrahydroxydiammine, [Pt(NH3)2(OH)4], by
the action of ammonia on a boiling soln. of the corresponding nitrate, cooling
the liquid, washing the precipitate, and drying at 130�. The yellow,
macrocrystalline
powder is not changed at 130� ; it decrepitates at a higher temp, losing water and
ammonia, and leaving platinum behind. It is scarcely soluble in water, but
soluble in hot, dil. acids ; boiling potash-lye does not dissolve or decompose the
compound. It was studied by W. Odling, O. Weltzien, H. Kolbe, C. Grimm, and
P. T. CIeve. B. E. Dixon prepared silver platinic hydroxytriamidodiamminohydroxide,
[Ag3{Pt(NH3)2(NH2)3(OH)}2](OH)3.
J. Jacobsen prepared platinic decahydroxyammine, [NH3Pt(OH)5J2, by
pouring an excess of ammonia into a soln. of dichloroplatinic acid. The liquid
turns a dark colour, and finally precipitates a brown, flocculent mass containing
no
chlorine and resembling ferric hydroxide. Washed with boiling water until free
from ammonia and dried, this precipitate presents a conchoidal structure. If
dried at 100� and then over sulphuric acid, it rehydrates with such avidity that
the
particles jump about. When it is heated gently above 250�, the compound blackens,
and finally explodes with some violence, giving spongy platinum, nitrogen, oxygen,
and water vapour. If pyridine is employed in place of ammonia, a similar detonating
H. Davy,2 and K. A. Hofmann and H. Hiendlmaier found that the yellow powder
obtained by the combustion of a platinum-potassium alloy behaved like a platinate ;
hydroxide and chloride are washed out, there remains a rust-yellow, colloidal
platinate which is coagulated by the addition of a salt. It contains 7 per cent,
of potassium oxide ; hydrochloric acid, and hot sulphuric and nitric acids remove
the alkali ; cone, hydrochloric acid slowly converts it into potassium
chloroplatinate,
and platinic chloride ; at a red-heat, the platinate passes into platinite
by the loss of oxygen ; it detonates violently when heated with combustible
matters.
metallic platinum and sodium hydroxide. The stability of the platinates is of the
same order as that of the manganates and ferrates, and the composition of the
latter is almost identical "with that of the corresponding platinum compounds.
oxygen gas, and leaves a black residue, from which the soda may be dissolved out
by water. The residual black powder appears to be a mixture of platinum and
platinic oxide, since hydrochloric acid extracts platinic oxide. Formic acid, with
the aid of heat, converts sodium platinate into platinum black, causing at the same
time a brisk evolution of carbon dioxide and formation of sodium formate. Heated
aq. soln. of oxalic acid dissolve sodium platinate with evolution of carbon
dioxide,
forming a dark liquid, which, on cooling, first becomes green and then dark blue,
and deposits copper-coloured needles of platinous oxalate. Acetic acid withdraws
all the soda from sodium platinate together -with a small quantity of platinic
oxide,
and leaves ochre-yellow hydrated platinic oxide. DiI. nitric acid dissolves it
easily
and completely, forming a deep yellow liquid, which forms, with nitrate of silver,
a yellow precipitate, soluble in nitric acid. DiI. oxygen-acids extract the soda
without dissolving the platinic oxide ; from the denser ochre-yellow compound,
strong nitric acid dissolves out nothing but soda.
Platinum is attacked by the alkaline earth oxides�by calcium oxide least,
and by barium oxide most ; platinum crucibles are attacked by fused barium
nitrate. J. J. Berzelius mixed a soln. of a platinic salt with a large excess of
baryta
and obtained barium platinate as a light yellow powder which at a red-heat gives
a mixture of baryta and platinum. G. Rousseau observed that when barium oxide,
mixed with an equal quantity of the chloride or bromide, is heated for several
hours at 1100� in an open platinum crucible, a considerable quantity of
crystallized
barium platinate is formed. It has the composition 3BaO-PtO2, and is more
readily obtained in crystals by first producing the amorphous platinate by heating
platinic chloride with barium oxide, and then adding a sufficient quantity of
barium chloride or bromide and heating at the melting point of copper. The
alkalinity of the mixture has great influence on the crystallization. The crystals
are prisms with hexagonal bases, and are insoluble in acetic acid, but dissolve in
hydrochloric acid. At an orange-red heat, in presence of barium chloride, the
platinate decomposes and metallic platinum separates. If the proportion of barium
oxide employed is less than 3O per cent., the product is barium platinate, BaPtO3.
baryta water, or sod a-lye ; it is soluble in acids, but cold acetic acid has no
action,
whilst the hot acid forms barium acetate and hydrated platinum dioxide.
For the tin platirtcU.es, vide 7. 46, 14 ; the vanadium platinates, 9. 54, 6 ;
chromium
platinates, 11. 60, 15 and 16; the molybdenum platinates, 11. 61, 11 ; and the
tungsten
of hydrated platinum dioxide in cone, nitric acid. "Lt. Wohler could not prepare
Ja. Wohler 4 and co-workers, C. Marie, M. Ie Blanc, and R. Ruer showed that
the oxide film which was observed by F. Kohlrausch to form on the anode during
and that the same film is formed when the metal becomes passive. E. Haber and
solid solution of the trioxide in the dioxide is formed. Platinum trioxide is not
acted on by dil. sulphuric, nitric, or acetic acids. It slowly liberates chlorine
from
dil. hydrochloric acid. Sulphurous acid dissolves it with the formation of a
colourless
complex. Cone, sulphuric and nitric acids slowly decomposed it with the formation
of the dioxide. On gently heating, it gives the dioxide. In the cold it has no
action on alcohol or acetic acid. The oxidation which takes place on warming is
due to the dioxide which is formed. It does not decompose into hydrogen dioxide,
and must therefore be classed as a polyoxide or peroxide of platinum of the
constitution
G. Grube,5 in his study of the behaviour of the oxygen electrode, found that
potentials from 1*5 volts downwards are due to solid soln. of platinum trioxide
in platinum dioxide, or of platinum dioxide in platinum monoxide. Since, however,
platinum electrodes can be polarized up to potentials of 2 volts, G. Grube
suggested
that an unknown platinum tetroxide, PtO4, is formed.
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PLATINUM 249
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H. Moissan x found that fluorine free from hydrogen fluoride does not attack
platinum below 100�, and combination does not readily occur below 500� to 600�.
If hydrogen fluoride is present, the reaction occurs more readily even in the case
of
liquid hydrogen fluoride saturated with fluorine. He prepared platinum difluoride,
or platinous fluoride, PtF2, together with the tetrafluoride, by heating platinum
wire to 500� or 600� in a current of fluorine. C. Poulenc observed that some
difluoride is formed when ammonium fluoplatinate is heated over 300�. According
to H. Moissan, the tetrafluoride is soluble in water, but the difluoride remains
attached to the surface of the metal as an insoluble, green layer. On ignition, it
decomposes into fluorine and platinum. H. Moissan prepared platinous
phospnopentafluoride.
J. J. Berzelius reported that when an aq. soln. of potassium fluoride is added
to an aq. soln. of platinic chloride, free from an excess of acid, as long as a
precipitate
continues to form, and the filtered liquid evaporated, platinic fluoride may
be extracted from the mass by means of alcohol�potassium chloroplatinate remains.
The alcoholic liquid mixed with water is then evaporated. On cooling to a low
temp., a non-crystalline, yellow, transparent mass is formed which is completely
soluble ; and if a temp, of 60� be employed, the mass becomes dark brown, and
260 INORGANIC AND THEORETICAL, CHEMISTRY
when extracted with water leaves a basic salt undissolved. S. Gr. Hedin reported
the possible existence of platinous difluorobispyridine, [Pt(C5H5N)2F2].
the formation of hydrofluoric acid and hydrated platinum dioxide. Very dil.
soln. are more stable, but they behave similarly if the liquid is warmed. This
hydrolysis shows why platinic fluoride cannot be prepared by the action of
hydrofluoric
acid on hydrated platinum dioxide ; and renders it questionable if
J. J. Berzclius' preparation was what it "was thought to be. The fact that fluorine
containing hydrogen fluoride attacks platinum more vigorously than fluorine alone ;
and the existence of double salts with the alkali metals made H. Moissan suggest
that
possibly a platinic hydrofluoride, PtF4.nHF, can be formed. Platinic fluoride forms
crystalline compounds with the fluorides and chlorides of phosphorus and boron.
J. J. Berzelius obtained a dark brown, gummy mass from a mixture of his
platinum fluoride and ammonium fluoride. The product was resolved by water
into a soluble acidic salt, and an insoluble basic salt. It was insoluble in
alcohol.
According to C. Poulenc, there is a state of equilibrium between ammonium
fluoride and platinic chloride in the molten state, some ammoniu m fluoplatinate,
probably (NH4)2PtF6, is formed, but it cannot be separated from the chloroplatinate
baser, Lund, 1886 ; JLunds Arsskr., (2), 22. 3, 1887 ; W. Jeroch, Versuche zur
Darstellung van
(3), 5. 454, 1891 ; Ann. Chim. Phys., (6), 24. 282, 1891 ; C. Poulenc, ib.t (7), 2.
74, 1894 ; O. Ruff
and W. Jeroch, Ber., 46. 922, 1913 ; O. Ruff and J. Zedner, ib., 42. 493, 1909 : H.
I. Schlessinger
(160 c.c.) for 10 to 12 hrs., the reduction is complete, and a red salt
crystallizes
out on evaporation. Similar results were obtained by heating potassium
chloroplatinite
(9 grms.) with potassium hypophosphite (1 grm.) and water (300 c.c),
at 80� to 90�, for 18 to 20 hrs. The completion of the action is shown by the pure
ruby colour of the soln., the least shade of orange indicating the presence of
chloroplatinite.
The first method is the safest, as the reduction cannot go beyond the
chloroplatinite, but in the secomd method, the red salt separates more easily and
completely, and, with care, very good results are obtained. If, when reducing
with potassium hypophosphite, the action is continued after complete conversion
into the red salt, the solution rapidly changes to dark brown. Hydrochloric acid
has no effect on this solution, nitric acid decolorizes it, potash causes a brown
precipitate soluble in excess of the precipitant, and ammonia a brown precipitate
insoluble in excess. This compound could not be isolated, but M. C. L�ea considered
than before, being of an orange tint. The filtrate is free from platinum ; but on
continued washing with water, the salt dissolves slightly, and the filtered liquid
becomes clouded. P. C. Ray and co-workers prepared platinum
ethylsulphinomonochloride,
PtCl.(C2H5)2S, or {(C2H5)2S : PtCl)2; platinum
etnylsulphinobenzylaminomonochloride,
Pt2Cl(CH2.C6H5.NH2)(C2H5)2S ; platinum ethylsulphinobispyridinomonochloride,
Pt2Cl(C5H5N)2(C2Hg)2S ; platinum hemiethylsulpmnopyridinomonocfaloride,
2Pt2Cl(C5H5N).(C2H5)2S; and platinum
ethylsulpnmoethylaminochloride, PtCl(C2H5.NH2).(C2H5)2S.
P. Schutzenberger s noted that some platinum dichloride or platinous chloride,
PtCl2, is formed when spongy platinum is heated in dry chlorine at 240� to 250� ;
there is scarcely any action at 200� ; and the yield is no greater at 300�.
According
to L. Troost and P. Hautefeuille, chlorine attacks platinum at 1400� to form
platinum dichloride which can be condensed in a cooled tube before the dichloride
has time to decompose. The phenomenon was discussed by P. Duhem. Ji. Pigeon
252 INORGANIC AND THEORETICAL. CHEMISTRY
liquid heated on a sand-bath, evaporated the dark brown soln., and heated it
to 230� to 240�. F. Gramp obtained yellow crystals of the dichloride by the
action of iodine on a soln. of platinum tetrachloride. M. Katayama noted the
anodic formation of platinum dichloride in the warm cell Pb : PbCl2Boiid : Cl(Pt
anode).
the product over sulphuric acid and potassium hydroxide in vacuo. The dark
brown, amorphous mass gives off water and hydrogen chloride at 100�.
I. IJ. Kondakoff and co-workers, and Hi. F. Nilson said that the aq. soln. contains
=41-83 CaIs. ; and (Pt,0,4HCl,Aq.)=31-55 CaIs. L.. Pigeon did not obtain
satisfactory
results by reducing hydrochloroplatinic acid with sulphurous acid since
it is difficult to determine whether the reduction has gone too far, or not far
enough ;
but he obtained a soln. by treating a soln. of a mol. of hydrochloroplatinic acid
with a mol. of dry barium carbonate, and a mol. of barium dithionate with 3 times
its weight of hot water, heating the mixture on a water-bath at 100�, and filtering
W. Peters 4 found that a mol. of platinous chloride at 20� to 26�, and 749 to
754 mm. press, slowly absorbs about 5 mols. of ammonia, and at the same time
changes to a white or pale grey platinous pentamminochloride, Pt(NH3)5C12 ;
and if this product be kept in vacuo, platinous tetramminodichloride,
[Pt(NH3)4JCl2-
H2O, is formed. J. Reiset prepared platinous tetramminochloride by boiling
platinous chloride with aq. ammonia, with frequent additions of more ammonia,
until the first-formed green [Pt(NH3)4]PtCl4 redissolves, and then evaporating the
soln. for crystallization. A similar process was employed by M. Peyrone, P. T.
Cleve,
and C. Grimm. M. Peyrone saturated the soln. of platinous chloride with aq.
ammonia,
in the cold, dissolved the precipitate in boiling hydrochloric acid, treated the
filtrate with alcohol, washed with alcohol, and purified by recrystallization from
cold water. P. T. Cleve, P. Klason, C. W. Blomstrand, and H. and A. Euler
described platinous dichlorotetrammine, Pt(NH3)4Cl2, formed by the action of
hydrochloric acid on the corresponding hydroxide, and by the action of the
calculated quantity of hydrochloroplatinous acid on ammonium
diamminotetrachloroplatinite.
The black powder dissolves in hydrochloric acid, forming platinous
cis-dichlorodiammine. S. M. Jorgensen recommended :
The filtered soln. of 20 grms. of ammonium chioroplatinite in K)O c.e. of cold
water
and 5O c.c. of JV-NH4OH, is allowed to stand in a covered flask, in ice-water for
18 hrs.
Add 100 c.c. 20 per cent. aq. ammonia, warm the mixture for some minutes on the
waterbath
until all the [Pt(NH8)^PtCl8 has dissolved, filter and cool. Triturate the product
three times with 1OO c.c. of cold 80 per cent, alcohol to remove the ammonium
chloride,
dissolve the residue in 45 c.c. of warm water, and when the filtered liquid is
cool, add 4 vols,
of absolute alcohol, and allow the flask to stand for half an hour in cold water.
Wash
the white product on a suction filter three times with 80 per cent, alcohol, and
once with
absolute alcohol, and dry it in air Yield 15-0 grms.
which have been dehydrated may decrepitate on cooling. When heated to about
250�, ammonia is evolved, and there remains platinous diamminochloride ; at a
higher temp., ammonium chloride, and hydrogen chloride are given off, and
platinum remains. A. A. Grinberg and B. V. Pittsin studied the subject.
M. Peyrone said that the evolution of ammonia begins at 220�, and becomes
energetic at 240�, and a soln. of the product in hot water yields crystals of
dichlorodiammine.
E. N. Gapon measured the diffusion coeff. J. Petersen gave 0-275�
for the lowering of the f.p. of a 1-837 per cent. soln. J. Thomsen found the heat
of soln. to be �8756 cals. N. Kurnakoff gave for the coeff. of refraction of a 7-
166
per cent, soln., 1-33993 for Li-light ; 1-34217 for Na-light ; and 1-34519 for Tl-
light ;
the mol. refraction with the //,-formula is 74-1 ; and the at. refraction of
platinum
is between 11-9 and 16*7. A. Werner and A. Miolati found the mol. conductivity
of a mol of the salt in 500, 1000, and 2000 litres of water to be, respectively,
247-6,
260-8, and 267-2. R. Lorenz and I. Posen found the eq. conductivity, A, of a mol
of the salt in v litres to be :
v . . . 32 64 128 256 512 1024 oo
A . . 121-2 128-8 133-7 137-9 140-9 144-7 150-8
The ionic velocity of the complex [Pt(NH3)4J-- is 37-8; for the complex [Pten2]\
32-0; for c^-LPt(NH3)2py2|'-, 25-8 ; and for [Ptpy4J", 21-0.
J. Reiset, and P. T. Cleve found that a sat. soln. contains 20 per cent, of the
salt at 16-5�, and that the solubility increases with a rise of temp. N. S.
Kurnakoff
and LA . Andrejewsky observed that when recrystallized from water a few times,
the product is a solid soln. of isomorphous PtCl2(NH3)4.H20 and PtCl2(NH3)2.
4PtCl2(NH3)4. J. Reiset observed that if chlorine is passed into the aq. soln.,
platinic dichlorotetramminochloride is formed ; and P. T. Cleve, that iodine
forms no definite compound, but only a mixture ; and M. Peyrone, that when
evaporated with hydrochloric acid, in excess, ammonium chloride and platinous
frans-dichlorodiammine are formed. L. Tschugaeff and S. Krassikoff studied the
action of sulphur dioxide. A. R. Klien studied the action of water, acids, and
alkaline soln. M. Peyrone also noted that sulphuric acid or nitric acid introduces
the sulphate or nitrate radicle in place of the chloride radicle ; and J. Reiset
added
that with hot nitric acid, platinic dichlorotetramminonitrate is formed.
I. I. Shukoff and O. P. Schipulina studied the adsorption of the ealt by charcoal,
PLATINUM 257
and the adsorption of the tetrammine on charcoal, and likewise compared the
results with other members of that series of complex salts. The addition of alcohol
or ether to the aq. soln. precipitates the original salt as a white, crystalline
powder.
M. Peyrone observed that oxalic acid converts the chloride into an oxalate.
H. Kautsky and W. Baumeister studied the adsorption of the [Pt(NHs)4]-'-ions
by silicic acid. J. Reiset found that a little ammonia is expelled when a soln. of
the salt is heated with alkali lye ; and M. Peyrone, that potassium carbonate
decomposes
the salt slowly in the cold, rapidly at 40� to 50�, forming potassium chloride,
and the tetramminocarbonate. J. Reiset found that with soluble silver salts, silver
on warming ; and when this soln. is cooled, the precipitate which is formed
contains
stannic oxide ; if the soln. is heated a red soln. is formed, along with ammonium
chloride and a precipitate of platinum and stannic oxide. With ferric chloride,
platinic dichlorodiamminochloride and ferrous chloride are formed. According
to M. Peyrone, platinous chloride in aq. soln. forms platinous
tetramminochloroplatinite,
[Pt(NH3)4JCl2.PtCl2 ; J. Reiset, that an excess of hydrochloroplatinic
acid gives an olive-green precipitate of platinous tetramminochloroplatinate,
[Pt(NH3)4 |C12.PtCl4, which, according to P. T. Cleve, is mixed with some platinous
watch-glass. An excess of sulphurous acid would decolorize the soln. and form
hydrosulphitoplatinous
acid. When no precipitate or only a slight one is produced by the
ammonium chloride, boil the soln. of hydroehloroplatinous acid so prepared, and add
an
excess of cone. aq. ammonia. Magnus' green salt is precipitated in acicular
crystals. The
precipitation continues as the soln. cools, and sometines there is also formed a
little yellow,
crystalline platinous dichlorodiammine which does not settle so readily and can be
decanted
off with the water. .Drain off the salt by suction, and wash successively with
water, alcohol,
and ether. The yield O-25 grm. is small because most of the platinum remains in the
value is 3-9 with 1 mol. of [Pt(NH3)4]PtCl4 in the unit cell. E. Hertel studied
the subject. J. Gros said that when heated the salt gives off some vapours of
ammonium chloride, etc. ; and platinum remains behind. L*. Tschugaeit and
N. Pschonicyn studied the depolymerization symbolized : [Pt(NH3)4JPtCl4
�2LPt(NH3)aCl2|. N. R. Dhar found the mol. conductivity of an aq. soln. of a
mol of the salt in 405O, 6750, 20,25O, and 60,75O litres of water to be,
respectively,
566-67, 640-56, 647*32, and 650*90. P. T. Cleve said that the salt is very
sparingly
soluble in water. L. Tschugaeff and I. Tscherniaeff oxidized Magnus' salt with
ammonium persulphate, and obtained (Pt,4NH3)2(S04)(PtCl4)2(OH)2; and with
nitric acid in the presence of hydrogen dioxide, [Pt,4NH3,(N03)]PtCl4. C. Gerhardt
observed that chlorine converts it into [Pt(NHg)4Cl2]PtCl4 and then into
[Pt(NHg)4Cl2JPtCl0. G. Magnus added that the aq. soln. is not decomposed by
hydrochloric acid, and J. Gros, that boiling hydrochloric acid or sulphuric acid
takes up no ammonia. J. Gros, and M. Raewsky found that nitric acid converts
the salt into [Pt(NH3)4Cl2J(N03)2 and [Pt(NH3)4(OH)Cl](N03)2 ; and A. Cossa,
that ammonium nitrate forms a mixture of different compounds, [Pt(NH3)4J[
Pt(NH3)Cl3J2, [Pt(NH3)4Cl2J(N03)2, and [Pt(NHg)2Cl2]. J. Reiset found that
boiling ammonia converts the salt into platinous tetramminochloride. I. I. Shukoff
and O. P. Schipulina observed that the salt is decomposed when it is adsorbed by
carbon. F. W. Clarke and M. E. Owens showed that the salt forms a brown soln.
with hot aq. potassium cyanate. J. Gros observed no evolution of ammonia occurs
when the salt is boiled with an aq. soln. of potassium hydroxide. P. T. Cleve
showed that silver nitrate forms silver chloroplatinite and platinous
tetramminonitrate
; and J. Reiset, that boiling hydrochloroplatinic acid forms platinous
chloride, and [Pt(NH3)4Cl2]PtCl4. The constitution of the green platinous
tetramminochloroplatinite
was discussed by C. Weltzien, and M. Peyrone.
S. M. Jorgensen and S. P. L. Sorensen observed that in preparing the green
salt by the action of potassium chloroplatinite on platinous dichlorodiammine, a
red isomeride may be formed. The conditions favourable for the production of the
red salt are : the absence of potassium chloroplatinate often present in traces
in the platinous salt, and a very dil. neutral or slightly ammoniacal soln. in the
PLATINUM
presence of a large excess of water. The formation of the green salt is favoured
by the use of concentrated solutions or of solutions acidified with hydrochloric
acid. E. G. Cox and co-workers prepared the pink salt by treating an aq. soln.
of [Pt(NH3)4"jCl2 with a quarter of its vol. of aq. ammonia of sp. gr. 0*88, and
then
with a neutral soln. of potassium chloroplatinite free from chloroplatinate. A good
yield of the pink salt is deposited, and it is contaminated with a little green
salt.
According to S. M. Jorgensen and S. P. L. Sorensen, the precipitate should be
washed with aq. alcohol, and finally with absolute alcohol ; it furnishes small,
ill-defined needles, rose-red in colour. The same salt is obtained in -well-
defined,
small, tetragonal prisms by interaction of the yellow platinous
dimethylamineamminochloroplatinite
with platinous dichlorodiammine. JE. Hertel and
K. Schneider found that the space-lattice of the red, tetragonal crystals has
a=6-293 A., c=5-25 A., and a : c==l : 0-8340. E. G. Cox and co-workers said that
these results are wrong. The crystals are rhombic and have a space-lattice with
a�7*9 A., 6=8-2 A., and c�7-9 A. ; the calculated sp. gr. is 3-9, when there are
two mols. of [Pt(NH3)4]PtCl4 per unit cell. The red and green salts are anhydrous,
and in the dry condition they are very stable, but on boiling the red salt with
water
it is changed quantitatively into the green salt ; the converse change has not been
precipitation of the green salt of Magnus, "whereas with the red tetrammine, there
is no action for some time, and if, on heating, the red salt becomes green, only
the
tetrammine, and no triammine is found in the filtrate ; and (iv) when the two salts
are treated with a cold aq. soln. of silver nitrate, silver chloroplatinite is
precipitated.
On removing the excess of silver with a soluble chloride, and treating the liquids
with an aqueous soln. of potassium chloroplatinite, in the one case, the initial
triammine is regenerated in red plates, and in the other case, acicular crystals of
the green salt are formed. With potassium chloropalladite so used instead of the
chloroplatinite, the triammine furnishes platinous chlorotriamminochloropalladite,
[Pt(NHg)3Cl)2PdCl4, whereas, the red salt of Magnus gave greyish-pink needles
of platinous tetramminochloropalladite, [Pt(NH4J4JPdCl4. The evidence shows
that there is no connection between the red platinous triammine and the red
form of Magnus' salt.
The red and green salts of Magnus appear to be similar in crystalline form when
viewed under the microscope ; their solubilities are similar ; no difference has
been
detected in the chemical reactions ; they have the same molecular weights ;
dichroism does not explain their occurrence ; and nothing has yet been observed
to show any difference in chemical structure. No other pair of red and green
isomeric platinous salts is known, but the substitution of the four ammonia
residues
in [Pt(NHg)4JPtCl4 by methyl-, n-butyl-, iso-butyi-, or amyl- amine forms a green
salt, whereas a similar substitution of ethyl- or of w-propyl-amine gives a red
salt, but platinous tetraetnylaminochloroplatinite, [Pt(C2H5NHo)4]PtCl4, is
green.
[Pt(NH3)3ClJ2PtCl4.
"K. Gr. Cox and co-workers found that the pink salt of Magnus is formed only
under special conditions, and that the salt usually called the pink salt of Magnus
is really Cleve's salt. The X-radiograms of the two salts are very similar. The
c-axes of the two are equal, and the a-axis of Cleve"s salt is probably 3 or 3/\/2
times that of the te tram mine salt.
A. R. Klien studied the action of water, acids, and alkalies on the salt. Platinous
treated with hydrochloric acid. Just as J. Reiset obtained the salt by heating
platinous dinitrato- or sulphato-diammine with hydrochloric acid or alkali
chloride,
M. Peyrone evaporated to dryness a mixture of platinous tetramminochloride and
an excess of cone, hydrochloric acid, and extracted the ammonium chloride with
water ; and J. Reiset, also, by boiling platinous tetramminochloroplatinite for a
long
time with a soln. of ammonium nitrate, sulphate, or chloride, and cooling the
liquid. A. Cossa observed that some [Pt(NHg)4][Pt(NH3)CIg)2, previously described,
is formed. S. M. Jorgensen found that dichlorodiammine is formed in the thermal
decomposition of ammonium chloroplatinite at 170�. H. and W. Biltz recommended
the following process :
Heat about 0*3 grm. of platinous tetramminochloride to 250� in a test-tube immersed
in a paraffin bath. If any �water is given off, stop the heating to remove tho
drops, con
until ammonia is evolved, the substance becomes dark coloured, and a brittle
platinum
262 INORGANIC AND THEORETICAL CHEMISTRY
black begins to deposit on the glass. The treatment occupies about 20 mine. Extract
the greyish-yellow mass in a beaker with 20 c.c. of boiling water ; and filter the
hot pale
yellow soln., from the black residue. On cooling, a mass of pale yellow crystals of
the
trans-salt is deposited from the soln. Drain the crystals, wash with alcohol, then
with
ether, and allow them to dry. Yield O-1 grm.
The colour of the trans-salt ranges from a pale yellow to a sulphur yellow.
It may occur in acicular crystals, or, according to A. Cossa, in rhombic, hexagonal
plates. A. M. Boldyreva said that the crystals are tetragonal and uniaxial.
H. D. K. Drew and co-workers found that the pale yellow crystals are tabular, and
often elongated, and twinning is common. The crystals have a straight extinction ;
positive elongation ; and refractive index 1*76. M. Peyrone said that the salt
decomposed at about 270� into ammonium chloride, hydrogen chloride, nitrogen
and platinum. J. Lifschitz and E. Rosenbohm studied the optical properties.
A. Werner and A. Miolati found the mol. conductivities of soln. with a mol of the
salt in 5OO and 1000 litres of water are respectively 22-6O and 22-42. A. Werner
and C. Herty said that the electrical conductivity of the soln. is characteristic
of
that of a n on-ionized salt. H. D. K. Drew and co-workers found that the
conductivity
increases rapidly with time, so that the mol. conductivities, /z, of soln.
with a mol. of the j8-salt in 2866 and 1234 litres, respectively, were :
Time ... O 62 131 174 2752
They attributed the change to the destructive action of water generating ammonium
chloride. A. Werner and A. Miolati made observations on the conductivity of
soln. of the salt. The salt dissolves very slowly in water. W. Odling observed that
the salt is very sparingly soluble in cold water ; but is more soluble in hot
water�
M. Peyrone observed that ] 40 parts of boiling water dissolve 1 part of salt, and
P. T. Clove, that 13O parts of boiling water or 4472 parts of water at 0� are
required
to dissolve 1 part of salt. H. D. K. Drew and co-workers said that 100 grms. of
water at 25� dissolve 0-036 grm. of the a-salt. The treatment of the salt with
chlorine, aqua regia, or a mixture of potassium chlorate and hydrochloric acid
furnishes citron-yellow, octahedra of platinic dichlorotetramminochloride ; biomine
more soluble than is the case with the yellow salt. The solubility of the salt in
hot water is much greater, and with boiling water, the brown salt passes into the
yellow form. Aqua regia, or a mixture of potassium permanganate and hydrochloric
acid, form [Pt(NHs)2Cl4] ; potassium iodide furnishes [Pt(NHg)2I2I ; and
ammonium sulphite gives crystalline needles of a double salt. F. Hoffmann prepared
platinous hydroxychlorodiammine, [Pt(NH3)2(OH)ClJ ; and A. R. Klien
studied the salt. A. Grunberg and D. I. Rjabtschikoff prepared platinous
diaquodiam minochloride, [Pt(NHg)2(H2O)2]Cl2, and platinous
hydroxyaquodiamminochloride,
[Pt(NH3)2(H20)(OH)JCl.
C. Grimm obtained a dark red, crystalline powder of what lie regarded as ammonium
platinous dichtorodiammtnochloride, 2NH4Cl.[Pt(NH3)gClg], by crystallizing a soln.
of
platinous tetramminochloride with a large excess of ammonium chloride. N. S.
Kumakoff,
and H. and A. Euler said that the product is probably impure platinic
diehlorotetrainminochloride
(q.v.).
W. Odling obtained platinous c^-dichlorodiammine, [Pt(NHg)2Cl2], or
Peyrone^s chloride, or platinous yg-dichlorodiam mine, by gently heating a soln.
of platinous chloride, tetramminochloroplatinite, or /rans-dichlorodiamniine in
aq. ammonia ; and P. T. Cleve, by precipitation from a soln. of the corresponding
nitrate or sulphate by the addition of hydrochloric acid or alkali chloride.
P. T. Cleve also prepared it by adding ammonia to a brown soln. of platinous
chloride in cold hydrochloric acid, boiling the greenish-yellow precipitate with
water, when insoluble platinous tetramminochloroplatinite and a soln. of the
cis-salt are formed. The soln. on cooling deposits the cis-salt. M. Peyrone
prepared
this salt by gently heating a soln. of platinous tetramminochloride in aq.
ammonia, dissolving the precipitate in boiling hydrochloric acid, washing the
precipitate with water to remove the tetramminochloride, and recrystallizing from
a soln. in hot hydrochloric acid. M. Peyrone obtained the salt by pouring potashlye
W. Lossen found that it is formed among the products of the action of hydroxylamine
Time 0 15 25 45 9O minutes
u. .
5-4 8-6 9-2 12-8 20-8
A. Werner and A. Miolati, and A. Werner and C. Herty discussed this subject.
W. Odling said that the salt is soluble in water, and, added M. Peyrone, without
change, but P. Klason found that at 100�, the cis-salt slowly passes into the
trans-salt, and that the change is faster at a higher temp. L. Tschugaeff and
I. Tscherniaeff oxidized Peyrone's salt with ammonium persulphate and obtained
PtCl2(OH)(NHs)2. M. Peyrone found that 1 part of the salt dissolves in 33 parts
of boiling water ; P. T. Cleve said 26 parts of boiling water, and 387 parts of
water
at 0� ; and P. Klason said 390 parts of water at ordinary temp. H. D. K. Drew
and co-workers found that 1OO grms. of water at 25� dissolve 0-2523 grm. of the
/?-salt. H. D. K. Drew and co-workers found the mol. conductivities of soln. with
a mol of theyS-salt in 1234 litres to be respectively 7*7, 14-4, 36-8, and 86-0 for
times
(), 6fi, 193, and 1397 min. ; and they attributed the change to the generation of
ammonium chloride by the disruptive action of water. L. Tschugaeff and
W. Chlopin observed that hydrogen dioxide converts Peyrone's chloride into
platinic dichlorodihydroxydiammine, ozone in hydrochloric acid soln. increases
the valency of Peyrone's chloride, but adds two chlorine atoms ; in alkaline
soln., both addition and substitution may occur simultaneously. P. T. Cleve
observed that chlorine, or aqua regia forms hexagonal or rhombic plates of cis[
Pt(NH3)2Cl4] ; M. Peyrone, that hydrochloric acid dissolves it without
decomposition
; P. T. Cleve, that sulphur dioxide passed into a boiling soln. forms cis[
Pt(NHa)2(HSO3)CIl, and sodium sulphite forms 3Na2SO3-PtSO3.IJH2O ;
M. Peyrone, that dil. sulphuric acid dissolves the salt without decomposition,
that the cold, cone, acid has no action, but the hot, cone, acid decomposes it with
NH3Cl NH3-NH3Cl
L t<LCl
^^NHgCl
and S. M. Jorgensen at first accepted these formulae, but finally reversed them.
The subject was discussed by F. Rosenblatt and A. Schleede, F. G. Angell and
co-workers, H. Reihlen and G. von Htihn, H. D. K. Drew and F. S. H. Head, and
HN Pt<NH�
HsN 1 t<:Cl
11^NH3Cl
and A. Werner used the planar formula?, now generally accepted, namely :
Cl-^^Cl ClH3N>L Cl
The )3-salt gives an intense purple coloration when rubbed with phenoxtellurine
dibisulphate, but not so with the ct- and y-salts, the reaction is analogous
with the behaviour of tellurides, selenides, and sulphides observed by H. D. K.
Drew,
and hence it is assumed that the y3-salt has a formula of the type PtX2- The
colorations produced by the tri- and tetra-ammines depend on the presence of a salt
The reaction of the dichlorodiammines with silver oxide is slow, but it proceeds
more rapidly with warm soln. The )8-salt gives a soluble, hygroscopic yellow base,
but the ct-isomeride produces the same base as the y-isomeride. The product is
266 INORGANIC AND THEORETICAL, CHEMISTRY
assumed to be the base of the y-salt because it yields the y-salt when neutralized
by hydrochloric acid, and the change from the <x- to the y-form is symbolized :
formed, since the /?-chloro-salt forms Pt(py.OH)2, and the <x-salt, the cx-base,
the three dichlorodiammines, resembles that of silver oxide, only the )8-base is
from tertiary aliphatic ammines, since only platinous chloride and a hydrochloride
of the amine are formed, is in agreement with the assumption that the )S-isomeride
has the halogen attached to nitrogen, and the tendency to ionization is feeble.
Cl
H3N V1 � /NH3 ClH3N^ ^Cl
Cl-" . ^ Cl ClH3N ~^x 1^Cl
Cl
a-Tetrachlorodiammine /J-Tetrachlorodiamminc
At 25�, 100 grms. of water dissolve 0-0491 grm. of the y-salt. For some reactions
of the salt, vide supra. F. Rosenblatt and A. Schleede concluded from the X-
radiograms
that the y-salt is another crystalline form of the trans-salt. H. D. K. Drew
and F. S. H. Head prepared a representative of the cis- and trans-isomerides of the
the product from the aq. soln. According to S. M. Jorgensen, the salt furnishes
orange-red, rhombic bipyramidal crystals resembling those of the potassium salt.
They effloresce and slowly lose their water over cone, sulphuric acid ; they are
rehydrated over water, and dehydrated at 98�. The aq. soln. furnishes crystals
of platinous tetramminochloride, and of platinous trichloroammino-
tetramminoplatinite,
[Pt(NH3)Cl3]2[Pt(NH3)4], and the reaction is almost quantitative. When
the salt is treated with mercaptan, P. Klason obtained platinous bissulphinoammine,
does not dissolve the salt, but with boiling alcohol, platinum is formed. A boiling
soln. of sodium hydroxide does not split off ammonia, but it forms a black
explosive
product. S. M. Jorgensen, and A. Cossa prepared pale brown crystals of silver
amminotrichloroplatinite, Ag[Pt(NH3)Cl3], by the action of silver nitrate on the
potassium salt. A. Cossa observed that an excess of silver nitrate in cold soln.
of potassium amminotrichloroplatinite precipitates two-thirds of the chlorine as
silver chloride, and with boiling soln., all the chlorine is precipitated. No
sparinglysoluble
complex salts are formed by potassium amminotrichloroplatinite with
zinc, mercuric, or stannous chlorides. According to A. Werner, when an excess of
a hot soln. of the potassium amminotrichloroplatinite is mixed with potassium
amminopentachloroplatinite, a compound crystallizing in green leaflets is deposited
H. Alexander, the salt is insoluble in water but sparingly soluble in hot water ;
insoluble in alcohol; soluble in hydrochloric acid, and the yellow soln. on a
waterbath
furnishes the trans-salt [Pt(NH2OH)2Cl2] ; it dissolves with the development
of red fumes in nitric acid ; hydroxylamine converts it into platinous
tetrahydroxylaminechloride
; and a suspension of the salt in water when treated with ammonia
forms a white precipitate.
According to H. Alexander, if the filtrate from the mixture of platinous chloride
with
2[Ft(NH2OH)4](OH)2-[Pt(NH2OH)4]Cl2, or [Pt(NH2OH)4](OH)2.2[Pt(NH2OH)](OH)Cl, is
mixed with cone, hydrochloric acid, with cooling, there is formed platinous
transdihydroxylaminediamminochloride,
[Pt(NHg)2(NH2OH)2]Cl2 ; and the same
product is obtained by dissolving the corresponding hydroxide in a little cone.
PLATINUM
hydrochloric acid, and treating the soln. at a low temp, with alcohol. The
colourless
needle-like crystals are soluble in water, and insoluble in alcohol, or in cone,
hydrochloric
acid. Alkali hydroxides form a gelatinous precipitate of the
dihydroxylaminediamminochloride
; alkali carbonates, oxalates, and phosphates give
white, crystalline precipitates ; and potassium chloroplatinite, or
hydrochloroplatinous
acid, forms platinous trans-dihydroxylaininediainiiiinochloroplatiiiite,
[Pt(NHa)2(NH2OH)2JPtCl4, in dark green, acicular crystals. L. Tschugaeff and
always turbid, and if the turbid soln. is clarified by animal charcoal, it slowly
becomes turbid again at ordinary temp., and rapidly when heated. When treated
with potassium chloroplatinite, violet crystals of platinous cis-
dihydroxylaminediamminochloroplatinite,
[Pt(NHg)2(NH2OH)2JPtCl4, are formed, sparingly soluble
in water and acids. L. Tschugaeff and I. I. TscherniaefE also prepared platinous
dihydroxylaminodiamminochloropalladite, [Pt(NH3)2(NH2OH)2JPdCl4 ; platinous
trihydroxylaminoamminochloride, [Pt(NH3)(NH2OH)3JCl2; platinous
trihydroxylaminoamminochloroplatinite,
[Pt(NH3)(NH2OH)3JPtCl4 ; platinous trihydroxylaminoamminochloropalladite,
[Pt(NH3)(NH2OH)3JPdCl4; platinous
hydroxylaminotriamminochloride, [Pt(NH3)3(NH2OH)JCl2 ; and platinous
hydroxylaminotriamminochloroplatinite,
[Pt(NH3)3(NH2OH JPtCl4.
H. Alexander prepared platinous /raws-dichlorodihyfcoxylamine,
JPt(NH2OH)2JCl2, by treating with warm hydrochloric acid the precipitate obtained
by adding an excess of hydroxylamine to a soln. of platinous chloride ; by
evaporating
on a water-bath the pale yellow soln. of platinous
tetrahydroxylaminechloroplatiiiite,
and cooling the liquor ; and by digesting platinous tetrahydroxylaminechloride
with an excess of hot hydrochloric acid and cooling�H. Wolfram employed
a similar process. R. TJhlenhut obtained the salt by evaporating the filtrate,
obtained in the preparation of platinous tetrahydroxylamine chloride, to about
half its vol. and then cooling. The orange-yellow, or golden yellow, acicular
crystals are less soluble in water than the tetrahydroxylaminechloride. They are
soluble in alcohol, and in ether. The salt can be recrystallized from a soln. in
dil.
hydrochloric acid. Aq. ammonia forms the dihydroxylaminediamminochloride ;
and hydroxylamine, the tetrahydroxylaminechloride. Neither alkali hydroxides
nor silver oxide produces the free base. When the soln. mixed with silver nitrate
is allowed to stand for a long time in the cold, a feeble turbidity appears.
H. Wolfram prepared platinous e/s-dichlorodihydroxylamine, [Pt(NH2OH)2Cl21,
by mixing 2 c.c. of an 83 per cent. soln. of hydroxylamine with 2 Cc. of water, and
soon as al1 is dissol vcd an excess of alcohol is added. The oil which separates
soon
crystallizes, and the product is then washed with absolute alcohol, followed
by dry ether. The product is dried a short time in air and finally over
phosphorus pentachloride. The colourless acicular crystals are more stable
and less soluble than the corresponding cis-salt. It gives a precipitate with
potassium iodide ; and a red precipitate of platinous
dihydrazinodiamminochloroplatinite,
[Pt(NH3)2(N2H4)? JPtCl4, which soon darkens, is formed when
the soln. is treated with potassium chloroplatinite. Hydrochloric acid in the
cold forms a stable and sparingly soluble platinous /m/v*-
dihydraJzinediamminodihydrochloride,
[Pt(NH3)2(N2H4)2JCl2.2HCl.
IJ. Tschugaeff and M. Grigorieff prepared platinous cis-dihydrazdnediammino-
Chloride, [Pt(NH3)2(N2H4)2JCl2, by the action of hydrazine hydrate on platinous
cis-dichlorodiammine, as in the case of the trans-salt. The cis-salt furnishes
colourless, prismatic crystals, which can be preserved for a few days, but
gradually
darken owing to liberation of platinum ; the soln. in water, which dissolves
large quantities of the solid, decomposes much more rapidly. The mol. conductivity
of a soln. of a mol of the salt in 250 litres of water at 25� is 236-6. Other salts
correspond with the normal reactions of the components of the double salt. It is
also
assumed that when the red salt is dihydrated, the space-lattice is destroyed. It is
not
probable that the red colour of the dihydrate is due to a special space-lattice
because the
dehydrated red salt changes from a yellow to a red colour, when re-hydra ted by
exposure
to moist air.
H. Reihlen and E. Plohr said that the ionized halogen atoms of Wolff ram's red salt
salt is tervalent because " no compounds of tervalent platinum are known," on the
contrary, several have been reported vide supra. H. D. K. Drew and H. J. Tress
considered
the red salt to have tervalent platinum, [Pt etn4Cl]Cla.2HaO, in contrast with the
uitertransformablo dimeric salt, [Cl etn4Pt.Pt etn4Cl]Cl4, in whieh the platinum is
quadrivalent. Wben the red salt is dissolved in water, one or other of these forms
enters
into equilibrium with the cations [Pt etn4]"* and [Pt etn4Cl2]** and Cl'-ions. K.
A. Jensen
said that it is doubtful if Wolffram's red salt contains tervalent platinum because
it
is diamagnetic, -whereas the other compounds of tervalent platinum are
paramagnetic.
H. Reihlen and E. Flohr not only prepared the salt [Pt(NHaC8H6)4]Cl2.2H20 ; but
also
the complex salts, [Pt(NHaCaH6)4]Cl8.Pt(NHaCaH5)4ClalCl2.4HaO ; [Pt(NH2C2HB)2Cl3] ;
Lc(CH3)a.NHa'^' ^NH8.CH(C6HS)J a
into antirneric optically active forms which is taken to show that the 4-covalent
platinum
must have a planar configuration of its valencies, since the regular tetrahedral
arrangement
VOL. XVI. T
274 INORGANIC AND THEORETICAL CHEMISTRY
sulphinetriamminochloride, [Pt(NH8)8[(CH8)aS)]Cla.HaO.
with carbon disulphide, and Math chloroform. K. A. Jensen could not confirm
H. Londahl's a- and y-forms of PtCla|(C4H8)aS}a. H. Londahl described platinous
trans-dichlorodlethylsulphinedlbutylsulphine, [Pt|(C8HB)aS)|(C4H9)8S)Cla], and a
complex
with chloroform. C. W. Blomstrand prepared platinous cis-dichloroblsdi-iso-
amylsulphine,
[Pt|(C,H11)aS}aCla]; P. T. Cleve, platinous trianlllnediamminochlorlde,
[Pt(NH3)8(CBH5lsrH8)8lCl2
; H. Londahl, M. "Weibull, and C. W. Blomstrand described platinous trans-dichloro
276 INORGANIC AND THEORETICAL CHEMISTRY
HCl
chloroethylphosphitobistoluidinechloride, [Pt(C7H7NHj)8(F(OC8Hg)8)ClJCl. A.
Rosenheim and
platinous hydroxychiorophosphoanilidephosphoxytoluidide,LPt(P(C7H8N)3)(PO(C7H8N)}
( OH)Cl];
trichloroplatinite, [Pt(P(C7H8N)3)Cl3JH(C7H7NH2).
which dissolved when the mixture was warmed ; the liquid then decolorizes,
and on evaporation deposits crystals of the chloroplatinite. C. E. Claus,
L. F. Nilson observed that the salt is stable in air, and at 100�, or confined over
sulphuric acid, it slowly loses about 1 per cent, of water which cannot be removed
from the crystals by pressure between bibulous paper. The ordinary salt decrepi
28O INORGANIC AND THEORETICAL CHEMISTRY
tates when heated, but not so if it has been previously dried. J. Petersen found
the
lowering of the f.p., and the calculated mol. wt. :
The calculated values for the J. H. van HofT's coeff.�1. 15, 10�range from 2-32
to 2-96. J. Thomsen found the heat of formation (Pt, Cl2, 2KC1) ==45-17 CaIs. ;
(Pt, Cl2, 2KCl, Aq.)=41-8 CaIs. ; and the heat of soln., �12-22 CaIs. J. Lifschitz
and E. Rosenbohm studied the optical properties ; D. P. Mellor and F. M. Quodling,
the birefringence ; S. Aoyama and co-workers, the X-ray spectrum ; and
W. Crookes observed that 1OO parts of water dissolve 0-926 part of the salt at 16�,
and 5-263 parts with boiling soln. According to J. Lang, a soln. of the salt is
Qoloured brownish-black by hydrogen sulphide, and with hot soln., a black
precipitate
is formed ; ammonium sulphide gives a black precipitate. W. Peters
observed that no ammonia is absorbed by the dry salt ; and J. Lang, that with
aq. ammonia, green platinous tetramminochloropJatinite is formed ; ammonium
carbonate also decolorizes the hot soln. H. D. K. Drew and co-workers symbolized
the reaction with ammonia : K2PtCl4-*K2Pt(NH3Cl) Cl3-> Pt(NH3Cl)Cl ; and by
K2PtCl4^ K2Pt(NH3Cl)2Cl2-^ Pt(NH3Cl)2. A. Sieverts studied the action of sodium
hypophosphite on dil. soln. of potassium chloroplatinite resulting in the formation
with potassium hydroxide, and when the mixture is boiled, a brown substance is
formed which, when washed, dried, and heated, explodes. N. S. Kurnakoff, and
thin, four-sided plates of the salt are formed. The salt is deliquescent in moist
air ; it effloresces in dry air ; it melts at 100�, and slowly loses 5 mols. of
water
passing into the chloroplatinate and platinum. L. F. Nilson prepared strontium
chloroplatinite, SrPtCl4.6H2O, by mixing purified hydrochloroplatinous acid with
the theoretical proportion of strontium chloride, evaporating to dryness,
extracting
with water, and evaporating the soln. over sulphuric acid. The thin, four-sided
plates effloresce over sulphuric acid ; they melt at 100� with the evolution of
twothirds
the water of hydration ; they deliquesce in moist air ; and they are freely
soluble in water. L. F. Nilson prepared barium chloroplatinite, BaPt04.3H20,
by saturating hydrochloroplatinous acid with barium carbonate, and crystallizing
the soln. J. Lang observed that with the spontaneous evaporation of the soln.,
barium chloride is first precipitated. The four-sided prisms are coloured a darker
red than the potassium salt. The salt loses 2 mols. of water at 100�, without
decomposition, and the last mol. of water is expelled at 150�. The salt is readily
dissolved by water, and with ammonia it forms green platinous
tetramminochloroplatinite.
The ruby-red, rhombohedral crystals do not change in dry air, but they deliquesce
in moist air ; at 100�, water and hydrogen chloride are evolved. The salt dissolves
become dark orange when heated, and then yellowish-brown. The hexahydrate
gives off all the combined water at 100�, without melting. At a high temp, the
salt is resolved into zinc chloride, platinum and chlorine with a " transient
jumping
motion." The salt is sparingly soluble in cold water, more easily soluble in
boiling
water, and the original salt separates out on cooling, or on the addition of
alcohol.
The aq. soln. gives a brown precipitate with ammonium sulphide ; and the salt
is but slightly attacked by sulphuric acid. The aq. soln. gives a yellow
precipitate
with a soln. of cuprous chloride in hydrochloric acid ; and a dingy flesh-coloured
precipitate with silver nitrate. G. B. Buckton obtained platinous
tetramminochlorozincate,
[Pt(NH3)4 JZnCl4, from a cone. soln. of platinous tetramminoehloride
and zinc chloride. The colourless plates are soluble in water. J. Thomsen, and
N. S. Kiirnakoff prepared zinc tetramminochloroplatinite, [Zn(NH;j)4JPtCl4, by
adding ammonium chloroplatinite to an ammoniacal soln. of zinc chloride. The
reddish needles are slightly soluble in water, and freely soluble in hydrochloric
acid, from which soln. the salt is precipitated unchanged on adding aq. ammonia.
L. Tschugaeff and N. K. Pschenicyn studied the depolymerization of this salt.
S. G. Hedin obtained a complex salt with pyridine.
IJ. F. Nilson prepared cadmium chloroplatinite, CdPtCl4, in soln., but not in
the solid state from soln. of cadmium sulphate and hydrochloroplatinous acid,
or of barium chloroplatinite. The soln. deposits cadmium chloride when
evaporated. J. Thomsen prepared brick-red cadmium tetramminochloroplatinite,
[Cd(NHs)4IPtCl4, as in the case of the corresponding zinc compound.
platinite. The four-sided, prismatic crystals deliquesce in air, they melt at 100�
slowly giving off 9� mols. of water. L. F. Nilson could not prepare indium chloro
salt is recrystallized from boiling water, and dried at 100�. The salt is sparingly
L. Wohler and F. Martin said that the powder is black with a greenish tinge unlike
platinum di- or tetra-chloride. R. Klement gave 5-256 for the sp. gr. at 25�/4�,
and 57-4 for the mol. vol. S. Streicher, and Li. Wohler and S. Streicher said the
decomposition temp, is 435�, and that the heat of formation is (2PtCl2, Cl2)
=26-2 CaIs. The trichloride was found by F. Martin, and L. Wohler and F. Martin,
to be reduced by hydrogen in the cold ; it is slightly soluble in cold water, and
only
after several days is enough dissolved to impart to the soln. a yellow colour ; it
immediately dissolves in boiling water to form a brownish-red soln. which reacts
acid, and probably contains hydroxytrichloroplatinosic acid, H2PtOCl3, as a
result of hydrolysis. This same acid is formed when an aq. soln. of
hydrochloroplatinic
acid is reduced with sulphur dioxide. The aq. soln. of platinum trichloride
yields the original salt if evaporated in vacuo at 60� and then at 100� ; the salt
is almost insoluble in cone, hydrochloric acid at ordinary temp., but the warm
acid forms a yellow soln. containing platinic and platinous chlorides ; it readily
dissolves in an aq. soln. of potassium iodide, forming a dark brown liquid ; and
alcohol reduces it to metal at the same time forming aldehyde. The free acid,
hydrochloroplatinosic acid, H2PtCl5, could not be isolated, but on passing a little
and they discussed the varying valency of platinum -with respect to the mercaptanic
The salt appears in dark green, cubic crystals. The salt readily decomposes into
a mixture of caesium chloroplatinite and chloroplatinate. In a warm aq. soln.
the green colour quickly changes to yellow�characteristic of caesium
chloroplatinate.
Sunlight accelerates the decomposition into the higher and lower
chlorides. The salt also decomposes when heated, or when exposed to moist air.
PLATINUM 287
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292 INORGANIC AND THEORETICAL, CHEMISTRY
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� 22. Platinum Tetrachloride
Li. Pigeon 1 observed that only a very small yield of anhydrous platinic chloride*
or platinum tetrachloride, PtCl4, is obtained by passing chlorine over heated,
finely-divided platinum. At 360� di- and tetra-chlorides are formed, but a
considerable
proportion of the metal is not attacked. C. Nogareda found that the
tetrachloride is formed between 600� and 850�. A. Gutbier and F. Heinrich added
that the yield is not much better if platinum be heated with arsenic trichloride in
Finely-divided, spongy platinum mixed with somewhat less than its own weight of
selenium is placed in a stout glass tube one-third filled with arsenic trichloride,
and a
current of chlorine is passed in, the tube being gradually heated until the liquid
boils.
The platinum is rapidly and completely dissolved, and the tube is then sealed and
heated
at 250� for several hours. After cooling, the tube contains a pale yellow liquid,
orangeyellow
crystals, and also, if the selenium is in excess, colourless crystals. The crystals
are separated and heated in vacuo at 110�. They then consist of platinum
tetrachloride
and selenium tetrachloride, and are heated at 360� in a current of chlorine, when
selenium
chloride sublimes and anhydrous platinum tetrachloride remains as a brown, very
hygroscopic
powder. At 440�, it is converted into the dichloride. If platinum selenide is used
instead of a mixture of platinum and selenium, no action takes place even at 300� ;
if
selenium is omitted altogether, the platinum is not completely attacked, but the
action
becomes complete if selenium is added.
for many days at 150�. The anhydrous salt can be obtained by dehydrating the
hydrated tetrachloride, or hydrochloroplatinic acid. Thus, Ei. Pigeon heated the
PLATINUM 293
is by far the best mode of preparing the anhydrous salt, and L. Pigeon employed
a modification of the process. L. Wohler and F. Martin, and F. Martin passed a
current of dry hydrogen chloride over dry hydrochloroplatinic acid at 275�,
and W. Pullinger employed a similar process although A. Rosenheim and
W. Lowenstamm, and A. Gutbier and F. Heinrich said that the product is a mixture
of platinum di- and tetra-chlorides. L�. Pigeon added the theoretical quantity of
potassium iodide to a hot soln. of hydrochloroplatinic acid, and then passed
chlorine over the washed and dried platinum tetraiodide heated by an oil-bath.
The salt has been obtained in soln. J. W. Mallet noticed that platinum black
exposed to the atmosphere on a filter whilst in contact with cone, hydrochloric
acid forms a yellow soln. containing platinic chloride. IJ. Opificius observed that
when aqua regia acts on a mixture of platinum and ammonium chloroplatinate, and
the temp, is gradually raised to boiling, whilst the soln. is evaporated, the
reaction
can be symbolized : 2Pt+(NH4)2PtCl6+10HNO3+6HCl==3PtCl4+12H2O + 6NO2
+6NO. The hydrated platinic chloride forms a clear soln. with alcohol showing
that the ammonium salt has been all destroyed�vid e infra, hydrochloroplatinic
acid. According to J. Brown, commercial platinic chloride contains some iron salt ;
and, according to W. Gintl and B. Reinitzer, some auric chloride, and, according
to A. F. Hollemann, some sulphuric acid. The subject was discussed by
K. W. G. Kastner.
A number of definite hydrates have been reported. F. Reiff studied the
tendency of the hydrates to form aquo-salts. According to L*. Pigeon, the
monohydrate,
PtCl4-H2O, is formed when the higher hydrates are exposed over potassium
hydroxide in vacuo at 100�. A. Gutbier and F. Heinrich said that this hydrate is
formed when the anhydrous salt is exposed to air for a short time. S. M. Jorgensen
observed that the monohydrate decomposes with the expulsion of the last mol.
of water by heat. A. Miolati prepared the tetrahydrate, PtCl4.4H2O, by adding
uranyl acetate to an alcoholic soln. of the pentahydrate, filtering off the
precipitate
and washing it with alcohol and ether, and drying it over cone, sulphuric acid in
vacuo ; M. Blondel, by drying the octohydrate over sulphuric acid in vacuo ;
liquid. R. Engel said that the crystals of the tetrahydrate are not deliquescent.
S. A. Norton added 2 mols. of a soln. of silver nitrate to a soln. of a mol. of
hydrochloroplatinic
acid, and evaporated the filtered liquid over sulphuric acid. R. Engel
represented the reaction : H2PtCl6+2AgNO3=2AgCl-f-2HNO3+PtCl4. The
analyses of the product by A. Gutbier and F. Heinrich, S. M. Jorgensen, IJ. Pigeon,
and S. A. Norton agree with the analysis of the pentahydrate, PtCl4.5H2O. IJ.
Pigeon
evaporated a neutral soln. of platinic chloride in vacuo at not too high a temp.,
and
obtained what he regarded as a heptahydrate, PtCl4.7H2O. C. H. D. Bodeker said
that the ordinary hydrated platinic chloride is the octohydrate, PtCl4.8H2O, but,
according to R. Engel, the partial analyses made by C. H. D. Bodeker may have
applied to H2PtCl6.6H2O instead of to PtCl4.8H20. M. Blondel obtained the
octohydrate by dissolving at ordinary temp, a mol. of platinic oxide in 2 mols.
of hydrochloric acid, allowing the soln. to crystallize, and drying the product in
air at 15� ; he also said that this hydrate is formed when an aq. soln. of the
pentahydrate
is allowed to crystallize. The report of W. W. Mather, H. Lawrow, and
M. Protopoff that the ordinary salt is the de�iahydrate, PtCl4.10H2O, is considered
which L. Wohler and F. Martin said are very hygroscopic, and which W. Pullinger
said are not hygroscopic. A. Rosenheim and W. Lowenstamm, and A. Gutbier
and F. Heinrich observed that the crystals gradually absorb moisture from the air
to form PtCl4-H2O, then PtCl4.5H20, and finally H2PtOCl4.4H20. R. Engel
observed that the crystals of the tetrahydrate are not deliquescent ; and
The mol. vols, are by I. Traube. G. T. Gerlach made some observations on the
sp. gr. of soln.
F. Martin, and L. Wohler and F. Martin found that in an atra. of chlorine, the salt
decomposes above 275�, and S. Streicher, and L. Wohler and S. Streicher gave
370� for the temp, of formation and decomposition. L. Wohler and F. Martin's
observations on the range of stability of the platinum chlorides are summarized
in Fig. 79. C. Nogareda studied the subject. A. Gutbier and F. Heinrich found
200 300 400 500 600� 700�
that the salt is stable at 360�, but decomposes at about 400� into platinous
chloride
and chlorine. S. M. Jorgensen observed that the pentahydrate loses a mol. of
water rapidly when confined over sulphuric acid, and another mol. is lost very
slowly. Both S. M. Jorgensen, and S. A. Norton found that the salt loses 4 mols.
of water at 100�, and S. M. Jorgensen added that the salt decomposes in the attempt
to expel the last mol. of water ; and, according to L. Pigeon, and S. A. Norton,
platinous chloride is formed in the vicinity of 360�. C. Gordon stated that after
24 hrs.' heating of the hydrated salt to 150�, metallic platinum, and only a little
platinous chloride, are formed. M. Blondel noticed that in vacuo over sulphuric
acid, the octohydrate loses 4 mols. of water.
According to G. Oddo, the mol. wts. calculated from the f.p. of soln. of the
anhydrous chloride in phosphoryl chloride for soln. of concentration 0-5410, 3-
1874,
and 3-7114, are, respectively, 171-23, 324-3, and 3201. L.. Pigeon gave for the
heat of formation of the anhydrous tetrachloride, (Pt, 2Cl2) �59-4 to 59-8 CaIs. ;
and (2PtCH3, Cl2) =23-55 CaIs. ; for the heat of formation of the tetrahydrate from
the anhydrous salt and liquid water, (PtCl4, 4H2O) =21-32 CaIs. ; and for the
pentahydrate, 21-42 CaIs. L. Pigeon also gave for the heat of soln. of the
anhydrous
salt, 19-58 CaIs. ; for that of the tetrahydrate, �1-74 CaIs. ; and for that of the
EJ. Doumer found the index of refraction of the soln. with respect to water to
be 0-267. J. H. Gladstone gave 71-06 for the mol. refraction ; 26-0 for the
refraction
equivalent ; and 0-132 for the sp. refraction- Observations were also made by
and K. Meyer studied the absorption spectrum of aq. soln. ; and A. Hebert and
0*05N- and 2V-PtCl4 ; he attributed the acidity and the high conductivity of soln.
of platinic chloride to the formation of a complex acid, H2PtCl4(OH)2 ; and this
was
confirmed by A. Miolati ; H. T. S. Britton and E. N. Dodd represented the reaction
by PtCl4-InH2O^nHCl-F Pt(OH)wCl4_�^-(n���)HCl+mH# -KPt(OH)^CT4-�� �.
O. Stelling studied the electrolytic reduction of the acid in hydrochloric acid
soln.
N. Thon studied the electrolysis with a rarefied gas electrode. W. Hampe noted
the conductivity of the aq. soln., and that platinum is electrolytieally
deposited ;
and that alcoholic soln. are good conductors, but ethereal soln. are bad ones.
1). M. Bose and H. G. Bhar, and J. A. Christiansen and R. W. Asmussen studied
the magnetic properties.
S. M. Jorgensen gave for the constitution of the pentahydrate :
d,=Pt<^=^ H . 4H2O
G. WyroubofT said Pt(OH)2Cl2.2HC1.2H20 ; and L. Pigeon added that all 5 mols.
of water are water of crystallization because they can be removed by gradually
heating the salt to 215� without interfering with thePtCl4-group. Chlorine is
first evolved at about 360�. S. M. Jorgensen, and F. Kohlrausch, however, showed
that the fifth molecule of the pentahydrate cannot be removed without decomposing
the salt. The constitution was discussed by A. Hantzsch, and A. Muller.
According to A. Miolati, the conductivity of aq. soln. of platinic chloride is
characteristic of that for a weak acid, and is similar to that of selenious acid.
W. Hittorf
and H. Salkowsky, and W. Dittenberger and R. Dietz observed that in the
electrolysis
of aq. soln., platinum goes to the anode. This is taken to indicate that an
oxy-acid, H2PtOCl4, is formed. W. Pullinger found that an aq. soln. of platinic
296 INORGANIC AND THEORETICAL. CHEMISTRY
chloride has a marked acidic reaction towards litmus, and rapidly decomposes a
soln. of sodium carbonate with the evolution of carbon dioxide. F. Kohlrausch
observed that, owing to hydrolysis, the conductivity of the aq. soln. changes
rapidly
as time goes on, and, when the limit of the hydrolysis in dil. soln. is attained,
all
the chlorine is present as hydrogen chloride ; in more cone, soln., the hydrolysis
does not go so far. The observed data agree with the assumption that H2PtOCl4
is a moderately-ionized, monobasic acid. The hydrolysis is accompanied by a
change in colour from an almost greenish-yellow to a bright orange-red, and in
more dil. soln., there is a kind of fluorescence, which is attributed to the
separation
of finely-divided platinic hydroxide. A. Miolati observed that when an aq. soln.
of platinic chloride is titrated with sodium hydroxide using phenolphthalein as
indicator, neutralization occurs when 2 eq. of the alkali have been added. The
sp. conductivities of soln. to which successive quantities of alkali have been
added,
showed that an acid and a normal salt were present. The presence of a dibasic acid
in aq. soJn. of platinic chloride is also shown when a standard soln. of ammonia is
H. Salkowsky said that the platinic chloride probably passes into soln. as the
monohydrate,
and that this added mol. of water causes the ready scission of the molecule.
It is assumed that platinic chloride is intermediate between ordinary metallic
chlorides, and those chlorides which are decomposed by water. W. D. Tread well
and M. Zurcher studied the electrometric titration of the salt.
F. C. Phillips observed that hydrogen reduces the solid, hydrated platinic
chloride below 80� with the evolution of water and hydrogen chloride ; and that
an aq. soln. of the chloride is slowly but completely reduced by hydrogen in the
cold, or at 100�. V. V. Ipateeff and co-workers found that at 20� to 30�, platinum
is precipitated by hydrogen under 25 to 50 atm. press. W. Pullinger, A. Rosenheim
and W. Lowenstamm, A. Gutbier and F. Heinrich, and L. Pigeon noted that
anhydrous platinic chloride is freely soluble in water, and that there remains a
pale, orange-red residue which is thought to be one of the lower chlorides ;
A. Gutbier and F. Heinrich, and L. Pigeon found that the hydrated forms also
dissolve in water�the monohydrate with the evolution of heat, and the tetraand
penta-hydrates with the absorption of heat. For the hydrolysis of the salt
in aq. soln., vide supra. According to R. Engel, dry hydrogen chloride liquefies
the solid tetrahydrate at 50�, forming hydrochloroplatinic acid ; and S. M.
Jorgensen
also observed that hydrochloric acid immediately converts the pentahydrate
into hydrochloroplatinic acid. A. Ditte observed that hydrated platinic chloride
dissolves more readily in hydrochloric acid, the more concentrated the acid.
D. Helbig and G. Fausti showed that hydrated platinic chloride is insoluble in
liquid hydrogen chloride. F. Gramp showed that iodine reduces an aq. soln. of
platinic chloride to platinous chloride. H. St. C. Deville and J. S. Stas, H. Rose,
C. T. Barfoed added that the precipitate dissolves in warm, dil. nitric acid, but
not
in hydrochloric acid ; N. W. Fischer said that the precipitate is soluble in
hydrochloric
acid, and H. Reinsch observed that a soln. of 1 part of platinic chloride in
1OO parts of water and mixed with 25 parts of hydrochloric acid does not give a
precipitate with hydrogen sulphide. This statement suggests that there is a
reversible reaction : PtCl4+2H2S^PtS2-J-4HC1�10. 57, 9. U. Antony and
A. Lucchesi found that all the metal is precipitated as platinic sulphide from a
3 per cent. aq. soln. of platinic chloride at 90�, and that for analytical
purposes,
the precipitate should be collected and washed in an atm. of hydrogen sulphide,
and dried in an atm. of nitrogen, at 70� to 80�. At ordinary temp., 15� to 18�, a
mixed yellow and brown precipitate is formed in soln. of hydrochloroplatinic
acid, and the supernatant liquid remains red ; the mixed precipitate continually
loses hydrogen sulphide on heating, and ultimately yields platinic sulphide at
200�. The brown and yellow precipitates are possibly platinic hydrosulphides.
The reddish mother-liquor contains colloidal platinic sulphide, which is slowly
deposited even at 0�. A 0 5 per cent. aq. soln. of hydrochloroplatinic acid gives
no precipitate at 15� to 18� with hydrogen sulphide, but only a red-brown
coloration
; no precipitate is obtained on boiling, but on adding hydrochloric acid, the
soln. deposits platinic sulphide, and becomes decolorized. The precipitation of
platinic sulphide from the more cone. soln. at 15� to 18� thus seems due to the
action of the liberated hydrochloric acid. H. SchifE found that potassium
polySUlphide�
or liver of sulphur�gives a precipitate which dissolves when boiled
with an excess of the reagent. L. Crosnier studied the action of metal sulphides
on platinic chloride ; and A. Levallois found that when the hydrated chloride is
heated with lead, sulphide, it is decolorized, and furnishes yellow anastosmosed
needles. O. Brunck found that sodium hyposulphite colours a soln. of platinic
chloride dark red, and hydrochloroplatinous acid is formed, and some sulphur is
precipitated. A soln. containing 0-1 grm. of platinum per litre is intensely
coloured
at once by the hyposulphite ; but a soln. with O01 grm. per litre is coloured when
warmed and viewed in a layer IO cms. thick. G. Geitner found that sulphurous
acid decolorizes a soln. of platinic chloride, and if the decolorized soln. be
heated
in a sealed tube at 200�, platinic sulphide is formed ; at ordinary temp., K.
Birnbaum
found that platinous chloride is formed and that the chlorine of that compound
can be replaced by the radicles HSO3, NH4SC3, etc. According to P. Berthier,
a soln. of platinic chloride is very rapidly decolorized by soln. of potassium or
ammonium sulphite, particularly when heated with an excess of the sulphite, a
white precipitate is formed which dissolves in an excess of water particularly when
heated. The precipitate formed in cold soln. is probably the chloroplatinite.
R. Silberberger found that the presence of platinum salts in dil. soln. does not
affect
the precipitation of barium sulphate by the addition of barium chloride ; in cone,
soln. some platinic salt may be adsorbed by the precipitated barium sulphate.
H. Vohl, and W. Knop observed that in acidic soln. platinum salts give a
precipitate
of platinous sulphide when they are treated with a soln. of sodium thiosulphate�
particularly with warm soln. ; and P. Schottlander, and P. Jochum, that in
ammoniacal soln., a complex platinous alkali thiosulphate is formed. M. C. Lea
observed that with an ammoniacal soln. of sodium thiosulphate, ammonium
chloroplatinate is first precipitated, and then, with heating, the soln. becomes
yellow, then colourless, and finally wine-red. C. Langlois observed that trithionic
acid gives a black precipitate ; M. C. Lea, that tetrathionic acid forms a wine-red
heirn and W. Levy observed that platinic chloride acts only on the esters of
quinquevalent
phosphorus and not on those of tervalent phosphorus ; with ethyl
phosphate, it interacts to form triethyl phosphate platinochloride, whilst it does
not act on ethyl phosphite. Platinous chloride, on the other hand, reacts with
esters of phosphorous acid, but not with esters of phosphoric acid. C. Claus, and
H. Rose found that sodium phosphate does not give a precipitate with cold or
boiling soln. of platinic chloride. B. E. Dixon studied the action of alkali
phosphates
on hydrochloroplatinic acid in ammoniacal soln. L. Kahlenberg and
J. V. Steinle represented the reaction with arsenic by 3PtCl4�}-4As-}-6H20
=3Pt-[-2As2O3-I-12HCl. J. F. Simon, and R. Bartels found that arsine gives a
black precipitate with soln. of platinic chloride. C. Reichard observed that
potassium
hydroarsenite precipitates platinic arsenite from soln. of platinic salts ;
and T. Thomson, that sodium arsenate gives a light brown precipitate soluble
in nitric acid. J. F. Simon, and R. Bartels observed that stibine gives a black
precipitate in soln. of platinic chloride, and that the precipitate contains
antimony
trioxide and platinum, and possibly a platinum and antimony compound is formed.
M. C. Harding found that a dil. soln. of platinic chloride, and an excess of
antimonious
acid, gives a dark brown precipitate containing platinum and antimony
trioxide.
According to E. Heymann, when a soln. of platinic chloride is treated with
carbon at room temp., hydrolytic absorption occurs ; and a reduction to metallic
platinum occurs at 100�. E. Heymann found that the platinum compound which
is adsorbed by carbon from aq. soln. of platinic chloride, at ordinary temp., is
probably a hydrolysis product, say, Pt(OH)4, at 100�, platinum is adsorbed.
According to Gr. Gore, coal gas, bubbled through a soln. of platinic chloride,
decomposes
only a vcTy small proportion during IO weeks ; the products of combustion also
produce only a slight decomposition. P. Kothner, and H. Erdmann and P. Kothner
found that ethylene, and �sobutylene have no action in the cold, whilst propylene,
trimethylene, and acetylene have no action in the cold or at 100�. In the
replacement
of chlorine atoms by hydrocarbon radicles, compounds like platinic
trimethylchloride,
(CH3)3PtCl, are formed. According to K. G. Cox and C. Webster, this compound
has a body-centred cubic lattice with <z = 1052 A., and 8 mols. per unit cell.
F. O. Phillips observed that carbon monoxide acts on cold and boiling soln. of
platinic chloride forming carbon dioxide ; no precipitate is formed, but the soln.
is reduced to platinous chloride, and if the action is continued for days or weeks,
and finally yellow when it is treated with ammonia ; the addition of more
ferrocyanide
produces a yellow soln. The green precipitate dissolves in hydrochloric
300 INORGANIC AND THEORETICAL CHEMISTRY
acid to give an indigo-blue soln., and this reaction enables 1 part of platinum in
1000 parts of soln. to be detected. D. Vitali noted that in ammoniacal soln. of
platinum chloride potassium ferrocyanide and ferricyanide give yellow precipitates
of potassium chloroplatinate, with a red soln. in the former case, and a green
soln.
in the latter case. E. H. Miller and J. A. Mathews, and F. van Dyke Cruser and
and H. Rose said that potassium thiocyanate darkens a soln. of platinic chloride
owing to the formation of a very soluble thiocyanate. The reaction -was studied
by G. B. Buckton. F. W. Clarke and M. E. Owens found that an alcoholic soln. of
platinic chloride gives a pale buff precipitate with potassium cyanate.
A. E. Dunstan, and A. E. Dunstan and L. Cleaverley observed that benzoflavol
forms a complex salt: (C2IH17O2N)4H2PtCl6; G. T. Morgan and F. M. G. Micklethwait
obtained a complex with cumarin, (C36H24O8)H2PtCl6^H2O; A. von Baeyer and
V. Villiger, with cinnamaldehyde, and benzylideneacetone ; and A. Rosenheim and
co-workers, with ethylacetoacetate, and acetylacetone. According to F. C. Phillips,
of platinic chloride ; and C. Claus, that borax does not give a precipitate in
cold or in boiling soln. E. Muller and W. Stein titrated the soln.
electrometrically
with titanous chloride.
F. Reitzenstein observed that sodium a-yrifl.lgft.Tifi does not react with cyanide
soln. of platinum salts, and similarly also with zinc dust. O. Lioew found that
hydrochloroplatinic acid and zinc frwifllgftiwi form mercury hydride. G. and W. van
PLATINUM 301
Dam observed that a drop of mercury causes the evolution of ammonia from soln.
of platinic alkylaminochlorides. A. Merget studied the action of mercury vapour.
does not give a precipitate at ordinary temp., but with a prolonged boiling sodium
platinate is formed ; calcium hydroxide forms a yellowish-white precipitate,
especially in sunlight, and barium carbonate gives no precipitate in the cold or
with boiling soln. J. F. W. Herschel studied the action of lime-water on the soln.
exposed to light. W. Kwasnik found that barium dioxide reduces a mixture of
platinic chloride and silver chloroplatinate to metal, but not so with
hydrochloroplatinic
acid. K. Birnbaum noted that silver chloride is readily dissolved in cone,
soln. of platinic chloride, as nearly neutral as possible, but is recovered
unchanged
on evaporating the soln. C. Olaus, and A. Commaille observed that silver nitrate
gives a yellow precipitate of silver chloroplatinite. F. W. Clarke found that with
Silver fluoride there is a reaction: PtCl4-+-4AgF-K2H20=Pt02-h4AgCl+ 4HF,
and with silver nitrate some nitric acid is formed. H. Grerresheim observed that
with a soln. of Millon's base, HgOH.NH.HgCl, in hydrochloric acid, ammonium
chloroplatinate is precipitated. C. Claus, and A. Commaille observed a reddish
precipitate with mercurous nitrate soln. C. T. Barfoed observed that stannous
Chloride colours soln. of platinic salts a deep reddish-brown, and after a time the
and G. A. Hulett obtained yellow colorations with very dil. soln. L. Wohler and
A. Spengel found that the red colour is developed by the presence of ether, or
better
still, of ethyl acetate ; it is not conditioned by the formation of platinous
chloride,
but rather by the formation of colloidal platinum�vide purple of Cassius�3. 23,
11 ;
7. 46, 14. K. Muller and W. Stein titrated the soln. electrometrically with
stannous
chloride. M. Frenkel said that no precipitate is produced by potassium chromate
in soln. of platinic chloride. O. W. Gibbs obtained a series of complex platinic
molybdates by the action of platinic chloride on soln. of ammonium molybdate;
and complex platinic tungstates, when sodium tungstate is used. F. W. O. de
Coninck observed that dil. soln. of uranous sulphate and manganous sulphate do
not act on soln. of chloroplatinates in darkness or in diffuse daylight ; in
sunlight,
the uranous sulphate is oxidized to uranic sulphate, and a basic sulphate whilst
platinous chloride is formed. A mixture of manganous chloride and platinic chloride
this acid is the hexahydrate, H2PtCl6.6H2O. R. Engel showed that the decahydrated
platinic chloride of C. H. D. Bodeker, II. Lawrow, and M. Protopoff is probably
the hexahydrated acid�vide supra. S. M. Jorgensen, R. Engel, and L. Pigeon
made some observations on the constitution. L. F. Nilson represented it by
(H.C1 : Cl)2== Pt=Cl2-OH2O ; R. Engel, (PtCl4.2H20)2(HC1.2H20) ; and JL. Pigeon,
PtCl4(HCl.2H2O)2.2H2O. J. J. Berzelius showed that the aq. soln. reacts acidic
to litmus. J. Thomsen showed that the acid is dibasic, and forms double salts
with the bases. The heats of neutralization of an eq. of the acid with 2, 4, and
6 eq. of NaOH�namely, 27-216, 27-24O, and 27-336 CaIs.�are characteristic of
strong acids. P. Klason, and P. Walden also showed that the properties of the
soln. agree with the dibasicity of the acid. L. Spiegel discussed the electronic
structure.
boiled several times -with dil. hydrochloric acid, then washed by decantation with
hot water,
and the residue digested with aqua regia, diluted -with 2 vols, of -water, and kept
warm
on a water-bath for 12 hrs. The soln. was evaporated in a slow current of chlorine,
with
frequent additions of hydrochloric acid to drive off the nitric acid.
IJ. Pigeon, and W. Dittmar and J. McArthur dissolved the spongy platinum in
hydrochloric acid through which a current of chlorine was passed for 12 hrs.
The excess of chlorine was removed from the clear liquid by evaporation.
P. Rudnick, and P. Rudnick and R. D. Cooke oxidized with cone, hydrogen dioxide.
H. C. P. Weber obtained a soln. of hydrochloroplatinic acid by dissolving spongy
or scrap platinum in aqua regia, removing the excess of acid by neutralization or
evaporation, and reducing the soln. with alkali formate or zinc. The precipitated
PLATINUM 303
platinum is warmed with a little dil. hydrochloric acid in order to remove iron,
and
covered with cone, hydrochloric acid. The electrodes are composed of sheet
platinum. The precipitated platinum thus forms the anode of an electrolytic cell.
this process.
of these processes�say over calcium oxide and cone, sulphuric acid as recommended
H. W. Hake said that the maximum quantity of water absorbed during a few days'
exposure to atmospheric air amounts to 47-82 per cent.�i.e. H2PtCl6.21H2O.
R. Engel said that the salt is relatively stable. When heated, it loses hydrogen
chloride and water, and then some chlorine is given off and platinous chloride is
formed. H. Topsoe observed that some hydrogen chloride, and chlorine are lost
at 110�, and, added J. J. .Berzelius, at a higher temp., platinous chloride and
platinum are formed. According to TJ. Pigeon, no platinous chloride is formed
when the hydrochloroplatinic acid is heated 5 hrs. in vacuo at 170� ; at 280�, a
small proportion of platinous chloride is formed, but more is produced at 358�.
When heated in vacuo in the presence of potassium hydroxide, the first product
of the action is HPtCl5.2H2O, and afterwards platinous chloride appears. The
heat of formation (2HC1.6H20, PtCl4)�20-46 CaIs., (HC1.4H.,0, HPtCl5.2H2O)
�lOOO CaIs., and (PtCl4, 2HCl)-=24-8 CaIs. ; the heat of soln. is 4-34 CaIs.
J. Thomsen gave (Pt, Cl4, 2HCl, Aq.) ^84-62 CaIs.; (Pt, O2, GHCl, Aq.) = 64-06
CaIs.
Y. Shibata and K. Ilarai, and R. Samuel and A. R. Despande. studied the absorption
spectrum.
K. Seubert said that the aq. soln. of the purified salt is golden-yellow, and
J. J. Berzelius added that if some iridium salt is present, the colour may be
reddishyellow,
or brown. According to A. Hantzsch, eq. soln. of hydrochloroplatinic acid
and of sodium chloroplatinate, containing the complex PtCl6"-ion, in the same
solvent, are optically identical�that is, they show the same absorption spectrum,
and the molecular absorption is independent of the degree of ionization. The
light absorption of the acid and of the salt is also unaffected by changes of
temperature.
The solvent does not appear to exercise any influence on the absorption
in the blue and violet parts of the spectrum, but does so to a very slight extent
in
the green and ultra-violet. The temp, coeff. of the absorption spectrum is very
small. F. Kohlrausch observed that the behaviour of soln. of hydrochloroplatinic
acid in light resembles that of soln. of platinic chloride�vide sujtra.
The electrical conductivity of soln. of 0-IiV-H2PtCl6 changes in light owing to
hydrolysis ; but more cone. soln. are stable, and are not affected by light. A
freshly-prepared soln. with 0-0002 gram-equivalent per litre had an eq.
conductivity
380, and when hydrolyzed in light, 1048, showing that all the chlorine
is probably present as hydrochloric acid. J. A. Prins and A. Fonteyne studied
the X-ray diffraction of aq. soln. The eq. conductivities, A, of soln. of the
following
concentration in gram-equivalents per litre, at 18�, were :
mobility, migration velocities, and the effect on the hydrolysis of acetates. The
eq. electrical conductivities of soln. with an eq. of the acid in v litres, at 25�,
are :
M. Boll, and M. Boll and P. Job also studied the conductivity of 0-OOOliV-soln.
of hydrochloroplatinic acid exposed to light, and the results show that in every
case an atom of chlorine remains combined with the platinum ; they suggested
that the compound formed will probably contain two atoms of platinum in the
molecule since the monoplatinic acids are unstable under the given conditions ; the
formate very tenaciously. If the ratio HCOONa : H2PtCl6 is less than 2:1 , the
black is mixed with hydroxide and gives off oxygen when heated ; gas-free platinum
black is produced when the ratio is just 2 : l,and the product is grey,and not
finely
pared a double salt with cocaine and hydrochloroplatinic acid ; and R. Fricke and
P. Walden showed that they are simple salts with the PtCl6 as a bivalent radicle,
and are not double salts. The general properties were studied by P. Rohland ;
and the relation stabilities of the halogenoplatinates, by H. I. Schlesinger and
R. E. Palmateer. O. Stelling studied the electrolytic reduction of the hydrochloric
A. Miolati found the mol. conductivities of soln. with a mol of the salt in 25O,
500,
IOOO, and 2000 litres to be, respectively, 432-5, 483-9, 522-9, and 553-5. G. Beck,
and
I. I. TscherniaefT and S. I. Chorunshenkofx studied the ionization constants ; and
A. A. Griinberg and G. P. Faermann, the acidity of the salts. A. A. Griinberg, and
G. Schwarzenbach gave for the effects of acidifying the platinum hexammines :
[Pt(NH3)614 + -^[Pt(NH3)5.(NH2) 13++H^ = �0-55 volt; and [Pt(NH3J5(H2O)]^
^lPt(NH3)5(OH)P+ +II+-== -�0-23 volt. B. Gerdes observed that platinic and
auric chlorides gave sparingly soluble precipitates. That produced by the former
is the dihydrate, [Pt(NH3)6 |04.2H20, which furnishes yellow octahedra which
lose their water at 120�, and become paler in colour.
O. Carlgren and P. T. CIeve prepared platinic dihydroxytetramminochloride,
[Pt(NH3)4(OH)2]Cl2, by the action of 3 per cent, hydrogen dioxide on p latino us
tetramminochloride ; and by the action of barium chloride on the corresponding
sulphate. Li. A. Tschugaeff and W. Chlopin found that this compound is formed by
the action of hydrogen dioxide on platinous cis-dichlorodiammine. O. Carlgren
and P. T. Cleve said that the aq. soln. furnishes colourless, monociinic plates
which
K. Johansson found to have the axial ratios a : b i c�1-5310 : 1 : 0-6702, and
and /?=100� 34' ; the (HO)-cleavage is incomplete. A. Werner, and A. Werner
and A. Miolati found the mol. conductivity of soln. with a mol of the salt in 125,
25O, and 5OO litres at 20� to be, respectively, 204-9, 218-8, and 225-7. O.
Carlgren
and P. T. Cleve found that 100 parts of cold water dissolve 0-485 part of the salt,
and allowed the soln. to cool slowly. W. Lossen, and H. Alexander obtained the
salt as a by-product in the preparation of hydroxylamine hydrochloride in the
mother-liquor remaining after the removal of ammonium chloride by platinic
chloride ; and F. Hoffmann observed that it is formed when platinic ci�s--
dihydroxylaminediamminochloride
is boiled with hydrochloric acid. The nature of the compound
was discussed by E. Gapon, C. Weltzien, C. Gerhardt, W. Odling,
S. H. C. Briggs, S. M. Jorgensen, and A. Werner and co-workers. The lemonyell
ow, crystalline powder consists of octahedral or quadratic plates. According to
E. G. Cox and G. H. Preston, the crystals of the a-salt are lemon-yellow,
tetragonal
�sometimes bipyramids�usually tabular on the (OOl)-face ; and the X-radiograms
corresponded with a cell having a�5-72 A., c=10-37 A., and 2 mols. per unit
cell, so that the calculated sp. gr. is 3-61, and the observed result is 3-3. Each
ammonia group in the cell is surrounded by 8 chlorine atoms, belonging to its own
or adjoining molecules, and each chlorine atom is surrounded by 4 ammonia mols.
TheyS-salt forms lemon-yellow rhombic plates tabular on the (010)-face and bounded
by the (lOl)-face or the (lOO)-face. The crystals are sometimes distorted. The
cell dimensions are a== 10-0 A., 6=11'2 A., and c=6-0 A. There are four molecules
per unit cell, and the calculated sp. gr. is 3-6, when the found value is 3-3.
P. T. Cleve observed that the crystals begin slowly to decompose at 200� to 216�,
and F. Hoffmann added that no explosion occurs. E. Petersen observed that a
mol of the salt dissolved in 250 litres of water depressed the f.p. 0-028� ; and
A. Werner and A. Miolati observed that the electrical conductivity of the soln.
308 INORGANIC AND THEORETICAL, CHEMISTRY
containing a mol of the salt in ICK)O litres is practically zero immediately after
the
salt has dissolved, but as time goes on, hydrolysis occurs, and after a minute, the
mol. conductivity, ^t, of a soln. with a mol of the salt in 1000 litres, after t
minutes,
was :
1 4 7 10 15 20 60
E. Petersen found the conductivity of soln. with a mol of the salt in v litres to
be :
v . 125 250 50O 10OO 20OO 4000
(at, O0 . � 116-5 123-5 128-5 128-8 128-6
^) at 25�. - 135-2 142-3 155-5 1800 204-9 242-3
hydroxide dissolves the salt without the evolution of ammonia, and a dirty yellow
precipitate is formed when acids are added to the golden-yellow soln. The chlorine
is all precipitated when a soln. of the salt is boiled for a long time with silver
nitrate.
P. T. Cleve prepared platinic c?s-tetracMorodiaminine, [Pt(NHa)2Cl4], by
treating platinous cts-dichlorodiammine with chlorine, or boiling it with nitric
acid ; and 8. M. Jorgensen, by the action of a cone. soln. of ammonium chloride
on silver dihydroxychloroplatinate. The orange-yellow powder consists of
rhombic or hexagonal plates, or needles. According to P. T. Cleve, the salt loses
no weight at 160�, but becomes olive-green; at 210�, it becomes dark green;
and at about 240�, slowly decomposes. E. Petersen found that the lowering of
the f.p. of a soln. with a mol of the salt in 250 litres is 0*014�. A. Werner and
A. Miolati found the electrical conductivity of aq. soln. is nearly zero
immediately after the salt has dissolved, but as time goes on, hydrolysis occurs,
and the conductivity increases, E. Petersen gave for the conductivities of
soln. with a mol of the salt in 125, 250, 500, and 1000 litres at 25�,
respectively,
16-9, 20-6, 24-0, and 27-3 ; and for a soln. of a mol of the salt in 1000 litres :
Ape of solution. . 0 5 15 30 60 minutes
Mol. conductivity . 25-6 32 0 39-6 53-3 79-2
The nature of the salt was studied by A. Werner and C. H. Herty, and A. Miolati.
P. T. Cleve said that 100 parts of water dissolve 0-333 part of salt at 0�, and 1-
54
parts at 100�. The salt is not decomposed by cone, sulphuric acid; sulphur dioxide
in the boiling aq. soln. forms platinous cis-hydrosulphitochlorodiammine, and
alkali-lye forms a pale yellow soln. without the evolution of much ammonia.
P. T. Cleve reported platinic tetrachlorotetrammine, Pt(NH3)4Cl4.H20, to
be obtained by heating platinic dihydroxytetrammine, Pt2(NH3J4(OH)2-H2O, with
aqua regia. The yellow, amorphous powder is dried at 100�. B. B. Dixon prepared
silver cmorodiamidotriamminochloride, [Ag3{Pt(NH3)3(NH2)2Cl}2]Cl5 ; and silver
platinic hydroxytriamidodiamminochloride, [Ag2{Pt(NH3)2(NH2)3(OH)}]Cl2.
P. T. Cleve prepared platinic dihydroxydicnlorobisaixudohexaniininochloride,
r H�\p t/ NH�\pt/ o H ici
L(NH3V ANH 2 / 1 ^ (NH3)J014
by the action of hydrochloric acid on the nitrate of the series, and drying the
product
over sulphuric acid, or at 100�. The snow-white, acicular crystals are sparingly
PLATINUM 309
soluble in water ; and silver nitrate precipitates all the chlorine from the salt
in
aq. soln.
Platinic chloride forms a number of complex salts with the alkyl and other amines,
sulphines, selenines, phosphines, etc. S. M. Jflrgensen a prepared platinic
dichloroquatermethylamlnechloride,
[Pt(CH3NH2)4C12]C12; I. I. Tscherniaeff, platinic
dichloroethylenedlaminopyridinoamminochloride,
[Pt(NH3) en py Cl2]Cl2 ; platinic dichlorethylenediaminodiamminochloride,
[Pt(NH3) a en Cl2 JCla ; platinic trichloroethylenediaminoamminochloride,
[Pt(NH3) en CI3]Cl; platinic triehloropyridinoethylenediaminochloride, | Pt en py
Cl3]Cl;
platinic trichloropyridinoethylenedlaminochloride, [Pt(NH3) en Cl3]Cl; platinic
trichloropyridinoethylenediaminoehloride,
[Ptenpy Cl3]Cl. 2H20 ; platinic trichloropyridinoethylenediaminochlorlde,
[Pt en py Cl3]Cl ; platinic dichloronltrltopyridinoethylenediaminochloride,
L Pt en py (NO2)C1]C1; platinic chlorodinitritopyridinoethylenedlaminochloride, [Pt
en py (NO2)2C1J
CL2HaO ; platinic chlorodinltritopyrldinoethylenediamlnohydroxide, [Ptenpy
(N02)aCl]OH ;
platinic chloroamidonitrltopyrldinoethylenediamlnochlorlde, [Ptenpy (NH2)
(NO2)Cl)C1.2HaO ;
platinic chloronitritopyrldinoethylenediaminoammonochloride, [Pt(NH3) en py
(NO2)Cl]Cl2 ;
platinic chloronitritoethylenedlaminodiamminochloride, [Pt(NH3)2en(N02)Cl]Cl2, and
platinic
dichloroethylenediamlnodiamniinochloride, [Pt(NH3)2 en Cl2]Cl2, and its isomerido ;
platinic
dichloronitritopyridinoethylenediamlnochloride, [Ptenpy (NO2)Cl2]Cl, and its
isomorides ;
platinic dichloronltritopyrldinoethylenediamlnohydroxide, [Ptenpy(NO2)Cl2]OH, and
its isomerides
; platinic dichloronitritoethylenediaminoammlnochloride, [Pt(NH3)en(NOa)Cl2]Cl, and
Srr^?^*S[l^l8hoff'
o f PIatinic
t?�T*vr*�^t�'**^Z*.^clodiii*t?tiona bispropyM-dibutylaminehydrochloride,
Pl*Unic
R��s, and P. Groth, the active and inactive forms of this salt; J. Tafel,
and N. Kursanoff, the compound with secondary amyl ; and M. Freund and F. Lenze,
PLATINUM 311
W. Rudneff, A. Hies, and P. Groth, two modifications of the compound with tertiary
amyl.
A. W. Hofmann, A. Ries, and J. A. Io Bel studied platinic
bisdiamylaminehydrochloride,
2(C5HiX)2]SrII-HCLPtCl4, with n-amyl ; R. T. Plimpton, and R. D. Silva, the
compound
�with inactive iso-amyl, and R. T. Plimpton, the compound with active iso-amyl.
A. W. Hofmann studied platinic blstriamylaminehydrochloride, 2(C5H11J3]Sr-HCLPtCl4,
Cl �
Cl\ � xNHa�CH
>Pt<
C1X^ NH 2-CH 2
[Pt(C12H7Ns)2Cl2].
L. Balbiano i a described platinic tetrachlorobisglyoxal, [Pt(C3H4N2)2C14J ; C.
Stoehr,
platinic tetrachloroblspyrazine, [Pt(C6H4N2)2Cl4] ; C. Stoehr, platinic
tetrachlorobis-2,
5-dimethylpyrazlne, [Pt(C6H8N2)2C14] ; C. Stoehr and M. Wagner, platinic
tetrachlorobis-2,
5-dimethyl-3-ethylpyrazlne, [Pt(C8H 12N 2)2C14] ; and O. Poppenberg, platinic
tetrachlorocinnamylpyrldazine,
[Pt(C18H10N8)2C14] ; C. Stoehr, pyrazlnium pyrazinepentachloroplatinate,
[Pt(C4H4N2)Cl6]H(C4H4N8) ; dimethylpyrazlnium 2, 5-
dimethylpyrazinepentachloroplatinate,
[Pt(C6H8N2)Cl6]H(C6H8N8); P. Brandes and C. Stoehr, trimethylpyrazinium 2, 3, 6-
trimethylpyrazlnepentaehloroplatinate,
[Pt(C7H10N2)Cl6]H(C7H10N2) ; C. Stoehr, 2, 5-dlmethyl-
3ethylpyrazinepentachloroplatinic
acid, [Pt(C8H12N2)Cl6]H ; G. T. Morgan and F. H. Burstall,
complexes with dipyridyl.
G. Pellizzari " described platinic tetraohlorobis-1, 3, 4-triazol, [Pt(C2H3N3)8C14]
;
A. Andreocci, and G. Pellizzari, platinic tetrachlorobls-l-phenyl-1, 3-triazol,
[Pt(C8H7Ns)8Cl4J;
G. Pellizzari and C. Maesa, platinic tetrachlorobls-l-phenyl-2, 3-triazol,
[Pt(C8H7N3)2Cl4J ;
G. Pellizzari and C. Massa, platinic tetrachlorobis-o-tolyl-1, 3-triazol,
[Pt(C9H9N3) 8C14] ;
and platinic tetrachlorobis-p-tolyl-1, 3-triazol, [Pt(C9HeN8)8Cl4] ; G. Pellizzari
and
M. Bruzzo, platinic tetrachlorobis-o-tolyl-2, 8-triazol, [Pt(C9H9N3)2C16] ; and
platinic tetra
314 INOKGANIC AND THEORETICAL CHEMISTRY
regia, etc, as before, and after evaporating the dil. soln. in a current of
chlorine, the
residue was dissolved in -water, and an ice-cold soln. of the calculated quantity
of ammonium
chloride was added whilst the soln. was being stirred. The precipitate was washed
by
decantation with water, separated on a suction-filter, and dried in an air-bath at
150�.
acid deposits the salt on cooling. P. Schottlander observed that with sodium
thiosulphate, there is formed a complex between sodium thiosulphate, and platinum
sulphite. R. Fresenius found that the salt is very slightly soluble in aq. ammonia
in the cold, but it readily dissolves in the hot liquid, forming, according to
chloroplatinate.
A. Laurent and C. Oerhardt found that alcohol precipitates from the ammoniacal
soln. a white amorphous mass approximately N4II10PtCl2-�but the composition
is not constant. J. J. Bcrzelius, and W. Knop noted that when ammonium
chloroplatinate
is digested with aq. ammonia, a pale greenish-yellow powder is formed,
containing, probably, some [ Pt(NII3)4 JPtCl4. R. Bottger observed that a cone,
soln. of ammonium chloride precipitates the salt almost completely from its aq.
soln., and JI. St. C Deville and J. S. Stas said that the salt is sparingly soluble
in a cold, sat. soln. of ammonium chloride, and that the yellow soln. slowly
becomes
colourless in contact with the chloroplatinate, or when warmed to 100�.
N. W. Fischer observed that the salt crystallizes out on cooling a soln. in hot
nitric acid. I. I. ShukofE and O. P. Schipulina found that the salt decomposes
when absorbed on charcoal. For the reduction by carbon monoxide, vide supra,
colloidal platinum. The salt is insoluble in ether, and in absolute alcohol.
R. Fresenius studied the solubility in alcohol. J. Dalietos and K. Makris found
alcohol vapour is oxidized by sodium but not by potassium chloroplatinate.
According to R. Fresenius, at 15� to 20�, 1 part of the salt dissolves in 26,535
parts
of 97-5 per cent, alcohol, in 1-476 parts of 76 per cent, alcohol, and 66-5 parts
of
55 per cent, alcohol. If free hydrochloric acid is present, 1 part of the salt
dissolves
in 76 per cent, alcohol. O. Dopping found that the salt is soluble in a soln. of
ammonium succinate ; and C. Claus, very soluble with decomposition in a soln.
of potassium thiocyanate. W. Knop observed that the salt is soluble in a soln.
of sodium hydroxide ; and E. von Meyer added that a large excess of potassium
hydroxide liberates an atom of nitrogen per mol. in the form of ammonia, and with
a smaller proportion of potassium hydroxide less nitrogen is so evolved.
Fulminating
platinum is one of the chief products of the action. N. W. Fischer observed
that the salt is soluble in a soln. of stannous chloride ; and J. B. Rogojsky, that
it
is less soluble in a soln. of hydrochloroplatinic acid than it is in water.
M.Zi. Huggins prepared tetramethylammonium chloroplatinate, (CHg)4NPtCl6,
PLATINUM
and found that the X-radiograms corresponded with a cubic lattice with edge
a=12*65 A., and having each platinum atom surrounded by six chlorine atoms at
the corners of a regular octahedron, and each nitrogen atom surrounded by four
carbon atoms at the corners of a regular tetrahedron. The distance of the Pt-Cl
atoms apart is 2*35 A., if that of the N-C atoms is assumed to be 1-47 A.
for potassium, 1-8O A.; and for chlorine, 1-75 A. Observations were made by
M. Mathieu. The sp. gr. found by G. Tschermak is 3-694 ; H. Schroder, 3-344 ;
C. H. D. Bodeker, 3-586 ; E. H. Archibald, 3-499 at 24�/4� ; and R. Klemcnt,
3-474 at 25�/4�, and for the mol. vol. 140-O. R. Romanis discussed the mol. vol.
I. Traube found that at 20�/4�, soln. with 0-874, 0-919, and 0-930 per cent, of
potassium chloroplatinate had the respective sp. gr. 1-00408, 1-00445, and 1-00457,
and the respective mol. soln. vol., 163-5, 159-9, and 157-6. G. B. Naess and
320 1NOKGANIC AND THEORETICAL, CHEMISTRY
in aq. soln. J. Thomson gave �13-76 CaIs. for the heat of solution. N. S. Kurnakoff
found that the index of refraction of a 13-375 per cent, soln., and of sp. gr., 1-
11225
at. 17-20/4�, is 1-34770 in Li-light, and 1-35021 in Na-light. This gives 80-5 for
the mol. refraction for Na-light, and with the /^-formula ; and the corresponding
at. refraction of j)latinum is 24-7. L. Raiteri gave 1-8103 for A=677 ; 1-8209 for
A=-606 ; 1 -8353 for A=535 ; and 1-8560 for A=458. J. Lifschitz and E. Rosenbohm
studied the optical properties. O. Stelling examined the X-ray spectrum.
R. Samuel and co-workers, A. Hantzsch, and H. I. Schlesinger and M. W. Tapley
studied the absorption spectrum ; and O. Stelling and F. Olsson, and S. Aoyama
and co-workers, the X-ray spectrum. P. Walden gave for the eq. electrical
conductivity,
A, of a soln. of a gram-equivalent in v litres :
V 32 64 128 256 512 1024
A 108-5 114-4 119-1 122-7 125-7 125-4
J. A. Prins and R. Fontayne, S. Nagami, and A. Werner and A. Miolati also made
some observations on this subject ; and E. R. Smith measured the potential of
the chloroplatinate-chloroplatinite electrode. E. Feytis found the magnetic
susceptibility to be �0-393x10-� mass unit. E. Rosenbohm studied the subject.
The salt was analyzed by K. Seubert, J. J. Berzelius, W. Halberstadt, M. Vezes,
and W. Dittmar and J. McArthur. K. Seubert always obtained a little water
PLATINUM 321
when the salt is reduced in hydrogen. W. Dittmar and J. McArthur said that the
trace of water which the salt contains may be present as hydroxide and not as
absorbed water or water of crystallization. J. S. Stas said that the salt can be
prepared " absolutely " free from water if obtained precipitated from very dil.
soln., and, according to K. H. Archibald, the salt dried at 400� is free from
water.
The constitution of the salt was discussed by J. A. N. Friend, and S. H. C Briggs.
According to J. J. Berzelius, and R. Finkencr, the salt is completely reduced to
platinum when it is heated in hydrogen. P. Vallet said that reduction by hydrogen
commences at 160�, and it is complete at 300�. The salt is sparingly soluble in
cold
water, but more soluble in hot water, forming a pale yellow liquid. W. Crookes
found that 1OO parts of water dissolve 0*926 part of salt at 15�, and 5-26 parts at
100�. G. Kirchhoff and R. Bunsen found the solubility, S grms. of salt per K)O
grms.
of water, to be :
217
K?
0 200
400 1000
hydrolysis is initiated by the salt 600 800
Minutes
and J. McArthur observed that 1OO parts of water dissolve 0-628 part of the salt ;
of 5 per cent, hydrochloric acid, 0-662 part; of 5 per cent. soln. of platinic
chloride,
0-233 part ; of a soln. of platinic chloride containing 0-05 grm. free HCl, and
0-05 grm. of platinum per e.c, 0168 part; and of sulphuric acid, containing 40
grms.
SO3 per litre, 0*900 part. JJ. Tschugaeff and S. Krassikoff studied the action of
sulphur dioxide. J. Lt. L�assaigne said that the salt is not attacked by cold,
cone,
sulphuric acid. C. Himly found that potassium chloroplatinate is readily dissolved
by a soln. of sodium thiosulphate that contains a little sodium hydroxide.
A. Minozzi observed that a selenite reduces the soln. to form platinum selenide.
According to W. Peters, potassium chloroplatinate does hot absorb dry ammonia,
hut it combines with methylamine to form potassium
dodeciesmethylaminechloroplatinate,
K2PtCl6.12CH3NH2, and with dimethylamine to form potassium
sexiesdimethylaminechloroplatinate, K2PtCl6.6 (CH3)2NH. A soln. of ammonium
chloride was found by R. H. Brett to dissolve potassium chloroplatinate
; A. Li. Winton and H. J. Wheeler observed that the action is very
small ; and H. Haefcke, and R. Finkener noted that the effect produced depends
on the duratjon of the attack, and the temp. P. Jannasch and C. Stephan observed
NaCl-* 0-6 O 7 0-9
3 0 mo
2 7\
%2 4 80
^2 1\ "5
U j.8
JF Mi
%40
U / I
S 0 9 sNrs
I *"
$0 6 20
0 3 ^c
0 OJr-._!_
K2PtCl8.
H. Precht observed that 1 part of the salt dissolves in 42,600 parts of absolute
ethyl alcohol ; 37,300 parts of 96 per cent, alcohol ; and 26,400 parts of 80 per
cent, alcohol ; and R. Fresenius, that at 15� to 20�, 1 part of the salt dissolves
in
12,083 parts of absolute alcohol ; in 3775 parts of 76 per cent, alcohol ; in 1053
parts of 55 per cent, alcohol ; in 1835 parts of 76 per cent, alcohol containing
hydrogen chloride. Measurements were also made by M. Peligot, and M. Pierrat.
JS. H. Archibald and co-workers found that the solubility, JS grm. of K2PtCl6 in
PLATINUM 323
1OO grms. of soln., at 20�, with ethyl alcohol containing different proportions of
water, Fig. 85, is as follows :
The solubilities in isobutyl alcohol saturated with water, and also with 91-8 per
cent, of water, are, respectively, 0-6250 and 0-3180 grm. of K2PtCl6 per IOO grms.
of soln. R. Finkener said that potassium chloroplatinate is less soluble in a
mixture
of alcohol and ether than it is in alcohol alone, and hence R. Finkener, and
100 parts of water at 15� dissolve 0-135 part of salt, and at 100�, 0-637 part;
and G. Kirchhoff and R. Bunsen measured the solubility of the salt, and
E. II. Archibald and L. T. Hallett's results are indicated below. The minimum
at 14� shows that the salt forms a hydrate. W. Peters observed that the salt does
not absorb dry ammonia. A. Werner and F. Fassbender prepared rubidium
pyridinepentachloroplatinate, Rb[Pt(C5H5N)Cl5]. G. Kirchhoff and R. Bunsen,
and A. Windaus prepared Cfiesium chloroplatinate, Cs2PtCl6, by the methods
employed for the rubidium salt. The pale yellow powder consists of microscopic,
regular octahedra, which are less soluble in water than the rubidium salt.
E. H. Ducloux examined the crystals of the salt ; G. B. Naess and O. Hassel, the
lattice constants. G. Engel gave � = 10-192 A. for the cubic crystals. W. Crookes
observed that 1OO parts of water at 15� dissolve 0*076 part of salt, and at 100�,
0-383 part ; and G. Kirchhoff and R. Bunsen measured the solubility of the
cHisium salt. The solubility�S grms. of salt per 100 grms. of water�of the rubidium
G. Natta and R. Pirani found that the crystals belong to the cubic system and that
the X-radiograms indicate that there are 4 mols. per unit cell, and that a=10-15 A.
;
the volume is 1045-7 X 10~24 c.c. ; and the density is 4*25. They also studied the
solid soln. of rubidium and caesium chloroplatinates, and of caesium
chloroplatinate
and chlorotell urate. G. Engel gave �= 10-185 A., and density, 4-205.
A. Werner and F. Fassbender prepared csesium pyridinepentachloroplatinate,
CsLPt(O5II5N)CJl5I.
C. Scheibler23 prepared lithium chloroplatinate, Li2PtCl6.6H2O, by evaporating
cone. soln. of the salt over sulphuric acid. The hexahydrate forms orange-yellow,
tabular crystals, which lose their water at 180�, and, according to W. Peters, the
salt decomposes. C. Scheibler added that the general behaviour of the salt
resembles
that of the sodium salt ; and it is readily soluble in water, alcohol, and a
mixture
of alcohol and ether, but not in ether. G. F. Smith and A. C. Shead recommended
the use of this salt in place of hydrochloroplatinic acid for precipitating
potassium.
A. Werner and F. Fassbender prepared lithium pyridinepentachloroplatinate,
Li[Pt(C5H5N)Cl5 |.wH20.
Li. N. Vauquelin, and A. von Mussin-Puschkin prepared sodium chloroplatinate,
Na2PtCl6.6H2O, by mixing aq. soln. of platinic and sodium chlorides, and
evaporating
; P. Rohland recommended using theoretical proportions of the two salts.
sp. gr. of a sat. soln. containing 39*77 per cent, of salt at 15�. B. L. Vanzetti
measured the rate of diffusion of the salt in aq. soln., and in gelatin ; and F.
Riidorff
observed that the diffusion experiments indicate that sodium chloroplatinate
behaves like a double salt in aq. soln.
PLATINUM 325
According to Li. N. Vauquelin, the hexahydrate loses all its water of hydration
when carefully heated, and leaves the anhydrous salt as an orange-yellow powder.
H. Precht said that the hexahydrate loses most of its water at about 100�.
J. C. G. de Marignac observed that the water is expelled at 100�, W. Peters at
150�, and J. Thomsen at 150� to 160�. M. A. Rakuzin studied the subject. The
anhydrous chloroplatinate was found by L. N. Vauquelin to swell up when more
strongly heated, but it requires a fairly high temp, for its complete decomposition
into platinum and sodium chloride. L. Wohler and P. BaIz observed no evidence
of the formation of complexes of univalent or tervalent platinum in the thermal
decomposition of the salt ; the chloroplatinate is stable below 600�, and above
800�, only the chloroplatinite is formed. G. Gire noted that the heat of formation
is 40-6 CaIs., and the vap. press., p, in mm. of mercury is :
503� 548� 601� 651� 094� 7520� 758"
and 25-29 CaIs. for the aq. soln. J. Thomsen gave (Pt, 2Cl2, 2NaCl) =73-72 CaIs. ;
(Pt, 2Cl2, 2NaCl, 6H2O) =92-89 CaIs. ; (Pt, 2Cl2, 2NaCl, Aq.) =-84-62 CaIs. ; and
for the reaction between gaseous chlorine and an aq. soln. of sodium
chloroplatinite,
43-03 CaIs. ; V. F. Miller and TI. Terry, 40-88 CaIs. ; J. Thomsen, for the heat of
crystallization, 19*17 CaIs., or an average of 3-195 CaIs. for each mol. of water,
when
the observed values are 4-32 CaIs. each for the first and second mols, 2-54 CaIs.
each for the third and fourth mols, and 2-725 CaIs. each for the fifth and sixth
mols. The heat of solution of the anhydrous salt is 8-54 CaIs., and for the
hexahydrate,
�10'634 CaIs., or for the hydrates :
TT2O 1 2 3 4 5
CaIs. . . +422O -O-1OO � 2-64O � 5-180 � 7-905
F. Doumer found the refractive index to be 0-267 when the value for water
is unity ; and N. S. KurnakofE gave for a 29-123 per cent, soln., and sp. gr. 1
-28259,
the refractive indices 1-38749 for Li-light, and 1-39085 for Na-light ; and the
mol.
refraction for Na-light with the /z-formula is 106-5. This makes the at. refraction
cent, of the hexahydrate. P. Rohland, and H. Precht said that the salt is
insoluble in ether free from alcohol. A. Werner and F. Fassbender prepared
sodium pyridinepentachloroplatinate, Na[Pt(C5H5N)Cl5].
Li. Pigeon observed that finely-divided cobalt reduces the salt and platinum
is formed. A. von Mussin-Puschkin reported that sodium or potassium hydroxide
or carbonate forms with a soln. of sodium chloroplatinate a precipitate which
dissolves in an excess of the alkali. E. H. Archibald and co-workers discussed the
action of potassium Chloride illustrative of the balanced reaction : K2PtCl6 H-
2NaCl
^Na3PtCl6-J-2KCl, exemplified by the effect of sodium chloride on the solubility
of potassium chloroplatinate�xride supra. W. Ostwald found that the theoretical
proportion of silver nitrate precipitates silver chloroplatinate quantitatively.
The (0Ol)-cleavage is perfect; the sp. gr. is 2-868, and the mol. vol. is 216-0.
W. Peters observed that the anhydrous salt takes up dry ammonia to form barium
hexamminochloroplatinate, BaPtCl6.6NH3, which, in vacuo, forms barium
pentamminochloroplatinate, BaPtCl6.5NH3.
J. Thomsen 2? prepared beryllium chloroplatinate, BePtCl6.8H2O, by dissolving
beryllium hydroxide, freed from adsorbed ammonium salts by digestion with
bromine water, in hydrochloroplatinic acid, and evaporating the soln. for
crystallization.
A. Wclkow evaporated a mixture of cone. soln. of beryllium and platinic
chlorides slowly over cone, sulphuric acid. The crystals are dark yellow, being
fouror
six-sided prisms, or six- or eight-sided plates. According to J. C. G. de Marignac,
the crystals belong to the tetragonal system ; and they were examined by K.
Haushofer.
A. WeIkow, and J. Thomsen said that the crystals of the octohydrate are
stable in dry air, but deliquesce in moist air ; they lose 4 mols. of water at 100�
to 120�, and above 150� water and hydrogen chloride are given off. The salt is
freely soluble in water, and alcohol, but insoluble in ether.
H. Topsoe,2� and A. von Mussin-Puschkin prepared magnesium chloroplatinate,
MgPtCl6.12H2O, by evaporating a soln. of the component salts, at a low temp.
H. Topsoe, and H. Topsoe and C. Christiansen observed that the dark reddishyellow
crystals of the dodecahydrate are trigonal with the axial ratio a : c= l : 0-7057,
and a�1060 39' ; the crystals arc birefringent. The sp. gr. is 2-060, and the mol.
vol. 315-3. The crystals are stable in air, but pass into the hexahydrate at 100�.
JJ. Pauling studied the crystals. P. A. von Bonsdorff obtained the hexahydrate
by the spontaneous evaporation of an aq. soln. of the component salts, .and
H. Topsoe added, at a temp, higher than that needed for the dodecahydrate ; it
is also obtained by slowly cooling a sat. soln. down to about 20�. H. Precht found
that the salt cannot be purified by recrystallization. H. Topsoe observed that the
pale yellow crystals arc trigonal, with the axial ratio a : c==l : 0-5169, and
ct-=ll2� 10' ; the sp. gr. is 2-437, and the mol. vol. 222-5. P. Gaubert found the
refractive indices vary with the moisture content ; and for the heptahydrate, for
sodium light, OJ= 1-561, and e=-l-91. P. A. von Bonsdorff said that the crystals
are stable in air, but H: Topsoe found that the crystals rapidly absorb moisture
to form a pale yellow powder. According to P. A. von Bonsdorff, the crystals lose
4 mols. of water when heated. H. Precht found that the hexahydrate dissolves
in absolute alcohol forming a sat. soln. with 43-2 per cent, of MgPtCl6, but with
the salt dried at 150�, the soln. contains only 37-8 per cent. P. Rohland added
that the salt is soluble in 8O per cent, alcohol of sp. gr. 0-8055 at 15� ; and in
methyl alcohol of sp. gr. 0-790 at 17�, but it is insoluble in ether. The alcoholic
P. A. von Bonsdorff obtained the salt by crystallization from a mixed soln. of the
PLATINUM
two component chlorides. L. Hunefeld said that the crystals of the hexahydrate
are pale yellow, and H. Topsoe described them as orange-yellow prisms belonging
to the trigonal system, with the axial ratio a : c, and a �112� IO'. The
(101)cleavage
is perfect. H. Topsoe and C. Christiansen discussed the positive birefringence.
L. Pauling studied the crystals. P. A. von Bonsdorff found the crystals
to be isomorphous with those of the hydrated magnesium and manganese
chloroplatinates.
S. M. Jorgensen gave 2-717 for the sp. gr. R. Romania discussed the
mol. vol. JL. Hunefeld said that when heated, the salt loses water becoming brown
and then grey ; W. Peters added that the salt is anhydrous and brown when
heated to 160�. A. Eberhard said that the crystals lose " 4H2O " at 102� to 103� ;
and the remaining '* 2H2O " is lost slowly above 130� ; P. A. von Bonsdorff, that
at a high temp., chlorine is evolved, zinc chloride is sublimed, and platinum
remains.
Ti. Hunefeld reported that the salt deliquesces in air ; but P. A. von Bonsdorff,
and H. Topsoe said not so. The salt was found by L. Hunefeld to be easily soluble
in water, and alcohol ; and to be easily decomposed with the evolution of chlorine
and hydrogen chloride when it is treated with sulphuric acid. W. Peters observed
that the anhydrous salt takes up dry ammonia to form zinc
eimeamminochloroplatinate,
ZnPtCl6. HNH3, which in vacuo forms zinc heptamminochloroplatinate,
ZnPtCl6.7NH3. P. A. von Bonsdorff, and H. Topsoe prepared cadmium chloroplatinate,
CdPtCl6.6H2O, as in the case of the magnesium salt. The pale yellow
crystals of the hexahydrate were found by H. Topsoe, and H. Topsoe and
the birefringence is positive ; the sp. gr. is 2-882 ; and the mol. vol. 218-7. The
crystals are stable in air at ordinary temp., and become anhydrous at 100�.
W. Peters obtained the trihydrate in the form of pale yellow needles, which become
grey at 170�. W. Peters observed that the anhydrous salt takes up dry ammonia
to form cadmium heptadecamminochloroplatinate, CdPtCl6.17NH3 ; and this in
vacuo forms cadmium duodecamminochloroplatinate, CdPtCl6.12H2O. By boiling
the aq. soln. with formaldehyde, or formic acid, a trace of platinum is deposited.
P. A. von Bonsdorff observed that mercurous chloride dissolves in warm
hydrochloroplatinic acid, and that crystals, possibly mercurous chloroplatinate,
are formed on cooling ; but K. Birnbaum found that mercurous chloride acts on
hydrochloroplatinic acid, forming a soln. which on evaporation deposits a crop of
crystals of mercuric chloride, then a deliquescent amorphous mass containing
mercuric and platinic chlorides which with aq. ammonia, produces a pale yellow
deposit containing mercury, platinum, and ammonia. Li. F. Nilson said that a
mixed soln. of mercuric and platinic chlorides does not furnish mercuric
chloroplatinate.
W. F. Salm-Horstmar,29 and A. Welkow prepared aluminium chloroplatinate,
AlPtCl7.15H2O, by evaporating over sulphuric acid a mixture of hydrochloroplatinic
acid and a soln. of aluminium in hydrochloric acid, and pressing the crystals
between bibulous paper. The lemon-yellow, or orange-yellow four- or six-sided
columns or plates are triclinic with the axial ratios a : b : c�1 : 0-6418 : 0-
5373,
and o,=92� O', �=91� 35', and y=90� 50'. The crystals are stable in dry air, but
deliquesce in moist air. When heated, the crystals become black, and on cooling,
red ; the m.p. and f.p. are 52� ; the salt loses 12 mols. of water at 120�, and the
remainder, with decomposition, at 200�. The salt is freely soluble in water, and
alcohol, but it is not soluble in ether. Platinum is deposited "when a soln. of the
salt
is treated with zinc. IJ. F. Nilson reported indium chloroplatinate, 2InCl3.5PtCl4.
acid and green chromic chloride, extracting the dry mass with water,
evaporating the soln. over sulphuric acid, and drying the crystals between bibulous
paper. G. O. Higley washed the crystals with acetone, and dried them on a porous
tile over sulphuric acid. The dark green, thin rhombic plates effloresce slowly in
dry air ; they lose all but IO mols. of water at 100�. They are freely soluble in
water and in alcohol, but almost insoluble in acetone. G. O. Higley treated a soln.
of the salt with silver nitrate and obtained silver chloroplatinate with a trace of
silver chloride, and he inferred that the salt is a complex with doubled water
molecules, [Cr(H4O2^5Cl]PtCl6. P. T. Cleve prepared chromic chloroaquo
PLATINUM 331
hexacetatodihydroxytrispyridinechloroplatinate,
2rCr3(OH)2(C6H51SI)3(C2H302)63PtCl8.
below 20�, H. Topsoe observed that the dodecahydrate, which appears in pale yellow
trigonal crystals with the axial ratio a : c�1 : 0-7073, and et=106� 36' ; positive
birefringence ; sp. gr. 2*112, and mol. vol. 322-6. The dodecahydrate is stable
in air at low temp., but effloresces at a higher temp. It loses IO mols. of water
at
100�. Ii. Pauling studied the crystals. W. Peters observed that the crystals are
stable at ordinary temp., in air, but they effloresce at a higher temp. They lose
water and become brown at 160�, and take up ammonia to form a basic manganese
salt, MnPt(OH)Cl5.
P. A. von BonsdorfF prepared ferrous chloroplatinate, FePtCl6.6H2O, by the
spontaneous evaporation of a soln. of the component chlorides. L. Pauling studied
the crystals. The dark yellow, or brownish-yellow crystals were found by H. Topsoe
to be trigonal, with the axial ratio a : c�1 : 0-5144, and ct=]12� 14'; sp. gr.
2-714, and mol. vol. 211-3. E. Herlinger gave 210-7 for the mol. vol. The salt is
deliquescent, and it is readily oxidized in air, or in aq. soln. IJ. F. Nilson
prepared
ferric Chloroplatinate, FeCl3-PtCl4.10� H2O, by evaporating to dryness, on a
waterbath,
a mixed soln. of 2 mols. of hydrochloroplatinic acid, and a mol. of ferric
chloride, extracting the mass with water, evaporating the aq. soln. over sulphuric
acid, and drying the crystals between bibulous paper. The yellowish-red,
deliquescent,
four-sided prisms give off 5 mols. of water at 100�. H. St. C. Deville and
J. S. Stas observed that when a soln. of platinic chloride is poured into one of
ferric chloride with a great excess of ammonium chloride, ammonium chloroplatinate
is precipitated, together with a yellow or brownish -yellow precipitate
containing both iron and platinum.
P. A. von BonsdorfT 34 prepared CObaltOUS chloroplatinate, CoPtCl6.6H2O, by
the spontaneous evaporation of soln. of the component salts. The brownishyellow,
or yellowish-brown deliquescent prisms of the hexahydrate were found by
332 INORGANIC AND THEORETICAL CHEMISTRY
H. Topsoe, and H. Topsoe and C. Christiansen to be trigonal with the axial ratio
a : c= l : 0-5140, and <x=^ 112� 14' ; the (1Ol)-cleavage is complete ; and the
birefringence
positive. 8. M. Jorgensen gave 2-699 for the sp. gr. Li. Pauling studied
the crystals. E. Herlinger gave 213-0 for the mol. vol. W. Peters obtained the
anhydrous salt by heating the hexahydrate to 170�. The olive-green powder
takes up dry ammonia to form the cobaltous dodecainnunochloroplatinate,
CoPtCl6.12NH3, at 22�, and at �20�, to form cobaltous octodecamminochloroplatinate,
*" N- Vauquelin noted that when hydrochloroplatinic acid is mixed with insufficient
soda-lye to give it an alkaline reaction, and allowed to evaporate spontaneously,
brownish
soln. of sodium chloroplatinate at 100� so that the soln. remains acidic. In. this
way.
reversing the acidity of the liquid. After dialysis, a product is formed with
variable pro
discussed the nature of this salt. The white or yellowish-white powder can be
obtained as tabular crystals. J. W. Dobereiner observed that at a red-heat,
the salt loses 25 per cent, of water and oxygen to form a residue of calcium oxide
and chloride, and platinous oxide. The salt is insoluble in water ; soluble in
hydrochloric and nitric acids ; silver nitrate precipitates from the acidic soln.
an
orange-yellow piecipitate ; the nitric acid soln. with ammonium chloride was
found by E. Weiss and E. Dobereiner slowly to form a precipitate of ammonium
chloroplatinate, E. Johannsen observed that the salt is slowly decomposed in the
presence of water and carbon dioxide. I. Bellucci, and A. Miolati and I. Bellucci
prepared strontium pentahydroxychloroplatinate, SrPt(OH)5CLH2O, by a process
analogous to that used for the calcium salt. A. Miolati also obtained barium
pentahydroxychloroplatinate, BaPt(OH)5CLnH2O. E. Johannsen also prepared
this salt ; and A. Miolati and I. Bellucci obtained the monohydrate. I. Bellucci,
and A. Miolati and I. Bellucci prepared mercuric pentahydroxychloroplatinate,
HgPt(OH)5Cl, by treating an acetic acid soln. of the barium salt with
mercuric acetate ; and similarly with thallous pentahydroxychloroplatinate,
TlPt(OH)5Cl ; but with lead acetate a basic lead pentahydroxychloroplatinate,
Pb(OH)2.PbPt(OH)5Cl, is formed.
A. Rosenheim and W. Lowenstamm obtained pale yellow dihydroxytetrachloroplatinic
acid, H2Pt(OH)2Cl4^H2O, or oxytetrachloroplatinic acid, H2PtOCl4.4H20,
by allowing a soln. of platinic chloride to stand exposed to the atm. for some
time.
The acid was obtained by S. M. Jorgensen, W. Pullinger, and S. A. Norton by the
action of hot water on silver chloroplatinate. The soln. is evaporated and heated
to 100� when H2PtOCl4 is formed, but a further dehydration cannot be effected
without decomposing the compound. The aq. soln. has an acidic reaction, and
334 INORGANIC AND THEORETICAL CHEMISTRY
in excess, evaporating the filtered liquor in vacuo over sulphuric acid, dissolving
the gum-like mass in absolute alcohol, adding dry ether, and evaporating the
filtered liquor in vacuo over phosphorus pentoxide. S. M. Jorgensen obtained
silver dihydroxytetrachloroplatinate, Ag2Pt(OH)2Cl4, by treating a cold soln. of
platinic chloride with silver nitrate, and drying the washed precipitate at 100�.
The salt was also discussed by F. ReifT, A. Miolati, W. Hittorf and H. Salkowsky,
and I. Jacobsen. The yellowish-brown, amorphous salt is decomposed by boiling
water to form the tetrahydroxydichloroplatinate, and hydrochloric acid converts
it into silver chloride and hydrochloroplatinic acid. A. Miolati prepared zinc
dihydroxytetrachloroplatinate, ZnPt(OH)2Cl4.3H2O, as in the case of the copper
salt. The yellowish-brown product is freely soluble in water and in alcohol. The
corresponding cadmium dihydroxytetrachloroplatinate, CdPt(OH)2Cl4, was also
prepared ; and likewise thallous dihydroxytetrachloroplatinate, Tl2Pt(OH)2Cl4,
as a yellowish-brown powder ; insoluble in water, decomposed when allowed to
stand over sulphuric acid ; and not changed by a prolonged digestion with a soln.
of thallous sulphate on a water-bath. The corresponding lead
dihydroxytetrachloroplatinate,
PbPt(OH)2Cl4, was prepared, and it appears to be associated with
more or less basic salt, Pb(OH)2.PbPt(OH2)Cl4.
1. Jacobsen prepared tetrahydroxydichloroplatinic acid, H2Pt(OH)4Cl2, in
aq. soln. by the action of silver nitrate on a cold soln. of hydrochloroplatinic
acid
in the molar proportions 2:1 , washing the precipitate with ice-water, and treating
the undissolved platinic oxide. A. Miolati and U. Pendini prepared the salt by
mixing equimolar parts of 0* IiV-HCl and hydrochloroplatinic acid in the cold,
evaporating the soln. to dryness, and extracting the dry mass with water.
Ammonium chloroplatinate remains undissolved, and the filtered soln. can be
again evaporated and the treatment repeated two or three times. A black,
hygroscopic
mass of tetrahydroxychloroplatinic acid is thus obtained. M. Blondel
observed that the solid is unstable even at 0�, and rapidly changes to
hydrochloroplatinic
acid, and when the acid soln. is diluted with water hydrated platinic
dioxide, PtO2.4H2O, is precipitated. 1. Jacobsen found that the soln. is darkened
by an excess of aq. ammonia, and after a time, a brown precipitate is formed.
The reaction proceeds more quickly with hot soln. M. Blondel showed that potassium
chloride does not give a precipitate of K2PtCl6 when added to the aq. soln. ;
and other alkali salts furnish a gelatinous precipitate which is soluble in much
water. S. M. Jorgensen reported dioxydichloroplatinic acid, H2PtO2Cl2, to be
formed as a brownish-black, amorphous, deliquescent mass by evaporating a mixed
soln. of equimolar parts of ammonia and of PtCl4.5H20, extracting the dry mass
with water, evaporating the aq. soln. on a water-bath, and drying the product
at 100�.
to a cold, cone. soln. of the corresponding acid. They also obtained mercuric
tetraliydroxydichloroplatinate, HgPt(OH)4Cl2, by adding mercuric acetate to a
soln. of the acid. The yellowish-red precipitate is soluble in hydrochloric acid ;
and impure thallous tetrahydroxydicUoroplatinate, Tl2Pt(OH)4Cl2, was prepared.
The corresponding lead tetrahydroxydichloroplatinate, PbPt(OH)4Cl2, was obtained
as a flocculent, reddish-yellow precipitate.
and more vigorously with slow heating. A. F. de Fourcroy and L.. N. Vauquelin
made analogous observations ; and E. Davy treated platinic sulphate with
ammonia, boiled the precipitate with potash-lye, and dried the washed precipitate.
The brown product is stable in air ; it does not detonate by trituration, shock,
or the electric spark, but it detonates vigorously when heated to 205�. Chlorine
water converts it into ammonium chloride and hydrochloroplatinic acid ;
hydrochloric acid does not attack it perceptibly ; sulphuric acid dissolves it,
forming a dark brown liquid without the evolution of gas ; and nitric acid converts
ammonia. It is a fine yellow body, closely resembling the compound last described
in most of its reactions. It is completely decomposed by treatment with zinc and
sulphuric acid, the platinum being thrown down in a finely-divided metallic state,
whilst the whole of the chlorine goes into solution. Sulphur dioxide passes into
water in which the compound is suspended, gradually dissolves it, forming a nearly
colourless solution, which when neutralized with sodium carbonate and evaporated
yields crystals of the salt, 2PtSO3.6Na2SO3^H2O.
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346 INOKGANIC AND THEORETICAL, CHEMISTRY
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PLATINUM
1895 ; A. Miolati, Zeit. anorrj. Chem., 22.445, 190O ; A. Miolati and I. Bellucci,
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The platinum ammines are here arranged as in the analogous cases of the
chromic and cobaltic ammines. There is a long list in the Platiake of W.
Loewenstein
in L. Gmelin and K. Kraut, Handbuch der anorganischen Ch&mie (Heidelberg,
compound of the type [M(NH3)TOjX�, the negative charge on the electrons will be
greatest at the corners of the usual octet, and -weakest at the centres of the
faces
of the corresponding cube since the positive charge of the central atom will there
be greatest. In other words, the central atom will be surrounded by an electric
field with six positive poles corresponding with the faces of the cube�Fig. 87.
Consequently, when the central atom is approached by a dipole molecule, like water
or ammonia, the negative portion�oxygen or nitrogen as the case may be �is
attached to one of the six mid-points of the faces of the cube�dotted in Fig. 88--
so
that the six molecules will be arranged about the central atom at the corners of
a regular octahedron. As previously indicated, P. Stoll (1926;, and R. W. G.
WyckofE
(1931), have shown that in the crystal lattices of compounds like K2[PtCl6],
Rb2[PdBr6], [Ni(NHa)6]Cl2, [Co(NHg)6]I3, and (NH4)2[SiF6J, the ammonia molecules
or the halogen atoms in the square brackets are arranged at the corners of an
octahedron surrounding the central atom. This shows the origin of the co-ordination
number 6. In this co-ordination, the " neutral " molecules are attached by
the negative portions to the positive surface of the central atom. The electrical
field is concentrated in the " neutral " molecules so that the electronegative X-
atoms
INORGANIC AND THEORETICAL, CHEMISTRY
are forced away from the central atom, and exhibit ionization : [M(NH3)W]XW
=[M(NH3y--|-wX'. The co-ordination number is 4 when the 4 molecules are
arranged about the central atom at the corners of a regular tetrahedron�Fig. 87 ;
and the co-ordination number is 8 when the 8 molecules are arranged about the
central atom at the corner of a cube�Fig. 89. When the six co-ordinated molecules
completely surround the central atom so that there is no space available for
the introduction of more molecules, the co-ordination number 6 cannot be exceeded.
Suppose each face of the cube�Fig. 88�could accommodate two molecules, the
co-ordination number would rise to 12.
The presence of electrical fields about atoms and molecules does not mean that
all are capable of dipole attachment without electronic exchange. The fields may be
too feeble, or vibrational energy of the molecules due to heat may prevent the
formation
of these compounds by dipole valency. The effect of the positive charge in
favouring this kind of union is more marked when it lies near to the atomic
nucleus,
such as occurs when the atoms are small ; and with a given metal, it is greater,
when the metal is exercising its higher valencies.
Molecules like NH3 and H2O act as dipoles, and they are attached to the central
atom covalently by electrostatic attraction, but charged ions may also attach
themselves also by electrostatic attraction. Thus, in ferric chloride, FeCl3, the
octets about the four atoms are completed electrovalently. The octet of iron has
positive charges located at the centres of six faces of the imaginary (dotted)
cube,
Fig. 88, and hero are attached electrostatically three Cl'-ions. The remaining
three positive charges attract the negative ions of three molecules of caesium
chloride. There are therefore six chlorine ions, respectively, at the six apices of
the octahedron, Fig. 88. The neutral molecules, CsCl, are attached to the positive
surface of the central atom by negative ions, and the oppositely-charged ions
remain in the outer sphere so that, on ionization, Cs3| FeCl6]^SCs* -4-[FeCl6]7".
The chlorine ions in such complexes, [MCl6J'", are not liberated as single ions
unless the complex is decomposed, but are held tenaciously by dipole valency
to the apices of the octahedron, Fig. 89. If one of these positions is taken up by
a
molecule of water, ammonia, or some other neutral body, a Cl'-ion is released.
The electrical nature of the combination is not apparent before the displacement
has taken place ; no charge is acquired by the chlorine ion in separating from the
complex, because it was already charged in the complex itself.
platinite, Ko[PtCl4] :
++ r ~1 O
NH , NH , NH , Cl Cl � Cl
�"** Pt . � � Pt � Pt o o
N H 3 � "NH, NH. + .�C I NH , Cl
�
O
Pt �
O
CI �. � Cl
(Pt(NH,)�J�-ion (Pt (NH,), Cl J*-ion (Pt(XH1), Cl1] [PtCl4] "-ion
PLATINUM 349
LNlV -NHjJ
a claw m
Pt .Pt;
% +* '
NH, "NH2-CH2
NH 3_W_
�I++++
NH, NH3
+ + + NH 3+ VNH 3 Cl 0VNH3
NH 3X Pt 2NH, x|NH 3 | Pt xNH3 Cl 8 Pt gCl
_NH 3 V NH,
JO + *0NH3 Cl
�c
C l ��� Cl Cl ��� Cl
(Pt(NH,)6]*�-ioi (Pt(NH3), Cl ]�*�-. [Pt(NHOaCl4] (Pt(NH8) Cl]'-ion
electrons in the valency group of the central atom is the same whether the co-
ordinated
units are molecules or univalent radicles ; and, accordingly, the one kind can
replace
those of the other kind, unit by unit. The special feature of A. .Werner's
hypothesis
still retained is the co-ordination number which represents the number of groups
joined to the central atom by non-ionizable linkages whether these are linkages
of univalent radicles, or whole molecules.
phate ; (4) nitritoplatinite ; (5) nitrate ; (6) picrate ; and (7) nitroprusside.
(xlvi) Dithioglycolesters.
(xlvii) Quaterethylselcnines, [Pt{(C2H5)2Se}4]X2, represented by (1) chloride
and chloroplatinite ; (2) sulphate ; and (3) nitrate,
(xlviii) BisdiethyldiselenotrimethyleTbeglycolSy [Pt(C2H5-Se-C3H6-ScC2H5J2]X2,
represented by (1) picrate ; and (2) nitroprusside.
the potassium salt ; (4) hydrosulphite and the potassium and sodium
salts ; (5) hydronitrite and the sodium salt ; (6) hydrocyanide and
the potassium salt ; (7) hydrothiocyanate.
(liv)
^*Vv-wa^A^^im^a�oZyi-/x-merca^an,LPt(HS.C.N(C1oH7)CH:CH.N:)2
J I
(Iv)
(lvi)
(lvii)
(lviii)
(6) bromoiodide.
(lix)
hydroxy nitrate.
H. and A. Euler, Brr., 37. 2393, 1904 ; F. Forster, ib., 24. 3753, 1891 ; B.
Qerdes, Ueber die
bei Elaktrolyse. de,a cnrbaminsauren vnd kohlensawren Amrnons mit W echselstromen
und Platinelektrodrn
entstehenden Blatinbasen, Leipzig, 1882 ; Jcmrn. prakt. Chem., (2), 26. 269, 1882 ;
K. A. Hadow, Journ. Chcm. Soc., 19. 345, 1866 ; A. W. Hofmann, Ber., 3. 587, 187O ;
J. Jacobsen,
Ootnpt. Rend., 149. 575, 1909 ; S. M. Jorgensen, Journ. prakt. Chem., (2), 33. 526,
1886 ;
P. Klason, Ber., 28. 1483, 1895 ; R. Koefoed, Om nogle
Nitrosoplatinammoniaforbindelser,
Kopenhagen, 1894 ; P. Schutzenberger, Ann. Chitn. Phys., (4), 21. 350, 1870 ;
Compt. Rend.,
70. 1 134, 187O ; 71. 69, 187O ; Bull. Soc.. Chim., (2), 14. 17, 1870 ; P.
Schutzenberger and
C. Fontaine, ib., (2), 18. HO, 1872; A. J. F. da Silva, ib., (3), 15. 835, 1896; T.
Wertheim,
JLiebtg's Ann., 51. 302, 1844.
� 24. Platinous Bromide
the dibromide. The dibromide is thus difficult to prepare because it is stable over
a temp, range of 5�. A. Gutbier observed that platinous bromide is formed when
platinic bromide is heated to 180� ; and W. Halberstadt, and H. Topsoe, when
hydrobromoplatinic acid is heated to 100�, or more rapidly at 200�. W. Halberstadt
observed that the bromide is formed in the electrolysis of a cone. soln. of
platinic
bromide ; and M. Katayama, during the working of the cell : Pb|PbBrsoiid|Br
(and platinum).
W. Pullinger observed that platinous bromide is black if it has not been heated
over 180�, and dark brown if prepared at 250�. W. Halberstadt, and H. Topsoe
said that the bromide forms a greenish-brown powder. R. Klement gave 6*652 for
the sp. gr. at 25�/4�, and 53*4 for the mol. vol. H. Topsoe showed that platinous
bromide does not lose weight at 100�, but if heated at 200� for a long time a small
bibulous paper, four-sided prisms or plates of the hemitrihydrate are formed. The
crystals effloresce in dry air ; they lose water at 100� ; and they dissolve freely
in
water. C. Nogareda, and A. A. Grinberg and B. V. Ptitsin studied the thermal
decomposition, and formation of the bromide from its elements. E. Biilmann and
A. C. Anderson prepared green platinous tetramniinobromoplatinate, [Pt(NH3)4JPtBr4,
bromic acid, and crystallizing from the aq. soln. of the residue. The heat of
formation
is (Pt, Br2, 2NH4Br, Aq.) =31-84 OaIs. J. Thomsen obtained potassium
bromoplatinite,
K2PtBr4.2H2O, by boiling a soln. of a mol. of potassium chloroplatinite
with 4 mols. of sodium bromide in so little water that a large proportion of the
sodium chloride which is formed separates out. By repeated evaporation, filtering,
and cooling, the potassium salt can be freed from most of the sodium chloride, and
the salt can then be re-crystallized from its aq. soln. E. Biilmann and A. C.
Anderson
obtained it by evaporating on a water-bath a mixture of 115*5 grms. of
hydrobromoplatinic
acid with four times its weight of water with 28*3 grms. of potassium
oxalate until the weight is about 218 grms. Allow the liquid to cool overnight,
separate the product by suction, and dry it in air�yield 44 grms. N. Demassieux
and J. Heyrovsky studied the dissociation of the salt in soln.
The prismatic crystals of the dihydrate are almost black, and, according to
bromate (bromide ?), and the filtered soln. evaporated. L. Pigeon employed a
process analogous to that used in the preparation of platinic chloride. V. Meyer
and H. Zublin employed the process indicated in connection with platinous bromide.
W. Halberstadt evaporated to dryness the soln. of hydrobromoplatinic acid,
obtained in V. Meyer and H. Ziiblin's process, in order to drive off the excess of
bromine, extracted the mass with water, evaporated the soln. again to dryness,
and then heated the brownish-red product to 180� to 200� with vigorous stirring
until the vapour of hydrogen bromide was no longer perceptible. The product is
boiled with water, and the soln. evaporated to dryness ; the residue is again
heated
to 180� and the sequence of operations repeated so that finally the filtered soln.
is evaporated. L. von Miiller observed that the nature of the product depends on
the time occupied in drying the mass, and A. Gutbier and co-workers observed
that the product is impure, and L. von Miiller, and A. Gutbier and co-workers
recommended drying the product in bromine at 180�. The product dried at different
temp, contained the following percentage proportions of platinum :
100� 110� 120� 120� to 130�
Platinum . 26-75 27.59 31-13 to 32-96 33-05 to 3412 per cent.
130� to 140� J 40� to 150� 150� to 175� 180�
Platinum . 36-59 to 37-89 37-14 39-19 to 40-31 41-34 per cent.
IJ. Wohler and F. Miiller obtained the anhydrous tetrabromide by heating
hydrobromoplatinic acid in a current of bromine at 300�. C. Nogareda studied the
374 INORGANIC AND THEORETICAL CHEMISTRY
formation of the bromide from platinum and found the stages are Pt�> PtBr->PtBr4.
Platinic bromide was analyzed by V. Meyer and H. Zublin, W. Halberstadt,
A. Gutbier and co-workers, L.. von Miiller, and A. Miolati and I. Bellucci. Dark
brown, amorphous platinic bromide is stable in air. W. Peters observed that when
it is dried in vacuo, it is somewhat moist. W. Halberstadt could not obtain it in
the crystalline state, but C. F. Rammelsberg did do so. R. Klement gave 5*687
for the sp. gr. at 25�/4�, and 90-6 for the mol. vol. W. Pullinger found that after
4 hrs.' heating at 310�, in a current of air, the salt was not completely converted
into
platinous bromide and bromine.
^PtBr2
PtBr4 1 JJBr3
found that the salt is sparingly soluble in water, 1OO parts of soln. at 20�
contain 0-59 part of the salt ; and H. Topsoe, that at 15�, 100 parts of water
dissolve 0-5 part of salt. E. H. Archibald and J. W. Kern observed for the
solubility,
S grms. (NH4)2PtBr6 per IOO grms. of water :
0-2� 7 3� 190� 25 O" 5O d� 00� 8U� 99�
A., and there are 4 mols. per unit cell. H. Topsoe gave 4-51 for the sp. gr. ;
�25-35 CaIs., and for heat of solution, �12*26 CaIs. H. I. Schlesinger and
M. W. Tapley studied the absorption spectrum. A. Miolati gave for the electrical
conductivity, A, of soln. with a gram-equivalent of the salt in v litres :
v .6 4 128 256 512 1024
Timo O 1 2 5 30 30 90 min.
The weight remains constant up to 120�. The remainder of the water is lost with
decomposition at 180�. P. A. von Bonsdorff, and H. Topsoe obtained zinc
bromoplatinate,
ZnPtBr6.12H2O, as in the case of the magnesium salt. The carmine
red, deliquescent crystals were found by H. Topsoe, and H. Topsoe and
H. Christiansen to be trigonal with the axial ratio a : c=l : 0-099O, and <x=^106�
52' ;
the optical character is negative ; the sp. gr. 2-877, and the mol. vol. 333-4.
C. J. Obermaier prepared thallous bromoplatinate, Tl2PtBr6, from a soln.
of thallous bromide and hydrobromoplatinic acid. The salt is yellowish-red, and
it is almost insoluble in water and in aq. hydrobromic acid. H. Topsoe obtained
lead bromoplatinate, PbPtBr6, by evaporating a soln. of lead bromide and
hydrobromoplatinic
acid. The gum-like mass furnishes a yellowish-brown powder of
sp. gr. (i-025, and mol. vol. 146-8. The salt suffers no change at 120�. It is
readily
soluble in water.
S. M. Jorgensen obtained chromic hexamminobromoplatinate, [Cr(NH3)6J2(
PtBr6)3.4H20, as a scarlet precipitate, by mixing soln. of chromic hexamminobromide
stable in air, they effloresce over calcium chloride ; lose 10� mols. of water at
110�
to 120�, and any further loss of water is attended by the decomposition of the
salt.
The optical character is positive ; W. Biltz gave for the sp. gr. 3-715 ; and the
mol. vol., 327-2. The crystals lose their water in a desiccator to form a yellow
powder.
P. T. Cleve prepared platinic hydroxybromotetramminobromide, [Pt(NH3)4(
OH)BrJBr2, in yellow prisms, sparingly soluble in water, by the action of
ammonium bromide on a hot soln. of the nitrate of the series. O. Calgren and
P. T. Cleve prepared platinic dihydroxytetramminobromide, [Pt(NHg)4(OH)2JBr2,
by the action of barium bromide on the corresponding sulphate. The evaporation
of the filtered soln. furnishes colourless prisms, sparingly soluble in water. A
mol
of the salt in v litres of water at 20� was found by A. Werner to have the
conductivity,
ft :
v . .125 2CO 50O IOOO
/* . . 204-7 217-4 226-5 235-5
A. Miolati and I. Bellucci stated that an aq. soln. of platinic bromide contains
dihydroxytetrabromoplatinic acid, H2Pt(OH)2Br4, and he inferred that a dibasic
acid is present in this soln. from the electrometric titration of the soln. with
aq.
ammoniawith a mo
or sodiuml of platinic
hydroxide,
bromide in
and
v litres :
from the electric conductivity, /A, of soln.
vft
.
.
.
.
128
344-4
256
348-9
512
353-6
1024
359-4
of sodium hydroxide in 0-IiVT-NaOH, has the mol. conductivity, /x, for soln. with a
washing the precipitate with cold water, and drying it at 100�. Neither by the
action of barium hydroxide nor carbonate on an aq. soln. of platinic bromide was
it possible to prepare barium dihydroxytetrabromoplatinate, BaPt(OH)2Br4.
A dark red precipitate of mercuric dihydroxytetrabromoplatinate, HgPt(OH)2Br4,
is produced when mercuric acetate is added to an aq. soln. of platinic bromide.
The silver, mercury, and thallous salts were also discussed by F. ReifF. The
brown precipitate of thallous dihydroxytetrabromoplatinate, Tl2Pt(OH)2Br4,
is formed when thallous acetate is added to an aq. soln. of platinic bromide
with lead acetate, dark brown lead dihydroxytetrabromoplatinate, PbPt(OH)2Br4,
is precipitated. S. M. Jorgensen obtained chromic hydroxydecamminobromoplatinate,
[ Cr2(OH) (NH3) 10 J2Br4(PtBr6)34H20, in salmon-red, four-sided crystals,
by the action of hydrobromoplatinic acid on the thiocyanatobromide. JJ. A.
Tschugaeff prepared platinic bromopentamminobromide, [Pt(NHs)5BrJBr3, in
yellow prisms ; and platinic chloropentamminobromide, [Pt(NH3)5Cl]Br3, in pale
yellow, sparingly soluble needles.
formed by crystallization from soln. with different proportions of the chloro- and
bromoplatinates. L. Pitkin said that the products are not mixtures because a
particular compound can be obtained by different modes of preparation, and
solubility determinations give constant values. On the other hand, C. H. Herty
found that the products change in composition with small changes in the ratio of
the two salts in soln., and he accordingly inferred that the products are
isomorphous
mixtures or solid soln. R. Klement also obtained potassium
tetrachlorodibromoplatinate,
K2PtCl4Br2, by the action of bromine on the chloroplatinate ; he gave
3-826 for the sp. gr. at 25�/4� and 150-3 for the mol. vol. Ii. Pitkin reported
potassium pentachlorobromoplatinate, K2PtCl5Br, to be obtained by crystalliza-
I ion from a warm soln. of 5 mols. of the chloroplatinate, and 1 mol. of the
bromoplatinate
; and potassium tetxachlorodibromoplatinate, K2PtCl4Br2, from a
soln. of 4 grms. of potassium bromide in the smallest possible quantity of water,
up to 2 c.c. of cone hydrochloric acid, and 0-5 grm. of platinic chloride. A.
Miolati
said that this product is also obtained by treating potassium chloroplatinite with
bromine. The salt can be recrystallized from warm water ; it furnishes orange-red,
dichroic, cubic crystals. The electrical conductivity, A, of a cold aq. soln.
changes
with time so that for half a mol of K2PtCl4Br2 in 128 litres, the change with time,
in minutes, is :
and the maximum value was attained in 22 hrs., and the results for a half mol of
the salt in v litres are represented by Aj, whilst the values with a soln. of two
246. 246, 1888 ; F. G. Angell, H. O. K. Drew and W. Wardlaw, Journ. Chem. Soc.,
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384 INORGANIC AND THEORETICAL CHEMISTRY
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� 25. Platinous Iodide
warming the mixture twice on a water-bath for a short time, allowing the soln. to
stand over night, washing the product with water, and drying at 90�.
The soft black powder, said J. L. Lassaigne, sticks to the fingers like lampblack
; it is tasteless, odourless, and stable in air. R. Klement gave 6*403 for the
sp. gr. at 25�/4�, and 70*1 for the mol. vol. When heated to the b.p. of mercury,
it gives off iodine, and leaves spongy platinum behind. Water, and cold
hydrochloric
acid have no action on the salt ; cold, aq. hydriodic acid, of sp. gr. 1-038,
acts on it forming platinum and platinic iodide which passes into soln. ; a hot,
aq. soln. of potassium iodide acts similarly, but the greater part of the platinous
iodide remains undecomposed. Cone, sulphuric and nitric acids have no action on
the salt. When digested with aq. ammonia, a dark yellowish-green powder is
formed, which, when heated, gives off water, ammonium iodide, and ammonia.
W. Peters said that the salt absorbs dry ammonia�vid e infra. J. Li. Lassaigne
found that alcohol has no action on platinous iodide, when the salt is digested
with
potash lye or soda lye, part of the platinous oxide which is formed separates as a
black powder, and part passes into soln.
W. Peters obtained orange-red platinous hexamminoiodide, PtI2.6NH8, by
PLATINUM
the action of dry ammonia on platinous iodide ; and this compound, in vacuo,
furnishes platinous tetramminoiodide, [Pt(NHg)4]I2. L. Ramberg prepared the
tetramminoiodide by heating a mol of platinous iodide with dil. aq. ammonia
(IOOO c.c. water and 5OO c.c. ammonia of sp. gr. 0-91) ; and J. Reiset, by the
action
of a soln. of barium iodide on a boiling soln. of the tetramminosulphate, and also
by
the action of ammonia on trans-diiodo-diammine. The dry salt does not change
at 120�. The tabular crystals change their colour when exposed to air. When the
aq. soln. is boiled, it forms the diiododiammine. A. A. Grrinberg and H. V. Ptitsin
studied the thermal decomposition of the salt. The salt forms with mercuric iodide
ethylenediaminoiodide, [Pt en2]I2, in its cis- and trans-forms ; and studied its
passage to [1**2 en4I(II20)12]l-5H20 by the action of acids.
gaeff prepared this salt bv boiling a soln. of platinous iodide with methylamuw ;
ami
F\ G. Mann, platinous bis-/9-methyltrimethylenediaminoiodide, LPt(CH(CH8)
(CH2.NH2)2}a|T2 ;
and platinous bis-a�y-triaminopropanobromide, LPt{NH,.CH,.CH.NHs.CHg.NH,i,JI,.
blstriethylstibine, [Pt{(C8H6)8Sb}8I8].
iodides formed by the partial decomposition of the platinic iodide by the hot
water.
bromoiodobisethylselenine, [ Pt{(C8H6)2S>aBrIJ.
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jprakt. Chem., (2), 105. 31, 1922 ; A. Schleicher and W. Schmidt, Zeit. anorg.
Chem., 142. 367,
1925 ; H. Topsoe, Danske SeUk. Forh., 74, 1869 ; L. A. Tschugaeff, Bull. Soc.
Chim., (4), 25. 234,
1919 ; L. A. Tschugaeff and M. S. Grigorieff, Ber., 47. 2451, 1914 ; Journ. Buss.
Bhys. Chem..
Soc., 51. 193, 192O ; L.. A. Tschugaeff, M. S. Grigorieff and A. Posnjak, Zeit.
anorg. Chem., 148.
37, 1925 ; Lt. A. Tschugaeff, M. S. Skanavi-Grigorieva and A. Posnjak, Ann. Inst.
PUitine, 4. 299,
1926 ; S. Tyden, Di-tiodiglykolatoplatosyra jamte ndgra saltcr och Additions-
Derivat, Lund,
1911 ; G. Wallin, Oefvers. Akad. Forh., 49. 21, 32, 1892; M. Weibull, ZcAt. Kryst.,
14. 116,
1888 ; A. Werner, Zeit. anorg. Chem., 21. 235, 1899 ; L. Wohler and F. Muller, ib.,
149. 377, 1925.
� 26. Platinic Iodide
said that very little iodine is lost at 100� ; and J. L. Lassaigne found that
iodine
vapour is developed at 130�, and platinum finally remains. W. Pullinger found that
the iodine is not completely removed from platinic iodide by molten sodium
carbonate. L. Pigeon gave for the heat of formation with gaseous iodine, (Pt, 2I2)
�39-0 CaIs., and with solid iodine 17-4 CaIs. F. Jez found the thermionic emission
INOKGANIC AND THEORETICAL, CHEMISTRY
about 6(X) litres. The conductivity increases rapidly with time as indicated in
Fig. 92, but constancy is attained in about 25 hrs. at 25�. The increase is
attributed
to a reaction involving the formation of a
~ition
5=>
i -5*
f/
\l
\l
75 platinic acid, and may be chlorine iodide.
Platinic iodide combines with other iodides
� �
2b
o^oT iodides, but not so readily in soln. of other
N-so Iution
not act on the iodide, but when heated, iodine is evolved. R. J. Kane observed
that ammonia converts the salt into the oxyiodide, PtOI2.2NH3.H2O, and H. Topsoe
showed that an ammine is formed when platinic iodide is dissolved in aq. ammonia.
I. .Bellucci found that platinic iodide forms a green soln. with alcohol, and some
of
the iodide is decomposed ; the salt dissolves in 95 per cent, alcohol without
decomposition
at ordinary temp., but in light the salt is slowly decomposed. A. Schleicher
and W. Schmitz prepared platinous bisethylenediaminoiodide, [Pt ^n2]I2, and
found that dil. sulphuric acid converts it into [(H2O)�Pt(en)2�(HoO)5J(H2O)5
�Pt(en)2 �(H20)JI.5H20.
colours the salt orange-yellow, but little or no ammonia is evolved ; and acids
yield a black product. P. T. Cleve obtained platinic diiodohexammino-Yz-
diimidoiodide,
[I(NH3)3Pt(NH)2Pt(NH3)3lJI2.H20, by boiling platinic diiodotetramminoiodide
with aq. ammonia. The chrome-yellow, rhombic plates furnish silver iodide
when treated "with, silver nitrate ; and nitric acid forms
iodonitroxyltetramminonitrate.
S. M. Jorgensen obtained platinic cis-tetraiododiammine, by the action
of potassium iodide on the cis-tetrachlorodiammine. The crystals resemble those
of iodine. P. T. Cleve reported platinic hexaiododiammine, [Pt(NHg)2I4(I2) J, to
be formed by the action of a hot tincture of iodine on the cis-tetraiodotetrammine.
The black powder consists of hexagonal dark purple-red plates. Alkali lye colours
the salt brown, then cinnabar-red, and when heated, ammonia is evolved and the
colour becomes yellow. L. A. Tschugaeff and co-workers prepared platinic hydra
zinocarbylaminoiodide.
glycine, Lrt(NH2.CH2.COO)2I2J.
H. Topsoe showed that the six-sided plates are monoclinic, and show twinning.
The faces of the crystals lose their metallic lustre when exposed to air, and
acquire
a black film of platinic iodide owing to the loss of hydrogen iodide. J. L.
Lassaigne
found that in a dry vacuum, the crystals evolve a little hydrogen iodide, and more
so at 100� ; at a higher temp., hydrogen iodide and iodine are evolved and platinum
remains. The compound is freely soluble in water, and when the wine-red soln. is
diluted with a large proportion of water, platinic iodide is deposited, and more
quickly if the aq. soln. be exposed to sunlight, or, according to H. Topsoe, if
heated.
J. Li. Lassaigne said that chlorine decomposes the aq. soln. with the deposition of
iodine, and platinic iodide ; and alkali lye forms alkali iodides. Hydriodoplatinic
crystals belong to the cubic system, and that the habit is not changed if an excess
of ammonium iodide be present in the mother-liquid. The sp. gr. is 4*61, and the
mol. vol. 216-0. R. L. Datta observed that when the salt is heated, iodine is
evolved, then white clouds of ammonium iodide, and finally platinum remains. The
salt forms a dark-red soln. with water, and the aq. soln. gradually deposits
platinic
iodide. The salt is insoluble in a sat. soln. of ammonium iodide ; and in alcohol.
J. L. Lassaigne prepared potassium iodoplatinate, K2PtI6, by allowing a
soln. of platinic iodide and potassium iodide to crystallize, and washing the
crystals with alcohol of sp. gr. 0-843 to remove admixed potassium iodide.
W. W. Mather, and H. Topsoe used a similar process. R. L. Datta added 10 per
cent, hydrochloroplatinic acid, with agitation, to a sat. soln. of potassium
iodide,
washed the crystals with a little water on a suction-filter, and then with alcohol.
R. J. Kane used a similar process but added some ether to the soln. The black,
rectangular plates were shown by H. Topsoe to belong to the cubic system, and by
recrystallizing in the presence of an excess of potassium iodide he obtained cubes,
and from aq. soln., octahedra. The sp. gr. given by C. H. D. Boedeker is 5*176 ;
by H. Topsoe, 5 031 ; and R. Element gave 4-963 for the sp. gr. at 29�/4�, and
208-5 for the mol. vol. H. I. Schlesinger and M. W. Tapley studied the absorption
spectrum ; and H. I. Schlesinger and R. E. Palmateer, the relative stabilities of
the halogen salts. J. L. Lassaigne observed that a part of the iodine is lost at
100�.
The salt is readily soluble in water forming a deep wine-red soln. Very dil. soln.
were found by J. L. Lassaigne, and W. W. Mather to deposit platinic chloride,
particularly when exposed to light. The salt is not decomposed by cone, sulphuric
acid. M. Vezes showed that with a boiling soln. of potassium nitrite, potassium
nitritoplatinite is formed. J. L. Lassaigne said that the salt is insoluble, or
very
sparingly soluble in absolute alcohol. R. L. Datta prepared rubidium iodoplatinate,
The rhombohedral crystals are not deliquescent, and dissolve freely in water, and
in alcohol. J. L. Lassaigne obtained barium iodoplatinate, BaPtI6.nH20, by
slowly evaporating a soln. of platinic iodide and barium iodide. The deliquescent
crystals resemble those of the sodium salt.
H. Topsoe obtained magnesium iodoplatinate, MgPtI6.9H2O, by evaporating,
over sulphuric acid, a soln. of an excess of magnesium iodide in
hydrochloroplatinic
PLATINUM
acid. The trigonal crystals have the axial ratio a : c= l : 1-87(X), and o.=72�
6' ;
the sp. gr. is 3-458; and the mol. vol. 302-3. H. Topsoe obtained zinc
iodoplatinate,
ZnPtI6.9H2O, from a soln. of platinic and zinc iodides ; and by evaporating, over
sulphuric acid, a soln. of an excess of zinc iodide in hydrochloroplatinic acid.
The
trigonal crystals resemble those of the magnesium and manganese salts ; the axial
ratio is a : c�1 : 1*8685, and a�72� 13' ; the sp. gr. is 3-689 ; and the mol. vol.
321-7. J. L�. Lassaigne also prepared the deliquescent crystals and said that they
have an astringent taste. Vide supra, for platinic tetramminoiodomercurate,
[Pt(NH3)4j(HgI3)2.
excess of hydrochloroplatinic acid. The trigonal crystals have the axial ratio
a : C= 1 : 1-8675, and ct=72� 11' ; the sp. gr. is 3-455 ; and the mol. vol. 340-
8.'
H5. Herlinger gave 340-0 for the mol. vol. of the hexahydrate. The deliquescent
crystals acquire a film of ferric hydroxide on exposure to air. H. Topsoe prepared
cobalt iodoplatinate, CoPtI6.9H2O, by evaporating, over sulphuric acid, a soln.
of an excess of cobalt iodide in hydrochloroplatinic acid. The trigonal crystals
of the enneahydrate have the axial ratio a : c= l : 1-8757, and a,�72� 2' ; the
sp. gr. 3-618 ; and mol. vol. 326-2. On exposure to air, the faces of the crystals
become matte, owing to the loss of iodine. Trigonal crystals of the dodecahydrate
are also obtained. The sp. gr. is 3-048, and the mol. vol. 408-1. E. Herlinger gave
325-5 for the mol. vol. H. Topsoe also prepared nickel iodoplatinate, NiPtI6.6112O,
The crystals are slightly deliquescent, and soon lose their lustre on exposure to
air.
They dissolve in water with decomposition. The enneahydrate is obtained by
spontaneously evaporating at ordinary temp., a soln. with the theoretical
proportions
of hydrochloroplatinic acid and nickel iodide. The trigonal crystals have the
axial ratio a : c= l : 1-8788, and <x=^71� 55'. The crystals are isomorphous with
the
corresponding salts of magnesium, zinc, manganese, iron, and cobalt. The sp. gr.
is 3-549 ; and the mol. vol. 332-5. E. Herlinger gave 331-8 for the mol. vol. The
crystals are deliquescent, and lose iodine on exposure to air. The salt is
decomposed
when it dissolves in water.
I. Bellucci obtained dihydroxytetraiodoplatinic acid, H2Pt(OH)2T4, in soln.
by allowing platinic iodide to remain in contact with 95 per cent, alcohol. The
soln. has an acidic reaction ; decomposes carbonates ; and. gives precipitates of
dihydroxytetraiodoplatinates when treated with soluble salts of the metals. By
adding a small excess of a IO per cent. soln. of silver nitrate to an alcoholic
soln.
of platinic iodide, washing the dark red precipitate with water, and drying it in
vacuo, silver dihydroxytetraiodoplatinate, Ag2Pt(OH)2I4, was formed. With a
cone. soln. of mercuric chloride in the presence of sodium acetate, there was
formed
red mercuric dinydroxytetraiodoplatinate, HgPt(OH)2I4; with a cone. soln. of
thallous acetate, brick-red thallous dinydroxytetraiodoplatinate, Tl2Pt(OH)2I4 ;
and with lead acetate greyish-red lead dinydroxytetraiodoplatinate, PbPt(OH)2I4.
K. Reiff also discussed the silver and thallous salts.
R. J. Kane in his study of the action of ammonia on platinic iodide reported
the formation of platinic dioxytetraiodotetrammine, Pt2(NH3J4O2I4, or
PtOI2.2NH3.H20 ; O. Carlgren and P. T. Cleve obtained platinic
dihydroxytetramminoiodide,
[Pt(NHa)4(OH)2]I2 ; E. Koefoed, platinic nydroxyiodotetrammino
392 INORGANIC AND THEORETICAL CHEMISTRY
REFERENCES.
1 E. H. Archibald and W. A. Patrick, Journ. Amer. Chem. Soc, 34. 369, 1912 ; I.
Bellucci,
Oazz. Chim. Ital., 33. i, 147, 1893 ; AUi Accad. Lincei, (5), 11. i, 8, 1902 ; W.
Biltz, Zeit. anorg.
Chem., 115. 241, 1921 ; C. W. Blomstrand, Journ. prakt. Chem., (2), 38. 357, 1888 ;
C. H. D. Boedeker,
Die Jieziehungen zunachen Dichte und Zusammenaetzung bei /eaten und liquidert
Stoffen,
Leipzig, 1860 ; A. Cahotirs and H. Gal, Compt. Bend., 70. 902, 187O ; O. Carlgren
and P. T. Cleve,
Zeit. anorg, Chem., 1. 68, 1892 ; G. Clementi, Nuovo Cimento, (2), 2. 192, 1855 ;
P. T. Cleve,
Svenska A lead. HandL, 7. 7, 1868 ; 10. 9, 1872 ; R. Iu. Datta, Journ. Chem. Soc.,
103. 427, 1913 ;
Journ. Amer. Chem. Soc., 35. 1187, 1913; R. L. Datta and T. Ghosh, ib� 86. 1019,
1914;
Bindefestigkeit der negativen Reste in den Kobalt-, Chrom-und Plat inammon taken,
Ziirich, 1899 ;
H. Londahl, Lunda Araalcr., (2), 27. 3, 1891 ; W. Manchot and O. Lchmann, Bar., 63.
B, 1221,
193O ; F. G. Mann and W. J. Pope, Proc. Hoy. Soc, 109. A, 444, 1925 ; W. W. Mather,
Amer.
Chem. Soc, 95. 571, 1909 ; "W. Pullinger, ib., 59. 598, 1891 ; F. lieiff, Zeit.
anorg. Chem., 208.
321, 1932 ; C. Rudelius, Lunda Araakr., (2), 22. 4, 1887 ; Journ. prakt. Chem.,
(2), 38. 505,
1888 ; A. Schleicher and W. Schmitz, Zeit. anorg. Chem., 142. 367, 1934 ; H. I.
Schlesinger and
R. 15. Palmateer, Journ. Amer. Chem. Soc, 52. 436, 193O ; H. I. Schlesinger and M.
W. Tapley,
ib., 46. 276, 1924; A. P. Smirnoff, Helvetica Chim. Acta, 3. 177, 1920; M. Topstie,
ltenake
SeUk. Forh., 2. 77, 1869; Arch. Science Geneve, (2), 38. 297, 1870; (2), 45. 223,
1872;
L. A. Tschugaeff, Bull. Soc. Chim., (4), 25. 234, 1919; Zeit. anorg. Chem., 137. 1,
1924;
L. A. Tschugaeff, M. Skanavi-Grigorieva and A. Posnjak, Ann. Inst. Blattnc, 4. 299,
1926 ;
M. Vezes, Ann. Chim. Phya., (6), 29. 207, 1893 ; G. Wallin, Oefvera. Akad. Forh.,
49. 32, 1892 ;
M. Wcibull, Zeit. Kriat., 14. 141, 1888 ; Iu. Wohler and P. Muller, Zf it. anorg.
Chem., 149. 377,
1925.
C Ridolfi 1 utilized the fact that sulphur does not attack platinum but attacks
the base metals to separate platinum from impurities. R. A. Cooper obtained a
mineral whose composition be represented by Pt(As, S)2, in the residue left after
the action of aqua regia on the platiniferous no rites of JBushveld, Transvaal. The
mineral was called COOperite. R. A. Cooper later reported that the arsenic was
present as an impurity in the form of sperrylite, and he changed the formula to
PtS2. H. Schneiderhohn, and LF. R. Adam made observations on the mineral on
the assumption that it is platinum disulphide. F. A. .Bannister showed that the
analyses agree better with the formula PtS. H. R. Adam studied the mineral.
air, boiling the residue with aqua regia, washing the product, and drying it in
vacuo ;
Li. N. Vauquelin, by igniting ammonium chloroplatinate with twice its weight of
sulphur in a closed crucible, and also by heating the same salt with an equal
weight
of sulphur and ignited sodium carbonate and washing away the sodium sulphide
by water�vid e infra, Pt4S5 ; J. J. Berzelius, by decomposing platinous chloride
with an alkali sulphide ; and W. Knop, C. Himley, and Ii. Vohl, by boiling a soln.
of platinic chloride with an excess of sodium thiosulphate until the liquid is deep
red, adding a large proportion of water, then hydrochloric acid, and keeping warm
for a long time nearly at 100� until the evolution of sulphur dioxide has ceased.
The liquid is then colourless, and there is a grey precipitate of platinous
sulphide
mixed with sulphur�the latter is easily removed by washing with a suitable solvent.
R. Juza gave 10-04 for the sp. gr. ; and 22-6 for
the mol. vol. E. Davy's value 6*2 for the sp. gr. is
too low. When platinous sulphide is heated in a
40 60 80 100 closed vessel, it shows signs of fusion. W. Biltz
Concentration Pt and R. Juza measured the isothermal decomposi
correspond -with a unit cell with a = 6-37 A., and c= 6-58 A. JEach coll contains
eight
(Pt,Pd,Ni)S-molecules. The sp. gr. is 8-63, and the value calculated from the
lattice
constants is 8-9.
E. Davy said that the compound is a non-conductor of electricity. R. Bottger
found that at 19�, hydrogen reduces the sulphide to spongy platinum. E. Davy
observed that the sulphide is stable in air, and when heated in air, it forms the
metal. A. Mailfert observed that with ozone there is formed some sulphuric acid.
B. Aulenkamp studied the sensitiveness of the sulphide to light. E. Davy observed
that the sulphide is not attacked by water, and it is scarcely attacked by boiling
mineral acids, or boiling aqua regia. R. Bottger said that in air, platinous
sulphide
acts on alcohol like platinum black, but less vigorously. R. Bottger, and
H. St. C. Deville and H. Debray showed that the sulphide is not attacked by boiling
potash lye ; and J. Ribau, that it is almost insoluble in alkali sulphides. E. Davy
observed that the sulphide is decomposed when heated with zinc filings, or with
potassium chlorate ; and R. Bottger also found that fused potassium nitrate acts
similarly. H. Londahl observed the possible formation of platinous sulphobis-
i-butylsulphine, LI*t{(C4HQ)2S)2S], as a brown, oily precipitate, by the action
of potassium sulphide on a soln. of the corresponding sulphate. F. Mylius and
F. Forster prepared platinous sulphocarbonyl, [Pt(CO)S]2, and a complex with
2H2S ; and V. N. Ivanoff, platinum bisthiocarbamidotetraliydroxysulphide,
Pt4(OH)4S{CS(NH2)}2. A number of platinous halogen-sulphines and thio-salts
have been described in connection with the platinum halides.
R. Schneider observed the formation of potassium sulphoplatinite, K2S.PtS,
or K2PtS2, but was unable to isolate the salt. He prepared potassium stannic
sulphoplatinite, K2S.3PtS.SnS2, by melting 1 part of spongy platinum with 2 parts
of stannic sulphide, 6 to 8 parts of dry potassium carbonate, and 6 to 8 parts of
sulphur, and found that when this salt is heated to dark redness in a current of
hydrogen, it loses sulphur as hydrogen sulphide to form a mixture of platinum,
tin, and potassium sulphoplatinite. When the residue is treated with water in the
PLATINUM 395
the air, the sulphur is entirely burned away. When strongly heated in a stream of
hydrogen it is entirely reduced. It is unacted upon by boiling hydrochloric or
nitric acid, but is slowly attacked by boiling aqua regia. Fused with nitre, it is
easily and completely decomposed. R. Schneider prepared platinous
dihydrohexasulphoplatinate,
Pt3H2(PtS6), by the action of warm hydrochloric acid on
K2S.3PtS.PtS2 ; it readily oxidizes in air to form water and platinum
sesquisulphide
; if the sodium salt 2Na2S.2PtS.PtS2 be similarly treated in the cold,
reddish-brown platinous tetrahydrohexasulphide, Pt2H4(PtS6), is formed.
and sulphur, and washing the product with water. The pale copper-red,
rhombic needles are coloured brown and black by exposure to air, or aerated
water ; they are decomposed by boiling water ; and sodium sulphide reacts :
Na2S-I-PtS+2H2O =H2PtS2+2NaOH. Dil. hydrochloric acid reacts as indicated
396 INORGANIC AND THEORETICAL, CHEMISTRY
in contact with neutral silver, zinc, cadmium, thallous, ferrous, and manganese
salts, exchanges sodium for the corresponding metal, but not so with salts of the
'alkaline earths.
The mineral cooperite wag at first represented by Pt(As, S)2, then by PtS2,
and later by PtS {q.v.). E. Davy prepared platinic sulphide, or platinum
disulphide,
PtS2, by heating to low redness a mixture of 2 parts of sulphur with 3 parts of
ammonium chloroplatinate in a glass tube closed with mercury, and stopping the
heating when the evolution of gas has ceased. R. Bottger said that the product
is contaminated with sulphur because the mixture has not been heated long enough.
W. Biltz and R. Juza, and H. G. Krall also prepared the disulphide from its
components,
and by heating sulphur with platinic chloride. E. A. Geitner heated
hydrochloroplatinic acid decolourized by sulphur dioxide, to 200� in sealed tubes.
J. Persoz heated to whiteness a mixture of platinum with 2 parts of sodium
carbonate
and 3 parts of sulphur, and washed the product with water ; the platinic
sulphide remains in long, aurora-red needles. L. Wohler and co-workers obtained it
by the action of hydrogen sulphide on platinic chloride, and by heating the product
disulphide to stand in a stoppered bottle for a week with occasional shaking. The
PLATINUM
product is then washed with 80 per cent, alcohol to remove the carbon disulphide,
rubbed to a pasty mass, and boiled with a large proportion of water. The product
is then washed with water until free from chlorides ; pressed between bibulous
paper ; and dried in vacuo over sulphuric acid at a temp, below 125�. J. J.
Berzelius
treated a platinic salt with hydrogen sulphide, or an alkali sulphide, washed the
precipitate with boiling water, and dried ix, in vacuo ; U. Antony and A.
Liueehesi,
at 90��if the temp, is below 90�, sulphoplatinates are formed�washed the produet
in an atm. of hydrogen sulphide and dried it at 70� to 80� until the weight was
found that the X-radiogram corresponds with a trigonal lattice having a ==3-537 A.,
c, =5019 A., and a : c= l : 1-419. F. A. Bannister gave a=3-54 A., and c=5-02 A.
The sp. gr., according to K. Davy, is 3-5. R. Schneider found this datum is too
low,
and gave 5*27 for the sp. gr. This is still too low for F. A. Bannister gave 7-80 ;
and W. Biltz and R. Juza gave 7-66, and 33*9 for the mol. vol. E. Davy said that
the sulphide does not fuse when heated. R. Bottger found that the thermal decom
than is the case with the other preparations. L. R. von Fellenberg showed that
at a dull red-heat, chlorine decomposes platinic sulphide producing platinum and
sulphur chloride. R. Bottger observed that boiling cone, sulphuric, hydrochloric
or nitric acid of sp. gr. 1-2 has no action on the sulphide ; and E. Davy, and
R. Schneider added that of all the acids tried, hot aqua regia alone exerts a
slight
action on this compound. J. J. Berzelius' preparation was observed to be rapidly
decomposed by aqua regia, and to be slowly and completely dissolved by fuming
nitric acid. A. Guerout found that sulphurous acid has no perceptible action on
the compound.
According to J. J. Berzelius, when hydrogen sulphide is passed over
precipitated, black platinic sulphide, the compound acquires a reddish-brown
colour by absorption of gas, but on exposure to air, the gas is given off and the
black colour is restored. E. von Meyer also indicated that the pale brown
precipitate
obtained by hydrogen sulphide with hot soln. of potassium chloroplatinate is eine
398 INORGANIC AND THEORETICAL CHEMISTRY
lockere Vcrbindung of platinic and hydrogen sulphides, which loses its hydrogen
sulphide when washed with hot water. K. A. Hofmann and F. Hdchtlen obtained
dark brown platinic dihydrotrisulphide, PtS2-H2S, or PtS(HS)2, or H2PtS3, by
the action of dry hydrogen sulphide on a soln. of platinic chloride in absolute
alcohol, and washing the product with carbon disulphide to remove free sulphur.
R. Bdttger observed that boiling aq. ammonia, and ammonium sulphide have
no perceptible action on the sulphide. J. Ribau observed that the sulphide is
insoluble in ammonium or alkali sulphides or polysulphides ; and P. de Clermont,
that it is insoluble in boiling soln. of ammonium salts. J. J. Berzelius'
preparation
dissolves completely in aq. soln. of alkali sulphides or hydroxides forming
platinum
and alkali thiosulphates. R. Bottger observed that platinic sulphide is decomposed
when it is kneaded with potassium at ordinary temp., and intense combustion
occurs ; sodium does not act until it is warmed. Boiling soln. of potassium
hydroxide, or sodium carbonate do not act on the sulphide. E. Davy said that the
sulphide is decomposed when heated with zinc, or when fused with potassium
chlorate, or hydroxide, and, added R. Bottger, with potassium nitrate. W. Skey
obst�rved that platinum disulphide reduces auric chloride.
C. Wirissinger obtained a colloidal solution of platinic sulphide by dialyzing
the liquid obtained by the action of hydrogen sulphide on a very dil. soln. of a
platinic salt. U. Antony and A. Lucchesi employed a 3 per cent. soln. of
hydrochloroplatinic
acid, or sodium chloroplatinate at 15� to 18�. G. Hofmeier employed
50 c.c. of a 1 : 1,000 aq. soln. of platinic chloride, diluted it to 20O c.c. and
passed the gas for a short time at 50� to 60�, and dialyzed the liquid. J. C. H.
Heyer,
and T. Svedberg added yellow soln. of ammonium sulphide to a soln. of platinic
chloride. G. Hofmeier recommended gum arabic as a protective colloid. The
colloidal soln. is brown or brownish red in transmitted light, and dark grey in
reflected light. The colloidal sulphide is coagulated by heat, by evaporation, by
hydrochloric acid, alkali chlorides, barium sulphate, and animal charcoal.
According to J. J. Berzelius, platinic sulphide precipitated by hydrogen sulphide
dissolves in ammonium sulphide to form a reddish-brown soln. of what was thought
to be ammonium sulphoplatinate, (NH4)2PtS3. The liquid�possibly a colloidal
soln.�deposits platinic sulphide when treated with acids. K. A. Hofmann and E.
Hdchtlen prepared ammonium polysulphoplatinate, (NH4)2PtS3.S12.2H20, by
saturating a 25 per cent. soln. of ammonium sulphide with sulphur at 30�, and
dropping the liquid, with constant stirring, into a cold, 10 per cent. soln. of
platinic
chloride. The reddish-brown precipitate is allowed to stand in a closed vessel for
2
or 3 days at 5�, filtered by suction, washed with carbon disulphide, and dried some
hours in vacuo over sulphuric acid. The red, rhombic pyramids are stable when
dry ; they are insoluble in ether ; and form a yellowish-red soln. with alcohol.
platinum black. The precipitated sulphide, indeed, contains some free platinum.
sulphide. Its sp. gr. is 6-286 ; it has a sour taste ; forms sulphuric acid when
treated
with water ; takes fire in air at 250�, burning with a hissing noise and violet
flame,
with the evolution of sulphurous oxides ; and it becomes warm in a current of
hydrogen above 25� and decrepitates giving off hydrogen sulphide, and leaving a
residue of spongy platinum.
E. von Meyer doubted if the so-called " oxidized sulphide " contains platinic
oxysulphide, PtOS, but it may contain the normal platinum dihydroxysulphide,
Pt(OH)2S, or else (PtS)2O(OH)2. The former is said to be the first stage
in the oxidation of platinic sulphide ; and the platinic oxydihydroxydisulphide,
(PtS)2O(OH)2, or PtOS.\ H2O, is produced when the dark brown precipitate
formed by hydrogen sulphide in hot soln. of potassium chloroplatinate, or
nearly neutral soln. of platinic chloride, and washing free from chlorides, is
dried
on a water-bath, and heated, with frequent stirring, for about K) days at 70� to
100�.
The product is washed with hot water, and the treatment repeated. The product
is finally dried at 100� to 110� in a current of carbon dioxide. If the temp, of
desiccation
is higher than this, oxidation occurs. When the powder is warmed in air,
sulphurous oxides are evolved, and platinum is formed. Hydrogen forms platinous
sulphide and water ; nascent hydrogen slowly forms hydrogen sulphide ; chlorine
in the presence of moisture forms sulphuric and hydrochloric acids ; cone,
hydrochloric
acid reacts slowly without the evolution of chlorine, and after some time
the soln. contains a little sulphuric acid ; hydrogen sulphide forms water and
sulphur ; sulphur dioxide forms sulphur trioxide with the evolution of heat ;
sulphurous acid is slowly oxidized ; ammonia is rapidly absorbed with the evolution
of heat and the formation of water ; nitrous and nitric oxides do not react with
the
oxysulphidc ; carbon monoxide forms platinous sulphide and carbon dioxide ;
oxalic acid slowly decomposes with the evolution of carbon dioxide ; methyl
alcohol is oxidized to formaldehyde ; ethyl alcohol becomes warm and forms aldehyde
H. K. Adam, Trans. Qeol. Soc. South Africa, 33. 103, 1931 ; 34. 35, 152, 1031 ; B.
Aulenkamp,
Zeit. Physik, 18. 7O, 1923 ; F. A. Bannister, Min. Mag., 23. 188, 1932 ; J. J.
BcrzelniH,
Lehrbuch der Chemie, Dresden, 2. i, 180, 1826 ; Schweigger's Journ., 34. 22, 1822 ;
W. BiHx. and
R. Juza, Zeit. anorg. Chem., 190. 161, 1930 ; R. Bottger, Journ. prakt. Chem., (1),
3. 274, 1834 ;
R. A. Cooper, Journ. Met. Min. Soc. South Africa, 28. 281, 1928 ; 29. 230, 1929 ;
E. Davy,
Phil. Mag., (1), 40. 27, 209, 35O, 1812; H. St. C. Deville and H. Debray, Cotnpt.
Rend., 89.
590, 1879 ; J. N. Frers, Zeit. Elektrochem., 40. 612, 1934 ; C. Himley, lAebig's
Ann., 43. 152,
1842; V. N. Ivanoff, Chem. Ztg., 47. 209, 1923; W. Knop, Chem. Centr., (2), 4. 17,
1859;
H. G. Krall, Beitrage zur Kenntnis der Sulfide der JPlatin metalle, Darmstadt, 1933
; H. .Londahl,
Lunds Arsskr., 27. 3, 1891 ; A. Mailfert, Compt. Mend., 94. 1186, 1882 ; F. Mylius
and F. FSrster,
Ber., 24. 2441, 1891 ; L,. Pauling and M. L.. Huggins, Zeit. Kriet., 87. 205,
1934 ; G. Preiiner,
Zeit. anorg. Chem., 55. 82, 1907 ; J. Ribau, Compt. Rend., 85. 283, 1877 ; Bull.
Soc. Chirn.,
(2), 28. 244, 1877 ; C. Ridolfi, Oiorn. Scienza Arti, 1. 24, 125, 1815 ; Quart.
Journ. Science, 1.
259, 1816 ; Ann. JPhU., 7. 29, 1817 ; 13. 70, 1819 ; Phil. Mag., (1), 48. 72,
1816 ; (1), 53. 68,
1819 ; Schtoeigger's Journ., 24. 439, 1818 ; F. Rossler, Synthese einiger
Erzmineralien und
analoger Metallverbindungen durch Aufiosen und Kristallisierenlassen derselben in
gexchmolzenenMetallen, Berlin, 1895 ; Zeit. anorg. Chem., 9. 59, 1895 ; R.
Schneider, Journ. prakt. Chem.,
(2), 2. 164, 1870; (2), 7. 227, 1873 ; (2), 8. 29, 1874; <2), 45. 40, 1892 ; (2),
48. 416, 1893 ;
Pogg. Ann., 136. 105, 1869 ; 138. 607, 661, 1869 ; 148. 625, 1873 ; H.
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Min., 193, 1929 ; H. Schneiderhohn and F. Ramdohr, Lehrbuch der Erzmikroskopie,
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2. 216, 1931 ; W. Skey, Chem. News, 22. 282, 1871 ; L.. Thomassen, Zeit. phys.
Chem., 135.
385, 1928 ; 2. B, 349, 1929 ; 4. B, 277, 1929 ; J. UhI, Ber., 28. 2512, 1890 ; Ts.
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Vohl,
Liebig's Ann., 96. 237, 1865 ; L. Wohler, K. Ewald and H. G. Krall, Ber., 66. B,
1638, 1933.
4OO INOKGANIC AND THEORETICAL, CHEMISTRY
TJ. Antony and A. Luochesi, Gazz. Chim. Ital., 26. i, 213, 1896 ; F. A. Bannister,
Min.
Mag., 28. 188, 1932 ; J. J. BerzeliuH, JLehrbuch der C hemic, Dresden, 2. i, 180,
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and R. Juza, Zeit. anorg. Chem., 190. 161, 1930 ; R. Bottler, Journ. prakt. Chcnt.,
(1), 3. 267,
1834 ; P. do Clermont, Compt. Rend., 88. 972, 1879 ; Bull. Soc. Chim., (2), 31.
483, 1879 ;
P. de Clermont and J. Frommel, Ann. Chim. Phys., (5), 18. 189, 1879; Bull. Soc.
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38. 368, 1879 ; E. Davy, Phil. Mag., (1), 40. 27, 209, 35O, 1812 ; J. W.
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70, 1840 ; E. A. Geitner, Liebig's Ann.,
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2. 164, 1870 ;
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1869 ; 138. 604, 661, 1869 ; 148. 625, 1873 ; P. Sohiitzenborger, Compt. Rend.,
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135. 385,
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49. 455, 1888 ;
Bull. Acad. BeIg., (3), 15. 390, 1888 ; L,. Wohler, K. Ewald and G. H. Krall, Ber.,
66. B, 1638,
1933.
� 28. Platinous Sulphates
tetramminosulphate, and when the liquid is boiled, and the product dissolved in
water, [Pt(NH3)4(OH)(N03)](N03)2, is formed. The tetramminosulphate is insoluble
in alcohol. P. T. Cleve reported platinous triamminosulphate, Pt(NH3)3S04,
to be formed by treating the corresponding chloroplatinite with silver sulphate,
evaporating the filtrate, and drying the snow-white mass of crystals at 100�.
does not lose water at 120�, but at higher temp, water is lost in the
decomposition.
The salt is sparingly soluble in cold water, but more soluble in hot water. The
aq. soln. reacts acidic. Soluble chlorides precipitate from the aq. soln. the
dichlorodiammine
; aqua regia forms platinic Z'ran&'-tetrachlorodiamrnine ; iodine tincture
forms platinic tetraiododiammine ; and aq. ammonia forms platinous
tetramminosulphate.
P. T. Cleve obtained the corresponding platinous cis-sulphatodiammine,
from the corresponding cis-dichlorodiammine.
C. Enebusko described platinous quatermethylaminesulphinosulphate,
[rt{(CH3)4S]S04J;
A. Wurtz, and H. Wolfram, platinous quaterethylaminesulphate, [Pt(C2H6NH 2)4]S04 ;
P. T. Cleve, platinous transbisethylaminediamminosulphate, [Pt(NH3)a(CaH5NH2)a]S04,
as well
as the hexahydrate ; P. T. Cleve, platinous bisanilinediamminosulphate,
[Pt(NH3)2(CeH5NH2)2]
[Pt(C6H6N)4J(HS04)2, alone and associated with pyridine ; there are also the double
sul
{(CaH5)aSe}S04l.
to dryness, the residue taken up with water, and when the soln. is treated with
half its
vol. of cone, sulphuric acid, it furnishes black plates. Since at 100� this
compound
loses 1*5 mols. of water per atom of platinum, it might be represented by the
formula 0{Pt(OH)(HS04)}2.3H20 ; and since it can be converted into an equimolar
mixture of H2PtCl4 and H2PtCl6, it was inferred that the platinum in the compound
is tervalent. The compound crystallizes from aq. soln. in black, rectangular
prisms.
The compound is extremely soluble in water, cone, sulphuric acid, acetic acid,
alcohol, and acetone forming reddish-brown soln. with ether it forms a compound
containing 2 mols. of ether, which is insoluble in ether. Alkali lye precipitates
forms the stable Pt(OH)(HS04)2. This compound does not change at 110�, but
at 150� it begins to lose sulphur trioxide, and is partially reduced. When exposed
to moist air for some days it forms a gum-like mass. The aq. soln. decomposes
slowly in the cold, and more quickly when heated, forming a brown precipitate
with a variable composition. An excess of hydrochloric acid produces a mixture
of platinous and platinic chlorides. The acid is dibasic. Although the addition
of the eq. of 2 mols. of sodium hydroxide forms a crystallizable sodium salt, more
alkali can be added because the salt is gradually polymerized with the liberation
of acid in a colloidal form. When an excess of the alkali lye is added to a boiling
of fuming nitric acid and platinic sulphide furnishes this salt. It was said
that the black porous mass has a sour, metallic taste, somewhat sharp ; that on
ignition at a red heat, it leaves metallic platinum behind ; it deliquesces quickly
in air ; it forms a dark brown soln. with water and with hydrochloric, nitric or
phosphoric acid, and in alcohol, and ether. J. J. Berzelius said that alkali lye
precipitates a basic salt from the aq. soln., and J. von Liebig, that alkali lye
does
not precipitate platinic oxide from the aq. soln. All this, said M. Blondel,
indicates
that platinosic hydroxydihydrosulphate was formed ; he also said that normal
platinic sulphate does not exist ; and E. Prost added that the chemical
individuality
of neither the normal sulphate nor double salts of the type R2SO4.Pt(S04)2, has
been established.
According to L. Stuchlik, the soln. of platinum in sulphuric acid of sp. gr.
1-840, obtained by M. Margules, by means of an alternating current, deposits
yellow crystals which retain sulphuric acid after several recrystallizations from
water. By repeatedly crystallizing the salt from water, in vacuo, large orange
leaflets of the tetrahydrate, Pt(SO4J2.4H2O, are obtained. The salt loses water in
a
desiccator, and becomes darker in colour. The anhydrous salt exhibits a green
metallic lustre. The salt containing sulphuric acid is stable, losing little in
weight
at 100�, and retaining its orange colour. Both salts dissolve readily in water, the
hydrated salt forms a yellow soln., and the anhydrous salt, a dark soln. The
yellow soln. deposits a brown basic salt when warmed, sulphuric acid precipitates
404 INORGANIC AND THEORETICAL, CHEMISTRY
the hydrated sulphate from the dark-coloured soln. The sulphuric acid soln. of
M. Margules gives brown precipitates "when treated with potash or soda lye ; and
with aq. ammonia, a pale yellow precipitate is formed.
B. Gerdes prepared platinic hexamminosulphate, [Pt(NH3)6](S04)2.H20, by
the action of sulphuric acid or of a soluble sulphate on a salt of the hexammine.
The white, crystalline powder is almost insoluble in water. IJ. TschugaefE and
N. VladimirofT, and W. Palmaer prepared platinic ehloropentamminosulphate,
[Pt(NH3)5Cl]2(S04)3 ; and I. I. Tscherniaeff prepared [Pt(NH3)5(H20)](S04)2, and
Pt(NHa)5(OH)(HSO4)SO4. P. T. Cleve prepared platinic dihydroxytetrammino-
SUlphate, [Pt(NHg)4(OH)2]SO4, by boiling the corresponding
hydroxysulphatotetramminosulphate
with an equivalent amount of barium hydroxide ; O. Carlgren
and P. T. Cleve, and A. Werner, by the action of hydrogen dioxide on a warm soln.
of platinous tetramminosulphate, and recrystallizing from hot water ; and
N. Tarugi, by the action of a cone, ammoniacal soln. of ammonium persulphate
on an excess of an aq. soln. of platinic chloride, and warming the mixture to
dissolve
the ammonium chloroplatinate which is first precipitated, and when the liquid is
decolourized" the salt separates out. The prismatic crystals do not lose weight
over cone, sulphuric acid, or at 100�. The salt is sparingly soluble in boiling
water.
A. Werner gave for the conductivity, /x, of a soln. with a mol of the salt in 125,
250, 500, and 1000 litres, respectively, 134-38, 162-36, 181-61, and 196-53, in
agreement
with a 3-ion salt. I. I. Tscherniaeff and S. I. ChorunshenkofE studied the
ionization constants. Hydrochloric acid forms the dichlorotetramminoehloride ;
and barium chloride precipitates all the sulphate. O. Carlgren and P. T. Cleve,
and A. Werner obtained the tetrahydrate, and O. Carlgren and P. T. Cleve, the
monohydrate. P. T. Cleve prepared platinic hydroxysulphatotetramminosulphate,
[Pt(NHa)4(OH)(S04)]2S04.3H20, by boiling an aq. soln. of platinic
dibromotetramminosulphate
with about two molar proportions of silver sulphate until
all the bromide is precipitated ; and A. Werner, by boiling an aq. soln. of
platinous
tetramminosulphate with two molar proportions of bromine added drop by drop.
The soln., filtered hot, furnishes tabular crystals on cooling. The salt is
sparingly
soluble in water. Barium salts precipitate from the soln. only one-third the
sulphate ;
cone, sulphuric acid forms a colourless soln. C. Gerhardt, and C. Weltzien prepared
to cool. R. Uhlenhuth employed a similar process, and said that the crystals are
triclinic prisms. According to H. Alexander, the salt loses about 3-3 per cent, of
water at 80� to 90�, and it decomposes at 100� with a slight detonation. It is
sparingly soluble in cold water, and readily soluble in hot water with a slight
decomposition. The neutral aq. soln. decomposes on a water-bath with the separa
PLATINUM 405
tion of brown flecks, and of platinum. It can be recrystallized from water, or from
the oxalate. The yellow, prismatic crystals are soluble in water at ordinary
temp. ;
the soln. becomes turbid at 30�. P. T. CIeve described platinic
nydroxyacetatotetramminosulphate,
[Pt(NH3)4(OH)(C2H302)]S04.l|H20. W. J. Pope and
which is soluble in water and easily polymerized. Some basic ammines are indicated
above.
Ammonium sulphide gives a dark brown precipitate ; cone, soda lye dissolves the
salt and no ammonia is evolved when the liquid is boiled ; hydrochloric acid forms
dichlorotetramminochloride ; barium chloride, and sodium phosphate give no
precipitates ; silver nitrate forms a precipitate at once ; ammonium oxalate forms
406 INORGANIC AND THEORETICAL, CHEMISTRY
246. 246, 1888 ; J. J. Berzelius, jLehrbuch der Chemie, Dresden, 2. ii, 946, 1826 ;
C. Birnbaum,
Ldebig's Ann., 139. 17O, 1866; C. W. Blomstrand, Oervers. A/cad. Forh., 25. 224,
1869; Bull.
Soc. Chim., (2), 13. 144, 1870 ; Ber., 2. 204, 1869 ; Journ. prakt. Chem., (2), 27.
191, 1883 ;
M. Blondel, Bull. Soc. Chim., (4), 7. 99, 1910 ; Ann. 'Chim. Phys., (8), 6. 125,
1905 ; Recherche*
sur quelques combinaisons du plattne, Paris, 1905 ; R. Bunsen, Liebig's Ann., 37.
1, 1841 ; 42.
14, 1842 ; Taylor's Scient. Mem., 3. 281, 1843 ; O. Carlgren and P. T. Cleve,
Oefvers. Akad.
Forh., 47. 305, 1890 ; ZeAt. anorg. Chem., 1. 74, 1892 ; P. T. Cleve, Svenska Akad.
Handl., 7. 8,
1868 ; 10. 9, 1872 ; Acta Upaala, 6. 5, 1866 ; E. Davy, Phil. Trans., 110. 108,
1820 ; Phil.
Mag., (1), 2O. 35O, 1812; (1), 56. 330. 1820; Ann. Phil.. 15. 297. J820 ; 16. 385,
1820;
PLATINUM 407
�1. L>elepine, Compt. Rend., 150. 107, 191O ; Bull. Soc. Chim., (4), 7. 103, 191O ;
H. IX K. Drew
and H. J. Tress, Journ. Chem. Soc., 1244, 1935 ; C. Enebuske, Isunds Araakr., (2),
22. 2, 1887 ;
H. and A. Euler, Ber., 37. 2391 1904 ; N. W. Fischer, KaatnerJa~Arch., 14. 149,
1828 ; Quart.
Journ. Science, 5. 193, 1829 ; B. Gerdes, ZTeber die. bei Elektrolyae, dea
carbaminaaurea und kohlensauren
Amnions mit Wechselstromen und Platinelektroden enatehenden Platinbaaen, Leipzig,
1882 ;
Journ. prakt. Chem., (2), 26. 257, 1882 ; C. Gerhardt, Compt. Rend. Trav. Chim.,
273, 1850 ;
C. Grimm, JLiebig a Ann., 99. 85, 1856 ; A. A. Grin berg and B. V. Ptitsin, Ann.
lnat. Platine,
9. 73, 1932 ; J. Gros, Liebig a Ann., 27- 245, 1838 ; S. G. Hedin, Om pyridinena
platinabaser,
L<und, 1886 ; Lunda Araskr., (2), 22. 3, 1887 ; F. Hoffmann, HydroxyhzmirihaUige
Platinbaaen,
Konigsbertf, 1889; K. A. Jensen, Zeit. anorg. Chem., 221. 6, 1934; 225. 97, 115,
1935;
A. R. KIien, Ueber die, Bindefeatigkeit der negativen Reate in den /Cobalt-, Chrom-
und Platinammoniaken,
Zurich, 1899 ; N. S. Kurnakoff, Journ. prakt. Chem., (2), 50. 489, 1894 ; (2), 51.
253, 1895 ; Journ. Muss. Phya. Chem. Soc., 25. 565, 1893 ; J. Lang, Om nagra nya
platinaoxydulforeningar,
Upsala, 1861 ; Journ. prakt. Chem., (1), 83. 417, 1861 ; Srenaka Akad. IIandl., 5.
5, 1865 ; J. von Liebig, Liiebig^s Ann., 28. 37, 1837 ; A. Litton and G. H. E.
Schnedermann,
ib., 42. 316, 1842 ; H. Londahl, Isunds Araskr., (2), 27. 3, 1891 ; M. Margules,
Wied. Ann.,
65. 633, 1898; 66. 540, 1898; A. von Mussin-Puschkin, Journ. Mines, 15. 195, J
934 ;
A. E. Nordenskjold, Bihang. Svenska Akad. Handl., 2. 2, 1874 ; W. Palmaer, Ber.,
22. 15, 1889 ;
J". Petren, Om Platinasthylseleninforeningar, Lund, 1898; M. !Tyrone, Ann. Chim.
Phya., (S),
12. 193, 1844 ; (3), 16. 462, 1846 ; W. J. Pope and S. J. Peachey, Journ. Chem.
Soc., 95. 571,
1909; E. Prost, Bull. Soc. Chim., (2), 46. 168, 1886; Bull. Acad. BeIg., (3), 11.
414, 1886;
L. Kamberg, Zett. anorg. Chem., 83. 36, 1913 ; Ber., 46. 1696, 2353, 1913 ; A.
Kccoura, Compt.
Bend., 120. 1335, 1895; 137. 189, 1903; J. Reiset, Ann. Chim.. Phys., (S), 11. 422,
1844;
E. RoBenbohm, Zeit. phys. Chem., 93. 693, 1919 ; A. Rosenheim and W. Handler, Ber.,
59. B,
1387, 1926 ; C. Rudelius, Lunda Araakr., (2), 22. 19, 1887 ; R. Ruer, Zeit. phys.
Chem., 44. 95,
1903 ; W. J. Sell and T. H. Easterfield, Chem. News, 68. 223, 1893 ; B. A. Rep.,
731, 1893 ;
Q. Sella, Mem. Accad. Torino, 17. 347, 1858 ; A. P. Smirnoff, Helvetica Chim..
Acta, 3. 177,
1920; L. Siuchlik, Ber., 37. 2913, 1904; N. Tarugi, Gazz. Chim. Hal., 36. i, 364,
1906 ;
H. Topsoe, Sitzber. Akad. Wien. 66. 5, 1872 ; I. I. Tscherniaeff, Ann. Inst.
Platine, 11. 55, 1933 ;
1. 1. THcherniaeff and S. I. Chorunshenkoff, ib., 8. 83, 1931 ; 1. I. Tscherniaeff
and A. N. Fedorova,
ib., 8. 73, 1931 ; L. A. Tschugaeff and M. S. Grigorieff, Ber., 47. 2451, 1914;
Journ. Russ.
Phys. Chem. Soc., 51. 193, 1920 ; L. A. Tschugaeff and I. 1. THcherniaeff, Ann.
Inst. Platine, 7.
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A. Tschugaeff
and N. Vladimiroff, ib., 160. 840, 1915 ; R. TJhlcnhuth, Licbig's Ann., 311. 121,
1900 ; 312. 235,
1900 ; L. N. Vauquelin, Ann. Chim. Phys., (2), 5. 26O, 1817 ; C. Weltzicn, IAehtg'*
Ann., 97.
27, 1856; A. Werner, Zett. anorg. Chem., 21. 236, 1899; Ber., 40. 4095, 1907; L.
Wohler
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Platinbasen,
Konigsberg, 1900 ; A. Wurtz, Ann. Chim. Phys., (3), 30. 487, 1850.
� 29. The Platinum Carbonates
No platinum carbonates have been prepared, but some complex carbonates are
known. J. Reiset1 obtained platinous tetramminocarbonate LPt(NII^)4 ]COa.H20,
by the action of atm. carbon dioxide on a aoln. of the corresponding hydroxide ;
and M. Peyrone, by the action of potassium carbonate on the corresponding chloride
at 40� to 50�. Hy saturating a soln. of the hydroxide with carbon dioxide, J.
Reiset
obtained platinous tetramminohydrocarbonate, [Pt(NH3)4](HC04)2, as a white,
crystalline powder which is not decomposed at 120�. When this salt is boiled with
water there is formed platinous tetramminocarbonatohydrocarbonate, [Pt(NH3)4|CO3.[
Pt(NH3)4]( HCO3)2, as a white crystalline powder which begins to
decompose at 200�. B. Gerdes obtained platinic dihydroxyheptamminotetracarbonate,
Pt2(NH3)7(OH)2(HC03)4, by electrolyzing, with an alternating current, for
some hours, soln. of ammonium carbonate with platinum electrodes, at 40� to 50�,
and cooling. S. G. Hedin described platinous
quaterpyridinetetramniinocarbonatohydrocarbonate,
[Pt(C5H5N)4C03.Pt(NHs)4](HC03)2.16H20, by treating the
sulphate with barium hydroxide, and passing carbon dioxide into the? filtered soln.
solving it in dil. soda lye, diluting the soln. with water and then saturating it
with
carbon dioxide ; and by treating a soln. of the corresponding chloride with sodium
carbonate. The white powder, consisting of octahedral crystals, is insoluble in
water. L. A. Tschugaeff, and L. A. Tschugaeff and N. VladimirofE prepared platinic
chloropentamminocarbonate, [Pt(NH3)5C112(C03)3. M. Raewsky prepared platinic
hydroxychlorotetramminocarbonate, [Pt(NHa)4(OH)ClJCO3-HgO, by treating the
corresponding nitrate with ammonium carbonate, and allowing the mixture to
stand for 24 hrs. The caseous precipitate becomes crystalline if the soln. is
boiled.
but when heated, with the two latter, there is formed a pale reddish-yellow liquid.
A soln. of sodium nitroprusside gives no colouration when dil. soda lye is added ;
and when boiled with methyl iodide, no mercaptan or methylsulphine is formed.
Red needles of platinous dichlorotetramminothiocarbonate, [Pt(NH3)2C12].
[Pt(NHg)2CS2J, were also prepared. A mixture of ammonium chloroplatinite, aq.
ammonia, and carbon disulphide also furnishes black crystals of platinous
amminothiocarbonate,
[Pt(NH3)C2S5J2, which is soluble in soda lye.
REKEKENCES.
B. Gerdes, Ueber die bei JQlektrolyse des carbaminsauren ttnd koMensauren Arnnums
mit Wechselstromen
und, Platinelektroden entstehenden Platinbasen, Leipzig, 1882 ; Joiirn. prakt.
Chem.,
(2), 26. 269, 1882 ; S. G. Hedin, Om pyridinens PIatinabaser, Lund, 39, 1886 ; K.
A. Hofmann,
Ze.it. anorg. Chem., 14. 278, 1897 ; M. Peyrone, Ann. Chim. Phytt., (3), 12. 193,
1844 ; (3), 16.
462, 1846; JLiebig's Ann., 51. 1, 1844; M. Raewsky, Compt. Rend., 23. 253, J 846;
24. U54,
1847 ; Ann. Chim. Phys., (3), 22. 278, 1848 ; J. Reiset, ib., (3), 11. 425, 1844 ;
D. Sohou, Zeit.
anorg. Chem., 13. 36, 1897 ; L. A. Tschugaeff, ib., 137. 1, 1924 ; L. A. Tschugaeff
and W. Chlopin,
Com.pt. Bend., 161. 699, 1915 ; Zeit. anorg. Chem., 151. 253, 1926 ; L. A.
Tschugaeff and
N. Vladimiroff, Compt. Mend., 160. 840, 1915.
� 30. The Platinum Nitrates
dihydroxyhexammino-vu-diamidonitrate, [(OH)(NH3)3Pt(NH2)2Pt(NH3)3(OH)](
N03)4.2H2O obtained by the action of silver nitrate on a boiling soln. of
\I(NH3)3Pt(
NH2)2Pt)NH3)3I](N03)4 ; or by crystallization from [(N03)(NH3)3Pt(NH2)2Pt(
NH3J3(NO3) 1(NOg)4.4H2O. The white, crystalline dihydrate becomes anhydrous
at 100� ; and it detonates like gunpowder if heated to a higher temp. It is
sparingly soluble in cold water but soluble in hot water. Hydrochloric acid
converts
it into the dihydroxychloride ; and sulphuric acid, into the dihydroxysulphate,
potassium iodide and bromide, and ammonium oxalate give precipitates. If the
salt be boiled with nitric acid, there is formed platinosic
nitratohexamminO-/xdiamidonitrate,
[(N03)(NH3)3Pt(NH2)2Pt(NH3)3(N03)](N03)4.4H20. Water reproduces
the original salt. The tetrahydrate becomes anhydrous at 100�. Bromine
converts it into platinosic dibromohexammino-;Li-djamidonitrate, [Br(NH3)3Pt(
NH2)2Pt(NH3)3Br](N03)4.2H20 ; and with iodine, platinosic diiodohexammino^-
diamidonitrate, [ I(NH3)3Pt(NH2)2Pt(NH3)3IJ(N03)4.3(or 4)H20. The pale orange
crystals become anhydrous at 100�, and detonate at a higher temp. If the dibromsalt
soln. of platinic nitrate and obtained on the platinum anode an ochre-yellow film,
soluble in hydrochloric and sulphurous acids, but insoluble in dil. nitric and
sulphuric
acids. It has an acidic reaction towards litmus. The deposit is a basic platinic
nitrate. E. Koefoed reported platinic iiitrosyltetrarnrninohydronitrate, Pt(NHg)4(
NO)(NO3)4:HNO3.
plates, is sparingly soluble in cold water, and soluble in hot water. The aq. soln.
and "when the mixture is boiled for half an hour, about half the chloride is
precipitated
as silver chloride, and hydroxychlorotetramminonitrate is formed, more
chloride is precipitated if the soln. be boiled for some days ; and P. T. Cleve,
that potassium chromate and dichromate precipitate yellow chlorochromates,
and hydrochloroplatinic acid forms dicmorotetramminochloroplatinate.
Li. A. TschugaefE prepared platinic ammocMorotetramminonitrate, [Pt(NH3)4(
NH2)Cl](NOa)2.
the liquid is cooled is dissolved in boiling water, and the soln. is evaporated
over
sulphuric acid in vacuo. The re-crystallization is repeated 4 times and finally
the product is dried at 120�. C. Gerhardt obtained it by boiling silver nitrate
with platinic dichlorotetramminochloride, E. A. Hadow used the
dichlorotetramminonitrate.
C. W. Blomstrand, W. O. Odling, M. Raewsky, C. Gerhardt, and
E. A. Hadow discussed the constitution of what is called Raewsky's nitrate. The
white powder consists of six-sided plates. When heated, water, etc., are evolved
with a feeble detonation. The salt is soluble in cold water, and more easily so in
hot water. Hydrochloric acid precipitates the dichlorotetramminochloride ;
ammonium chloride forms the chloride ; sulphuric acid or alkali sulphates give no
precipitate except that sodium sulphate gives a precipitate after some time ;
nitric
acid, the chloronitratotetramminonitrate ; sodium phosphate gives a crystalline
precipitate ; potassium hydroxide forms a yellow liquid and develops ammonia ;
alkali carbonates, and ammonium carbonate give a white precipitate of the carbonate
; acetic, tartaric, and succinic acids give no precipitate ; silver nitrate gives
no precipitate with cold soln. nor with cold soln. that have been boiled for half
an
hour but with IO hrs. boiling, about two-thirds of the chlorine is precipitated as
silver chloride ; potassium chloroplatinite gives a green crystalline precipitate ;
water, but freely soluble in hot water ; it dissolves in aq. ammonia ; ammonium
bromide precipitates the red bromide; ammonium chloride precipitates the chloride ;
silver nitrate precipitates silver bromide in cold soln., and with boiling soln.,
the
hydroxybromotetramminonitrate is formed ; potash lye forms an orange-red soln.
but no ammonia is given off, but that gas is evolved with the heated lye ; alkali
carbonates give a mixed precipitate ; sodium phosphate precipitates
phosphatotetramminobromide
; and potassium ferrocyanide gives a red precipitate.
C. Fontaine, Compt. Rend., 70. 1414, 1870 ; Q. Sella, Mem. Accad. Torino, (2), 17.
353, 1858 ;
A. P. Smirnoff, Helvetica Chim. Acta, 3. 177, 1920 ; I. 1. Tseherniaeff, Ann. Inst.
Platine, 11.
65, 1933 ; I. I. Tseherniaeff and S. I. Chorunshenkoff, ib., 8. 83, 1931 ; T. 1.
Tseherniaeff and
A. N. Fedorova, ib., 8. 73, 1931 ; L. A. Tschugaeff, ib., 4. 37, 1926; Zeit. anorg.
Chem., 137.
140, 1924 ; L. A. Tschugaeff and W. Chlopin, Compt. Rend., 161. 699, 1915 ; L. A.
Tschugaeff,
M. S. Skanavi-Grigoreva and Posnjak, Ann. Inst. Platine, 4. 299, 1926 ; L. A.
Tschugaeff and
W. Sokoloff, Ber., 40. 3463, 1907 ; 42. 58, 1909 ; L. A. Tschugaeff and N.
Vladimiroff, Compt.
Rend., 160. 840, 1915 ; R. Uhlenhuth, Liebig's Ann., 811.121, 1900 ; 312. 235, 1900
; M. Weibull,
Zeit. Kryst., 14. 139, 1889 ; C. Weltzien, Liebig's Ann., 97. 19, 1856 ; 100. 108,
1856 ; A. Werner,
Zeit. anorg. Chem., 8. 158, 1895 ; Ber., 40. 4097, 1907 ; A. Werner and A. Miolati,
Zeit. phys.
Chem., 14. 507, 1894; L. Wohler, Die pseudokatalytische Sauerstojfaktivierung des
Platrns,
Karlsruhe, 1901; H. Wolffram, Ueber aethylaminhaltige Platinbasen, Konigsberg,
1900;
A. Wurtz, Ann. Chim. Phys., (3), 30. 462, 1850.
416 INORGANIC AND THEORETICAL CHEMISTRY
VOL. XVI.
GENERAL INDEX
(Compiled
Aarite, 9. 80 ; 15. 5
Abichite, 9. 161
Abloclastite, 15. 9
" Abnormal " in chemistry, 1. 192
Abnormal steol, 12. 675
Abraumsalze, 2. 428
Abrazite, 6. 711
Abriachanite, 6. 913
Abschrecken, 12. 675
Absolute boiling j>oint, 1. 165
-�-�- temperature, 1. 160
zero, 1. 160
Absorption coefficient, 1 527
X-rays, 4. 33
mass, 4. 34
index, 3. 47
spectra, 4.19
Abu-r-Iiaihan, 1. 42
Academic des Sciences, 1. 5
Academy of Nature's secrets, 1. 2
Acadialite, 6. 729
Acadiolito, 6. 729
Acanthite, 14. 193
Acantoide, 6. 584
Aecadomia del Cimento, 1. 4
dei Segreti, 1. 2
Acceleration, period of, 2. 15O
Acceptor, 7. 565
Aeciaio, 12. 709
lead, 7. 542
Aeerado, 4. 697
Acerdese, 12. 238
Acero cementado, 12. 753
Acetamide and hydrogen, 1. 304
Acetatosodalite, 6. 583
Acetic acid, 13. 613, 615
black, 5. 752
carbides, 5. 847
Acetylides, 5. 845
Acetyl phosphorous acid, 8. 1005
Miss E. M. Rigby)
history, 1. 382
primitive, 1. 384
primordial, 1. 384
salts, 1. 387
sulfureux, 10. 187
Acide a la craie, 6. 2
carbonique, 6. 2
Acidirnotry, 1. 391
Acidity, principle of, 1. 384
Acids, 1. 385
� strength measurement, 1
1004
salts, reactions, 1. J002
basicity, 1. 1002
binary, 1. 387
theory, 1. 404
constitution theories, 1. 402
Graham's theory, 1. 402
hydro-, 1. 386
^ weak, 1. 981
419
GENERAL INDEX
A, 4. 142
-B, 4. 143
C, 4. 143
C8, 4. 144
D, 4. 144
X, 4. 139
emanation, 7. 889
Actinolite, 6. 391, 405, 426 ; 12. 529
Aetinon, 7. 889
Actinoto, 6. 405
Active charcoal, 5. 747
oxygon, 1. 925
valency, 1. 207
Activity of colloids, 1. 777
_._ _ molecules, 16. 153
optical, 1. 608
Adamantine spar, 5. 247
Adamas, 5. 7IO
Adamite, 4. 408, 660 ; 5. 271 ; 9. 4, 181
Adamsite, 6. 606
Adelforsite, 6. 738
Adolite, 9. 18O
Adelpholito, 5. 517; 7. 100; 9. 839; 12.
529
Adhesion, 1. 821
Adiabatic compression gases, 1. 863
� elasticity, 1. 82O
olectrical, 5. 8Ol
Qibbs equation, 1. 854
isotherm, 5. 793
equation, 5. 793
positive, 1. 854
Aduceradtjern, 12. 709
Adularia, 6. 662
habit, 6- 67O
Adularie, 6. 662
Aerolites, 12. 523
Aegirine, 6. 914
� augites, 6. 915
Aegirite, 6. 914 ; 7. 1OO ; 12. 529
Aenigmatite, 6. 391, 845, 846; 7. 3; 12.
529
solids, 1. 82O
Aerial acid, 6. 1
Aerinite, 6. 622
Aero, 1. 122
Aerosite, 9. 294
Aerugite, 9. 231
candidum, 7. 279
cuprium, 8. 2
eyprium, 3. 2
905 ; 12. 5
JEthor, 1. 33
Aethiops apyros, 4. 943
empyros, 4. 943
harrisii, 4. 943
martialis, 18. 736, 762
kind, 1. 205
pressure, 1. 235
reciprocal, 1. 298
residual, 8, 234
Afrodito, 6. 428
AftorschOrl, 6. 911
Afwillite, 6. 359
Agalmatolite, 6. 498, 619
Agate, 6. 139
moss, 6. 139
tree, 6. 139
Ageing steel, 12. 680
Aglaite, 6. 643
Agnesite, 9. 704
Agnolito, 6. 9OO ; 12. 148
Agricola, C , 1. 51
Agricolite, 6. 836 ; 9. 589
Aguilarite, 3. 300 ; 10. 694
Aguilerite, 10. 919
Aich-metal, 13. 545
Aikainite, 9. 589
Aikenite, 3. 7
Aikinite, 7. 491 ; 9. 693 ; 15. 9
Aimatolite, 9. 22O
Ainalite, 7. 394
Ainolite, 9. 839
Air, 1. 61, 122, 123 ; 13. 607
adsorption by solids, 8, 37
and CO8, 6. 32
composition, 8. 1
(element), 1. 32
factitious, 6. 1
fire, 1. 344
fixed, 6. 1
hardening steels, 18. 634
inflammable, 1. 125
marine acid, 2. 2O
mephitic, 8. 45, 46
mixture or compound, 8. 14
phlogisticated, 1. 125 ; 8. 45
preservation liquid, 1. 873
pressure of, 1. 149
properties (physical), 8. 22
INDEX 421
Air respirable, 1. 69
solubility of, 1. 534 ; 8. 37
vital, 1. 69
vitiated, 1. 344
weight of, 1. 143
Airol, 9. 63O
Aithalite, 12. 266
Akanthikonite, 6. 721
Akermanite, 6. 403
Akontite, 9. 309
Akrit, 14. 542
Alabandin, 12. 387
Alabandina sulfurea, 12. 387
Alabandite, 12. 148, 387
Alabaster, S. 76O
Alabastroix, 9. 339
Alaite, 9. 715, 753
Alalite, 6. 409
Alamosite, 7. 491
Alaskaite, 7. 491 ; 9. 589, 693
Alaunerdo naturliehe, 6. 497
Alavandina, 6. 9IO
Albata metal, 15. 23O
Albertus Magnus, 1. 46
Albin, 6. 368
Albite, 6. 662, 663 ; 7. 896
microclirxe, 6. 664
twinning, 6. 67O
Albitic acid, 6. 295
Album sublimatum, 4. 797
Alcaparrosa verde, 14. 245
Alchemy, 1. 49 ; 4. 147
in China, 1. 23
Alcogel, 1. 771
Alcohol, 9. 339
Alcohols, 1. 389
Alcool, 9. 339
Alcosol, 1. 771
Aldebaranium, 5. 505, 705
Aleacion do plata con bismato, 9. 635
Alexandrite, 4. 206 ; 5. 154, 294 ; 11. 177
Alexandrolite, 6. 865
Alfenide, 15. 209, 210
Algaroth, powder of, 9. 504
Algerito, 6. 763
Algiers metal, 7. 332
Algodonite, 3. 7 ; 9. 4, 62
Alipite, 6. 933 ; 15. 5
Alisonito, 7. 491, 796
Alite, 6. 556
Alkahest, 1. 5O
Alkali alkaline earth tungsten-bronzes, 11.
751
aluminium silicates, 6. 64O
amalgams properties chemical, 4. 1Ol 8
physical, 4. 1015
antimonatomolybdates, 9. 459
antimonitomolybdates, 9. 433
antimonitotungstates, 9. 433
beryllium pyrophosphate, 4. 247
bicarbonates, 2. 772
bismuth pyrophosphate, 9. 712
borates, 5. 65
bromides, 2. 577
carbides, 5. 844, 847
carbonates, 2. 7IO ; 13. 608
acid, 2. 772
impurities, 2. 724
caustic, 2. 495
chlorides, 2. 521
� hexametaphosphate, 2. 87O
hoxamminotetrachloroaluminates, 5
322
history, 1. 382
hydrocarbonates, 2. 773
hydrorthophosphates : secondary, 2
851
hydrosulphates, 2. 677
hydroxides, 13. 608
iodides, 2. 596
iodoplumbato, 7. 764
metals binary alloys, 2. 478
history, 2. 419
occurrence, 2. 423
preparation, 2. 445
relations, 2. 879
metaphosphate, 2. 867
metry, 1. 391
mild, 2. 495
mineral, 2. 42O
monosulphide, 2. 621
nitramidatos, 8. 269
nitrates, 2. 802
ortho-phosphates, 2. 847
perarsenatos, 9. 147
pcrphosphates, 8. 993
poly sulphides, 2. 629
pnilomolanes, 12. 266
pyrophosphate, 2. 862
salts, catalysis by, 1. 487
silicates, 6.* 317, 324
sulphate, 2. 656
sulphates, 10. 255
sulphozincato, 4. 607
tellurosulphostanntites, 11. 114
tetrametaphosphates, 2. 869
tourmalines, 6. 741, 742
trimetaphosphat.es, 2. 869
uranous carbonate, 12. 112
vanadates, 9. 757
vegetable, 2. 42O
works, 2. 735
Alkalies: caustic.-, 2. 421
fixed-, 2. 42O
mild-, 2. 421
volatile-, 2. 420
Alkaline earth borates, 5. 85
chlorosrnatos, 15. 72O
metal amalgams, 4-I Ol9
perphosphates, 8. 993
silicates, 6. 347
sulphites, 10. 282
vanadates, 9. 768
earths, 5. 494 ; 11. 522
Alkalites, 6. 587
Al-Khazini, 1. 42
Alkohol, 9. 339
opaline, 6. 497
Allotellum acid, 11. 87
Allotrimorphic crystals, 12. 876
Allotropism, 4. 131
AIlotropy, 5. 719
dynamic, 5. 723
enantiomorphic, 5. 723
enantiotropic, 10. 25
monotropic, 5- 723
Alloy, 3. 358
natural, 15. 179
steel, 12. 711
Vaucher's bearing, 4. 671
� � fusible, 9. 630
heat resisting, 13. 457
hotorogenoous, 12. 871
pyrophoric, 5. 610
Alluaudite, 12. 463
Allumettes chimiquos, 8. 1059
infornales, 8. 1059
Alluvial gold, 3. 491
Allyla.mirictric;hloroX->latinous acid, 16. 273
Allylammonium bromopalladite, 15. 677
Almadine, 5. 295
Alinandina, 6. 91 O
Almandine, 6. 714, 910 ; 12. 529
Almaosite, 6. 886
Aloxite, 5. 271
Alpakka, 15. 209, 2IO
Alpax, 6. 184
Alpha rays or a-rays, 4. 73, 8O
� � ionization by, 4. 83
ments, 4. 81
Alquifol. 5. 714
Alshedite, 5. 512 ; 6. 84O ; 7. 3
Alstonite, 3. 622, 625, 834
Altaito, 7. 491 ; 11. 2, 56
Altered mica, 12. 148
Aluandite, 2. 426
Aludel, 4. 7Ol
bath, 4. 7Ol
� furnace, 4. 701
fusibility, 5. 167
hydratod, 5. 253
hydrogel, 5. 276
hydrosol, 5. 276
� magnesia-lime, 5. 295
preparation, 5. 254
Bayer's process, 5. 254 *
from bauxite, 5. 254
from clays, 5. 257
Aluminatoa, 5. 284
Alumine hydratee des Beaux, 5. 249
Aluminilite, 5. 353
Aluminite, 5. 154, 338
silieeous, 6. 497
Aluminium, 5. 148, 151 ; 7. 2O
�-� activated, 5. 206
�� alloys, 5. 229
aluminoxyorthosilicate, 6. 458
--- amalgams, 5. 240
-� amminobromide, 5. 326
amminoiodopentamide, 5. 328
ammonium barium oxydodecamolyb
_ carbonate, 5. 359
chromium sulphate, 11. 463
dithionate, 10. 593
dodecamolybdate, 11. 599
ferric alums, 14. 349
hydroxysulphate, 5. 353
phosphate, 5. 367
selenate, 10. 869
silicododecatungstate, 6. 880
sulphate, 5. 344
weight, 5. 227
azide, 8. 352
barium alloys, 5. 235
hexahydrated, 5. 324
pentahydrated, 5. 325
� potassium trimesodisilieato, 6.
746
_ sulphatophosphate, 5. 37O
� -�-� tetrahydromotasihcate, 6. 707
� -- uranyl silicate, 6. 883
� carbide, 5. 846, 87O
� carbonate, 5. 358
� carbonyl, 5. 952
-- chlorate, 2. 353
� chloride, 5. 311
ennoahydrated, 5. 315
hexahydrated, 5. 314
preparation, 5. 312
properties, chemical, 5. 318
physical, 5. 316
chloroantimonite, 9. 481, 482
chlorobromide, 5. 326
hexahydrated, 5. 326
chloropalladite, 15. 67O
chloroplatinato, 16. 329
chloroplatinite, 16. 283
chlorostannate, 7. 449
chlorosulphate, 5. 319, 335
chromide, 11. 172
chrornite, 11. 2OO
chromium alloys, 11. 172
mosopentasilieato, 6. 766
orthotrisilioate, 6. 751
beryllium hoxametasil irate, 6.
804
calcium aluminohydroxytriorthosilicate,
6. 722
dihydropentamesodisilieate,
6. 748
� dihydrotriorthosilicate, 6.
718
dimanganous tetrahydrohexorthoHilicato,
6. 896
dimesotrisilicate, 6. 755,
761
-- ferrous boratotetrortlio silicate,
6. 911
hoxamotasilirato, 6. 733
magnesium dihydrotri
orthosilicate, 6. 718
- manganous boratototrorthosilicate,
6. 911
� orthosilicate, 6. 715
orthotriHilicatc, 6. 735, 738,
749
pentametasilicate, 6. 747
� totrainctasilieatc, 6. 729,
73O, 739
triorthodisilicate, 6. 747
triorthosilicate, 6. 752
dicalcium pentametasilicate, 6.
739
ferrous triorthosilicate, 6. 910
� lithium orthosilicate, 6. 569
pentametasilicate, 6. 641
magnesium triorthosilicate, 6.
815
manganese totrahvdroxyclimetasil
if-ate, 6/9OO
triorthosilicate, 6. 9Ol
-� potassium calcium pentamesodisilicate.
6. 747
dihydropontamoModiHilicate,
6. 748
sodium dihydropentamesodisili
cate, 6. 748
orthotrisilicate, 6. 653
pentametasilicate, 6. 747
tetrametasilicate, 6. 734
triorthosilicate, 6. 58O, 752
� oxychloride, 14. 35
� heptitabromorthosilicate, 6. 573
orthosilicate, 6. 569
paratetrasilicate, 6. 641
ferroxytetraluminyldiorthosilicate, 6.
phosphate, 5. 367
909
sulphate, 5. 342
fluoaluminato, 14. 3
totrametasihcate, 6. 641
fluoride, 5. 30O
alixminatorthosilicate, 6. 812
hemiheptahydrated, 5. 302
�� carbonate, 5. 359
moiiohydrated, 5. 302
trihydrated, 5. 302
fluosilicide, 6. 954
� mesopentasilicate, 6. 826
hemitrisilicato, 6- 184
� homitristannide, 7. 383
pentaluminatortnosilicate, 6. 813
henetricontabromopentantimonate, 9.
-� phosphate, 5. 37O
497
silicates, 6. 808
hoptaluminylborohydroxytriorthosili
sulphate, 5. 354
cate, 6. 462
hoxabromoantimonite, 9. 496
vanadatosilicate, 6. 836
hexabromobismuthite, 9. 673
hexaiodoliexanitritotriplatinite, 8. 523
hexammineiodide, 8. 262
hoxamminoiodide, 5. 328
hoxamminotriiodide, 5. 328
metachloroantimonate, 9. 491
history, 5. 148
metantimonate, 9. 457
hydroarsenate, 9. 186
hydrophosphate, 5. 365
metasilicate, 6. 475
hemitridecaphosphate, 5. 365
metavanadate, 9. 776
hydropyrophosphate, 5. 365
monantimonide, 9. 408
monohydroxide, 5. 274
monophosphide, 8. 846
� monoxy orthosilicate, 6. 458
� dihydrate, 5. 360
enneahydrate, 5. 360
hexahydrato, 5. 360
octohydrate, 5. 36O
pentadecahydrate, 5. 360
nitride, 8. 111
nitrite, 8. 495
nitrosyl chloride, 8. 617
hexachloride, 8. 438
occurrence, 5. 153
-�� octobromoplumbite, 7. 753
��� octobromostannite, 7. 454
octochlorostannito, 7. 434
octodecamminoiodido, 8. 262
octohydroxytrisulphite, 10. 3Ol
octosulphoheptachlorido, 10. 643
� octylaluminylhydroxytrioi'thosilicate,
6. 462
orthoantimonate, 9. 457
orthoarsenato, 9. 186
octohydrate, 9. 1 86
orthophosphate, 5. 362
__ colloidal, 5. 363
�� orthosilicate, 6. 454
hydratod, 6. 574
selenate, 10. 869
selenatoaulphate, 10. 930
sulphate, 5. 343
sulphatoselonate, 10. 93O
tellurate, 11. 96
triorthoarsenate, 9. 186
preparation, 5. 16O
production, 5. 152, 160
properties, chemical, 5. 202
physical, 5. 1 73
purification, 5. 169
pyroarsenate, 9. 186
pyrophosphate, 5. 362, 365
rubidium selenate, 10. 869
-� sulphate, 5. 345
selenate, 10. 869
solenide, 10. 781
selonite, 10. 829
trihydrate, 10. 829
silicates, 6. 453
alkali, 6. 640
hydrated, 6. 467
silicide, 6. 183
sihcododecamolybdat-c, 6. 871
silicododecatungstato, 6. 880
silicon cobalt alloys, 14. 536
iron alloys, 13. 57O
nickel alloys, 15. 231
silver, 5. 233 ; i5. 21O, 225
alloys, 5. 232
dioxymolybdate, 11. 6OO
-nickel alloys, 15. 231
oxydodecamolybdate, 11. 6OO
phosphate, 5. 37O
silicate, 6. 683
sulphate, 5. 341, 345
sulphide, 5. 329
sodium alloys, 5. 229
amide, 8. 262
arsenitosilicate, 6. 826
calcium sulphatotriorthosilicate,
6. 584
carbonate, 5. 359
chlorotriorthosilicate, 6. 582
chromatosilicate, 6. 866
dimetasilicate, 6. 643, 644, 645
dodecamolybdato, 11. 599
fiuoarsenate, 9. 259
hydrotrimetasilicate, 6. 651
hydroxy orthosilicate, 6. 574
hydroxysulphate, 5. 353
GENERAL, INDEX
hydrated, 6- 573
phosphate, 5. 367
pyrophosphate, 5. 367
selenate, 10. 869
silicomolybdate, 6. 871
sulphate, 5. 342
, sulphatotriorthosilicate, 6. 584
tricarfoonatotriorthosihoate, 6.
58O
triorthoarsenate, 9. 186
trisulphotriorthosilicate, 6. 587
basic, 5. 336
decahydrated, 5. 333
dihydrated, 5. 334
__ dodocahydrated, 5. 333
_ heptacosihydrated, 5. 333
hcptadeeahydrated, 5. 333
hoxadecahydrate, 5. 332
hexahydrated, 5. 333
octodecahydrate, 5. 333
trihydratod, 5. 333
sulphates, 5. 332
acid, 5. 333
�� sulphite, 10. 301
� sulphitoiodido, 5. 327
sulphodecachlonde, 10. 647
cate, 6. 607
potassium trimesotrisilicate, 6.
665
� trihydroxydiphosphate, 5. 366
trihydroxyphosphate, 5. 366
trihydroxytetranitritodiplatinite, 8.
52O
triiodohexarsenito, 9. 257
trimanganeside, 12. 211
trioxyenneaselenite, 10. 829
�� tritetritazirconide, 7. 117
zirconium, 7. 116
zoisite, 6. 72O
Aluminolitos, 5. 249
- colloidal, 5. 249
crystalline, 5. 249
Aluminosilicates, 6. 304
constitution, 6. 311
Aluminosulphuric acid. 5. 336
Aluminotherrnic reactions, 5. 218
Aluminotriorthosilicates, 6. 605
Aluminotungstates, 11. 789
Aluminous azide, 8. 352
Aluminovanadium, 9. 727
Aluminum, 5. 151
Aluminyl aluminium (di) magnesium ortho
pentasilicate, 6. 809
pseudo, 6. 356
X-radiograms, 1. 642
Alun de Rome, 5. 353
Alundum, 5. 271
Alunite, 2. 657 ; 5. 154, 257, 353 ; 14. 344
ammonia, 5. 353
soda, 5. 353
zinc, 5. 154
GENERAL, INDEX
Amidotetrimidopentaphosphoric acid, 8.
719
Amidothioimidosulphonic acid, 8. 635
Amidothiophosphoric acid, 8. 725
Amines, 8. 252
ju-amino-salt, 14. 672
Aminoacetal, 16. 272
Aminotrisulphonates, 8. 667
Ammines, 14. 690
constitution, 8. 228
metal, 8. 243
Ammino compounds, 4, 845
Amminomonimidototraphosphoric acid, 8.
715
Ammiolite, 9. 343, 437
Ammonal, 5. 219
Ammonia, 11. 368 ; 13. 608, 612, 015
adsorption by solids, 8. 200
alum, 5. 344 ; 13. 609
alunite, 5. 353
analytical reactions, 8. 224
effect on catalysis, 1. 487
gallic alum, 5. 385
hemihydrate, 8. 194
hexamminochloride, 8.216
- history, 8. 144
hydrate, 8. 194
hydroxypontachlorosmate, 15. 720
in air, 8. 13
indium alum, 5. 404
liquid, analogy with water, 8. 276
ionization, 8. 279
metal, 8. 243
occurrence, 8. 146
oxidation, 8. 207
pectohte, 6. 367
physiological action, 8. 205
preparation, 8. 148
� from gas-liquor, 8. 1 66
�� - Haber's process, 8. 1 58
.� Sorpek's process, 8. 112
properties, chemical, 8. 205
physical, 8. 173
rate absorption, 8. 1 96
- Serpek's process, 8. 112
solubility (various solvents), 8. 197
(water), 8. 194
substituted, 8. 252
turpeth, 4. 788, 979
Ammoniacum, 2. 781
Ammoniatos, metal, 8. 243
Ammotiiobasic compounds, 4. 786, 845
Ammoniojarosite, 12. 529 ; 14. 328, 343, 344
Ammonium, 2. 781 ; 4. 1007
aluminato, 5. 289
�-� aluminium carbonate, 5. 359
chromium sulphate, 11. 463
dimetasilicate, 6. 645
. dithionate, 10. 593
dodecamolybdate, 11. 599
ferric alums, 14. 349
hydroxy sulphate, 5. 353
phosphate, 5. 367
� selenate, 10. 869
silicododecatungstate, 6. 880
sulphate, 5. 344
aluminotungstate, 11. 789
amalgam, 4. 1005
amidochromate, 8. 266
amidodiphosphate, 8. 716
GENERAL, INDEX
date, 9. 76O
amminoiodoeuprite, 8. 205
amminosulphides, 8. 218
anuninotrichloroplatinite, 16. 267
antimonatomolybdate, 9. 459
antimonatotriiodobromide, 9. 512
antimonitomolybdate, 9. 433
antimonitoturtgstat.es, 9. 433
� arsenatoetomolybdate, 9, 209
arsenatoctovanadatohenieositungstato,
9. 202
�� arsenatoctovanadatopentaeosimolybdate,
9. 202
arsenatodecavanadatoctodecamolybdate,
9. 202
arsenatodecavanadatohenamolybdato,
9. 202
arsenatodecavanadatoheptadecamolybdate,
9. 202
arsonatodecavanadatopontadecarnolybdate,
9. 202
arsenatodecavanadatotridecamolybdate,
9. 202
�� arsenatodivanadate, 9. 20O
� arsonatododecavanadatodecamolybdate,
9. 202
arsenatododdcavanadatopentadecamolybdate,
9. 202
arsen at oh exa v anadatoi cosim oly bdate,
9. 202
arsonatototrachroinate, 9. 204
molybdate, 9. 202
arsenatotrimolybdate, 9. 209
arsonatavanadatotungstato, 9. 202,
215
arsenatovanaditovanadatotungstaie,
9. 202
arsonitoarsenatotungstate, 9. 214
-� arsenitomolybdate, 9. 131
arsenitotungstate, 9. 132
arsenitovanaditotungstate, 9. 132
anrosic tetrasulphite, 10. 28O
aurouH sulphite, 10. 28O
triamminodisulphite, 10. 280
octamrainohexasulphite, 10.
315
dimetaphosphate, 8. 893
diphosphatoc to vanadatotetra
decamolybdate, 9. 834
� � nitrilotrisulphonate, 8. 669
paramolybdate, 11. 586
phosphatomolybdate, 11. 663
� pyrophosphate, 4. 247
sulphate, 4. 241
tetraorthoarsenato, 9. 175
� bisulphate, 2. 703
ammines, 2. 594
bromoaurate, 8. 607
- bromobisarsenite, 9. 256
bromocarnallite, 4. 314
- bromocuprate, 3. 20O
� bromodiiodoplumbite, 7. 773
dihydrate, 7. 773
bromoiodide, 2. 595, 619
bromoiodostannate, 7. 463
bromoiridate, 15. 776
bromopalladate, 15. 678
bromopalladite, 15. 677
bromoperiridite, 15. 775
decaborate octohydratod, 5. 86
decabromoaluminate, 5. 326
decahydropentaseleni tododeca v ana
hexahydrate, 7. 772
decametaphoaphate, 2. 878
decamolybdate, 11. 597
� diamidodiphosphate, 8. 711
� � diamidophosphate, 8. 707
diamminototrachlorocujirate, 3. 186
diarsenatodecatungstate, 9. 213
diarsenatohenicositungstato, 9. 214
diarsenatoheptadecatungstate, 9. 213
diarsenatoheptamoly bdate, 9. 206
diarsenatohexatungstate, 9. 213
diarsenatotellurate, 11. 96
diarsenatotetracositungstato, 9. 214
diarsenatotetradeeatungstate, 9. 213
dibrornocuprito, 3. 195
~ dibromodichlorostannite, 7. 454
diceious octosulphate, 5. 659
� � diehlorobisdimethylglyoximorhodite,
15. 577
diehlorocuprite, 3. 163
dichlorodibromoplumbite, 7. 751
dichlorodicuprite, 3. 163
dichlorotribrornobiBmuthito, 9. 673
dichromate, 11. 323
dichromyl tetrafluoehromato, 11. 365
dicupric sulphate, 3. 255
difluodioxyphosphate, 8. 997
9. 207
� dihydroarsenatomolybdate, 9. 206
dihydroarsenatotrimolybdato, 9, 208
dihydroarsenite, 9. 12O
dihydrornanganidiorthophosphato, 12.
461
dihydrophosphatohomipontamolybdate,
11. 668
�� heptadeeahydrate, 11. 668
heptahydrate, 11. 668
- dihydrotetraselenitohexavanadate, 10.
835
dihydrothoridodecamolybdates, 11.
6Ol
dihydrotrioxysulpharsenate, 9. 327
tetrahydrate, 9. 327
dihydrotriselenite, 10. 821
dihydroxylaminometavanadate, 9,
470
dihypovanadatodivanadatoctocosimolybdate,
9. 793
Ammonium dihypovanadatotetradocatungstate,
9. 747
dihypo vanada to to tra vanadate, 9.
792
dihypovanadoctovanadate, 9, 792
diimidopentathiodiphosphato, 8. 727
diimidopontathiopyrophosphato, 8.
1056
diiodate, 2. 340
diiodothiosulphate, 10. 533
dilanthanum octosulphate, 5. 659
(di) dimercuriammonium nitrate, 4.
10Ol
dihydrated, 4. 1001
-� mercuric dinitratodiehloride, 4. 997
oxymerouriammonium nitrate hydrate,
4. 1001
dimercuriammoniuni chloride, 4. 845
chrornate, 11. 284
_ nitrate, 4. 999
dihydrated, 4. 1000, 1001
sulphate, 4. 978, 979
dodeeahydrated, 4. 978, 979
dimotaphosphate, 2. 876 ; 8. 985
--� dimolybdate, 11. 58O
dimolybditetramolybdate, 11. 531
dimolybditotetramolybdate, 11. 593
dioxydiselonotungstate, 10. 798
dioxydisulphomolybdate, 11. 654
dioxydisulphotungstate, 11. 861
molybdato, 9. 831
diphosphatoctovanadatohenanxolybdate,
9. 832
diphosphatoetovanadatoheptadecamolybdate,
9. 83O
� diphosphatoctovanadatotetradecamolybdato,
9. 83O
ootocosihydrate, 9. 83O
.. pentadecahydrate, 9. 83O
Ammonium, diphosphatohexavanadato
tetradecamolybdate, 9. 831
diphosphatohexavanadatotridecarnolybdate,
9. 831
d iphosphatotetradecavanadatohena
molybdato, 9. 882
diphosphatovanaditotungstate, 9.
826
diplatinic triacontatungstate, 11. 803
dipraaeodymium hexasulphate, 5. 659
tetrahydrate, 5. 352
disxilphatoehroinato, 11. 452
disulphatocuprate, 3. 255
disulphatoindate, 5. 404
tetrahydratod, 5. 404
disulphatovanadite, 9. 82O
disulphide, 2. 651
disulphitodiarnrrimocobaltato�trans-,
10. 318
disulphitodiethy lonediamminoeobaltito
trans-, 10- 318
disulphitod ipropylenediarnmmoeobaltato
trans-, 10. 318
disulphitocthylenediamine�vis-, 10318
trans-, 10. 318
disulphitotetramrriinocobaltate� cis-,
10. 317
� hexachloroplati natohypoantimonate,
9. 485
hexacbloroplumbite, 7. 727
hexachloro8tannatohypoantimonate,9.
485
hexachlorostannite, 7. 432
hexachlorotellurite, 11. 102
hexachlorothallate, 5. 445
dihydrated, 5. 445
hexachrornate, 11. 352
hexadecabromotriantimonite, 9. 496
hexadecatungntate, 11. 832
hexafluoaluminate, 5. 303
hexafluoantimonate, 9. 468
hexafluoarcenate, 9. 236
hexafluoferrate, 14. 7
hexafluohafniate, 7. 171
hexafluotitanite, 7. 66
hexafluovanadite, 9. 796
hexahydroarsenatoctodecamolyb�
date, 9. 211
hexaiodotellurite, 11. 106
hexamolybdate, 11. 594
hexaphosphatodivanadatohexaconta
tungstate, 9. 835
hexaselenitohexamolybdate, 10. 837
VOL. XVI.
hydroxynitrilomononosulpbate, 8. 671
2 F
GENERAL, INDEX
11. 671
pyrophosphate, 7. 88O
� trimetaphosphate, 2. 877
luteodivanadatophosphate, 9. 828
luteovanadatophosphate, 9. 827
magnesium arsenate, 9. 177
bromide, 4. 314
carbonate, 4. 37O
chloride, 4. 306
chromate, 11. 275
cobaltous sulphate, 14. 781
dimetaphosphate, 4. 306
dithiophosphato, 8. 1068
ferrous sulphate, 14. 297
hydrocarbonato, 4. 371
iodide, 4. 317
manganous sulphates, 2. 423
� molybdate, 11. 562
monothiophosphate, 8. 1O60
niekelous sulphate, 15. 475
orthosulpharsenato, 9. 321
paratungstato, 11. 818
persulphate, 10. 470
phosphate, 4. 384
-�-�- monohydrated, 4. 386
selenate, 10. 863
sulphate, 4. 342
sulphite, 10. 285
telluride, 11. 5O
thiosulphate, 10. 545
vanadate, 9. 773
voltaito, 14. 353
_ manganate, 12. 287
manganese arsenate, 9. 221
dithionate, 10. 506
oxytrifluoride, 12. 347
manganic alum, 12. 420
tetracosihydrate, 12. 429
�� dodecamolybdate, 11. 602
molybdate, 11. 572
para tungstate, 11. 82O
pentachloride, 12. 378
pentafluoride, 12. 345
� � porphosphate, 12, 463
pyrophosphate, 12. 462
trihydrate, 12. 462
tetrasulphate, 12. 420
tridecamolybdate, 11. 602
tungstate, 11. 707
manganous carbonate, 12. 439
chromate, 11. 309
cobaltous sulphate, 14. 782
decamolybdate, 11. 598
dihydrophosphatohemipentamolybdate,
11. 669
dimetaphosphate, 12. 458
disulphate, 12. 414
dodecamolybdate, 11. 602
ferrous sulphate, 14. 301
fluoride, 12. 344
heptachloride, 12. 364
Ammonium manganous hoxachloride, 12.
364
hexamrainotetrachloride, 12. 365
hydroxyla.iximoohlorid.es, 12. 364
molybdate, 11. 571
nickelous sulphate, 15. 477
oxy trisulphate, 12. 415
permanganitomolybdate, 11. 573
phosphate, 12. 452
heptahydrate, 12. 453
phosphatohemipentamolybdate,
11. 669
pyrophosphatomolybdate, 11. 671
selenate, 10. 878
sulphite, 10. 311
tetrabromide, 12. 383
tetrachloride, 12. 364
364
trichloride, 12. 363
trischrornate, 11. 309
trisulphate, 12. 415
mophite, 6. 2
hydratcd, 4. 927
tribromototraiodido, 4. 917
triiodide, 4. 926
hydrated, 4. 926
tungstate, 11. 788
_ decahydrate, 9. 570
enneahydrate, 9. 57O
tetrahydrate, 9. 570
INDEX 435
Ammonium metasulphotetrantimonite,
533
motasulphotriarsenite, 9. 29()
motatungstate, 11. 821
hexahydrate, 11. 821
tetrahydrate, 11. 821
metavanadate, 9. 758
molybdate, 11. 551
molybdatosulphate, 11. 658
molybda to trisulphate, 11. 658
molybdenum amminopentachloride,
11. 622
chloride, 11. 629
dioxytetrachloride, 11. 632
enneafluoride, 11. 6IO
hemipentoxide, 11. 532
hoptachlorido, 11. 621
hexaehloride, 11. 621
oxypontabrornide, 11. 637
pentabromide, 11. 635
pontachloride, 11. 621
totrachlorotetrabromido, 11. 64O
totrachlorotetraiodide, 11. 64O
tetradocachloride, 11. 623
totrafluorido, 11. 609
trioxytctradecafluondo, 11. 611
tungstate, 11. 796
� � molybdonyl pentabromide, 11. 637
pentachlonde, 11. 629
molybditotramolybdato, 11. 533
molybdosic sulphates, 11. 657
molybdous hoptachloride, 11. 619
octochloridc, 11. 618
monamidodiphosphato, 8. 7IO
monamidophosphate, 8. 705
monoporditungstate, 11. 834
tetrahydrate, 11. 834
� monoseleiiotrithionato, 10. 926
monosulphide, 2. 648
ammino, 2. 65O, 651
--� monothiohydrox>hosphite, 8. 1063
monothiophoaphate, 8. 1069
� neodymium carbonate, 5. 666
� molybdate, 11. 587
nitrate, 5. 671
nickel azide, 8. 355
cadmium nitrate, 8. 512
carbonate, 15. 486
chromate, 11. 313
� diamminochromate, 11. 313
d ihy drophosphatohemipen ta molybdate,
11. 67O
dihydroxyquatorchromate, 11.
313
dimotaphosphato, 15. 496
disulphate, 15. 467
dithionato, 10. 598
� hexamminosulphate, 15. 468
nitrotobismuthite, 8. 512
orthophosphato, 15. 495
dihydrate, 15. 495
hexahydrate, 15. 495
persulphate, 10. 480
phosphatohemipentamolybdate,
11. 670
phosphite, 8. 92O
selenate, 10. 887
sulphatofluoberyllate, 15. 478
sulphide, 15. 443
sulphite, 10. 319
GENERAL, INDEX
nitramidato, 8. 269
physical, 2. 833
nitratoaurate, 3. 616
nitratometatungstate, 11. 814, 861
-- nitratoplumbite, 7. 864
�� nitratostannato, 7. 481
nitratosulphato, 2. 843 ; 8. 692
nitrilodiphosphate, 8. 714
nitrilodithiophosphate, 8. 726
nitrilosulphinato, 8. 667
nitrilotrisulphonate, 8. 667, 681
nitrite, 8. 470
nitritoperosmite, 15. 728
nitrohydroxy lamina to, 8. 305
nitrosylchlororuthenate, 15. 537
tetrahydrated, 5. 81
octobutaborate, 5. 80
octochloroantimonate, 9. 490
octochlorotrimercuriate, 4. 851
octofluotantalato, 9. 917
octofiuovanadate, 9. 802
octohydroarsenatoenneamolybdate, 9.
210
octomolybdate, 11. 595
octomolybdatodisulphite, 10. 307
octosulphate, 10. 447
octosulphido, 2. 654
oc to tungstate, 11. 830
octovanadatohexamolybdate, 9. 782
octovanadatotetradecatungstate, 9.
786
octovanadatotridecamolybdate, 9. 782
orthoarsenate, 9. 155
orthophosphate, normal, 2. 874
orthosilicate, 6. 329
orthosulpharsenate, 9. 316
orthosulpharsenite, 9. 290
orthosulphoantimonate, 9. 569
orthosulphoantimonite, 9. 533
orthosulphovanadate, 9. 816
osmiamate, 15. 727
osmium dodecachloride, 15. 720
osmyl bromide, 15. 724
oxalatobisdinitritobisdiamminooobaltiate,
8. 5IO
oxalatotriamminochromate, 11. 409
11. 342
oxyfluopertitanate, 7. 68
oxyhenafluodicolumbate, 9. 873
oxyhexafluocolumbate, 9. 872
oxyhexafluotantalate, 9. 918
oxyhydroheptafluotantalate, 9. 918
oxypentachlorocolumbate, 9. 879
oxypentachlorotungstate, 11. 849
oxypentafluocolumbate, 9. 872
oxypentafluomolybdate, 11. 611
oxytetrafluocolumbate, 9. 872
oxytriselenophosphate, 10. 932
palladious solenate, 10. 89O
palladium polysulphide, 15. 682
palladous sulphatoselenate, 10. 930
paramolybdate, 11. 583
4Ol
pentabromoperrhodite, 15. 581
pontabromotungstite, 11. 854
pentachloroantimonito, 9. 479
monohydrate, 9. 479
pentachloroaquoperrhodite, 15. 578
pontachlorobismuthite, 9. 666
heptapentahydrato, 9. 666
� pentachlorocuprito, 3. 163
pentachlorodimercuriato, 4. 852
pentachlorodiplumbite, 7. 726
trihydrate, 7. 726
pentachloroferrate, 14. 99
pentachloroindate monohydrated, 5.
400
798
pentadecaiodotetrantimonite, 9. 502
pentafluoaluminate, 5. 303
pentafluoantimonite, 9. 465
pentafluovanadite, 9. 796
pentahydrododecaselenitohexa vanadate,
10. 835
pentahydrotrimolybdate, 11. 674
pentahydrate, 11. 694
8. 650
hemipentahydrato, 8. 650
heptahydrate, 8. 65O
pentasulphide, 2. 652
pentathiopyrophosphate, 8. 1070
pentatungstate, 11. 828
pentavanadylhydropentacosifluoride,
9. 799
penterosulphotriarsenate, 9. 316
penterotetradecavanadato, 9. 760
perborate hemihydrated, 5. 119
percarbonate, 6. 84
percoric carbonate, 5. 668
perchlorate, 2. 396
perchromate, 11. 356
perdichromates, 11. 359
perdisulphoraoly bdate, 11. 654
perdiuranate, 12. 71
perhydroxyoarbonato, 6. 85
periodates, 2. 408, 409, 410
permanganate, 12. 3Ol
pormaiiganite, 12. 275
permanganitomolybdates, 11. 572, 573
pennanganous ootomolybdate, 11. 597
permolybdate, 11. 607
permonosulphomolybdate, 11. 653
� � pervanadate, 9. 795
phosphates, 2. 871
phosphatoarsenatovanadatotungstate,
9. 203
ph osphatoarsenatovanaditotu ngs tato,
9. 202
phosphat oarsenatovanaditovanadato
tungstate, 9. 203
phosphatoctomolybdato, 11. 667
phosphatoeuprito, 3. 287
phosphatodecarnolybdate, 11. 664
phosphatododocamolybdato, 11. 662
phosphatododecatungstate, 11. 866
phosphatoenneamolybdate, 11. 666
phosphatoenneatungstato, 11. 871
� phosphatohemihenicositungstate, 11.
869
phosphatohemiheptadecarnolybdate,
11. 667
phosphatohemiheptadecatungstate,l 1.
871
phosphatohemiheptatungstate, 11. 873
phosphatohenamolybdate, 11. 664
phosphatohenatungstate, 11. 868
phosphatoheptamolybdate, 11. 667
phosphatohexamolybdate, 11. 667
phosphatohexatungstate, 11. 872
ph osphat oplatinate, 16. 416
phosphatotetrachromate, 11. 482
phosphatotetramolybdate, 11. 667
phosphatotritungstate, 11. 874
phosphitododecamolybdate, 8. 918
INDEX 437
263
dichlorodisulphite, 10. 323
disulphite, 10. 322
sulphitodiamminosulphite cis-,
10. 321
trans, 10. 32O
tetramminohydrophosphate, 16.
416
� tetrasulphite, 10. 322
trihydrate, 10. 322
trichlorohydrosulphite, 10. 323
plumbite, 7. 668
� polysulphoplatinute, 16. 398
potassium arsenatodecavanadatohoxadecamolybdate,
9. 202
arsenatododecavanadatodecamolybdate,
9. 202
arsenatotetradocavanadatododecamolybdate,
9. 202
arsenatototradocavanadatotndcoamolybdato,
9. 202
barium Bilieovanadatodecatungstato,
6. 838
- chloroplumbita, 7. 729
deearnetaphosphate, 2. 878
- diphosphatoctovanadatototradecamolybdate,
9. 833
- diphosphatodecavanadatotridecamolybdate,
9. 833
- diphosphatododecavanadatodecamolybdate,
9. 833
- diphosphatododecavanadatododecamolybdate,
9. 833
- diphosphatohxeavanadatootodecamolybdate,
9. 833
- diphosphatohoxavanadatopentadecamolybdato,
9. 833
- diphosphatotetradecavanadatoenneamolybdato,
9. 833
- diphosphatotetradeeavanadatohenamoIybdate,
9. 833
� diphosphatototravanadatoicosimolybdate,
9. 833
disulphatocuprate, 3. 259
hexachlorobismuthite, 9. 667
- hexavanadatopentamolybdate,
9. 784
imidochromate, 8. 266
iridium disulphate, 15. 786
manganous permanganitomolyb
323
trichlorosulphite, 10. 323
. pyrophosphate, 2. 876
silicovanadatodecatungstate, 6.
838
silieovanadatomolybdates, 6. 837
sulphitochloroiridite, 15. 758
tetravanadatotetramolybdate, 9.
784
ti-isolenitodecamolybdato, 10. 836
tnterodecavanadate, 9. 766
viranyl trisulphate, 12. 108
� i>yroarsemto, 9. 120
pyrophosphate, 2. 876
pyrosulpharsenate, 9. 316
pyrosulpharsenatosulphomolybdato, 9.
323
pyrosulphate, 10. 445
pyrosuljmite, 10. 327
pyrotellurito, 11. 77
rhodic dodecamolybdate, 11. 603
rhodium alum, 15. 588
� scolecite, 6. 75O
seloiiato, 10. 853
selenatoalummate, 10. 869
seleriatoarsonate, 9. 203 ; 10. 875
selenatochromato, 10. 876
selenatomonoiodate, 10. 914
selenatophosphatc, 10- 932
selena tosulphate, 10. 925
solonatotriiodate, 10. 914
Ammonium silicovanadatomolybdate, 6.
837
539
diiodotetrathiosulphate, 10. 54O
hoptasulphito, 10. 28O
heptathiosulphate, 10. 536
nitrate, 8. 479
-� orthosulphoantimonite, 9. 542
phosphatoheiniheptatungstate,
11. 873
rhodium chloronitrate, 15. 59O
sulphite, 10. 28O
tetrahyclroenneasulphite, 10. 28O
thiosulphato, 10. 536
� trithiosulphate, 10. 536
monohydrate, 8. 5OO
hydroarsenato, 9. 156
� hydrorthophosphate, 2. 874
hydrosuhphite, 10. 270
457
1 : 3-meta tungstate, 11. 824
nitratoimidodisulphonate, 8. 651
988
phosphatohemiheptadecamolyb
GENERAL
784
. tetreroctocolumbato, 9. 865
tetrerotetradecavanadate, 9. 765
trihydrodiorthoarsenate, 9. 153
triterodecavanadate, 9. 766
hydroxynitrilodisulphonato, 8.
677
imidosulphonate, 8. 654
nickel nitrite, 8. 511
trioxysulpharsenato, 9. 329
151
acid, 2. 703
monohydrate, 10. 255
properties, chemical, 2. 701
physical, 2. 696
sulphatobisrnuthite, 9. 670
Hulphatohexafluodiantimonite, 9. 466
sulphatohypovanadate, 9. 818
�� sulphatopertitanate, 7. 95
sulphatophosphate. 8. 948, 1071
sulphatotellurite, 11. 118
sulpha to titanite, 7. 92
sulphatotrifluoantimonito, 9. 466
-� sulphide, 2. 645
effect oix catalysis, 1. 487
sulphimido, 8. 663
sulphirnidodiamide, 8. 665
sulphitochloroiridite, 15. 758
sulphoferrite, 14. 182
sulphomolybdato, 11. 65O
sulphoplatinate, 16. 398
sulphostannate, 7. 474
heptahydrated, 7. 474
trihydrated, 7. 474
sulphostanmte, 7. 478
sulphotellurite, 11. 113
sulphotungstate, 11. 858
sulphovanadatomolybdato, 11. 652
sulphovanadites, 9. 816
sulphurylbromide, 10. 689
sulphurylchloride, 10. 689
sulphurylnitrate, 10. 689
sulphurylthiocyanate, 10. 689
syngenite, 8. 812
tellurate, 11. 89
tellur at oar senate, 9. 203
telluratohexamoly bdate, 11. 97
telluratotriarsenate, 9. 204
tellurite, 11. 77
tellurium sulphite, 10. 306
INDEX 439
80
tetrabromoaluminate, 5. 326
tetrabromobismuthite, 9. 672
tetrabromoferrate, 14. 124
tetrabromoplumbito, 7. 751
monohydrate, 7. 751
totrabromostannite, 7. 453
tetrabromothallate, 5. 452
tetrachloroaluminate, 5. 321
tetrachloroantimonite, 9. 479
tetrachlorobromodiplumbite, 7. 751
� tetrachloroferrate, 14. 99
tetrachloroferrite, 14. 31
tetrachloroindate, 5. 4OO
totrachloromercuriato, 4. 849
monohydrated, 4. 849
tctrachloroplumbite, 7. 726
tetrachloi'ostannite, 7. 432
totrachlorotollurite, 11. 1OO
tetrachlorozincate, 4. 552
totrachromate, 11. 351, 352
- totracosivanadatopontamolybdale, 9.
782
totraenneasulphidc, 2. 652
tetrafluobismuthite, 9. 659
tetrafluodioxytungstate, 11. 838
tetrafluodioxyvanadate, 9. 799
tetrafl uoferrate, 14. 3, 7
tetrafluovanadate, 9. 8Ol
tetrafluovanadite, 9. 796
tetrahydroarsonatododecamolybdalo,
9. 211
tetrahydroarsenatohemipentamolyb
date, 9. 207
tetrahydrorthohcxavanadatc, 9. 759
tetrahydrorthotetravanadate, 9. 759
tetrahydroxylaminotetramoly bdate,
11. 592
tetraiodobismuthite, 9. 676
tetraiodopluinbite, 7. 772
dihydrato, 7. 774
tetrahydrate, 7. 773
� � tetraphosphatodi vanadatoctotessareontamolybdate,
9. 829
totraphosphatodivanadatodotossaracontamolybdate,
9. 829
totraphosphatododeeavanaditotetratessaracontatungstato,
9. 826
tetraphoHphatohcxadeeavanadatotetratrifontatungstate,
9. 835
tetraphosphitototradecavanaditohen itricontatungstate,
8. 919
tetraselenotungstate, 10. 798
tetrasulphide, 2. 652
tetrasulphocuprate, 3. 227
tetrathionato, 10. 617
tetrauranate, 12. 67
tetrauranyl pentasulphite, 10- 308
tetravanadatodimolybdate, 10. 781
tetravanadatopentamolybdate, 9. 782
GENERAL, INDEX
Ammonium tetravanadatotetramolybdate,
9. 781
tetravanadylhydrododecafluoride, 9.
80O
tetrorodeea vanadate, 9. 759
tetroxydisulphatodivanadate, 9. 825
thallic bromoplumbite, 7. 753
ehloroplumbito, 7. 732
disulphate, 5. 469
trisulphate, 5. 469
_ phosj^hate, 5. 478
-� thiocarbamate, 6. 132
-� thiocarbonate, 6. 121
thiophosphato, 8. 1064
thiosulphato, 10. 514
thoridodecamolybdates, 11. 601
thorium carbonate, 7. 249
dodecachlorido, 7. 234
fluoride, 7. 227
hoxachloride, 7. 234
� hexanitrate, 7. 251
� hexasulphate, 7. 246
hydronitrate. 7. 251
pontachloride, 7. 235
pentanitrate, 7. 250
�.� _ dihydrate, 7. 251
pentahydrate, 7. 250
pentasulphate, 7. 246
� tetrasulphate, 7. 245
trisulphato, 7. 245
titan ate, 7. 5O
titanium carbonate, 7. 96
oxysulphato, 7. 95
titanous alum, 7. 92
sulphate, 7. 92
titanyl sulphate, 7. 95
triamidodiphosphate, 8. 712
triammino-bromocuprite, 3. 195
triamminochloride, 8. 206
triamminocuprite, 3. 205
triarsonatotellurate, 11. 96
triarsenatotetravanadate, 9. 201
triazomonosulphonate, 8. 684
trihromide, 2. 594
tri-brornocuprite, 3. 195
tribromomagnesiato, 4. 314
� tribromoplumbite, 7. 751
tribromostannite, 7. 453
trichlorocuprate, 3. 184
trichlorocuprite, 8. 163
trichlorohypobismuthate, 9. 662
trichloromagnesiate, 4. 306
trichloromercuriate, 4. 851
monohydrated, 4. 851
� trichloroplumbite, 7. 726
� trichlorostannite, 7. 432
� � trichlorosulphitopalladite, 15. 669
� trichlorotribromobismuthite, 9. 673
� trichromats, 11. 349
� tridecachlorotetraferrate, 14. IO1
� tridecafluoantirnonite, 9. 465
� trifluodioxy tungstate, 11. 838
� trifluoferrate, 14. 3
� trifluoroeuprate, 8. 156
trihydrotetraselenitohexavanadate,
10. 835
triimidochromate, 8. 266
tri-iodate, 2. 340
triiodide, 2. 619
8. 666
trisulphatochromate, 11. 464
trisulphatocuprate, 3. 255
trisulphatododecafluotetrantimonite,
9. 466
trisulphatoplumbate, 7. 823
trisulphide, 2. 651
gold, 2. 651
trisulphimide, 8. 663
trisulphitotriamminocobaltate, 10. 318
trisulpbomolybdato, 11. 651
triterohexatantalate, 9. 900
triterohexavanadate, 9. 759
hexahydrate, 9. 759
pentahydrate, 9. 759
trithionate, 10. 607
trithiophosphate, 8. 1067
tritungstate, 11. 8IO
triuranyl disulphite, 10. 308
trivanadyl disulphite, 10. 305
tungstate, 11. 773
tungsten tetrafluoride, 11. 837
ultramarine, 6. 589
uranate, 12. 18, 61
� uranium hydroxydisulphotetrauranate,
12. 97
hydroxyhydrodisulphotetrauranate,
12. 97
oxytrifluoride, 12. 75
red, 12. 97
tetracarbonate, 12. 116
tungstate, 11. 797
uranous carbonate, 12. 112
hexasulphate, 12. 103
oxalatofluoride, 12. 74
tetrasulphate, 12. 103
uranyl arsenate, 9. 215
carbonate, 12. 17
chloride, 12. 17
chromate, 11. 308
INDEX 441
Amylaminium carhonyltrichloroplatinito,
16. 273
dt-wio-amylammonium bromopalladate, 15.
678
-__ bromopalladite, 15. 677
539
wo-amylammonium bromopalladate, 15.
678
carnea, 6. 752
Analysis, 1. 91
ionic hypothesis, 1. 1009
positive ray, 4. 5O
Analzim, 6. 644
Anapa'ite, 14. 395
Anapaite, 12. 529
Anatase, 7. 2, 3O
Anauxite, 6. 495
Anaxagoras, 1. 32
Anaximeiwg, 1. 32
Aneudite, 6. 477
Ancylite, 7. 185
Andalusito, 0. 458
Andorborgite, 5. 512 ; 6. 847
Anderberjite, 7. IOO
Andosine, 6. 662, 693, 7OO
Andradite, 6. 714, 921 ; 12. 529
Andreasbergolite, 6. 766
Andreolite, 6. 766
Andrewsite, 12. 529 ; 14. 410
Anemousite, 6. 662, 695
Angaralite, 6. 922
Anglarite, 9. 553 ; 14. 390
Angle of optical extinction, 1. 608
principal incidence, 3. 47
Angles, axial, 1. 615
of crystals, interfacial, 1. 593
Anglesite, 7. 491, 803
Anhydrobasiche Tetrammin-Diaquodiam
278
Animal charcoal, 5. 75O
Animals metabolism, 6. 10
Ammicite, 4. 698
Animikite, 9. 404 ; 15. 9
Anion, 1. 92
o-anisidimum bromosmate, 15. 723
p-anisidimum bromopalladite, 15. 677
liquids, 1. 645
Anistropy ultramieroscopic, 5. 760
Ankerito, 4. 251, 371 ; 12. 148, 15O, 529 ;
14. 359
Anlassen, 12. 69O
Annabergite, 9. 4, 230 ; 14. 424 ; 15. 5
Annealing, 12. 673, 723
Anrierodite, 5. 516 ; 7. 1OO ; 9. 839 ; 12. 4
Annite, 6. 608
Annivite, 9. 4, 291
Anode, 1. 92
mud, 3. 27
slime, 3. 27
Anomite, 6. 608
Anomites, 6. 611
Anophorito, 13. 529
Anorthite, 6. 662, 692, 693
baryte, 6. 707
ferric, 6. 698
hydrated chloro-, 6. 700
potash, 6. 662, 698, 706
soda, 6. 698
strontia, 6. 707
zinc, 6. 698
Anthosiderite, 6. 907
Anthracitic diamond, 5. 719
Anthropomorphical chemistry, 1. 2
Anticatalysts, 1. 938
Anticathodo, 4. 31
Antedrite, 6. 751
Antifriction metal, 4. 671 ; 7. 362
Antigorite, 6. 422
Antihypo, 6. 87
Antillite, 6. 392
Antimoino natif arsenifere, 9. 69
� oxyde octaedrique, 9. 421
sulphure, 9. 577
Antimonates, 9. 446
Antimonatotungstatos, 11. 795
Antimonatotungstit! acid, 9. 459
Aritimonbleikupferbleridc, 9. 55O
Antimonblendo, 9. 577
Antimoiibliithe, 9- 421
Antimonglanz, 9. 513
Antimonial copper, 9. 343
crocus, 9. 578
fahlerz, 15. 9
nickel, 9. 415
ores plumose, 9. 546
saffron, 9. 577, 578
silver, 3. 3OO ; 9. 343, 404
blende, 9. 294
Antimoniale causticum, 9. 469
Antimonic aoids, 9. 439
borotungstate, 5. Ill
diarsonatoetodecatungstato, 9. 214
nitrosyl chloride, 8. 617 ; 9. 476
oxide,* 9. 421, 439
Antimonides, 9. 4Ol
Antimonidiantimonious heinafhioride, 9.
468
Antimonii butyram, 9. 469, 504
� cerussa, 9. 452
cinnabasis, 9. 469
cum sulphur Hofmanii, 9. 574
stellao, 9. 340
Antimonioiis acids, 9. 428
antimonate, 9. 434
barium thiosulphate, 10. 553
borotungstate, 5. Ill
calcium thiosulphate, 10. 533
lead enneaiodide, 7. 762
oxide, 9. 42O, 421
potassium thiosulphate, 10. 553
sodium thiosulphate, 10. 553
strontium thiosulphate, 10. 553
thallous thiosulphate, 10. 553
Antimonipentantimonious icosifluoride, 9.
468
Antimonite, 9. 343, 513
Antimonites, 9. 425, 428
Ant imonitet rant imonious hep tadecafluo
ride, 9. 468
Antimonitophosphatotungstate, &� "*33
Antimonitriantimonious tetradecafluoride,
9. 468
Antimonium, 9. 341
Antimonkupferglanz, 9. 550
Antimonocker, 9. 435
Antimonspath, .9. 421
Antimony a-, 9. 361
- altotropes, 9. 357
-� amminotrichloride, 9. 476
-� amminotrioxide, 9. 426
_ chloromtrosylpentachloi'ide, 9. 488
chlorosulphides, 9. 583
- cobaltic dichlorobisethylenediaminehexachloruio,
14. 67O
colloidal solutions, 9. 362
decafluoiodide, 9. 510
deeafluopentachloride, 9. 5IO
deeafluopentadeeachloride, 9. 51O
diamminochloride, 9. 496
diamminotrinuorido, 9. 464
difluotrichloride, 9. 509
dihydride, 9. 391
dinitroxylpcntadceachloride, 8. 542
dinitroxyltrispentachloride, 9. 488
dioxide, 9. 434
dioxysulphide, 9. 578
dioxytetrasulphide, 9. 577
disulphatotrioxide, 9. 582
monohydrate, 9. 582
trihydrate, 9. 582
disulphoselenide, 10. 921
ditritoxide, 9. 421
dodecabromolanthanato, 5. 645
electronic structure, 9. 389
enneachloride, 9. 475, 487
ethyl pentabromide, 9. 493
explosive, 9. 359
extraction, 9. 348
female, 9. 587
octodecachloride, 14. 1 25
ferro\is sulphide, 14. 168
flores, 9. 378
444 GENERAIL,
INDEX
pentaiodide, 9. 502
pentaselenide, 10. 794
pentasulphide, 9. 564
colloidal, 9. 566
pentasulphodichloride, 9. 583
pentoxide, 9. 421, 439
alcogels, 9. 444
hydrates, 9. 441
di-, 9. 442
� hemiennea-, 9. 442
� hemi-, 9. 442
hexa-, 9. 442
� mono-, 9. 442
penta-, 9. 442
tetra-, 9- 442
--_ _ tripenta-, 9. 442
�--� hydrogels, 9. 445
hydrosols, 9. 444
pentoxydibromide, 9. 507
-� pentoxydichloride, 9. 505
pentoxydi iodide, 9. 507
pentoxysulphide, 9. 578
perchlorato, 2. 401
phosphate, 9. 585
phosphodecachloride, 8. 1Ol5
phosphopentadecaohloride, 8. 1015
phosphorus decachloride, 9. 489
phosphonyl octochloride, 9. 489
physiological action, 9. 385
potassium henasulphate, 9. 583
sulphate, 9. 583
properties, chemical, 9. 378
physical, 9. 363
refining, 9. 353
selenate, 10. 875
selenium dioxyenneachloride, 10. 906
silicide, 6. 188
silver sulphate, 9. 583
sodium sulphate, 9. 582
solubility of hydrogen, 1. 306
star, 9. 35O, 355
strontium sulphate, 9. 583
suboxide, 9. 421
subsulphide, 9. 512
sulpharsenate, 9. 322
sulpharsenite, 9. 301
sulphate, 9. 58O, 582
sulphide golden, 9. 564
sulphides, 9. 512
higher, 9. 564
� sulphite, 10. 304
sulphobromide, 9. 584
- sulphochloride, 9. 584
sulphodocosichloride, 9. 584
sulphoenneachloride, 10. 647
sulphohalides, 9. 583
sulphoiodide, 9. 584
sulphotrichloride, 9. 584
GENERAL INDEX
�� tetrasulphatotrioxide, 9. 581
tetrasulphide, 9. 564
totritapentaselonide, 10. 794
tetroxido, 9. 351, 421, 434
monohydrated, 9. 437
tetroxybischromate, 11. 305
totroxyheptachloride, 9. 506
tetroxysulphide, 9. 578
thiophosphate, 8. 1066
triarnminodifluotrichloride, 9. 509
triarnminopontachloride, 9. 488
triammino trichloride, 9. 476
triamminotrifluoride, 9. 464
triarsenide, 9. 69
tribromido, 9. 493
trichloride, 9. 469
� trigonal, 9. 357
trihydride, 9. 391
trioxide, 9. 421
_ acetogels, 9. 43O
alcogels, 9. 43O
colloidal, 9. 422
hydrogels, 9. 429
physical, 9. 423
trioxypontahydroxychloride, 9. 504
trioxytetrasulphide, 9. 578
� trioxytrihydroxytrichloride, 9. 504
triselenide, 10. 793
trisulphido, 9. 512, 513
colloidal, 9. 526
� hydrogel, 9. 526
hydrosol, 9. 526
properties, chemical, 9. 521
� physical, 9. 518
trisulphodiselenido, 10. 921
trisulphohexaiodide, 9. 584
tritatetraselenide, 10. 794
tungstates, 11. 795
uses, 9. 386
vanadates, 9. 779
vermilions, 9. 565
yellow, 9. 358
Antimonyl, 9. 425
bromide, 9. 507
chloride, 9. 504
copper oxytriiodide, 9. 508
iodide, 9. 507
lead oxychloride, 9. 507
mercury oxytriiodide, 9. 508
metacolunbotantalate, 9. 905
nitrate, 9. 685
Antlerite, 8. 265
Antophyllite, 6. 396
Antozone, 1. 899
Antrimohte, 6. 749
Aonia, 7. 277
Apatelite, 14. 328, 333
Apatite, 8. 623, 697, 896 ; 5. 530 ; 7. 896 ;
8. 733 ; 9. 261
cerium, 5. 675
didymium, 5. 675
X-radiogram, 1. 642
Aphanese, 9. 161
Aphenesite, 9. 161
Aphoizito, 6. 741
Aphrodite, 6. 42O, 428
Aphrosidorite, 6. 624; 12. 529
Aphthitalito, 2. 430, 657
Aphthorite, 9. 291
Aphtit, 15. 314
Apjohnito, 5. 154, 354 ; 12. 148, 423
Aplome, 6. 921 ; 12. 148
Apollinaris, 6. 6
Apophyllite, 6. 368
Apparent equilibrium, 1. 715
Apples, 18. 615
Applied chemistry, 1.11
Apyrito, 6. 741
Aqua bromata, 2. 71
618
chlorata, 2. 71
chrysulca, 2. 21
dissolutiva. 8. 556
fortis, 8. 555, 556
phagadcenica, 4. 774
prima, 2. 20 ; 8. 556, 618
regia, 2. 2O ; 8. 617
stabilized, 8. 619
� regis, 8. 618
salis ammoniaci, 8. 618
armoniaci, 2. 20
� nitri, 2. 2O
secunda, 2. 2 O
Aquadag, 5. 753
Aquamarine, 4. 204 ; 6. 803
Aquamol, 5. 219
Aquilarite, 10. 773
Aquobasic compounds, 4. 845
Aquodisulphitotriamminocobaltic acid, 10.
318
Aquopentachloroperiridous, 15. 763
X-radiogram, 1. 642
Arakawaite, 4. 664
Aramayoite, 9. 692
Arbor jovis, 7. 298, 338
saturni, 7. 516
Arsenic white, 9. 9O
Arsenical copper, 0. 4
mundic, 12. 529
nickel, 9. 4
pyrites, 9. 72, 73 ; 12. 529
axotortious, 9. 73
prismatic, 9. 73
silver blende, 9. 294
soot, 9. 91
album, 9. 1, 90
calci forme, 9. 9O
cristallinum, 9. 90
faricacoum, 9. 9O
nativxim, 9. 9O
Arsenides, 9. 61
Arsenikbliithe, 9. 94
Arsenikkalk naturliehon, 9. 94
Arseniksauor kalk, 9. 169
Arsonikspiessglanz, 9. 69
Arsenikwismuth, 9. 703
Arsenioploi'te, 3. 623
Arseniopleite, 9. 4, 222 ; 12. 148
Arseniosidorite, 3. 623 ; 9. 4, 228 ; 12.
529
Arsenious acid, 9. 9O
barium thiosulphate, 10. 552
load enneaiodido, 7. 762
phosphoctochloride, 8. 1015
potassium thiosulphate, 10. 553
bromide , 9. 249
chloride, 9. 237
fluoride, 9. 237
monochloride, 9. 245
physical, 9. 53
Arsinic acid, 9. 1Ol
Arsonic acid, 9. 101
Art bronzes, 7. 348
Artiads, 1. 208
Artinite, 4. 365
Aryans, 1. 2O
Asbeferrite, 6. 917
Asbestinon, 6. 425
Asbestolite, 6. 426
Asbestos, 6. 426
actinolite, 6. 426
amphibole, 6. 426
chrysolite, 6. 426
hornblende, 6. 426
porcelain, 6. 426
Asbolan, 14. 424
Asbolite, 12. 148, 266 ; 14. 424
Ascharite, 2. 43O ; 5. 4, 97
Aschentrecker, 6. 740
Aschirite, 6. 342
Asem, 4. 67O, 695
Asiderites, 12. 523
Asmanite, 6. 247
Aspasiolite, 6. 811
Asperolite, 6. 343
Asperolithite, 3. 8
Aspidelite, 7. 3
Aspidolito, 6. 605, 608
Associated liquids, 1. 856
Association of liquids, 1. 858, 86O
Aster samius, 6. 428
Asterism, 6. 614
Astorium, 4. 21 ; 7. 890
Asteroidal elements, 4. 3
Asteroite, 6. 915 ; 12. 148
Astochite, 6. 916 ; 12. 148
Astracanite, 2. 43O
potassium, 2. 43O
Astrakanito, 4. 252, 336 ; 7. 896
potassium, 4. 339
Astrites, 6. 607
meroxenuH, 6. 608
Astrolite, 12. 529
Astrophyllite, 6. 843 ; 7. 3 ; 12. 149
Atocamite, 2. 15 ; 3. 8, 178, 179
Ataxitos, 12. 523, 528
Atelesite, 9. 589
Atelestite, 9. 4, 198
Ateline, 3. 178
Aterite, 15. 21O
Atheriastite, 6. 763
Atlasite, 3. 275
Atmolysis, 1. 342
Atmosphere, 1. 147, 148
primitive, 6. 4
Atom, 1. 103, 187 ; 4. 910, 158
architecture, 4. 165
Bohr's, 4. 167
calcium, 4. 175
cataclysm, 4. 180
composite, 4. 12
helium, 4. 169
hydrogen, 4. 169
Langmuir's octet theory, 4. 196
Le1WTiS' cubical, 4. 195
Rutherford, 4- 166
INDEX 449
INDEX
B
Bababudanite, 6. 913
Babbit metal, 7. 362
Babingtonite, 6. 391, 917 ; 12. 149, 529
Babo's ozonizer, 1. 885
Back electromotive force, 1. 1029
Bacon Roger, 1. 46
Bacterium radicicola, 8. 359
Bacterized peat, 8. 36O
Baddcleyite, 7. IOO, 123
Badenite, 14. 424 ; 15. 5
Backstrornite, 12. 149, 22r>
Bagrationite, 5. 509 ; 6. 721
Baierine, 9. 906
Bakerite, 5. 4 ; 6. 441
Baldauflte, 12. 529
Bald-win's phosphorus, 3. 740
Ball mills, 3. 497
Ballesterosite, 14. 20O
Balling up, 12. 637
Balmer's spectrum, 4. 169
Balneum regis, 9. 341
Baltimorite, 6. 422, 624
Bamlite, 6. 455
Bamprite, 8. 860
INDEX 451
� d iphosphatododecavanadatododecamolybdate,
9. 834
diphosphatododeoavanadatooctomolybdate,
9. 835
diphosj >hatohexa vanada tohoji tadecamolybdate,
9. 834
diph osphatote tradeca vanadatodecamolybdate,
9. 835
di vanada to trimo Iy bdate, 9. 784
dodeca vanada tohe xa tricontamolybdate,
9. 784
hydro xy nitrilo - iso - disulphonate,
8. 679
icosihydroquiniusdiarsenitodimolybdate,
9. 131
imidodisulphonate, 8. 655
imidosulphinite, 8. 646
iridium disulphate, 15. 786
nickel nitrite, 8. 511
nitrilotrisulphonate, 8. 669
paramolybdate, 11. 586
phosphatomolybdate, 11. 663
potassium silicovanadatodecatungstate,
6. 838
trinetaphosphate, 2. 877 ; 3. 894
analytical reactions, 8. 641
antimonatotungstate, 9. 459
antimonious thiosulphate, 10. 553
antimonite, 9. 432
antimony alloys, 9. 406
sulphate, 9. 583
arsenatoc to vanada to trie on tamolyb date,
9. 202
72O
CuClB-NH4Cl-H20, 3. 715, 720
dihydrated, 3. 705
hydrated, 3. 702, 705
KCl-NaCl, 8. 720
preparation, 3. 697
properties, chemical, 3. 714
6. 922
fiuoaluminato, 5. 308
fluoarsenatoapatite, 9. 259
preparation, 8. 688
physical, 8. 689
fluoroapatite, 3. 901
�� fluorobromide, 8. 731
fluoroehlorido, 3. 694, 718
fluoroiodide, 3. 739
fluoronitrate, 3. 694
fluorophosphate, 3. 901
fluosilicate, 6. 951
fluostannate, 7. 423
trihydrate, 7. 423
fluosulphonate, 10. 685
fluotantalate, 9. 917
fl.uotitan.ato, 7. 72
hemihydrated, 7. 72
fluotriorthoarsenate, 9. 259
fluozirconate, 7. 141
gold thiosulphate, 10. 545
hemisilicide, 6. 179
honamercuride, 4. 1032
heptapermanganite, 12. 278
heptauranato, 12. 68
hexaborate hexahydrated, 5. 92
hexadecamercuride, 4. 1031
hexafluoferrate, 14. 8
hexahydroarsenatoctodecamolybdate,
9. 211
hexahydroferriarsonate, 9. 228
hexahydropontaphosphite, 8. 916
hexahydrotetrarsenitotetratriconti
molybdate, 9. 131
hexaiododiplumbite, 7. 777
hexametaphosphate, 3. 895
� hexammine, 8. 249
hexainrninochloroplatinate, 16. 328
hexamminoiodido, 3. 737
hexaphosphatotetravanadatohexa
contatungstate, 9. 835
hexarhodate, 16. 571
hexarsenite, 9. 126
hexasulphitodicobaltate, 10. 315
hexavanadatoctodecamolybdate, 9.
784
hexavanadatododecatungstate, 9. 787
hydride, 8. 649
history, 8. 619
hydrazinodisulphinate, 8. 682
hydrazinodisulphonate, 8. 683
hydrazinomonosulphonate, 8. 683
� hydroaluminoarsenate, 9. 186
hydroarsenate, 9. 171
� hydroarsenite, 9. 125
hydrocarbonate, 3. 844
hydrodioxydiselenophosphate, 10. 932
� hydrodisulphate, 8. 784
� hydrohyponitrite, 8. 414
hydroimidodisulphonate, 8. 655
hydrophosphate, 8. 881
INDEX 453
hypobromite, 2. 273
hypochlorite, 2. 272
hypouitrite, 8. 414
hydrated, 8. 414
tetrahydratod, 8. 414
hypophosphate, 8. 937
hypophosphito, 8. 884
hypophosphitomolybdate, 8. 888
hypophosphitotungstato, 8. 888
hypovanadatovanadatomolybdato, 9.
793
imide, 8. 26O
imidodiphosphate, 8. 713
iodate, 2. 347
hydrated, 2. 348
iodide, 3. 734
dihydrated, 3. 734
iodoarsenatoapatite, 9. 263
iodoaurate, 3. 610
iodoplatinate, 16. 39O
iodostannite, 7. 46O
iodotriorthoarsenate, 9. 263
iodotriorthovanadate, vanadatiodapatite,
9. 814
isopropylstannonato, 7. 410
isotetrahydroborododecatungstate, 5.
110
isotopes, 8. 648
hexahydrated, 4. 94O
pentamminochloroplatinate, 16. 328
jjentamolybdatodisulphite, 10. 307
pentapermanganito, 12. 278
pentasulphide, 3. 755
pentathionate, 10. 627
pentauranato, 12. 68
perborate, 5. 12O
porchlorate, 2. 399
porcobaltite, 14. 6Ol
perdicobaltite, 14. 6Ol
l^erdi chroma te, 11. 359
perditungstate, 11. 835
pordiuranato, 12. 73
perferrate, 13. 936
perforrito, 13. 926
periodates, 2. 412, 413
permanganate, 12. 333
pprmangamto, 12. 278
� photoluminescence, 3. 745
plagioclaso, 6. 707
� dimetaphosphato, 3. 894
diphosphatototravanadatoctodccamolybdate,
9. 834
hydroxynitrilodisulphonate, 8.
677
hyponitritosulphate. 8. 69O
imidodisulphonate, 8. 655
iron nitrite, 8. 5Ol
nickel nitrite, 8. 511
nitnlotrisulphonate, 8. 669
nitrite, 8. 488
� oxytrisulpharsenate, 9. 33O
-- pontabromidc, 3. 732
� phosphate, 3. 877
deeahydratod, 3. 877
� phosphatohenatungstate, 11. 868
� silicododecatungstate, 6. 878
silicovanadatoonnoatungMtatc, 6,
838
� � sulphatochlorido, 3. 813
sulphatonitrate, 3. 813
tetrachloride, 3. 719 ; 4. 3IO
trichroinato, 11. 351
physical, 3. 631
py roar sen ate, 9. 171
pyroarsonite, 9. 125
pyrophosphate, 3. 891
* dihydrated, 3. 891
monohydratod, 3. 891
pyroselenite, 10. 825
� pyrosulpharsonate, 9. 32O
pyrosulpharsenatosulphomolybdate, 9.
323
pyrosulpharsenatoxymolybdate, 9.
331
� pyrosulpharsenite, 9. 296
pentahydrato, 9. 296
pyrosulphate, 10. 447
pyrosulphoantimonite, 9. 542
-� pyrovanadate, 9. 769
Barium salts, catalysis by, 1. 487 Barium sulphide and metasilicato, 6. 364
hexahydrated, 3. 744
monohydrated, 3. 744
sulphides, 3. 740
sulphimide, 8. 664
sulphimidodiamide, 8- 665
sesquiborate, 5. 9O
sesquithioearbonate, 6. 127
sulphometastannate, 7. 476
silicodecatungstate, 6. 882
silicododecamolybdate, 6. 871
silicododecatungstate, 6. 878
silicotitanate, 7. 54
silicovanadatoenneatungstates, 6. 838
sulphovanadites, 9. 816
telluride, 11. 5O
phosphatododecatungstate, 11.
tellurite, 11. 8O
867
tetraborate, 5. 91
phosphatohenatungstate, 11. 868 tetracetochlorochromate, 11. 398
trithiosulphate, 10. 545 tetrachlorobismuthite, 9. 667
sodium arsenate, 9. 173 tetrachloroplumbite, 7. 731
� ultramarine, 6. 590
� uranato, 12. 63
� uranite, 8. 625
� uranium hydroxydisulphotetrauranate,
12. 98
hydroxyhydrodisulphotetrauranate,
12. 98
rod, 12. 98
uses, 3. 644
vanadatomolybdate, 9. 784
vanadatomolybdatoarsenate, 9. 211
tetraiodide, 4. 584
zincate, 4. 53O
_ heptahydrated, 5. 91
� hydroxynitrilomonosulphonate, 8. 672
potassium trirnetasilieato, 6. 371
(hopta)barium potassium octometasilicate,
6. 371
(tetra)barium octoalurninylheptarnetasilicate,
6. 734
(tri)barium aluminate, 5. 291
� decaborate hexahydrated, 5. 91
hydroxynitrilodisulphonate, 8. 677
imidodisulphonate, 8. 655
anorthite, 6. 707
Barytobiolite, 6. 608
Barytocalcite, 3. 622, 625, 814, 834, 846
Barytocelestines, 3. 763
Barytophillite, 6. 620
Basalt, 7. 896
Basaltes albus, 6. 648
crystallizations, 6. 909
Basaltine, 6. 817
Basanomolano, 7. 57
Base, acidifiable, 1. 385
bullion, 7. 277
history, 1. 382, 383
metal, 3. 358, 525
Bases, 1. 393
and acids, neutralization, 1. 1006
strength measurement, 1.
1004
of acids, 1. 389
Basilito, 9. 460
Basitomglanz, 9. 551
Basler Tauffstein, 6. 909
Basset ite, 12. 136
Bastite, 6. 392
Bastntisite, 5. 522
Bastonite, 6. 608
Batchelorite, 6. 492
Batrachite, 6. 408
Baudisserite, 4. 349
Bauerofon, 12. 584
Bauldaufito, 14. 392
Baulite, 6. 663
ferruginous, 5. 249
nonferruginous, 5. 249
Bauxitite, 5. 249
Bauxium, 5. 251
Bavalite, 6. 623
Bavenite, 6. 733
Baveno habit, 6. 67O
twinning, 6. 671
458 GENERA INDEX
metals, 7. 348
Belonesite, 4. 296
Belonite, 4. 296 ; 9. 693
Belonites, 1. 628
Bolonosite, 11. 488, 561
Bementite, 6. 448, 90O ; 12. 149
Benedict metal, 15. 179
Benitoile, 6. 835 ; 7. 3, 54
X-radiogram, 1. 642
Benjaminito, 9. 695
Bentonito, 6. 495
Benzalanilinium bromosmato, 15. 723
telluride, 11. 42
Benzyl ultramarine, 6. 59O
Benzylammonium bromoiridate, 15. 777
375
bromosmate, 15. 723
chloroiridate, 15. 770
trichloropalladito, 15. 671
16. 375
bromosmate, 15. 722
chloroiridate, 15. 770
golden, 4. 204
X-radiogram, 1. 642
Beryllatos, 4. 228
Beryllerde, 4. 205
Beryllia, 4. 221
antimonite, 9. 432
arsenide, 9. 66
arsenates, 9. 126
atomic number, 4. 22O
weight, 4. 218
auric chloride, 4. 233
azide, 8. 35O
GENERAL INDEX
basic, 4. 242
chlorate, 2. 349
chloride, 4. 231
diammino-, 4. 232
hexammino-, 4. 232
iodic, 4. 233
properties, chemical, 4. 232
chloromercuriate, 4- 86O
ohloropalladate, 15. 673
chloropalladite, 15- 67O
ohloroplatinato, 16. 328
heptahydrato, 9. 866
tetrahydrate, 9. 866
copper alloys, 4. 668
nickel alloys, 15. 206
cnpric sulphate, 4. 241
� cupride, 4. 668
_ deuterohexavanadate, 9. 773
diammine, 9. 773
dodecammine, 9. 773
hexammino, 9. 773
dihydrophosphate, 4. 246
dihydroxydisilicate, 6. 381
diiododinitritoplatinite, 8. 528
diiodotriarsenito, 9. 257
dioxide, 4. 228
dodecachlorothallato, 5. 447
enneadecahromotriantimonate, 9. 497
Beryllium hydroxyorthoborato, 5. 96
hypophosphate, 8. 937
hypophosphite, 8. 885
iodate, 2. 350
iodide, 4. 234
sesquiammino, 4. 235
iodoantimonite, 9. 502
iodobismuthito, 9. 677
iron alloy, 13. 542
- xnetasilicate, 6. 38O
metatungstate, 11. 826
metavanadate, 9. 772
molybdato, 11. 561
tetrahydratod, 4. 245
nitratometatimgstate, 11. 862
nitratophosphatc, 4. 246
nitride, 8. 104
nitrite, 8. 488
occurrence, 4. 204
-� orthosilicato, 6. 38O
homi hydra tod, 6. 381
oxide, 4. 221
preparation, 4. 221
properties, chemical, 4. 223
physical, 4. 222
oxybromide, 4. 234
� oxycarbonate, 4. 242
oxychlorido, 4. 232
'� tetrahydratod, 4. 232
oxydioxide, 4. 228
oxyfluoride, 4. 229
oxyiodide, 4. 234
oxymolybdato, 11. 561
oxynitrato, 4. 245
oxynitratomolybdate, 11. 659
oxynitrato vanadate, 9. 826
oxyorthoarsenate, 9. 175
oxysolenites, 10. 825
oxysulphite, 10. 284
oxytetranitritodiplatinite, 8. 520
oxytetraphosphitos, 8. 916
oxytrisulphite, 10. 284
Parsons' test, 4. 216
pentachloroantimonite, 9. 481
tetrahydrate, 9. 481
trihydrate, 9. 481
pentachloroferrato, 14. 104
pentaselenite, 10. 825
46O GENERAL, INDEX
� preparation, 4. 211
properties, 4. 211
chemical, 4. 214
physical, 4. 212
pyrophosphate, 4. 246
_ dihydrated, 4. 236
heptahydrated, 4. 236
hexahydratod, 4. 236
monohydratod, 4. 236
potassium, 4. 240
tetrahydrated, 4. 235
sulphide, 4. 235
sulphite, 10. 284
sulphomolybdate, 11. 652
sulphosilicate, 6. 382
sulphotungstate, 11. 859
tellurate, 11. 94
tolluride, 11. 50
� tellurite, 11. 8O
tetraiodoplumbite, 7. 778
tetravanadate, 9. 772
thiosulphate, 10. 545
triselenite, 10. 826
tungstate, 11. 787
uranate, 12. 63
uses, 4. 217
valency, 4. 218
vagaries of, 4. 215
zinc sulphate, 4. 64O
Beryllus, 4. 204
Berzelainite, 10. 694
Berzelianite, 3. 7 ; 10. 769
Berzeliite. 8. 623 ; 4. 252 ; 9. 4, 221 ; 12.
149
soda, 9. 222
Berzeline, 6. 584 ; 10. 769
Berzelite, 6. 651 ; 7. 740
Borzelium, 5. 504 ; 7. 174, 209
Berzelius' electrochemical theory, 1. 399
Bessemer steels, 12. 711, 648
magnetic spectrum, 4. 85
Betaiite, 5. 519 ; 9. 839, 867, 905 ; 12. 4
Betaine bromoplatinate, 16. 376
Bettendorff's reaction, 9. 111
test arsenic, 9. 38
Beudantite, 7. 491, 877 ; 9. 4, 334 ; 12.
pea-shaped, 9. 298
rod-shaped, 9. 298
Biological test arsenic, 9. 39
Biotina, 6. 693
Biotite, 6. 604, 605, 608
baryta, 6. 608
titaniferous, 6. 609
Biphosphamide, 8. 709
2, 2'-bipyridal, 15. 576
Birofringent liquids, 1. 645
Birides, 5. 23
Birkeland and Eyde's furnace, 8. 374
Birolingite, 6. 432
Bisbeeite, 6. 341
Bischofite, 2. 15, 43O ; 4. 252, 298
Bisemutum, 9. 587
Bisethylallylaminetrichloroplatinous acid,
16. 273
Bisethylenediaminopropylene diamines, 11.
4Ol
Bishop's ring, 8. 2
Bisiryl, 6. 216
bis-iso-undecylaminechloroplatinite, 16. 272
Bismatosmaltite, 9. 589
Bismite, 9. 589
Bismithides, 9. 589
Bismon, 9. 598
Bismuth, 9. 587
a-, 9. 603
/S-, 9. 603
10. 552
molybdate, 11. 570
nitrate, 9. 7IO
sodium nitratonitrite, 8. 5OO
thiosulphate, 10. 554
tungstate, 11. 795
amorphous, 9. 598
� antimonide, 9. 409
arsenates, 9. 198
arsenite, 9. 13O
atomic disintegration, 9. 633
number, 9. 633
weight, 9. 632
barium thiosulphate, 10. 554
boride, 5. 28
bromides, 9. 67O
bromosulphide, 9. 702
cadmium nitrate, 9. 7IO
caesium nitrate, 9. 7IO
nitrite, 8. 499
14. 817
chloropentamminoctoiodide, 14.
746
dichlorobisethylenediarninebromide,
14. 729
dichlorobisethylenediaminechloride,
14. 67O
dichlorotetramminosulphato, 14.
8Ol
dinitritotetramminoiodide, 8. 508
� dinitritotetramminoperohlorate,
8.508
dinitritotetramminoselenate, 8.
508
hexamminohexabromide, 14. 721
hexamminohexaiodide, 14. 743
trisethylenediaminechloride, 14.
657
colloidale, 9. 598
nitrate, 9. 7IO
� dihydrotetrasulphate,* 9. 7OO
dihydroxynitrate, 9. 708
diiodide, 9. 674
� dimethide, 9. 675
nitrate, 9. 710
flowers of, 9. 646
fluorides, 9. 659
fluosulphido, 9. 659, 702
glance, 9. 684
halogenosulphides, 9. 702
hemioxide, 9. 643
hemipentamminotnbromide, 9. 672
hemiselonide, 10. 795
. henieosihromocerata, 5. 645
hoptoxydisulphate, 9. 7 OO
hexabromocerato, 5. 645
hexabromolanthanate, 5. 645
hoxasulphitodicobaltate, 10. 315
higher oxides, 9. 653
history, 9. 587
hydride, 9. 624
hydrogel, 9. 598
hydrohoptachloride, 9. 664
hydrosol, 9. 598
hydrotetraehlorido, 9. 662
hydrototraiodide, 9. 676
hydroxide, 9. 65O
hydroxy chromate, 11. 3()6
hydroxydichromate, 11. 306, 343
hydroxynitrato, 9. 708
hydroxysulphate, 9. 700
hydroxysulphatostannate, 7. 479
hydroxy sulphite, 10. 305
� hyponitrite, 8. 417
hypophosphate, 8. 939
hypophosphito, 8. 887
iodides, 9. 674
iodoazide, 8. 337
iodosulphido, 9. 702
isotopes, 9. 633
lanthanum sulphate, 9. 7Ol
lead sulphosolenides, 10. 921
magistry of, 9. 707
magnesium nitrate, 9. 710
manganese nitrate, 9. 710
manganite, 12. 279
manganous nitrate, 12. 446
mereurous tungstate, 11. 795
metallic precipitation, 9. 63O
metantimonato, 9. 46O
metaphosphate, 9. 712
metasulphoctoantirnonite, 9. 553
molybdate, 11. 570
monarsenido, 9. 7 O
monobromide, 9. 67O
monochloride, 9. 66O
monoselenide, 10. 794
monoxide, 9. 643
nickel nitrate, 9. 710 ; 15. 492
nitrate, 9. 705
basic, 9. 707
dihydrate, 9. 705
GENERAL, INDEX
nitride, 8. 124
nitrite, 8. 499
nitrosyl chloride, 8. 438, 617
nitrosyltrichlorido, 9- 665
nitroxyl tetrachloride, 9. 665
nitroxy!trichloride, 9. 665
� occurrence, 9. 588
ochre, 9. 589, 646
organosol, 9. 599
orthoantimonate, 9. 460
orthoarsenate, 9. 197
hemihydrato, 9. 197
orthoborate dihydrated, 5. 107
��� orthophosphate, 9. 711
trihydrate, 9- 712
� orthosilicate, 6. 836
orthosulphoantimonite, 9. 553
orthosulphophosphate, 9. 713
orthotellurate, 11. 97
orthovanadate, 9. 779
oxybromide, 9. 68O
oxychloride, 9. 679
oxychromite, 11. 2Ol
oxydihydrotrifluoride, 9. 678
oxydihydroxycarbonate, 9. 704
oxydisulphide, 9. 699
oxyfluorido, 9. 678
oxyhahdes, 9. 678
oxyiodide, 9. 681
oxysulphides, 9. 698
oxytrifluoride, 9. 679
passive, 9. 627
pentachloride, 9. 660
pontadeeoxyhoxabromide, 9. 681
pentafluoride, 9. 659
pentasulphide, 9. 684
hydrated, 9. 655
permonoBulphomolybdate, 11. 653
pernitrate, 9. 708
peroxide, 9. 653
phosphates, 9. 711
phosphide, 8. 852
phosphite, 8. 918
physiological action, 9. 628
potassium chromate, 11. 305
hydroxydichromate, 11. 343
hydroxydisulphate, 9. 701
__ nitrite, 8. 499
hemiheptahydrate, 9. 699
sulphates, 9. 698
sulphatodihydrochloride, 9. 7Ol
sulphatohydrochloride, 9. 7Ol
sulphatoperiridite, 15. 784
sulphatotetrahydrochloride, 9. 7Ol
sulphides, 9. 682
complex, 9. 689
sulphite, 10. 305
sulphoditelluride, 11. 6O
sulphoditellurite, 11. 114
sulphohalides, 9. 702
sulphomolybdate, 11. 652
sulpho tellurite, 11. 114
sulpho tungstate, 11. 859
-� sulphurated, 9. 684
sulphuret, 9. 684
tollurate, 11. 97
tolluride, 11. 6O
dihydrate, 9. 664
tridecaoxyheptabromide, 9. 681
trifluoride, 9. 659
trihydride, 9. 626
trihydrohexachloride, 9. 664
trihydroxyvanadate, 9. 780
triiodide, 9. 675
� trioxide, 9. 646
colloidal, 9. 65O
dihydrate, 9. 650
monohydrate, 9. 651
organosols, 9. 65O
trihydrated, 9. 65O
trioxydichloride, 9. 680
trioxysulphide, 9. 698
triselenide, 10. 795
trisulphide, 9. 684
colloidal, 9. 685
trisulphotelluride, 11. 61
tritaoctochloride, 9. 661
tritetritasulphide, 9. 685
trithionate, 10. 609
trithiophosphate, 8. 1067
tungstate, 11. 795
uranyl arsenate, 9. 216
bi&muthates, 9. 657
bismuthaurite, 3. 494, 531.; 9. 636
bismuthic gold, 9. 636
bismuthicum subnitricum, 9. 707
Bismuthides, 9. 634
Bismuthin, 9. 684
Bismuthine, 9. 626
Bismuthinite, 9. 589, 684
Bismuthite, 9. 589, 684
Bismuthoplagionite, 7. 491
Bismuthosphaerite, 9. 703
Bismuthous metasulphoctoantimonite, S
684
orthosulphoantimonite, 9. 684
Bismuthplagionite, 7. 491
Bismuthspar, 9. 589
Bismuthum phosphoricum solubile, 9. 71 I
Bismuthyl bromide, 9. 68O
carbonate, 9. 703
monohydrate, 9. 703
chloride, 9. 679
�� dihydrated, 9. 662
monohydrated, 9. 662
chrornate, 11. 305
cobaltie hoxanitrite, 8. 505
-� totranitrite, 8. 505
diarsenate, 9. 198
diehromate, 11. 306, 343
dihydrotrifluorido, 9. 678
dithionate, 10. 595
diuranato, 12. 67
fluoride, 9. 678
heptahydroxydecasulphite, 10. 305
� orthoarsenate, 9. 198
INDEX 463
16. 273
15. 763
Bisulfure d'hydrogeno, 6. 94
spar, 4. 371
Bittern, 2. 525
Bittersalzerde, 4. 25O
Bituminous limestone, 3. 815
Bityite, 4. 206
damp, 6. 7
gold, 3. 531
� � heart cast iron, 12. 724
- jack, 4. 408
lead, 5. 713
light, 4. 53
� nickel, 15. 5
nickollmg, 15. 38
precipitate. 4. 809
Blatterblende, 4. 408
d'espagrio, 9. 707
d'Oifenbanya, 11. 1
de zinc, 4. 507
Blanquette, 2. 713
smelting, 3. 23
Blasting powder, 2. 826
Blattererz, 11. 1, 47
Blattertellur, 11. 1
Blatterzeolith, 6. 758
Blauofen, 12. 584
Bleach-liquor, 2. 244
Bleaching, 2. 243, 262
constitution, 2. 26(>
manufacture, 2. 259
properties, 2. 26O
Bleiarsenite, 9. 300
Bleierde, 7. 832
Bleierze salzsaures, 7. 852
Bleifahlerz, 9. 55O
Bleiglatte, 7. 638
Bleiglanz, 7. 781
Bleiglas, 7. 803
Bleiniere, 7. 491 ; 9. 458
Bleischimmer, 9. 555
Bleischwarze, 7. 832
464 GENERAL INDEX
Bleischweiff, 7. 781
Bleispath, 7. 829
Blende, 4. 586
cadmium, 4. 587
resin, 4. 407
Schwarze, 12. 387
Sidot's, 4. 592
zinc, 4. 407, 586
Blister copper, 3. 25
roasting, 3. 25
steel, 12. 752
12. 4
Blood and hydrogen, 1. 304
charcoal, 5. 750
Bloodstone, 6. 139 ; 13. 775
Bloom, 12. 583, 597
Bloomary, 12. 583
Bloomery, 12. 583
Blown metal, 12. 709
Blue Berlin, 3. 274
gron, 7. 883
Boast, 5. 72O
Bobierrite, 4. 252, 382 ; 8. 733
Bodenbenderite, 12. 5
Bodenite, 5. 509
Boehme, J*., 1. 48
Boeumlerite, 2. 431
Bog manganese, 12. 149, 267
absolute, 1. 165
determination, 1. 563
Beckmann's process, 1. 563
effect volatility of solvent,
1. 565
Landsberger's process, 1.
564
points colloids, 1. 774
solutions with two, 2. 327
Bole, 6. 472 ; 13. 887
of Stolpen, 6. 498
Boloite, 2. 15
Boleite, 7. 491, 743
Bolivarite, 5. 366
Bolivian, 9. 542
Bolivianite, 9. 542
Bolivite, 9. 589, 699
Bologna spar, 3. 619
137
cadmium, 5. 140
cobalt, 5. 140
ferrous, 5. 14O
iron, 5. 137
manganese, 5. 140
nickel, 5. 14O
Turkish, 5. 89
zinc, 5. 14O
Boracium, 5. 3
Borak, 5. 1
Boramide, 5. 132 ; 8. 261
Boranes, 5. 35
Boranol, 5. 35
Borate magnesio-calcaire, 5. 137
Borates, 5. 47, 65
Boratobromides, 5. 14O
Boratofluoric acid, 5. 123, 124
Boratoiodides, 5. 140
Boratosodalite, 6. 583
Borax, 5. 1, 3
calcined, 5. 670
dehydrated, 5. 48
glass, 5. 71
lime, 5. 93
usta, 5. 7O
veneta, 5. 68
Borazite, 5. 137
GENERAL, INDEX
Bose's swarm theory, liquid crystals, 1- 649 Braunstein metal, 12. 141
Bosjemanite, 5. 154 ; 12. 149 piedmontischer, 6. 768
BoBJesmanite, 12. 424 reduoirten, 12. 141
Bosphorite, 12. 529 ; 14. 392 roter, 12. 432
!Boss process silver extraction, 3. 304 Braunsteinblende, 12. 387
Botallacite, 3. 178 Braunsteinerz Luftsaures, 12. 432
Botriolite, 6. 449 schwarz, 12. 231, 265
Botryite, 14. 348 Braunsteinkalk, 12. 141
Botryogen, 4. 252 ; 12. 150, 529 ; 14. 328, Braunsteinkies, 12. 387
348 Braunsteinkonig, 12. 141
Botryolite, 6. 449 Braunsteinregulus, 12. 141
Botryte, 14. 348 Bravaisite, 6. 624, 921
Boulangerite, 7. 491 ; 9. 343, 544 Bravoite, 9. 715 ; 15. 5, 449
Bound energy, 1. 716 Brazilite, 7. 723
Bournonite, 6. 455 ; 7. 491 ; 9. 343, 55O Brazing solder, 4. 671
nickel glanz, 9. 550 Breccia, 3. 81.5
Boussingaultito, 4. 342 Bredbergite, 6. 921
Bovillo bordolaise, 3. 262 Broislakite, 6. 916
Bowenite, 6. 422 Breithauptite, 3. 220 ; 9. 343, 415 ; 15. 5
Bowl-sprite, 9. 2 Breunorite, 4. 251, 349 ; 14. 369
Bowmanite, 4. 206 ; 5. 370 Brevicito, 6. 573, 653
Boydonite, 12. 8OO Brevium, 4. 122, 127
Boyle, R., 1. 52, 53 Brewstorite, 3. 625 ; 6. 575, 758
Boyle's law, 1. 151 Brewsterlin, 6. 562
and kinetic theory gases, 1. 743 Brewsterlinite, 6. 562
� solutions, 1. 543 Brewstolin, 6. 562
deviations, 1. 152 Bricks Dinas, 6. 289
effect of molecular weight on, 1. ganister, 6. 289
194 sand-lime, 6. 283
Brackebuschite, 9. 715, 778 Brilliant, 5. 711
Brackebushite, 7. 491 ; 12. 149 Brimstone, 10. 1
Braes, 4. 67O Briquets phosphoriques, 8. 1059
Braggite, 12. 4 ; 15. 592 ; 16. 5, 394 Britannia metal, 7. 332
Bragite. 5. 516 Britholite, 5. 529 ; 6. 835
Brandisite, 6. 816 ; 12. 529 Brithynspar, 6. 751
Brandtite, 3. 623 ; 9. 4 ; 12. 149 British cement, 6. 554
Brannerite, 12. 4 thermal unit, 1. 699
Brass, 3. 1, 2 ; 4. 67O Brittle silver ore, 3. 30O
thermochemistry, 2. 218
�� occurrence, 2. 15
pentoxide, 2. 293
physical properties, 2. 46
preparation, 2. 38
purification, 2. 40
solubility, 2. 72
and soln., 2. 82
organic solvents, 2. 84
salt soln., 2. 82
. water, 2. 71
trifluoride, 2. 113
trioxide, 2. 281, 285
uses, 2. 96
valency, 2. 108
water, 2. 71
Bromite, 2. 16 ; 3. 418
Bromlite, 3. 625, 846
Bromoaiiilinium foromopalladite, 15. 677
m-broirioanilinium bromopalladito, 15. 677
_-� bromosmate, 15. 723
16. 375
Bromoplatinates, 16. 377
Bromoplumbites, 7. 751
Bromopyromorphite, 7. 885
Bromoruthenates, 15. 538
Bromosilicomethane, 6. 979
Bromosodalites, 6. 583
Bromostannates, 7. 456
Bromostannites, 7. 453
Bromosulphonic acid, 10. 689
Bromotellurites, 11. 104
Bromotriiodosilane, 6. 984
BromouB acid, 2. 285
� anhydride, 2. 285
age, 1. 19
aluminium, 5. 222, 229
analysis ancient, 3. 1, 2
caries of, 3. 76
complex, 4. 67O ; 7. 347
manganese, 4. 67O ; 4. 671
phosphor, 7. 347
� silicoux, 7. 356
silicieux, 5. 17
silicon, 7. 348
zinc, 7. 347
borotungstate, 5. 110
Cabrerite, 4. 252 ; 9. 4, 231 ; 14. 424 ; 15. 5 bromate, 2. 350
Cacheutaite, 10. 771, 788 araraino-, 2. 350
Cacoclasite 6. 713 bromide, 4. 564
Cacodylic acids, 9. 101 monohydrated, 4. 567
Cacoxenite, 12. 529 ; 14. 408 tetrahydrated, 4. 567
Cadmia, 4. 398, 642 ; 6. 442 bromoapatite, 4. 66O
pentaiodide, 4. 583
tetrabromido, 4. 572
tetrachloride, 4. 558
tetraiodide, 4. 583
tribromido, 4. 572
-� chloride, 4. 535
dihydrated, 4. 54O, 541
homipentuliydrated, 4. 541
heptatritahydrated, 4. 54O
_ monohydrated, 4. 541
pei itah yd rated, 4. 541
properties, chemical, 4. 548
� physical, 4. 536
��� totrahydrated, 4. 541
chloroapatite, 4. 66O
chloroarsenatoapatite, 9. 26O
chloroaurate, 3. 595
chloroiridato, 15. 772
chloromereuriato, 4. 861
chloropalladate, 15. 673
--- chloropalladite, 15. 67O
chlorophosphate, 4. 66O
chloroplatmate, 16. 329
_ hoxahydrate, 16. 329
trihydrate, 16. 329
chloroplatinite, 16. 283
chloroplumbite, 7. 731
chlorostanrialo, 7. 449
- chlorotriorthoarsonate, 9. 26O
chromate, 11. 28O
dihydrate, 11. 28O
- -� chromite, 11. 2OO
chromiurn alloy, 11. 171
cobalt alloys, 14. 533
cobaltic aquopentamminoennoabromide,
14. 723
aquopentamminolieptachloride,
14. 661
aquopentamrainoiodido, 14. 745
dichlorobisethylenediaminebromide,
14. 73O
diehlorobisethylenediamineiodide,
14. 747
dichlorobisethylenediaminochloride,
14. 67O
� dodecanitrite, 8. 504
hexamminoheptachloride, 14.
656
hexamminohexabromide, 14. 720
hexamminoiodide, 14. 743
hexarnminopentachloride, 14. 656
cobaltous carbonates, 14. 813
hexachloride, 14. 644
diammino, 9. 774
dodecammme, 9. 774
triamiiiine, 9. 774
diamidodiphosplmte, 8. 711
diamminobromide, 4. 571
� diamminochloride, 4. 55O
diamminoiodide, 4. 582
diamunnopotasBainide, 8. 261
� diamminosulphate, 4. 633, 634
diamrninothiocarbonate, 6. 128
diarsenatoctodecatungstate, 9. 214
diarsemde, 9. 67
diarsenite, 9. 1 27
diborate, 5. K)O
dihydroarsenate, 9. 182
- dihydroarscnatotrimolybdate, 9. 208
dihydrochloride, 4. 549
dihyclrophosphate, 4. 661
dihydrated, 4. 661
dihydrotetraorthoarsenato, 9. 182
dihydrotrjselonide, 10- 827
� � monohydrate, 10. 827
dihydroxytetrachloroplatmate, 16. 334
� diiodceamminochloro��latinato, 16. 329
diiododirutritoplatinite, 8. 523
dixnercuride, 4. 1039
dimetaphoBphate, 4. 663
396
disodium phosphate, 4. 661
disulphitotetramminocobaltatc, 10.317
ditritantimonide, 9 4()7
ditritaphosphide, 8. 843
� ditritarsenide, 9. 67
- extraction, 4. 421
ferric chloride, 14. 104
-_ disulphide, 14. 194
ferrite, 13. 918
� � ferrous hexachloride, 14. 35
sulphate, 14. 299
hoxahydrated, 7. 73
gold alloys, 4. 684
distannide, 7. 384
hemiamminochromate, 11. 28O
hemioxide, 4. 505
homiphosphide, 8. 843
heptadecaniminochloroplatinate, 16.
329 *
heptamminomotachloroantimonate, 9.
491
hexadecaboratodibromido, 5. 14O
hexadecaboratodichlonde, 5. 14O
470 GENERAL
9. 211
hoxaiodoplurnbite, 7. 778
hoxamminobromide, 4. 571
hexamminochloride, 4. 55O
hexamminoiodide, 4. 582
hexamminonitrate, 4. 656
hexamminopersulphato, 10. 479
hexamminosulphate, 4. 633
history, 4. 398, 404
� � hydrazinebromide, 4. 570
hydrazinechloride, 4. 551
hydrazineiodide, 4. 581
hydrazinohydrosulphite, 10. 287
hydrazin.osulph.ite, 10. 287
hydrobromide, 4. 57O
hydrofiuocolumbate, 0. 872
hydroiodide, 4. 58J
- hypophosphite, 8. 885
iodato, 2. 351
atnmino-, 2. 351
iodide, 4. 574
iodobismuthito, 9. 677
iron alloys, IS. 545
-��� isotetrahydroborododecatungstate, 5.
HO
lithium alloys, 4. 668
trichloride, 4. 554
941
oxybromitlo, 4. 894
oxynitrato, 4. 998
� tetrabromide, 4. 894
� _ . tetraiodide, 4. 94O
_ _ � tetrammmototraiodido, 4. 923,
941
mercuridos, 4. 1039
mercury, 1. 520
metaborato, 5. IOO
metaoolumbato, 9. 866
hemiheptahydrate, 9. 866
metantimonate, 9. 456
hexahydrato, 9. 456
,� pen tally dra to, 9. 456
metarsenato, 9. 182
- metasilicate, 6. 441
trihemihydrated, 6. 442
-� metavanadate, 9. 774
molybdate, 11. 562
molybdenum alloys, 11. 523
�monantimonide, 9. 407
� monoamminochlorido, 4. 551
monohydroxide, 4. 505
monomercuride, 4. 1039
monothiophosphate, 8. 1069
INDEX
429
trisethylenediaminochloride, 16.
417
trisethylenediaminoiodide, 15.433
nickelous sulphate, 15. 476
nitrate, 4. 650
basic, 4. 655
dihydrated, 4. 651
enneahydrated, 4. 651
tetrahydrated, 4. 651
nitride, 8. 107
nitrite, 8. 490
nitrohydroxylaminate, 8. 306
occurrence, 4. 404
octoborate, 5. 1OO
octofluozirconate, 7. 142
octomolybdate, 11. 597
officinalis, 6. 442
or t hoar seriate, 9. 182
orthoarsenite, 9. 127
orthodisulphomolybdate, 11. 652
orthophosphate, 4. 659
orthosilicato, 6. 440, 444
orthosulpharseriate, 9. 321
orthosulphoantimonito, 9. 543
oxalatodinitritohexamminocobaltiate,
8. 510
oxide, 4. 506, 508
��- properties, chemical, 4. 515
physical, 4. 5IO
oxychlorides, 4. 546
oxychromate, 11. 280
oxydibromide, 4. 569
oxydiiodide, 4. 580
oxynitrite, 8. 490
oxyorthosilicate, 6. 444
oxypyrophosphorylchlorido, 8. 1028
palladium alloy, 15. 648
paratungstate, 11. 819
pentafluoferrate, 14. 8
pentafluovanadite, 9. 797
pentahemimercuride, 4. 1039
pentamminochloride, 4. 55O
pentamminochromate, 11. 28O
pentapermanganite, 12. 278
pentasulphide, 4. 608
perchlorate, 2. 400
periodate, 2. 414
permanganate, 12. 335
hexahydrate, 12. 335
permonosulphomolybdate, 11. 653
peroxides, 4. 521, 530
pervanadate, 9. 795
phosphate, 4. 658
phosphatohemipentamolybdate, 11.
669
phosphatohexatungstate, 11. 873
phosphide, 8. 843
phosphite, 8. 916
platinum alloy, 16. 207
polybromide, 4. 581
polyiodide, 4. 581
potassamide, 8. 261
GENERAL INDEX
bromoaurate, 3. 607
bromocuprates, 3. 2OO
bromoiodide, 2. 61O
thiocarbonate, 6. 127
thiohypophosphato, 8. 1063
thiopyrophosphate, 8. 107O
-- triamminobromidc, 4. 57 1
bromostannate, 7. 456
triamminochloridc, 4. 550
tnarsenatototi'avanadatc, 9. 2Ol
�� pontaiodide, 4. 583
triarsenide, 9. 67
tetrabronude, 4. 572
�� tetrachloride, 4. 558
tetraiodide, 4. 583
tribromido, 4. 572
trioxydinitrate, 4. 655
ootohydrated, 4. 655
carbide, 5. 847
trioxysulpharsenate, 9. 329
carbonate, 2. 725
triphosphate, 4. 664
physical, 2. 747
� triterohexavanadate, 9. 774
- �� chlorate, 2. 326
preparation, 2. 528
ultramarine, 6. 59O
Caesium chlorotitanito, 7. 77
chromate, 11. 259
chromic selenate, 10. 876
-� diiododinitritoplatinite, 8. 522
dimorcuric pentaiodide, 4. 934
diuiercunde, 4. 1015
dioxide, 2. 487
diphosphate, 2. 862
492
dodeeamoreuride, 4. 1015
enneabromodiporrhodate, 15. 581
enneabromodithallate, 5. 453
enneachlorodiantimonite, 9. 481
enneachlorodiarsenite, 9. 244
enneachloi'odibismuthite, 9. 667
onnoachlorodithallato, 5. 446
enneaiododiantimomte, 9. 502
� enneaiododibismuthite, 9. 677
enneanitritodibismuthite, 8. 499
ferrate, 18. 934
ferric alum, 14. 345
ohlorobromide, 14. 77
decachloride, 14. 103
dichlorotribromide, 14. 125
disulphate, 14. 345
dodecachloride, 14. 103
hexachloride, 14. 103
octochloride, 14. 103
pentabromide, 14. 125
. tetrachloride, 14. 32
trichloride, 14. 32
fluoborate, 5. 127
fluogermanate, 7. 269
fluoride, 2. 512
fluoroperiodates, 2. 417
fluorophosphate, 2. 851
fluosilicate, 6. 947
fluostannate, 7. 423
fhiosulphonato, 10. 685
-� fluotitanate, 7. 72
fiuozirconato, 7. 141
gallium selenate, 10. 870
hemimercuride, 4. IOin
hemipcntaphosphido, 8. 835
- hexabromohypoantimonato, 9. 496
hexabromoiridato, 15. 777
hoxabromoplumbite, 7. 752
� hexaehloroindate, 5. 4OO
-- hexachlorolanthanato, 5. 642
hexachloroplumbite, 7. 73O
hexachlorotellurite, 11. 1()2
- -� hexafmoaluminate, 5. 307
hexafluocolumbate, 9. 872
hexafluoplumbato, 7. 705
hexafluotaixtalate, 9. 916
� � hexahydroarsenatoctoclccainolybdate,
9. 211
hexaiodotellurite, 11. 1<>6
hoxamorcuride, 4. 1OJ 5
hoxasulphidc, 2. 631, 64O
history, 2. 422
hydrocarbonate, 2. 774
hydronitrate, 2. 821
hydroxytetrafiuoride, 9. 504
Jhydrosulphite, 10. J 82
icosifluotantalate, 9. 918
iodato, 2. 333
iodato-pci-iodate, 2. 408
� � iodide, 2. 596
� carbonate, 4. 37O
ehlorido, 4. 308
ehromate, 11. 277
perothoeolumbate, 9. 870
Helena to, 10. 864
sulphate, 4. 34O
thiosulphate, 10. 545
chlorodibromido, 4. 893
_ di bromodi iodide, 4. 934
� <iiehlorodibromide, 4. 893
� dichlorodiiodide, 4. 935
. _ _ nitrate, 4. 997
_ octoiodido, 4. 934
� -��- pentabromide, 4. 893
pentaiodide, 4. 934
. _ totrabromide, 4. 893
. totraiodido, 4. 934
tribromide, 4. 893
_ tnbromodiiodide, 4. 934
� triehlorodibromidf, 4. 893
_ trnodide, 4. 934
metaehloroantimonate, 9. 491
metaphosphate, 2. 867
� metasilieate, 6. 335
meta vanadate, 9. 766
molybdate, 11. 558
molybdenum dioxytetrachloride, 11 .
632
-� dioxy trichloride, 11. 632
_ . hexachloride, 11. 622
998
monomercuride, 4. 1Ol5
monosulphide, 2. 622
hydrated, 2. 624
2. 627
physical, 2. 624
monoxide, 2. 486
neodymium sulphate, 5. 658
nickel amminotrichloride, 15. 419
nitritobismuthite, 8. 513
� nitratoplumbite, 7. 866
nitride, 8. 99
nitrite, 8. 479
nitroxylchloroperruthenite, 15. 532
-� � orthododecacolumbate, 9. 865
orthododocatantalato, 9. 9Ol
orthohexaeolumbate, 9. 864
orthohexatantalato, 9. 902
orthopertantalato, 9. 914
orthophosphate, normal, 2. 847
properties, chemical, 2. 849
physical, 2. 848
osmiamate, 15. 728
oxypentabromocolumbate, 9. 88O
oxypentachlorocolumbate, 9. 879
oxypontachlorotungstate, 11. 849
oxypentafluocolumbate, 9. 874
paramolybdate, 11. 586
paratotrarsenate, 9. 155
pentabromide, 2. 588
pentabromoferrato, 14. 1 25
pentabromoindate monohydrated, 5.
4Ol
pentabromoperrhodite, 15. 581
� pentabromotungstitc, 11. 854
pentachloroaquoperrhodite, 15. 578
- pentaehlorocuprite, 8. 163
pentaehlorodimercuriate, 4. 859
pentachlorodiplumbite, 7. 73O, 752
pentachloroferrate, 14. 103
� hydrated, 5. 446
� pentaeosifiuoheptantimonite, 9. 465
-- pentafluoantimonite, 9. 465
� pentafluotellurite, 11. 98
� pentafluozirconato, 7. 14O
� pentaiodide, 2. 61O
� pentaiodoatannite, 7. 460
� pentamolybdatodisulphite, 10. 307
� pentasulphide, 2. 631, 638
� perborate, 5. 119
GENERAL INDEX
Cainosite, 5. 514
CaI, 11. 673
Calaom, 4. 402, 408
Calaito, 8- 733
sinter, 3. 814
Calcaria sulphuratostibiata, 9. 574
CaI car iu m spa turn, 6. 766
Calcaroni, 10. 14
Calcii hypojjhosphis, 8. 88<)
Calcimagnite, 3. 814
Calcimangite, 12. 149
Calcination, 1. 55, 68
Calciners, Brunton's, 7. 287
Oxland'H, 7. 287
Calcioforrite, 3. 623 ; 8. 733 ; 12. 529 ; 14.
411
Calciomalachite, 3. 274
(Uilciopahgorscite. 6. 825
Calciostrontianite, 3. 622, 834
Cal<-iothorito, 5. 514
Calciovolborthitc, 9. 715
CalciovorborUiite, 9. 767
Cahite, 3. 622, 814 ; 5. 530 ; 7. 896 ; 12. 267
�� - dolomitic. 3. 814
X-radiogram, 1. 641
Calcium, action on -water, 1. 135
� aluwiinates, 5. 29O
--� aluminatoferrite, 13. 920
677
� imidodisulphonate, 8. 654
� nickel nitrite, 8. 511
11. 873
trisulphate, 3. 811
analytical reactions, 3. 621
antimonious thiosulphate, 10. 553
antimonite, 9. 432
antimony alloys, 9. 405
sulphate, 9. 583
argentide, 4. 685
� arsenate, 9. 166
-� preparation, 3. 814
properties, chemical, 3. 839
physical, 3. 833
solubility, 3. 824
trihydrated, 3. 822
carbonatodiorthosilicate, 6. 365
carbonatosulphatometasilicate, 6. 365
carnotite, 9. 789
cerium alloys, 5. 606
phosphatOBilicate, 6. 820
silicozircatotantalate, 6. 859
chlorate, 2. 344, 345
hydrated, 2. 345
chloride, 3. 697 ; 13. 615
GENERAL, INDEX
hydrogen, 2. 303
BaCl8-SrCl2, 3. 72O
cuprous chloride, 3. 718
dihydrated, 3. 703
hexahydrated, 3. 704
hydrated, 3. 702, 703
lithium chloride, 3. 718
ISTaCl-KCl, 3. 720
preparation, 3. 697
properties, chemical, 8. 714
� chlorite, 2. 284
chloroaluminate, 5. 293
chloroarsenato, 9. 258
chloroarsonatoapatite, 9. 26O
chloroarsenatowagnorito, 9. 258
chloroaurato, 3. 595
chloroborate, 5. 44
ctilorochromato, 11. 398
chlorodihydrophosphato, 3. 902
chloroiridate, 15. 772
chlorornetasilicate, 6. 364
chloropalladate, 15. 673
chloropalladite, 15. 67O
chlorophosphate, 3. 869
chloroplatinate, 16. 327
� enneahydratc, 16. 327
� chlorostannito, 7. 433
- chlorotriorthoarsenate, 9- 260
chlorotriorthophosphato, 3. 896
ehl or o vanadate, vanadatowagneri to,
9. 809
chromate, 11. 267
chromatosulphato, 11. 450
chromito, 11. 198
cobalt alloy, 14. 532
cobaltic dodecanitrite, 8. 504
tetrasulphate, 3. 811
pyrovanadate, 9. 767
sodium arsenate, 9. 174
tungstate, 11. 818
vanadate, 9. 772
ouprate, 3. 149
cupric ammonium tetrasulphate, 3.
813
decachloride, 3. 719
disulphate, 3. 812
oxycarbonato-phosphate, 8. 897
dihydrated, 5. 88
hexahydrated, 5. 88
� a-totrahydratod, 5. 88
/3-tetrahydrated, 5. 88
diborylmetasilicate, 6. 448
diborylstannate, 7. 419
tllcoTiiim. aluxninohydroxytriorthosili
cate, 5. 5IO
cate, 6. 722
tetrorthotitanatosilicate, 6. 846
triorthosilicate, 6. 921
diferrous aluminohydroxydiorthosili
cate, 6. 919
dihydroantimonate, 9. 454
dihydroarsenate, 9. 172
dihydroarsenatotrimolybdate, 9. 208
dihydroarsenite, 9. 124
flibydrodeuterohoxavanadate, 9. 77()
dihydrodeutorotetraplurribate, 7. 700
dihydrodeuterotriplumbate, 7. 7OO
dihydrodiboryldiorthosilicate. 6. 449
� dihydrohypophosphate, 8. 937
dihydrophosphate, 3. 886
monohydrated, 3. 887
478 GENERAL,
1026
dihydroxymetasilicato, 6.
dihydroxytetraaluminium
cate, 6. 717
dihydroxythiocarbonato,
. dihydrated, 6. 126
� � diiodonitritoplatinito, 8.
� diiodotriarsonito, 9. 257
358
triorthosili6.
126
522
� -�
� �-�
-
�_
��
hoxorthosilicate, 6. 896
dimereuride, 4. 1032
dimotaphosj>hato, 3. 893
__ dihydratod, 3. 893
dioxide, 3. 666
dihydratod, 3. 668
diporoxy hydra to, 3. 668
hydroxy hydra to, 3. 671
ootohydratod, 3. 668
dioxyaluminium diorthosilicato, 6dipormanganite,
12. 277
disiluido, 6. 176
disilicodmitrido, 8. 115
dithioiiate, 10. 588, 592
dithiophosphate, 8. 1068
713
dititanatohoxarnetantimonito, 9. 433
ditritasihcide, 6. 177
-- ferrodiboryldiorthosilicate, 6.
forroheptamtrosyltrisulphide,
silicate, 6. 911
chlorides, 14. 33
mesozirconate, 7. 136
metasilieato, 6. 915
orthosilicate, 6. 908
phosphate, 14. 395
phosphatosilicatos, 6.
826
327
227
450
8. 442
borato
INDEX
-
�
hexahydroxysulphido, 3. 757
hexahydroxythiocarbonate, 6. 1 25
hoxaiododiplumbite, 7. 777
hoxametaphosphate, 3. 895
hexaramine, 8. 248
� hexamminobromido, 3. 73O
hexamminochloroplatinate, 16. 327
hexamminoiodide, 3. 737
hexantimonite, 9. 432
hoxantipyrinopermanganato,
hoxasulphitodicobaltate, 10.
hoxerohexadocavanadate, 9.
hexerohexaphosphate, 8. 992
history, 3. 619
12. 334
315
771
hydrazinodisulphinate, 8. 682
hydrazinomonosulphonate, 8. 683
hydride, 8. 649
� hydroarsenato, 9. 169
dihydrate, 9. 169
monohydrate, 9. 169
hydroarsenite, 9. 124
hydrocarbonate, 3. 843
hydrodisulphate, 3. 783
hydrofluoride, 3. 694
hydrohyposulphite, 10.
hydroimidodisulphonate,
hydrophosphate, 3. 880,
colloidal, 8. 882
dihydrated, 3. 882
sosquihy drated, 8.
hydroselenido, 10. 775
183
8. 654
882
882
GENERAL, INDEX
hydroxyhexaphosphate, 3. 903
hydroxyhydrosulphide, 3. 755
hydroxyhypochlorites, 2. 272
hydroxylamito, 8. 29O
hydroxymetasulphoantimonite,
hydroxynitrate, 8. 861
�r� hydroxyn.itrilodisulphon.ato, 8.
hydroxyphosphate, 3. 902
hydroxythioearbonato, 6. 115
hypoantimonate, 9. 437
hypohromite, 2. 273
hypocshlorito, 2. 272
hypoiodito, 2. 273
hyponitrite, 8. 414
tetrahydrate, 8. 414
hypophosphato, 8. 937
� hypophosphite, 8. 883
hyposulphite, 10. 182
hemitrihydrate, 10. 1 82
hypovanadatodecavanadate, 9.
9. 542
676
793
hypovanadatophosphate, 9. 826
_ . hypovanadatovanadato, 9. 77O
imide, 8. 26O
iodatachromato, 11. 270
iodate, 2. 347
.� hydrated, 2. 347
__ iodide,'3. 734
hexahydrated, 3. 735
iodoarsonatoapatite, 9. 263
iodoborate, 5. 44
iodochloride, 3. 738
� iodophosphate, 3. 897
iodoplatinate, 16. 39O
iodotriorthoarsenate, 9. 263
433
phosphatomolybdate, 11. 671
sulphatohydrosilicate, 6. 89O
sulphide, 7. 797
tlihydratod, 6. 359
� � hernihydratod, 6. 359
__� � hemipentahydrated, 6. 360
�_ homitrihydrated, 6. 359
� � hydratod, 6. 358
pentitahydrated, 6. 36O
metaHulpharsonatoxymolybdato, 9.331
metai-mlpharKonite, 9. 296
iiietaHiilphoctarseriite. 9. 296
inetanulphoonncarsenito, 9. 296
riif�tatetrarsemte, 9. 124
� uietatitanate, 7- 52
metatungstate, 11. 825
metavanadato, 9. 769
totrahydrato, 9. 769
trihydrato, 9. 769
� � metazirconate, 7. 136
inolybdtite, 11. 56O
-�� - molybdenum oxytotrabromidc, 11. 638
monomctaphosphate, 3. 893
__� monosilicido, 6. 176
monosulphide, 3. 740
� � monothiophosphato, 8. 1069
monoxide, 3. 653
nickel alloys, 15. 205
arsenate, 9. 231
� . � physical, 3. 856
_ solubility, 3. 85O �
tetrahyd rated, 3. 85O
trihydrated, 3. 850
nitratosihcododecatungstatc, 6. 877
nitride, 8. 101
nitrite, 8. 485
nitritoperosmito, 15. 728
mtrohydroxylaminate, 8. 305
occurrence, 3. 622
octamminochloride, 3. 716
octerohoxaphosphato, 8. 992
octoborate dodeeahydratod, 5. 93
oniieahydratod, 5. 92
� � octobromoaluminato, 5. 326
� -- octochlorodithallate, hexahydrated,
5. 447
octodecachlorototraaluminate, 5. 322
� - octomercuride, 4. 1032
octotnolybdate, 11. 596
orthoarsenate, 9. 167
� � orthoarsenite, 9. 124
orthoborate, 5. 87
� orthoboratodichloride, 5. 141
� orthocolumbato, 9. 865
ox-thodiplumbato, 7. 700
orthodisilicate, 6. 364
orthoferrite, 13. 911
orthopentantalate, 9. 914
orthophosphate, 3. 866
�� colloidal, 3. 866
tetrahydrated, 7. 699
orthopyrophosphate, 3. 892
orthosilicate, 6. 347, 351
a-, 6. 352
P-, 6. 352
0'-, 6. 352
y-, 6. 352
monohydrated, 6. 358
trihydrated, 6. 359
orthostannate, 7. 419
orthosulpharsenate, 9. 32O
orthosulpharsenite, 9. 295
orthosulphoantimonate, 9. 574
orthosulphoantimonito, 9. 542
orthovanadate, 9. 768
osmate, 15. 706
oxide, higher, 3. 666
magnosia-alumino, 5. 295
properties, chemical, 3. 663
physical, 3. 660
oxides, 3. 652
oxy&wchromate, 11. 269
oxybisphosphoryl trichloride, 8. 1026
oxybromide, 3. 73O
oxy chloride, 3. 716
oxychloroplatinatos, 16. 333
oxychromate, 11. 269
oxychromite, 11. 198
oxyhoxaphosphate, 3. 904
oxyiodide, 3. 738
oxymetaferrite, 13. 911
oxynitrate, 3. 853
dihydrated, 3. 853
homihydrated, 3. 853
trihydrated, 3. 853
ternary, 3. 866
tribasic, 3. 866
phosphates, 3. 864
phosphatoetotungstate, 11. 872
phosphatodeeatungstate, 11. 87O
phosphatohexatungstate, 11. 872
phosphatosilicate, 6. 364
phosphatosilicatos, 6. 826
phosphatozireonate, 7. 165
phosphide, 8. 841
phosphite, 8. 914
platinum alloy, 16. 205
plumbide, 7. 614
� plumbito, 7. 668
- poly bromide, 3. 73O
�� polyiodide, 3. 737
- polyplumbate, 7. 699
� - aluminium trimesodisilieate,
746
ammonium disulphato, 3. 812
� � arsenate, 9. 173
carbonate, 3. 845
� chromate, 11. 269
� � _ dihydrate, 11. 269
-� - deuterotetravanadate, 9. 771
_ _ � pentacarbonate, 3. 845
perorthocolumbatc, 9. 870
phosphate, 3. 877
phosphatohomipontamolybdato,
11. 669
phosphatoplumbate, 7. 886
phosphatostannato, 7. 483
phosphatothorate, 7. 253
phosphatotitanate," 7. 97
pyrophosphate, 3. 892
-- quinquaraonochrornate, 11. 27O
hemi hep tally drate, 11. 27O
selenate, 10. 862
seximonochromate, 11. 27O
sodium carbonate, 3. 845
sulphatochromates, 11. 269
thiosulphate, 10. 544
tribromide, 3. 732
trichloride, 8. 719
trisulphate, 8. 806
preparation, 8. 626
VOL. XVI.
physical, 3. 631
pyroantimonate, 9. 455
pyroarsenate, 9. 17O
pyroarsemte, 9. 124
pyrocolumbate, 9. 865
-� pyrophosphate, 3. 891
tetrahydrated, 3. 891
- pyrosulpharsenate, 9. 32O
� pyrosulpharsenatoxymolybdato, 9. 331
pyrosulpharsenate, 9. 295
pyrosulphoantimonite, 9. 542
pyrosulphate, 10. 446
- pyrotantalate, 9. 903
-� pyrotellunte, 11. 8O
pyrovanadate, 9. 769
dihydrate, 9. 769
__ . enneahydrate, 9. 769
-� rare earth eolumbato tantalate, 9. 904
orthocolumbato tantalate, 9.
904
relations Ba, Sr, 3. 907
rubidium disulphate, 3. 810
-� sesquisilicate, 6. 347
-� silicate hydra tod, 6. 358
-� silicide, 6. 176
-� silicozirconates, 6. 855
socialites, 6. 583
._ � sodium aluminium sulphatotriorthosilicate,
6. 584
and aluminium fluorides, 5. 308
_ -. arsenate, 9. 173
carbonate, 3. 866
dihydroxytotrasulphato, 3. 806
� hexafluoaluminate hydrated, 5.
309
� _ hexametaphosphato, 3. 895
hoxarsenato, 9. 173
_ � hydrotrimotasilicate, 6. 367
imidodisulphonate, 8. 654
magnesium fluoaluminate. 5. 309
manganese hydrotrimetasihcate ,
6. 9OO
2 I
482 GENERAL INDEX
� iron deuterohexacolumbate, 9.
905
titanocolumbate, 9. 905
� metacolumbate, 9. 904
red, 12. 98
titanocolumbate, 9. 906
�� pentafluorido, 12. 79
� uses, 3. 644
vanadatobromowagnerito, 9. 813
� � vanadatopyromorphito, 9. 827
vanadatotungstate, 9. 787
vanadvltriflvioride, 9. 8Ol
wagnorito, 3. 897, 902 ; 4. 388
INDEX 483
6. 369
(tetra)calcium decarborate, 5. 89
dialuminate, 5. 29O
� hexaluminate, 5. 292
hexaplumbic dihydroxytriorthosilicate,
6. 888
(tri)calcium decaborate enneahydrated, 5.
91
decaluminate, 5. 293
dialuminate, 5. 291
ferrous tetramotasilieate, 6. 405
imidodisulphonate, 8. 654
magnesium orthosilicate, 6. 409
Big, 1. 699
Oram, 1. 699
Kilogram, 1. 699
Pound, 1. 699
Calorito, 15. 245
Calotype process, 3. 416
Calvonignite, 12. 266
Calvptohte, 6. 857 ; 7. IOO
Calx, 1. 55
antimonii alba, 9. 452
clota, 9. 42O
martis phlogisto juncta, 14. 390
plumbi acrata, 7. 846
dulcis, 7. 856
Campylite, 9. 4, 261, 262
Camsellito, 5. 97 ; 6. 451
Canaanito, 6. 409
Canal rays, 5. 42, 47
Canbyite, 6. 908 ; 12. 529
Cancrinite, 6. 58O
lime, 6. 582
Candite, 5. 297
Canfieldite, 7. 275, 283
Canizzarite, 9. 694
Cannizzarite, 9. 692
Canton's phosphorus, 8. 74O
Capacity factor of energy, 1. 712
Capillary electrometer, 1. 1Ol6
Capillose, 15. 435
Capnite, 4. 643
484 INDEX
442 history, 6. 94
Carbascot-silicium, 8. 115 occurrence, 6. 94
history, 5. 70
arsenide, 9. 68 �
� hydrosulphide, 6. Ill
hydrosulphotrisulphonate, 6. 92
_____ oeto-, 6. 51
self-oxidation, 5. 812
_ ilx air, 8. 7 87
sesquisulphide, 6.
natural waters, 6. 6, 51 silicide, 5. 875
occlusion in solids, 6. 57 silicides, 6. 186
occurrence, 6. 2 solubility in iron, 12. 809
properties, chemical, 6. 61
sulphotelluride, 11. Il l
, INDEX 485
tetritasulphide, 6. 87 Carynite, 9. 4
Cathode, 1. 03
rays, 4- 25
Cation, 1. 93
Cat's-eye, 4. 206 ; 6. 139, 913
Cause, 1. 13, 57
Caustic alkali, 2. 495
alkalies, 2. 421
lime, 3. 619, 653
Caustification, 2. 497
ionic theory, 5. 498
molecular theory, 2. 498
Solway's, 2. 36
Sueur's, 2. 35
Cellaring' receiver, 2. 163
Cellular structure metals, Quincke's theory,
1. 603
Colsian, 6. 662, 698, 706
Oolsite, 14. 542
Oeltia, 5. 706, 708
Celtium, 5. 498, 708 ; 7. 166
hydroxide, 5. 708
oxide, 5. 708
Cement, 6- 553
British, 6. 554
clinker, 6. 554
copper, 3. 30
Kneno'B, 3. 776
Mack's, 3. 776
Parker's, 6. 554
- plasters, 3. 775
Portland, 6. 554
-� ltoman, 6. 554
Scott's selenitic, 3. 776, 800
steel, 12. 753
Cementation, 3. 3O ; 12. 736
iron, 12. 736
process gold parting, 3. 508
steel, 12. 736
isolation, 5. 55O
preparation, 5. 587
Ceric ammonium dihydroctodecamolyb
colloidal, 5. 632
hydrosol, 5. 632
hydroxynitrate, 5. 672
iodate, 2. 354
lanthanum sulphate, 5. 662
magnesium nitrate, 5. 674
manganous nitrate, 12. 446
molybdate, 11. 564
-� neodymium sulphate, 5. 662
nickel nitrate, 15. 492
nickelous decafluoride, 15. 405
nitrate, 5. 672
octodecaohromite, 11. 2Ol
oxide, 5. 629
oxycarbonates, 5. 666
oxychloride, 5. 64O, 641
oxy sulphate, 5. 662
oxytetrasulphate, 5. 661
pontitadichromito, 11. 2OO
perchlorate, 2. 402
potassium nitrate, 5. 673
sulphate, 5. 662
praseodymium sulphate, 5. 662
pyrophosphate, 5. 676
rubidium nitrate, 5. 673
selemte, 10. 831
silver dodecamolybdate, 11. 6OO
sulphate, 5. 662
sodium dodecamolybdate, 11. 6OO
sulphate, 5. 662
sulphate, 5. 661
tetrachromite, 11. 200
thallium sulphate, 5. 662
tritoctochromite, 11. 20O
zinc nitrate, 5. 674
Cerine, 5. 509
� __ � _ orthophosphate, 5. 675
sulphate, 5. 65S
sulphite, 10. 3<>2
pyroarwenite, 9. 297
pyrophosphate, 5. 675
pyroBulpharsenato, 9. 322
sulphate, 5. 657
_ sulphite, 10. 302
usta. 7. 673
Cerussite, 7. 49J, 829
Cervantito, 9. 343, 435
Cosarolite (or Cesarolite), 12. 149, 267, 279
Coylonite, 5. 297
Chabasin, 6. 729
Chabasite, 6. 729
silver, 6. 683
Chabazite, 6. 575
ammonium, 6. 733
barium, 6. 733
magnesium, 6. 733
natron, 6. 734
potassium, 6. 733
sodium, 6. 733
thallo-, 6. 826
Chacal, 5. 714
Chain reactions, 16. 152
Chalcanthite, 3. 7, 234
Chalcanthites, 4. 639 ; 12. 403
Chalcanthon, 14. 242
Chalcedony, 6. 139
Chalcites, 14. 243
Chalcitis, 3. 3 ; 14. 243
Chalcocite, 3. 7, 2lO
Chalcodite, 6. 624 ; 12. 529
Chaleolamprite, 6. 829 ; 7. 3, 1OO ; 9. 839
Chalcolite, 12. 2, 4, 133
Chalcolithite, 3. 8
Chalcomonite, 10. 694. 823
Chalcomiklite, 14. 189
Chalcomorphite, 6. 362
Chaloophat-ite, 9. 186
Chalcophanito, 12. 149
Chalcophyllite. 9. 4, 162
4IO
Chalcostibnito, 3. 7
Chalcotriehite, 3. 117
Chaldea, 1. 20
Chalitito, 6. 709
Freneh, 6. 43O
Chalkornelan, 3. 131
Chalkostibit, 9. 536
Chalybinglenz, 9. 546
crystals, 8. 696
Chamoisite, 6. 623
\u INDEX 489
Chemistry, Kgypt, 1. 24
Grecian, 1. 29
Hindu, 1. 22
history of, 1. 1
Indian, 1. 21
language, 1. 114
�-� mythological, 1. 2
Ti omenclature, 1. 114
object of, 1. 11
origin of term, 1. 43
Persian, 1. 2O
- philosophical, 1. 3
Phoenician, 1. 28
pneumatic, 1. 122
prehistoric, 1. 19
Roman, 1. 37
- Syrian, 1. 4O
Cheneviscite, 9. 4, 227
Chonovixite, 12. 529
Cherokine, 7. 883
Chert, 6. 14O
Cherzolite, 11. 199
Chessylito, 3. 274
Chesterlite, 6. 663
Chhilua, 2. 808
Chiastolito, 6. 458
Childrenite, 5. 155, 370 ; 8. 733 ; 12. 149,
529; 14. 397
Chiloite, 9. 715, 778 ; 13. 877
Chilenite, 9. 635
Chilinite, 9. 589
Chill cast pig iron, 12. 596
Chillagito, 7. 491 ; 11. 678, 793
China, 1. 22
bone, 6. 515
� � clay, 6. 467
� rock, 6. 467
� ironstone, 6. 515
silver, 15. 209, 210
Chinese rod, 13. 782
- white, 4. 507
Chinkolobaroito, 6. 883
Chinkolobwe, 12. 52
Chinkolobwite, 12. 4, 52
Chiolite, 2. 1 ; 5. 154, 303, 305
Chiviatite, 7. 491 ; 9. 589, 695
Chladnite, 6. 392
Chloanthite, 9. 4, 76, 81 ; 15. 5, 9
Chloracetio acid and hydrogen, 1. 303
Chloral hydrate and hydrogen, 1. 304
Chlorargyrite, 3. 39O
Chlorastrolite, 6. 718
Chlorates, 2. 296
detection, 2. 319
preparation, 2. 297
-�� electrolytic process, 2. 298
properties, 2. 305
uses, 2. 319
Chloratosodalite, 6. 583
Chlorazido, 8. 336
Chloric acid, 2. 296
� constitution, 2. 32O
_ � preparation, 2. 296, 299
� � properties, 2. 305
Chlorides acid, 2. 219
_._ complex, 2. 228
detection, 2. 209
preparation, 2. 214
properties, 2. 217
thermochemistry, 2. 218
49O GENERAL INDEX
Acker's process, 2. 36
active, 2. 156
chemical reactions, 2. 90
Deacon's process, 2. 31
dioxide, 2. 286
� acid soln., 2. 82
� organic solvents, 2. 84
_ SfXit soln., 2. 82
water, 2. 71
sulphur dioxide, 1. 518
tetroxido, 2. 287
trioxido, 2. 281
uses, 2. 96
valency, 2. 108
water, 2. 71
Weldon and Peehiney's process, 2.
34
Weldon'H process, 2. 28
Chlorinization gold, 3. 507
Chlorite, 4. 251 ; 6. 621
ferruginouse, 6. 624
iron, 6. 624
mica, 6. 622
spar, 6. 620
-� talc, 6. 622
Chloritis, 6. 621
Chloritite a-, 6. 624
Chloritoid, 6. 62O ; 12. 529
Chloroaluminates, 5. 321
Chloroamide, 8. 604
Chloroamine, 8. 604
strontium, 8. 902
Chloroaquomolybdous acid, 11. 617
Chloroaquototrammines, 11. 403
Chloroaquotungstous acid, 11. 841
barium, 6. 733
sodium, 6. 733
Chlorochroite, 2. 657
Chlorochromates, 11. 397
Chlorochromic acid, 11. 397
and CO8, 6. 32
Chlorogeri, 2. 268
Chlorohydrosulphurous acid, 10. "686
Chlorohypoazotiquc acid, 8. 618
Chlorohypomanganites, 12. 378, 379
Chloriodides, 2. 237
Chloromagnesite, 4. 298
Chloromanganites, 12. 379
Chloromanganokalite, 12. 149, 367
Chlorornarialito, 6. 764
Chloromelano, 6. 623
Chloromelanite, 6. 643
Chloromercurates, 4. 848
Chloromereurichloroacetvlene, 5. 869
Chloromolybdates, 11. 634
Chloronitrie acid, 8. 541, 618
Chloronitrous acid, 8. 618
Chloropal, 6. 906 ; 12. 529
16. 375
Chlorophoenicite, 9. 221, 222
Chlorophyll, 6. 12
Chlorophyllite, 6. 811
GENERAL, INDEX
anhydride, 2. 281
Chloro-wagnorite, 4. 388
Chloroxiphite, 7. 743
Chlorozirconates, 7. 143
Chlorozone, 2. 268
Chlorure de soufrobiammoniacal, 10. 646
diopside, 6. 41O
iron ore, 11. 123 ; 12. 529
ochres, 6. 865 ; 11. 185
ore, 11. 123
red, 11. 283
spinel, 5. 154 ; 11. 199
tin pink, 7. 421 ; 11. 29O
tourmalines, 6. 742
478
hexaehloride, 11. 417, 418
pentachlorido, 11. 418
anhydride, H . 211
aquoehlorototrainriiinochromate, 11.
306
aquochlorotetramininod ichlorotriamercurichloride,
11. 419
aquopentainminobromoplatinatc, 16.
379
aquopontatmnitiodithiotiato, 10. 595
_ aquopentamzriinohydrotetranitratc,
11. 476
414
bromodiaquotriaiiiininodibromide, 11.
424
bromodiaquotriamminodichlorido, 11.
424
bromodiaqxiotriamminosulpliate, 11.
466
bromopentamminobromoplatinate, 16.
379
INDEX
Chromic decahydroxytetramminosulphate,
11. 467
docarnrninodihydroxydithionate, 10.
596
decamminohydroxydithionate, 10. 596
diaxnmines, 11. 406
dianiminodihydroxydinitrate, 11. 478
diamminohydr oxide, 11. 189
diamminonitrate, 11. 409
d iamminopentahy droxy nitrate, 11. 478
�-� diamminoxalate, 11. 409
cis - d iaquobisothylonediaminotribro mido,
11. 424
trans-salt, 11. 424
cis - diaquobisethy lenedi amminotri chloride,
11. 412
trans-salt, 11. 412
diaquototramminohydrotetranitrate,
11. 477
diaquotetramnjinotribromide, 11. 423
diaquototramminotrichloride, 11. 411
-� dibromoaquotriamrninobromide, 11.
425
dibromoaquotriamminoiodido, 11. 428
dibrornoaquotriamminonitrate, 11. 477
dibromoaquotriamminosulphate, 11.
466
cia-dibromobisethylenediaminobromide,
11. 425
trans-salt, 11. 425
�- dibromobisethylenediaminobromomorcuribromide,
11. 425
cis - dibromobisethy lenediaminodithio nate,
10. 596
*/"�w.�-dibromobisethylenediaminodithionato,
10. 596
__ ds - dibromobi se thy lenediaminoiodide,
11. 428
� trans-salt, 11. 428
----trans- dibromobisethy lenediami nonitrate,
11. 478
dibromodiaquodiamrninobromido, 11.
425
dibromodiaquodipyridinobromide, 11.
425
dibromodiaquodipyridinoiodido, 11.
428
dibromodiaquodipyridinonitrate, 11.
478
� dibromohexaquobromide, 11. 422
� � dibromotetraquoaluminohexaquodisulphate,
11. 468
-��� dibromotetraquochloride, 11. 425
-� dibromotetraquochromihexaquodisulphate,
11. 468
��- dibromotetraquoferrihexaquosulphate,
11. 468
dibromotetraquosulphate, 11. 466
dibromotetraquovanadihexaquodisulphate,
11. 468
dichloroaquotriamminochloride ,11.415
dichloroaquotriamminochl oroiridate,
15. 772
dichloroaquotriamminoiodide, 11. 428
� dichloroaquotriamminonitrate, 11. 478
dichloroaquotriamminosulphate, 11.
466
c*s-dichlorobisethylenodiaminobromide,
11. 425
trans-salt, 11. 425
GENERAL, INDEX
Chromic cis-dichlorobisethylenediamminochloride,
11. 415
trans-salt, 11. 415
cis- d ichlorobisethy lenediairiinochloroantimonato,
11. 42O
cis- dichlorobisethy lenediamindoithio nate,
10. 596
ci�-dichlorobisethylonediaminohydrosulphate,
11. 466
cis-dichlorobisethylenediaminoiodide,
11. 428
ci�-dichlorobisethylenediaminonitrate,
11. 478
trans-salt, 11. 478
<rari.�-dichlorobisethylendiaininodithionate,
10. 596
diehlorodiaquodiamminochlorido, 11.
415
-� d ichlorodiaquodipy ri di nobromide, 11.
425
dichlorodiaquodipyridinoehloride, 11.
415
� dichlorodiaquodipyridinonitrate, 11.
478
dichloronitrate, 11. 476
-� dichloroquatorothylenediamineehloroplatinate�
cis, 16. 331
trans, 16. 331
� dichlorotetramminoiodide, 11. 428
� diehlorototramminosulphate, 11. 466
dichlorotetraquoahmiinohoxaquodi
377
� � dihydrate, 11. 376
_ hexahydrate, 11. 377
diehlorotetraquochromihexaquodisulphate,
11. 468
diohlorotetraquohexaquosolonato, 10.
877
cliehlorotetraqviovanadihexaquodisulphate,
11. 468
dihydroheptasulphate, 11. 446
� dihydroxydiaquodipyridinobromide,
11. 425
� dihydroxydiaquodipyridinochlorido,
11. 415
� dihydroxydiaquodipyridinoiodide, 11.
428
� d ihydroxydiaquodipyridinonitrate, 11.
478
� dihydroxydiaquodipyridinosulphate,
11. 466
Chromic dihydroxydiaquoethylenediaminochloride,
11. 415
dihy d roxy d iaquoethy loned iara inoiodide,
11. 428
dihydroxy hexaceta to tripyridinonitrato,
11. 478
dihydroxyquaterethylenodiaminotetraiodide,
11. 428
11.' 478
trans-salt, 11. 478
dithiocyanatobisethyleriediaminobromide,
11. 425
ci#-dithiocyanatobisothvlenediaminochloride,
11. 416
trans-salt, 11. 416
cis-dithiocyanatobisethylenediaminohydrosnlpliate,
11. 466
-� trans-salt, 11. 466
dithiocyanatobisothylenediaminoiodomercuriiodide,
11. 428
dithiocyanatotetrammi nobromide, 11.
425
--� dithiocyariatototramminochloride. 11.
416
dithiocyanatotetramminonitrate, 11.
478
dithionate. 10. 595
-� ferric bromosnlphate, 14. 350, 353
- hexaearbamidodichromatopormanganate,
12. 336
- hoxacarbami dod isulph atodichromate,
11. 343
- hexaoarbamidonitratodichromate, 11.
343
GENERAL, INDEX
Chromic hoxacarbamidoperchloratodichro
- hexacetatodihydroxytripyridinoiodide,
11. 428
hexacotatodihydroxytrinpyrid ineohloroplatinate,
16. 33J
-� hexacetatohydroxyaquotripyridinochlorostannatc,
11. 419
--- hoxaethylanodiaimnehexahydroxydithionate,
10. 596
hexaethylenediaminohoxahydroxyahrornato,
11. 307
hoxahydroxysoxieBethylenediaminolioxaehloride,
11. 416
� hexahydroxysexiesethylenediaimrjohexaiodide,
11. 428
hexahydroxysoxiosethylonodiaminoh(
5xaiodomorcuriiodide, 11. 428
hexahydroxysoxiesethylenodiamiiiohexanitrate,
11. 478
haxahydroxysexiesathylonodiaminosulphate,
11. 467
hexaraminobromide, 11. 423
� hoxamtninobromoiridato, 15. 776
bexaniminobronioplatinate, 16. 379
haxamminochlorido, 11. 373
- hydroxycJilorohexamminochloroplatmite.
16. 284
haxarriTiiinohydrotetranitrate, 11. 476
hoxamminohydroxychloroiridate, 15.
772
haxamminoiodosulphato, 11. 468
hexammiiioriitratobrornoiridate, 15.776
hoxaninvmonitratoohloroperiridite, 15.
787
hexaniminoiwrmanganate, 12. 336
haxamrninophosphate, 11. 481
hexamminoselenate, 10- 877
hexamminosulphate, 11. 465
hcxamminosulphatobromoiridate, 15.
776
hexamminosulphatochloroiridate, 15.
785
bexamminotrichloride, 11. 41O
hexamminotrichloromercurichloride,
11. 419
hoxamminotriiodide, 11. 427
hexantipyridiiiodichromate, 11. 363
hexantipyrinoborofluoride, 11. 363
hexantipyrinopermanganate, 12. 336
hexaquochlorosulphate, 11. 468
hexaquofLuoride, 11. 363
Chromic hexaquosexiesethylenediaminohexabromide,
11. 425
hexaquotribromide, 11. 422
hexaquotrichloride, 11. 382, 412
hexaureanitrate, 11. 477
hydroxide, 11. 185
cis -hydroxyaquobisethylenediaminedithionate,
10. 595
� /raw^-hydroxyaquobisethylenediamminedithionate,
10. 595
ci#-hydroxyaquobisethylenediaminodibromide,
11. 424
trans-salt, 11. 424
16. 381
hydroxydecamminochloroplatinate,
16. 333
hydroxydecamminochlorotetraiodide,
11. 428
hydroxydecamminohydroxydichlorodnodide,
11. 428
hydroxydecamminohydroxytetrabro mide,
11. 425
hydroxydecamminopentaehloride, 11.
416
�� �- liydroxydecamminopontaiodide, 11.
428
hydroxydecamminoperitanitrate, 11.
478
hy droxy decamminosulphate, 11. 466
hydro xydecamminototrabromido, 11.
425
hydroxy diaquodipyr idinodichlori de,
11. 412
hydroxydinitrita, 11. 475
hexahydrate, 11. 475
hydroxylamine chloropentaquochlorosulphate,
11. 468
chloropentaquosulphatohydrosulphata,
11. 468
��� hydroxypontachlorido, 11. 391
hydroxypentamminobromide, 11. 424
� hydroxypentamminochloride, 11. 412
187
465
hydroxytriaquodipyridinosulphate, 11.
466
iodide, 11. 627
INDEX 495
hexamminopyrophosphate, 11.
482
selenate, 10. 876
� triorthoarsonate, 9. 204
stannato, 11. 29O
sulpharsonate, 9. 322
sulpharsenite, 9. 3OI
sulphate, 11. 435
465
tetraquodipyridinotribromide, 11. 412,
424
tetraquodipyridixiotrmitrata, 11. 477
thallous selenate, 10. 836, 876
c*"�-thioeyanatobisethylonodiamino
� thiocyaiiatopeutarnrninodibroiuide,
11. 424
thiocyanatoperitamminodichlorido,
11. 415
thiocyanatopentamminodichromato,
11. 343
thiocyanatopcntamniinodiiiitrate, 11.
477
thiopyrophosphato, 8. 1070
triamminochlorodibromide, 11. 425
tnamminodichlorobronude, 11. 425
trianuninotribroniide, 11. 425
triaquochloride, 11. 381
triaquotriaminiriodiehloronitrate, 11.
477
triaquotriamminotribromide, 11. 424
triaquotriamminotrichloride, 11. 411
11. 478
trioxysulphite, 10. 306
trioxytrisulphate, 11. 445
triphosphate, 11. 482
tripyridinochloride, 11. 373
trisethylenediamidoselenate, 10. 877
trisethylenediaminodichromate, 11.343
423
trisethylenediaminotriehloride, 11. 411
trisethylenediaminotriiodide, 11. 427,
428
trispropylenediaminotriiodido, 11. 427
vanadium dichlorodecaquodisulphate,
9. 825
voltaite, 14. 352
xantho-nitrites, 8. 498
463
ferric alums, 14. 350
triammino-oxalatochloride, 11.
417
antimonioctochlorido, 11. 372
aquo trill ydroxy dioldecamminothio
azide, 8. 354
beryllium pentachloride, 11. 419
bismuth alloys, 9. 639
borotungstate, 5. HO
GENERAL
amminocobalfciato, 8. 510
chromate, 11. 206, 2IO
chromates, 11. 306
cobalt alloys, 14. 538
dihydroxyazide, 8. 356
diiodide, 11. 427
dioxide, 11. 208
dioxyamide, 8. 266
dioxydichloride, 11. 391
dioxydifluoride, 11. 364
dioxyphosphochlorotribromide, 11.
395
dipentitacarbide, 5. 888
diselenite, 10. 836
disilicide, 6. 191
ditritaboride, 5. 29
ditritacarbide, 5. 888
ditritasilicide, 6. 191
electronic structure, 11. 169
erythro-salts, 11. 408
VOL. XVI.
INDEX 497
- hypophosphito, 8. 887
� � imides, 8. 266
iodato, 2. 358
iridium alloy, 15. 75O
iron alloys, 13. 586
� pontaborate, 5. 107
� pentammines, 11. 402
pentatungstato, 11. 829
pontahydrato, 11. 829
pentitadodecoxide, 11. 210
pentitatridocoxido, 11. 206, 210
pentitenneaoxide, 11. 206
ennealiydrato, 11. 207
pentoxysulphite, 10. 306
permanganite, 12. 28O
phosphates, 11. 479
phosphite, 8. 918
physiological action, 11. 163
platinates, 16. 248
platinum alloys, 16. 215
copper alloys, 16. 216
gold alloys, 16. 216
iron alloys, 16. 219
nickel-cobalt alloy, 16. 220
molybdenum alloy,
16. 220
silver alloys, 16. 22O
silver alloys, 16. 216
potassium hexaehloride, 11. 419
hexafluoride, 11. 364
oxypontachloride, 11. 391
pentachloride, 11. 418
pentafluoride, 11. 363
Chromium triamminodichloroaquoiodide,
11. 417
triamminodiehloroaquonitrate, 11. 417
triamminodichloroaquosulphate, 11.
417
�-� triainininotetr oxide, 11. 358
� triamminotriaquodichloroniti-ate, 11.
412
��� triarnininotriaquodihydroxy iodide, 11.
417
triamminotriaquotribromide, 11. 417
triamminotriaquotriperchlorate, 11.
412
triantimoniododecachloride, 11. 372
trichloride, 11. 371
trifluoride, 11. 362
trihydroxytotranitritodiplatinito, 8.
521
triiodide, 11. 427
� ennealiydrate, 11. 427
-� trioxide, 11. 211
�___ properties, chemical, 11. 229
395
trioxyphosphopontaehloride, 11. 395
trioxytrichloride, 11. 395
tripyridinotribromide, 11. 423
tritadinitrido, 8. 127
-� tritasilicide, 6. 191
� tritatetraoxide, 11. 175
. _ � -_ � monohydrate, 11. 175
trihydrato, 11. 175
tritatetrasulphido, 11. 433
- � - trithiophosphato, 8. 1067
tungstato, 11. 796
INDEX 499
Chromospinel, 4. 251
Chryscolla, 5. 7
GENERAL, INDEX
Chrysitine, 7. 638
Chrysitis, 7. 644
Chrysoberyl, 4. 206 ; 5. 154, 294 ; 7. 896
Chrysocollas, 3. 8 ; 4. 406 ; 6. 342
Chrysolite, 6. 385 ; 15. 9
Chrysolithos, 7. 98
Chrysophane, 6. 816
Ohrysophrase earth, 6. 933
Chrysopras, 6. 624
Chrysoprase, 6- 139
Chrysotile, 6. 422, 426
Chrysotylie acid, 6. 295
Chrystis, 7. 638
Chrysulca, 8. 556
Chvibutite, 7. 491
Chumbe Cianoo, 7. 797
Churchite, 5. 529
Chydraza'ino, 8. 223
chloride, 8. 223
chloroplatinate, 8. 223
nitrate, 8. 223
sulphate, 8. 223
Cider, 13. 615
Ciment eloctrique, 6. 559
fondu, 6. 559
noir, 6. 559
Cimolian earth, 6. 496
Cimolite, 6. 495
Cinchonidino bromoiridate, 15. 777
16. 273
hepatic, 4. 696
Indian, 4. 942
X-radiogram, 1. 642
Cinnabaris, 7. 673
Cinnabarite, 4. 696
Ciimamon-stono, 6. 715
Cipliyte, 3. 903
Ciplyte, 6. 835
Circumstantial evidence, 1. 90
Cirite, 7. 896
Clarkoite, 12. 4, 64
Clarus hyahnus, 7. 98
Claiidelite, 9. 4, 94
1. 971
Clausthalie, 10. 787
Clausthalite, 7. 491, 896 ; 10. 694, 787 ; 15.
592
Clay, 5. 531
blue, 5. 716
colloidal, 6. 487
physical, 6. 476
(see also China clay)
substance, 6. 473
true, 6. 473
� aquopentamm.inoirnidodis-ulph.onato,
8. 659
aquopentamminonitrilotrisulphonate,
8. 669
arsenate colloidal, 9. 229
hydrogel, 9. 229
atomic disruption, 14. 527
number, 14. 527
weight, 14. 525
auric hexamminochloride, 8. 595
pentamminonitratochloride, 3.
595
aut unite, 12. 135
azide, 8. 355
barium sulphide, 14. 757
62O
bismuth alloys, 9. 64O
nitrate, 9. 7IO
bloom, 9. 4, 228 ; 14. 424
blue, 14. 519
� boracite, 5. 140
boride, 5. 31
boron alloy, 14. 534
borotungstate, 5. Il l
bromato, 2. 360
; ammino, 2. 36O
bromide, X-radiogram, 1. 642
bromoplatinate, 16. 38O
bromostannate, 7. 456
bronze, 14. 519
cadmium alloys, 14. 533
ammino-, 2. 360
chloroantimonate, 9. 492
chloroaurate, 3. 595
chlorochromate, 11. 399
chloropentamminodihydrosulphate,
10. 448
chloroplatinate, 16. 284
chlorostannate, 7. 45O
chromic pentanuoride, 14. 608
chromite, 11. 204
chromium alloys, 14. 538
cobaltous trisethylenediaminoctochloride,
14. 658
colloidal, 14- 453
337
. lead alloys, 15. 337
zinc alloys, 15. 337
silicon alloys, 14. 536
644
diarsenatoctodecatungstate, 9. 214
diarsenide, 9. 76
1 : 6-diazidobisethylenediamine azido,
8. 355
1 : 6-diazidobisethylenediamino chloroaurate,
8. 355
1 : 6-diazidobisothylenodiamiriochloroplatmate,
8. 355
diazidobisethylenediaminodithionate,
IO. 598
1 : 6-diazidobisethylenediamminonitrate,
8. 355
1 : 6-diazidobisothylenodiaminothiocyanate,
8. 355
1 : 6-diazidobisethylonodithionato, 8.
355
diazidotetramminodithionate, 10. 598
� � diazidotetramminonitrato, 8. 355
��� diazototramminodithionatc, 8. 355
� diazototramminoiodido, 8. 355
diborate, 5. 114
diboride, 5. 32
1 : 2-dichlorobisethy]enediamine azide,
8. 355
1 : 6-dichlorobisethylenediamine azido,
8. 355
dichlorodiethylenediaminoantimony
pentachloride, 9. 492
dichromate, 11. 344
ci�-diethylenediaminoaquohydroxydi
10. 598
diferride, 14. 545
dihydrazinohydrosulphite, 10. 315
dihydrazinosulphite, 10. 314
dihydride, 14. 508
dihydroantimonate, 9. 461
dihydroarsenatotrimolybdate, 9. 208
Cobalt e?>-dinitritotctramminoamidosulphonate,
8. 644
� <r�w*-dinitrototramminoamidosuli>honate,
8. �44
ci�-dinitritotetramminonitrilosulphonate,
8. 669
�ran�-dinitritotetramminonitrilotri-
Hulphonate, 8. 669
dinitrosyldecamminodinitratotetranitrate,
8. 443
� � d in itrosyldeoamminod i nitra totetraperohlorate,
8. 443
dinitroBylenneamininoiojiotetraoxalate,
8. 443
dioxide, 14. 598
dioxytetrafluomolybdate, 11. 614
dipentarsenido, 9. 75
� � cv#-dipropylenediarninodiehlorodithionate,
10. 59�
/r��.#-dipropylenodiaminodichlorodithionate,
10. 598
diselenide, 10. 8OO
disilicidc, 6. 208
disidphide, 14. 756
� � dithionate, 10. 597
� � hexahyclrato, 10. 597
� � � octohydrato, 10. 597
dithiophosphato, 8. 1068
ditritaphosphido. 8. 859
-. � ditritarsonide, 9. 73
ditritatulu-ide, 6. 209
ciitungstate, 11. 8JO
� � dodecamminohexahydroxydithionato,
10. 598
electronic structure, 14. 527
othylstannonate, 7. 41O
�� � extraction, 14. 433
-�� ferrate, 13. 936
ferroxis sulphoarsonitobismuthite, 9.
696
filaments, 14. 453
fluoberyllate, 14. 607
� heptaliydrate, 14. 607
� fluoborate, 5. 128
� fluorides, 14. 6()3
fluosilieate, 6. 957
fluotitanato, 14. 607
hexahydrated, 7. 73
fluovanadate, 14. 607
fluoxy vanadate, 14. 6OS
glance, 9. 4, 308 ; 14. 424
gold allov, 14. 532
green, 14. 519, 602
homiarsenide, 9. 75
bemiboride, 5. 32
� � hemionnealuminide, 14. 535
� hemiheptasulphide, 14. 752
� � hemihydrazinosulphite, 10. 314
heniipontaluminido, 14. 535
hemiphosphide, 8. 859
hemiselonidf^, 10. 800
hemisilicide, 6. 208
hemistannide, 14. 537
hemisulphide, 14. 753
bornitriarsenide, 9. 75
hemitrichromide, 14. 539
hermtrimolybdide, 14. 54O
hemitriphosphide, 8. 859
hemitriselenide, 10. 8OO
hemitritelluride tetrahydrat�, 11. 73
� hexahydroarsenatoctodecamolybdate,
9. 211
hexahydrodichloride, 14. 627
� � hexamminoamidosulphonate, 8. 644
hexamininochloroplatinite, 16. 284
hexamminochlorostannite, 7. 434
� � hexamminodihydroxynitrilomonosvilphonate,
8. 672
hexamminodisulphatopersulphato, 10.
480
hexamminof err oheptanitrosyltrisul pbide,
8. 442
hexamminofluoborate, 5. 128
hexamrainofluorido, 14. 605
� hexamminofluotitanate, 7. 73
hexamminoimidodisulphonate, 8. 659
� - -- hexanxminonitrilotrisulphonato, 8.
669
hexamminothiocarbouate, 6. 128
hexammainotrihydroxyditliionate, 10.
598
hoxamrninotrinitratoaquodihydroxydithionate,
10. 598
hexamminoxydiaqiiohydroxydithionate,
10. 598
� � hexaperrnanganito, 12. 28O
---- hexitapentasulphidc, 14. 75O
� - hexitatungstide, 14. 541
� higher oxides, 14. 598
history, 14. 419
� � hydrazinohydrosulphito, 10. 315
hydroarsenato vanadate, 9. 2OO
� � hydrochloride, 14. 628
hydrofluocolumbate, 9. 872
� -� hydrofluorido, 14. 605
hydrogol, 14. 453
hydrosel, 14. 453
� � hydrophosphatodimolybdate, 11. 67O
hydroselenite, 10. 841
� -~ hydrosulphide, 14. 754
hydroxyazide, 8. 355
� -� hydroxychlorido, 14. 628
hydroxyhydrosulphide, 14. 754
� � hyponitrite, 8. 417
� - hypophosphate, 8. 939
hypophosphito, 8. 89O
intermediate oxides between CoO and
Co3O4, 14. 577, 582
� intermetallic compounds, 14. 529
iodate, 2. 361
_ __ ammino-, 2. 362
� � iodoplatinite, 16. 391
dodecahydrate, 16. 391
enneahydrate, 16. 391
� iridium alloy, 15. 75O
iron alloys, 14. 544, 553 ; 15. 565
aluminium alloys, 14. 553
chromium alloys, 14. 553
tungsten alloys, 14. 554
manganese alloys, 14. 554
molybdenum alloys, 14. 554
tungsten alloys, 14. 554
iso-ehloropentamminohydroxynitrilodisulphonate,
8. 680
ct'�-iso-dinitritotetramminohydroxynitrilodisulphonate,
8. 680
GENERAL INDEX
Cobalt /ras^-iso-dinitritotetrarnminohydroxynitrilodisulphonate.
8. 686
iso-hexainxninohydroxynitrilodisul
phonate, 8. 68O
iso-nitritopentamminohydroxynitrilodisulphonate,
8. 680
isotopes, 14. 525
borate, 5. 114
malleable, 14. 453
manganite, 12. 243
manganese alloys, 14. 543
dihydrato, 9. 461
dodecahydrate, 9. 461
homipentahydrate, 9. 461
hexahydrate, 9. 461
pentahydrate, 9. 461
metasilicate, 6. 932
� metasulphaimsonatoxymolybdate, 9.
332
metatantalate, 9. 9IO
metatetrarsenite, 9. 134
me tat i tana te, 7. 6O
metavanadate, 9. 791
mirrors, 14. 453
molybdenum alloys, 14. 54O
10. 598
� octamminodihydroxydithionate, 10.
598
octoborate dodecahydrated, 5. 114
orthoarsenate, 9. 228
orthoarsenite, 9. 133
orthoborate, 5. 114
orthosilicate, 6. 932
orthostannate, 7. 42O
orthosulphoantimonite, 9. 555
osmium alloys, 15. 697
310
pentafluoforrate, 14. 8
pentafluovanadite, 9. 797
pentamminochlorodithionate, 10. 598
pentamminohydrocarbonatodithio
azide, 8. 355
barium nitrite, 8. 505
cadmium nitrite, 8. 505
decasulphide, 14. 756
diamminototranitrite, 8. 502
GENERAL INDEX
10.
598
c^-tetramminochlorodithionate, 10.
598
tetramminoperrhenate, 12. 477
trihydrate, 12. 477
__ __ tetrapyridinotetrathionato, 10. 62O
~ -- tetravanadate, 9. 791
tetrazincide, 14. 532
tetritatrisulphide, 14. 75O
� � tetroxyorthoarsenite, 9. 133
� tetroxysulphate, 14. 769
decahydrate, 14. 769
tetrad'ecahydrate, 14. 769
thallium alloys, 14. 536
nickel nitrate, 8. 512
Cobaltic jti-acetato-amino-ol-hexamminoehloroplatinate,
16. 332
aeetatopentammines, 14. 697
acetylacetonatobisethylenediamines,
14. 697
� (trans), 8. 508
� /x-amino-decamminobromide, 14. 731
decamminopentachloride, 14. 673
decamminosulphate, 14. 804
__ diol-hexamminobromide, 14. 734
hexamminochloride, 14. 679
.� hoxaiTiminoiodide, 14. 748
hexamminonitrate, 14. 848
ol-octamminobromide, 14. 733
tetrahydrate, 14. 733
octamminochloride, 14. 677
octamminonitrate, 14. 847
octamminosulphate, 14. 674,
805
-� peroxohexamminonitrate,
14. 848
quaterethylenediaminebromido,
14. 733
quatere tl iy lened iamineiodide,
14. 748
peroxo-octamminobromide, 14.
733
�-� octamminochloride, 14. 674
octamminonitrate, 14. 846
dihydrate, 14. 846
hexahydrate, 14. 846
octamminosulphate, 14. 674,
805
ol-hexamminobromide, 14.
734
- dihydrate, 14. 734
hexamminochloride,
14. 680
quatere thylenediaminebromide,
14. 733
hexahydrate, 14. 733
INDEX 505
- quaterethylenediaminechloroplatinate,
16. 332
quaterethylenediamineiodide,
14. 748
dextro-salt, 14. 748
lwsvo-salt, 14. 748
575
barium decamolybdate, 11. 575
decamolybdate, 11. 598
disulphate, 14. 789
dodecamolybdate, 11. 574
hexamminochlorosulphate, 14.
791
hexamminosulphate, 14. 791
hexanitrite, 8. 504
� � hydroxyammino-poroxo-ol-hexaamminosulphato,
14. 805
hydroxy triamminochloroplati nate,
16. 333
antimony dichlorobisethylenediaininehexachlorido,
14. 67O
- aquobisethylenediaminoammines, 14.
693
- aquobisothylened iamineamminobromido,
14. 723
cis-form, 14. 723
trans-foi-m, 14. 723
-� aquobisothylened iamineamminochloroplatinate,
16. 332
trans-aquobisothylonodiaininoamminofluoride,
14. 610
trans -aquobisothylened iamineamminoiodide,
14. 745
ci�-aquobisethylenodiamineamminonitrate,
14. 834
^ran�-aquobisothylenediamineamminonitrate,
14. 834
aquobispyridinetriamminobromido, 14.
723
aquobromotetramminosolonate, 10.
886
aquochlorotetrarnminoselenato, 10.
886
aquoctamminochloride, 14. 66O
aquohenamminochloride, 14. 66O
aqiiohoptamminochloride, 14. 66O
aquohydroxytetramminosolonate, 10.
886
aquonitratotetramminohydroselenate,
10. 886
aquonitritotetramminohydroselenate,
8. 507
506 GENERAL INDEX
Cobaltic aquomtritototramminohydrosulphate,
8. 507
aquonitritototramminomolybtlate, 11.
575
aquoiiitritotetramminooxalate, 8. 507
� � aquonitritototrarnminose]enate,8. 507;
10. 886
aquonitritotetramminotartrate, 8. 507
aquooctoamrahiobroraide, 14. 723
aquopontadecamminobromide, 14. 723
aquopentadeoamminoiodido, 14. 745
aquopentammines, 14. 692
aquopentamrninobromido, 14. 722
aquopentamminobromoiridato, 15. 776
aquopentaniminobromoplatinate, 16.
38O
� monohydrato, 16. 38O
tetrahydrate, 16. 38O
aquopentamminobroniosuliihato, 14.
794, 795
� aquopontarnrriinoehrornatobisdichromate,
11. 344
aquopeiitamminodichromato, 11. 344
� � aqiiopentarnrninofiuoricle, 14. 61O
aquopentamminohydromtrato, 14. 834
� aquopcntamminohydrophosphate, 14.
857
tetrahydrate, 14. 857
aquopentamnunohydropyrophosI>
hato, 14. 858
aquopentamminohydroxide, 14. 595
� � aquopentamminoiodido, 14. 745
aquopentamminoiodonitrate, 14. 834
aquoperitamminoiodosulphato, 14.
795
aquopontamminomolybdate, 11. 575
��- aquopontamminonitrato, 14. 833
aquopontamminonitrilotrisulphonato,
8. 682
� aquopontamminonitrito, 8. 506
aquopentamminopyropliosphato, 14.
858
dodocahydrate, 14. 858
aqu ojxm tamm i nor thoph ospha to, 14.
856
aqnopentamminoselexiate, 10. 886
� -� aquopentamminosulphato, 14. 793
tetrahydrate, 14. 793
__. trihydrate, 14. 793
aqi topentamminosulphatobromoiridate,
15. 776
aquopentamminosulphatodihydrosulphate,
14. 794
aquopentamminostilphatonitrate, 14.
834
aquopentarnminosvilphatototrahydrosulphato,
14. 794
aqviopentamminotrifluorohexahydrofluoride,
14. 61O
� - aquopentan^minotrisulphite, 10. 316
aquopyridinetetrammines, 14. 693
Cobaltic aquopyridinetetramminonitrate,
14. 834
aquoselenatototramminochloride, 10.
886
aquosolenatototramminohydroselenate,
10. 886
aquoselenatotetramminoselonate, 10.
886
aquoselonatototrarnrninostxlphate, 10.
886, 93O
aquosulphatotetramminoselenate, 10.
886, 93O
�-�� aqixosulphitotetramminocyanide, 10.
317
aquosulphitototramminohydroxide,
10. 316, 317
- aquosulphitotetramminothiocyanate,
10. 317
-� barium ammonium octamminohoxastxlphite,
10. 315
�� � � dodecanitrite, 8. 504
ermearnolybdate, 11. 575
ootamminohexasulphito, 10. 315
� a-benstilmonoximebisdiothylonediamine,
14. 698
benzolhexacarbonatopontammines, 14.
699
-� benzolpentaoarbonatopentammines,
14. 699
- benzylsulphoac;atatobisothylonodiamines,
14. 705
bischromatototrammines, 14. 705
bisdiaminodiethyleiieaminotri iodide,
14. 744
bisdimothylglyoxiyriebisanilinas, 14. 703
� bisdimethylglyoximodiaminos, 14. 667,
699, 703, 705
bisdimethylglyoximinebisethylamines,
14. 703
bisdimethylglyoxiniinebishydroxylamines,
14. 703
biadimethylglyoximinobia-p-toluidines,
14. 703
bisdimethylglyoximinobispyridines,
14. 703
bisdimothylglyoxiTninodiammino
Cobaltic 2rarw�-bisethylenediaminediamminochloride,
14. 658
c*>-bisethylonediaminediamminoiodide,
14. 744
trans - bisethy lenediamin ediamm in o iodide,
14. 744
ci�-bisetnylenediaminediarnminonitrate,
14. 833
/rart�-bisethylenedia;minediarnrninonitrate,
14. 833
c*�-bisethylenediaminediamrninopontachloride,
14. 658
<ran*-bisethylenediarninediamxninopentachloride,
14. 658
bisethylenediamine-1-cyclopentanodiaminebromide,
14. 722
dextro-salt, 14. 722
bisethy leziediamine-1 - oy clopentanodiaminechloride,
14. 659
bisethylenodiaminephonanthrolinenitrate,
14. 833
bisethylenediaminopropylenodiamino,
14. 692
bisethylonodianiinepyridineamminos,
14. 692
bisothylenediaminopyridineamrninochlorido,
14. 658
� biHothylonediaininodiarninepontario,
14. 722
bisothylenediaminodiaminopantane,
14. 692
bisethylonediarnino-trans-cyclopentanodiaminebromide,
14. 722
dextro-salt, 14. 722
~ laevo-salt, 14. 722
bisethylenediamine-trans-eyclopentanediammechloride,
14. 659
bishoxarnininochloroplatinate, 16. 332
bishoxamininoennoasulphate, 10. 315
bisliydrosoJenatotetramminoselenato,
10. 886
bismonomothylglyoximinediamminos,
14. 703
bismuth, oar bona totetramminoiodide,
14. 817
ohloropentarnminoetoiodide, 14.
746
dichlorobisethylenodiaminebromide,
14. 729
dichlorobisethylonediarninochloride,
14. 670
diohlorototrainrninosulphate, 14.
8Ol
dinitritotetramminoiodide, 8. 508
dinitritotetrarnminoperchlorate,
8. 508
dinitritotetramxninoselenate, 8.
508
hexamminohexabromide, 14.
721
trisethylenediamineohloride, 14.
657
dextro-salt, 14. 657
laevo-salt, 14. 657
INDEX 507
Cobaltic bis-o-nitrophenolatobisothylenediamines,
14. 697
bis-p-nitrophenolatobisethylenodiamines,
14. 697
-� bispropyldiaminodiainminoclichromate,
11. 344
_ �� bispropylonedianiinodianimines, 14.
692
--� bisx>ropylenodiaininodiamininobromide,
14. 722
--- bispropylenediaminediamminochlorido,
14. 658
-� bispropyleiiediaminediamniinoiodido,
14. 744
�� bispropylenediaminediamminonitrate,
14. 833
bispyropyldiaminodiamminodicHromate,
11. 344
-� - bissalioylatobisethylenediarriinos, 14.
701
bistriaminopropanediamminoiodide,
14. 744
bistriaminopropanos, 14. 692
bistriaininotriethylaiinnesoxiesethyl
� bromoaqiio-/i-amino-octamminosiiIphato,
14. 804
bromoaqiiobisnthylenodittininebromide,
14. 728
- bromoaquobisethylenediamine iodide,
14. 746
c*>-bromoaquobisothylonediaminonitrate,
14. 839
bromoaquobisetbylenediamincR, 14.
695
brornoaquotetrammin.es, 14. 695
bromoaquotetramminobromide, 14.
728
cta-bromoaquototramminobromosulphate,
14. 799
bromoaquototramminochlorido, 14.
728
- cis-bromoaquotetramminoiiitrate, 14.
839
_ ri�-bromoaquotetramminosulpbato,
14. 799
bromobenzeno-3 : 4-disulphonatobisethylenediamines,
14. 705
brornobisethylenediamincammines, 14.
695
cis -bromobiscthylcnadia mineammino bromide,
14. 726
dibydrate, 14. 726
irarw-bromobisothylenediaminoamminobromido,
14. 726
c��-bromobisethylonediamineammino
bromonitrate, 14. 839
GENERAL, INDEX
Cobaltic brornobisethylenediamineamminoiodide,
14. 747
e*�-bromobisethylenedian^inearnminonitrato,
14. 839
�ran.�-bromobisethylenediaminearnminonitrate,
14. 839
monohydrate, 14. 839
bromobisethylenediaminehydroxylaminos,
14. 694, 725
bromobisethylened iaminepyridines,
14. 695
bromoehloroaquoethylenediamineammines,
14. 702
broraochloroaquoethylenediaminearaminobromide,
14. 731
brornoehloroaquoethylenediarnineamminoiodide,
14. 748
bromoehloroaquoothylenediamino
14. 731
monohydrato, 14. 731
bromochloroaquotriarmninoiodide, 14.
748
bromochloroaquotriamnnnonitrato,
14. 842
broTnochlorobisothylenecliaraiiiebro
��� bromochlorobisethylenediaminechloride,
14. 731*
cis- bromoehlorobisethy lenediaminenitrato,
14. 842
dextro-salt, 14. 842
hevo-salt, 14. 842
</ri/t#-bromochlorobisethylenediaminenitrate,
14. 842
bromochlorobisethylencdiamines, 14.
702
c"i�-bromochlorobiscthylened iaminesulphato,
14. 802
dextro-salt, 14. 803
lffivo-salt, 14. 803
bromohydroxy bisothy lonodiaminos,
14. 702
bromohydroxylaminebisethylenediaminobromide,
14. 726
bromohydroxylaminebisethylenediaminechloride,
14. 726
bromohydroxylaminebise thy lened iamineiodide,
14. 746
bromohydroxylaminebisethylenediaminenitrate,
14. 839
bromohydroxylaminobisethylonodiamines,
14. 695
bromonitrobisethylenediamines, 14.
702
bromonitrotetrammines, 14. 702
brornopentarximines, 14. 695
bromo})entamminobromide, 14. 724
bromopentamminobromoplatinate, 16.
380
bromopentamminobromoBulphate, 14.
799
bromopentammiiiochloroplatinate, 16.
382
bromopentamminochromate, 11. 311
bromopentamminodichloride, 14. 725
Cobaltic bromopentamminofluosilicate, 6.
958
bromopentamminohydrosulphate, 14.
799
broiriopentammiiioiodide, 14. 746
bromopentamminoiodostilph-ate, 14.
799
bromopentamminonitrate, 14. 839
bromopentamminosulphate, 14. 798
14. 661
aquopentamminoioditle, 14. 745
chlorobisetliy lenediam ino
656
hexamminohexabromide, 14. 720
hexamminoiodide, 14. 743
hexamminopeiitachloride, 14. 656
14. 819
dextro-salt, 14. 819
Uevo-salt, 14. 819
monohydrato, 14. 819
� carbonatobisethylenediaminohydroxide,
14. 818
carbonatobisethylenodiamineiodide,
14. 819
-� carbonatobisethylenediaminenitrate,
14. 819
car bona tobise thy lenediamines, 14.
703
carbonatobisethylenediaminesulphate,
14. 819
pentahydrate, 14. 819
carbonatobispentammines, 14. 698
carbonatobispropy lenediamines, 14.
704
carbonatobistrimethylenediaminechloride,
14. 819
carbonatobistrimethylenediamines, 14.
704
carbonatodecamminosulphate, 14. 819
carbonatohexamminoiodide, 14. 817
carbonatohydrosulphitotetrammine,
10. 318
carbonatopentammines, 14. 698
VL, INDEX 509
816-6
carbonatopentamminochloride, 14. 815
car bona topentamxninoiodide, 14. 816
carbonatojjentamminonitrite, 8. 506
carbonatopentamminoselenate, 10. 886
oarbonatopentamminosulphate, 14.
816
tetrahydrate, 14. 816
carbonatotetrammines, 14. 703
� carbonatotetramminobromide, 14. 817
carbonatototramminobromoiridato,
15. 776
carbonatotetramminocarbonate, 14.
816
trihydrate, 14. 816
carbonatotetramminochloride, 14. 816,
817
carbonatotetramminofluorido, 14. 816
carbonatotetramminohydrocarbonate,
14. 816
monohydrate, 14. 816
carbonatototraxnminohydroxide, 14.
816
�- earbonafcotetramminomethylsulphate,
14. 816
carbonatototramminonitrate, 14. 818,
840, 842
monohydrate, 14. 818
carbonatotetramminopyrocarbonate,
14. 816
14. 666
dextro-salt, 14. 667
laevo-salt, 14. 667
839
chloroaquotetramminoTiitrite, 8. 508
r��-chloroaquotetrariiminosulphato,
14. 797
chloroaqviotriamminonitrato, 14. 839
- chlorobenzylaminebisethylenediaminebromido,
14. 726
chlorobonzylaminebisethylonodiaminechloride,
14. 666
chlorobenzylaminobisothylenodiamineiodide,
14. 747
chlorobenzylaminebisethylenodiamhionitrate,
14. 839
ohlorobenzylaminobisothylenediainines,
14. 695
chlorobisethylonetliamineammirios, 14.
694
ri�-chlorobisethylonediaminoamminobromido,
14. 726
dextro-salt, 14. 726
laevo-salt, 14. 726
chlorobisethylenediamineamminochloride,
14. 665
dihydrate, 14. 665
ci�-ehlorobisethylenediamineamrnmo
chlorobisethylenediamineammino
chlorobisethylenediamineammino
�ran�-chlorobisethylenediamineam
chlorobisethylenediaminehydroxyl
Cobalt ic chlorobisethylenodiaminopyridinephosphate,
14. 857
ehlorobisethylenediaminepyridinesulphate,
14.^797
� � fhlorobromobisethylonediaminenitrate,
14. 842
ehlorodiaquoothylenediamineamininos,
14. 695
� � ohlorodiaquotriaimnmes. 14._ 695
14.
chlorod laquotrianiminobromido,
728
14.
� chlorodiaquotriamminochloride,
667
14.
� chlorod iaquotriamminosulphato,
798
chloroothylaminebisdiothylenediamint-
�ehloride. 14. 666
chloroothylaTiiinebisothylenedianiineiodide,
14. 747
� -- chloroethylaminebisothyloiiodiarnines,
14. 694
chlorohydroxybisethylenediarriine
� - cvhlorohydroxvbisethvlenodiaxninos,
14. 7<>2
chlorohydroxyiotramminefl, 14. 702
� - chloronitratn-/�-amiiio-octamimti.OTiitrato.
14. 845
chloroiiitritodiothylenodiaminos, 8.
r><>8
fliloronitrobiHetbylonediaminos, 14.
7<)2
chloronitrobispyridinodianiniines, 14.
7()2
chloroiiitrototranvminos, 14. 7U2
t-hloronitrototramminonitrito, 8. 508
chloropontammiiios, 14. 694
chloropentammmobromoiridato, 15.
776
- t-hloropentamminobromoplatiiuxte, 16.
382
��- chloropentarnminobromosulphate, 14.
797
�� chloropontamininocaTboiiate, 14. 815
�- homihenahydrate, 14. 815
772
ohloropentamminochloroplatinato, 16.
332
chloroperitarnminochromate, 11. 311,
312
797
chloropontaraminomolybdato, 11. 575
chloropentarnminonitrate, 14". 838
858
chloropentamrninoselenate, 10. 886
chloropentamminosulphate, 14. 796
14. 695
chloropurp-ureofluosilieato, 6. 957
chloropyridinebisethylenediariiitie
312
-� chromatopcntamminonitrato, 11. 312
� � chrorriatototraminines, 14. 705
chromatototramminochromate, 11.
312
� � chromatotetramminodichromate, 11.
344
chromatototramminonitrate, 11. 312
eitraconatobisethylenediamines, 14.
704
citraconatobispentammines, 14. 699
citratopentammino, 14. 699
cobaltous bispropylenediaminediam
minopontachloride, 14. 659
oxynitritonitrate, 8. 505
trisethylenediaminepenta
-� ft-diomino-octamniino-bromide, 14.
732
-- tetrahydrato, 14. 732
dia.inmin.es, 14. 706
-� diamminosulphito, 10. 314
� diaquo-/z-ainino-ol-bexarnrninonitrato,
14. 847
-�- diaquobisethylonediaminebromido, 14.
724
-- -- rt\?-diaquobisethyIenediarninebroinide,
14. 724
c�/�-diaquobisethylenodiaminechlorido,
14. 662
-� <r�/w�-diaquobisetliylenediammochioride,
14. 662
diaquobisetbyleriodiaminebydroxide,
14. 595
cis-diaquobisethylenediarninenitrato,
14. 835
� moiiohydrate, 14. 835
� �rem�-diaqiiobisetbyleriodiaminenitrate,
14. 835
diaquobisethylonediamiiios, 14. 693
r�8-diaquobisethylonodiaTniTiesulphate,
14. 796
-- 2ra?t0-diaquobisethyleriodiaixuneHiilphato,
14. 796
diaquobispyridinediamminos, 14. 693
diaqiiobispyridiiiediarnminobromide,
14. 724
�� diaquobispyridinediainininonitrate,
14. 835
diaquobispyridinodiatTvminosulphatohydrosulphate,
14. 796
diaquobistrimetliylenodiamines, 14.
693
diaquochlorotriamminosolonate, 10.
886
diaquodichlorodiarnminohydroselenate,
10. 886
diaquo-diol-hexamminosulpbate, 14.
805
--� diaqiiodipyridinediarnrninocblorido,
14. 662
diaquodipyridinodiamminoby droselenate,
10. 886
diaquo-pentol-hexammmoehlorido, 14.
681
796
-� diaquotetranaminochloride, 14. 661
-� diaquotetramminohydroxide, 14. 595
INDEX 511
Cobaltic diaquotetramminopyrophosphate,
14. 858
hexahydrate, 14. 858
diaquotetramminorthophosphato, 14.
856
diaquotetramminoselonate, 10. 886
diaquototramrninosulphate, 14. 795
dihydrato, 14. 795
bainipentahydrate, 14. 795
trihydrato, 14. 795
diaquotetramminosulphatobrornoiridato,
15. 776
diaquotetramminosnlphatotetrahydrosuipliate,
14. 795
diaquo-tetrol-quator-otliyloiiediamineiodide,
14. 748
diaquo-tetrol-quator-otbyloned iaminosulphate,
14. 805
-� hoptahydrate, 14. 806
diaquotrimothylenediaminonitrato, 14.
835
<libromo-/i-ariiino-peroxo-hexainino
16. 382
dibromototraraminodichromate, 11.
366
<rcm#-dibrornototrarntninoiodido, 14.
748
�ra/i�-dibromotetramminonitrato, 14.
842
� dibromotetramminosulpbate, 14. 802
dichloro-yx-amino-peroxo-hoxamminocbloride,
14. 672, 676
�- hexamrninoriitrate, 14. 847
dicbloroaquoethylenediaminoammines,
14. 700
2ran.�-dichloroaquoothylenodiamineamminochloride,
14. 671
dichloroaquoethy lenediaminediamineamminitrate,
14. 842
512 GBNERi U- INDEX
Cobaltic trans-dichloroaquoquaterpyridirxenitrato,
14. 841
dichloroaquotriammines, 14. 7OO
. dichloroaquotriarn:mi:noohloride,14. 67O
dichloroaqiiotriamminohydrosulphate,
14. 802
dichloroaquotriarriiriinonitrato, 14. 842
� c?"�-dichlorol>i8cyclopontanediarnineohlorido,
14. 670
<ran#-clic;hlorobiHcyclopentanediamiiiochlorido,
14. 67O
~ � diclilorobiscyclopeiitaiiediamines, 14.
7OO
diohlorobmdiarninojjentanochloride,
14. 67O
-- difhlorobiwetbylonediaTninobrornido,
14. 73O
/rf*�.�-dicblorobip�othylonediamineehloride,
14. 669
-- diehlorobisotliylonodiarniiiodiamiwines,
14. 7OO
L ran�-diehlorobisethylenodiaminohydroehlorido,
14. 670
t rans -11 ichlorobisethy lenediaminehydrotvulphato,
14. 802
ci#-diehlorobisothylenediarmiieiodido,
14. 747
�ra.w.#-dicblorobisetbylen.odiamiiioiodide,
14. 747
c itf-diohlorobisethylonediaminenitrate,
14. 841
__ dextro-salt, 14. 841
loevo-salt, 14. 841
#ran#-dichlorobiHethylenediarniriorii
� ci�-dicblorobisethyletiediamminochloroiridate,
15. 772
trans -diehlorobisethyleriediarnrninocbloroiridate,
15. 772
dichlorobisphenylethylenediaminoehloride,
14. 67O
<r�n.�-dicblorobispropyldiaininebroinide,
14. 730
^rem-a-diehlorobispropylonechloride, 14.
670
eis-diohlorobispropyleiiediamineohlorido,
14. 670
dichlorobispropylenediamineehloroplatinate,
16. 332
dichlorobispropylenediamiriechloroplatinite,
16. 285
dichlorobispropylenediaxninehydrochloride,
14. 670
<ran�-dichlorobispropylenediaminehydrosulphate,
14. 802
<ra**�-dichlorobispropylenediaminenitrate,
14. 841
Cobaltic �r<m*-dichlorobispropylenedia
14. 842
dichlorobietrimethyldiamines, 14. 700
-� dichlorobistrirnethylenediamirie
671
dichlorodiaquodiammitiohydrosu.1phate,
14. 802
dichlorodiaquodiainminonitrate, 14.
842
dichlorodiriitrodiamminocobal tates,
14. 707
trans-A ichloroethylenediairiinediarriminobromide,
14. 731
trans - diohloroethylened iarninodi am ininochloride,
14. 670
<rari#-dichloroethylenediaminediamminohydrosylphate,
14. 802
/raw^-dichloroethylenediarninodiaiximinoiodide,
14. 747
trans - diohloroo thylonediaminediamxninonitrate,
14. 842
cis-diehloroethylonediaixirrunobro
730
^rarts-dichlorotetrarrmiinobroiriide, 14.
730
dichlorotetramminochloride, 14. 668
<r�n.s-dichlorotetrammiiiochloride, 14.
668
cis-diehlorototrarnrniiiochloroiridate,
15. 772
dichlorotetramminochloroplatinate,
16. 332
� dichlorotetramminoohloroplatinite,
16. 286
dichlorotetramminodichromate, 11.
344
monohydrated, 11. 344
<rt*�.�-dichlorotetrammirxofluoride, 14.
668
<r�r*�-dichlorotetramminohydroselenate,
10. 886
*raw�-dichlorotetramminohydros\ilphate,
14. 8Ol
c^s-dichlorotetrairiminoiodide, 14. 747
iron^-dichlorotetramminoiodide, 14.
747
ct�-dichlorotetramminonitrate, 14.
841
GENEKAL, INDEX
Cobaltic $raw�-dichlorotetramminonitrate,
14. 841
dichlorotetramminonitrite (cis), 8. 508
(trans), 8. 508
ci�-dichlorotetramxninosulphate, 14.801
trans - dichlor o te trapyridinechloride,
14. 669
trans - d ichlorote trapy ridinohy droselenate,
IO. 886
<r<xw.�-dichlorotristrimethylenediaminechloride,
14. 67O
diehro-salts, 14- 7OO
� dichromatopentamminochromate, 11.
344
dichromatotetramminodichromato, 11.
344
ci#-difl.uobisethylenediamineiodide, 14.
747
<?^�-difl.uobisethylenediarn.inenitrato,
14. 841
difluobisethylenediamines, 14. 699
difluorobisethylenedianiinebroinido,
14. 73O
�rGm.�-difluorobisethylonodiarninechloride,
14. 668
--- /ran^-difluorobisethylenediarninofluoride,
14. 61O
trans - difluorobi so thy lenod iamino
� dihydroxytetramrninohydroxide, 14.
596
dihydroxytetramminoiodide, 14. 747
dihydroxytetramminonitrate, 14. 840
diiodotetramminonitrito (cis), 8. 508
(trans), 8. 508
diisothioeyanatobisethylenediamines,
14- 702
diisothioeyanatobispropylenediamines,
14. 702
dimethylmalonatobisethylenediamines,
14. 704
dimolybdatotetrammines, 14. 705
dimolybdatotetramminotrimolybdato,
11. 575
dinitratobisethylenediaminehydronitrate,
14. 84O �,
dinitratobisethylenediaminenitrato,
14. 84O
monohydrate, 14. 84O
dinitratobisethylenediamines, 14. 7Ol
dinitrato-diol-hexaxnxninonitrate, 14.
846
dinitratotetrammines, 14. 7Ol
dinitratotetramminonitrate, 14. 840
monohydrate, 14. 84O
dinitritobisethylenediamines, 14. 7Ol
dinitritobispyridinediammines, 14. 7Ol
dinitritobromotriammine, 8. 509
dinitritoohlorotriammine, 8. 509
�~� dinitri todiaxninopentanes, 14. 696
dinitritodiamminohydronitrate (cis),
8. 507
VOL. XVI.
8. 507
(trans), 8. 507
cis - dinitri totetramminochloroir idate,
15. 772
2ran#-dinitritotetramniinochloroiridate,
15. 772
�-� dinitritotetramminochoroplatinato, 8.
dinitritotetramminochloroplatmite, 8.
507 ; 16. 285
(cis), 8. 507
dinitritotetramminoohromate, 8. 508
10. 886
(cis), 8. 507 ; 10. 886
(trans), 8. 507 ; 10. 886
dinitritotetramminosulphate (cis), 8.
507
(trans), 8. 507
dinitritotetramminotetramminobromoiridate,
15. 776
dinitroaqnotriamrninos, 14. 7Ol
� dinitrobisdimethylglyoximinocobaltates,
14. 707
dinitrobisethylenediamines, 14. 7Ol
dinitrobispyridinediammines, 14. 7Ol
2 L
GENERAL INDEX
� dinitromalonatodiamminocobaltates, dithioearbimidobisetliylenediamino14.
707 hydroselenate, 10. 886
dinitrooxalatodiainminecobaltates, 14.
707
dinitroplienolatoaquobisethylenediairiin.
es, 14. 697
dinitropropylenodiaminethylenedi
� diol-octamminochloroplatinate, 16.332
. diolootamminoehloroplatinite, 16. 285
diol-octamminohydrophosphato, 14.
857
14. 678
�� diol -peroxo-HOxiesallylaminexiitrate,
14. 847
��- diol-peroxo-soxieopropylaininochloride,
14. 679
d iol-quatoreth vleriediarninobroxnido,
14. 732
� dihydx-ate, 14. 732
- totrabydrate, 14. 732
diol-quaterothylenediaxninochloride,
14. 677
diol-qiiaterothylonediarnineiodidc, 14.
748
diol -qua terethylenediaminenitrate, 14.
845
� dioxalatodiamminooobaltates, 14. 707
dioxalatoethylonediamineoobaltato,
14. 707
� � dioxydecamminodichromate, 11. 344
diozo-triimidodecamrninoohloride, 14.
673
-� diozo-triimidodecamminonitrate, 14.
844
diozo-triimidodexamminobromide, 14.
733
--� diozotriimidecainminonitrato, 8. 274
diozotriimidodecamminoctabromide,
8. 274
diozotriiinidodecarnrninoctaehloride,
8. 274
diphosphatobisethylenediaminephospliate,
14. 857
dipliospliatobispropylenediaminephos
14. 702
dodecamminoehloride, 14. 655
enneamminochloride, 14. 655
onneamminodichromate, 11. 344
� ethylenodiarninedicyclopentanediamines,
14. 692
-- ferric cshloropyridinebisethylonediaminechloride,
14. 666
oxide, 14. 586
forrite, 13. 925 ; 14. 586
flavo-salts, 8. 5()7 ; 14. 701
14.
--fluobiaethylonediaminoamminos,
694
�� -fluobisethylenediarniiieamrninobroxnido,
14. 725
__ (eis), 14. 726
(trans), 14. 726
- riA-fluobisothylenetiiainineamminofluorido,
14. 6IO
ri�-fluobisethylenediamineamminonitrate,
14. 838
fluohydroxytetrammines, 14. 702
� -fluohydroxytetrainminomtrate, 14.
842
fluopentainrnixios, 14. 694
14. 794
aquopentamminohexachloride,
14. 661
bisethylenediaminediamminoenneachloride,
14. 658
bisethylenediaminediamminoliexachloride,
14. 658
exiloropontamminopentacxiloride,
14. 665
dibronaotetraiximinotetrachloride,
14. 729
dichlorobispropylenediaminetetrachloride,
14. 670
GENERAL INDEX
792
hexamminochlorosulphate, 14.791
sulphodiaeotatobisethylenedi
11. 575
hexahydroxylaminebromide, 14. 721
hexahydroxylaminechloride, 14. 656
hexahydroxylaixxinenitrate, 14. 832
hexahydroxylamines, 14. 691
399
hexamminochloroiridato, 15. 772
hoxamminochlorometapliosi)hate, 14.
859
336
hexarnrninodichroinate, 11. 344
hexainiriinodinitratofliaosvilphonate,
14. 832
hexamxxiinoemieaiodide, 14. 743
hexarnxxiinofluodichloride, 14. 655
hexamininofluonitrato, 14. 832
hexamminofluoride, 14. 609
hexamminofluosilicate, 6. 957
-� hexarnrninoheptaftuotetroxyditixngstate,
11. 840
��� hexamminohexanitrite, 8. 506
hexamminohydrooarbonate, 14. 815
858
hexamminohydroselenate, 10. 885
hexamminohydroxide, 14. 594
hexamminohydroxychloroiridate, 15.
772
776
hoxarnrninosulphatodecahydrosiilI^
hato, 14. 791
hexarnininosulphatodihydrosulphato,
14. 791
� � poritahydrate, 14. 791
hexariirriinosulphatoriitrate, 14. 832
� hexatnrninosulphatotetrahvdrosulphate,
14. 791
hexarmninosulphito, 10. 314
---hexarriniinotrinitrite, 8. 506
hexamininotrisulphite, 10. 315
hexapotasaium octohydrotetrahypoI^
hosphato, 8. 939
hexol-dodocamminobromide, 14. 734
dihydrates, 14. 734
���-�--octohydrate, 14. 734
� � dodeuaniminochloride, 14. 681
dodecamrmnoehloroplatinate, 16.
332
�-�� dodecarmmiionitrato, 14. 848
� � dodecamminoRulphalu, 14. 8O6
oxineahydrate, 14. 8O6
hexahydi'ate, 14. 8O6
tetrahydrate, 14. 8O6
hexamminobromide, 14. 734
hexamminochlonde, 14. 68O
hexammiriosulpliate, 14. 805
soxiesetliylenediaixiinoehloride,
14. 681
� -� � sexiosethylenediairiineiodide, 14.
749
� � � sexiesethylenediaminonitrate, 14.
848
hornophthala tobisetl1ylened iaminos,
14. 704
� hydrocai'boiiatonitrotetrarnixiines, 14.
702
� hydrocarbonatopentamminos, 14. 697
� hydrocarbonatopontamminobromide,
14. 815
� hydrocarbonatopentainininoiodido, 14.
815
� -hydrocitratotrispentammines, 14.
699
� hydronitritoimidoctarniriineriitrate, 8.
506
� hydronitritoimidoetamminodisiilphate,
8. 273
� hydronitritoimidoctamminotetrachloride,
8. 273
516 INDEX
Cobaltic hydronitritoimidoctamminotetranitrate,
8. 273
hydroniti'itoirnidohexainminotetraehloride,
8. 274
hy dronitri toimidohexamminotetraohloride,
8. 506
� hydrophosphatopentammines, 14. 698
hydrosulphatoimidoctarnrninodichloronitrate,
8. 273
hy d rosuljihatoimidoc t amm i nohydrodisulphate,
8. 273
hydrosulphatoimidoetamminotribromide,
8. 273
hydroaulphatoiTnidoctarnrninotrichloride,
8. 273
hydrosulphatoimidoctarnrninotriiodide,
8. 274
hydrosidphatoimidoctamminotrinitrato,
8. 273
hydrosulphatothiocarbonatotriammino,
14. 82O
hydroxide, 14. 589
colloidal, 14. 590
� hy<iroxyammino-peroxo-hexamminosulphate,
14. 805
ci*-hydroxyaquobisethylenediaminebrornide,
14. 727
� /rowi.#-hydroxyaqiiobisathyleTiediarninobromide,
14. 727
ri'#-hydroxyaquobisethylenodiarninechloride,
14. 667
� <r�r*�-hydroxyaqtiobisothylonediaminechloride,
14. 667
ci#-hydroxyaquobisothylenodiainineiodide,
14, 747
<r�rt�-hydroxyaq\iobisethylenediaminoiodide,
14. 747
ri�-hydroxyaquobisethylenadiamineiiitrate,
14. 838
hydroxyaquobisethylenediamines, 14.
694
hydroxyaquobisathylenediamminochloroiridate
(cis), 15. 772
(trans), 15. 772
-- hydroxyaqiiobispyridinodiarnrriinos,
14. 694
hydroxyaquobispyridinediartvminobromide,
14. 727
� hydroxyaquobispyridinediamminonitrato,
14. 838
hydroxyaquodipyridinediamminochloride,
14. 667
_ hydroxyaquo-peroxo-ol-hexaraminobromide,
14. 732
hydroxyaquo-peroxo-ol-hexamminochloride,
14. 677
� hydroxyaquo-peroxo-ol-hexamminonitrate,
14. 846
hydroxyaquotetrainmines, 14. 694, 696
� hydroxyaquotetramminobromide, 14.
727
hydroxyaquotetramminochloride, 14.
667
monohydrato, 14. 667
hydroxyaquototramminonitrate, 14.
838
hydroxyaquotetramminosulphate, 14.
796
Cobaltic hydroxyaquotetramminosulphato
hydroxynitritototramminobromide, 8.
508
hydroxynitritotetrancinainochloride, 8.
508
hydroxynitritototramminohydrobromide,
8. 508
hy droxynitritotetramminohy dro chloride,
8. 508
� hydroxynitritotetramminohydroiodido,
8. 508
liydroxynitritotetramminonitrate, 8.
508
hydroxypentammines, 14. 693
hydroxypentamminobromide, 14. 726
hydroxypentamminochloride, 14. 667
� hydroxypentamminohydroxide, 14.
595
hydroxypentamminoiodide, 14. 747
hydroxypentamminomolybdate, 11.
575
hydroxypentamminonitrate, 14. 837
monohydrate, 14. 837
hydroxypyridinetetrammines, 14. 694
hydroxypyridinetriarnrninonitrate, 14.
838
hydroxysulphitotetrammine, 10. 316
imido-salts, 14. 7IO
iraidoctammine, 8. 273
imidoctamminodisulphate, 8. 273
imidoctamminotetrabromide, 8. 273
-� imidoctamminotetrachloride, 8. 273
imidoctamminotetranitrate, 8. 273
imidohexamminotetrabromide, 8. 274
imidohexaniminotetrachloride, 8. 274
inxidohexamminotetraiodide, 8. 274
Cobaltic imidohexamminotetx*anitrate, 8.
274
imidosulphonate, 8. 507
iminobispyridin eoctamminotetrabro
(trans), 8. 508
isonitritopentamminodiohloride, 8. 506
isothiocyanatoaquobisethylenedi
506
isothiocyanatopontaxnmines, 14. 697
i sothiocy aiiatopontaraminoohroraate,
11. 311
isoxantho-salts, 14. 696
itaconatobisothylonediamines, 14. 704
itaconatobispentamminos, 14. 699
lanthanous hexamminosulphatc, 14.
791
744
trishexamminotridecabromido,
14. 721
lithium hexanitrite, 8. 504
luteochloride, 14. 653
lutoofluosilicate, 6. 957
luteo-salts, 14. 688, 690
magnesium aquoquinquesbenzyl
INDEX 517
12. 346
manganic pentafluoride, 14. 608
� melanochloride, 14. 672, 803
� mercuric aquochloropontamminoenneachloride,
14. 661
aq uopontam minoch 1 or os ulpha to,
14. 794
aqu opentammi noonnoabrorni do,
14. 723
aq u open tammi nopon tabr omido,
14. 723
aquopentamminopontachloride,
14. 661
aquopentamminopentaiodido, 14.
745
�� ^retrwr-bisethylonediaminediamminotrideoachloride,
14. 658
bispropylenediaminediammixioheptachlorido,
14. 659
_ _� broinopentamniinobromoheptaehloride,
14. 725
� broraopontamminoctobromide,
14. 725
bromopontarnminoctochlorido,
14. 725
� carbonatopontamminoiodido, 14.
817
chloropentamminoctoclilorido,
14. 665
�� chloropentam ni inohexaiodide,
14. 746
chloroperitamminotati"ac;hloride,
14. 665
� � chloropontamminofcetraiodide,
14. 746
� ohloropyridinebisathylonodiaminechlorido,
14. 666
� � d iaq uotetrammi noohloride, 14.
662
dibrombisothylenediaminebromide,
14. 73O
dichlorobisetbylenodiaminetrichlorido,
14. 669
(trans). 14. 67O
diehlorobispropylenediamineheptaohlorido,
14. 670
dichlorotetrarmninototrachloride,
14. 669
dichlorotetramm in o t r ich 1 oi'ido,
14. 669
dichlorotetrapyridinedodocachlorido,
14." 669
hexaraminochlorosulpbate, 14.
792
hexamminoenneabromide, 14.
72O
hexamminoenneachloride, 14. 656
hexamminoenneaiodide, 14. 743
hexamminoheptachlonde, 14. 656
hoxamrninopentabromide, 14.
72O
hexamminopentachloride, 14.
656
GENERAL, INDEX
704
inesotartrBiobispentammines, 14. 699
mesotartropontammines, 14. 698
metaboratopentamminos, 14. 697
methionatobisothylenediamines, 14.
705
mothionatobispentamminos, 14. 699
molybdates, 11. 574
molybdatonitritotetramminomolyb
� molvbdatototramminotrimolybdate,
11. 575
molybdenvl hexaraminofluorido, 14.
61O
--- monamminoH, 14. 707
- � nickel ethyleivediaminochloride, 15.
422
_ _____ trisothylenediaminootochloride,
14. 658
nickelic ferric oxide, 14. 586
nitrate complex salts, 14. 830
� nitratoaquo-/t-amiiio-oc!tammirionitrate,
14. 844
nitratoaq_o-/_-amino-ol-hoxarrirninonitrate,
14. 847
nitratoaquotetramminos, 14. 696
nitratoaquotetraxnminonitrate, 14.
837
nitratoaquotetramminosulphate, 14.
839
xiitratobisethylened iamineammines,
14. 696
nitratobisethylenediaminearnrninobromide,
14. 837
2r_rw�-nitratobisethylenediamineamminonitrate,
14. 837
ni tratoimido triaquohexamminotri chloride,
8. 274
nitratoixnidotriaquohexaxnminotrinitrate,
8. 274
nitratonitrobisethylenediamines, 14.
702
nitratonitrobistrimethylenediaixiine,
14. 7Ol
696
n i tritoaqu obistrimethylenediamines ,
14. 696
nitritoaquopentamminobromoiridate,
15. 776
nitritoaqnotetramxninetetranitritodiamminocobaltiate,
8. 507
-�- nitritoaquotetramminos, 8. 507; 14.
696
nitritoaquotetramminocarbonate, 8.
507
-� nitritoaquotetramminochloroiridate,
15. 772
� nitritoaqnotetramminodibromide, 8.
507
nitritoaquotetramminodichloride, 8.
507
nitritoaquototranixninodi iodide, 8. 507
-� nitritoaquotetramminonitrate, 8. 507
nitritoaquotetramminosxilphate, 8. 507
nitritobisothvlenediamineamxnines, 14.
696
i-ntritochlorodiethylenediaminebromide*(
cis), 8. 508
(trans), 8. 508
� chloride (cis), 8. 508
(trans), 8. 508
dide, 8. 507
sulphatoperiodide, 8. 507
tetranitritodiamminoeobaltiate,
8. 506
nitritopentamnaines, 8. 506 ; 14. 696
nitritopentamrninoaniidosulphonate,
8. 507
nitritopentamminochromate, 11. 311
nitritopentamrninadicliloride, 8- 506
nitritopentamminodichroTriato, 11. 344
nitritopentarnrninodinitrate, 8. 5()7
nitritopentarnrriinodinitrite, 8. 506
nitritopentamminohydrosulphate, 8.
506
nitritopentainrninonitrilotrisiilpho
nate, 8. 682
nitritopontarnminonitrite, 8. 506
nitritopentamminoselenate, 8. 506 ; 10.
886
rntritopentamminosulphate, 8. 506
� nitritopentainrninothioferrocyanide, 8.
507
nitritopentamminothiooxalate, 8. 507
nitritopentarnininothiosulphate, 8.
317
cttf-nitritotetrarnniinodichrornate, 11.
344
nitri tothiocy an a t odiethy Id iammi n ochloride,
8. 508
nitritothiocyanatodiethyleriecliarnines,
8. 508
nitritothiocyanatotetraiiiinines, 8. 508
nitritotrisulphonato, 8. 507
nitritoxalatotriaminine, 8. 509
nitrohydroxytotrammines, 14. 702
886
oxalatopontammines, 14. 698
oxalatopentamminohydroselenate, 10.
886
oxalatopentamrainonitrite, 8. 506
oxalatopontamminoselenate, 10. 886
oxalatotetrammines, 14. 704
oxobisimidobisoctarnminootachloride,
8. 273
oxobisimidobisoctamrnirxototrasulphate,
8. 273
oxobisiinidobisoctoaraminoctariitrate,
8. 273
oxobisimidoctamminoctabromide, 8.
273
ozoim idohexammin ohy<Irotri ohloride,
8. 274
ozoimidohoxarnminotrinitrate, 8. 274
ozotrimido-salts, 14. 710
pasonolobisethylenediamiries, 14. 697
pentahydrated trioxo-octamminodi
804
docamminochlorototranitrate,
14. 843, 844
� decamminodisulphate, 14. 803
14. 843
decamminoiodide, 14. 748
decamminotiitratodisulphato, 14.
844
decamminopentachlonde, 14. 673
docamminopentanitrate, 14. 843
decamminos\xlphatodihy drosul
844
� phenanthrolinebisethylenodiaminoohlorosulphate,
14. 793
� a-phenanthrolinebisothylenGdiainineiodide,
14. 745
doxtro-salt, 14. 745
lievo-salt, 14. 745
� phenanthrolinebisethylenediaminesulphate,
14. 792
� phosphate, 14. 856
� phosphatopentamniino, 14. 699, 856
� phosphatopentamminocliloride, 14. 857
� phosphatopentamminodihydrophosphate,
14. 857
dihydrate, 14. 858
52O GENERAL, INDEX
� dichloroaquotriamminosulphate,
14. 802
� _ dichlorobisethylenediaminesulphate,
14. 802
dichlorobispropylenediaminesulphatonitrate,
14. 841
dichlorotetramminosulphate, 14.
8Ol
hexanitrite, 8. 604
/x-imino-peroxo-quaterothylenediaminenitrate,
14. 846
nitritopentamminotrinitrite, 8.
506
oxyhexanitrite, 8. 504
trisethylenediamineiodide, 14.
744
sodium aquopentammi n opyrophosphate,
14. 858
aquopentamminotrisuli>hite, IO.
316
dipotassium nitrite, 8. 504
hexamminohexasulphite, 10. 318
hoxamminohypophosphate, 8.
939
hexamminopyrophosphate, 14.
858
hexanitrite, 8. 503
� � octamminohexasulphite, 10. 318
-� oxyoctonitrite, 8. 502
� pentamminotrisulphite, 10. 315
per carbonate, 14. 82O
. __ pyrophosphatopentamminocobaltate,
14. 859
sulphite, 10. 315
. sulphitopentamminotrisxilphite,
10. 316
trisethylenediamineheptachloride,
14. 657
stannic dichlorobisethylenediaminebromide,
14. 729
dichlorobisethylenediamineehloride,
14. 67O
stannous bispropylonediaminediamminohoptachloride,
14. 659
ohloropyridinebisethylonediaminochloride,
14. 666
dichlorobisethylenediaminochloride,
14. 67O
__�__ hexamminodecachloride, 14. 656
decahydrate, 14. 6.56
octohydrate, 14. 656
hexamminoiodide, 14. 743
strontium dodecanitrite, 8. 504
oxyoctonitrite, 8. 504
succinatobisethylenediamines, 14. 704
succinatobisethylenediaminobromide,
14. 722
succinatobisethylenediaminonitrate,
14. 833
sulphate, 14. 787
_ complex salts, 14. 787
sulphato-/x-amino-octamminobromide,
14. 804
octamminochloride, 14. 804
octamminodichloronitrate, . 14.
845
. ootamminohydrosulphate, 14. 804
GENERAL INDEX
Cobaltic 8ulphato-/i-amino-octammino
14. 804
q-uaterethylenediaminenitrate,
14. 845
Bulphatocujuotetrammines, 14. 698
sulpha toaquo te tramminohydros ul
8OO
dialcohlate, 14. 80O
dihydrate, 14. 80O
tetrahydrate, 14. 800
14. 803
sulphatobisothylonediamines, 14. 703
BulphatodiaquotriammineB, 14. 698
sulphatodiaquotriamminosulphate, 14.
8Ol
sulphatoiiriidoctarnrnmodiohloride, 8.
273
sulphatoimidoctamminodiriitrate, 8.
273
sulj>hatoimino-octammirxonitrate, 14.
844
sulphatopentammines, 14. 698
sulphatopentamminobromide, 14. 80O
sulphatopentamminobromoiridate, 15.
776
sulphatopentamminocarbonate, 14. 816
sulphatopentamminochloride, 14. 80O
sulphatopentamminohydrosulphate,
14. 799
Cobaltic sulphodiacetatobisothylenediaminechloride,
14. 671
sulphodithioearbonatohexarnmincs 14.
819
sulphonyldiacetatobisethy leiied i
6. 932
tetramminotrisuli>hite, 10. 315
tetramminotriterosilicatoTTietasilit;ato,
6. 932
tetranitrobis-p-toluidirieoobaltates, 14.
707
tetranitrodiarnrninocobaltatos, 14.
706
tetraquodiammines, 14. 693
tetraquodiaiTiminoehloride, 14. 662
tetraquodiamminonitrato, 14. 835
tetrath iofiyanatodiamminochromates,
11. 311
tetrerosilicate, 6. 932
totrol- diaquoquaterethyIoncdiami n e
- totrol-quatorothylonediairiiiiochloride,
14. 680
thallium hexamminosulphate, 14. 791
_ . hexanitrite, 8. 505
silver hexanitrites, 8- 5()4
thiocarbimidopentammiriosolenate, 10.
886
thiocarbonates, 14. 710
thiooyanatopentamminomolybdate,
11. 575
tliiosulphatobisothylenediaminos, 14.
703
thiosulphatopentammines, 14. 698
thiosulphatopontaiTiTTunobromide, 10.
557
thiosulphatoi>entamminocliloride, 10.
557
thiosulphatopentamminofhromate, 10.
557 ; 11. 311
� thiosvilphatopontamminodithionate,
10. 557
thiosulphatopentairiTTiinoiodido, 10.557
tli iosulphatopentammi noni trate, 10.
557
thiosulphatopentainmiriothiosulphato,
IO. 557
triammines, 14. 706
triaquotriainmines, 14. 693
c**-triaquotriamminochloride, 14. 662
�raw*-triaquotriammmoehlorido, 14.
662
triaquotriarnrninochloroplatiriate, 16.
332
triaquotriamminonitrate, 14. 835
� tribromotriammine, 14. 731
trioarbonatohexammino, 14. 819
trichloro-^-amino-hexamminochloride,
14. 672
522 GENERAL, INDEX
� trieiB-cyclopontanediarninochloride,
14. 658
_ � tetrahydrate, 14. 658
_ trihydrate, 14. 658
� triethylenediaminotrihydroselenato,
10. 886
trinitratotriammine, 14. 843
trinitritoethylenediam.inainm.iiie, 8.509
� � trinitritotriammine, 8. 608
triol-hexamminobromide, 14. 733
hexamminochlorido, 14. 678
... . hexamminonitrate, 14. 847
__ dihydrate, 14. 847
__ hexamminosulphate, 14. 805
sexieshenzylaminechloride, 14.
679
�� - trisfoutylenediamineiodide, 14. 744
trishutylenediamines, 14. 692
744
557
trisphenylenediaminechloride, 14. 722
trisphenylenediamines, 14. 692
trispropylenediamineforonido, 14. 722
diamminocofoaltiate, 8. 5IO
Cofoaltiferous manganese ore, 15. 9
Cobalt ihexammine tetranitritodiammino
cobaltiate, 8. 510
Cobaltine, 0. 308
Cobaltmitratopentammine tetranitritodi
amminocobaltiate, 8. 510
Cobaltinitritoaquotetrammine tetranitritodiamminocobaltiate,
8. 510
Cobaltocadamite, Q. 181
Cobaltocalcite, 8. 814
� cobaltic crs-bisethylenediaminediamminopentaohloride,
14. 658
�ran.�-bisethylenediaminediamminopentachloride,
14. 658
bispropylenediaminediamminopentachloride,
14. 659
oxynitritonitrate. 8. 505
trisethylenediaminopentachlo
phosphatohemipentamolybdate, 11.
669
platinous *r�7i�-sulphitodiamminos\il
�- hexamrninodibromosulphate, 14.
771
hexamminodiiodosulphate, 14.771
hexasulphitodicobaltate, 10. 315
hydrocarbonate, 14. 812
magnesium sulphate, 14. 782
11. 67O
selenato, 10. 884
INDEX 525
854
trisethylenediaminochloroplatinito, 16.
284
tungstate, 11. 802
dihydrate, 11. 802
�� uranyl phosphate, 14. 853
zinc carbonate, 14. 813
Cobaltum, 9. 2
acido arsenico mineralisatum, 9. 228
arsenico mineralisatum, 9. 76
ceneraceum, 9. 76
cum ferro sulfurato et arseriicato
mineralisatum, 9. 308
ferro sulphurato minoralisatem, 14.
757
nigrum, 12. 266
purissimum, 14. 452
testaceum, 9. 3
GENERAL INDEX
� specific, 1. 848
Cohesive attraction, 1. 841
� pressure, 1. 841
Coinage, Uritish, 4. 671
Coke, 5. 749 ; 12. 585
-- absorption, oxygon, 1. 371
hard, 5. 749
soft. 5. 749
Coking, 5. 749
Colehotar, 13. 782
Colcothar, 10. 351 ; 13. 781, 782, 783
< -old-working steel, 12. 67O
Coldsharo iron, 13. 61
Coldshore iron, 13. 61
Colomanito, 3- 623 ; 5. 4, 9O
(neo), 5. 9O
Colerainito, 6. 622
Coleshiro iron, 13. 61
Collidmiuin bromopalladate, 15. 678
reversible, 1. 771
carbonate, 3. 457
__ orthophosphate, 3. 486
solution, 16. 398
solutions, boiling points, 1. 774
compressibilities, 1. 774
dialysis, 1. 774
diffusibility, 1. 774
electrical conductivity, 8. 543
volumes, 1. 774
surface tension, 1. 774
thermal expansion, 1. 774
_ viscosities, 1. 774
state, 1. 771
tellurium disulphido, 11. 110
Colloidoscope, 1. 774
Colloids, 1. 77O
Avogadro's constant, 1. 778
collision frequency, 1. 776
diflocculation, 8. 536
-� carbide, 5. 888
carbonate, 9. 882
carbonitride, 8. 126
chloride, 9. 875
chromate, 11. 306
dichloride, 9. 875
dioxide, 9. 855
� dioxyfiuorido, 9. 872
electronic structure, 9. 853
fluoride, 9. 870
history, 9. 837
hydride, 9. 855
hydroxydichlorido, 9. 876
iodides, 9. 880
iron alloys, 18. 586
isotopes, 9. 853
molybdate, 11. 57O
mononitride, 8. 125
nickel alloys, 15. 238
Combustion, 1. 6O, 68
fractional, 1. 488
heat of, 1. 710
Components, 1. 445
of spectrum, 4. 7
Composition, chemical and solubility, 1. 585
law of chemical, 1. 95
constant, 1, 76, 78
F. WaId on, 1. 80
Compounds, 1. 85
chemical, 1. 78
complex, 4. 195
first order, 1. 40O
higher order, 1. 400
indefinite, 1. 519
INDEX 527
854
cells, 1. 1021
critical, 1. 523
solutions and osmotic pressure, 1. 543
Conchito, 3. 816
Concurrent reactions, 1. 36O
Condensation, binary mixtures gases, 1. 167
-� retrograde, 1. 168
Condensed oxide, 7. 224
Conductivity electrical, 3. 52
thermal, 3. 52
Confitello, 2. 711
Confolensito, 6. 498
Congelation, aqueous, 8. 565
spiritous, 8. 565
Conichalcite, 9. 4, 173
Conite, 4. 371
Conjolo, 2. 803
Connarite, 6. 931 ; 15. 5
Consecutive reactions, 1. 359
Conservation energy and matter, 1. 695
Constant, chemical, 1. 737
gas, 1. 161
thermochemical, 1. 7IO
Constantan, 15. 179
Contacts of crystals, 1. 615
Constantinople, 1. 44
Constituents, vicarious, 1. 651
Contact action, 2. 143
acid, 3. 25
basic, 3. 25
528 GENERAL, INDEX
9. 186
phosphate, 5. 368
tetroxydiarscnate, 9. 186
alummoarsonatosulphate, 9. 162
aluminosilicate, 6. 344
aluminotungstato, 11. 789
amalgam colloidal, 4. 1023
amalgams, 4. 1022
amidosulphonate, 8. 641
amrninochlorosmate, 15. 72O
amminopermanganate, 12. 332
ammmoxythiooarbonato, 6- 125
ammonium, ammoniohydroxyantirno
nato, 9. 454
calcium tetrasulphate, 3. 811
cerous nitrite, 8. 496
chromato, 11. 262
cobaltous sulphate, 14. 781
diamminochromate, 11. 262
diamminomolybdate, 11. 559
dithionate, 10. 587
ferrous sulphate, 14. 297
fluotitanate, 7. 72
hexahydrotrisdiarson itodimolyb
date, 9. 131
lead nitrite, 8. 498
rnolybdate, 11. 559
nickel sulphate, 15. 474
oc tohy drobisdiarsen itodimoly b
date, 9. 131
pentafluodioxytungstate, 11. 839
phosphatoheinipentamolybdate,
11. 669
selenate, 10. 859
tellurite, 11. 99
tungstate, 11. 782
tungsten totramminoonneachlo
arsenides, 3. 98 ; 9. 62
weight, 3. 110
aurides, 3. 573
autunite, 12. 135
barium ammonium nitrite, 8. 488
silicate, 6. 373
beryllium alloys, 4. 668
beta, or /5, 3. 115
bisethylenediaminodithionate, 10. 587
bisethylenediamminonitrite, 8. 48O
bisethylenediaminopersulphate, 10.478
bisethylenediaminosulphite, 10. 274
-� bisethylenediaminotetrathionate, 10.
618
bisethylenediaminothiosulphate, 10.
535
bisethylenediaminotrithionate, 10. 609
bismuth alloys, 9. 635
arsenate, 9. 798
nitrate, 9. 710
thiosulphate, 10. 554
- bistx-imethylaminechloroplatinate, 16.
326
tetrasulphate, 3. 811
� arsenate, 9. 173
� carbonato-arsenate, 9. 173
hydroxy arsenate, 9. 174
hydroxyorthoarsenate, 9. 173
hydroxyorthovanadate, 9. 767
�� metadimetasilicate, 6. 372
ortho vanadate, 9. 767
potassium nitrite, 8. 488
tetrasulphate, 8. 811
pyrovanadate, 9. 767
tungstate, 11. 818
uranyl carbonate, 12. 116
vanadate, 9. 772
carbonate, 13. 615
carbonyl, 5. 951
catalysis by, 1. 487
catalytic, 3. 32
cement, 8. 3O
cerium alloys, 5. 605
chemical properties, 8. 69
chloride, 13. 609, 615
chloroantimonite, 9. 481
chloromo'tavanadate, 9. 809
chloroplatinite, 16. 281
chloroplumbite, 7. 73O
chlorostannate, 7. 449
Copper chromate, 11. 26O
chromium alloys, 11. 170
nickel alloys, 15. 245
iron alloys, 15. 327, 337
pentafluoride, 11. 364
steels, 13. 616
coarse, 3. 25
cobalt alloys, 14-. 529
nickel alloys, 15. 337
silicon alloys, 14. 536
zinc alloys, 14. 533
� cobaltic dichlorobisethylenediaminechloride,
14. 67O
hexamminopontachloride, 14.
656
� /tx-irnino-peroxo-quaterethylenediaxninonitrate,
14. 846
rnanganito, 12. 243
nitrite, 8. 504
pentamminotrisulphite, IO. 318
._ � trisethylenediaminopentachloride,'
14. 657
- cobaltite, 14. 594
�� eobaltous dioxysulphate, 14. 781
- hydrosulphate, 14. 781
__ _ iiitrate, 14. 828
�� sulphate, 14. 78O
trihydroxynitrate, 14. 828
� trioxydibromido, 14. 718
trioxydiohloride, 14. 641
trioxydisulphate, 14. 781
colloidal, 3. 31, 554, 563
compounds reduction, 3. IO
decafluodicorate, 5. 638
�� doeahy droxy or thoarsenate, 9. 162
decamminomonoxybischromate, 11.
262
-- dendritic, 3. 33
deuterotetravanadate, 9. 767
dialuminide, 5. 231
diamidodiphosphate, 8. 711
diarnrninodinitrito, 8. 48O
diamirdnodisilicate, 6. 341
diamminohexanitrite, 8. 479
� diamminomolybdato, 11. 559
--�- diamminoiiitrite, 8. 479
diamminotungstate, 11. 782
diantimonide, 9. 404
diethyldiamminoselenate, 10. 859
diheptitasilicido, 6. 172
dihydroarsenatomolybdate, 9. 208
dihydroxyrnanganate, 12. 288
dihy droxy or t ho vanadate, 9. 767, 778
dihydroxytetrachloroplatinic acid, 16.
334
diiodeciesdimethylaminechloroplatinate,
16. 326
diiodeviciesrnethylamininechloroplatinate,
16. 326
dioxide, 3. 116, 149
monohydrated, 8. 147
dioxyarsenite, 9. 121
dioxy chromate, 11. 261
dioxyorthotetravanadate, 9. 767
dioxytetrafluomolybdate, 11. 614
dipentitantimonide, 9. 403
dipentitaphosphide, 8. 838
dipentitarsenide, 9. 64
dipentitasilicide, 6. 172
diphosphide, 8. 839
VOL. XVI.
INDEX 529
778
� � tetroxychloride, 7. 742
16. 326
rod, 3. 117
refining, 3. 26
by electrolysis, 3. 27
rhodium alloy, 15. 564
rubidium selenate, 10. 86O
rust, 3. 270
ruthenium alloy, 15. 510
selenate, 10. 858
� thiocarbamate, 6. 132
thiohypophosphato, 8. 1063
tin alloys, 7. 347
� cadmium, 7. 361
calcium, 7. 361
chromium, 7. 361
cobalt, 7. 362
iron, 7. 362
manganese, 7. 362
nickel, 7. 362
lead, 7. 362
phosphorus, 7. 362
sodium, 7. 361
_ triamminomotantimonate, 9. 454
--- triarmriinoselenate, 10. 859
__ � tetrahydrate, 10. 859
� tritahoptastannide, 7. 351
� tritorodecavanadate, 9. 767
diammino, 9. 768
dodecammine, 9- 767
hexamraine, 9. 768
trithionate, 10. 609
trithiophosphate, 8. 1067
tritoxide, 8. 116, 118
tritungstate, 11. 811
tough pitch, 8. 27
tungstate, 11. 782
dihydrato, 11. 782
tungsten alloys, 11. 741
iron-nickel alloys, 15. 33O
nickel-tantalum alloys, 15. 251
uranate, 12. 63
uraniomica, 9. 216
uranite, 9. 216 ; 12. 43
uranium alloys, 12. 38
uranyl arsenate, 9. 215
phosphate, 12. 133
sulphate, 12. 110
uses, 8. 104
vanadates, 9. 766
vanadide, 9. 733
vitreous, 8. 7
voltameter, 1. 964
white, 15. 208
wool, 3. 32
world's production, 3. 6
X-radiogram, 1. 641
zinc alloys, 4. 67O
127
hydrosulphate, 4. 640
manganese alloys, 12. 207
._ .. _ oxychloride, 4. 546
phosphate, 4. 664
phosphatoarsenate, 9. 1 82
sulpharsonite, 9. 296
sulphates, 4. 639
basic, 4. 64<>
zirconate, 7. 136
zirconium, 7. 116
white, 4. 613
Coppite, 3. 623 ; 9. 291
Coprolito, 3. 623
Coprolites, 2. 1
Copulated compounds, 1. 219
Coquimbite, 12. 529 ; 14. 303, 307
Coquina, 3. 815
Coracite, 12. 4, 52
Coral, 3. 622
Coralline earth, 4. 696
� limestone, 3. 815
Corandite, 7. 896
Cordierite, 6. 809
ct-, 6. 809
�-, 6. 809
X-radiogram, 1. 6542
Cordylito, 5. 522
Cor indite, 5. 271
Corindon, 5. 247
Corkite, 7. 877 ; 9. 334 ; 12. 529 ; 14. 412
Cornotite, 3. 289
Corneus crystallosatus, 6. 821
fissilis, 6. 821
solidus, 6. 821
Cornish stone, 6. 467
Cornuite, 6. 342
Cornwallite, 9. 4, 161
Coronadite, 12. 279, 529
Corondito, 12. 149
Coronguite, 9. 343
Coronium, 4. 21 ; 5. 617 ; 8. 6
Corpse candles, 8. 803
Corpuscles ignees, 1. 6O
Corresponding states, 1. 759
Corrosion acid theory, 13. 408
� colloid theory, 13. 435
cimolia, 6. 496
fulIonia, 6. 496
rlispamca, 6. 4 29
� � Sartoria, 6. 429
Criehtonito, 7. 2, 57 ; 12. 529
Crispite, 7. 2, 3O, 34
Cristobalito, 6. 139
a.-, 6. 24O
� analyses, 6. 242
/3-, 6. 24O
preparation, 6. 237
Crith, 1. 174
metallorum, 9. 577
Crofting, 2. 243
Cromfordite, 7. 491, 852
Crompton's formula, 1. 835
Cronstedtite, 6. 623 ; 12. 529
Crookes' dark space, 4. 24
spinthariscope, 4. 8O
Crookesite, 3. 7 ; 10. 694, 782
Cross-stone, 6. 458
Crossite, 6. 913 ; 12. 529
Crucible steel, 12. 753
Crucilite, 6. 909
Crushers, 3. 497
Cryohydrates, 1. 517
Cryolite, 2. 1 ; 5. 154, 303, 304 ; 7. 896
� alumina-fluospar fusibility, 5. 167
fusibility, 5. 167
ash, 2, 715
glass, 5. 304
Cryophillite, 6. 607
Cryophylite, 2. 426
Cryosol, 1. 517
Cryosol, 7. 882
Cryphiolite, 4. 388
Cryptohalite, 6. 945
Cryptolin, 6. 562
Cryptolite, 5. 523
Cryptomorphite, 5. 4, 89, 93
Cryptoperthites, 6.
Cryptosiderites, 12.
Cryptotile, 6. 571,
Cryptotite, 6. 812
Crypto valencies, 1.
Crystal, 5. 711
axes, 1. 614
663
523
605
208
constants, 1. 615
ponds, 2. 525
rhythmic, 1. 599
speed of, 1. 455
synchronous figures, 12. 89O
zone of rapid, 1. 456
616
Crystallography, 1. 616
Crystallo-luminescence, 1. 6OO ; 2. 531
Crystalloids, 1. 77O
Crystals, 1. 693
acicular, 1. 597
seolotropic, 1. 610
allotrimorphic, 12. 876
anisotropic, 1. 610
architecture, 1. 616
biaxial, 1. 607
birth of, 1. 627
Curie's capillarity theory, 1. 628
dendritic, 1. 597
distortion, 1. 598
-� inclusions, 1. 592
interfacial angles, 1. 593
isotropic, 1. 6IO
liqxiid, 1. 642
regeneration, 1. 631
structure, 1. 623, 633
Crystolites, 7. 185
Crytholite, 7. 185
Crytolite, 7. 1OO
Cuban, 14. 192
Cubanite, 3. 7 ; 12. 529 ; 14. 183, 192
Cube ore, 9. 4, 226 ; 12. 529
Cubeite, 14. 328, 348
Cubic elasticity, 1. 82O
system, 1. 616
Cuprane, 8. 157
Cupranea, 3. 157
Cuprates, 8. 149
Cuprein, 3. 2IO
Cupreous lead sulphide, 7. 796
Cupri resina, 3. 157
Cupric acotylide, 5. 853
acid, 3. 149
a-stannate, 7. 418
tetrahydrate, 7. 418
aluminate, 5. 289
amminoazide, 8. 348
amminometasLlicate, 6. 341
amminopyrophosphato, 3. 291
ammonium a-stannate, 7. 418
amminosulphite, IO. 278
diammino-iodide, 8. 209
dichromate, 11. 337
dimotaphosphato, 3. 292�3
sulphate, 3. 255
anhydride, 3. 149
azide, 8. 348
basic, 8. 348
barium chloride, 3. 720
beryllium sulphate, 4. 241
bromide, 3. 192, 196
hydrated, 3. 196
properties, 3. 196
cadmide, 4. 683
calcium decachloride, 3. 719
disulphate, 3. 812
oxycarbonatoi>hoaphato, 3. 897
tetrachloride, 3. 719
carbide, 5. 853
oarbonatosilicates, 6. 343
chlorate, 2. 342
- ammino-, 2- 343
hydratod, 2. 342
chloride, 3. 157, 168
BaCl2-TCCl-TIaO, 3. 716, 72O
BaCl2-NaCl-H2O, 3. 716, 72O
BaCl2-NH4Cl-H2O, 3. 716, 72O
colour of soln., 3. 173
-� hexol, 3. 178
hydrated, 3. 168, 17O
preparation, 3. 168
properties, chemical, 3. 177
physical, 3. 169
trihydrated, 3. 17O
decamminobromido, 3. 198
��� decamminochloride, 3. 189, 19O
decamminoiodide, 3. 208, 209
diamminobromide, 3. 198
diamminocarbonate, 3. 275
diamminochloride, 3. 19O
diamminohydroarsonato, 9. 159
monohydrate, 9. 159
diammino-hydroxido, 3. 151
diamminohydroxyfluorido, 8. 156
diammino-iodide, 3. 209
diamminometasilicate, 6. 341
diamminooxybromide, 3. 198
diamminosulphate, 3. 252
diborate, 5. 84
dichromate, 11. 339
dihydro-orthosilicate, 6. 342
dihydrotetrachloride, 3. 183
GENERAL INDEX
dipyrophosphate, 8. 291
tetrametaphosphate, 3. 293
� dithiobate, 10. 586
hydrate, 10. 587
� pontahydrate, 10. 586
tetrahydrate, 10. 586
enneaoxysulphate, 3. 261
hypophosphate, 8. 936
iodide, S. 206
oxybromide, 4. 893
oxychloride, 4. 86O
oxynitrate, 4. 995, 998
sulphite, 10. 3OO
tetramminohexaiodide, 4. 936
�� tetramminotetrabromide, 4. 887
tetramminotetraiodide, 4. 936
me tabor ate, 5. 84
metaplumbate, 7. 698
metasilicate, 6. 341
hemihydrated, 6. 341
hydrated, 6. 342
monohydrated, 6. 341
nitrate, 3. 281
enneahydrated, 3. 281
� hexahydrated, 3. 281
properties, chemical, 3. 283
physical, 3. 282
trihydrated, 8. 281
nitride, 8. 1OO
nitrogen iodide, 3. 209
octochlorodithallate, 5. 447
hexahydrated, 5. 447
� __ octofluozirconate, 7. 141
octoxytrisulphate, 3. 265
orthoarsenato, 9. 158
� hexahydrate, 9. 158
monohydrate, 9. 158
. pentahydrate, 9. 159
. tetrahydrate, 9. 158
trihyd'rate, 9. 159
� orthocarbonate, 3. 27O
orthophosphate, 3. 287
orthosulpharsenate, 9. 318
� orthosulpharsenite, 9. 293orthosulphoantimonate,
9. 574
orthosulphoantimonite, 9. 537
� � hydrated, 3. 142
physical properties, 3. 133
prepax'ation, 3. 131
oxyazide, 8. 348
oxybromide, 3. 198
oxycarbonate, 3. 29O
oxychlorate, 8. 342
oxy chlorides, 8. 178
oxydisulphide, 3. 226
oxydisulphite, 10. 278
oxydithiocarbonate, 6. 124
__ oxyfluoride, 3. 156
oxymonosulphide, 3. 226
oxyoctochromite, 11. 198
oxypentasulphide, 3. 226
oxysulphate, 3. 266
oxysulphite, 10. 278
pontaborate, 5. 84
pentahydroxydicarbonate, 3. 269
pentahydroxylamine sulphate, 3. 256
pentametaphosphate, 3. 293
� pentamminobromide, 3. 198
pentamminochloride, 8. 19O
pentamminohexaiodide, 3. 209
pentamminonitrate, 3. 284
pentamminosulphate, 3. 251
pentasulphide, 8. 225, 226
Cupric pentoxy carbonate, 3. 268
pentoxydioarbonate, 8. 269
pentoxydisuiphate, 8. 265
perborate, 5. 120
perchlorate, 2. 399
ammino-, 3. 399
phosphates basin, 3. 288
platinous trans -sulphitodiamminosul
nitrite, 8. 480
selenate, 10. 859
thiosulphate, 10. 534
trisulphite, 10. 276
pyrophosphates, 3. 29O
pyrosulpharsenate, 9. 318
pyrosulpharsenito, 0. 293
salts, 3. 139 ; 11. 602
solenide, 10. 770
silicododecatungstate, 6. 877
silver nitrate, 3. 481
sulphide, 3. 447
--� sodium airitninosulphite, 10. 279
chlorophosphates, 3. 29O
� hexametaphosphate, 3. 293
phosphate, 3. 29O
silicate, 6. 341
sulphate, 3. 256
trimetaphosphate, 3. 292
sulphate, 3. 234
basic, 3. 261
dihydrated, 3. 237
electrolysis, 1. 962
� � - enneahydrated, 3. 237
heptohydrated, 3. 237
hexahydrated, 3. 237
monohydrated, 3. 235
Na2SO4-H2O, 3. 257
-� physical, 3. 238
_ solubility, 3. 237
. _ trihydratod, 3. 235
sulphide, '3. 22O
-. alcosol, 3. 225
colloidal, 3. 225
ethorsol, 3. 225
_ hydrosol, 3. 225
preparation, 3. 22O
properties, chemical, 3. 223
physical, 3. 222
sulphite, 10. 278
sulphomolybdate, 11. 652
tetraborate, 5. 85
tetradecafluodizirconate, 7. 141
tetrametaphosphate, 3. 293
tetramminochlorido, 3. 190
tetramminohexaiodide, 3. 209
tetrammino-hydroxides, 3. 151
tetrammino-iodide, 3. 209
tetramminonitrate, 3. 284
tetrammino-octoiodothallate, 5. 461
terramminoorthophosphate, 8. 29O
tetrammino-oxyfluoride, 8. 156
tetramminopyrophosphate, 3. 291
tetramminosulphate, 8. 251
hydrated, 8. 253
INDEX 537
X-radiogram, 1. 641
Cuprites, 3. 145
Cuproacetyloxide, 5. 851
Cuproadamite, 9. 181
Cuproautunite, 12. 4
Cuprobismuthite. 3. 7 ; 9. 69I
Cuprobismutite, 9. 589
Cuprobromides, 3. 195
Cuprocalcite, 3. 274
Cuprocassiterite, 7. 283, 417, 476
Cuprodosoloizite, 7. 491 ; 9. 715, 777
Cuproferrite, 14. 295
Cuprogoslarite, 4. 64O
Cuproiodargyrite, 3. 426
Cuprojarosite, 14. 343
Cupromagnesite, 4. 252
Cupromartial arsenate, 9. 224
Cupronickel, 15. 179
Cuproplatinum, 16. 6
Cuproplumbites, 9. 196
Cupropyrite, 14. 192
Cuproscheehte, 3. 623 ; 11. 678, 782, 818
Cuprosic amminosulpho thiosulphate, 10.
536
ammonium sulphite, 10. 278
Cuprosilieotitanium, 7. 12, 24
� � allylenide, 5. 853
__ a-stannate, 7. 417
triamminopentaiodide, 4. 936
triiodide, 4. 935
mercuroua oc to thiosulphate, 10. 549
mesosulphoctobismuthite, 9. 691
metaphosphate, 8. 287
metasulpharsenite, 9. 293
metasulphotetrabismuthite, 9. 691
INDEX 539
triamminoiodide, 8. 205
275
276
(tri)cuprous potassium dihydrotri sulphite,
10. 276
Cuprovanadito, 9. 778
(/uprovanaclium, 9. 726
Cuprozincite, 4. 648
Cuprum gummatBObum, 3. 157
nicolai, 9. 80 ; 15. 2
� sulphxiro mineralisatum, 3. 2IO
vitreum, 3. 2IO
Curio's capillarity theory of crystals, 1. 628
constant, 13. 267
law, 18. 267
Curite, 7. 491 ; 12. 4, 68
Current of electricity unit, 1. 963
Curves, breaks in solubility, 1. 513
Cyanide process, 8. 499, 504
� gold, 3. 305
silver, 3. 305
Cyanite, 5. 155 ; 6. 458
-� X-radiogram, 1. 642
Cyaroinochte, 2. 657 ; 3. 257
CyanochroiTie, 2. 657
Cyanoferrite, 14. 295
Cyanogen and CO2, 6. 32
Cyanolite, 6. 362
Cyanosite, 3. 7
Cyanotetrazote, 8. 339
Cyanotrichite, 5. 154, 353 ; 6. 344
Cyanurtriamide salts, 16. 314
Cyanus, 6. 586
Cyclic reactions, 16. 152
Cyeloborene, 5. 34
Cyclohexasiltrioxone, 6. 233
Cyclopeite, 6. 916
Cyclopite, 6. 693
Cylindrite, 7. 283, 491 ; 9. 552
Cymophano, 4. 206 ; 5. 294
Cyprian vitriol, 3. 234
Cypnne, 6. 726
Cvpruaite, 5. 154 ; 14. 328, 335
Cyptolite, 5. 512
Cyrtohte, 4. 206 ; 6. 846 ; 7. 167, 896 ; 12. 4
Czermak and Spirek's furnace, 4. 701
Dalarnite, 9. 306
INDEX
Daltonides, 1. 519
Law, 1. 93
Deduction, 1. 17
Dee, J., 1. 48
Deeckite, 6. 747
Degeroite, 6. 908
gases, 1. 79O
rays or S-rays, 4. 85
Delvauxene, 14. 411
Dolvauxite, 8. 733 ; 14. 408
Domantoid, 6. 921
Demidoffite, 6. 344
Domidovito, 6. 344
Demonium, 5. 504
Dendrite, 12. 267, 885
Dendritic crystals, 1. 597
Denebium, 5. 498
Density, critical, 1. 164, 762
current, 1. 1032
gases, 1. 175
reticular, 1. 628
Dental alloys, 16. 197
amalgams, 4. 1027
Dentrite, 12. 149
Dephlogisticated muriatic acid, 2. 21
INDEX 541
Devonite, 5. 274
Deweyhito, 5. 531
Deweylito, 6. 423
Dewindito, 7. 491
Dewpoint, 8. 9
Diabantito, 6. 623
Diaboleite, 7. 743
Diachylon, 7. 591
Diaclasite, 6. 392
Diagonite, 6. 758
Diallago, 6. 818
metalloide, 6 391
verte, 6. 392
759
Dialysis, 1. 771
colloids, 1. 774
Diamant brut, 7. 98
Diamantine, 5. 271
Diamide, 8. 308
10. 878
� � anthracitic, 5. 719
� black, 5. 72O
Cullinan, 5. 711
Excelsior, 5. 711
� Florentine, 5. 711
Genesis, 5. 731
occurrence, 5. 716
-- Orloff, 5. 711
Pitt, 5. 711
polymorphic, 5. 757
Regent, 5. 711
* Sancy, 5. 711
Victoria, 5. 711
X-radiogran, 1. 64O
Diamonds, 12. 859
Matura, 7. 98
synthesis, 5. 730
Dianite, 9. 906
606
Diasporite, 5. 249
Diastatite, 6. 821
r>iatoiiute, 6. 142
Diazobenzene, 8. 308
, iso-, 8. 297
Diborane, 5. 36, 37
Diboron dihydi-oxido, 5. 4O
� hoxahydndo, 5. 37
monobromohydndo, 5. 37
rnorioohlorohydrido, 5. 37
Dibromodichlorosilano, 6. 98O
!Dibromodiiodosilane, 6. 984
Dibromosilane, 6. 977
Dibroinosilicomethane, 6. 979
Dichlorobisdimothylglyoximorhoclous acid,
15. 577
IMchlorodiiodosilane, 6. 983
INDEX
11. 365
Dickinsonito, 12. 149, 455 ; 14. 396
Dieksbergite, 7. 23O
Dicobaltie ^-acetato-amino-ol-hexammines,
14. 710
diol-hexammines, 14. 7IO
acetatoaquo-/x-acetato-ol-hexammines,
14. 709
it-amidonitrito-octamminoselenate, 8.
510
quaterethylonediamines,
14. 709
ol-octamminos, 14. 709
� peroxo-hexammines, 14.
710
quatorethylenediaminos,
14. 709
poroxo-ootamminos, 14. 709
/z-ammonium-peroxo-quatorethylenediamines,
14. 709
bromoaquo-ft-amino-octammines, 14.
708
chloroaquo-/Lt-amino-octamminos, 14.
708
chloronitrate-/i-amino-octammines, 14.
708
/x-diamino-octammines, 14. 709
diaquo-/x-acetato-amino-hexamminos,
14. 709
/z-amino-ol-hexammines, 14. 709
diol-hexammines, 14. 708
� dichloro-/z-amino-nitrohoxammines,
14. 709
� peroxo-hexammines, 14.
709
/i-nitro-ol-hexamminos, 14. 709
dinitrato-diol-hexammines, 14. 708
� /tt-tlinitro-ol-hexammines, 14. 710
� diol-octammines, 14. 708
quaterethylene-diamincs, 14.
708
/x-hydroxyaquo-peroxo-ol-hexammines,
14. 709
/x-imino-peroxo-quater-ethylenediamines,
14. 709
nitratoaquo- /i - amino - octammines, 14.
708
� ol-hexammines, 14. 709
� diol-hexammines, 14. 709
- /i-nitritodihydroxyhexanaminoselenate,
8. 511
/x-nitro-diol-hexammines, 14. 7IO
peroxo-decammines, 14. 707, 708
quaterethylenediamines, 14.
708
/x-imi no-octammines, 14. 708
tetrabromo-/x-hexammines, 14. 708
GENERAL INDEX
Dicobaltic tetrachJoro-jx-amino-hexainrnine,
14. 708 �
tetranitrito-/Lt-solenatohexammine, 8.
51O
thiocyanatochloro-/i,-amino-octammines,
14. 708
trichloroaquo-/x-amino -hexammines,
14. 708
trichlorohydroxy-peroxo-hexamminos,
14. 708
trichloronitrato-/*-amino-hexammines,
14. 708
apatite, 5. 675
bismuth sulphate, 9. 7Ol
borate, 5. 104
borotungstate, 5. 110
bromato, 2. 354carbonate,
5. 665
- chloride, 5. 642
ohloroplatinito, 5. 643 ; 16. 284
chromato, 11. 287
cobaltous nitrate, 14. 828
. diborocyanido, 5. 643
metatungstate, 11. 826
motavanadate, 9. 755
nickel bromide, 15. 429
nitrite, 8. 496
oxyoctoselonite, 10. 831
paratungstate, 11. 819
perchlorate, 2. 402
Didymolite, 6. 767
683
Dienerite, 9. 79
gases, 1. 338
nitc, 8. 518
cobaltic dihydroxyoctamminototrachloride,
14. 674
potassium palladous tetranitrite, 8
514
� tetranitritoplatinite, 8. 518
rubidium tetranitritoplatmito, 8. 519
Dimetaphosphates, 8. 985
Dimetaphosphimic acid, 8. 717
Dimethyl-o-toluidinium bromopalladite, 15.
677
bromosmate, 15. 723
chloroiridate, 15. 77
chloropalladite, 15. 67O
�jo-toluidinium bromosmate, 15. 723
Diphosphoryl anhydrosulphatohexachloride,
10. 346
titanium decachloride, 7. 85
I3ipnosphotriam.id.ic acid, 8. 711
Diplasites plumbicus, 7. 681
Diplatinio ammonium triacontatungstate,
11. 803
' barium triacontatungstate, 11. 803
mercurous triacontatungstate, 11. 803
potassium triacontatungstate, 11. 803
thallous hexasulphoplatinate, 16. 396
Diplatinous cadmium hexasulphoplatinate,
16. 396
copper hexasulphoplatinate, 16. 396
dinitritodihydrazinodiamminosulphate,
8. 517
dinitritodihydroxylaminodihydrazinosulphate,
8. 517
dinitritodihydroxylaminoethylenedi aminodiammine,
8. 517
ferrous hexasulphoplatinate, 16. 396
lead hexasulphoplatinate, 16. 396
manganese hexasulphoplatinate, 16.
396
silver hexasulphoplatinate, 16. 396
sodium hexasulphoplatinate, 16. 395
stannic hexasulphoplatinate, 16- 396
seine hexasulphoplatinate, 16. 396
Diplosis of gold, 1. 49
Diplumbie acid, 7. 685
Dipotassium silver cobaltic hexanitrito, 8.
504
sodium cobaltic nitrite, 8. 504
Dippel, J. K., 1. 52
Dipropyl stannone, 7. 4IO
Dipropylarnmonium bromopalladate, 15.
678
bromoperruthenite, 15. 538
bromoru then ate, 15. 538
bromosmate, 15. 723
chloroiridate, 15. 77O
chloropalladato, 15. 673
ehloroperruthenite, 15. 532
chlororhodate, 15. 579
chlororuthenate, 15. 534
chlorosmate, 15. 719
Dipyro, 6. 763
Dipyridyl, 16. 273
Direct metal, 12. 709
process iron, 12. 635
Directed valencies, 4. 186
Discenite, 9. 4
Discharge electric in gases, 4. 24
potential, 1. 1031
Discontinuous spectrum, 4. 5
Discrase, 9. 404
Diselenatouranic acid, 10. 877
Diselonotrithionate acid, 10. 928
Diselenotrithionic acid, 10. 925
Disglomeration, 7. 302
Disilane, 6. 216, 222
Disilanic acid, 6. 216
Disilene, 6. 216
Disilenyl, 6. 216
Disilicane, 6. 222
Disiloxane, 6. 233
Disilver potassium cobaltic hexanitrite, 8.
504
Disilyl, 6. 216
Disilylamine, 8. 262
VOIi. XVI.
INDEX 545
INDEX
law, i. 798
� �� rule and atomic weights, 1.
804
. quantum theory
of energy, 1.
811
meaning of, 1. 808
Dumas' process vapour density, 1. 184
Dumesite, 6. 624
Dumontite, 12. 4
Dumortierite, 6. 462
Durnreicherite, 4. 252 ; 5. 154, 354
Dundasite, 7. 855
Dunito, 6. 386
Duralumin, 1. 279 ; 5. 237
Durangite, 5. 155 ; 9. 4, 259
Durdenite, 11. 2 ; 12. 529
tetrahydrate, 11. 82
Duriron, 13. 559
Dussertite, 9. 227
Dust in air, 8. 1
Dutch metal, 4. 671
Dyad, 1. 224
Dyads, 1. 206
Dycrasite, 9. 343
Dynamic allotropy, 5. 723
Dynamical electronic hypothesis valency, 8.
1091
Dynamite, 2. 829 ; 6. 289
Dyne, 1. 692
Dysanalyte, 7. 3 ; 9. 863, 867
Dyscrasite, 3. 3OO ; 9. 404
Dyskrasit, 9. 404
Dysluite, 5. 154, 296, 297 ; 12. 149
Dyslytite, 8. 860
Dysprosia, 5. 499, 702
isolation, 5. 696
Dysprosium, 6. 696
ammonium carbonate, 5. 704
atomic number, 5. 700
weight, 5. 699
bromate, 2. 354
bromide, 5. 703
GENERAL, INDEX
Eakleite, 6. 360
Earth, 3. 619
alkali-alkaline tungsten-bronzes,
751
alkaline chlorosmates, 15. 72O
chrysopras, 6. 624
cimolian, 6. 496
coralline, 4. 696
Diana's, 6. 471
diatomaeeous, 6. 142
(elements, 1. 31
fuller's, 6. 496
inflammable, 1. 64
Lemnian, 6. 47 I
mercurial, 1. 64
porcelain, 6. 472
porcellana, 6. 472
sinopisian, 6. 472
Earthenware, 6. 514
Earths, 5. 494
alkaline, 5. 494
history, 1. 383
rare, 5. 494
Earthy cobalt, 14. 424
manganese ochro, 12. 267
Eau do chaux, 3. 676
Javelle, 2. 243, 268
Labarraque, 2. 244, 268
oxygenee, 1. 936
regale, 8. 618
Ebelmenite, 12. 266
Ebers' papyrus, 1. 26
Ebigite, 12. 4
Ebullition, see Boiling
Ecdemite, 7. 491 ; 9. 4, 257
Echellite, e. 717
Ectogan, 4. 531
Ecume de mer, 6. 427
Edelite, 6. 718
Edelpatina, 3. 78
Edenite, 6. 391, 821 ; 12. 149
Edingtonite, 8. 625 ; 6. 575, 751
Edisonite, 7. 30
Edwardsite, 5. 523
Effect, 1. 13
Efflorescence, 1. 81, 502
Effusion gases, 1. 342
Egeran, 6. 726
Eggonite, 6. 442
Eglestonite, 2. 15 ; 4. 697, 805
Egypt, 1. 24
Elements, Anaximedes, 1. 32
Aristotle, 1. 33
asteroidal, 4. 3
Bridge, 1. 257
classification, 1. 249, 263
common, 4. 3
devolution, 4. 156
distribution of, 1. 272
electrochemical series, 1. 1Ol 3
electronegative, 4. 176
electropositive, 4. 176
Empedocles, 1. 33
� evolution, 4. 156 -
Lockyer on, 4. 21
� Bieracleitus, 1. 32
� heterologous, 1. 267
� isotopic, 4. 50, 13O
� missing, 1. 261
� mixed, 4. 158
Emulsoids, 1. 770
Enantiomorphic allotropy, 5. 723
Enantiomorphism, 1. 596 ; 5. 723
Enargite, 3. 7 ; 9. 4, 317
Enceladite, 7. 54
Encre sympathetique, 14. 421
Endeiolite, 5. 52O ; 6. 83O
Endellione, 9. 550
Endellionite, 9. 550
Endeolite, 7. 100
Endlichite, 7. 491 ; 9. 4, 261, 809
Endosmosis, 1. 539
Endothermal compounds, 1. 707
Endrometer, Volta, 1. 144
Energetic hypothesis of matter, 1. 691
Energetics, first law of, 1. 693, 694
atomic, 1. 785
available, 1. 717
bound, 1. 716
chemical, 1. 1Ol 1
conservation matter and, 1. 695
cost of reaction, 1. 716
degradation and eutropy, 1. 726
of gases, 1. 792
� - intra-atomic, 4. IHO, 155
kinetic, 1. 696, 712
persistence, 1. 692
. transformation, 1. 689
mass factor, 1. 712
nonproductive, 1. 721
potential, 1. 696, 727
��� quantity factor, 1. 712
quantum theory, 1. 811
�� relation of electrical and thermal, 1.
1036
stability function, 1. 727
strength factor, 1. 712
surface, 1. 712, 846, 847
total, 1. 717
transformations of, 1. 689
units of, 1. 693
volume, 1. 712
Engelhardite, 6. 857
Engel's magnesia potash process, 4. 369
English drops, 2. 781
red, 10. 351
salts, 4. 249
Enneabromodiperrhodite pepridinium acid,
15. 580
Enneachloroditungstic acid, 11. 842
Enneachloromolybdous acid, 11. 618
Enneamercuriammonium iodide, 4. 924
Enneamerouric ammonium cioosichloride, 4.
851
INDEX 549
10. 540
Ennerohexaphosphoric acid, 8. 992
Enophite, 6. 423 ; 12. 529
Enstatite, 1. 521 ; 6. 390, 391, 408
Eotvos' rule, 1. 855
Eolido, 10. 915
Eosite, 9. 715
Eosphorite, 5. 155, 370; 8. 733; 12. 149,
aluminium, 6. 722
-� cerium, 5. 510
iron, 6. 722
magnesia, 6. 722
manganese, 6. 768
� manganesoifcro, 6. 768
orthates, 5. 510
X_radiogram, 1. 642
Epidymite, 6. 38O
Epigenite, 3. 7 ; 6. 894 ; 9. 4, 324 ; 12. 529
Epinatrolite, 6. 654
Epiphanite, 6. 62 ; 12. 529
Episomorphs, 1. 662
Epistilbite, 6. 575, 760
Epistolite, 6. 838 ; 7. 3 ; 9. 839, 867
Epongo m6tallique, 12- 767
Epsom salts, 4. 249, 252, 321
Epsomite, 2. 430 ; 4. 252, 321
Epsornito, 15. 9
Equation building, 1. 361
characteristic, 1. 161
� gas, 1. 161, 754
� Clausius', 1. 761
�� -Diotoriei's, 1. 758
temperature, 2. 145
Equilibrium, 2. 141
apparent, 1. 715
chemical, 1. 730
732
metastable, 1. 715
pressure, 1. 348
stable, 1. 714
Equivalent, 1. 187
chemical, 1. 964
electrochemical, 1. 964
transparency, 4. 32
weights, 1. 79, 99
Equla, 10. 1
isolation, 5. 696
550 GENERAL INDEX
Erbium, 5. 696
ammonium sulphate, 5. 704
atomic number, 5. 7OO
weight, 5. 699
bromato, 2. 354
chlorate, 2. 354
chloroplatinate, 16. 330
chloroplatinite, 16. 284
chromate, 11. 288
dihydrotetraselenite, 10. 831
dioxysulphate, 5. 704
dithionate, 10. 594
dodecanitritotriplatinite, 8. 521
earths isolation, 5. 696
hexaiodohexanitritotriplatinite, 8. 523
hydroxide, 5. 703
iodato, 2. 354
isolation, 5. 554
nitrate, 5. 704
nitride, 8. 115
occurrence, 5. 696
oxide, 5. 702
� oxychloride, 5. 703
peroxide, 5. 703
potassium sulphate, 5. 704
properties, S. 698
selonate enneahydratod, 10. 872
octohydrated, 10. 872
selenite, 10. 831
enneahydrato, 10. 831
� pentahydrato, 10. 831
silicododecatungstato, 6. 880
sodium pyrophosphate, 5. 704
tungstato, 11. 791
solubility of hydrogen, 1. 307
� sulphate, 5. 703
sulphite, 10. 302
Krcinito, 6. 766
Erdmannite, 4. 206 ; 5. 509 ; 6. 451 ; 7. 100
Eremite, 5. 523
Erg, 1. 692
Erikite, 5. 529 ; 6. 835
Erinite, 6. 498 ; 9. 4, 161, 162
Eriochaloito, 3. 168
Erionite, 6. 768
Errite, 6. 896
Error, probable, 1. 131
Ersbyite, 6. 763
Erubescono, 14. 189
Erubescite, 12. 529 ; 14. 189
Eryophylite, 2. 426
Erythrite, 6. 663
Erythrine, 9. 228
Erythrite, 9. 4, 228 ; 14. 424 ; 15. 9
Erythrochromic dithionate, 10. 596
Erythroconite, 9. 291
Erythronium, 9. 714
Erythro-salts, 11. 408
Erythrosiderite, 2. 15 ; 12. 529
Erzalum, 4. 613
Escarboucle, 8. 730
Escherite, 6. 721
Eschewegite, 12. 6
Eschimite, 9. 839
Eschwegeite, 9. 839
Esmarkite, 6. 449, 811
Esmeraldaite, 12. 529
Esmeraldite, 18. 895
Espumilla, 2. 711
Essonite, 6. 715
Estano, 7. 276
Estrichgyps, 3. 774
Etain, 7. 276
Etch figures, 1. 611
Ethane and CO2, 6. 32
Ether, 18. 615
and CO8, 6. 32
solubility in water, 1. 523
Etherine theory, 1. 217
Ethers, 1. 389
Ethoxyorthodisilicate (hexa), 6. 310
Ethyl acetate and hydrogen, 1. 304
alcohol, 16. 277
and hydrogen, 1. 303
amidosulphinate, 8. 634
ammonium(tetra) metasilicate, 6. 329
�� antimony pentabromide, 9. 493
�� chloride, 13. 615
chloro-/3-thiocarbonate, 6. 120
ferrisulphate, 14. 319
ferrodinitrosylsulphide, 8. 442
hexamotaphosphate, 8. 989
hypophosphato, 8. 932
�� metasilicate, 6. 309
orthosilicate, 6. 309, 972
orthothiooarbonate, 6. 119
--- silicic acid, 6. 309
silicon(di) dichloride, 6. 309
oxide, 6. 3O0
(tri) acetate, 6. 309
hydroxide, 6. 309
trichloride, 6. 309
stannic bromide, 7. 455
chloride, 7. 446
iodide, 7. 463
stannone, 7. 410
stibonium iodomercuriato, 9. 407
� sulphide, 15. 762
sulphite symmetrical, 10. 240
unsymmetrical, 10. 24O
sulphone, 10. 162, 238
sulphonic acid, 10. 239
chloride, 10. 239
sulphoxide, 10. 238
thiolcarbamate, 6. 1 32
thioncarbamate, 6. 132
trithiocarbonato, 6. 120
ultramarine, 6. 590
Ethylallylaminetrichloroplatinous acid, 16.
273
Ethylamine, 15. 762
uranyl phosphate, 12. 132
Ethylammonium bromoiridate, 15. 776
� bromopalladate, 15. 678
bromoperruthenito, 15. 538
bromoruthonate, 15. 538
bromosmate, 15. 722
chloroiridate, 15. 770
chloropalladate, 15. 673
chloropalladite, 15. 670
chloroperruthenite, 15. 532
chlororhodate, 15. 579
chlororuthenate, 15. 534
chlorosmate, 15. 719
ferric fluorides, 14. 7
fiLuoferrate, 14. 8
heptachloroferrate, 14. 101
heptachloroperruthenite, 15. 533
tetrachloroferrate, 14. 101
Ethylanilinium hromopalladite, 15. 677
GENERAL INDEX
Facellite, 6. 571
Factor, capacity of energy, 1. 7X2
intensity of energy, 1. 712
mass of energy, 1. 712
quantity of energy, 1. 712
strength of energy, 1. 712
Factors of energy, 1. 712, 1011
Facts, 1. 5
empirical, 1. 8
Faltspath, 6. 661
Fahlerz, 3. 7 ; 4. 406 ; 9. 4, 291, 589 ; 15. 9
mercurial, 9. 291
Fahlite, 9. 291
Fahlkupferorz, 9. 291
Fahloros mercurial, 4. 697
Fahlun brilliants, 7. 63O
Faience, 6. 513
Fairfieldite, 3. 623 ; 8. 733 ; 12. 149, 454 ;
14. 396
Falerts, 9. 291
Falkenhaynito, 9. 291, 536
Falkstoinmark, 6. 472
False equilibrium, 1. 715
ore, 15. 419
Famatinito, 3. 7 ; 9. 343, 573
Farad, 1. 963
Faraday's dark space, 4. 24
effect, 4. 19
gold, 3. 554
laws electrolysis, 1. 963
Faratsihito, 6. 907
Furgito, 6. 652
Farina arsenical is, 9. 90
Faroelite, 6. 709
Faserblende, 4. 408
Faserkiesel, 6. 455
Fasserzeolith, 6. 758
Fassaite, 6. 39O, 817
Faujasite, 6. 575, 747
Fauserite, 4. 252 ; 14. 149, 422
Fava, 7. 124
Fayalite, 6. 386, 906 ; 12. 529
manganese, 6. 906
zmo, 6. 906, 909
Feather-alum, 14. 299
mica, 6. 613
FedorofTs crystallochomical analysis, 1. 616
Fehling's solution, 3. 120
Feldspar, 6. 662
Feldspath krummbl&ttiger, 6. 663
Felite, 6. 556
Felsite, 6. 663
Felsobanyite, 5. 154, 338
Felspar, 6. 661
aventurine, 6. 693
baryta, 6. 698, 706, 707
blue, 3. 274 ; 5. 370
csesia, 6. 662, 668
ferric, 6. 695
glassy, 6. 662
Kapnik, 6. 896
Labrador, 6. 693
lazur, 6. 663
lead, 6. 662, 698
lithia, 6. 662, 668
magnesia, 6. 662, 698
rubidia, 6. 662, 668
strontia, 6. 662, 698, 707
formation, 14. 40
fluosilicate, 6. 957
fluotitanate, 7. 73
guanidinium paratungstate, 11. 82O
heminitrosylchloride, 14. 81
hen ripen tahy dr ohernihennachloride,
14. 75
hemiphosphorylehloride, 14. 82
homitrihydroheniennachloride, 14. 75
heptoxysulphito, 10. 312
��� hexacolumbate, 9. 868
hexahydroxypentasulphate, 14. 329
hexaiodohexanitritotriplatinite, 8. 523
� hexametaphoHpliate, 14. 415
hexamminobromide, 14. 124
hexamminochloride, 14. 79
hcxamminosulphate, 14. 32O
hoxantipyridinoborofluoride, 14. 8
boxaquocbloride, 14. 47
hydrazinochloride, 14. 80
hydroarscnate, 9. 226
hydrodiselenite. 10. 84O
hemienneahydrate, 10. 840
� hydroxysulphatophosphatarsenate,
9. 334
hydroxytetrasulphate, 14. 349
�- oxytriaulphate, 14. 349
leucite, 6. 649, 919
lithium chloride, 14. 102
manganous phosphate, 14. 4X2
magnesium alum, 14. 348
ferrous trisulphate, 14. 353
hydroxysulphide, 14. 194
tetrahydrotrisulphate, 14. 348
tetrasulphate, 14. 348
� pentamminochloride, 14. 80
310
heptasulphate, 14. 339
hexafluorido, 14. 8
hydrophosphite, 8. 92O
hydroxytetrasulphate, 14. 343
metasilicate hydratod, 6. 92O
nitrate, 14. 387
oxyseptieschromato, 11. 310
pentachlorido, 14. 102
pen tadecoxydecieschro mate, 11.
310
pentoxydecieschromate, 11. 3IO
phosphate, 14. 410
pyroarsonate, 9. 227
solenatosulphate, 10. 930
sulphatoselenate, 10. 93O
sulphide. 14. 182
triorthoarsonate, 9. 227
trioxynovioschromate, 11. 3IO
~ pyroarsenite, 9. 133
pentahydrate, 9. 133
pyrophosphate, 14. 412
rubidium alum, 14. 344
� chlorobromido, 14. 77
415
dihydroxypyrophosphate, 14.
414
dimetasilicate, 6. 913
sulphatohypophosphites, 8. 890
sulphatophosphate, 14. 412
Bulphide, 14. 179
-~ -- aulphoantimonato, 9. 575
14. 125
trichlorobromide, 14. 125
trihydrodiarsenate, 9. 226
silicate, 6. 722
tetrorthotitanatosilicato, 6. 846
triorthosilicate, 6. 921
phosphite, 8. 889
Forrierite, 6. 749
Ferrikalite, 14. 344
Ferrimolybdite, 11. 573
Ferrmatrite, 14. 346
Ferr!pyrophosphates, 14. 413
Forrisulphatosulphitos, 10. 312
Ferrisulphuric acid, 14. 319, 320
Ferrisymplesite, 12. 529
Ferrite, 6. 388 ; 12. 776, 797, 863
Ferrochromotungstenovanadium carbide, 5.
900
Ferrooobaltite, 9. 308 ; 14. 424
Ferrogoslavite, 4. 613
Ferroilmenite, 9. 906
Ferromagnetism, 18. 244
Ferromanganese, 12. 194
carbides, 5. 9OO
Ferromanganowolframites, 11. 798
Ferromolybdenum, 13. 617
carbide, 5. 900
Forronatrite, 2. 656 ; 12. 529 ; 14. 328, 346
Ferro-nickel, 15. 257
enneacarbonyl, 5. 96O
Ferropallidite, 12. 529 ; 14. 245, 251
Ferropicolite, 13. 732
Ferroplatinurrx, 16. 5, 6, 216
Ferrorhodonite, 12. 149
Ferrosic arsenate, 9. 223
fluoride, 14. 3
hydrosulphate, 14. 299
oxychloride, 14. 35
phosphates, 14. 395, 397
amidosulphonate, 8. 644
amminobromide, 14. 12O
ammonium aquopentamminosulphate,
14. 290
arsenate, 9. 224
beryllium fluosulphate, 14. 297
bromide, 14. 121
carbonate, 14. 369
cobaltous sulphate, 14. 783
copper sulphate, 14. 297
dithionate, 10. 597
ferric octosulphate, 14. 351
antimonatosilicate, 6. 836
antimonito, 9. 433
antimony sulphide, 14. 168
aquoamminofluoride, 14. 3
�- aquohemiamminofluoride, 14. 3
aquopentamminofluoride, 14. 2
arsenate colloidal, 9. 223
hydrogel, 9. 223
arsenide, 9. 73
arsonite, 9. 133
auric iodide, 14. 133
azide, 8. 354
barium ferric ferry1 decametasilirate,
6. 922
orthosilicate, 6. 908
beryllium sulphate. 14. 297
bismuth chloride, 14. 35
nitrate, 9. 7IO
boracite, 5. 14O
borate, 5. 113
bromate, 2. 359
bromide, 14. 117
dihydrate, 14. 117
hemihydrate, 14. 117
hoxahydrate, 14. 117
monohydrato, 14. 117
preparation, 14. 117
tetrahydrate, 14. 117
bromostannate, 7. 456
cadmium hoxachloride, 14. 35
sulphate, 14. 299
sulphide, 14. 167, 194
caesium selenate, 10. 881
sulphate, 14. 293
tetrachloride, 14. 32
trichloride, 14. 32
calcium aluminium manganese borato-
silicato, 6. 911
chlorides, 14. 33
dialuminium boratototrorthosilicate,
6. 911
rnesozirconate, 7. 136
metasilicate, 6. 915
orthosilicate, 6. 908
phosphate, 14. 395
phosphatosilicates, 6. 835
carbide, 5. 894
carbonate, 14. 356
colloidal, 14. 357
complex, 14. 369
formation, 14. 357
preparation, 14. 357
properties, chemical, 14. 363
physical, 14. 358
558 GENERAL , INDEX
fluoferrite, 14. 4
chloride, 14. 9
fluoride, 14. 1
dihydrate, 14. 13
octohydrate, 14. 1
formation, 14. IO
tetrahydrate, 14. 1
hoxahydrate, 14. 12
preparation, 14. IO
fluotitanate, 7. 73 ; 14. 3
gas, 1. 123
physical, 14. 13
� tetrahydrate, 14. 13
heminitrosylchloride, 14. 26
-� chloroborate, 5. 114
heptachlorodibismuthite, 9. 668
chlorostannate, 7. 45O
hexadecaboratodibrornide, 5. 14O
hexaiodoplumbito, 7. 779
hoxamethylaminochloride, 14. 25
hoxamethylenetetramminochloride,
cobalt sulphoarsenitobismuthite, 9.
14. 28
696
hexamminochloride, 14. 24
columbatotantalato, 9. 905
� titariometasilicate, 6. 845
triphosphate, 14. 398
� tripotassium hoxachloride, 14. 32
� thiocarbonate, 6. 128
thiophosphate, 8. 1066
thiophosphite, 8. 1062
thiopyrophosphate, 8. 1070
thiosulphate, 10. 555
titanium sodium trimetasilicate, 6. 843
tourmaline, 6. 742
triamminosulphate, 14. 274
521
trioxysulpharsenate, 9. 329
tungstate, 11. 798, 801
Feuerblende, 9. 539
Feuerstein, 6. 14O
Feux follets, 8. 803
Fibroferrite, 12. 529 ; 14. 328, 333
Fibrolite, 6. 455
Fick's law of diffusion, 1. 536
Fiedlerite, 2. 3 5; 7. 737
Field of force about molecules, 4. 187
Fieldite, 9. 291
Fierroso, 4. 697
Figures, corrosion, 1. 611
etch, 1. 611
interference, 1. 6IO
Fillowite, 3- 623 ; 8. 733 ; 14. 149, 455
Finnemanito, 9. 5, 257, 262
Fire, 1. 55, 59
air, 1. 344
astral, 1. 64
blende, 3. 3OO ; 9. 539
(element), 1. 32
� � elemental, 1. 64
marble, 3. 815
matter, 1. 384
sacred, 1. 59
Fischaugenstein, 6. 368
Fischerite, 5. 155, 366 ; 8. 733
Fittig's reaction, 6. 966
Fixed alkalies, 2. 42O
Fixing soln., 13. 615
Fizelyite, 9. 55
Flajolotite. 9. 461 ; 12. 529
Flame, 1. 56, 61
electrical, 1. 882
musical, 1. 127
philosopher's, 1. 126
spectrum, 4. 7
Flannel, N., 1. 48
Flames in nitrous oxide, 8. 396
Flatus, 1. 61, 122
Flavite, 12. 745
Fleehes d'amour, 7. 34 ; 13. 877
Flours do �>iane, 5. 2
vitriol philosophique, 5. 2
Fliegelstoin, 9. 3
Fliegengift, 9. 3
Flinkite, 9. 5, 220 ; 12. 149
Flint, 6. 140
clays, 6. 477
Flints, liquor of, 6. 317
sulphur, 10. 19
tin, 7. 395
Flue dust, 7. 503
Fluellite, 2. 1 ; 5. 154, 3OO
Fluid magnesia, 4. 361
Flume, 3. 498
Fluoadelite, 9. 258
Fluoaluminates, 5. 303
Fluoarsenates, 9. 235
Fluoborates, 5. 125
Fluoboryl lead barium calcium diorthotri
silicate, 6. 890
Fluocerite, 5. 520, 637
Fluochlore, 5. 519
Fluochromie acid, 11. 365
Fluocolumbates, 9. 851
Fluodichromates, 11. 365
Fluodioxytungstatos, 11. 838
Fluohypomanganites, 12. 342
Fluomanganites, 12. 342, 347
Fluomimetito, 9. 259
Fluopentamminos, 11. 4<)3
Fluoperborates, 5. 129
Fluoperboric acid, 5. 129
Fluopyromorphito, 7. 882
Fluor, 2. 1
acid, 2. 3
apatite, 2. 1
lapis, 2. 3
Fluorencito, 5. 529
Fluoroscence si>eetrum, 12. 19
Fluorescent spectrum, 4. 7
X-ravs, 4. 35
Fluoridos/2. 137
acid, 2. 138
� complex, 2. 738
detection, 2. 135
determination, 2. 135
double, 2. 138
etching tost, 2. 1 35
hydroxy-, 2. 1 39
� � oxy-, 2. 139
� � thermochemistry, 2. 218
uses, 2. 134
Fluorine, 2. 3, 4
action acetone, 2. 13
ammonia, 2. 12
arsenic, 2. 12
trichloride, 2. 12
trifiuoride, 2. 12
��� trioxide, 2. 12
borates, 2. 13
boric oxide, 2. 12
boron, 2. 12
� trichloride, 2. 12
bromides, 2. 13
bromine, 2. 12
calcium carbide, 2. 3
carbon, 2. 12, 13
� dioxide, 2. 13
disulphide, 2. 13
monoxide, 2. 13
tetrachloride, 2. 13
carbonates, 2. 13
carbonyl chloride, 2. 13
chlorides, 2. 13
2 O
Fluorine action chlorine, 2. 11
chloroform, 2. 13
cyanides, 2. 13
cyanogen, 2. 13
ethylene tetrachloride, 2. 13
glass, 2. 12
hydrofluoric acid, 2. 12
hydrogen, 2. 11
bromide, 2. 12
chloride, 2. 12
iodide, 2. 12
sulphide, 2. 11
� iodides, 2. 13
iodine, 2. 12
metals, 2. 13
nitrates, 2. 13
nitrides, 2. 13
nitrogen, 2. 12
. peroxide, 2. 12
nitrous oxide, 2. 12
oxides, 2. 13
oxygen, 2. 11
ozone, 2.11
phosphates, 2. 13
phosphides, 2. 13
phosphorus, 3. 12
_ oxyfluoride, 2. 12
pentachloride, 2. 12
pentafluoride, 2. 12
pontoxide, 2. 12
� trichloride, 2. 12
selenium, 2. 11
�-� silica, 2. 12
. , silicon, 2. 12
.�__ tetrachloride, 2. 12
sulphates, 2. 13
�__ sulphides, 2. 1 3
sulphur, 2. 11
dioxide, 2. 11
sulphuric acid, 2. 11
_. telluritim, 2. 11
water, 2. 11
atomic weight, 2. 13
boiling point, 2. 10
bromine compounds, 2. 113
capillarity, 2. 10
chlorine compounds, 2. 113
colour, 2. 9
decomposition voltage, 2. IO
density (relative), 2. IO
dispersion, 2. IO
elementary nature, 2. 9
expansion (thermal), 2. 10
history, 2. 3
� � in bones, 2. 2
index of refraction, 2. 10
iodine compounds, 2. 114
magnetic susceptibility, 2. 114
melting point, 2. IO
mineral waters, 2. 2
molecular weight, 2. 13
occurrence, 2. 1
preparation, 2. 7
Arago's process, 2. 9
Moissan's process, 2. 8
Poulence and Meslans' process, 2
properties, chemical, 2. IO
physical, 2. 9
refraction, 2. 10
INDEX
Fluorine smell, 2. 9
spectrum, 2. 10
transport number, 2. IO
Fluorite, 2. 1, 3 ; 3. 688 ; 12. 149
stinking, 8. 692
Fluorium, 2. 4
Fluoroapatite, 3. 896
barium, 3. 9Ol
strontium, 3. 9Ol
Fluorocuprates, 3. 156
Fluoroheavy spar, 3. 802
Fluoro-iodic acid, 2. 363
Fluorspar, 2. 1, 3 ; 5. 530, 531 ; 7. 896 ;
12. 6
catalysis by, 1. 487
coloration, 3. 692
cryolite-aluminia fusibility, 5. 167
sp. gr., 5. 168
fusibility, 5. 167
stinking, 3. 692
X-radiogram, 1. 64O
Fluosilicates, 6. 934, 940, 944
Fluostannates, 9. 422
Fluosulphonates, 10. 684
Fluosulphonic acid, 10. 684
Fluotantalates, 9. 851, 914
Fluotelmrites, 11. 98
Fluotitanatos. 7. 69 ; 9. 851
Fluotitanites, 7. 66
Fluotitanous acid, 7. 66
Fluotrichromates, 11. 366
Fluovanadatapatito, 9. 801
Fluovanadimte, 9. 8Ol
Fluozirconates, 7. 137, 138
Fluss, 2. 3
Flusspath, 2. 3
Flusssaure, 2. 3
Flussspath, hepatic, 2. 1
stink, 2. 1
Flutherito, 12. 5
Flux density of magnetism, 13. 245
Foetid limestone, 3. 815
Fogs, chemical, 10. 401
Foie d'arsenic, 9. 116
Foliated tellurium, 3. 494
Folgerite, 15. 5, 445
Fondant de Rotrou, 9. 420
Fondon process extraction silver, 3. 303
Fonte, 12. 708
blanche, 12. 708
en gneuso, 12. 708
6puree, 12. 709
grise, 12. 708
malleable, 12. 709
mazee, 12. 709
truitee, 12. 708
Food-pastes, 13. 615
Footeite, 2. 15
Footeite, 8. 178
Forbesite, 9. 5, 232 ; 14. 424 ; 15. 5
Force, 1. 689
Foresite, 4. 206 ; 6. 759
Formaldehyde, 18. 615
Formatosodalite, 6. 583
Formic acid, 6. 72 ; 18. 613, 615
Formula weight, 1. 179
Formulae chemical compounds, 1. 223
constitutional, 1. 206
empirical for properties of solids, 1. 834
graphic, l."206
GENBRAI, INDEX
aabbro. 15. 9
Gabbronite, 6. 569, 762
Gabronite, 6. 569
Gadilonite, 4. 206
Gadolinia, 5. 502, 693
isolation, 5. 686
Gadolinito, 5. 508 ; 7. 185, 255, 896 ; 12. 529
Gadolinium, 5. 686
ammonium nitrate, 5. 695
atomic number, 5. 69O
weight, 5. 69O
� bromide, 5. 694
� carbonate, 5. 695
� chloride, 5. 693
� chloroaurate, 3. 595
� chloroplatinum, 16. 33O
� chromate, 11. 288
� cobaltous nitrate, 14. 828
� dihydrotetraselenite, 10. 831
� dithionate, 10. 594
� fluoride, 5. 693
� hydrazine sulphate, 5. 695
� hydroxide, 5. 693
� hydroxy carbonate, 5. 695
� hyposulphite, 10. 183
� isolation, 5. 551
� magnesium nitrate, 5. 695
� manganous nitrate, 12. 446
� metaborate, 5. 104
� nickel nitrate, 15. 492
GENERAL, INDEX
� fulginosum, 1. 122
laws and osmotic pressure, 1. 543
musti, 6. 1
pingue, 1. 122
sicum, 1. 122
sylvestre, 1. 122
uvarum, 6. 1
vinorum, 6. 1
� � equilibrium, 1. 152
kinetic theory, 1. 742
- liquefaction, 1. 868
� ��� molecular lieat, 1. 795
of, effect of pressiire, 1. 796
temperature,
1. 796
permanent, 1. 869
refractive index, 1. 681
separation "by diffusion, 1. 341
527
_ effect of pressure, 1. 529
-� in salt solutions, 1. 535
of mixed, 1. 533
specific gravity, 1. 175
heat, constant pressure, 1. 786,
787
volume, 1. 786, 787
thermal effects, compression, 1. 862
_ � . _�. expansion, 1. 862
fluoboriquo, 5. 126
Gearksutite, 3. 623 ; 5. 154, 309
Geber, 1. 4O
latin, 1. 40
pseudo-, 1. 40
Gedrite, 391. 396
Geekis, 14. 183
Gohlonito, 6. 713, 728
Geikielite, 7. 3, 54 ; 12. 529
Gel, 1. 771
Gelbbleierz, 11. 566
Gelbeisenerz, 14. 343
Gelbeisenstein, 13. 886
Gelberde, 6. 472
Gelberz, 11. 1, 2
Gemmahuzi, 6. 498
Genthite, 6. 932 ; 15. 5
Geocoronium, 8. 6
Geocronite, 7. 491 ; 0. 545
Geokronite, 9. 343, 545
Georgiadesite, 9. 5, 263
Gerhardtite, 3. 285
German silver, 4. 671 ; 15. 208
.209
fifths, 15. 209
firsts, 15. 209
weight, 7. 261
bromide, 7. 271
carbide, 5. 885
carbonates, 7. 275
chloride, 7. 269
chloroform, 7. 263, 27O
copper sulpharsenite, 9. 298
difluoride, 7. 268
� diiodido, 7. 272
dioxide, 7. 265
discovery, 7. 254
disulphide, 7. 274
colloidal, 7. 274
electronic structure. 7. 262
extraction, 7. 256
- fluorides, 7. 268
glass, 6. 522
hydrides, 7. 263
hydro trichloride, 7. 27O
hydroxide, 7. 265
iodide, 7. 271
iron alloys, 13. 576
isotopes, 7. 262
-preparation, 7. 256
� properties, chemical, 7. 259
physical, 7. 257
� sulpharsenite, 9. 3Ol
sulphates, 7. 275
_ _. sulphide, 7. 273
tetrabromide, 7. 271
tetrachloride, 7. 269
tetrafluoride, 7. 268
tetrahydride, 7. 263
tetraiodide, 7. 272
ultramarine, 6. 59O
Germanochloroform, 7. 270
Germanoethane, 7. 264
Gerrnanoformic acid, 7. 265
I Germanomethane, 7. 263
GENERAL
see
Gennanopropano, 7. 264
hydroxide, 7. 265
iodide, 7. 272
phosphate, 7. 275
oxide, 7. 265
sulphide, 7. 273
Germarite, 6. 392
Gersbyite, 5. 370
Gersdbrffite, 9. 4, 3IO ; 14. 424 ; 15. 5
Geyserito, 6. 141
and Helmholtz'i
spar, 6. 456
Glantz, 5. 713
Glantzkobolt, 9. 308
Glanzarsenikkies, 9. 306
Glanzersenstein, IS. 886
Glanzmanganerz, 12. 238
Glanzspath, 6. 456
Glaser, C, 1. 52
Glaserite, 2. 430, 657, 688
Glaserz, 3. 300
Glassv felspar, 6. 662
Glaskopf, 13. 877, 885
Glaskopfe, 18. 774, 775
Glass, 6. 520 ; 12. 19
Bohemian, 6. 522
borosilicate, 6. 522
bottle, 6. 522
crown, 6. 522
cryolitic, 5. 304
crystal, 6. 522
flint, 6. 522
INDEX
Jena, 6. 522
malleable, 6. 520
manufacture, 6. 522
muscovy, 6. 606
ore, 3. 300
phosphatosilicate, 6. 522
lime, 6. 522
pots, 6. 522
ruby, 8. 564
soda-lime, 6. 522
thallium, 6. 826
toughened, 6. 531
Glasses, germanium, 6. 522
Glasspat, 2. 3
Glassschorl, 6. 911
Glasstein, 6. 911
Glasurite, 6. 907
Glauber, J. R., 1. 52
Glauberite, 2. 430 ; 8. 623, 805
Glauber's iron tree, 14. 10
Glauchroite, 12. 149
Glaucochroite, 6. 894
Glaucodidymia, 5. 502
Glaucodote, 9. 4 ; 12. 529 ; 14. 424 ; 15. 9
Glaucodotite, 9. 309
Glaucodymia, 5. 502
Glaucolite, 6. 762
Glauconite, 6. 582, 919 ; 12. 529
� soda, 6. 92O
Glauconitic limestone, 3. 815
Glaucophane, 6. 391, 643 ; 12. 529
lithia, 6. 644
Glaucopyrite, 9. 74, 308
Glaucosiderit, 14. 390
Glaze salt, 6. 514
Glazed pig, 13. 558
Glazerz, 3. 438
Gleba, 10. 1
Glimmer, 6. 604
Glinkite, 6. 385
Globosito, 14. 411
Globulites, 1. 628
Glockerite, 11. 53O ; 14. 328, 335
Glossecollite, 6. 495
Glottalite, 6. 752
Glucinates, see Beryllonates
Glucine, 4. 205
Glucinium, see Baryllium
Glucinum, see Beryllium
Glucose and hydrogen, 1. 304
Gliihen, 12. 673
Glycerol and hydrogen, 1. 304
Glycerophosphoric acid, 8. 964
Glycine, 4. 205
Glycocol and hydrogen, 1. 304
Glycozone, 1. 946
Gmelinite, 6. 575
potassium, 6. 735
sodium, 6. 735
Gneiss, 15. 9
Gnomium, 14. 421, 525
Goblet-fiend, 9. 2
Goethite, 12. 63O ; 18. 877
- ammonium amminophosphatomolybdate,
11. 671
sodium pyrophosphatohemihenamolybdate,
11. 671
� dichlorobispropylenediaminetetrachloride,
14. 670
dichlorotetramminotetrachloride,
14. 669
� dichlorotetrapyridine tetrachloride,
14. 669
� hexamminobromosulphate, 14.
792
he xamminochlor osulphate, 14.
791
sulphodiacetatobisethylenediaminechloride,
14. 671
coinage, 8. 532
Gold nickel palladium alloys, 15. 652 Gold silver telluride, 11. 46
silicon alloys, 15. 231 tellurobismuthite, 11. 62
silver alloys, 15. 205 sodium alloy, 3. 571
�tungsten alloy, 16. 216 white alloys, 15. 651 ; 16. 219
iron alloys, 16. 219 world's production, 3. 493
mercury alloys, 16. 205 .2C-radiogram, 1. 641
nickel alloys, 16. 220 zinc alloys, 4. 682
palladium alloys, 16. 225 zmcide, 4. 682
silver alloys, 16. 205 zirconium, 7. 116
��� aluminium alloy, 16. 2IO Goldfieldite, 11. 2
copper alloys, 16. 205 Goldgltitte, 7. 644
zinc alloys, 16. 205, 207 Goldscheidewassor, 8. 618
Grammatite, 6. 404
Grammite, 6. 353
Granaten, weisse of, 6. 648
Granatite, 6. 909
QranatuB, 6. 714
Grand Mogul diamond, 5. 711
Grandidierite, 6. 917
Grandite, 6. 714
Granite, 7. 896
ware, 6. 515
Graphic teUuriurn, 3. 494
Graphite, 5. 714, 790 ; 12. 859
Greenalite, 6. 907
Greenlandite, 9. 906
Greenockite, 4. 409, 587
Greenovito, 6. 830 ; 7. 3 ; 12. 141, 149
Greenstone, 6. 405
Gregorito, 9. 704
Grenat, 6. 714
Fahlun, 6. 910
resinite, 6. 921
syriam, 6. 715
Griqualandito, 6. 913
Grochanite, 6. 622
Grochanites, 6. 621
Groddeckito, 6. 734
Groppite, 6. 812
Grothite, 6. 84O ; 7. 3
969
Griinbleierz, 7. 883
Griinoison's formula, 1. 834
Grunordo, 6. 92O
Grunerite, 6. 912
Guanajucitito, 9. 589
phosphitohoxamolybdato, 8. 919
836
Gulth, 3. 296
Gummispath, 7. 877
Gummite, 6. 494 ; 7. 491 ; 12. 5, 52
Gun-cotton, 2. 829
prismatic, 1. 597
tabular, 1. 597
Hacknianite, 6. 583
Haddainite, 9. 839
Haemafibrite, 9. 219
Haematite, 7. 896 ; 13. 774, 874
brown, 13. 886
columnar, 13. 775
compact, 13. 775
fibrous, 13. 775, 785
homisphooricus, 18. 885
micaceous, IS. 775
red, 13. 774, 775
specular, 13. 774, 775
Haamatolite, 5. 155 ; 9. 220
Hsematophanite, 12. 530 ; 13. 922 ; 14. 105
Hasinatostibirte, 9. 46O
Haemoglobin, 6. 11
Haematites, 12. 139, 530
X-radiogram, 1. 642
Haff sickness, 9. 43
Hafnefiordite, 6. 693
Hafnia, 7. 166
extraction, 7. 167
Hafnium, 5. 708 ; 7. 166
atomic weight, 7. 172
history, 7. 166
iodide, 7. 172
nitride, 8. 120
occurrence, 7. 166
oxalate, 7. 172
oxychloride, 7. 172
phosphide, 8. 847
properties, 7. 17O
salicylate, 7. 172
salts, 7. 170
selenide, 10. 784
sulphate, 7. 172
sulphide, 7. 172
tetrachloride, 7. 172
thorium zirconium orthosilicate, 7. 167
INDEX 571
HiLlebrandite, 6. 358
Hiorldahlite, 7. 100
Hippocrates, 1. 32
Hiranya, 3. 296
mangan-, 6. 908
Hislopito, 3. 814
History of chemistry, 1. 1
Hodgkinsonite, 6. 894
Hogbomite, 5. 298 ; 7. 3, 57
HooTnafibrite, 9. 5
Hoematolite, 9. 5
Hcernesite, 4. 252 ; 9. 5, J 76
Hoffmannite, 9. 73
atomic number, 5. 7 OO
weight, 5. 699
carbide, 5. 873
chloride, 5. 703
hydroxide, 5. 7(>3
isolation, 5. 553
nitrate, 5. 704
occurrence, 5. 696
oxide, 5. 702
propei-ties, 5. 698
sulphate, 5. 703
Holmquisite, 6. 644
Holmquistite, 12. 530
Holohedral symmetry, 1. 613
Holosiderites, 12. 523
Homberg's phosphorus, 3. 697, 74O
Homichlin, 14. 208
Homilite, 5. 4, 514 ; 6. 450
Homitite, 12. 530
Homoeomeriae, 1. 33
Homogeneous substances, 1. 86, 95
Homologous spectra, 4. 13
Homomorphism, 1. 663
Hooke's law, 1. 819
Hopcalcite, 5. 945
Hopeite, 4. 408, 658 ; 8. 733
a, 4. 658
�, 4. 658
Horbachite, 14. 136, 758 ; 15. 5
Horn lead, 7. 706, 852
asbestos, 6. 426
Labrador, 6. 391
soda, 6. 916
Hommangan, 6. 897
Hornstein, 6. 821 ,.
absolute, 8. 9
relative, 8. 9
specific, 8. 9
Hurnite, 6. 813
Hunterite, 6. 495
Huntilite, 4. 698 ; 9. 4, 64
Hureaulite, 4. 66O ; 8. 733 ; 12. 149, 448,
452
Hurka, 2. 711
Huronito, 6. 693
Hussakite, 5. 528
Hutchinsonite, 5. 406 ; 7- 491 ; 9. 4, 3O
Hvorlora, 6. 921
Wversalt, 12. 53O ; 14. 299
Hyacinte blanche de la Somma, 6. 762
do Visuvo, 6. 726
volcaniquo, 6. 726
Hyacinth, 7. 98, 100
Hyacinthe blanche, 6. 766
cruciformo, 6. 766
Hyacinthica figura, 6. 766
Hyacinthine, 6. 726
Hyacinthus, 7. 98
octodecahedricus, 6. 726
Hyalite, 6. 141
Hyalophano, 3. 625 ; 6. 662
Hyalosiderite, 6. 908
Hyalotecite, 6. 889
Hyalotekite, 7. 491
Hydracids, 1. 386
Hydrargillite, 5. 154, 274
Hydrargyri subchloridi ungentum, 4. 813
subchloridum, 4. 813
Hydrargyrum, 4. 695
Hydrargyrus calcinatus ruber, 4. 771
Hydrated. corous selenide, 10. 782
lime, 3. 673
salt, 1. 397
salts, 1. 498
Hydrazine, 8. 308
amidosulphonato, 8. 641
ammonium dihydrohypophosphate, 8
933
analytical reactions, 8. 320
anhydrous, 8. 310
arsenoehlorido, 0. 242
bisdihydrophosphate, 8. 328
bromoplatinate, 16. 376
carbonate, 8. 327
carboxylatedihydrazinate, 8. 317
cerium sulphate, 5. 659
chloroacetatobismuthite, 9. 682
chromium sulphate, 11. 454
chromous sulphate, 11. 435
cobaltous disulphate, 14. 774
hydrazinochloride, 14. 637
tetrachloride, 14. 637
� constitution, 8. 32O
� copper selenate, 10. 859
� cupric nitrate, 3. 286
sulphate, 3. 256
� cuprous thiosulphate, 10. 530
� dibromide, 8. 324
� dichlorido, 8. 323
� diphoride, 8. 323
� dihydrohypophosphate, 8. 932
� dihydrophosphate, 8. 328
� diiodide, 8. 324
� dinitrate, 8. 327
� dinitrite, 8. 473
� disulphate, 8. 325
� disulphinic acid, 8. 314
� disulphuric acid, 8. 314
� dithionate, 10. 583
� ditritaiodide, 8. 324
� ferrohoptanitrosyltrisulphide, 8. 441
� fluosilicate, 6. 946
� fluotitanate, 7. 7O
� gadolinium sulphate, 5. 695
� hexachloroantimonite, 9. 479
� hexachlorobismuthite, 9. 666
�hexahydrododecaborate decahydrated,
5. 81
� hydrate, 8. 310
� hydrazinocarboxylate, 8. 682
� hydrazinomonosulphonate, 8. 683
� hydrodisulphate, 8. 326
� hydrodithionate, 10. 583
� hydrophosphite, 8. 912
� hydrosulphate, 8. 325
� hydrosulphide, 8. 337
� lanthanum sulphate, 5. 659
hydrated, 4. 927
mercurous nitrate, 4. 784
� trihydrohypophoaphate, 8. 932
� uranite, 12. 43
uranium hydroxydisulphotetrauranate,
12. 98
hydroxyhydrodisulphotetrauranate,
12. 98
red, 12. 98
uranyl tetrachloride, 12. 90
yttrium sulphate, 5. 682
zinc, 8. 314
a-hydrazino-/8-aminoethane, 8. 671
Hydrazoates, 8. 344
Hydrazobenzene, 8. 308
constitution, 8. 341
physical, 8. 334
Hydrazonium, 8. 335
cobaltous tetrabromide, 14. 718
salts, 8. 322
selenite, 10. 821
sulphate, 8. 325, 326
Hydrides, 1. 326
and periodic Ia-W, 1. 328
Hydriodic acid, preparation, 2. 170
GENERAL INDEX
uses, 2. 134
Hydrofluorite, 5. 521
Hydrofluosilicic acid, 6. 934, 94O
�! dihydrate, 6. 942
monohydrate, 6. 942
tetrahydrate, 6. 942
Hydrofluostannous acid, 7. 422
Hydrofluotitanic acid, 7. 69
Hydrofluozirconic acid, 7. 138
Hydrogol, 1. 771
Hydrogen, 1. 264 ; 13. 606
action on oxides, 1. 328
salt solutions, 1. 328
activated, 1. 321, 322
allotropic, 4. 51
amalgam, 4. 753
�� amide, 8. 229
amidoide, 8. 229
amminophosphide, 8. 832
and chlorine, union in light, 2. 148
CO3, 6. 32
arsenide, 9. 48
atom, 4. 169
atomic, 1. 336
magnetism, 1. 322
refraction, 1. 316
volume, 1. 313
weight, 1. 335, 38O
autocombustion process, 1. 282
azide, 8. 323
boiling point, 1. 315
bromide hydrates, 2. 184
non-aq. soln., 2. 197
physical properties, 2. 173
preparation, 2. 167
� properties, chemical, 2. 200
solubility, 2. 182
by-product, 1. 286
calx, 1. 128
carbophosphide, 8. 847
chloride, 11. 368
and CO8, 6. 32
composition, 2. 208
hydrates, 2. 182
non-aq. soln., 2. 196
physical properties, 2. 173
preparation, 2. 158
properties, chemical, 2. 200
solubility, 2. 182
576 GENERAL.
INDEX
- hydroxylamine sulphate, 1.
941
hypochlorous acid, 1. 939
- hyposulphites, 1. 941
indigo, 1. 946
iron, 1. 943
sulphide, 1. 943
iodates, 1. 94O
iodic acid, 1. 940
iodine, 1. 939
GENERAL INDEX 577
Hydrogen peroxide action lanthanum oxide, Hydrogen peroxide action vanadium salts,
1. 943 1. 942
sulphide, 1. 943
VOL. XVI.
2 P
GENERAI. INDEX
yellow, 8. 83O
polysulphidos, 10. 154
preparation, 1. 125, 275
primordial, 4. 2
properties, 1. 126
purification, 1. 275, 287
reducing power, 1. 332
solenide, 10. 757
sical process, 1. 279
siliciurottod, 6. 216
silicol process, 1. 284
g]y�;erol, 1. 304
- -- glyeocoll, 1. 304
solubility in acetamide, 1. 304
� acetone, 1. 304
amidopropionic acid, 1. 304
ammonium chloride, 1. 303
hydrochloric acid, 1. 303
chloride, 1. 303
hydroxide, 1. 305
nitrate, 1. 303
sugar, 1. 304
sulphuric acid, 1. 303
toluene, 1. 303
urea, 1. 304
water, 1. 301, 302
� xylene, 1. 304
zinc sulphate, 1. 303
- isobutyl acetate, 1. 304
alcohol, 1. 303
� lithium chloride, 1. 303
specific gravity, 1. 313
� heat, 1. 315
ratio two, 1. 315
INDEX 579
Hypobismuthates, 9. 655
Hypoborates, 5. 38, 39
Hypobromites, 2. 250, 267
preparation, electrical processes, 2. 28O
uses, 2. 256
Hypobromous acid, preparation, 2. 243, 245
properties, 2. 250
anhydride, 2. 242
Hypochlorites, 2. 250, 267
constitution, 2. 257
preparation, electrical processes, 2. 276
uses, 2. 256
Hypochloronitric acid, 8. 618
Hypochlorous acid, preparation, 2. 243, 244
properties, 2. 250
anhydride, 2. 241
Hypoeutectic, 1. 518
iron (steel), 12. 799
Hypoiodique anhydride, 2. 291
Hypoiodites, 2. 250, 267
��� preparation, electrical pi'ocesses, 2. 280
Hypoiodous acid, preparation, 2. 243, 246
properties, 2. 25O
anhydride, 2. 242
Hypomanganous acid, 12. 225
Hypomercuromorcurosic sulphite, 10. 287
Hypomercurosic sulphite, 10. 287
Hyponitrites, 8. 407, 410
Hyponitritosulphates, 8. 687, 688
Hyponitritosulphuric acid, 8. 687, 688
Hyponitrosylic acid, 8. 407
Hyponitrous acid, 8. 382, 405
constitution, 8. 408
preparation, 8. 405
properties, 8. 407
anhydride, 8. 394
chloride, 8. 433
oxide, 8. 382, 394
Hypophosphates, 8. 931
Hypophosphitos, 8. 873
Hypophosphoric acid, 8. 924
dihydrate, 8. 930
dihydrated, 8. 928
monohydrate, 8. 93O
monohydrated, 8. 928
anhydride, 8. 923
Hypophosphorous acid, 8. 870
Hyporuthonites, 15. 517
Hyposclerite, 5. 531 ; 6. 663
Hyposiderite, 18. 886
Hypostilbite, 6. 759
Hyposulfite de soude, 10. 485
Hyposulphites, 10. 166, 180
Hyposulphitosodalite, 6. 583
Hyposulphuric acid, 10. 576
Hyposulphurous acid, 10. 166
constitution, 10. 176
preparation, 10. 166
properties, chemical, 10. 170
physical, 10. 169
anhydride, 10. 184
Hypotellurites, 11. 71
Hypotheses, 1. 57, 58, 59
rival, 1. 16
Hypothesis, 1. 13
verification, 1. 15, 30
Hypotribromites, 2. 252
Hypotri-iodites, 2. 252
Hypotyphite, 9. 3
Hypovanadates, 9. 743, 745
Hypovanad.atovaiiad.ates, 9. 792
Hypovanadatovanadatophosphates, 9. 826
Hypovanadic acid, 9- 744
Hypovanadite, 9. 740
Hyrgoi, 4. 708
Hystatite, 7. 2 ; 12. 530
Hysteresis, 1. 152
Ianthimto, 12. 5, 6O
Jatro-chemistry, 1. 50
Iberito, 6. 619, 812
Ice, anchor, 1. 464
-- hardness, 1. 466
plasticity, 1. 466
{see water), 1. 435
sheet, 1. 464
� slush, 1. 464
spar, 6. 662
stone, 5. 304
X-radiogram, 1. 465
Young's modulus, 1. 466
mangano, 6. 726
Idrialine, 4. 696
Idrialite, 4. 696
Idrisaite, 14. 328, 353
Idrociano, 3. 234
Idunium, 9. 714
Igelstrdmite, 6. 908 ; 13. 895, 916
Iglesiasite, 7. 491, 829, 855
Igneous corpuscles, 1. 56
Ignis caelestis, 1. 64
fatuus, 8. 803
subtilis, 1. 64
- tenuis, 1. 64
Ignition temperatures, 1. 485
Ihleite, 12. 530 ; 14. 303, 307
Ildeforsite, 9. 906
Ilesite, 12. 149
Iliorite, 7. 896
Illium, 15. 245, 251
INDEX 581
Illuderite, 6. 719
crystals, 1. 615
lndianite, 6. 495
Indiarubber, permeability to gases, 1. 309
� oxygen, i. 371
Indicator, 1. 389
Indicators and boric acid, 5. 59
Indices of crystals, 1. 615
acetylacetonate, 5. 398
weight, 5. 395
csesia alum, 5. 404
carbonate, 5. 405
chloroiodide, 5. 402
chloroplatinate, 16. 329
582 GENERAL INDEX
� oxybromide, 5. 4OO
oxychloride, 5. 399
oxysnlphite, 10. 301
perchlorato, 2. 402
__ phosphate, 5. 405
platinum alloy, 16. 2IO
properties, chemical, 5. 393
physical, 5. 39O
rubidia alum, 5. 404
selenate, 10. 870
selenide, 10. 781
selenite, 10. 830
sesquioxide, 5. 397
solubility of hydrogen, 1. 307
� sulphate, 5. 404
telluride, 11. 54
tribromide, 5. 401
� trichloride, 5. 399
trifluoride enneahydrated, 5. 399
trihydrated, 5. 399
trihydroxytetranitritoplatinite, 8. 521
triiodide, '5. 402
. trioxide, 5. 397
trisulphide, 5. 403
colloidal, 5. 403
tungstate, 11. 789
uranate, 12. 64
Induced radioactivity, 3. 1005 ; 4. 97
Induction, 1. 17
electrolytic, 8. 585
magnetic, 13. 245
period, 1. 295 ; 2. 149
of photochemical, 2. 149
Inert gases, 1. 263 ; 7. 889
occurrence, 7. 892
preparation, 7. 902
properties, physical, 7. 906
Inertia, 4. 160
Inesite, 6. 894 ; 12. 149
ionization, 4. 189
Internal energy, 1. 695, 717
of gases, 1. 792
friction, 1. 749
� pressure, 1. 841
work, 1. 695
liquids, 1. 841
Invar steels, 15. 257
Invariant systems, 1. 446, 447
Invasion coefficient, 6. 49
Inverarite, 14. 136 ; 15. 445
Inversion temperature, 1. 866
Tnyoite, 5. 91
Iodamide, 8. 605
Iodammonium iodide, 2. 620
ammine, 2. 620
Iodargyrite, 3. 426
Iodates, 2. 296
Iodatosodalite, 6. 583
Iodatosulphuric acid, 10. 689
trihydrate, 10. 689
preparation, 2. 291
properties, 2. 292
extraction from caliche, 2. 43
seaweed, 2. 42
fluorine compounds, 2. 114
hemianhydrosulphate, 10. 683
heptoxide, 2. 380
history, 2. 20, 23
hydrosol, 2. 98
in air, 8. 11
iodate, 2. 285, 292
isotopes, 2. 107
mol. wt., 2. 107
monobromide, 2. 122
monochloride, 2. 116
preparation, 2. 116
properties, 2. 117
monoxide, 2. 242
nitrate, 2. 292 ; 8. 621
occurrence, 2. 16
oxyfluoride, 2. 292
pentafluoride, 2. 114
pentitanhydrosulphatopentoxide, 10.
683
pentoxide, 2. 293
preparation, 2. 293
acid soln., 2. 82
organic solvents, 2. 84
salt soln., 2. 82
water, 2. 71
Millon's, 2. 292
sulphite, 2. 292
sulphoctochloride, 10. 646
sulphodecachloride, 10. 647
sulphoheptachloride, 10. 647
tetroxide, 2. 291
trianhydrosulphate, 10. 683
trianhydrosulphatopentoxide, 10. 683
trichloride, 2. 119
trioxide, 2. 281, 285
uses, 2. 96
valency, 2. 108
Iodite, 8. 426
Iodoargyrite, 3. 300
Iodoazide, 8. 337
Iodoboracites, 5. 9
INDEX 583
hydroxide, 2. 108
Ionizing potentials, 4. 16
weak, 1. 1015
Iozite, 12. 530 ; 13. 702
Iridic barium chloronitrite, 8. 514
� hexanitrite, 8. 514
sodium chloronitrite, 8. 514
hexanitrite, 8. 514
584 GENERA] INDEX
chloropentamminoohloroplatinate, 15.
762
chloropentamminohydrosulphate, 15.
783
chromium-molybdenum alloys,
18. 626
anthophyllite, 6. 912
337
lead alloys, 13. 579
molybdenum alloys, 13. 626
nickel alloy, 15. 312
15. 337
manganese alloys, 15. 313
zinc alloys, 15. 313
diarsenide, 9. 73
diberyllide, 13. 542
diboride, 5. 31
dicarbide, 5. 894, 896
dichroism, 18. 171
dichromide, 18. 587
dielectric constant, 18. 236
diffusion, 13. 28
dihydride, 18. 309
dimolybdide, 18. 619
dioxide, 18. 702, 925
-�
dipentitasilicide, 6. 200
direct process, 12. 635
diselenide, 10. 799
disilicide, 6. 201
distannide, 18. 676
disulphide, 14. 199, 202
317
ditritantimonide, 9. 412
ditritaphosphide, 8. 857
ditritarsenide, 9. 72
ditritasilicide, 6. 20O
ditungstide, 13. 629
dodecazincide, 13. 544
dodecitacarbide, 5. 897
ductility, 13. 67
earth, blue, 14. 390
effect carbon content on corrosion, 13.
461
vibrations, 13. 84
pentacarbonyl, 5. 958
pentahemiboride, 5. 31
pentitacarbide, 5. 896
pentitadinitride, 8. 133
sesquiphosphide, 8. 857
shearing stress, 13. 72
-� shock test, 18. 78
silicates, 6. 905
465
strength, 13. 35
tetracarbonyl, 5. 96O
tetrapentitarsenide, 9. 73
tetrarsenide, 9. 73
tetratriantimonide, 9. 412
tetratritaphosphide, 8. 857
tetritacarbide, 5. 894, 895
Jacinth, 7. 98
Jack-o'-lanterns, 8. 803
Jacksonite, 6. 718
Jacupirangite, 7. 124
de Saussure, 6. 694
Swiss, 6. 694
tenace, 6. 694
Jadeite, 6. 405, 643
de Ceylon, 7. 98
Jargonia, 7. 99
Jargonium, 7. 99
Jarosite, 12. 530 ; 14. 328, 343, 344
Jasper, 6. 140, 515
Egyptian, 6. 140
Jaspery clay ironstone, 13. 775
Jaspohamatite, 13. 775
Jaime brilliant, 4. 593
cadmium, 4. 593
INDEX
526
Julianite, 9. 4, 291
Julienite, 14. 424, 826
Junck6rite, 14. 355
Junonium, 4. 404 ; 5. 504
Jurinite, 7. 2
Jurupaite, 6. 420
Jval, 3. 296
Jvalita, 3. 296
K-radiations, 4. 36
Kammererite, 6. 622 ; 15. 9
Kiirarfvetite, 5. 523
Kaersutite, 6. 821, 823
Kainite, 2. 430, 657 ; 4. 252, 343 ; 7. 896
Kakochlor, 12. 266
Kakoxen, 12. 530
Kakoxene, 8. 733
Kalaite, 5. 155
Kalbaite, 6. 742
Kalgoorlite, 3. 494 ; 11. 2, 53
Kaliborite, 5. 4, 99
Kali carbonicum e tartan, 2. 714
magnesia, 2. 660
Kalinito, 2. 657 ; 5. 154, 342
Kaliophilito, 6. 571
Kaliophilites hydrated, 6. 574
Kaliphite, 18. 886
KaIk flusssaurer, 2. 3
Kalklabrador, 6. 763
Kalkmilch, 3. 676
Kalkowskito, 7. 6O
Kalkschaum, 3. 822
Kalkwasser, 3. 676
Kallais, 5. 362
Kallihte, 9. 696 ; 15. 5
Kallochrom, 11. 29O
Kaluszite, 3. 623, 808
Kamacito, 12. 528 ; 15. 26O
Kamasite, 12. 53O
Kammkies, 14. 218
Kampylite, 7. 491
Kanaka, 1. 22
Kancelstein, 6. 715
Kaneite, 2. 149
Kane's salt, 4. 788
4. 785
Kaolin, 6. 467
a-, 6. 47O
P-, 6. 470
S-, 6. 470
y-, 6. 470
Kaolinization, 6. 468
Kapnikite, 6. 896
Kapnite, 4. 643
Kara, 2. 711
Karelinite, 9. 699
Karinthine, 0. 821
Karpholite, 6. 90O
Karstenite, 2. 430 ; 8. 761
Karynite, 9. 222
Kastira, 7. 277
Katabolic metabolism, 6. 11
Kataphoresis, 3. 541
Katungite, 6. 342
Katzenauge, 6. 139
Katzensilber, 6. 604
Keatingite, 6. 898
Keeleyite, 9. 549
cement, 3. 776
Keffekil tartarorum, 6. 921
Keffekill, 6. 427
Keffeklite, 6. 921
Kehoeite, 5. 371
Keifun, 4. 799
Keilhauite, 5. 513 ; 6. 840 ; 7. 3, 896
Kelley, E., 1. 48
Kelp ash, 2. 437
char, 5. 750
Kelvin's equation, 1. 1038
rule, 1. 1037
Kempito, 12. 149, 357, 378
Kenotime, 5. 527
Kentrolite, 6. 889 ; 7. 491 ; 12. 149
Keottigite, 9. 5
Kopler Johann, 1. 47
Keramohalito, 5. 154, 333 ; 12. 149, 424
Keramyl, 6. 945
Kerargyrito, 3. 300, 39O
Kcrasine, 7. 739, 852
Kermes, 9- 513, 577
vegetable, 2. 513
Kermesite, 9. 343, 577
Kerrite, 6. 609, 619, 622
Kerstenite, 7. 491 ; 9. 76 : 10. 697, 873
Kertsehenite, a-, 14. 391
896
Kilbriokenite, 7. 491 ; 9. 546
Kilbruckenite, 9. 343
Killenite, 6. 619
Killinite, 6. 643
Kilmacooite, 7. 797
Kiln charcoal, 5. 748
Kilogram-calorie, 1. 699
Kimitotantalate, 9. 909
Kinetic energy, 1. 696
of gases, 1. 744
748
VOL. XVl.
pressures, 1. 744
� diffusion, 1. 744
atoms, 1. 782
gases, 1. 742
history, 1. 767
� liquids, 1. 840
molecules, 1. 765
of Henry's law, 1. 531
solids, 1. 819
iron, 6. 908
Knebetite, 12. 530
Knopite, 5. 513 ; 7. 3, 52
Knowledge, empirical, 1. 8
scientific, 1. 8
Kobald, 14. 419
Kobalt, 14. 419
Kobaltarsenikies, 9. 309
Kobaltbleierz, 10. 787
Kobaltfahlerz, 9. 291
Kobaltwismuthfahlerz, 9. 291
Kobellite, 7. 491 ; 9. 343, 589, 693
Kobelt, 14. 419
Kobold, 14. 419
Koboldbluthe, 9. 228
Koboldin, 14. 757
Kobolt, 14. 419
Koboltblomma, 9. 228
Kobolterz, 9. 308
Koboltglantz, 9. 76
Koboltkies, 9. 308
Koboltmalm, 9. 76, 308
Kochelite, 5. 517 ; 9. 839, 904 ; 12. 6
Kochite, 6. 454
Kodolite, 2. 2
Koechlinite, 11. 570
Kolbingite, 6. 845
Koeltigite, 14. 424
Koenenite, 2. 431
Konigwasser, 8. 618
Kottigite, 9. 18O, 181 ; 15. 9
Koh-i-noor, 5. 711
2 Q
GENERAL INDEX
KoM, 9. 341
Kohlenschwefelwasserstoffsaure, 6. 119
Kohlenstoffcalcium, 5. 856
Kohlenstoffkalium, 5. 847
Kohlrausch's conductivity equation, 1. 987
law, 1. 987
law, 1. 979
Kohol, 9. 339
Kokscharoffite, 6. 821
KoIm, 12. 6
Kolophonite, 6. 921
Kolovratite, 9. 791
Konel, 15. 343
Kongsborgite, 4. 1024
Konichalcjito, 3. 623
Koninckite, 12. 530 ; 14. 4Ol
Konstrastin, 7. 121
Koppar-lazur, 14. 189
Koppite, 5. 519 ; 9. 839, 904
Korginite, 9. 222
Kornelite, 12. 530 ; 14. 303, 308
Kornerupino, 6. 812
Korynite, 9. 343
Kosmium, 5. 504
Kossel's hypothesis valency, 4. 183
Kotschubeito, 6. 622
Kowalsky and Moscicky's furnace, 8. 375
Krablito, 6. 663
Kraflite, 6. 663
Kraurite, 8. 733 ; 12. 530 ; 14. 407
Krausite, 12. 530 ; 14. 34O
Kreittonnite, 5. 296
Kromersite, 2. 15 ; 12. 53O
Krennorite, 3. 494 ; 11. 2, 46
Kretizbergito, 12. 530; 14. 411
Kreuzkristalle, 6. 766
Kreuzstcm, 6. 766
Krisoberil, 5. 294
Krisurigite, 4. 639
Kroeberite, 14. 136
KrShnkite, 3. 256, 257
Krokalite, 6. 573
Krugite, 2. 430, 657 ; 3. 623 ; 4. 252, 344 ;
7. 896
Kryolite, 5. 304
Kryolith, 5. 304
Kryptol, 5. 833
Krypton, 7. 889
isotopes, 7. 948
occurrence, 7. 892
preparation, 7. 902
physical, 7. 906
Ktypeite, 8. 815
Kubizite, 6. 644
Kuboid, 6. 644
Kuboizite, 6. 729
Kuhnite, 9. 221
KuId, 3. 296
Kunckel, J., 1. 52
Kunheim metal, 5. 610
Kunzite, 2. 425 ; 6. 640
Kupaphrite, 9. 161
Kupferacetylen, 5. 853
Kupferantimonglanz, 9. 536
Kupferblau, 6. 343
Kupferglanz, 3. 210
prismatoidischer, 9. 550
Kupferglas, 3. 210, 22O
Kupferglaserz, 3. 2IO
Kupferglimmer, 9. 162
Kupfergriin, 6. 343
Kupferkis, 14. 183
Kupferlasur, 3. 274
Kupfer-lazul, 14. 189
Kupfernickel, 9. 80 ; 15. 1, 5
Kupferpeckerz, 6. 343
Kupferphyllito, 9. 162
Kupferschaum, 9. 161
Kupferschwarzo, 3. 131
Kupfersmaragd, 6. 342
Kupferwismutherz, 9. 690
Kupferwismuthglanz, 9. 69O
Kupfferite, 6. 396
Kuphite, 6. 574
Kuphonspars, 6. 574
Kuprite, 7. 349
Kutnohorite, 4. 371 ; 12. 149, 433
Kyanite, 6. 458
Kylindrit, 9. 552
Kylindrite, 9. 343
Kyrosite, 14. 200
L-radiations, 4. 36
La-bile states, 1. 454
Labrador, 6. 693
-- felspar, 8. 693
Labradorite, 6. 662, 693
baryte, 6. 707
strontia, 6. 707
Labradorstein, 8. 693
Labrodorite, 3. 9Ol
Lac argonti, 3. 391
perpetual, 1. 5O
Lampadite, 12. 149, 266
Lampblack, 5. 750
Lamprophyllite, 8. 843 ; 7. 3 ; 12. 149
Lanarkite, 7. 491, 818, 854
Lancasterite, 4. 365
Landesite, 12. 149, 455 ; 14. 411
Langbanite, 9. 343 ; 12. 149
Langbeinite, 2. 430 ; 4. 338 ; 7. 896
rubidium, 4. 339
Langite, 3. 7, 263
Langmuir's octet theory atoms, 4. 196
preparation, 5. 587
Lanthanates, 5. 628
Lanthania isolation, 5. 55O
Lanthanite, 5. 507, 521, 665
Lanthanocerite, 5. 507
Lanthanous ammonium molybdate, 11. 587
-� weight, 5. 621
barium tungstate, 11. 791
bismuth sulphate, 9. 7Ol
borate, 5. 104
bromate, 2. 354
bromide, 5. 645
heptabromide, 5. 645
bromoaurate, 3. 607
� caesium nitrate, 5. 671
calcium carbonate, 5. 666
-� carbide, 5. 873
carbonate, 5. 664
� coric sulphate, 5. 662
chloride, 5. 641
hydrated, 5. 641
hexahydrated, 5. 641
ehloroaurate, 3. 595
chloroplatinate, 16. 33O
chloroplatinite, 16. 284
chromate, 11. 286
-- dioxysulphate, 5. 651
disulphide, 5. 649
dithionate, 10. 594
dodecanitritotriplatinite, 8. 521
� fluocarbonate, 5. 665
fluoride, 5. 638
fluosilicate, 6. 954
-� hexaiodohexanitritotriplatinite, 8. 523
hexamminonitrate, 5. 669
hydrazine sulphate, 5. 659
hydride, 5. 602
hydroarsenate, 9. 187
hydroarsenite, 9. 128
� hydroazide, 8. 352
hydrofluoride, 5. 638
hydropyrophosphate, 5. 675
hydroselenite*, 10. 831
dihydrate, 10. 831
hydrosulphate, 6. 656
hydroxide, 5. 628
hydroxytetraselenite, 10. 831
iodate, 2. 355
iodide, 5. 646
iron alloy, 18. 557
� hexahydrate, 5. 654
sulphatocerate, 5. 660
sulphatostannate, 7. 479
sulphide, 5. 648
sulphite, 10. 302
tetrahydropentaselenite, 10. 831
totraluminido, 5. 608
thallous nitrate, 5. 671
trihydromolybdate, 11. 564
tungstate, 11. 790
uranyl sulphite, 10. 309
zinc nitrate, 5. 672
INDEX
Laumontite, 6. 738
vanadio, 6. 739
Laurionite, 2. 15 ; 7. 738
Lauriorite, 7. 491
Laurite, 15. 498, 540, 686 ; 16. 5
Lausenite, 12. 530 ; 14. 303, 308
Lautarite, 2. 347
Lautite, 9. 305, 318
Lavendulan, 9. 159
Lavendulane, 14. 424
Lavendulanite, 9. 159
Lavendulite, 9. 5 ; 15. 9
Lavenite, 6. 855 ; 9. 839 ; 12. 149, 530
Lavenzstein, 6. 430
Lavoesium, 4. 672
Lavoisier and Laplace, law of, 1. 698
Lavroffite, 6. 818
Lavrovite, 6. 409, 818
Law, 1. 10, 13, 31
continuity, 1. 14
� of chemical composition, 1. 95
compound proportion, 1. 1OO
constant composition, 1. 76, 78
. _� Dalton, 1. 93
definite proportions, 1. 77
� equivalent ratios, 1. 79
indestructibility of matter, 1. 1Ol
mass action, 1. 933
multiple proportions, 1. 93, 96
_ persistence of weight, 1. 101
proportionality, 1. 79
reciprocal proportions, 1. 97
three states, 1. 1
-� Proust's, 1. 76
Richter's, 1. 79, 97
Lawrencite, 2. 15 ; 12. 528, 530 ; 14. 10 ;
15. 5
Lawroffite, 6. 409, 818
Lawrowite, 6. 409 ; 9. 716
Laws, 1. 157
Lawsonite, 6. 708
Laxmannite, 8. 733 ; 11. 125
Lazulite, 3. 274 ; 4. 252 ; 5. 154, 370 ; 6.
587; 8. 733 ; 12. 530 ; 14. 396
calcium, 5. 370
Spanish, 6. 808
Lazur felspar, 6. 663
Lazurapatite, 3. 896
Lazurite, 6. 580, 587
Lazurstein, 6. 586
Lead, 7. 484 ; 15. 9
acety!pyrophosphate, 7. 880
alcosol, 7. 509
allotropic, 7. 520
alloys, 12. 217
aluminate, 5. 297
aluminium alloys, 7. 624
oxydodecamolybdate, 11. 600
aluminophosphate, 7. 877
amalgams, 1. 3 ; 7. 618
amidosulphonate, 8. 644
amidothioimidosulphonate, 8. 636
amminoxide, 7. 668
ammonium chromate, 11. 304
cobalt nitrite, 8. 506
copper nitrite, 8. 498
dimetaphosphate, 7. 881
hydroxynitrilodisulphonate, 8.
678
imidochromate, 8. 266
GENERAL INDEX
11. 671
pyrophosphate, 7. 88O
rhodium chloronitrate, 15. 591
trithiosulphate, 10. 551
colloidal, 9. 191
arsenides, 9. 68
arsenious enneaiodide, 7. 762
� arsenite, 9. 12&
colloidal, 9. 129
arsonoenneadiiodide, 9. 254
ash, 7. 563, 639
__ iodide, 8. 738
orthophosphate, 7. 876
oxychloride, 7. 744
sulphide, 7. 797
� thiosulphate, 10. 552
baryte peritomous, 7. 740
benzylsulphinate, 10. 163
bismuth alloys, 9. 639
sulphoselenides, 10. 921
bismuthide, 9. 639
boratodichloride, 5. 14O
borosilicate, 6. 451
-� borotungstate, 5. Il l
� � bromate, 2. 356
bromide, 7. 745
properties, chemical, 7. 748
physical, 7. 746
bromoarsenatoapatite, 9. 263
bromobismuthite, 9. 673
bromocarbonate, 7. 853
bromofluoride, 7. 750
bromoiodide, 7. 766
bromoplatinate, 16. 379
bromosulphobismuthite, 9. 703
bromotriorthoarsenate, 9. 262
bromotriorthophosphate, 7. 885
bromotriorthovanadate, vanadatobro
mapatite, 9. 813
bullion, 7. 503, 504
cadmium alloys, 7. 617
caesium copper hexanitrite, 8. 500
433
phosphatomolybdate, 11. 671
�� sulphatohydrosilicate, 6. 89O
sulphide, 7. 797
trioxydichloride, 7. 743
trithiosulphate, 10. 552
carbide, 5. 885
carbonate, 7. 828
basic, 7. 836
colloidal, 7. 831
�- preparation, 7. 830
properties, chemical, 7. 832
physical, 7. 832
carbonatochromate, 11. 473
cerous orthophosphate, 7. 877
chamber crystals, 8. 696
chambers, theory of, 10. 372
colloidal, 7. 708
properties, chemical, 7. 712
physical, 7. 708
chlorides, 7. 706
� chlorite, 2. 283
chloroarsenite, 9. 13O
chlorobishydrophosphate, 7. 885
chlorobromide, 7. 750
ehlorocarbonato, 7. 852
chlorodiorthophosphato, 7. 885
chloroferrite, 13. 922
� chloroiodide, 7. 765
dihydrate, 7. 765
homihydrate, 7. 765
chloromotavanadate, 9. 809
� chloroplatinate, 16. 33O
chloroplatinite, 16. 284
chlorostannate, 7. 45O
ehlorosulphate. 7. 817
chlorosulphobismuthito, 9. 703
chlorotrimetarsenate, 9. 262
chlorotriorthoarsonato, 9. 260
chlorotriorthoarsenite, 9. 257
chlorotriorthophosphato, 7. 883
hydrated, 7. 883
chlorotriorthophosphatoarsenate, 9.
262
chlorotriorthovanadate, 9. 809
chromate, 11. 290
basic, 11. 301
colloidal, 11. 293
chromioxydodecarnolybdate, 11. 602
chromite, 11. 2Ol
chromium alloys, 11. 173
cobalt alloys, 14. 538
dinitrosyldecamminotetranitratonitratc,
8. 443
sulphide, 14. 757
cobaltic aquopentamminobromide, 14.
723
dodecanitrite, 8. 505
hexamminopentachloride, 14.656
trisethylenediaminoiodide, 14.
744
GENERAL INDEX
aluminophosphate, 7. 878
aluminosulphate, 7. 822
ehromate, 11. 304
ferric trioxydisulphate, 14. 350
hoxahydroxytetrasulphate, 7. 819
hydroxy arsenate, 9. 196
hydroxychloride, 7. 742
hydroxyortho vanadate, 9. 777
� � hydroxysulphate, 7. 820
iron alloys, 18. 579
��- nickel-cobalt alloys, 15. 337
_� octohydroxyhexaorthoarsenate,
9. 196
orthosnlphoantimonite, 9. 550
__ __ _ oxyphosphate, 7. 877
rod, 7. 515
silver octoxyhenacosicbloride, 7.
743
� orthosulphototrabismu
thite, 9. 695
tetrahydroxydiehloride, 7. 743
tetrahydroxyortbo vanadate, 9.
778
tetroxychloride, 7. 742
� - tetroxydecachloride, 7. 743
tin-iron alloys, 13. 579
. trioxydichlorido, 7. 743
corneous, 7. 852
__ corrosion, 7. 565
� electrolytic theory, 7. 565
hydrogen dioxide theory, 7. 565
_ triterosulphodecabismuthite, 9.
695
decoxytotraiodide, 7. 768
desilvered, 7. 505
desilverization, 3. 311 ; 7. 505
� -- dialuminodiorthosilicate, 6. 889
diamminobromide, 7. 749
diarnminodichloride, 7. 716
diamminoiodide, 7. 761
diamminotetrachloride, 7. 719
diarsenatoctodecatungstate, 9- 214
diarsenatohexatungstates, 9. 213
diboratodichloride, 5. 14O
dibromoctofluoride, 7. 750
hydrated, 7. 685
physical, 7. 683
dioxycarbonate, 7. 836
dioxychromate, 11. 302
dioxydibromide, 7. 754
dihydratod, 7. 754
dioxydichloride, 7. 739
dioxydihydroxide, 7. 661
dioxydiiodide, 7. 767
dioxydinitrate, 7. 868
dioxydinitrite, 8. 498
dioxy diphosphite, 8. 918
dioxydisulphotungstate, 11. 861
dioxyhenabromide, 7. 755
dioxyheptabroxnide, 7. 755
dioxyiodochloride, 7. 768
dioxynitrite, 8. 497
dioxypentabromide, 7. 755
dioxyselenate, 10. 874
dioxysulphate, 7. 818
� dioxytrimetaphosphate, 7. 881
dioxytrisulphate, 7. 819
diphosphatoctodecavanadatohexa
molybdate, 9. 835
diphosphatoc to vanadatododeca molybdate,
9. 835
diphosphatoctovanadatopentadecamolybdate,
9. 835
diphosphatootovanadatotetradecamolybdate,
9. 835
GENERAL INDEX
Lead diphosphatoctovanadatotridecamolybdate,
9. 835
diphosphatohexavanadatotridecamolybdate,
9. 835
diphosphatote tradeca vanadat ohena
molybdate, 9. 835
diphosphide, 8. 849
diplatinous hexasulphoplatinate, 16
396
diselenide, 10. 786
disulphatarsenite, 9. 333
disulphate, 7. 822
disulphide, 7. 794, 795
disulphopyrosulpharsenite, 9. 298
disulphopyrosulphoantimonite, 9. 546
disulphopyrosulphobismuthite, 9. 695
disulphorthosulpharsenate, 9. 69
dithioimide, 8. 265
dithionate, 10. 594
ditungstate, 11. 81O
diuranate, 12. 67
diuranyl phosphate, 12. 136
dodeeabromodiiodide, 7. 766
double refined, 7. 505
earth, 7. 638
electrodeposition, 7. 542
electronic structure, 7. 602
� enneadecasulphoctoantimonite, 9. 547
enneaiodoantimonite, 9. 502
enneaiodobismuthite, 9. 677
enneaoxytetraiodide, 7. 767
enneatitarsenide, 9. 69
enneauranate, 12. 68
ethyl alcosol, 7. 509
extraction, 7. 495, 5Ol
� hydroxysulphatophosphatarsenate,
9. 334
hydroxytetrasulphate, 14. 349
oxytrisulphate, 14. 349
ferrite, 18. 921
ferrous chloride, 14. 35
cuprous enneasulphodiantimonite,
9. 554
ferrite, 18. 924
� hexaiodide, 14. 133
manganese metatitanate, 7. 56
orthovanadate, 9. 778
sulphide, 14. 168
tetradecasulphohexantimonite,
9. 554
filaments, 7. 607
films, 7. 508
� fluotriorthophosphatoarsenatos, 9. 259
fluotri ortho vanadate, 9. 8Ol
sulphide, 7. 796
chemical, 7. 505
hemiamminoiodide, 7. 762
hemiamminomotesihciato, 6. 887
horniarsenide, 9. 69
hemicosisulphoctoantimonite, 9. 548
hemihexamminobromide, 7. 749
hemihexaphosphate, 7. 882
hemimercuride, 7. 619
hemioxide, 7. 636
hemisulphido, 7. 780
hemitriamminodichloride, 7. 716
hemitrimercuride, 7. 619
hemitrioxide, 7. 67O
hemitritelluride, 11. 58
tetrahydrate, 11. 58
henasulphohexantimonite, 9. 549
henasulphototrantimomte, 9. 544
henicosoxydocosinitrite, 8. 498
heptadecasulphoctantimonito, 9. 547
heptadocasulphoctobismuthito, 9. 695
heptoxydichloride, 7. 742
heptoxyhoxamtrite, 8. 497
heptoxypentaiodide, 7. 768
hexaborate, 5. 106
hexachlorodiiodide, 7. 765
hexahydroarsenatoetodeeamolybdate,
9. 211
hexahydroxydinitrate, 7. 867
hexahydroxydisulphate, 7. 819
hexametaphosphate, 7. 882
hydrate, 7. 882
hexanitritodinitiate, 7. 87O ; 8. 498
hexaphosphate, 7. 882
hoxasulphodichloride, 7. 795
hexoxydibromide, 7. 755
hexoxydichloride, 7. 742
dihydrate, 7. 742
hoxoxydiiodatohexachloride, 7. 768
hexoxydiiodide, 7. 767
hexoxytetraiodide, 7. 768
history, 7. 484
horn, 7. 707, 852
hydrazine sulphuryl hydrazide, 8. 666
GENERAL INDEX
_ � monothiophosphate, 8. 1069
monochloride, 7. 706, 74/5
monohydroxide, 7. 637
monoiodido, 7. 757
monotelluride, 11. 56
monoxide, 7. 638
properties, 7. 650
physical, 7. 644
�� native, 7. 490
433
nitrate, 7. 856 ; 11. 831
properties, chemical, 7. 862
_ physical, 7. 857
X-radiogram, 1. 642
nitrates, basic, 7. 867
nitratobisdihydrophosphate, 7. 885
nitratohypophosphite, 8. 887
nitratometatungstate, 11. 827, 862
nitratorthophosphate, 7. 885
nitratotellurate, 11. 120
nitride, 8. 122
nitrilodithiophosphate, 8. 727
nitrite, 8. 497
nitritonitrate, 7. 869
GENERAIi
monohydrate, 7. 738
oxydihydroxide, 7. 661, 664
oxydiiodide, 7. 766
hemihydrate, 7. 767
monohydrate, 7. 767
oxydinitrite, 8. 498
� oxydiphosphite, 8. 918
oxydiselenitoplumbate, 10. 833
� oxydisulphate, 7. 819
oxydithionate, 10. 595
oxyfluoride, 7. 703
� oxyhexachloride, 7. 736
oxyhexahydroxytetranitrate, 7. 868
oxyiodide, 7. 766
oxymolybdate, 11. 568
oxymolybdatochloroarsenate, 9. 263 ;
11. 668
INDEX 601
pentahydroxyirnidodisulphonate, 8.
659
pentamminoiodide, 7. 761
pentarnolybdate, 11. 594
pentapermanganite, 12. 279
-�- pentaphosphide, 8. 849
pentasulphide, 7. 794
-� pentathionate, 10. 628
pentauranite, 12. 68
��� pentitaheptoxide, 7. 67O
-�- pentitahexoxido, 7. 670
pentitoctoxide, 7. 67O
pentoxybischromate, 11. 302
pentoxydichloride, 7. 742
_ pentahydrate, 7. 742
pentoxydiiodide, 7. 767
heptahydrate, 7. 767
pentoxydinitrate, 7. 867
hydrate, 7. 867
�-� pentoxydisulphopyrovanadate, 9. 818
pentoxyorthoarsenate, 9. 192
pentoxy orthophosphate, 7. 875, 877
pentoxyorthovanadato, 9. 776
� perchlorate, 2. 402
periodate, 2. 415, 416
permanganate, 12. 336
permanganite, 12. 279
permonosulphomolybdate, 11. 653
pervanadate, 9. 795
peroxide, 7. 681
persulphate, 10. 48O
trihydrate, 10. 48O
phosphate, 7. 875
fava, 7. 877
phosphatoctotungstate, 11. 872
phosphatododocamolybdate, 11. 663
phosphatododecatungstate, 11. 867
� phosphatoenneatungstate, 11. 871
phosphatohexatungstate, 11. 873
phosphatophosphates, 7. 882
phosphide, 8. 849
phosphite, 8. 917
phosphorous ennoaiodide, 7. 762
physiological action, 7. 588
platinous 2ran.�-sulphitodiarnrninosulphite,
10. 321
602 GENERi INDEX
�� porous, 7. 507
potassimide, 8. 265
potassium arsenate, 9. 195
chromate, 11. 504
.. nitrilotrisulphonate, 8. 669
octonitritotetranitrate, 7. 872 ; 8.
498
orth.opliosph.ato, 7. 876
orthosulphoantimonite, 9. 552
pyrophosphate, 7. 880
tetranitrito, 8. 498
trithiosulphate, 10- 552
� powdered, 7. 507
praseodymium chlorovanadate, 9. 809
properties, chemical, 7. 561
_ � physical, 7. 515
purification, 7. 504
electrolytic, 7. 505
purified, 7. 508
pyrottutiinonate, 9. 458
dihydrate, 9. 458
-�� -��- hemitrihydrate, 9. 458
-� hexahydrate, 9. 458
monohydrate, 9. 458
. pentahydrate, 9. 458
totrahydrate, 9. 458
pyroarsenate, 9. 195
pyroarsenite, 9. 13O
pyrobismuthite, 9. 651
pyrolignite, 7. 591
pyrophoric, 7. 563
� pyrophosphate, 7. 88O
pyroplumbite, 7. 67O
pyrosilicate, 6. 887
pyrosulphantimonite, 9. 548
pyrosulpharsenate, 9. 322
pyrosulpharsenite, 9. 299
pyrosulphate, 10. 447
pyrosulphobismuthite, 9. 694
pyrovanadate, 9. 776
quadrantosulphide, 7. 78O
red, 7. 672
rhodium alloy, 15. 565
chloride, 15. 579
rubidium cobalt nitrite, 8. 506
trithiosulphate, 10. 552
�� ruthenium alloys, 15. 510
sacred, 9. 341
selenato, 10. 873
selenide, 10. 786
selenite, 10. 833
selenoaulphohexabismuthite, 9. 695
sesquioxide, 7. 67O
sesquisulphide, 7. 793
silioide, 6. 187
silicite, 6. 236
INDEX
azide, 8. 345
hydrate, 8. 345
azodithiocarbonate, 8. 338
/9-, 2. 458
barium silicate, 6. 371
ci�-bischromatotetramminocobaltiate,
11. 311
borosilicate, 6. 448
bromate, 2. 33O
bromide, 2. 577
ammines, 2. 586
physical, 2. 579
.**<-
606 GENERAL INDEX
� � octohydratod, 4. 927
tribromide, 4. 891
trinitrite, 8. 495
� metaborate, 5. 65, 79
�. octohydrated, 5. 65
metabromoantimonate, 9. 497
metachloroantimonate, 9. 491
- metadizirconate, 7. 136
metaluminate, 5. 287
metantimonate, 9. 450
metaphosphate, 2. 867
metaplumbate, 7. 696
metarsenite, 9. 116
metasilicate, 6. 329
hydrated, 6. 331
metasulpharsenate, 9. 317
� metasulphoantimonite, 9. 533
metasulphotetrantimonite, 9. 534
metatungstate, 11. 822
metavanadate, 9. 761
metazirconate, 7. 135
molybdate, 11. 552
trioctohydrate, 11. 553
molybdenum dioxydibromide, 11. 638
oxytetrabromide, 11. 638
monamidophosphate, 8. 706
monomercuride, 4. 1012
monosulphide, 2. 621
properties, chemical, 2. 627
physioal, 2. 624
monoxide, 2. 486
� orthododecacolumbate, 9. 685
orthophosphate, normal, 2. 847
properties, chemical, 2. 849
physical, 2. 848
orthosilicate, 6. 329
orthosulpharsenate, 9. 317
orthosulphoantimonite, 9. 533
orthotellurate, 11. 89
orthotetravanadate, 9. 761
orthovanadate, 9. 760
enneahydrate, 9. 760
hexahydrate, 9. 760
osmium alloy, 15. 697
oxyorthovanadate, 9. 76O
monohydrate, 9. 76O
tetradocahydrate, 9. 76O
tetrahydrate, 9. 760
-� palladium alloys, 15. 642
� paramolybdate, 11. 584
dodecahydrate, 11. 584
_ octocosihydrate, 11. 584
paratungstate, 11. 814
� percarbonate, 6. 84
- pentachloroantimonito, 9. 479
hexahydrate, 9. 479
pentahydrate, 9. 479
pentachlorodiplumbite, 7. 727
pentaiodoplumbite, 7. 776
pentahydrate, 7. 776
tetrahydrate, 7. 776
pentamercuride, 4. 1012
pentamolybdatodisulphite, 10. 307
pentasilicate, 6. 329
pentatantalate, 9. 901
��� perchlorato, 2. 395
perdichromate, 11. 359
perditungstate, 11. 835
perdiuranate, 12. 72
perferrite, 13. 926
periodate, 2. 406, 408, 409
ammonium, 2. 409
permanganate, 12. 302
permonosulphomolybdate, 11. 653
persulphate, 10. 476
� pertetratungstate, 11. 836
peruranate, 12. 72
pervanadate, 9. 795
phosphatoenneamolybdate, 11. 666
phosphatohexamolybdate, 11. 667
phosphatohexatungstate, 11. 872
phosphide, 8. 834
phosphitododecamolybdate, 8. 918
GENERAL INDEX
hexafluotetraluminotrimesosilicate,
6. 608
hy< lrotrialuminotriorthosilicate,
' 6. 608
molybdate, 11. 558
silicate, 6. 337
sulphate, 2. 687
siilphatochromate, 11. 244
sulphite, 10. 260
tungstate, 11. 781
� _ physical, 2. 451
pyridinepentachloroplatinate, 16. 312,
324
pyrophosphate, 2. 862
pyrophosphatododecamolybdate, 11.
671
pyrosulpharsenate, 9. 316
pyrosulphoantimonito, 9. 533
� pyrotellurite, 11. 77
� pyrovanadate, 9. 761
_ hexahydrate, 9. 761
totrahydrate, 9. 761
sulphate, 2. 688
ruthenium alloy, 15. 5IO
salts extraction, 2. 442, 443, 444
orthosulphoantimonite, 9. 542
sulphate, 3. 454
sodium alloys, 2. 480
chloroperrhodite, 15. 579
fluoaluminate, 5. 306
molybdate, 11. 556
selenate, 10. 866
silicate, 6. 337
sulphate, 2. 687
sulphite, 10. 26O
trioxysulpharsenate, 9. 329
tungstate, 11. 779
1 : 3-tungstate, 11. 779
silicate, 6. 371
subchloride, 2. 530
sulphamidate, 8. 662
sulphate hydrates, 2. 667
preparation, 2. 660
properties, chemical, 2. 672
physical, 2. 660
� sulphatoaluminate, 5. 342
pentahydrated, 5. 66
�� tetrabromoaluminate, 5. 326
tetrachloroaluminate, 5. 321
tetrachloromercuriate, 4. 852
tourmaline, 6. 742
trialuminiurri hexahydroxydimetasili
hexafluoride, 12. 79
nitrate, 12. 126
phosphate, 12. 132
pyrophosphate, 12. 132
X-radiogram, 1. 642
zinc silicate, 6. 444
sulphate, 4. 636
trichloride, 4. 554
silicododecatungstate, 6. 875
Lithographic limestone, 3. 815
Lithomarge, 6. 472
green, 6- 472
Lithophone, 4. 600
Lithophosphorus, 2. 3
Lithosiderites, 12. 523
Live lime, 3. 653
Liveingito, 7. 491 ; 9. 4, 300
Liver of sulphur, 2. 621
soda, 2. 621
volatile, 2. 645
Livingstonite, 4. 697 ; 9. 343, 543
Llicteria, 9. 553
Loaisito, 9. 225
Loboite, 6. 726
Loekyor's evolution hypotheses elements, 4.
21
Lodestone, 12. 530
Lbffebikobelt, 9. 3
Lollingito, 9. 4, 73 ; 12. 530
Lowigite, 5. 353
Lowite, 2. 430 ; 4. 252
Loganite, 6. 622, 821
Logronito, 6. 392
Lomonite, 6. 738
Lonchidite, 14. 2OO
Longbanite, 6. 836
Longitudinal elasticity, 1. 82O
Longulites, 1. 628
Looking-glass ore, 12. 530
Lophoito, 6. 622
Lorandite, 5. 407 ; 9. 4, 297
Loranscite, 5. 481, 516, 519 ; 9. 903
Loranskite, 7. IOO
Lorenzenito, 6. 842 ; 7. 3, 1OO
Lorettoite, 7. 491, 742
Lossonite, 7. 491 ; 9. 334 ; 12. 530
Loseyite, 12. 149, 439
Lotalite, 6. 915
Lotrite, 6. 722
Louderbackito, 14. 328, 351
Louisite, 6. 368
philosophicum, 1. 126
Luminescence, crystallo-, 1. 6Ol
tribo-, 1. 6Ol
VOL. XVI.
repax, 9. 341
isolation, 5. 705
Lutecin, 15. 2IO
Lutecite, 6. 139
Lutecium, 5. 498, 705
� hydroxide, 5. 707
isolation, 5. 555
properties, 5. 706
sulphate, 5. 707
Macfarlanite, 9. 64
Machine cast pig iron, 12. 596
Mackensite, 6. 921 ; 12. 530
Mackintoshite, 5. 515 ; 6. 883 ; 7. 185 ; 12. 5
Mack's cement, 3. 776
Made, 6. 458
Macluerite, 6. 817
Maconite, 6. 619, 622
Macrolepidolite, 6. 615
Macromolecular, 1. 657
Macupite, 5. 531
Manaken, 7. 56
2 R
6IO GENBRAT,
K6d, 6. 768
�ec magnesium oxido
sodalite, 6. 583
solida, 12. 14O
spinel, 5. 154, 295
squamosa, 12. 14O
striata, 12. 140
tossulato, 12. 140
usta, 4. 280, 282
� vitriariorum, 12. 140
Magnesian pharmaeolifco, 9. 221
tourmalines, 6. 741, 742
Magnesio, 4. 280 ; 12. 140
hydratee, 4. 290
Magnesii carbones, 4. 364
pondorosus, 4. 365
Magnesioanthophyllite, 6. 916
Magnesiochromite, 11. 199, 2Ol
Magnesioferrite, 4. 251 ; 12. 530 ; 13. 914
Magnosious azide, 8. 350
Magnesite, 4. 251, 349 ; 6. 427
--�� burnt, 4. 280
caustic, 4. 35O
crude, 4. 350
- � dead-burnt, 4. 35O
raw, 4. 350
spar, 4. 349
Magnesium, 12. 141
action on water, 1. 135
aluminate, 5. 295
alumiuiuna alloys, 5. 235
alurninatorthosilicate, 6. 812
. carbonate, 5. 359
� copper alloys, 5. 237
iron alloys, 13. 557
mesopentasilicate, 6. 826
nickel alloys, 15. 231
copper alloys, 15. 231
pentaluminatorthosilicate, 6. 813
INDEX
aramino-, 4. 314
diammino-, 4. 314
hexahydrated, 4. 313
hexammino-, 4. 314
bromoallylenide, 5. 867
bromoarsenate, 0. 258
bromoarsenatowagnorite, 9. 258
bromocarbide, 5. 867
bromoplatinate, 16. 379
bromostannate, 7. 456
cadmide, 4. 688
cadmium alloys, 4. 688
hexachloride, 4. 559
sulphate, 4. 641
�� csRsium bromide, 4. 315
� carbonate, 4. 37O
chloride, 4- 308
chrornate, 11. 277
pororthocolumbate, 9. 87O
selenate, 10. 844
sulphate, 4. 34O
thiosulphato, 10. 565
�� carbonate, 4. 371
chloride, 4. 309
cobalt arsenate, 9. 23O
dialuminium dihydrotriorthosili
cate, 6. 718
dihydro-orthodisilicate, 6. 420
dimetasilicato, 6. 4IO
onnealumonoxyaluminotrisili
cate, 6. 816
_ fluorthoarsenate, 9. 258
� hexaborate hexahydratod, 5. 100
_ __ orthosilicate, 6. 408
sodium fluoaluminate, 6. 309
(tri)orthosilicate, 6. 409
trihydrohoxalumiiioxyaluminotriorthosilicate,
6. 817
carbide, 5. 867
carbonate, 4. 349
action heat, 4. 352
colloidal, 4. 351
dihydrated, 4. 354
hydrated, 4. 354
heavy, 4. 365
light, 4. 364
monohydrated, 4. 354
pentadecatetritahydrated, 4. 356
pentahydrated, 4. 356
preparation, 4. 35O
properties, physical, 4. 351
solubility, 4. 358
tetrahydrated, 4. 356
trihydrated, 4. 355
carbonatosulphate, 4. 360
eerie nitrate, 5. 674
cerous nitrate, 5. 671
chabazite, 6. 733
chlorate, 2. 349
chloride, 4. 298 j IS. 615
ammino, 4. 305
chloroarsenate, 9. 258
chloroarsenatowagnerite, 9. 258
chloroaurate, 3. 595
chlorochromate, 11. 398
hexanitrito, 8. 504
cobaltite, 14. 594
cobaltous sulphate, 14. 781
carbonate, 4. 370
enneadecahydrate, 9. 773
deuterotetravanadate, 9. 773
enneahydrate, 9. 773
� octohydrate, 9. 773
dialuminium triorthosilicate, 6. 815
dialuminylaluminium orthopentasilicate,
6. 809
diamidodiphosphate, 8. 711
diamminopotassamide, 8. 260
diamminosodamide, 8. 26O
diborate, 5. 97
octohydrated, 5. 98
trihydrated, 5. 97
diborido, 5. 25
GENERAL, INDEX
dihydroxybisphosphoryltrichloride, 8. 9. 211
1026 hexahydrotetrasulphate, 4. 325
dihydroxycarbonate, 4. 355 �- hexaiodoplumbite, 7. 778
diammino, 4. 317
hexammino, 4. 317
iodochloride, 4. 317
INDEX 613
424 enneahydrated, 5. 96
chloride, 12. 368 orthocolumbate, 9. 866
dipermanganite, 12. 278 orthohexatantalate, 9. 903
hoxabromide, 12. 383 -�� orthophosphate, 4. 382
hexachloride, 12. 369 orthosilicate, 6. 384, 42O
sulphates, 12. 422 orthosulpharsenate, 9. 321
oxycarbonate, 4. 364
a.t 6. 391
�., e. 391
oxychlorovanadate, 9. 809
hydrated, 6. 42O
metasulpharsenatoxymolybdate, 9.332
- metasulpharsenite, 9. 296
metatetrarsenite, 9. 126
oxyorthocolumbate, 9. 866
metatitanate, 7. 54
oxypyrophosphorylchloride, 8. 1028
oxytetrachromite, 11. 2 OO
metavanadate, 9. 773
oxytrisphosphoryltrichloride, 8. 1026
monothiophosphate, 8. 1069
pentabromoantimonite, 9. 496
pentachloroantimonito, 9. 481
arsenate, 9. 231
pentachlorobismuthite, 9. 667
dihydrorthosilicate, 6. 932
metasilicate, 6. 932
pentachlorovanadite, 9. 805
penterasulphotetrarsenato, 9. 321
orthotrisilicate, 6. 932
tetrahydrotriorthosilicate, 6. 932
phosphite, 8. 916
� platinized, 4. 273
platinum alloys, 16. 206
plumbite, 7. 669
polysulphide, 4. 320
potassium alloys, 4. 666
bromide, 4. 314
calcium sulphates, 4. 344, 345
carbonate, 4. 368, 369
� chlorosulphate, 4. 343
5. 99
hexarsenate, 9. 179
hydrocarbonate, 4. 367
hydrodiorthoarsenate, 9. 179
_ _ dihydrate, 9. 179
� pentadecahydrate, 9. 179
_ pentahydrate, 9. 179
tetrahydrate, 9. 179
-� � hydrophosphate, 4. 384
hydrosulphate, 4. 342
iodide, 4. 317
: metasilicate, 6. 407
� trisilicate, 6. 408
� tungstate, H . 788
zinc sulphate, 4. 641
praseodymium nitrate, 5. 672
.preparation, 4. 253
a-heptahydrated, 4. 323
/3-heptahydrated, 4. 323
a-hexahydrated, 4. 323
/S-hexahydrated, 4. 323
and hydrogen, 1. 303
diaquodiammine, 4. 543
dihydrated, 4. 323
� dodecahydrated, 4. 324
hydrates, 4. 321
monohydrated, 4. 322
octohydrated, 4. 323
. pentahydrated, 4. 323
pentatotritahydrated, 4. 322
_ properties, chemical, 4. 331
physical, 4. 326
tetra-aquodiammine, 4. 343
tetrahydrated, 4. 323
� tri-aquo-triammine, 4. 343
trihydrated, 4. 329
sulphatocarbonate, 4. 36O
sulphatoselenate, IO. 929
sulphide, 4. 318
sulphite, 10. 285
hexahydrate, 10. 285
trihydrate, 10. 285
sulphosilicate, 6. 987
sulpho tellurite, 11. 113
sulphotrimolybdate, 11. 652
sulphotungstate, 11. 859
tellurate, 11. 94
telluride, 11. 50
tellurite, 11. 80
decitaennoahydrate, 11. 80
pentitaenneahydrato, 11. 8O
tetraborate, "5. 97, 98
tetrachloroferrite, 14. 33
tetrachloromercuriate, 4. 861
tetrachloroplumbite, 7. 731
tetrachromite, 11. 2OO
tetrahydrodisilicate, 6. 421
hydrosilicododecatungstate, 6. 879
tetrahydrotriorthosilicate, 6. 423
tetrahydrotriselenite, 10. 826
trihydrate, 10. 826
tetrahydrotrisilicate, 6. 427
tetramercuride, 4. 1035
tetrametaphosphate, 4. 396
decahydrated, 4. 396
tetrammonium diphosphate, 4. 385
tetramolybdate, 11. 593
tetranitritoplatinite, 8. 520
tetrapermanganite, 12. 278
tetraphosphate, 4. 394
tetrasulphatoaluminate, 5. 354
thallium voltaite, 14. 353
thallous carbonate, 5. 472
chloride, 5. 441
orthophosphate, 5. 498
selenate, IO. 871
� titanide, 7. 2O
triamidodiphosphate, 8. 712
triarsenatotetravanadate, 9. 2Ol
trihemialuminide, 5. 235
trihemimercuride, 4. 1036
trimetaphosphate, hydra ted, 4. 396
trimolybdate, 11. 590
trioxydisulphomolybdate, 11. 655
trioxynitrate, 4. 38O
trioxyorthoarsenito, 9. 126
trioxysulphotungstate, 11. 861
tripentitasilicide, 6. 180
trisulphide, 4. 317
tritamercuride, 4. 1036
triterodecavanadato, 9. 773
tritetritaaluminide, 5. 236
tritetritasilicide, 6. 181
trithellide, 5. 427
trithionate, 10. 609
� trithiophosphate, 8. 1067
� tritungstate, 11. 811
uranate, 12. 63
-�-� uranium alloys, 12. 38
uranyl disulphate, 12. HO
- orthodisilicate, 6. 883
sulphate, 12. 17
vanadates, 9. 772
vanadyltrifluorido, 9. 8Ol
X-radiogram, 1. 642
zinc alloys, 4. 687
� alurmnide, 5. 240
aluminium alloys, 5. 240
iron alloy, 13. 545
manganoua sxilphate, 12. 423
sulphates, 4. 64O
tetrachloride, 4. 559
zirconate, 7. 136
zirconium, 7. 116
(di)magnesium diborate, 5. 97
hexaborate, 5. 98
pentacalcium silicate, 6. 404
potassium hydrodecalu rnino trior tho
silicate, 6. 608
thallous sulphate, 5. 467
(tetra)magnesium copper hoxaluminido, 5.
237
1. 682
separation of ores, 3- 22
Magnetis, 6. 428
GENERAL, INDEX
X-radiogram, 1. 64O
Magnetites titaniferous, 7. 11
smelting, 7. 11
Magnium, 4. 251
Magnolia, 7. 362
Magnosia, 4. 250
rule, 1. 1039
Maier, M., 1. 48
Maitlandite, 12. 5
Majolica, 6. 513
Majorana effect, 12. 693
Malachite, 8. 27O
load, 8. 274
lime, S. 274
preparation, 8. 270
properties, 3. 272
zinc, 4. 648
Manganes, 4. 250
Manganese, 1. 520 ; 4. 250 ; 12. 139, 140,
141
allotropes, 12. 169
alloys, 12. 200, 216, 217, 218
alum, 5. 154, 354
aluminium alloys, 12. 208
vanadatosilipate, 6. 836
amalgam, 12. 208
amide, 8. 272
amidosulphonate, 8. 644
� sodium pyrophosphatotungstate,
11. 874
amphibole, 6. 897
analytical reactions, 12. 189
apatite, 12. 449
colloidal, 9. 217
arsenatometasilicate, 6. 836
arsenitometasilicate, 6. 836
atomic disruption, 12. 199
� bishexamethylenetetraminopersulphate,
10. 480
bismuth alloys, 9. 639
nitrate, 9. 710
bismuthide, 9. 639
boracite, 5. 14O
borotungstate, 5. 111
brass, 4. 670
brornate, 2. 359
bromides, 12. 381
bromoapatite, 12. 45O
bromoarsenate, 9. 258
bromoarsenatoapatite, 9. 262
bromoarsenatowagnerite, 9. 258
bromoaurate, 8. 607
carbide, 5. 892
carbonates, 12. 432
chlorate, 2. 359
ammino-, 2. 359
chlorides, higher, 12. 374
chloroantimonate, 9. 492
chloroarsenate, 9. 258
INDEX 617
-� tetravanadate, 9. 791
� arsenate, 9. 222
ealcium arsenate, 9. 222
metasilicate, 6. 898
nitrate, 12. 445
-� metasulpharsenatoxymolybdate, 9.
332
motatantalato, 9. 905
metatotrarsonite, 9. 132
metatitanate, 7. 56
metavanadate tetrahydrate, 9. 79O
mica, 6. 608
mirrors, 12. 167
molybdenum alloys, 12 217
� orthoarsenate, 9. 217
orthoarsenite, 9. 132
orthoborate, 5. 113
orthosilicate, 6. 893
dihydrated, 6. 894
ditritahydrated, 6. 894
hydrated, 6. 894
orthosulphoantimonite, 9. 553
orthotitanate, 7- 56
oxide, 12. 141
plumbite, 7. 669
��- potassium arsenate, 9. 221
diamminoamide, 8. 272
. penterotetradecavanadate, 9. 791
selenatosulphate, 10. 930
selenide, 10. 799
sulphatoselenate, 10. 930
tetrahydrodihypophosphate, 8.
939
GENERAL, INDEX
0. 79O
hexadecahydrate, 9. 790
pentadecahydrate, 9. 79O
dihydrate, 9. 219
pyroselenite, 10. 838
� rouge, 6. 768
salts, catalysis by, 1. 487
selenate, 10. 878
dihydrate, 10. 878
pentahydrate, 10. 878
selenide, 10. 798
selenite, 10. 838
dihydrate, 10. 838
moriohydrate, 10. 838
sesquiborate, 5. 113
sesquisilicate, 6. 898
silicates, 6. 892
silicide, 6. 197
silicododecatungstate, 6. 881
silicon steels, 13. 667
titanium steel, 13. 667
silver alloys, 12. 204
aluminium alloys, 12. 215
sodium arsenate, 9. 221
calcium hydrotrimetasilicate, 6.
90O
diorthoarsenato, 9. 221
phosphite, 8. 919
pyrophosphatotungstate, 11. 874
solubility of hydrogen, 1. 306
spar, 6. "896 ; 12. 432 ; 14. 359
spinel, 5. 297
stannate (a-), 7. 420
steels, 12. 194, 752
strontium metasilicate, 6. 897
sulpharsenatosulphomolybdate, 9. 323
sulpharsenite, 9. 301
sulphates, higher, 12. 427
sulphides, 12. 387, 397
sulphite, 1. 52O ; 10. 309
hemipentahydrate, 10. 309
sulphoantimonate, 9. 575
sulphochromite, 11. 433
sulpho tellurite, 11. 114
sulphotungstate, 11. 859
tellurate, 11. 97
telluride, 11. 63
tellurite, 11. 82
tetrarsenate, 9. 219
pentahydrate, 9. 219
tetraborate, 5. 113
pent any drated, 5. 113
trihydrated, 5. 113
tetrabromide, 12. 383
tetrachloride, 12. 374
tetrafluodioxytungstate, 11. 84
tetrafluoride, 12. 342, 346
tetrahydro-orthoborate monohydrated,
5. 112
tetrahydroxydiarsenate, 9. 219
arsenate, 9. 222
dihydroxyorthosilicate, 6. 894
�� hydroarsenate, 9. 222
hydrocarbonato, 12. 439
tetradecahydroxyaraenate, 9. 221
(di)manganese calcium aluminohydroxytriorthosilicate,
6. 768
Manganesis, 4. 25O
Manganhisingerite, 6. 908
608
di hydro tetrasulphate, 12. 429
diselenite, 10. 839
INDEX
ManganouR hydro xylarnino dichloride, 12. Manganous permanganates, 12. 268, 336
hemihydrated, 6. 900
Mangantantalite, 9. 906
Mangolite, 6. 897
of St. Nicholas, 9. 42
Mansjocite, 6. 409
Mantle, incandescent, 7. 213
Welsbach's, 7. 218
Maranito, 6. 458
Marble, 8. 622, 814, 815
Carrara, 8. 815
fire, 3. 815
onyx, 3. 815
panno di morti, 3. 815
parian, 3. 815
puddingstone, 3. 815
verd antique, 3. 815
202 ; 15. 9
comparison pyrite, 14. 221
properties, chemical, 14. 221
1. 555
Marialito, 6. 762
Marialitic acid, 6. 764
Marionglas, 3. 761
Marignacite, 5. 519 ; 7. 3 ; 9. 903
Marionite, 4. 646
Mariposite, 6. 608
Mariupolite, 9. 839
Marjatskite, 12. 149
Markaschite, 9. 587
Markus's alloy, 15. 2 K)
Marmairolito, 6. 916
Marmatite, 4. 408 ; 12. 53O ; 14. 167
Marmolite, 6. 422
Manner motallicum, 3. 62O
serpentinum, 6. 420
zeblicium, 6. 420
Marquashitha, 14. 199
Marsh ore, 13. 886
Marshito, 2. 17 ,- 3. 201
Marsh's test arsenic, 9. 39
Martensite, 12. 822
I Medicine, universal, 1. 49
Medico-chemistry, 1. 50
Medium dispersion, 1. 769
Medjidite, 12. 5, HO
Meerschalumite, 6. 473
Meerschaum, 6. 420, 426
Megabar, 1. 149
Megabasite, 11. 798
Megabromite, 8. 418
Megalaise, 12. 140
Mehl zeolite, 6. 758
Meiler, 5. 748
Meionito, 6. 762
Meizonite, 6. 763
Melaconise, 3. 131
Molaconite, 3. 7, 131
Melanargyrite, 9. 54O
Melanglanz prismatischer, 9. 54O
I Melanites, 6. 921
Melanocerite, 5. 514, 529
Melanochalcite, 6. 343
Melanochroite, 11. 125, 302, 303
Melanolite, 6. 624 ; 12. 530
Melanosiderite, 6. 908
Melanotecite, 6. 889
Melanotekite, 7. 491 ; 12. 530
Melanothallite, 2. 15
Melanovanadate, 9. 77O
Melanovanadite, 9. 793
Melanteria, 3. 3
Melanterie, 14. 243, 245
Molanterite, 14. 245 ; 15. 9
Melanterites, 4. 639 ; 12. 403, 53O
Melichrysos, 7. 98
Melilite, 6. 403, 713, 752
Melinophane, 2. 2 ; 4. 206 ; 6. 380
Melinose, 11. 563
Melinum, 4. 404
Meliphane, 4. 206
Meliphanite, 4. 206
Mellephanite, 7. 896
Mellite, 5. 155
Mellitic anhydride, 5. 906
Mellonite, 7. 729
Melnikoffite, 14. 208
Molnikovite, 14. 208
Melnikowite, 12. 53O ; 14. 208
Melonite, 11. 2, 64 ; 15. 6
Melopsite, 6. 423
Molting point and solubility, 1. 585
surface tension, 1. 852
Memaphyllite, 6. 423
Membrane semipermeable, 1. 539
Memilite, 6. 141
Menacanite, 7. 1, 3
Menaccanite, 7. 56, 57 ; 12. 530
Menacconite, 7. 56
Menakanite, 7. 56
Menakeisenstein, 7. 56
Mendeleeffite, 9. 868 ; 12. 5
Mendeleeff's periodic law, 1. 255
Mendeleefite, 9. 906
Mendipite, 2. 15 ; 7. 491, 736, 739, 740
Mendozite, 2. 656 ; 5. 154, 341
Meneghinite, 7. 491 ; 9. 343, 546
Mengite, 5. 523 ; 9. 906
Mennige, 7. 491
Menstruum sine strepitu, 3. 626
Mephites, 6. 2
Mephitio air, 8. 45, 46
INDEX 625
dimercuriammonium sulphate, 4.
98O
hydroxyamidosulphate, 4. 979
mercuric diamminonitrate, 4. IOOI
dihydrated, 4. 3 OOl
hydrated, 4- IOOI
hydroxyamidonitrate, 4. IOOO
phosphate, 4. 1005
mercurihydroxysulphatoamide, 4- 977
� hydrated, 4-977
oxidimercuriammonium sulphate, 4.
979
oxydimorcuriammonium nitrate, 4.
iooo
oxymereuriammonium phosphate, 4.
1005
decahydratod, 4. 1005
oxynitrate, 4. 1002
oxysulphate, 4. 978
_ !� dihydrated, 4. 978
Mercuriammonium(di), see Dimercuriam
monium
(mono)morcurianxmonium nitrate, 4. IOOO
(tetra)mercuriammonium bromide, 4. 889
chloride, 4. 869
Mercuric acid, 4. 779
allylenide, 5. 869
� amide, 4. 784
amidochromate, 11. 284
amidonitrate, 4. IOOI
hemihydrated, 4. IOOI
-� amidosulphonate, 8. 643
� ammidochloride, 4. 786
ammines, 4. 786
amminochloridos, 4- 845
� amminoiodide, 4. 786
� amminoiododisulphide, 4. 963
amminooxysulphite, 10. 292
amminosulphite, 10. 292
ammonium bromosulphite, 10. 296
�� bromotetrachlorido, 4. 882
chlorosulphite, 10. 292, 296
dibromochloride, 4. 882
dibromodiiodide, 4. 918
. dibromotrichlorido, 4. 882
imidodisulphonate, 8. 657
nitrates, 4. 999
nitratotetrachloride, 4. 997
oxynitrate, 4. 1002
pentabromide, 4. 891
VOl-- XVI.
�� imidodisulphonate, 8. 658
pentahydrate, 8. 658
octamminotetraiodide, 4. 940
octochloride, 4. 86O
hexahydrated, 4. 86O
phosphatohenatungstatc, 11. 868
sulphide, 4. 957
pentahydratod, 4. 957
sulphite, 10. 3OO
tetrabromide, 4. 894
� tetraiodide, 4. 94O
. pentahydrate, 4. 94O
beryllium chloride, 4. 86O
� borate, 5. 1OO
- borotungstato, 5. 110
bromate, 2. 352
-� bromide, 1. 52O
ammonia compounds, 4. 885
basics 4. 884
properties, chemical, 4. 879
physical, 4. 877
brornodisulphide, 4. 963
- bromoiodide, 4. 917
bromonitride, 4. 789
bromosulphide, 4. 961
cadmium chlorides, 4. 861
941
oxybromide, 4. 894
oxynitrate, 4. 998
tetrabromide, 4. 894
. tetrachloride, 4. 859
tetraiodide, 4. 934
� tribromide, 4. 893
tribromodiiodide, 4. 934
trichloride, 4. 859
trichlorodibromide, 4. 893
triiodide, 4. 934
�_ oxynitrate, 4. 997
tetrabromide, 4. 894
2 s
626 GENEKAL
octohydrated, 4. 939
___..� carbide, 5. 868
� carbonate, 4. 982
colloidal, 4. 982
chloramide, 4. 785, 862, 869
chlorate, 2. 351
chloride, 4. 816 ; 13. 609
physical, 4. 818
chlorite, 2. 284
chloroantimonite, 9. 482
chlorodecabromide, 4. 893
-- chlorodisulphide, 4-. 961
chloroiodide, 4. 806, 917
� chloroiodoHulphide, 4. 963
ehloronitride, 4. 869, 87O
chloroplatinate, 16. 329
chlorosulphide, 4. 961
chromate, 11. 282
chromic sulphotrithiocyanatodiam
� bromopentammmoctobromide,
14. 725
bromopentamminoctochloride,
14. 725
car bona topentamminoiodide, 14.
817
__ chloropentamminoctochloride,
14. 665
chloropentamminohexaiodide,
14. 746
chloropentamminotetrachloride,
14. 665
� chloropentammino tetraiodide,
14. 746
chloropyridinebisethylenediaminechloride,
14. 666
diaquotetramminochloride, 14.
662
dibromobisethylenediamine bromide,
14. 730
INDEX
� hexamminoenneachloride, 14.656
hexamminoenneaiodide, 14. 743
hexamminoheptachloride, 14.656
hexanuninopentabromide, 14.720
hexamminopentachloride, 14.656
hexamminopentaiodide, 14. 743
hexammino tr ichloropen ta
� /n-peroxo-decamminohenachloride,
14. 673
trisethylenediaminebromido, 14.
722
cobaltous bromide, 14. 718
hexaiodidc, 14. 741
oxybromide, 14. 718
tetrachloride, 14. 645
tetraiodide, 14. 741
935
hexaiodide, 4. 936
hexamminohexaiodide, 4. 936
octamminotetraiodide, 4. 935
tetraiodide, 4. 935
tetramminopentaiodide, 4. 936
triamminopentaiodide, 4. 936
triiodide, 4. 935
diamidodiphosphate, 8. 711
diamminobromide, 4. 886
diamminochloride, 4. 786, 84O
monohydrated, 4. 977
diamminoxynitrate, 4. 10Ol
diammonium dinitratodichloride, 4.
997
diarsenatoctodecatungstate, 9. 214
diarsenite, Q. 128
GENERAL INDEX
hexanitrite, 8. 495
tetrabromide, 4. 891
tetrachloride, 4. 852
tetraiodide, 4- 927
� hexahydrated, 4. 927
octohydrated, 4. 927
tribromide, 4. 891
trichloride, 4- 852
trinitrite, 8. 495
.� tetrabromide, 4. 894
tetrachloride, 4. 861
tetraiodide, 4. 94O
ennoahydrate, 4. 94O
4. IOOI
dihydratod, 4. IOOI
hydrated, 4. 10Ol
phosphate, 4. 1005
mercuriimidonitrito, 8. 495
�� hemihydrate, 8. 495
monohydrate, 8. 495
metantimonato, 9. 456
pentahydrate, 9. 456
metasulpharsenite, 9. 297
metasulphotetrantimonite, 9. 543
metatungatate, 11. 826
� metavanadate, 9. 774
molybdato, 11. 563
monamminochloride, 4. 845
___ monamminoiodide, 4. 922
inonomorcuriammoniurn liydroxyami
donitrate, 4. 100O
monoxydisulphate, 4. 973
monoxysulphate, 4. 973
monoxytrisulphate, 4. 973
nickel amminoiodides, 15. 433
nitraniidate, 8. 269
nitrate, 4. 991
basic, 4. 994
complex salts, 4. 995
hemihydrated, 4. 992
monohydrated, 4. 992
octohydrated, 4. 992
properties, chemical, 4. 993
physical, 4. 992
nitratobromide, 4. 997
nitratochloride, 4- 997
nitratodisulphide, 4. 996
nitratoiodide, 4. 915, 997
nitride, 4. 784 ; 8. 107
nitrite, 8. 493
INDEX
colloidal, 9. 184
orthoarsenite, 9. 127
orthohexatantalate, 9. 904
orthosulpharsenate, 9. 321
orthosulphoantimonate, 9. 575
orthotellurate, 11. 95
osmiamate, 15. 728
oxide, 4. 771
colloidal, 4. 772
preparation, 4. 771
physical, 4. 774
red, 4. 773
yellow, 4. 773
oxyamidoarsenate, 9. 184
� oxyamidophosphate, 4. 1005
oxyamidosulphonate, 8. 643
oxy bromides, 4. 884
� oxybromoamide, 4. 888
dihydrated, 4. 888
oxy chlorides, 4. 839
oxychloroamide, 4. 867
� � oxyiodoaluminate, 5. 329
oxyiodotrisulphato, 4. 975
oxymercuriammonium phosphate, 4.
1005
sulphite, 10. 296
oxy nitrate, 4. 994
oxysulphatosulphides, 4. 973
oxysulphite, 10. 294
oxysulphosulphato, 4. 974
oxytetrasulphite, 10. 296
� oxytrimercuriammonium nitrate, 4.
10Ol
oxytriselenite, 10. 828
pentachloropyridinoiridate, 15. 768
pentachloropyridinoporiridito,* 15. 766
pentahydroxychloroplatinato, 16. 333
orthotellurate, 11. 94
osmiamate, 15. 7O
dihydroxytrinitrate, 4. 99O
oxide, 4. 768
dihypovanadatoheptadecatungstate,9.
747
oxybromide, 4. 876
dinitratarsenate, 9. 337
oxychloride, 4. 805
oxydiiodonitritoplatinite, 8. 523
dioxynitrate, 4. 989
oxydinitrate, 4. 989
hydrated, 4. 989
_ hydrated, 4. 989
fluoride, 4. 793
oxyimidosulphonate, 8. GBH
fluosilicate, 6. 954
oxynitratophosphate, 4. 1002
oxytetranitritoplatinite, 8. 52O
hydroxytrinitrate, 4. 99O
669
hyponitrite, 8. 414
phosphitotungstate, 8. 919
793
imidosulphonate, 8. 655
iodate, 2. 352
pyroarsenate, 9. 183
iodide, 4. 895
pyrophosphate, 4. 1002
colloidal, 4. 897
preparation, 4. 895
pyrosulpharsenate, 9. 321
physical, 4. 897
pyrosulpharsenite, 9. 296
lead oxyhexanitrate, 7. 869
luteovanadatophosphate, 9. 828
plumbite, 7. 669
preparation, 4. 700
properties, chemical, 4. 752
physical, 4. 711
purification, 4. 706
red oxide, 4. 771
reduction compounds to, 4. 702
sickening of, 3. 498
silicate, 6. 438
silicates, 6. 438
silicide, 6. 782
tetradeoaiodide, 7. 238
Meretrix motallorurn, 3. 69
Merim6e's yellow, 9. 46()
Meroxones, 6. 611
Merwinite, 6. 409
Mesiterispath, 14. 369
Mesitino, 4. 349 ; 14. 369
Mesitito, 4. 349 ; 12. 530 ; 14. 369
Mesoboric acid, 5. 48
Mesodiphosphoric acid, 8. 948
Mesodisilicic acid, 6. 294
Mesohexasilicic acid, 6. 294
Mesoiodic acid, 2. 322
Mesole, 6. 709
Mesolin, 6. 729
Mesolite, 6. 749
__ soda, 6. 652
thallium, 6. 751
thallo-, 6. 826
1, 7. 186
2, 7. 188
Mesotrisilicic acid, 6. 294
Mesotype, 6. 749
epointee, 6. 368
soda, 6. 652
Messelite, 8. 733
Messing, 4. 399
Meta-alumina, 5. 282
Meta-alumina tes, 5. 285
Meta-aluminic acid, 5. 274, 285
Metacarbonatos, 6. 72
Motacarbonic acid, 6. 72
Metaceria, 5. 501
Metachlorite, 6. 623
Metachromatism, 2. 221
Meta-elements, 5. 495
�� ammonias, 8. 243
antifriction, 4. 671
noble, 3. 525
of salt, 2. 421
white, 3. 25
Metalanthanates, 5. 628
Metallo defosforato, 12. 709
Metallography, 12. 791
rex, 3. 297
Motalonchidite, 14. 200
Metals base, 1. 248
603
634 INDEX
noble, 1. 248
perfect, 1. 248
sacrificial, 1. 1025
semi-, 1. 240
transmutation, 1. 49
Metaluteotungstic acid, 11. 77O
Metamerism, 5. 122
Metanatrolite, 6. 654
Metantimonic acid, 9. 442
Metantimonious acid, 9. 420
Metapercolumbic acid, 9. 869
Metaperiodic acid, 2. 386
Metaperowskite, 7. 63
Metapertantalic acid, 9. 913
Metaphosphimic acid, 8. 716
Metaphosphoric acid, 8. 948, 977
hydration, 8. 979
physical, 8. 978
Metaphosphorous acid, 8. 921
Metaphosphoryl chloride, 8. 1019, 1028
Metaplatinic acid, 16. 244
Metaplumbic acid, 7. 685
Metargon, 7. 890
Metarossite, 9. 769
Metarsenic acid, 9. 140
Metarsenious acid, 9. 102
Metascolecite, 6. 750
Metasericite, 6. 606
Metasilicalosodalite, 6. 583
Metasilicic acid, 6. 293, 294
acids, 6. 308
Motastable equilibrium, 1. 715
states, 1. 454
Metastannic acid, 7. 406
Metastibnite, 9. 343
Metasulfamidique acide, 8. 670
Metasulfazilique acide, 8. 67O
Metasulpharsenatosulphomoly bdates, 9.
322
Metasulpharsenic acid, 9. 315
Metasulpharsenious acid, 9. 289
Metasulphatoplumbic acid, 7. 823
Metasulphennearsenious acid, 9. 289
Metasulphoantimonious acid, 9. 532
Metasulphoctoantimonious acid, 9. 532
Metasulphoctarsenious acid, 9. 289
Metasulphootodecarsenious acid, 9. 289
Metasulphosilicic acid, 6. 987
Metasulphotetrarsenious acid, 9. 289
Metasulphotriarsenious acid, 9. 289
Metasulphoxylic acid, 10. 165
Metasulphuric acid, 10. 357
Metasulphurous acid, 10. 238
Metatantalic acid, 9. 898
Metatelluric acid, 11. 83, 87, 88
Metathiocarbonic acid, 6. 119
Metathoric acid, 7. 224
Metatetrarsenious acid, 9. 117
Metatitanic acid, 7. 4O
Metatorbernite I, 12. 134
Methanides, 5. 846
Methoxyphenylammonium bromoplatinate,
16. 375
15. 67O
Methylene nitratobismuthate, 8. 272
3-methylypyridinium bromoplatinate, 16.
376
Metillkalk, 11. 122
Metillure, 13. 559
Metolhydroquinone, 13. 615
Meyerhofferite, 5. 91
Meyer's process vapour density, 1.185
Meymaoite, 11. 764
Miargyrite, 0. 343, 539
Mica, 6. 604
baryta, 6. 607
biaxial, 6. 606
border, 6. 612
bronzes, 6. 62O
chlorite, 6. 622
feather, 6. 613
green, 12. 1
lime, 6. 708
lithia, 6. 607
manganese, 6. 608
oblique, 6. 606
pearly, 6. 708
potash, 6. 606, 607
ribbon, 6. 613
ruled, 6. 613
sericitic, 6. 47O
soda, 6. 608
uranium, 12. 2
uses, 6. 619
� vanadium, 6. 836
viridis, 12. 1
water, 6. 606
brachydiagonal, 6. 613
brittle, 6. 603
macrodiagonal, 6. 613
Michaelsomite, 7. IOO
Michaelsonite, 5. 509
Microbalance, 1. 184
Microbromite, 8. 418
Micrococeus nitrificaiis, 8. 357
Microclase, 6. 664
Microcline, 6. 662, 663
albite, 6. 664
macroperthite, 6. 663
oligoclase, 6. 664
perthite, 6. 663
Microclines soda, 6. 669
Microlepidolite, 6. 615
Microlite, 5. 519 ; 7. 896 ; 9. 839, 903 ; 12. 6
Microlith, 3. 623
Microorganisms in air, 8. 2
Microperthite, 6. 663
microcline, 6. 663
Microscope polarizing, 1. 608
Microsommite, 6. 58O, 584
Microstructure iron, 12. 791
Micro-weighing, 1. 184
Miedziankite, 9. 296
Miemite, 4. 371
Miersite, 8. 426
Miesite, 7. 883
Migration of ions, 1. 983
Migsite, 14. 329
Milanite, 6. 495
Milarite, 6. 746
Milchquartz, 6. 138
Mild alkali, 2. 495
alkalies, 2. 421
purple stone, 6. 468
Milk, 13. 615
of lime, 3. 676
sulphur, 10. 3O
Millerito, 15. 5, 435
Miller's system, crystal notation, 1. 614
Millibar, 1. 15O
Millimol, 1. 392
Millival, 1. 392
Millon's base, 4. 787, 792
second, 4. 788
chloride, 4. 867
nitrate, 4. IOOO
salts of, 4. 788
sulphate, 4. 979
sulphureuse, 9. 684
cobalt, 9. 76
arseniale, 9. 76
arsenicosulfureuso, 9. 308
sulfureuse, 14. 757
mercure cornee, 4. 798
volatile, 4. 798
plomb, 5. 713
noire, 5. 713
waters, 13. 611
Minera antimonii plumosa, 9. 546
argenti alba, 9. 291
rubra pellucida, 9. 294
blue, 11. 745
ferri alba spathiformis, 14. 355
attractoria, 13. 731
lacuotris, 13. 885
nigricans magneti arnica, 13. 731
palustris, 18. 885
subaquosa, 13. 885
fuliginea, 12. 14O
plumbi rubra. 11. 122, 29O
viridis, 9. 26O
Mineral alkali, 2. 42O
de Coromandel, 6. 831
green, 8. 27O ; 9. 122
lac, 11. 29O
turbite, 4. 964
turpeth, 4. 964, 972
GENERAL, INDEX
synthesis, 6. 313
Minervite, 5. 155, 362 ; 8. 733
Mines d'antimoino aux plumes, 9. 546
Minette, 12. 530
Minguetite, 6. 624 ; 12. 53O
Mining gold hydraulic, 3. 496
placer, 3. 496
reef, 3. 497
vein, 3. 497
Minium, 4. 942 ; 7. 672, 673
nativum, 7. 673
Mirabilite, 2. 656
Miriquidite, 7. 491 ; 9. 228
Mischmetall, 5. 608
Mispiokol, 9. 4, 306 ; 12. 530
Mispikkol, 9. 306
Mistpickel, 9. 306
Mists, chemical, 10. 401
Misy, 3. 3 ; 14. 243, 329
Misylite, 14. 329
Mitchellite, 11. 201
Mitis green, 9. 122
Mitschorlioh's law isomorphism, 1. 652
Mochastone, 6. 139
Mock lead, 11. 673
silver, 4. 400
of elasticity, 1. 820
sheer, 1. 82O
Young's, 1. 82O
Mohsino, 9. 73
Mohsite, 7-57
in air, 8. 9
MoI, 1. 392
of colloids, 1. 773
weights, abnormal, 1. 569
and molecular volumes, 1. 763
volumes, 1. 2Ol
ratio of two specific heats and, 1.
788
Molecule, electric charges "within, 4. 188
Molecules, 1. 174, 740
� elementaires, 1. 173
field of force, 4. 187
free path, 1. 748
integrantes, 1. 173
Molongraaffite, 6. 843 ; 7. 3
Molisite, 14. 4O
Mollito, 5. 37O
Molt rami to, 7. 491
Molybdan, 11. 485
Molybdama, 5. 713 ; 7. 638
Molybdandichlorid, 11. 619
Molybdanglanz, 11. 485
622
chloride, 11. 629
~- dioxy tetrachloride, 11. 632
_ � enneafluoride, 11. 610
hemipentoxide, 11. 532
- heptachlorido, 11. 621
� bishydroai'senate, 9. 205
bismuth alloys, 9. 639
blue (natural), 11. 530
boride, 5. 29
bromides, 11. 634
cadmium alloys, 11. 523
caesium dioxy tetrachloride, 11. 632
INDEX 637
� silicate, 6. 866
silver alloys, 11. 522
sodium alloys, 11. 522
borate, 5. 108
Monoperoxycarbonates, 6. 86
Monoperoxydiearbonates, 6. 86
Monopliane, 6. 761
Monophosphamide, 8. 709
Monosilandiol, 6. 216
Monosilane, 6. 216
Monosilanol, 6. 216
Monosilieopropano, 6. 216
Monouranates, 12. 61
Monox, 6. 235
Monoxodioxydisiloxarie, 6. 235
Monradito, 6. 821
Monrolito, 6. 456
Montanin, 6. 945
Montanite, 9. 589 ; 11. 2, 97
Montmorillonito, 6. 497
Moonstone, 6. 662
ignis, 1. 60
Moufette atmospherique, 1. 68
Mountain blue, 5. 370 ; 6. 343
soap, 6. 498
Mud, 8. 27
Miillerin, 11. 45
Mullerine, 3. 494
Muldan, 6. 663
Mullite, 6. 454
173
Multivalent elements, 4. 174
Mundic, 12. 53O ; 14. 199
Muntz metal, 4. 671
Murate, 6. 896
Murclisonite, 6. 663
Muriacite, 3. 761
Muriate de rciercure des chirnistes, 4. 798
Muriatic acid, 2. 2O, 21
Muromonite, 4. 206 ; 5. 509
Muscovite, 6. 603, 604, 606
gold, 7. 469
Muscovy glass, 6. 606
Musenite, 14. 757
Mushet steol, 13. 634
Musite, 5. 521
Mussite, 5. 521 ; 6. 409
Muthmannito, 11. 2, 49
Myelin, 6. 472
Mysorine, 3. 267, 269
Mythological chemistry, 1. 2
Naak, 7. 277
Nacrite, 6. 477, 606
Nadoleisenerz, IS. 877
Nadelerz, 9. 693
Nadorite, 7. 491 ; 9. 343, 507
Naegite, 6. 857 ; 7. 167 ; 12. 5
Napchenkobold, 9. 2, 3
Napfchenbobelt, 9. 3
Naga, 7. 277
Nagiakorerz, 11. 114
Nagyager orz, 11. 1
silber, 11. 45
Nagyagite, 3. 494 ; 7. 491 ; 11. 2, 114
Nagygite, 11. 1, 5
Nail-head spar, 3. 814
Namaqualito, 5. 154
Nantokite, 2. 15 ; 3. 157
Nantoquite, 3. 157
Naphthylamine bromopalladite, 15. 677
yellow, 9. 457
Nareoticus knielii, 4. 943
Narsarsukite, 6. 843 ; 7. 3 ; 12. 53O
Nascent state, 1. 331
Nasonite, 6. 889 ; 7. 491
GENERAI, INDEX
Nasturan, 12. 5, 50
Natar, 2. 419
Natroalun, 5. 341
Natroalunite, 14. 344
Natroamblygonite, 2. 426
Natrocaleite, 3. 622
Natrochalcite, 3. 257
Natrojarosite, 12. 53O ; 14. 343, 344
Natrolite, 6. 575, 652, 762
iron, 6. 653
meta-, 6. 654
palaeo-, 6. 652
potash, 6. 654
thallo-, 6. 826
Natromicrocline, 6. 664
Natron, 2. 7IO
Natronchabazite, 6. 734
Natrophylite, 2. 426 ; 12. 149, 454
Natrophyllite, 8. 733
Natroxonotlite, 6. 36O
Natural alloy, 15. 179
smolt, 5. 37O
Naumannite, 3. 3OO ; 10. 771
Nebulte spectra, 4. 19
Nebulium, 4. 21, 171 ; 5. 617
Neeronito, 6. 663
Noodle ironstone, 12. 530 ; 13. 877
ore, 9. 589, 693
tin ore, 7. 394
Nofedieffite, 6. 825
Nefedjewite, 6. 825
Negative, 3. 412
catalysts, 1. 938
corpuscles, 4. 28
evidence, 1. 83
glow, 4. 24
valence, 4. 191
Nemalite, 4. 29O
Nemaphyllite, 6. 407
Nexnatolite, 4. 29O
Neocoleinanito, 5. 9O
Neoofcese, 9. 224
Neocyanite, 6. 341
Neodidymium, 5. 501
Neodymia, 5. 625
preparation, 5. 588
Neodymium, 6. 5Ol
ammonium carbonate, 5. 666
molybdate, 11. 587
nitrate, 5. 671
analytical reactions, 5. 608
atomic number, 5. 622
weight, 5. 621
barium tungstate, 11. 791
bromate, 2. 354
bromide, 5. 645
caesium sulphate, 5. 658
carbide, 5. 873
carbonate, 5. 664
oeric sulphate, 5. 662
chloride, 5. 643
hexahydrated, 5. 643
monohydrated, 5. 643
chloroxalate, 6. 643
chromate, 11. 287
octohydrate, 11. 287
cobaltous nitrate, 14. 828
cuprous disulphite, IO. 302
dithiosulphate, 10. 55O
diamminochloride, 5. 644
VOL. XVI.
baryta, 6. 571
silver, 6. 570
strontia, 6. 571
Neponite, 15. 5
Nertsehinskite, 6. 495
Netor, 2. 419
rule, 1. 805
Neurolite, 6. 500, 921
Neusilbor, 15. 209
Neutral salts, 1. 388
Neutrality, Richter's law of, 1. 391
Neutralization, 1. 389, 391
acetonesol, 15. 41
aerosols, 15. 41
alcoholsol, 15. 41
313
dimetaphosphate, 15. 496
disulphate, 15. 467
dithionate, 10. 598
hexamminosulphate, 15. 468
lead nitrite, 8. 512
_ nitritobismuthite, 8. 572
11. 670
phosphite, 8. 92O
selenate, 10. 887
strontium nitrite, 8. 511
sulphate electrolysis, 1. 962
sulphatofluoberyllate, 15. 478
- antimonite, 9. 433
aquohemiamminofluoride, 15. 404
aquomonamminofluoride, 15. 404
aquopentamminofluoride, 15. 404
aquopentamminosulphate, 15. 464
arsenical, 9. 8O
arsenitornolybdate, 9. 131
atomic disruption, 15. 177
number, 15. 177
weight, 15. 175
autunite, 12. 135
azide, 8. 355
barium alloy, 15. 206
pentasulphide, 15. 444
tetranitrite, 8. 511
benzenosol, 15. 41
beryllium alloys, 15. 205
chromium steels, 15. 327
fluoride, 15. 405
biarseniet, 9. 76
bisdiacetyldioximosulphate, 15. 466
bisethylenediaminechloroplatinate, 10.
332
INDEX 643
Nickel bishexamethylenediaminotetrathionate,
10. 62O
bishexamethylenetetraminopersulphate,
IO. 48O
bismethylhydroxyglyoximosulphate,
15. 466
bismuth alloys, 9. 640
nitrate, 9. 71O ; 15. 492
bisphenylenediaminosulphate, 15. 465
bisquinolinosulphate, 15. 465
bissulphoarsenoantimonide, 9. 556
bistriaminopropanoiodide, 15. 433
bistriaminopropanosulphate, 15- 466
bistriannnopropylarninoiodide, 15. 433
bistriannnotriethylenebrornide, 15. 429
bistriaminotriethylenoiodide, 15. 433
bistriaminotripropylaminohydroxyiodide,
15. 433
bistrimethylenediaminosulphate, 15.
465
blende, 15. 435
bloom, 9. 5 ; 15. 5
boracite, 5. 14O
boride, 5. 31
boron alloys, 15. 223
borotungstate, 5. Il l
bournonite, 9. 550
brass, 4. 676
brasses, 15. 2IO
bromate, 2. 36O
ammino-, 2. 361
bromide, 15. 425
bromoplatinate, 16. 38O
bromostannate, 7. 457
-��� bronze, 15. 179
bronzes, 15. 235
cadmium alloys, 15. 222
trisethylonodiaminobromide, 15.
429
� trisethylonodiaminochloride, 15.
417
trisothylonediaminoiodide, 15.
433
caesium amminotrichloride, 15. 419
barium nitrite, 8. 512
chromate, 11. 313
iodide, 15. 433
nit ri to bismuth! to, 8. 513
solenate, 10. 889
tribromide, 15. 429
trichloride, 15. 419
calcium alloys, 15. 205
arsenate, 9. 231
sulphate, 15. 475
carbonate, 15. 483
hexahydrate, 15. 483
trihydrate, 15. 483
carbonyl, 5. 953
catalysis by, 1. 487
catalyst, 15. 47
eerie nitrate, 15. 492
cerium alloys, 15. 232
cerous nitrate,"15. 492
chlorate, 2. 360
ammino-, 2. 36O
chloride, 15. 406
dihydrate, 16. 407
> dodeoahydrate, 15. 407
heptahydrate, 15. 407
hexahydrate, 15. 407
317
ditelluride, 11. 64
dithionate, 10. 598
ditritantimonide, 9. 414
ditritaphosphide, 8. 860
ditritarsenide, 9. 79
ditritasilicide, 6. 207
ditritastannide, 15. 232
ditungstate, 11. 8IO
dodecabromodidymate, 5. 645
dodecabromolanthanate, 5. 645
dodecametavanadate, 9. 792
dodecamminochloroplatinate, 16. 332
electrodeposition, 15. 33, 96
electronic structure, 15. 177
enneaamminonitrate, 15. 49O
ethylenediamino disulphate, 15. 469
ethylstannonate, 7. 4IO
extraction, 15- 15
433
lithium metaphosphato, 15. 496
trichloride, 15. 419
malleable, 15. 27
406
manganide, 15. 251
manganite, 12. 243
matte, 15. 446
mercuric amminoiodides, 15. 433
metabromoantimonato, 9. 497
metantimonate, 9. 461
dodecahydrato, 9. 461
INDEX
� monotellurido, 11. 64
tetrabydrate, 11. 64
monothiophosphate, 8. 1069
monoxide, 15. 373, 374
preparation, 15. 374
properties, chemical, 15. 578
physical, 15. 375
native, 15. 435
neodymium nitrate, 15. 492
nitrate, 11. 831
nitrates, 15. 487
nitride, 8. 137
occurrence, 15. 3
ocihre, 15. 6
octitoaluminide, 15. 223
octoborate decahydrated, 5. 115
octochloriodide, 15. 432
octonuozirconate, 7. 142
oreide, 15. 210
organosol, 15. 41
ort hoar senate, 9. 230
dihydrate, 9. 23O
octohydrate, 9. 230
� orthoarsenite, 9. 134
orthoborate, 5. 115
orthophosphate, 15. 494
orthosilicate, 6. 932
orthostannate, 7. 420
orthosulphantimonite, 9. 555
orthosulpharsenate, 9. 324
orthovanadate, 9. 791
osmium alloys, 15. 697
oxalatodinitz'itodecamminocobaltiate,
8. 51O
oxide aerosol, 15. 385
oxides, higher, 15. 398
intermediate, 15. 395
oxyarsenate, 9. 231
oxy chloride, 15. 412
oxychrornate, 11. 313
oxydut-raagnesia, 15. 401
oxyfluoride, 15. 404
� perborate, 5. 120
perchlorate, 2. 403
ammino-, 2. 404
periodate, 2. 416
permonosulphomolybdato, 11. 654
peroxide, 15. 398
perrhenate, 12. 477
pentahydrate, 12. 477
tetrahydrate, 12. 477
peruranate, 12. 73
phenylhydrazinosulphato, 15. 466
phosphates, 15. 494
physical, 15. 5O
purification, 15. 27
pyridinopermanganate, 12. 336
pyridinosulphate, 15. 465
pyrites, 15. 435
pyrosulpharsonate, 9. 324
- pyrosulpharsenatoxymolybdate, 9. 331
- rubidium chromate, 11. 313
. disulphate, 15. 471
nitritobismuthite, 8. 513
selenate, 10. 888
� tetrachloride, 15. 419
- ruthenium alloys, 15. 5IO
smaragol, 15. 6
Yf 15. 437
sulpharsenite, 9. 302
tellurite, 11. 82
monohydrated, 11. 82
tetraborate hexahydrated, 5. 115
tetraquoothylenediaminosulphate, 15.
465
tetraselenite, 10. 841
� tetrasulphido, 15. 443
tetrathionate, 10. 619
tetravanadate, 9. 792
tetrazincide, 15. 208
tetritacobaltide, 15. 333
tetritantimonide, 9. 414
tetritaoxide, 15. 373
tetritasilicide, 6. 207
tetritastannide, 15. 232
tetritatrihydrazinosulphite, 10. 319
tetroxide, 15. 373, 402
tetroxysulphate, 15. 462
decahydrate, 15. 462
enneahydrate, 15. 462
thallic octochloride, 15. 42O
thallium alloys, 15. 231
cadmium nitrite, 8. 512
cerous nitrite, 8. 512
cobalt nitrite, 8. 512
mercuric nitrite, 8. 512
uranyl nitrite, 8. 512
thallous lead nitrite, 8. 512
nitrite, 8. 512
nitritobismuthite, 8. 513
selenate, 10. 889
sulphite, 10. 319
thiocarbarnidophenylhydrazinonitrate,
15. 491
thiocarbonate, 6. 128
thiohypophosphate, 8. 1064
thiophosphate, 8. 1066 ; 15. 496
thiophosphite, 8. 1062
thiopyrophosphate, 8. 1070
thiosulphate, 10. 557
thorium alloy, 15. 232
nitrate, 15. 492
tin alloys, 15. 232
aluminium alloys, 15. 235
titanium alloys, 15. 232
cobalt alloys, 15. 338
hexafluoride, 15. 405
trialuminide, 15. 224
triamminoarsonate, 9. 231
triamminofluoride, 15. 404
triamminosulphite, 10. 319
triamminothiocarbonate, 6. 128 ; 15.
441, 486
triaquotriamminochloride, 15. 415
triarsenatotetravanadate, 9. 201
triarsenide, 9. 81
tribismuthide, 9. 640
trichloride, 15. 422
trihydrazinochloride, 15. 414, 416
trihydrazinodithionate, 10. 598
trihydrazinonitrate, 15. 491
trihydrazinosulphite, 10- 319
trioxide, 15. 373, 4Ol
trioxysulpharsenate, 9. 329
Nickelerz, 9. 230
Nickelfahlerz, 9. 291
Nickelic ammonium tridecamolybdate, 11.
602
tungstate, H . 802
barium tungstate, 11. 802
chloride, 15. 422
cobaltic ferric oxide, 14. 586
fluoride, 15. 406
oxide, 15. 373, 392
Nickelous dihydroxybrophosphoryltrichlor
ide, 8. 1026
enneaoxydiiodide, 15. 431
ferric fluoride, 15. 406
nitrite, 8. 511
oxide, 15. 373, 374
paratungstate, 11. 820
pernickelite, 15. 396, 4Ol
475
cobaltous sulphate, 15. 478
ferrous sulphate, 15. 477
hexadecamolybdate, 11. 604
magnesium sulphate, 15. 475
manganous sulphate, 15. 477
zinc sulphate, 15. 476
quater-o-phenylenediaminochloride,
15. 417
quaterpyridinochloride, 15. 417
sodium disulphate, 15. 472
a, 15. 455
P, 15. 455
Nickelovanadium, 9. 726
Nickelspiessglanzerz, 9. 555
Nickelspiessglaserz, 9. 555
Nicomelane, 15. 6
Niebeckite, 6. 391
INI>EX
Nitrites, 8. 470
analytical reactions, 8. 464
constitution, 8. 466
preparation, 8. 455
properties, 8. 459
(di )nitritodichlorodiamminocobaltiates, 8.
51O
(di)nitritodimethylglyoximinocobaltiates,
8. 51O
(di)nitritodimethyIglyoximinocobaltic acid,
8. 510
Nitritopentammines, 11. 403
Nitritoperosmous acid, 15. 728
Nitritosulphamide, 8. 66O, 662
m-nitroanilinium. chloropalladite, 15. 670
o-nitroanilinium chloropalladite, 15. 670
jD-nitroanilinium chloropalladite, 15. 670
Nitrobacterine, 8. 360
Nitrocaleite, 3- 623, 849
Nitrocellulose, 2. 829
Nitrocobalt, 8. 545
Nitrocopper, 8. 544
Nitrogen, 1. 69; 8. 36O ; 11. 611; 15.
151
absorption coeff., 8. 75
activated, 8. 85
allotropic, 8. 58, 83
a.-, 8. 58
/S-, 8. 58
I-, 8. 58
H-, 8. 58
amminotriiodide, 8. 607
and CO2, 6. 32
antimonide, 9. 409
arsenide, 9. 69
atomic disintegration, 8. 95
number, 8. 95
weight, 8. 94
bromide, 8. 605
carbide, 5. 887
chloride, 8. 599
cycle, 8. 361
diamminotetrasulphide, 8. 628
dibromopentasulphide, 8. 627
dioxide, 8. 382
discovery, 8. 45
disruption of atom of, 4. 152
disulphide, 8. 629
electronic structure, 8. 96
fixation by direct oxidation, 8. 365
electric discharges, 8. 367
Birkeland and
Edye, 8. 374
_ Island, 8. 376
Kowalsky and
Moscicky, 8*
375
Pauling, 8. 376
Schonherr, 8. 375
Scott, 8. 376
� organisms, 8. 357
halides, 8. 598
hexabromotetrasulphide, 8. 627
hexoxide, 8. 383, 53O
hydrotetrasulphatopentoxide, 10. 345
iodide, 8. 605
in air, 8. 3
isopentoxide, 8. 530
�. isotopes, 8. 95
manufacture from liquid air, 1. 874
GENERAL INDEX
- Linde's process,
1. 874
mercury compounds, 4. 785
molybdenum tetrasulphopentachloride,
11. 625
monotelluride, 11. 58
monoxide, 8. 382
occurrence, 8. 46
oxides, 8. 382
in air, 8. 11
oxysulphides, 8. 631
pentasulphide, 8. 63O
pentoxide, 8. 382, 551
peroxide, 8. 529, 53O
constitution, 8. 546
hydrated, 8. 54O
properties, chemical, 8. 536
�� physical, 8. 531
persulphide, 8. 629
� phosphide, 8. 851
preparation, 8. 48
properties, chemical, 8. 79
physical, 8. 53
selenido, 10. 788
solubility, 8. 75
stannic ehlorosulphide, 7. 444
oxychloride, 7. 445
trioxychloride, 7. 445
sulphide, 8. 624
sulphides, 8. 624
sulphonitrate, 8. 630
tetrachlorododecasulphido, 8. 627
tetrachlorotetrasulphide, 8. 627
tetrasulphide, 8. 624
blue allotrope, 8. 626
tetroxide, 8. 382, 529, 530
titanium hexachlorotetrasulphide, 7.
77
sulphotetrachloride, 7. 84
sulphotrichlorido, 7. 84
trihydrazinide, 8. 339
trihydrotrinitride, 7. 761
trioxide, 8. 449
properties, chemical, 8. 452
physical, 8. 45O
tungsten tetrachlorotetrasulphide, 11.
843
valency, 8. 89
Nitrogene, 8. 46
Nitroglauberite, 2. 691, 803, 816
Nitroglycerol, 2. 829
Nitrohydrochlorio acid, 8. 618
Nitrohydroxylamio acid, 8. 582
Nitrohydroxylaminie acid, 8. 305
Nitroiron, 8. 545
Nitromagnesite, 4. 252, 379
Nitromuriatic acid, 8. 618
Nitron, 8. 419 ; 5. 1
bromoiridate, 15. 777
Nitronamblygonite, 6. 367
Nitronickel, 8. 545
Nitronium hydrosulphate, 8. 567
oxyperchlorate, 8. 567
perchlorate, 8. 567
pyrosulphate, 8. 567, 703
Nitrosic acid, 8. 540
Nitrosisulphonic acid, 8. 692
Nitroxan, 8. 212
Nitroxyl amide, 8. 268, 382
bromide, 8. 623
chloride, 8. 623
fluoride, 8. 623
halides, 8. 622
iodide, 8- 623
oxide, 8. 552
tetrantimonyltetrachloride, 9. 476
(di)nitroxyl dinitric acid, 8. 542
selenyl, 8. 696
Nitroxylphosphoric acid, 8. 542
Nitroxylsulphonates, 8. 699
Nitroxylsulphonic acid, 8. 696, 698
anhydride, 8. 699
Nitroyl, 8. 306
� hydrate, 8. 307
(di)nitroyl, 8. 306
Nitr ozone, 8. 88
Nitrum, 2. 419 ; 5. 1
flarnmans, 2. 829
vitriolatum, 2. 656
Nitryl bromide, 8. 623
chloride, 8. 623
fluoride, 8. 623
halides, 8. 622
iodide, 8. 623
Nivenite, 7. 491 ; 12. 5, 50
Nix alba, 4. 506
stibii, 9. 378
Nixes' ore, 15. 1
Nobel metal, 3. 525
Nobilite, 8. 494 ; 14. 114
Nocerino, 2. 2
Nocerite, 3. 623 ; 4. 252
Noctiluea acrea, 8. 73O
consistons, 8. 73O
constans, 8. 73O
glacialis, 8. 730
guimnosa, 8. 73O
Noegite, 7. 1OO
Noheet metal, 7. 607
Nohlite, 5. 516 ; 9. 839 ; 12. 5
Noir d'aeetylene, 5. 752
de fume, 5. 751
platine, 16. 48
vigne, 5. 749
Nomenclature chemistry, 1. 114
chemist's, evolution, 1. 119
Werner's, 1. 209
Non-corrosive steels, 13. 606
metals, 1. 248
polarized molecules, 4. 187
valence, 1. 206
Nonproductive energy, 1. 721
Nontronite, 6. 906 ; 12. 530
Nora minora plumbi, 11. 290
Noralite, 6. 821
Nordenskioldino, 5. 105
Nordenskioldite, 5. 105
Nordenskjoldine, 7. 283, 419
Nordenskjoldite, 6. 404
Nordhausen sulphuric acid, 10. 351
Nordmarkite, 6. 909 ; 12. 53O
Norerde, 7. 99
Noria, 7. 99
Noric acid, 12. 499
Norite, 5. 75O
Norium, 7. 99
Normal liquids, 1. 856
Octochlorotetrasilane, 6. 975
Octochlorotrisilane, 6. 216, 972
Octocosivanadates, 9. 202
Octodecatungstic arsenic acid, 11. 832
Octodecavanadates, 9. 202
Octohydroctosiltridecoxane, 6. 232
Octometaphosphatea, 8. 989
Octometaphosphoric acid, 8. 989
Octomolybdates, 11. 582, 595
Octomolybdic acid, 11. 548
Oc to vanadates, 9. 202
Octovanadatohexadecatungstic acid, 9.
Odontolite, 5. 368
Oedolite, 6. 718
Oerstedite, 6. 847 ; 7. 1OO
Oersted's reaction, 5. 313
Oetotungstates, 11. 773
Oeuil de chat, 6. 139
Off a Helmonti, 2. 800
Offretite, 6. 729
Ohm, 1. 963
Oildag, 5. 753
Oisanite, 6. 721 ; 7. 3O
Okenite, 6. 36O, 361
Olafite, 6. 663
Olata pina, 3. 304
Old Nick's Copper, 15. 1
Oloic acid, 18. 615
Oleum, 10. 351
glaciale vitroli, 10. 332
silicixm, 6. 135
sulphur is, 10. 332
vini, 2. 21
Oligiste, 13. 775
Oligoclase, 6. 662, 693
baryta, 6. 707
microclino, 6. 664
strontia, 5. 707
Oligonite, 12. 15O ; 14. 355, 369
Oligonspath, 14. 355
Oligosiderites, 12. 523
Oliveiraite, 7. 56, 1OO
Olivenerz strahligos, 9. 161
Olivenite, 3. 8 ; 9. 5, 159
Olivine, 6. 385 ; 12. 53O ; 15. 9
Lime-, 6. 386
peridote, 6. 385
titano-, 6. 846
Ollacherite, 6. 607
Ollae fossiles, 6. 512
Ol-salt, 14. 672
Oltremare giallo, 11. 273
Omphacite, 6. 818
Omphazite, 6. 818
Oncophyllite, 6. 607
Ondanique, 12. 853
One Thing, 1. 48
Oneyite, 12. 530 ; 18. 877
Ongoite, 6. 622
Onkoite, 6. 622
Onocsine, 6. 606
Onofrite, 4. 697 ; 10. 694, 780, 919
Ontariolite, 6. 763
Onyx, 6. 139
marble, 8. 815
Oolitic limestone, 8. 815
ore, 5. 249 ; 18. 775
Oosite, 6. 619, 812
Opacity X-rays, specific, 4. 33
Opal, 0. 300, 141
ferric, 6. 662
Orthodiphosphoric acid, 8. 948
Orthodisilicic acid, 6. 310
Ortliodiva.na.dic acid, 9. 758
Orthoferric acid, 13. 905
Orthoferrites, 18. 905
Orthohexaphosphoric acid, 8. 991
Orthohypophosphoric acid, 8. 928
Orthoiodic acid, 2. 322
Orthoraanganous acid, 12. 23J
Orthomolybdic acid, 11. 547
Orthoperiodic acid, 2. 386
Orthophosphates, 8. 966
Orthophosphirnic acid, 8. 716
Orthophosphoric acid, 8. 947, 948
chloride, 8. 1O] 9
Orthoplumbic acid, 7. 685
Orthopyrophosphoric acid, 8. 948
Orthopolyvanadic acid, 9. 758
Orthose, 6. 662
Orthosilicic acid, 6. 293, 294, 308
Orthostannic acid, 7. 408
Orthosulpharsenic acid, 9. 315
Orthosulpharsonious acid, 9. 289
Orthosulphoantimonious acid, 9. 532
Orthosulphoctoantimonious acid, 9. 532
Orthosulphosilieic acid, 6. 987
Orthosulphotetrantimonious acid, 9. 532
Orthosulphotetrarsonious acid, 9. 289
Orthosulphoxylic acid, 10. 165
Orthosulphurie acid, 10. 357
Orthosulphurous acid, 10. 238
Orthotelluric acid, 11. 83, 87, 88
Orthotetrarsenious acid, 9. 117
Orthothiocarbonic acid, 6. 119
Orthothiophosphoric acid, 8. 1062
Orthotitanie acid, 7. 39
Orthotungstie acid, 11. 764
Orthozirconic acid, 7. 128
Oruetite, 11. 2, 60
Orvillite, 6. 844 ; 7. 1OO
Oryzite, 6. 755
Osannito, 6. 917 ; 12. 53O
Osman, 15. 727
Osman-osmic acid, 15. 727
Osmelite, 6. 366
Osmiamic acid, 15. 727
Osmic acid, 15. 705, 707
10. 324
negative, 1. 541
positive, 1. 541
reversed, 1. 541
concentration, 1. 543
� freezing point, 1. 568
� gas la-ws, 1. 543
558
pressures abnormal, 1. 570, 573
Osmous sulphate, 15. 726
sulphite, 15. 726
1002
Ostwald's dilution law, 1. 992
salts, i. 919
Oxozone, 1. 899
Oxyacids, 1. 386
656 GENERAL, INDEX
IOOO
ammonium dichromate, 11. 342
chloride, 4. 867
chroraate, 11. 284
fluoride, 4. 796
iodide, 4. 924
morcuriammonium nitrate, 4. 10OO
sulphate, 4. 979
� mercuric oxyquadrichromate, 11. 284
oxytrimorcuriammonium sulphate, 4.
980
_ weight, 1. 38O
--� boiling point, 1. 365
combustion, 1. 374
, calcium, 1. 374
chloride, 1. 370
cyanide, 1. 370
hydroxide, 1. 369
iodide, 1. 37O
nitrate, 1. 37O
sugar, 1. 37O
sulphuric acid, 1. 369
water, 1. 369
spark, 1. 367
stark effect, 1. 368
storage, 1. 356
surface tension, 1. 364
thermal conductivity, 1. 365
expansion, 1. 365
uses, 1. 379
vapour pressure, 1. 365
velocity of molecules, 1. 363
sound, 1. 364
INDEX
pentoxide, 1. 907
� ammonia, 1. 907
tribromide, 1. 907
aniline, 1. 911
trichloride, 1. 907
trichloride, 1. 907
1. 911
arsine, 1. 907
acid, 1. 905
�. benzene, 1. 911
alkaline, 1. 905
tellurium, 1. 906
thallous salts, 1. 9IO
tin, 1. 909
water, 1. 903
zinc, 1. 908
as oxidizing agent, 1. 905�9IO
reducing agent, 1. 904
boiling point, 1. 894
hydrate, 1. 90S
in air, 8. IO
luminescence. 1. 901
occurrence, 1. 891
physical properties, 1. 893
preparation, 1. 878
anhydride, 1. 897
carbon tetrachloride, 1. 898
chloroform, 1. 898
essential oils, 1. 897
ethereal oils, 1. 897
ethyl acetate, 1. 897
fats, 1. 897
in alkaline solutions, 1. 897
salt solutions, 1. 897
. sulphuric acid, 1. 897
water, 1. 896
solutions action acetaldehyde, 1. 897
oxalic acid, 1. 897
paraldehyde, 1. 897
__ quinine salts, 1. 897
stabilizing, 1. 897
specific gravity, 1. 894
heat, 1. 895
magnetization, 1. 896
tests, 1-951
uses, 1. 911
water, 1. 898
Ozonic acid, 1. 906, 908
Ozonides, 1. 897, 899
Ozonite, 5. 119
Ozonizer, Babo's, 1. 885
Brodie's, 1. 886
Siemens', 1. 886
Ozonous acid, 1. 908
Ozonwasserstoff, 1. 321
Ozo-salt, 14. 672
Ozozobutylene, 1. 899
Ozozonides, 1. 899
Pacherite, 9. 779
Pachnolite, 2. 1 ; 3. 623 ; 5. 303, 309
Pacite, 9. 308 ; 12. 530
Packfong, 15. 2, 209
Packtong, 15. 209
INDEX
dichlorodiamminomethylphosphite,
15. 666
15. 666
d ichloroethylenebisdiethylsulphine,
15. 66
dibromoetbylenebisdiethylsulpbine, 666
15. 676 diehlorotoluidinoethylphosphite, 15.
INDEX 661
gas, 2. 73O
washing, 3. 496
Panabas, 9. 291
Panacea coelestis, 4. 797
mercurialis, 4. 797
Panacoea duplicata, 2. 656
Panchymachogum minerale, 4. 797
uercetani, 4. 797
Pandermite, 3. 623 ; 5. 3, 89
Panning, 3. 496
Panno di morti marble, 3. 815
Pantogon, 3. 911 ; 4. 3
Papin's autoclave, 1. 437
digester, 1. 437
Paposite, 14. 328, 332, 333
Papyrus, Ebors*, 1. 26
Ley den, 1. 26
Rhind, 1. 26
Parabayldoriite, 9. 196
Paracelsian, 6. 707
Paracelsus, 1. 5O
Paraceric oxide, 5. 673
Parachlorite, 6. 609
Parachromic acid, 11. 24O, 302
Parachrosbaryt isometricher, 12. 432
Pentaaulphitotetrammine, 8. 636
detection, 2. 381
determination, 2. 381
� preparation, 2. 371
electrolytic processes, 2. 3
properties, 2. 381
Perchloratosodalite, 6. 583
Perchloric acid, 2. 370
composition, 2. 382
constitution, 2. 382
hydrates, 2. 378
preparation, 2. 371
phvsical, 2. 376
anhydride, 2. 380
Perchlorides, 2. 233
Perchloromethylmercaptan, 6. 110
Perchlorosilicoethane, 6. 971, 981
Perchlorotrisilane, 6. 216
Perchromates, 11. 353
597
Percobaltites, 14. 6OO
Percolumbates, 9. 869
Percolumbic acid, 9. 856
colloidal, 9. 869
Percussion powder, 8. 1059
Peroylite, 2. 15 ; 7. 491
twinning, 6. 67O
Poridote, 6. 385 ; 15. 9
titaniferous, 6. 386
acids, 2. 386
basicity of, 2. 391
preparation, 2. 387
� properties, 2. 389
law, 4. 1 72
and occurrence of elements, 1.272
graphic representation of, 1. 26O
Mendeleeff's, 1. 255
misfits, 1. 263
occurrence of elements, 1. 273
long, i. 257
short, 1. 257
Perissads, 1. 208
Peristerite, 6. 663
Perlatum, 2. 851
Permalloy, 15. 258
Permanent gases, 1. 869
yellow, 11. 273
Permanganates, 12. 3Ol
Permanganic acid, 12. 281, 291, 293
597
Perofskite, 7. 52
hydrogel, 6. 278
Perstannates, 7. 412
Perstannic acid, 7. 404, 412
Persulphates, 10. 475
Persulphuric acid, 1. 276 ; 10. 419, 448, 449
Pertantalates, 9. 913
Pertantalic acid, 9. 913
INDEX
Perthiocarbonates, 6. 130
Perthiocarbonic acid, 6. 131
Perthite, 6. 662, 663
microcline, 6. 663
Pertitanates, 7. 50
Pertitanic acid, 7. 27, 63
phosphate, 7. 97
potassium sulphate, 7. 65
Pertungstates, 11. 833
Pertungstic acids, 11. 833
Peru silver, 15. 209
Peruranates, 12. 69
Peruranic acid, 12. 71
Peruvite, 9. 691
Per vanadate, 9. 794
Per vanadates, 9. 794
Pervanadic acid, 9. 794
Perzincic acids, 4. 531
Perzirconates, 7. 34
Pesillite, 6. 897 ; 12. 236, 266
Petalite, 2. 425 ; 6. 651
Petong, 15. 209
Petrifying springs, 3. 814
Petrol, 13. 613, 615
Petroleum and hydrogen, 1. 304
Pettenkofer's series, 1. 253
Petterdite, 7. 74O
Pettkoite, 14. 353
Petzite, 3. 30O, 494 ; 11. 2, 49 ; 14.
424
Pewter, 7. 63O
Peyrone's chloride, 16. 263
Pezzi fusi dighisa malleabile, 12. 709
Pfaffite, 9. 458, 555
Pfennigerz, 13. 886
Phacolite, 6. 729
Phaeactinite, 6. 821
Phastine, 6. 392
Pharmacocholzite, 9. 159
Pharmacolite, 3. 623 ; 9. 5, 169
magnesian, 9. 221
Pharmacolzite, 9. 159
Pharmacopyrite, 9. 73
Pharmacosiderite, 9. 4, 226 ; 12. 53O
Phase colloidal, 1. 771
disperse, 1. 769
rulo, 1. 444
modifications, 1. 449
X-radiogram, 1. 642
o-phenetidinium bromosmate, 15. 723
chloropalladite, 15. 67O
Phengites, 6. 605, 607
phlogopites, 6. 608
p-phenitidinium bromosmate, 15. 723
chloropalladite, 15. 670
Phenyl carbamazide, 8. 339
ferrodinitrosylsulphide, 8. 442
Phenylbenzylmothylammonium bromoplatinate,
16. 375
Phenyldiethylammonium bromoplatinate,
16. 375
Phenyldimethylaxninonium. bromoplatinate,
16. 375
Phenyldimethylarsine tetraiodobismuthite,
9. 676
m-phenylenediamine bromopalladite, 15.
677
chloropalladite, 15. 67O
o -pheny lenediamine] f erroheptanitrosyltrisulphide,
8. 442
Phenylenediammonium bromoplatinate, 16.
375
m-phenylenediammonium bromosmate, 15.
723
Phenylethylammonium bromoplatinate, 16.
375
Phenylhydrazine, 8. 308
ferroheptanitrosyltrisulphide, 8. 442
hydrochloride, 11. 831
Phenylmethylammonium bromoplatinate,
16. 375
chlorosmate, 15. 719
Phenylsilicanediol (di), 6- 309
Phenylsilicic acid, 6. 309
Phenylthiotetrazoline, 8. 339
Phonylultramarine, 6. 59O
Pherecydes, 1. 31
Philadephite, 6. 609
Philathes erenasus, 1. 48
eupeniug, 1. 48
Philippia, 5. 560
Philippium, 5. 497
Philipstadite, 6. 821
Phillipite, 12. 53O
Phillipsite, 6. 575, 736, 738 ; 14. 189
Philosopher's salt, 10. 331
stone, 4>. 148
Philosophical chemistrv, 1. 3
Phlogeston, 1. 64, 70, 72, 125
Phlogisticated air, 8. 45
sulphuric acid, 10. 187
Phlogopite, 6. 604, 605, 608
Phoenicia, 1. 28
Phoenicite, 7. 491 ; 11. 125, 303
Phcenicochroite, 11. 125, 303
Pholerite, 6. 477
Phonolite, 5. 531 ; 7. 897
Phosgene, <6. 962
spar, 7. 852
Phosgenite, 2. 15 ; 7. 491, 852
Phospham, 8. 269, 708
Phosphamic acid, 8. 705, 716
Phosphamide, 8. 708
Phosphamidic acid, 8. 716
Phosphaminic acid, 8. 708
Phosphate bone, 8. 904
boulder, 8. 735
pebble rock, 8. 736
rock, 8. 735
soft, 8. 736
soil, 8. 905
Phosphated baryte, 8. 841
lime, 8. 841
Phosphates, 8. 948
primary, 8. 948
secondary, 8. 948
tertiary, 8. 948
/3, 8. 748
colloidal, 8. 749
hydroxide, 8. 822
iodide, 8. 824
sulphate, 8. 828
Phosphophyllite, 12. 55O
Phosphor bronze, 7. 347
copper, 3. 97
tin, 8. 848
Phosphorcarburetted hydrogen, 8. 847
Phosphore de Homberg, 8. 697
noir, 8. 747
Phosphorescence spectrum, 12. 19
Phosphoreseopes, 3. 745
Phosphorgummite, 12. 52
Phosphoric acid, 8. 947 ; 13. 63 3, 615
constitution, 8. 959
decitahydrate, 8. 952
hemihydrate, 8. 952
� hydrates, 8. 951
� monohydrate, 8. 952
� nitrosyl, 8. 435
� physiological action, 8. 965
properties, physical, 8. 953
anhydride, 8. 94O
chloride, 8. 1009
ether, 8. 966
fluoride, 8. 996
oxide, 8. 940
oxychloride, 8. 1Ol 9
spar, 2. 3
� tapers, 8. 1059
titanium, enneachloride, 1. 85
Phosphorite, 2. 1 ; 3. 623, 896 ; 8. 734
Phosphorochalcite, 8. 733
Phosphorosic oxide, 8. 922, 923
Phosphorosophosphoric oxide, 8. 923
Phosphorous acid, 8. 899
amidosulphuryl tetrachloride, 8. 662
anhydride, 8. 891
chloride, 8. 999
fluoride, 8. 994
lead enneaiodide, 7. 762
oxide, 8. 891
titanium heptachloride, 7. 85
triamide, 8. 704
Phosphorphyllite, 14. 396
Phosphors alumina rhodium, 15. 565
Phosphorus, 8. 729 ; 12. 528
alio tropes, 8. 744
amide, 8. 271, 704
� antimonide, 9. 409
antimony decachloride, 9. 489
arsenide, 9. 69
atomic weight, 8. 799
Baldwin's, 3. 740 ; 8. 729
black, 8. 747, 748
borotribromodiiodide, 8. 1039, 104O
bottles, 8. 1059
boxes, 8. 1059
Boyle's, 8. 730
physical, 8. 1010
pentafluoride, 8. 996
pentaiodide, 8. 1038
pentamide, 8. 271
pentaselenide, 10. 791
pentasulphide, 8. 105K
pentathiodichloride, 8. 1074
pentoxide, 8. 940
preparation, 8. 941
properties, chemical, 8. 944
physical, 8. 942
pentoxydecachloride, 8. 1015
persulphide, 8. 1047
physiological action, 8. 794
preparation, 8. 74O
properties, chemical, 8. 782
physical, 8. 754
purification, 8. 743
pyropus, 8. 730
s- red, 8. 744
colloidal, 8. 749
rhombic, 8. 747
scarlet, 8. 746
selenides, 10. 93O
selenoxide, 10. 931
sesquisulphide, 8. 1049
silicate, 6. 835
silicide, 6. 188
sulphates, 8. 1071
sulphatodocachlorido, 8. 1Ol7
sulphides, 8. 1047
sulphoselenide, 10. 791, 92O
tetrachlorobromide", 8. 1043
�� tetracosisulphotriiodide, 10. 95
- tetracosithiotriiodide, 8. 104O, 1078
tetramminotetritadecasulphide, 8.
1056
tetratritaiodide, 8. 1038
tetritadecasulphide, 8. 1055
tetritaheptoxide, 8. 1053
tetritahexasulphide, 8. 1052
tetritaiodide, 8. 1038
tetritapentasulphide, 8. 1047
tetritaselenide, 10. 79O
tetritasulphide, 8. 1047
tetritatriselenide, 10. 79O
tetritatrisulphide, 8. 1048
physical, 8. 1000
trichloroctobromide, 8. 1044
trichlorodibromide, 8. 1043
trichlorodiiodide, 8. 1045
trichloromercuriate, 8. 1007
� trihydride, 8. 802
triiodide, 8. 1039
trioxide, 8. 891
� trioxydisulphide, 8. 1061
trisiodomercuriate, 8. 1041
tritahexasulphide, 8. 1054
tritahydroxide, 8. 869
-- tritapentanitride, 8. 123
� tritapentasulphide, 8. 1047
trithiodiiodide, 8. 1079
uses, 8. 795
valency, 8. 799
violet, 8. 747
white, 8. 747
zirconium oxyheniohloride, 7. 145
tridecachlorido, 7. 145
physical, 8. 1021
chlorodibromido, 8. 1046
dichloroamide, 8. 1024
dichlorobromide, 8. 1045
diimidosulphide, 8. 727
fluoride, 8. 997
hexamminotrichloride, 8. 1024
hydrasulphido, 8. 1071
imidoamide, 8. 708
molybdenum octochloride, 11. 625
monochioride, 8. IOIO, 1026
monofluoride, 8. 998
nitrile, 8. 709
sulphate, 8. 1071
� titanium heptachloride, 7. 85
triamide, 8. 707
trichloride, 8. 1019
Photicite, 6. 897
Photizite, 6. 897
Photography, 8. 411
Photolite, 6. 366
Photoluminescence, 8. 745
Photolysis, 2. 154
668 GENERAL,
INDEX
Pigeonite, 6. 916
Pigs, 12. 596, 597
Pilarite, 6. 344
Pilasonite, 11. 2
Pilbarite, 5. 515 ; 7. 491 ; 12. 5
Pilolite, 6. 423
a, 6. 825
/8, 6. 825
Pilsenite, 11. 6O
Pilula hydrargyri subchloridi composita, 4.
813
Pimelite, 6. 624, 933 ; 15. 6
Pinakiolite, 5. 113 ; 12. 15O
Pinakolite, 5. 4
Pinchbeck, 4. 671
Pingos d'agoa (drops of -water), 6. 562
Pingiute, 6. 907 ; 12. 530
Pinite, 6. 619, 812
Pinitoid, 6. 619
Pink chrome-tin, 7. 421
salt, 7. 447
Pinnoite, 2. 43O ; 4. 252 ; 5. 495
Pintadoite, 9. 769
Piombo muriato corneo, 7. 706
Piotine, 6. 432
Piperidinium bromopalladite, 15. 677
bromoplatinate, 16. 376
bromosmate, 15. 723
chloroiridate, 15. 771
chloropalladite, 15. 670
chloroperruthenite, 15. 533
chlororuthenate, 15. 534�5
chlorosmate, 15. 720
Piperno, 6. 762
Pirodmalite, 6. 896
Pirssonite, 3. 844
Pisanite, 12. 53O ; 14. 295
Pisekite, 12. 6
Pisilomelane, 3. 625
Pisolitic ore, 5. 249
Pissophane, 5. 338
Pistacite, 6. 721
Pistomesite, 4. 349 ; 12. 53O ; 14. 369
Pit carantite, 6. 416
charcoal, 5. 748
Pitchblende, 5. 530 ; 7. 896 ; 12. 1, 5, 49
Pitt diamond, 5. 711
Pitticite, 9. 5, 227 ; 12. 53O
Pittinite, 12. 5, 52
Pittizite, 9. 227 ; 18. 886
Placer deposits, 8. 496
gold, 8. 491
mining, 8. 496
Placodine, 9. 79
Placodite, 15. 6
Plagioclase, 6. 694
barium, 6. 707
Plagiocitrite, 4. 252 ; 5. 154 ; 12. 530 ; 1*.
328, 353
Plagionite, 7. 491 ; 9. 343, 547
\ INDEX 669
381 bisdimethvlbonzylselenoniumchloride,
amidochlorotetramminochloride, 16. 16. 315 ~
306 bisdimethylbenzylsulphoniumchloaminochlorotetramminonitrate,
16.413 ride, 16. 314
313 bisdimethylethylsulphoiiiumehloride,
bis-a/Sy-trimethylpyridinehydro-16. 314
chloride, 16. 312 bisdimethylhydrazinehydroehloride,
bis-aya'-trimethylpyridinehydro-16. 311
chloride, 16. 312
bisdipropylallylaminehydroehlorida,
bis-ay/T-trimethylpyridinehydrochloride,
16. 312 16. 311
bis-/J-methyl-y-ethylpyridinehydro-bisdipropylamiriehydroiodido, 16. 389
bisethylallylaminehydrochlorido, 16.
311
bis-y-isopropylpyridinehydrochloride,
16. 313
bis-y'-isopropylpyridinehydrochloride,
bisethyl-i-dibutylaminehydrochloride,
16. 310
bisethyl-i-propylaminehydrochloride,
16. 310
bisethyl-iso-butylaminehydrobromide,
16. 375
bisethyl-n-butylaminehydrochloride,
16. 310
bisethyl-n-propylaminehydrochloride,
16. 31O
bise thy lphosphinehy drochloride, 16.
315
bisethy lpropy 1 - i- buty laminehy dro cHloride,
16. 310
� bisethyl-sec-butylaminehydrochloride,
16. 3IO
bisothylthioglycolatodiainrninonitrate,
16. 412
biso t hy 1 tribenzy lphosphon iu.mch.loride,
16. 315
bi se thy ltr i -i - bu ty lammoniumchloi'ide,
16. 310
bisethy It r ipr opy lammoniumchloride,
16. 31O
bis-i-butylaminohydrochloride, 16. 3IO
bis-i-dibutylaminehydrochloride, 16.
31O
375
bis-iso-quirioliriehydroehloride, 16. 313
bislutidinehydrobromide, 16. 376
bis-m-toluidinehydrochloride, 16. 312
bismethyl-i-amylaminehydroehloride,
16. 311
bismothyl-i-butylaminehydrochloride,
16. 310
bisrnethyl-i-dipropylaminehydrochloride,
16. 310
bismethyl-i-propylaminehydrochlorido,
16. 310
bismethyl-i-propylbenzylsulphoniumchloride,
16. 314
bisme thy 1 -n -butylaminehy drochloride,
16. 31O
bismethyl-n-dipropylaminehydrochloride,
16. 31O
bismethyl-n-propyiaminehydrochlo
Platinic bismethyldi-i-propylsulphoniumchloride,
16. 314
bismethyldi-n-propylsulphoniumchloride,
16. 314
bismethyldiethylaminehydrochloride,
16. 309
bismethyldiethylamylammoniumchloride,
16. 311
bismethyldiethylpropylammoniumchloride,
16. 310
bismethyldiethylsulphoniumchloride,
16. 314
� bismethylethylpropylaminehydrochloride,
16. 3IO
bismethyltribenzylarsoniumchlorido,
16. 315
� bistetrabenzylarsoniumohloride, 16.
315
bistetrabutylarsoniumehloride, 16. 315
bistetraethylammoniumbromide, 16.
375
bistetraethylammoniumcbloride, 16.
309
bistetraethylammoniumiodide, 16. 389
bistetraethylarsoniumchloride, 16. 315
bistetraethylphosphoniumchlorido, 16.
315
bistetraetbylstiboniumcliloride, 16. 315
bistetra-i-propylarsoniumchloride, 16.
315
� bistetrallylammoniumehloride, 16. 311
� bistetramethylammonium bromide,16.
375
bistotramothylamrnoniumchloride, 16.
309
bistetramethylammonium iodide, 16.
389
bistetrarnethylphosphoniumchloride,
16. 315
� bistetramothylstiboniumchloride, 16.
315
bistetramylammoniumchloride, 16.311
bistetra-n-propylarsoniumehlorido, 16.
315
� bistotrapropylammoniumbromide, 16.
375
bistotrapropylainrnoiiiurniodido, 16.
389
bistetrapropylstiboniumchlorido, 16.
315
bisthioearbamidehydrochlorido, 16.
314
bistoluidinehydrobromido, 16. 376
bistriallyaminehydroehloride, 16. 311
bistriamylamiiiehydrochloride, 16. 311
bistribvitylsulphoniuxnehloride, 16. 314
bistriethylallylammoniumchloride, 16.
311
bistriethylallylphosphoniumehloride,
16. 315
bistriethylaminehydrobromide, 16. 375
bistriethylaminehydrochloride, 16. 309
bistriethylaminehydroiodide, 16. 389
bistriethy lamylphosphon iumchloride,
16. 315
bistriethylbutylammoniumbromide,
16. 375
bistriethy 1 - i-amylammoniumchloride,
16. 311
bistriethy 1 - i -buty lammoniumchloride,
16. 310
bistriethyl-n-butylammoniumehloride,
16. 310
bistriethylphosphinehydrochloride, 16.
315
INDEX 671
Platinic bistriethylpropylammoniumbroinide,
16. 375
bistriethylpropylammonivimchloride,
16. 31O
bistriethylpropylphosphoniumchloride,
16. 315
� bistrimethylallylammoniixmchloride,
16. 311
bistrimethylaminehydrobromide, 16.
375
bistrimethylaminehydrochloride, 16.
309
bistrimethylaminehydroiodide, 16. 389
bistrirnethylamylamxnoniiimchlorido,
16. 311
� bistrirnethylamylphosphoniumchloride,
16. 315
bistrimethylethylammoniumbromide,
16. 375
bistrimethylethylammonivtmchloride,
16. 309
bistrimethylethylphosphoniumchloride,
16. 315
bistrimethyl-i-butylammoniumchloride,
16. 310
315
bistripropylaminehydrobromide, 16.
375
bistripropylaminehydrochloride, 16.
309
bistripropylbutylammoniumchloride,
16. 31O
� � bistripropylsulphoniumohloride, 16.
314
bisxylidinehydrobromide, 16. 376
bisxylidinehydrochloride, 16. 312
bromide, 16. 373
bromoamidotetramminobromide, 16.
374
bromoearbonatotetramminocarbonate,
16. 408
bromocarbonatotetramminocarbonatedibromotetramminonitrate,
16. 414
bromochlorotetramminochloride, 16.
382
bromodinitratotriamminobromide, 16.
414
bromoiodides, 16. 392
bromonitratoquaterpyridinehydro
!Platinic brornonitratotetramminonitrate,
16. 414
brotnonitratotetramminosulphate, 16.
414
bromoBulpliatotriamminobromide, 16.
406
bromotriiododiethylselenine, 16. 392
carbonatonitrat otetranaininocarbo
413
chloronitritoethylenediazninodiamminochloride,
16. 309
chloronitritopyridinoethylenediamino
Platinic chloropentaxnminochloroplatinate,
16. 305
chloropentamminohydroxide, 16. 306
chloropentamminonitrate, 16. 412
chloropentamminosulphate, 16, 404
chloroaulphatotetramixiinosulphate,
16. 405
chlorotribrornobisethylsoleriine, 16.381
chlorotriiodide, 16. 392
chlorotriiodobisethylselenine, 16. 392
chromatobisethylsulphide, 11. 314
cobaltic hexammmocositungstate, 11.
803
copper cositixngstate, 11. 803
molybdate, 11. 576
376
dibromobisj>ropylenediarainochloride,
16. 381
dibromodichloroethylphosphate, 16.
381
dibromodiiodobisamidoacetate, 16.392
dibromodiiododethylsulphinediethyl
414
ri�-dibromodinitritodiammine, 16. 383
trans -dibromodinitritodiammine, 16.
383
dibromodinitritoothylsulphineethylselenine,
16. 383
dibromohexammine-/x-diarninosulI^
hate, 17. 406
dibrom ohexammi no-/i- diarni nochloride,
16. 381
dibrornoiiitratotriaxnrninoiodide, 16.
414
dibroxnopropylenediamitieamixiinochloride,
16. 381
dibromoquaterpyridinehydrorxitrate,
16. 414
16. 313
dichlorobis-1-phenylpyrazol, 16. 313
dichlorobis-1-phenyl tetrachloropyra
16. 313
dichlorobis-1 -phenyl- 3-methyl 1, 3-triazol,
16. 314
dichlorobis-1 -phenyl-3-methyl-3-triazolone,
16. 314
d ichlorobispropy lenediaminechloride,
16. 311
dichlorobispyrazol, 16. 313
dichlorobispyridinephenylpyrazol, 16.
313
dichlorodibromobisamidoacetate, 16.
383
dichlorodibromobisethylamidoacetate,
16. 383
dichlorodibromobisethvlphosphine,
16. 381
dichlorodibromobisethylphosphite, 16.
383
dichlorodibromobisothylselenine, 16.
381
dichlorodibrornobisethylsulphine, 16.
376, 381
dichlorodibroraobismethylsulphine,
16. 381
dichlorodibromobispyridine, 16. 381
dichlorodibromobutylsulphine, 16. 381
dichlorodibromoethylphosphate, 16.
383
�� dichlorodibromoethylphosphite, 16.
383
dichlorodibromoothylsulphinoethylselenine,
16. 323, 381
dichlorodibromomethylphosphate, 16.
383
dichlorodibromopropylsulphine, 16.
381
dichlorodicarbonylbispyridine, 16. 312
dichlorodiiodide, 16. 392
dichlorodiiodobisbutylsulphine, 16.392
dichlorodiiodobisethylphosphine, 16.
392
dichlorodiiodobisethylselenine, 16. 392
dichlorodiiodobismethylsulphine, 16.
392
dichlorodinitratodiainxnine, 16. 413
c*�-diohlorodinitritodiamm.ine, 16. 335
�rc�n�-dichlorodinitritodiammine, 16.
336
dichloroethylenediaminodiaxnmine, 16.
311
� � diohloroethylenediaroinodiamminochloride,
16. 309
dichloroethylenediaminopyridinoamminoohloride,
16. 309
diohloronitritoethylenediaminoaniminoohloride,
16. 309
diohloronitritopyridinoethylenediaminoohloride,
16. 309
VOIi. XVT.
Platinic dichloronitritopyridinoethylenediarninohydroxide,
16. 309
dichloro-p-tolypyrazol, 16. 313
dichloroquaterethylaminechloride, 16.
309
dichloroquaterethylaminechloroplatinite,
16. 309
dichloroquaterxne thylaminechlorido,
16. 309
dichloroquaterrnethylaminenitrate, 16.
413
dichloroquatermethylpseudolutidostyrilchloride,
16. 314
dichloroquaterpyridinechloride, 16.312
dichloroquaterpyridinechloroplatinate,
16. 312
dichloroquaterpyridinechloroplatinite,
16. 312
dichloroquaterpyri dinehy droni trate,
16. 413
dichloroquaterpyridinenitrate, 16. 413
dichlorotetramminobromide, 16. 381
dichlorotetramminochloridc, 16. 306
monohydrate, 16. 306
dichlorotetramminochloroplatinate,
16. 307
dichlorotetrarnrninochloroplatiriite, 16.
306
dichlorotetramminochromato, 11. 313
dichlorotetramminodichromate, 11.
345
dichlorotetramminohydroxydihydrophosphate,
16. 417
dichlorotetrarnminonitrate, 16. 412
dichlorotetramminosulphato, 16. 405
dihydrate, 16. 405
dihydrotrisulphide, 16. 398
dihydroxydiamidohexamminodichronaate,
11. 345
d ihy droxydichlor obisamidohexamiminochloride,
16. 308
dihydroxydinitratobisethylselenine,
16. 412
dihydroxydinitratobispropylsulphino,
16. 412
�row*-dihydroxydinitratodiamm ino,
16. 411
dihydroxyheptamininotetracarbonate,
16. 407
dihydroxy hoxammino- /x-diarn inesulphate,
16. 404
dihydroxy laminodiammi nosulpha te,
16. 405
dihydroxynitratotriamminonitrato,
16. 411
ci�-dihydroxysiilphatodiainmine, 16.
404
/ran�-dihydroxysulphatodiammine,16.
404
dihydroxysulphatohoxanamitiochromatodiohromate,
11. 467
dihydroxysulphide, 16. 399
dihydroxytetrarominosulphate, 16.404
monohydrate, 16. 404
tetrahydrate, 16. 404
2x
674 INDEX
Pla.tin.ic diiodobispyridinediamminoiodide,
16. 389
di iododinitr i toe thy I sulphinoethy lselenine,
16. 392
diiodohexammine-/x-diiinidosulphatotetramminoplatinous
sulphate, 16.
406
diiodohexammino-/x-diamineiodide,
16. 388
diiodohexammmo-/*-diaminosulphate,
16- 406
diiodohexamnriino-^-diirnidoiodide, 16.
389
diiodotetramminoiodide, 16. 388, 392
diiodotetramminoiodomercurate, 16.
388
diiodotetrarnminonitrate, 16. 414
diiodotetramrninosulphate, 16. 406
dimethylarainedimethylpropylarniiie
345
dinitratototramminonitrate, 16. 411
dinitritochloroethylenediamino
345
dinitritotetraxnminonitrate, 16. 415
dioxytetraiodotetramrnine, 16. 391
disulphoallylsulphine, 16. 398
disulphoallylsulphineallylchloroplati
16. 398
disulphovinylsulphinevinylchloroplati
16. 406
hydroxysulphatotetranaxninochloride,
16. 405
dihydrate, 16. 405
hydroxysulphatotetramminochloroplatinate,
16. 406
hydroxysulphatotetramminoohromate,
11. 314
hydroxysulphatotetranuninodichromate,
11. 346, 467
Platinic hydroxysxilphatotetramminonitrate,
16. 414
hy droxysulphatotetramminosulphate,
16. 404
iodide, 16. 387
iodonitritotetraraininonitrate, 16. 415
iodotrimethylaminodiammine, 16. 389
iron, 16. 6
mercuroufl cositungstate, 11. 803
rnethylethylaminedipropylaminehy
� methylethylpropyl-i-amylammoniumohloride,
16. 311
meth yIethylpropylphenylammoniumiodide,
16. 389
methyl-i-propyl -i-butylsulphoniumchloride,
16. 314
mothyl-n-propyl-i-butylsulphoniumchloride,
16. 314
-� niothyltri-i-butylamrnoniuinchloride,
16. 31O
motoxyhydroehloride, 16. 332
nitrate, 16. 410, 412
nitratoethylthioglycocolatoammino,
16. 41O
ni tritochloroothylonediaxtiinodiamrnine,
16. 311
nitri todichloroethylenediaminomethy1aminochloride,
16. 311
nitrosyltetramminohydronitrato, 16.
411
orthoarsenite, 9. 134
oxide, 16. 242
311
pyrophosphate, 16. 417
pyroarsenite, 9. 134
quaterethylaminechloroplatinite, 16.
286
quaterethylaminobromide, 16. 375
quatertetraethylstiboniumchloride,
16. 315
quatertriethylphosphinechloroaurate,
16. 327
silver cositungstate, 11. 803
hydroxytriamidodiamminochloride,
15. 308
hydroxytriamidodiamminohydroxide,
16. 245
INDEX
sulpharsenate, 9. 324
314
sulphatotetrapyridinodichromate, 11.
345
sulphide, 16. 396
sulphite, 11. 320
tetrabromobisbenzonitrilo, 16. 376
313
tetrachloro -/SjS'/S''-1riaminopropanemonohydroehloride,
16. 311
tetrachloro-/9/8'/8"-triaminopropanemonohydrochloroplatinate,
16. 311
tetrachlorobis-a.-mothylisoxazol, 16.
314
tetrachlorobis-a-naphthyl-1, 3-triazol,
16. 314
tetrachlorobis-a-naphthyl-2, 3-triazol,
16. 314
tetrachlorobis-)3-hydroxyethy!pyri
16. 314
totrachlorobis-j8-naphthyl-2, 3-triazol1,
16. 314
tetrachlorobis-�-pyridine- a-lacotate,
16. 314
tetrachlorobis-2, 5-dimethyl-3-ethylpyrazine,
16. 313
tetrachlorobis-2, 5-dimethylpyrazine,
16. 313
tetrachlorobis-3, 5-dimethylpyrazol,
16. 313
tetrachlorobis-4, 5-dimethylpyrimidine,
16. 313
tetrachlorobis-3, 5-dimethylfcetrachloropyrazol,
16. 313
tetrachlorobis-3, 5-methylchloropyrazol,
16. 313
GENERAL. INDEX
313
tetrachlorobis-1-phenyl-2, 3-triazol, 16.
313
tetrachloro-o-phenylenebigvianidine,
16. 313
dihydrate, 16. 313
tetrachlorobis-o-tolyl-2, 5-dimethyl-2,
3-triazol, 16. 314
tetrachlorobis-o-tolyl-1, 3-triazol, 16.
313
tetrachlorobis-o-tolyl-2, 3-triazol, 16.
313
tetrachlorobis-p-dimethyloxyphosphinebenzoate,
16. 315
tetrachlorobis-p-tolyl- 3-imidotriazoline,
16. 314
tetraclilorobis-p-tolyl-1, 3-triazol, 16.
313
tetrachlorobis-p-tolyl-2, 3-triazol, 16.
313-4
tetrachlorobis-p-tolylpyrazol, 16. 313
tetrachlorobis-/4-imidoazolylmercap
� tetrachlorobis-v-methylimidozaolyl-ftmercaptan,
16. 314
tetrachlorobis-v-phenylimidoazolyl-/xmercaptan,
16. 314
tetrachlorobis-v-m-xylylimidoazolyl-/xmercaptan,
16. 315
tetrachlorobis-v-p-tolylimidoazolyl-/xmercaptan,
16. 314
tetrachlorobisamidoacetate, 16. 314
tetrachlorobisbenzonitrile, 16. 313
tetrachlorobiscollidine, 16. 312
tetrachlorobisdibenzylselenine, 16. 315
tetrachlorobisdiethylenethiocarbamide,
16. 314
tetrachlorobisdiethylselenine, 16. 315
tetrachlorobisdiethylsulphine, 16. 314
tetrachlorobisdi-i-butysulphine, 16.
314
tetrachlorobisdimethylselenine, 16.
315
tetrachlorobisdimethylsulphine, 16.
314
tetrachlorobisdimethyltriazoline, 16.
314
tetrachlorobisdi-n-butylsulphine, 16.
314
tetrachlorobisdipropylsulphine, 16.314
tetrachlorobisethylamidoacetate, 16.
314
tetrachlorobisethylenesulphine, 16.314
tetrachlorobisglyoxal, 6. 313
tetrachlorobisimidoazolylmercaptan,
Platinic tetrachlorobismethylethylsulphine,
16. 314
tetraohlorobisphosphoripentachloride,
16. 304
tetrachlorobispicoline, 16. 312
tetrachlorobispropionitrile, 16. 313
tetrachlorobispyrazine, 16. 313
tetrachlorobispyrazol, 16. 313
c^-tetrachlorobispyridine, 16. 312
*ran*-tetrachlorobispyridine, 16. 312
tetrachlorobisquinoline, 16. 313
tetrachlorobistetrahydroquinoline, 16.
313
tetrachlorobistetrazoline, 16. 314
tetrachlorobistriohloropyridine, 16.313
tetrachlorobistriethylphosphite, 16.
315
tetrachlorobistrirnethylenethiocarbamide,
16. 314
tetrachlorobistrithioformaldehyde, 16.
tetrachlorocinnarnylpyridazine, 16.313
tetrachlorodiallylhexasulphine, 16. 315
tetrachlorodianuinodiethylarninohy
304
tetrachloropicoline, 16. 312
tetrachloropilocarpidine, 16. 313
�ran�-tetrachloropiperidinepyridine,
16. 313
tetrachloropropylenediamine, 16. 311
tetrachloropyridineammiine, 16. 312
tetrachlorotetrammine, 16. 308
tetrachlorotriaminopropanes, 16. 3IO
tetrachloro trie thy lphosphate, 16. 315
tetrachlorotriethylphosphite, 16. 315
tetraethylaminechloride, 16. 309
tetrahydroxydiammine, 16. 245
tetrahydroxylaminesulphate, 16. 404
tetraiodobisamidoacetate, 16. 389
tetraiodobisethylselenine, 16. 389
tetraiodobisethylsulphine, 16. 389
tetraiodobis-i-butylsulphineiodide, 16.
389
tetraiodobis-i-propylsulphine, 16. 389
tetraiodobismethylsulphine, 16. 389
tetraiodobispyridine, 16. 389
ci*-tetraiododiammine, 16. 389
<ran�-tetraiododiammine, 16. 388
tetraiodoethylselenine, 16. 389
tetramethylammonivuntrimethylethyl
INDEX 677
- barium ci�-sulphitodiamminosulphite,
10. 321
- irantf-sulphitodiamminosulphite,
10. 321
bisaoetonitritotetramminochloride, 16.
274
274, 276
bisaminoace taldiarnminochloroplati
16. 277
bisanilinebismetbylpbosphites, 16. 354
bisanili nebismethy lphosphitochlor ide,
16. 277
bisaniliiiediairirnin.es, 16. 353
rt�-bisanilinediamminochloride, 16.273
~ � Iran^-bisanilinediarnrninochloride, 16.
273
� c^#-bisanilinediamn~iinochloroplatinite,
16. 273
� �7*an.#-bisanilinediamminochloroplatinite,
16. 273
ci�-bisanilinediamminonitrate, 16. 409
� Jrems-bisanilinediarnminonitrate, 16.
409
bisanilinediamminosvdphate, 16. 401
bisanilinehydrochloride, 16. 273
352
bisdiethylaminechloride, 16. 272
bisdiethylamines, 16. 355
bisdiethyldiselonotr imethyleneglycols,
bisdiethyldithioethyleneglycolatochloride,
16. 276
bisdiethyldithioethyleneglycolatochloroplatinate,
16. 276
bi sdiethy ldithioethy lenegly colatochloroplatinite,
16. 276
bisdiethylditbioethyleneglycols, 16.
352
bisdiethyldithiohydroxyethyleneglycolatochloroplatinite,
16. 276
bisdiethy ldithiopropy lenegly colatochloroplatinite,
16. 276
bisdiethy ldithiotrimethyleneglycols,
16. 352
bisdiethyldithioxydiethylglycols, 16.
352
bisdiethylselenines, 16. 358
INDEX
cis -bisdiraethylaminechloroplatinite,
16. 271
trans -bisdimethylaminediamminochlo
^raywr-bisdimethylaminediamminochlo
bisdimethylaminediamminoiodide, 16.
385
bisdimethylamines, 16. 356
bisd ime thy ldithi oethy lenegly colato
352
bis-2, 5-dimethylpyrazine, 16. 366
bis-3, 5-dimethylpyrazole, 16. 366, 367
bis-4, 5-dimethylpyrimidines, 16. 365
bisdimethylsulphinediamminochlorido,
16. 275
bis-3, 5-dimethyltetrachloropyrazole,
16. 366
bisdimethyltriazolines, 16. 366
bisd ipheny lgl yoximine, 16. 358
bisdiphenylthioglycolate, 16. 358
bisdipropyldithioethyleneglycolato
� bisdipropyldithiotrimethylenoglycols,
352
bisdipropylsulphines, 16. 357
bisethylalcohols, 16. 367
cis-bisotlrylaminebispropylamine
16. 271
� hemihydrate, 16. 271
2raro6-bisethylaminediamminochlori de,
16. 271
cis -bisethylaminediamminochloroplatinate,
16. 271
trans - bisethy laminediamminochl oro platinite,
16. 271
bisethylaminediamminonitrate, 16.
409
trans- bisethy Iaminediamminosulphate,
16. 4Ol
367
GENERAL INDEX
Platmousbisethylenediaminebromocuprate,
16. 372
bisethylenediaminechloride, 16. 272
bisethylenediaminechlorocobaltate,
16. 272
bisethylenediamineehlorocuprate, 16.
272
bisethylenediaminechlorocupriplatiziate,
16. 272
bisethylenediaminechloroplatinite, 16.
272
bisethylenediamines, 16. 351
239
bisethylenesulphineiodide, 16. 386
bisethylenesulphines, 16. 352, 367
bisethylenesulphinesulphate, 16. 4Ol
bisethylenethiocarbamide, 16. 367
bisethylenethioglycollate, 16. 358
bisethylmethylglyoollate, 16. 357
bisothylphosphines, 16. 367
bisethylphosphinodianiminos, 16. 353
bisethylphosphites, 16. 367
bise thy lphosphitodiainrninochloride,
16. 277
bisethylseloxiines, 16. 367
bisetbylsulpbirie, 16. 367
16. 366
bismethyl-iso-butylgloximine, 16. 358
bis-a-methylisoxazols, 16. 365
bismethyloxyphosphinebenzoates, 16.
367
bismethylphosphates, 16. 367
bismethylpropylglyoximine, 16. 358
bis-3, 5-methylpyrazol, 16. 366
bis-3, 5-methylpyrazols, 16. 367
bismethylselenines, 16. 367
bismethylsulphine, 16. 367
bismethylsulphinedihydroxide, 16. 239
bismethylsulpbin.odiammin.es, 16. 353
bismethylthioglyeollate, 16. 358
bis-y8-methyltrimethylenediamines, 16.
353
bis-^8-methyltrimethylenediaminobromide,
16. 372
bis-)3-methyltrimethylenediam.ino
bis-/3-methyltrimethylenediamino
16. 368
bis-**-phenylirnidazolyl-/LA-MiGrcaptan,
16. 366
bis- 1-phenyl-3-imidotriazoline, 16. 366
bisphenylmethylethyli>yrazoles, 16.
368
bis-1 -phenylmethylethyltrichloro
bisphosphaminodiamminechlorido, 16.
278
bisphosphorichlorides, 16. 367
bisphosphorus acid, 16. 358
bisphosphorustribomide, 16. 358
bisphosphorus trichloride, 16. 358
bispicolines, 16. 365
bispiperidines, 16. 356
bispiperidinochloride, 16. 274
bispotassiumthioglycollate, 16. 357
bispropionitrilediaminos, 16. 353
� bispropionitrilos, 16. 356, 365
� bispropylaminedianunines, 16. 353
ciVr-bispropylaminediamminochloro
tfrarw-bispropylaminedianiminochloro
bispropylenediaminehydroxide, 16.239
274
/raw�-bispyridinediamminochloride,
16. 273
r?"# -bispyridinediamminochloroplatinite,
16. 274
Zraws-bispyridinediamrninochloroplatinite,
16. 274
bispyridinedihydroxylaminechloro
16. 277
bisthiocarbamidebispyridinehydroxide,
16. 239
bisthiocarbamidediamrninochloride,
16. 276
bistbiocarbamides, 16. 356
bistbiocarbamidiammines, 16. 353
bisthiocarbarnidodiammines, 16. 353
bisthiodiglycollate, 16. 358
bisthioglycollate, 16. 358
bisthioglycollic acid, 16. 357
bis toluidinebisethy !phosphites, 16. 354
bistoliridinebisethylphosphi tochloride,
16. 278
bistoliridinebismethylphosphites, 16.
354
bistoluidinebisxnetbylphospbitochlo
16. 366
bis-m-tolylenediaminochloride, 16. 274
bis-r-tolylimidazolyl-/i.-mercaptan, 16.
366
bis-l-tolyl-3-imidotriazioline, 16. 366
bis-p-tolylpyrazole, 16. 366
bistolylpyrazols, 16. 367
bia-1-tolyltriazole, 16. 366
bis-�*-tolynediamino, 16. 4Ol
Platinous bis-a^y-triaminopropaiiobromide,
16. 372, 385
bis-ojSy-triairunopropanocbloride, 16.
272
bistriethylphosphinediamminochloride,
16. 277
bistrietbylphosphinediamminochloroplatinite,
16. 277
biatriethylphoBpliiziea, 16. 358
bis-��-xylylimidazolyl-^i.-mercaptaii, 16.
366
bromide, 16. 37O
bromoamidotetrammines, 16. 362
bromobisbariumthioglycolate, 16. 372
bromobispotassiumthioglycolate, 16.
372
bromobisthiodiglycolato, 16. 372
� brortiocarbonatotetraramines, 16. 364
bromodiaminodie th vlaixxi nobromide,
16. 372
bromoiodobisethylselenine, 16. 386
bromopentammines, 16. 362
bromosulphatotetrammines, 16. 364
bromotriammirxobromoplatinite, 16.
371
carbonatobismetbylsulphine, 16. 407
carbonatobispyridine, 16. 407
carbonatotetrammineH, 16. 363
carbonyl oxide, 16. 236
carbonylethylenes, 16. 360
carbonylphenylhydrazin.es, 16. 359
carbonylpyridines, 16. 36O
carbonyls, 16. 36O
carbonyltrie&iylphosphite, 16. 360
chloride, 16. 251, 271
chloroamidonitritopyridi noethylene
16. 273
chlorobisanilinee thy !phosphite, 16. 355
chlorobisethylthioglycollate, 16. 358
a-chlorobispyridinoamminoohloride,
16. 273
a-chlorobispyridinoamminochloroplatinate,
16. 273
chlorobistoluidineethylphosphite, 16.
355
chlorobromobisethylselenine, 16. 286
chlorobromoethylsulphineethylsele
INDEX 681
414
cblorophosphaininediainminochloride,
16. 278
chlorotriamminochloroplatinite, 16.
26O
chlorotriamrriinotrichloroainminoplat i nite,
16. 261
chlorotrisdiethylenedisulphinechloride,
16. 275
ehlorotrisdiethylseleninechloroplatinite,
16. 277
chlorotrisdiethylsulphineehlorido, 16.
275
chlorotrisxnethylsulphinechloroplati
cobaltous <raw�-sulphitodiaminiiiosulphite,
10. 321
cnpric /raw�-suli�hitodiaTnminosulphite,
10. 321
diallylhexasulphines, 16. 368
diaxnxnines, 16. 355, 365
diamminobismethylphosphite, 16. 353
diamminodiethylthioglycollate, 16. 353
diaxxxminodiiodide, 16. 387
GENERAL, INDEX
16. 372
dibromobisamidoacetate, 16. 372
dibromobisbenzonitrile, 16. 372
dibromobisbutylsulphine, 16. 372
dibromobisdimethylamine, 16. 372
dibromobisdimethylaminediammine,
16. 372
dibromobisethylamidoacetate, 16. 372
cis-dibromobisethylamine, 16. 372
_
dibromobisphosphorotribromide, 16.
371, 372
dibroinobispotassiurnthioglycolate, 16.
372
dibromobispropylenediamines, 16. 363
dibromobispropylsulphine, 16. 372
c*�-dibromobispyridine, 16. 372
<ran�-dibromobispyridine, 16. 372
dibromobisthiodiglycolate, 16. 372
dibromobistriethylphosphino, 16. 372
dibromocarbonyl, 16. 372
dibromocarbonylpyridine, 16. 372
dibromodiammine, 16. 371
372
dibromoethylamineammine, 16. 372
dibromoethylenesulphine, 16. 372
:� dibromoethylphosphite, 16. 372
dibromoethylpropylsulphine, 16. 372
dibromoethylselenine, 16. 372
dibromoethylseleninebrornoplatinite,
16. 372
dibromoethylseleninepyridine, 16. 372
dibromoe thylsvdphineethylselenine,
16. 372
dibromohexamraine-)Li-diamines, 16.
369
dibromohoxammine-/*-diimines, 16.
369
dibromo-oxycacodyl, 16. 372
dibromophosphorobromide, 16. 372
dibromophosphorotribromide, 16. 371
dibromopropylenediaminedianamines,
16. 364
dibromoqnaterpyridines, 16. 363
dibromotetrammines, 16. 362
dibromotriethylphosphite, 16. 372
dibutylthioethyleneglycols, 16. 357
diearbonyls, 16. 366
dichloro-�, 16. 274
Platinous dichloroaoetylenediethylsulphine,
16. 276
dichloroamidoacetates, 16. 361
dichloroamidopropionates, 16. 361
dichloroaminoacetate, 16. 274
dichloro-jS-aminodiethylsulphide, 16.
276
dichloroammine, 16. 266, 275
diohloroanilineme thy lphosphite, 16.
278
dichloroanilinethylene, 16. 273
dichloroanilinethylphosphite, 16. 278
dichlorobisaoetonitrite, 16. 274
��- dichlorobis-2-amino-l-acetylpyridine,
16. 274
dichlorobis-3-aminopyridine, 16. 274
dichlorobisaniline, 16. 273
dichlorobisbenzonitrite, 16. 274
dichlorobisbenzyltelluride, 16. 277
diehlorobisbenzyltellurine, 16. 277
dichlorobisbutylcarbylamine, 16. 276
dichlorobisohlorocarbonyl, 16. 273
2ran*-dichlorobisdibenzylsulphine, 16.
275-6
c�*-dichlorobisdiethylselenine, 16. 277
�raro�-dichlorobisdiethylselenine, 16.
277
dichlorobisdiethylseleninechloromercurate,
16. 277
dichlorobisdiethylseleninochloroplatinite,
16. 277
dichlorobisdiethylsulphine�cis, 16. 275
trans-, 16. 275
diohlorobisdi-iso-amylsnlphine c is,
16. 275
dichlorobisdi- iso -propylsulphine
trans, 16. 275
dichlorobisdirnethylamine, 16. 271
dichlorobisdimethylethylpyrazole, 16.
274
dichlorobisdimethylsulphine�cis, 16.
274
trans, 16. 274
dichlorobisdi-n-butylsulphine�cis, 16.
275
trans, 16. 275
diehlorobisdipropylsulphine cis, 16.
275
trans, 16. 275
dichlorobisdipropylsulphinechloromercurate,
16. 275
diehlorobisdipropylsulphinechlorox->latinate,
16. 275
dichlorobisdipropylsulphinechlorostannite,
16. 275
dichlorobisethylamine cis, 16. 271
16. 276
dichlorobisethylphosphite, 16. 278
dichlorobis-iso-undecylthiocarbamide,
16. 277
dichlorobismethylamine, 16. 271
dichlorobismethylcarbylamine, 16. 276
dichlorobismethylphenylpyrazole, 16.
274
dichlorobismethylphosphite, 16. 278
dichlorobismethylthioethylglycolate,
Platixious dichlorobispheriylcarbylarnine, 16.
274, 276
dichlorobisphenylcyanide, 16. 276
dichlorobispheny ldiethy lphosphin e�
253
dichlorobisphosphorotrihydroxide, 16.
253
dichlorobispiperidine, 16. 274
dichlorobispropylamine�cis, 16. 272
diehlorobispropylenediamines, 16. 363
dichlorobispyridine, 16. 274
� dichlorobisthiobariurnglycolate, 16.
277
dichlorobisthiocarbamide, 16. 276
dichlorobisthioethylglycolato, 16. 276,
277
diclilorobisthioglyeolate, 16. 277
dichlorobisthioxnethylglycolato, 16.277
dichlorobisthiopotassiurnglycolate, 16.
277
dichlorobistolidine, 16. 273
dichlorobistoluidino, 16. 273
diehlorobistributylarsine, 16. 278
277
�r�n.s-dichlorobistriinothylphosphine,
16. 277
diehlorobistriphonylstibino, 16. 278
dichlorobistripropy lphosphine^�cis,
16. 277
278
dichlorocarbonylphenylhydrazine, 16.
273
dichlorocarbonylpyridine, 16. 274
dichlorodiaoetonitrile, 16. 276
dichlorodiamidoacetal, 16. 277
dichlorodianiidoacetate, 16. 277
dichlorodiamidoethylacetate, 16. 277
dichlorodiamidomethylaoetate, 16. 277
dichlorodiaminodiethyleneaxnino
INDEX 683
Platinoua dichlorodiamniinedichlorotetrarnminoplatinite,
16. 257
dichlorodiamzxiinobisethy lthiolacetate,
16. 276
dichlorodiaxxitninochlorocarbonate, 16.
403
dichlorodiamminotrithiocarbona todiammine,
16. 277
dichlorodicarbonyl, 16. 273
dichlorodiethylaminoethy 1 sulphino,
16. 275
dichlorodiethylenedisulphino, 16. 275
dichlorodiethylsulphixie, 16. 275
dichlorodiethylsulphinedibutylsulphino�
trans, 16. 275
dichlorodiethylsulphinediethylselejxxsxQ)
cis, 16. 277
trans, 16. 277
dichlorodiethylsulphinediethylseleninechloroplatinito,
16. 277
dichlorodiethylsulphinedipropylsulphine�
trans, 16. 275
dichlorodiethy]8\xlphinopyridino-c��,
16. 275
trans, 16. 275
dichlorodihydroxylairune cis, 16. 269
trans, 16. 269
dichlorodi-iso-butylsixlphine�cis, 16.
275
trans, 16. 275
� dichlorodimethylanilirie, 16. 273
diohlorodimethylsulphinediethylsulphine,
16. 275
dichlorodimethyltrimethyleneethylsulphine,
16. 276
dichlorodi-n-propylsulphiriedi-iso-propylsulphine,
16. 275
dichlorodisilverphosphite, 16. 278
dichlorodithioacetamide, 16. 277
dichlorodithioethylenebutylglycolate,
16. 276
dichlorodithioetiiyleneethylglycolate,
16. 276
dichlorodithioethylenemethylglycolate,
16. 276
dichlorodithioethylenepropylglycolato,
16. 276
dichlorodithiooxytrimethylenoethylglycolate,
16. 276
diohlorodith iopropyleneethylglycolate,
16. 276
dichlorodithiopropylenepropylglycolate,
16. 276
dichloroerythritylethylsulphino, 16.
276
dichloroothylamine, 16. 271
dichloroethylammeammiiie, 16. 271
dichloroethylene, 16. 272
dichloroethyleneairimirie, 16. 272
dichloroothylenediamine cis, 16. 272
trans, 16. 272
dichloroethylenediaminodiammines,
16. 363
dichloroethylenedianiinodiarnniinochloride,
16. 362
dichloroethylenediethylamine, 16. 271
dichloroethylenethioglycolate, 16. 277
dichloroethylenothiopotassiumglycolate,
16. 277
dichloroethylphosphite, 16. 278
684 GENERAL INDEX
Platinous diohloroethylphosphifcechloroplatinite,
10. 278
dichlorohydroehloro- a/9y-triaminopropane,
16. 272
dichlorohydroxylaminepyridme, 16.
274
dichlorohydroxylaminoaixxmine, 16.
270
dichloronitritoethylene<Harmnoarnxninochloride,
16. 364
dichloronitritoethylenediaminoamminohydroxide,
16. 365
dichloronitritopyridinodiamixiinochloride,
16. 364
dichloronitritopyridinoethylenediaminochloride,
16. 364
dichloronitritopyridinomethylaminoamminochlonde,
16. 364
dicJiloronitritotriainininochloride, 16.
364
dichlorophosphorotrichloride, 16. 253
dichloriphosphorotrichloroplatinite,
16. 253
dichlorophosphorotrihydroxide, 16.
253
dichlorophosphorustriehloridethylphosphide,
16. 278
dichlorophosphorustr ioxidethylphos
278
diehlorotohiidinethylphosphite, 16.
275
monohydrate, 10. 275
diethylsulphinetriaxnminochloroplatinite,
10. 275
difluorobispyridine, 10. 25O
� dihydrazinedianimines, 10. 352
dihydrazinediamminochloride�cis, 10.
27O
trans, 10. 270
dihydrazinediamminochloroplatinite�
cis, 10. 270
dihydrazinediamminodihydrochloride
�cis, 10. 27O
10. 276
dihydrazinoctoethylcarbylaminochloride,
16. 276
dihydrazinoctoethylcarbylaminoiodide,
16. 385
eihydrazinoctoethylcarbylaminonitrate,
16. 41O
dihydrazinoctomethylcarbylamino
16. 27O
dihydrazinodiamrainoiodide, 16. 385
dihydrazinodihydrochlorotetracarbyl
� dihydrazinodihydrochlorotetraethylcarbylamminochloride,
16. 276
dihydrazihohy drochlorotetracarby 1 amines,
16. 369
dihydrazinohydrochlorotetraethylcarbylamines,
16. 360
� dihydrazinooctocarbylarmnes, 16. 369
dihydrazinooctoethylcarbylamines,
16. 369
dihydrohexasulphoplatinate, 16. 395
dihydrotetrachloride, 16. 254
dihydroxoctoethylcarbylamminochloroplatinate,
16. 276
dihydroxybispyridine, 16. 239
decahydrate, 10. 239
dihydrate, 10. 239
dihydroxydiaxxxmine, 10. 238
dihydroxydihydroxylamine, 10. 239
dihydroxyhexammine-^-diamineB, 10.
309
dihydroxylaminebispyridine
INDEX 685
Platinoxis dimethylaminetriammiTiochloroplatinite,
16. 271
)8j8-dimethyldipyridyls, 16. 365
dimethyldithioethyleneglycols, 16. 357
dimethylethylenedithiolchloride, 16.
275
2, 5-dimethyl-3-ethylpyrazine, 16. 366
dimethylphenylamine, 16. 359
dimethylaulphinetriamminochloride,
16. 275
dinitratobisethylselenine, 16. 41O
dixxitratobisethylsulphine�cis, 16. 4IO
trans. 16. 41O
dinitratobisethylthiola,cetatodia,mmine�
trans, 16. 4IO
dinitratobismethylsvilphin.e, 16. 409�10
dinitratobistriethylphosphine, 16. 4IO
� dinitratobromotriammines, 16. 365
dinitratobutylsulphine�cis, 16. 4IO
trans, 16. 410
dinitratochlorotriammines, 16. 365
dinitratodiammine cis, 16. 409
trans, 16. 409
dinitratoethylenedisulphine, 16. 4IO
diixitratoethylphosphite, 16. 4IO
dinitratoethylsixlphinethylselonine, 16.
41O
dinitratohexammine-/x-diimines, 16.
369
dinitratohexaixunino-/x-diarnixies, 16.
369
dinitratopropylsulphine cis, 16. 410
trans, 16. 4IO
dinitratopyridineethylselenine, 16. 410
dinitratotetramminos, 16. 363
dinitratoxycacodyl, 16. 4IO
� dinitrito complexes, 16. 359
dinitritobispyridine-ci�, 16. 409
trans, 16. 409
dinitritochloroethy lenediami noammines,
16. 364
dinitidtochloroe thy loned iamin oe th y 1 amines,
16. 364
dinitritochloroethylenediamiriopyridines,
16. 364
dinitritodihydrazine, 16. 27O
dinitritoethylenediaminotetramminochloride
ehloroplatinite, 8. 517
dinitritohydroxylamine (cts), 8. 516
(trans), 8. 516
dinitritotetrammines, 16. 363
dinitroethylenediamine, 8. 517
dinitrohydroxylaminopyridino (trans),
8. 517
diphenyldimethyldiaminobisethylenediarainochloride,
16. 272
diphosgenes, 16. 356
diphosphoctochloride, 8. 1007
dipropylpropylenesnlphines, 16. 357
dipropylthioethyleneglycols, 16. 357
disalicylaldoxixninochloride, 16. 274,
277
dithiocyanates, 16. 359
dithiocyanatobisethylenediamines, 16.
363
dithiocyanatobispyridine, 16. 359
dithiooyanatodictmmine, 16. 359
difchiocyanatoethylenediamine, 16. 359
ditbioglycolesters, 16. 352
dithionate, 10. 598
686 GENERAL. INDEX
275
ethylamineammines, 16. 359
ethylaminehydroxylamines, 16. 359
ethylamines, 16. 36O
ethylbutylsulphines, 16. 360
ethyl oarbylaminohydrazinoiodide, 16.
386
ethyleneammines, 16. 359
ethyleneanilines, 16. 359
ethylenediaminebisethylene, 16. 359
ethylenediaininediarornines, 16. 353
ethylenediarninediainininochloride, 16.
272
ethylenedianiinediainininochloroplatinate,
16. 272
ethylenediaminediarmrtinochloroplatinito,
16. 272
ethylenediaminedihydrochloride, 16.
272
dihydrate, 16. 272
ethylenediarninehydrochloroplatinito,
16. 272
ethylonediarninepropylenodianimines,
16. 353
ethylenediamines, 16. 356, 365
ethylonodiaminium ethylenediamine
ethylenetrichloroplatinite, 16.272
ethylenediethylamines, 16. 359
ethylenedisulphines, 16. 357
ethylenepotassiumthioglyeollato, 16.
358
ethylenes, 16. 360
ethylenesulphineamminosulphato, 16.
4Ol
ethylenesulphinetriammirxosulphate,
16. 401
ethylonesulphinodiammines, 16. 353
ethylenesulphinotriairirnines, 16. 350
ethylonethioglycollate, 16. 358
ethylenethioglycollic acid, 16. 358
ethylenetriethylphosphite, 16. 36O
ethylniercapti.de, 16. 368
ethylphosphates, 16. 368
�� ethylphosphitedihydroxide, 16. 239
ethylphosphites, 16. 368
ethylphosphitochlorido, 16. 277
ethylpropylsulphines, 16. 360
ethylsulphinearnmines, 16. 359
ethylsulphineethylselenines, 16. 360,
368
ethylsulphines, 16. 361
ethylsulphinosulphate, 16. 406
ethylstilphinotriammines, 16. 352
fluoride, 16. 249
glycinodiainminochloride, 16. 273
hemitricarbonylchloride, 16. 273
hexachlorobispyridinediammine, 16.
369
hexachloroethylenediamines, 16. 361
hexammines, 16. 362
hexamminohy droxyhydrophosphate,
16. 416
hexamminoiodide, 16. 384
hexamminosulpliatodihydrosulphatodinitrosylhy
dr osulphatohy drochloride,
8. 444
hexasulphoplatinate, 16. 395
hydrazinocarbylaminoohlorides. 16.270
263
hydroxybispyridinodihydroxylamine
278
hydroxychlorotetraxrwxiines, 16. 363
hydroxydinitratotriamminos, 16. 365
� hy droxy iodotetrammines, 16. 363
hydroxylaroineammin.es, 16. 359
-� hydroxylaminehydroxide, 16. 238
hydroxylamines, 16. 36O
hy droxy laminoammines, 16. 355
a-hydroxylaminobispyridinoamminoc'hloride,
16. 273
ct-hydroxylaminopyridinechloride, 16.
273
hy droxy !amino triamminos, 16. 350
hydroxylaminotriamminochloride, 16.
269
hydroxylaminotriamminochloroplatinite,
16. 269
a-hydroxylaminotrispyridinochloride,
16. 273
hydroxynitratobisbenzylsulphine, 1641O
hydroxynitratopropylsulphine�trans,
16. 410
hydroxynitratosilverphosphite, 16. ,410
hydroxynitratototrammines, 16. 363
hydroxynitritohydroxylaxninoammine,
8. 516
hydroxypentammines, 16. 362
hydroxysulphatobispyridine, 16. 4Ol
hydroxysulphatotetrammines, 16. 364
hydroxytriammines, 16. 354
hydroxytriamminohydroxide, 16. 238
hypophosphite, 8. 890
iodide, 16. 384, 387
iodoe thy lenesulphineamminoiodide,
16. 385
iodoethylenesulphineamminoiodochloroplatinite,
16. 386
iodoethylenesulphinediammines, 16.
355
iodoethylmercaptidodiammine, 16. 385
iodomercaptanodiammine, 16. 386
iodotrichloroiodoammine, 16- 386
a/3-isobutylenediamines, 18. 365
jaborinates, 16. 368
jaborines, 16. 368
lead phosphites, 16. 361
Platinous lead /rari#-sulphitodiamminoeulphito,
10. 321
manganous �ran�-sulphitodiamminosulphite,
10. 321
3-methyl-2-aminomethyl-4-ethylquinolines,
16. 365
me thy lcarbylaminehy drazinoiodide,
16. 386
methylethylsulphines, 16. 357, 360,
367
methylphosphates, 16. 368
methylsulph^notriammines, 16. 352
monammines, 16. 36O, 368
(acidic), 16. 361
monoxide, 16. 235
nickel �re**t^-sulphitodianuninosulphite,
10. 321
nitrate, 16. 408
nitratohromoquaterpyridines, 16. 364
nitratobromotetrammines, 16. 363
nitratocarbonatoammines, 16. 364
nitratochlorotetrammines, 16. 363
� nitratodibromotriammines, 16. 365
nitratoethylthioglycolatodiainrnine,
16. 409
nitrat oeth y 1 thiogly coll atoammines,
16. 358
nitratoethylthiolaeotatodiammine, 16.
41O
�� nitratoethylthiolacetatomonarnmine,
16. 410
nitratotriammines, 16. 354
nitratotriamminonitrate, 16. 409
�-� nitratotrisethylsulphinenitrate, 16. 4IO
nitritoamminodiethylenediamine, 8.
517
�- nitritoamminodiethylenediaminohydroxide,
8. 517
� nitritochloridedihydroxylaminoamrninechloroplatinite,
8. 516
nitritochloroethylenediami nodiammines,
16. 363
nitritochlorohydroxylammine, 8. 516
nitritodichloroethylenediaminomethyl
354
nitritohydroxylaminodiamminonitrite
(cis), 8. 516
(trans), 8. 516
nitritohydroxylaminopyridinoaxnrnine.
8. 517
nitritohydroxylaminopyridinoammines,
16. 354
nitritohydroxylaminopyridinoamminocbloride,
8. 517
nitri tohydroxylajninopyridinoamminonitrite
(trans), 8. 516
ohloroplatinite, 8. 516
nitritopyridinodiammines, 16. 354
nitritopyridinodiamniinochloride
(trans), 8. 517
nitritopyridinodiamminonitrite (cis),
8. 517
ohloroplatinite, 8. 517
nitri topyr idinohydroxylaminoammine,
8. 516
nitritotriamxnines, 16. 364
INDEX 687
� qiiaterbutylaininechloroplatinite, 16.
273
quaterbutylamines, 16. 351
quaterbutylcarbylamineohloride, 16.
276
quaterbutylcarbylaminechloroplatinite,
16. 276
quaterbutylcarbylamines, 16. 351
qua terbuty lsulphines, 16. 352
quaterdiethylseleninechloride, 16. 277
quaterdiethylseleninechloroplatinite,
16. 277
quaterdiethylthiocarbamide, 16. 351
quaterdiethylthiocarbamidechloride,
16. 277
quaterdi - iso - undecyltb iooarbamide,
16. 351
quaterdi - iso - undecyl thiocarbaraidechloride,
16. 277
quaterdixnethylaxninechloride, 16. 271
quaterdimethylaminechloroplatinite,
16. 271
quaterdimethylamines, 16. 351
quaterdi-n-butylsulphinechloroplatinite,
16. 275
quaterdipropylsulphinechloroplatinite,
16. 275
quaterethylaminebromide, 16- 372
quaterethylaminechloroplatmite, 16.
27O, 271
qua terethylaminenit rate, 16. 409
quaterethylaminepyridinetrichloroplatinite,
16. 274
quaterethylamines, 16. 35O
quaterethylaminesulphate, 16. 401
quaterethylaroinochloride, 16. 270, 271
INDEX
VOL. XVI.
- sulphatodiamminobisethylthiolacetate�
trans, 16. 4Ol
� sulphatodibenzylsulphine, 16. 4Ol
sulpha toe thylenediarnine, 16. 4Ol
sulphatoethylsulphinepyridine, 16. 4Ol
sulphatoe thy lsulphinoethylselen ino,
16. 401
aulphat o te train mines, 16. 363
sulpha to triammines, 16. 354
sulphatotrisethylselenino, 16. 4Ol
sulpha totrise thy lsulphines, 16. 355
sulphatoxycacodyl, 16. 401
sulphide, 16. 393
16. 268
tetrahydroxylaminenitrato, 16. 4OO
tetrahydroxylarninephosphate, 16. 416
tetrahydroxylamines, 16. 35O
tetrahydroxylaminosulphate, 16. 4Ol
tetranxminepyridinetrichloroplatinite,
16. 274
tetrammines, 16. 35O, 362
tetranuxunoallylalcoholtrieliloroplatinite,
16. 273
tetramminoarsenatomolybdate, 9. 131
tetramminoarsenitotungstate, 9. 132
tetramminocarbonatohydrocarbonate,
16. 407
tetramminochiorobarytate, 16. 257
tetramminochlorocobaltate, 16. 257
tetramminochlorocobaltite, 16. 284
tetramminochlorocuprate, 16. 257, 281
tetramminochloromercurate, 16. 257
tetraniminochloropalladite, 16. 259
tetramminochloroplatinate, 16. 259
tetramminooliloroplatinite, 16. 257
totramminochloroplumbate, 16. 257
totramminochlorostannate, 16. 257
totramminochlorostannite, 16. 257
tetramminochlorozincate, 16. 257, 283
tetramminochromate, 11. 313
tetramminodichloride, 16. 255
� tetraniminodichloro-dichloronitrosylhydrochloride,
8. 443
� tetramminodichlorodinitrosylhydrosulphate,
8. 443
,� teti'ainminodichloronitrosylhydrochloride,
8. 443
tetramminodichromate, 11. 344
tetramminodihydrotrisulpliite, 10. 322
tetramminodihydroxide, 16. 235, 239
tetramrninodinitratonitrosylhydronitrate,
8. 443
tetramxainodinitratotetraraminochloroplatinate,
16. 260
tetramminodinitrite, 8. 514
tetramrainodisulphite, 10. 321
tetramrainoethylaminetrichloroplatinite,
16. 271
tetramminoethylenedichloroplatinite,
16. 272
tetrainminohexachloroarsenitotungstate,
0. 132
tetramminohydrocarbonato, 16. 407
tetramminoliydrophospliate, 16. 416
tetrannninohydrosulphate, 16. 400
tetramminohydroxide, 16. 238
tetramminoiodide, 16. 385
tetramminoiodomercurate, 16. 385
tetramminonitrate, 16. 408
tetramrain.osulph.ate, 16. 400
tetrammmosulphatohydroxychloroplatinite,
16. 406
tetramminosulphite, 10. 321
tetramminosulphitoohloroplatiriite, 16.
260
tetramminotetrachloroamminoplatinate,
16. 323
tetramminotetranitritoplatinate, 8.575
tetranirninotrichloroallylalcoholoplati
Platinous tristetrahydroxylaminetetrahydroxydiehloride,
16. 268
trithiocyanatocarbonyls, 16- 362
ultraphosphate, 16. 416
uranyl �ran�-sulphitodiamminosulphite,
10. 321
vinylsulphines, 16. 368
zinc Irarz^-sulphitodian^minosulphite,
10. 321
Platinschwann, 16. 50
Platinschwarz, 16. 44
INDEX 691
� dinitratohexammino-ft-diimidosulphate,
16. 414
dinitritodibromobisdimethylselenide,
8. 518
dinitritodibromodiammine (cis), 8. 518
(trans), 8. 518
dinitritodibromotetraethylsulphoselenide,
8. 518
dinitr itodichlorobisd i me thy lselenide,
8. 518
dinitritodichlorodiarrirnine (cis), 8. 518
(trans), 8. 518
dinitritodiiodobisdimethylselenide, 8.
518
dinitritodiiodotetraethylsulphoselenide,
8. 518
dinitritohydroxychlorodiammine, 8.
518
dinitritonitratochlorodiammine, 8. 518
dinitritosulphatodiammine (cis), 8. 518
(trans), 8. 518
dinitritotetrammine nitrite, 8. 517
dioxide, 16. 242
dihydrate, 16. 243
hemitrihydrate, 16. 243
monohydrato, 16. 243
tetrahydratc, 16. 244
_ trihydrate, 16. 244
dipentitantimonide, 9. 416
diphosphido, 8. 861
diplumbide, 16. 214
dipropylsulphinodithiosulphate, 10.
558
diselenide, 10. 801
distannide, 16. 212
distannyl stannate (a-), 7. 42O
stannic oxide, 7. 393
disulphide, 16. 396
ditelluride, 11. 64
ditritasilicide, 6. 212
dizincido, 16. 206
dodecasilicido, 6. 212
electrode potential, 16. 102
eloctrodeposition, 16. 116
electromotive foree, 16. 107
electronic structure. 16. 192
enneaiodoctammine, 16. 369
ethylsulphinobenzylamminomonochloride,
16. 251
ethylsulphinobispyridinomonochloride,
16. 251
ethylsulphinoethylaminochloride, 16.
251
ethylsulphinomonochloride, 16. 251
explosive, 16. 49
extraction, 16. 22
dry processes, 16. 25
sulphide ores, 16. 22
-wet processes, 16. 26
16. 369
hexachloroxyhypovanadate, 9. 806
� mirrors, 16. 61
molybdate, 11. 676
molybdenum alloys, 16. 216
monamidodiphosphate, 8. 710
monantimonide, 9. 416
moxiochloride, 16. 251
monophosphide, 8. 861
monosilicide, 6. 212
monosulphide, 16. 393
monotelluride, 11. 64
native, 16. 5
nickel alloy, 16. 219
22O
copper alloys, 16. 22O
gold alloys, 16. 22O
iron alloys, 16. 220
silver alloys, 16. 220
chloride, 8. 518
nitritotrichlorodiammine, 8. 518
osmium alloys, 16. 225
organosol, 16. 55
oxides (lower), 16. 235
. hydrates of lower oxides, 16. 235
oxyarsenide, 9. 59
palladium alloy, 16. 223
electric, 16. 97
magnetic, 16. 97
mechanical, 16. 62
-= optical, 16. 80
thermal, 16. 68
purification, 16. 34
reactions of analytical interest, 16. 171
recovery, 16. 30
rhenium alloy, 16. 216
rhodium alloys, 16. 221
GENERAL.
INDEX 693
Plombagina, 5. 714
Plombierite, 6. 360
Plumbago, 5. 713 ; 7. 780, 781
anglica, 5. 713
scriptoria, 5. 713
Plumballophane, 6. 497
Plumbates, 7. 695
Plumbea graphis, 5. 713
Plumbeine, 7. 782
(di)plumbhydroxyl hydroxynitrilodisulpho
nate, 8. 678
(tetra)plumbhydroxylacetobishydroxynitrilodisulphonate,
8. 678
(tr i )plumbhy droxylhy droxy n i tr ilodisul
phonate, 8. 678
Plumbi minora spathacoa, 7. 829
Plumbic acid, 7. 685
colloidal, 7. 685
bishydrophosphate, 7. 886
ehromate, 11. 293
dichromate, 11. 342
dihydrophosphate, 7. 886
694 GENERAL
meal, 9. 90
INDEX
physical, 2. 516
soft, 6. 515
spar, 6. 763, 766
Porcellophite, 6. 422
Porosity metals, 13. 423
Porpezite, 15. 593
Porpizite, 15. 648
Porricine, 6. 818
Portable fire-boxes, 8. 1059
Portite, 6. 921
Portland cement, 6. 554
Porzellanite, 6. 763
Porzellanspath, 6. 763
Positive, 3. 412
chemistry, 1. 4
column, 3. 932
election, 3. 937
rays, 3. 955, 956
analysis, 3. 958
-�- valence, 4. 191
Potarite, 15. 592 ; 16. 5
Potash, 2. 420, 438
acinite, 6. 914
Potashsodalite, 6. 583
Potassamide, 8. 253
Potassammonium, 8. 244
Potassiophosphine, 8. 816
Potassium acetylene carbide, 5. 849
action on 'water, 1. 135
allylalcoholotrichloroplatinite, 16. 273
allylalcoholtribromoplatinite, 16. 372
aluminate, 5. 289
aluminium alloys, 5. 229
amide, 8. 262
carbonate, 5. 359
decamolybdate, 11. 598
dimetasilicate, 6. 648
hydrated, 6. 574
selenate, 10. 869
selenatosulphate, 10. 930
sulphate, 5. 343
sulphatoselenate, 10. 930
tellurate, 11. 96
triorthoarsenate, B. 186
277
amidoaluminate, 5. 212
amidoargentate, 8. 259
amidobariate, 8. 26O
amidochlorosmate, 15. 718
amidochromate, 8. 266
amidohydrochlorosmate, 15. 718
amidopropionatodichloroplatinite, 16.
277
amidosulphonate, 8. 641
amidothioimidosulphonate, 8. 636
ammine, 8. 244
amminoaluminate, 5. 289
amminoarsenide, 9. 61
ammoniocadmiate, 8. 261
ammoniomolybdite, 8. 267
amminopentachloroplatinate, 16. 323
amminotetrarsenide, 9. 61
amminotrichloroplatinite, 16. 267
� ammoniotungstito, 8. 268
ammonium arsenatodecavanadatohexadecamolybdate,
9. 202
arsenatododecavanadatodocamolybdate,
9. 202
arsenatotetradeeavanadatododecamolybdate,
9. 202
arsonatotetradecavanadatotridecamolybdate,
9. 833
calcium disulphato, 3. 812
chlor opium bite, 7. 729
. chromato, 11. 257
chromium sulphate, 11. 463
decametaphosphate, 2. 878
decamolybdatotrisulplute, 10.
307
diphosphatoctovanadatotetradecamolybdate,
9. 833
diphosphatodecavanadatotridecamolybdate,
9. 833
diphosphatododecavanadatodecamolybdate,
9. 833
diphosphat ododeca vanadat od o decamolybdate,
9. 833
diphosphatohexavanadatoctodecarnolybdate,
9. 833
� hexavanadatopentamolvbdate,
9. 784
imidoehromato, 8. 266
iridium disulphate, 15. 786
manganous permanganitornolyb
2. 877 ; 8. 088
permanganitomolybdate, 11. 573
platinous chlorodisulphite, 10.
323
838
silicovanadatomolybdates, 6. 837
sulphitochloroiridite. 15. 758
tetravanadatotetramolybdate, 9.
784
triselenitodecamolybdate, 10. 836
triterodecavanadate, 9. 766
uranyl trisulphate, 12. 108
zinc sulphate, 4. 641
- ammonomagnesiate, 8. 26O
- amylonotrichloroplatinite, 16. 273
and magnesium chlorides : crystallization
2. 432
and sulphates : crystallization,
2. 434
sulphates : crystallization,
2. 432
sodium sulphates and chlorides :
crystallization, 2. 689
antimonatotriiodobromide, 9. 511
antimonatotungstate, 9. 451)
antirnonide, 9. 403
antimonious thiosulphate, 10. 553
antimonite, 9. 431
antimonitophosphatotungstate, 9. 433
antimonitotungstate, 11. 817
antimony henasulphate, 9. 583
sulphate, 9. 583
antimonyl pentachloroantimonate, 9.
506
aquochloroperiridite, 15. 765
aquochloroperruthenite, 15. 531
aquopentaboroiridate, 15. 777
aquopentahypophosphitoferrate, 8.889
aquopontasulphitosmate, 10. 325
argento iodide, 8. 432
arsenatoctodecavanadatopentamolyb
date, 9. 202
arsenatoctoicosivanadatoheptamolybdate,
9. 202
arsenatoctovanadatodimolybdate, 9.
202
arsenatodecavanadatohexadecamolybdato,
9. 202
� arsenatodioxydichromate, 9. 205
arsenatodivanatate, 9. 20O
arsenatododeca vanadatododecamoly b date,
9. 202
arsenatododecavanadatoh eptamolybdate,
9. 202
arsenatohemipentamolybdate, 9. 207
arsenatohexadecavanadatododecamolybdate,
9. 202
arsenatohexavanadatopentadecamolybdate,
9. 202
arsenatoicosivanadatohexamolybdate,
9. 202
arsenatoicosivanadatopentamolybdate,
9. 202
arsenatotellurate, 11. 96
arsenatotetracosivanadatoctomolyb
date, 9. 202
Potassium arsenatotetradecavanadatotridecamolybdate,
9. 202
arsenatotetravanadatohemipentamolybdate,
9. 202
arsenatotrimolybdate, 9. 209
arsenious thiosulphate, 10. 653
arsenitoarsenatotungstate, 9. 137
arsenitotetraphosphatotungstate, 9.
132
arsenitotungstate, 11. 817
astracanite, 2. 430
astrakanite, 4. 339
at. wt., 2. 470
aurate, 8. 584
auric octosulphite, 10. 281
tetramminohexasulphite, 10. 281
aurochloride, 8. 589
aurous disulphite, 10. 281
autunite, 12. 135
azide, 8. 347 ; 11. 368
azidodithiocarbonate, 8. 338
azidoplatinite, 16. 254
barium ammonium silicovanadatodecatungstate,
6. 838
arsenate, 9. 173
calcium carbonate, 8. 846
carbonate, 3. 845
chromate, 11. 273
chromidodoeamolybdate, 11. 602
cobalt nitrite, 8. 505
dimetaphosphate, 3. 894
diphosphatotetravan adatoc to decamolybdate,
9. 834
hydroxynitrilodisulphonate, 8.
677
hyponitrilosulphate, 8. 69O
imidodisulphonate, 8. 655
iron nitrite, 8. 501
nickel nitrite, 8. 511
nitrilotrisulphonate, 8. 669
nitrite, 8. 488
oxytrisulpharsenate, 9. 330
pentabromide, 3. 732
phosphate, 8. 877
decahydrated, 3. 877
phosphatohenatungstate, 11. 868
silicododecatungstate, 6. 878
silicovanadatoenneatungstate, 6.
838
sulphatochloride, 3. 813
sulphatonitrate, 8. 813
tetrachloride, 8. 719; 4. 310
trichromate, 11. 351
trimetaphosphate, 8. 894
beryllate, 4. 228
beryllium carbonate, 4. 244
dimetasilicate, 6. 803
fluoride, 4. 230
hydrosulphate, 4. 241
nickelous fluosulphate, 15. 475
oxydiorthoarsenate, 9. 175
� pyrophosphate, 4. 247
silicate, 6. 382
sulphate, 4. 240
trisulphite, 10. 285
�ran*-bisohromatotetramminocobalti
701
nitrite, 8. 499
thiosulphate, 10. 554
tungstate, 11. 795
bismuthate, 9. 657
bismuthotungstate, 9. 651
bismuthyl dichromate, 11. 343
metantimonate, 9. 460
boratofluoride, 5. 125
boride, 5. 23
borohydrates, 5. 4O
borylphosphate, 5. 147
bromate, 2. 330
bromide, 2. 577 ; 11. 368
- dialuminium pentamosodisilicate,
6. 747
dimetaphosphate, 3. 894
disulphate, 3. 807
� hexasulphato, 3. 808
� hydrodimetasilicate, 6. 369
nickel nitrite, 8. 512
� sulphate, 15. 475
nitrite, 8. 488, 501
- orthopertantalate, 9. 914
pentacarbonate, 3. 845
perorthocolumbate, 9. 870
phosphate, 3. 877
phosphatohemipentamoly bdate,
11. 669
phosphatoplumbate, 7. 886
phosphatostannate, 7. 483
phosphatothorate, 7. 253
phosphatotitanate, 7. 97
phosphatozirconate, 7. 165
pyrophosphate, 3. 892
quinquemonochromate, 11. 270
physical, 2. 747
� carbonatostannite, 7. 48O
� carbonyl, 2. 450 ; 5. 951
� carburet, 5. 847
� carnotite, 9. 788
� oeric nitrate, 5. 673
sulphate, 5. 662
� cerous carbonate, 5. 665
698 GENERAL, INDEX
� octosulphate, 5. 658
pentasulphate, 5. 658
nickel nitrite, 8. 512
nitrate, 5. 670
orthophosphate, 5. 675
sulphate, 5. 658
sulphite, 10. 302
� _ properties, 2. 529
chemical, 2. 552
physical, 2. 529
purification, 2. 527
X-radiogram, 1. 636
� chlorite, 2. 283
chloroamidosulphonate, 8. 641
chloroaquoperruthenito, 15. 532
chloroarsenite, 9. 255
chloroaurates, 3. 593
chloroaurites, 8. 588
chlorobisarsonite, 9. 255
chlorobromoplatinates, 16. 381
ehlorochromate, 11. 397
chlorocolumbite, 9. 876
chloroimidodisulphonate, 8. 653
chloroiodide, 2. 610, 611
chloroiridate, 15. 768
chloroiridiosmate, 15. 772
chloromanganite, 12. 380
chloropalladate, 15. 672
chloropalladite, 15. 668
chloropontabromoplatinate, 16. 382
chloroperiridito, 15. 763
monohydrato, 15. 764
trihydrate, 15. 764
chloroperosmite, 15. 717
chloroperpalladite, 15. 671
chloroperruthenite, 15. 529
monohydrate, 15. 530
a.t is . *53o
0-, 15. 530
monohydrated, 7. 449
chlorosulphate, 2. 691
� triorthoarsenate, 9. 204
chromidodecamolybdate, 11. 601
chromihexasulphate, 11. 465
chromioxydodecamolybdates, 11. 601
chromipentasulphate, 11. 465
chromipyrophosphate, 11. 481
chromitetrasulphate, 11. 464
Potassium dibromotetranitritoplatinate, 8.
624
dicadmiura sulphate, 4. 638
dicalcium cadmium sulphate, 4- 640
644
c%>-dichlorodiamidosulphonatoplatiiiite,
8. 644
�ran�-dichlorodiamidosulphonatoplati
nite, 8. 645
dichlorodinitritoplatinite, 8. 522
dichloroglycineplatinite, 16. 267
dichlorotetrabromoplatinate, 16. 382
dichloro tetrani tritoplatinate, 8. 524
dichromate, 11. 328
didicovanadate, 9. 802
hexahydrate, 9. 802
514
tetranitritoplatinite, 8. 518
dihydroantimonate, 9. 447, 448
dihydroarsenate, 9. 154
dihydroarsenatomolybdate, 9. 206
dihydroarsenatotrimolybdate, 9. 208
dihydroarsenitopentamolybdate, 9.131
dihydrochromiarsenate, 9. 205
dodecahydrate, 9. 205
heptahydrate, 9. 205
dihydroferriarsenate, 9. 227
dihydrohexasilicate, 6. 337
dihydrohexasiilph.itosrnate, 10. 325
dihydrohypophosphate, 8. 935
dihydrornanganidiorthophosphate, 12.
461
dihydro-octosilicate, 6. 337
dihydrophosphatohemipentamolyb
� dihydrophosphite, 8. 914
dihydropyroantimonate, 9. 449
dihydropyrophosphate, 2. 865
dihydropyrophosphite, 8. 922
dihydrorthophosphate, 2. 858
dihydrotetrachlorotetrasulphite, 10.
325
dihydrotetraselenitohexa vanadate, 10.
835
dihydrotetrasilioate, 6. 337
dihydrotrialuminotriorthosilicate, 6.
608
dihydrotrioxysulpharsenate, 9. 328
dihydroxydiiodotriarsenite, 9. 257
dihydroxylaminsulfate, 8. 676
� dihypovanadatoctovanadate, 9. 793
dihypovanadatovanadate, 9. 793
diimidomonosulphonate, 8. 683
di-iodate. 2. 335
Potassium <rarw�-diiododiamidosulphonato
diplatinite, 8. 645
diiododinitritopalladite, 15. 681
diiododinitritoplatinite, 8. 622
dimagnesium hydrodialuminotriortho
silicate, 6. 608
dimanganese oxyoctofluoride, 12. 347
dimerouric sulphide, 4. 966
dimercuride, 4. 1015
dimetaphosphato, 8. 985
dimolybdate, 11. 581
dimolybdatotetratungstate, 11. 796
dimolybditomolybdate, 11. 593
dinitratotellurate, 11. 119
dinitrosylsulphide, 8. 441
dinitrosylsulphite, 8. 434
dinitroxyltetranitritoplatinite, 8. 518
dioxide, 2. 487
dioxydifluochromate, 11. 365
dioxydisulpharsenate, 9. 329
dioxydisulphomolybdate, 11. 654
dioxydisulphotungstate, 11. 860
dioxyenneasulphodicuprate, 3. 229
dioxytetraiodotricarbonatotetraplum
bite, 7. 854
dioxytetramolybdate, 11. 613
dioxytrifluomolybdate, 11. 613
dipalladite, 15. 657
diperchromato, 11. 357
diperhydroxycarbonate, 6. 85
dipermanganite, 12. 275
dipermolybdate, 11. 607
diphosphate, 2. 862
d iphosphatoctodecavanadatoennea
molybdate, 9. 833
diphosphatoctovanadatotetradecamolybdate,
9. 833
diphosphatodecavanadatoctodecamolybdate,
9. 833
diphosphatodecavanadatohenarnolybdate,
9. 833
diphosphatodecavanadatotridocamolybdate,
9. 833
diphosphatodivanadatoheptatung8tato,
9. 835
diphosphatododeca vanadatododecamolybdate,
9. 833
diphosphatoheptadecavanadatoenneamolybdate,
9. 833
diphosphatohexavanadat open tadecamolybdate,
9. 833
diphosphatotetradecavanadatohenamolybdate,
9. 833
diphosphatotetravanadatoicosimolyb
date, 9. 832
diplatinic triacontatungstate, 11. 803
diplumbide, 7. 608
diselenitododecamolybdate, 10. 837
diselenitopentamolybdate, 10. 837
disilicate, 6. 336
dihydrated, 6. 337
hydrated, 6. 337
disilicozirconate, 6. 864
disilver cobaltic hexanitrite, 7. 504
trihydroxydiamidophosphate, 8.
704
disodium cobaltic nitrite, 8. 504
distannide, 7. 346
Potassium disulphatoaluminate, 5. 343
heptahydrate, 5. 352
tetrahydrate, 5. 352
disulphatoaurate, 8. 615
disulphatobismuthite, 9. 701
disulphatochroxniate, 11. 454
disulphatocuprate, 8. 257
disulphatodipluinbite, 7. 82O
disulphatoindate, 5. 405
disulplxatoph.ospb.ate, 8. 948
disulphatoplumbite, 7. 82O
disulphatovanadite, 9. 820
disulphide, 3. 630, 632
ci*-disulphitotetramminocobaltate, 10.
317
disulphohydroxyazotate, 8. 675
dithioaurite, 3. 612
dithionate, 10. 584
dithiophosphate, 8. 1068
ditungstate, 11. 809
dihydrate, 11. 809
trihydrate, 11. 809
diuraxiate, 12. 66
hexahydrate, 12. 66
trihydrate, 12. 66
diuranyl disulphite, 10. 308
enneafluoride, 12. 79
heptafluoride, 12. 79
ort ho vanadate, 9. 788
pentahypophosphite, 8. 889
trisulphate, 12. 110
divanadatodimolybdate, 9. 783
divanadatododecamolybdate, 9. 783
divanadatohexamolybdate, 9. 783
divanadatophosphate, 9. 828
divanadatotetratungstate, 9. 786
divanadatotrimolybdate, 9. 783
divanadium dihydroaluminotriorthosilicate,
6. 836
divanadyl trisulphate, 9. 824
divanadyldodecafluovanadate, 9. 801
� divanadylhydrodecafluoride, 9. 799
� divanadylpentafluoride, 9. 80O
divanadyltrihydrohenanuoride, 9. 799
INDEX 701
Potassium ethylaminetrichloroplatinite, 16.
�
.
271
ethylenetriehloroplatinite, 16. 272
arsenate, 9. 227
difluotrichloride, 14. 77
3IO
enneaoxyquaterchromate, 11.31O
hoptasulphato, 14. 339
hexafluoride, 14. 8
hydrophosphite, 8. 920
hydroxytetrasulphate, 14. 343
metasilicate hydrated, 6. 92O
nitrate, 14. 387
oxyseptieschromato, 11. 3IO
pentchloride, 14. 102
� pentadecoxydecieschromate, 11.
31O
pentoxydocieschromate, 11. 310
phosphate, 14. 4IO
pyroarsenate, 9. 227
selenatosulphate, 10- 930
sulphatoselenate, 10. 93O
sulphide, 14. 182
triorthoarsenate, 9. 227
trioxynovieschromate, 11. 310
decahydrate, 11. 310
hexahydrate, 11. 310
trioxysexiesehrornato, 11. 310
trisulphate, 14. 339, 344
t ungate, to, 11. 801
ferrite, 13. 908
ferrisulphatodisulphite, 10. 313
ferrisulphatosulphite, 10. 312
ferrodinitrosylsulphide, 8. 442
ferroheptanitrosylsulphide, 8. 440
ferronitrosylthiosulphate, 8. 442
ferrosio bromide, 14. 126
sulphite, 10. 312
ferrous carbonate, 14. 369
cobaltous sulphate, 14. 783
nickelous sulphate, 15. 477
orthosulphoantimonite, 9. 553
persulphate, 10. 48O
selenate, 10. 881
� dihydrate, 10. 881
hexahydrate, 10. 881
GENERAL INDEX
tetrachloride, 14- 32
dihydrate, 14. 32
morxohydrate, 14. 32
tetrachloride, 14. 3
trichloride, 14. 32
trifluoride, 14. 3
fluobismuthate, 9. 66O
fluobismuthite, 9. 659
nuoborate, 5. 126
fluochromate, 11. 365
fluodidymates, 5. 638
fluodivanadate, 9. 802
� fluogermanate, 7. 269
fluoiridate, 15. 757
fluomanganite, 12. 347
fluopalladito, 15. 658
fluoperborate, 5. 129
fluoplatinate, 16. 250
fluoplumbite, 7. 704
fluoride, 2. 512 ; 11. 368
fluorometaphosphate, 2. 867
fluorophosphate, 2. 85O
fluorosulphate, 2% 691
fluoscandate, 5. 4*89
fluosilicate, 6. 947
fluostannate, 7. 423
a-salt, 7. 423
�-saIt, 7. 423
fluostannite, 7. 423
fluosulphonate, 10. 685
fluotetravanadate, 9. 802
fluotitanate, 7. 71
hydrated, 7. 71
fluozirconate, 7. 14O
gadolinium, chromat.es, 11. 288
germanium sulphate, 7. 269
gmelinite, 6. 735
gold amidosulphonate, 8. 642
� harraotome, 6. 767
hemicosihydrodecasolenitohexavanadato,
10. 835
hemienneamercuride, 4. 1015
hemirnercuride, 4. 1015
hemipentaphosphide, 8. 835
hemiplumbide, 7. 608
hemistannide, 7. 346
hemithallide, 5. 426
hemitritelluride, 11. 41
henachlorodihypoantimonate, 9. 485
henadocamercuride, 4. 1014
heptabismuthite homihydriodido, 9.
677
heptabromoaluminate, 5. 326
heptadecahydroctoselenitohexa vanadate,
10. 835
heptaennitabismuthide, 9. 635
heptafluoantimonate, 9. 468
heptafluoarsenate, 9. 236
� heptafluocolumbate, 9. 872
heptafluodithallate, 5. 437
heptafluotantalate, 9. 916
heptailuozirconate, 7. 141
heptahydrododecamolybdate, 11. 596
cosiphosphate, 9. 826
�i hepteroctodecavanadate, 9. 765
heptoxyenneasulphotatramolybdate,
11. 655
heulendite, 6. 767
hexaborate, 5. 78
hexabromoiridate, 15. 777
hexabromoselenate, 10. 901
hexabromo tellurite, 11. 104
hexachloroaluminate, 5. 322
hexachloroantimonite, 9. 48O
hexachlorobismuthite, 9. 677
hexachlorohypoantimonate, 9. 485
hexachloroindate dehydrated, 5. 400,
402
hexachloropalladite, 15. 669
hexachloroperrhodite, 15. 578
9. 485
hexachlorostannatohypoantimonate,
9. 485
hexachlorostannite, 7. 433
hexachlorotellurite, 11. 102
� hexaphosphatoctovanadatoctodecatungstate,
9. 835
� hexarhodite, 15. 571
� hexarsenite, 9. 120
Potassium hexaselenitoheptadecamoly b date,
10. 836
hexasilicate, 6. 328
hexasulphide, 2. 630, 64O
hexatellurite, 11. 79
hexathionate, 10. 628
hexatitanate, 7. 51
hexatungstate, 11. 829
hexauranate, 12. 68
decahydrate, 12. 68
hexahydrate, 12. 68
hexavanadatododecatungstate, 9. 786
hexavanadatoicosimolybdate, 9. 783
hexavanadatotetraraolybdate, 9. 782
hexavanadyl tetrasulphite, 10. 305
hexoxypentafluocolurnbate, 9. 873
history, 2. 421
liydrazinodisulphonate, 8. 682
hydrazinornonosulphonate, 8. 683
hydride, 2. 481
hydroaraenate, 9. 154
hydroarsenatodimolybdate, 9. 206
hemiheptahydrate, 9. 206
hydroarsenatoctomolybdate, 9. 209
hydrobromide, 2. 587
hydrocarbonate, 2. 763, 774, 778
hydrochloroplatinito, 16. 285
hydrochlorosulphitosmate, 15. 726
hydrochlorotetranitritoplatinite, 8. 521
hydroctofluoplumbate, 7. 705
hydrodifluodiselenate, 10. 903
hydrodiiodotrichlorostannito, 7. 461
hydrodioxydistilphoantimomte, 9. 578
hydrodiphosphatotellurate, 11. 120
heptadecahydrate, 11. 12O
tetrahydrate, 11. 120
- hydrodisilicate, 6. 336
hydroheptafluotantalate, 9. 916
hydrohypophosphato, 8. 935
hydroinetasulphotetrantimonite, 9.535
hydroraonamidophosphate, 8. 706
hydronitrate, 2. 821
hvdro-orthopbosphate : secondary, 2.
~851
hydro-oxypentafluocolumbate, 9. 874
hydropentasulphatocolumbate, 9. 882
liydropermonosulphomolybdate, 11.
670
hydrophosphatodimolybdate, 11. 670
hydroplumbito, 7. 666
� � hydropyrosulphate, 10. 446
hydropyrotellurate, 11. 91
hydropyrotellurite, 11. 79
hydroselenate, 10. 858
hydroselenatouranate, 10. 877
hydroselenide, 10. 768
hydroselenite, 10. 822
hydroselenophosphite, 10. 931
hydrostannite, 7. 391
hydrosulphatarsenate, 9. 334
hydrosulphate : hydrated, 2. 682
hydrosulphates, 2. 677, 678, 679, 682
hydrosulphide, 2. 641
hydrosulphite, 10. 268
hydrosulphitochlorosmate, 15. 7J9
hydrosulphoplatinite, 16. 395
hydrotellurate, 11. 91
hydrotetramidophosphate, 8. 716
hydro tetraselenitohexavanadate, 10.
835
INDEX 703
Potassium, hydrotetroxytrisulphodimolybdate,
11. 655
hydrotrifluothallite, 5. 437
hydrotriiodotrichlorostannite, 7. 461
hydrotrioxysulpharsenate, 9. 328
hydroxide, 1. 521 ; 2. 495
and hydrogen, 1. 303
properties, 2. 500
purification, 2. 499
uses, 2. 509
hydroxychlororuthenate, 15. 531
hydroxylamine hydrouranate, 12. 62
hypophosphite, 8. 882
paramolybdate, 11. 552
hydroxylamineisodisulphonato, 8. 674
hydroxylaminopentahydromolybdate,
11. 552
hydroxynitrilodisulphonate, 8. 675
hydroxynitrilomonosulphonato, 8. 671
hydroxypentabromoruthenate, 15. 538
hydroxypentachloroplatinato, 16. 335
hydroxypentachlororuthenate, 15. 536
hydroxypentachlorosmate, 15. 72O
hydroxyperosmate, 15. 713
hydroxyperoxylamidosulphonate, 8.
686
hydroxytetrasulphatocuprate, 3. 259
hyperditungstate, 11. 836
hyperiridite, 15. 756
hyperoxypertitanate, 7. 65
hypertungstate, 11. 836
� hypoantimonate, 9. 437
-�� hypoborate, 5. 38, 12O
-�-� hypobromite, 2. 269
hypoiodite, 2. 269
hypomolybdatomolybdate, 11. 604
hypomolybditoperitarnolybdato, 11.
593
-� hyponitrite, 8. 411
hyponitritosulphate, 8. 688
hypophosphate, 8. 935
hypophosphite, 8. 882
hypophosphitomolybdate, 8. 888
hypophosphitotungstate, 8. 888
hyporuthenite, 15. 517
hyposmato, 15. 728
hyposulphite, 10. 182
hypovanadato-vanadatotungstate, 9.
793
hypovanadous sulphate, 9. 818
icosihydrodecaselenitohexavanadate,
10. 835
imidomolybdate, 8. 267
imidomonosulphonate, 8. 647
imidosulphinite, 8. 646
iodate, 2. 332
hydrated, 2. 335
iodatophosphate, 2. 851
iodatosulphate, 2. 691
iodide, 2. 596 ; 11. 368
impurities, 2. 598
properties, chemical, 2. 605
physical, 2. 598
X-radiogram, 1. 638
� iodoarsenite, 9. 256
� iodoaurate, 3. 6IO
� iodobisarsenite, 9. 256
� iodochromate, 11. 429
� iodoiridate, 15. 779
� iodopalladite, 15. 681
GENERAL INDEX
isopropylstannonate, 7. 410
isotetrahydroborododecatungstate, 5.
HO
(di)hexasulphate, 5. 658
(di)octosulphate, 5. 658
nitrate, 5. 67O
orthophosphate, 5. 675
selenate, 10. 872
sulphate, 5. 658
sulphite, 10. 302
� dinitritodinitrate, 7. 872
dioxychromate, 11. 304
heptanitrite, 8. 498
heptapyrophosphate, 7. 880
hydroxynitrilodisulphonate, 8.
678
molybdato, 11. 569
nickel nitrite, 8. 512
� nitrilotrisulphonate, 8. 669
octonitrilotetranitrate, 7. 872 ; 8.
498
orthophosphate, 7- 876
� orthosulphoantimonite, 9. 549,
552
pyrophosphate, 7. 880
tetranitrite, 8. 498
trithiosulphate, 10. 552
6. 608
hexanuotetraluminotrimesosili
cate, 6. 608
molybdato, 11. 558
silicate, 6. 337
� sulphate, 2. 687
sulphatochrornate, 11. 244
sulphite, 10. 260
tungstate, 11. 781
luteodivanodatodiphosphate, 9. 828
Potassium luteodivanadatophosphate, 9.
828
magnesium alloys, 4. 666
arsenate, 9. 179
heptahydrate, 9. 179
monohydrate, 9. 179
bromide, 4. 314
calcium sulphates, 4. 344, 345
carbonate, 4. 368, 369
chloride, 4. 307
chlorosulphate, 4. 343
chromate, 11. 276
dihydrate, 11. 276
hexahydrate, 11. 276
cobaltous sulphate, 14. 782
dihydrotriorthoarsenate, 9. 179
dimetaphosphate, 4. 395
disulphatochromate, 11�. 465
- ferrous sulphate, 14. 297
- fluoride, 4. 297
- fluosilicates, 6. 953
� hexadecaborate, enneahydrated,
5. 99
hexarsenate, 9. 179
hydrocarbonate, 4. 367
hydrodiorthoarsenate, 9. 179
dihydrate, 9. 179
� pentadecahydrate, 9. 179
pentahydrate, 9. 179
tetrahydrate, 9. 179
hydrophosphate, 4. 384
hydrosulphate, 4. 342
iodide, 4. 317
manganous sulphates, 12. 423
metasilicate, 6. 407
molybdate, 11. 562
nickelous sulphate, 15. 475
nitrite, 8. 489
nitrosylcyanide, 8. 427
orthopertantalate, 9. 914
para tungstate, 11. 818
perorthocolumbato, 9. 870
persulphate, 10. 479
phosphate, 4. 383, 384
selenate, 10. 864
diamminoamide, 8. 272
dodecachloride, 12. 379
hexachloride, 12. 38O
hexanuoride, 12. 347
octofluoride, 12. 347
orthosulphoantimonite, 9. 553
oxytetrafluoride, 12. 347
penterotetradecavanadate, 9. 791
selenatosulphate, 10. 730
selenide, 10. 799
sulphatoselenate, 10. 930
tetrahydrodihypophosphate, 8.
939
tr iter odecavanadate, 9. 790
INDEX 705
11. 669
pyrophosphate, 12. 457
octohydrato, 12. 457
selenate, 10. 878
mephite, 6. 2
mercurammonium hydroxy sulphonate,
8. 643
mercuriate, 4. 779
mercuria amidosulphonate, 8. 643
VOL. XVI.
sulphide, 4. 956
heptahydrated, 4. 956
monohydrated, 6. 956
pentahydrated, 4. 956
-hydratod, 4. 892
triiodide, 4. 929
hydrated, 4. 930
trinitrite, 8. 494
mercurous chromate, 11. 282
mesodistannate, 7. 417
metaborate, 5. 77
metabromoantimonato, 9. 497
metachloroantimonato, 9. 491
metachromite, 11. 197
metacolumbate, 9. 863
metantimonato, 9. 451
metaphosphato, 2. 867
motaphosphatometaborate, 5. 79
metaplumbate, 7. 695
metarsenite, 9. 119
metaselenoarsenate, 10. 874
metasilicate, 6. 333
dihydrated, 6. 334
hemihydrated, 6. 333
monohydrated, 6. 334
tetrahydrated, 6. 334
metasulfazate, 8. 675
metasulpharsonate, 9. 317
metasulpharsenatosulphomolybdate,
9. 322
motasulpharsenatoxymolybdato, 9.
331
metasulpharsonito, 9. 29O
metasulphazilate, 8. 68O
metasulphoantimonite, 9. 534
metasulphobismuthite, 9. 689
metasulphotetrantimonite, 9. 535
metasulphotetrarsenite, 9. 291
-� metasulphotriarsenite, 9. 291
metatantalate, 9. 901
metatetrarsenite, 9. 119
me t at i tana to, 7. 5O
tetrahydrated, 7. 51
metatungstate, 11. 824
octohydrate, 11. 824
pentahydrate, 11. 824
metavanadate, 9. 764
heptahydrate, 9. 765
methyl stannonate, 7. 4IO
molybdate, 11. 556
tetritatrihydrate, 11. 556
molybdatodecatungstate, 11. 796
molybdatopentatungstate, 11. 796
molybdatosulphate, 11. 658
molybdatotetratungstate, 11. 796
molybdatotrisulphate, 11. 658
molybdatotritungstate, 11. 596
molybdenum dichloride, 11. 628
. dioxytetrachloride, 11. 632
dioxy trichloride, 11. 632
GENERAL, INDEX
� monamidodiphosphate, 8. 71O
monamidophosphate, 8. 706
monobismuthide, 9. 635
monofluotrihydrorthophosphate, 8.998
monomercuride, 4. 1015
monopermolybdate, 11. 607
monoselenothiosulphate, 10. 925
monoselonotrithionate, 10. 927
-� - monostannide, 7. 345
monosulphide, 2. 622
hydrated, 2. 624
__ � . properties, chemical, 2. 627
physical, 2. 624
monothiophosphate, 8. 1060
monoxide, 2. 485
neodymium carbonate, 5. 666
� azide, 8. 355
cadmium nitrite, 8. 512
carbonate, 15. 486
chromato, 11. 313
� fiuozirconate, 7. 142
_ hexanitrite, 8. 511
hydroearbonate, 15. 486
hypophosphate, 8. 940
nitritobismuthite, 8. 512
nitrosylthiosiilphate, 10. 558
orthophosphate, 15. 495
orthosulphoantimonite, 9. 555
� penteroheptadecavanadate, 9.792
persulphate, 10. 481
phosphatohemipentamolybdate,
11. 67O
phosphite, 8. 92O
� selenate, 10. 888
selenatosulphate, 10. 930
sulphatofluoberyllate, 15. 478
sulphatoselenate, 10. 930
tetrafluoride, 15. 405
tetrasulphide, 15. 443
trichloride, 15. 419
physical, 2. 808
nitratoaurate, 8. 616
nitratoplumbite, 7. 865
nitratosilicate, 6. 345
nitratosulphite, 8. 692
nitratosulphotungstate, 11. 862
nitride, 8. 99
nitrilodiphosphate, 8. 714
nitrilodithiophosphate, 8. 727
nitrilomolybdate, 8. 267
nitrilotrisulphonate, 8. 681
� nitrite, 8. 473
� hemihydrated, 8. 474
n it ritodi chromato, 11. 476
nitritoporosmite, 15. 728
nitritoplatinite, 8. 518
nitritotrichromate, 11. 476
nitrodichromate, 8. 546
nitrohydroxylaminato, 8. 305
~ octobromodiplumbite, 7. 752
octobromotriplumbite, 7. 751
octodecamercuride, 4. 1014, 1015
octofLuodecavanadate, 9. 802
octofluodivanadate, 9. 802
octomolybdato, 11. 596
octopermanganite, 12. 276
octosulphate, 10. 447
octotungstate, 11. 830
orthoarsenate, 9. 154
�� orthoarsenite, 9. 117
orthochromite, 11. 197
orthocolumbate, 9. 863
orthoctovanadate, 9. 765
orthododecacolumbate, 9. 865
orthohexacolumbate, 9. 864
orthohexatantalate, 9. 902
orthopertantalate, 9. 914
hemihydrate, 9. 914
orthophosphate : normal, 2. 847
properties, chemical, 2. 849
physical* 2. 848
orthoselenoantimonite, i0. 834
orthosulpharsenate, 9. 316
orthosulpharsenite, 9. 290
orthosulphoantimonate, 9. 672
enneahydrate, 9. 572
GENERAL.
-� oxydiiodohexadecaantimonite, 9. 508
oxydodecafluodiarsenate, 9. 237
oxyfluoperplumbate, 7. 705
oxyfluopertitanate, 7. 69
oxyhexafluocolumbate, 9. 873
� oxyhoxafluoride, 9. 679
oxyhexafluotantalate, 9. 918
oxyhexafluotetratantalato, 9. 918
oxyhoxanitrifcoplatinite, 8. iylfi
oxy hexasulphopyro vanadate, 9. 817
oxyhydroheptafluotantalate, 9. 918
oxyhydrototraphosphide, 8. 833
oxyiodoantimonite, 9. 425, 585
oxynitrosotetrasulphite, 10. 326
oxyoetonitritotriplatinite, 8. 514
oxyorthovanadate, 9. 764
oxypentachlorotungstite, 11. 849
oxypentafluocolumbate, 9. 873
monohydrate, 9. 873
oxypentafluomolybdate, 11. 611, 612
oxyphosphatostannate, 7. 482
oxyphosphatotiranate, 7. 96
oxysulfazotinate, 8. 685
oxytetrabromide, 11. 638
oxytetrafluoarsenate, 9. 237
oxytriselenophosphate, 10. 932
oxytrisulpharsenate, 9. 330
oxytrisulphotungstate, 11. 860
ozonate, 1. 908
palladic hexanitrite, 8. 614
palladous iodonitrite, 8. 514
oxalatonitrite, 8. 514
tetranitrite, 8. 514
paramolybdate, 11. 585
parastannate, 7. 417
parasulphomolybdate, 11. 652
paratetrarsenite, 9. 119
INDEX 707
Potassium paratrititanate, 7. 51
paratrizirconate, 7. 135
paratungstate, 11. 816
decahydrate, 11. 816
henahydrate, 11. 816
tetradecahydrate, 11. 816
pentabarium octometasilicate, 6. 371
pen tabor ate, 5. 78
pentabromobismuthite, 9. 673
pentabromodiplumbite, 7. 751
pentabromoperrhodite, 15. 581
pentacalcium tetrafluohexametosilicate,
6. 369
pentachloroantimonite, 9. 48O
pentachloroaquoperrhodite, 15. 578
pentachlorobismuthite, 9. 666
hemipentahydrate, 9. 666
pentachlorobromobismuthite, 9. 673
pentachlorobromoplatinate, 16. 382
pentachlorodiplumbite, 7. 728
pentachloroferrate, 14. 102
pontachloromercuriate, 4. 856
dihydrated, 4. 856
� pentachloronitritoplatinato, 8. 524
pontachloroperrhodite, 15. 578
__ dihydrate, 15. 578
monohydrate, 15. 578
87O
pentaiodobismuthite, 9. 677
pentaiodonitritoplatinate, 8. 524
pentamercuride, 4. IO15
pentamolybdato, 11. 593
pentamolybdatodisulphite, 10. 307
pentanitratothallate, 5. 477
pentapermanganite, 12. 275
pentaphosphide, 8. 834
pentaselenatodiarsenate, 10. 875
tetradecahydrated, 6. 337
pentasulphide, 2. 63O, 636
pentasulphocuprite, 3. 227
pentatantalate, 9. 902
pontathionate, 10. 627
pentatungstate, 11. 828
penterotetradecatantalate, 9. 901
pentoxydifluopernolybdate, 11. 615
pentoxyfluodioolumbate, 9. 873
perborate hemiperhydrate, 5. 119
hemihydrated, 5. 119
percarbonate, 6. 833
perceric carbonate, 5. 666
perchlorate, 1. 361, 591 ; 2. 393
percobaltic enneamolybdato, 11. 597
perdecatungstate, 11. 836
708 GENERAL INDEX
phosphatohemiheptadeeamolvbdate,
pentanitrite, 8. 513
ruthenous disulphite, IO. 326
salts : extraction, 2. 437
438
wood ashes, 2. 437
wool fat, 2. 438
amidosulphonate, 8. 642
bromide, 8. 424
� carbonate, 8. 458
chromidodecamolybdate, 11. 6Ol
hyponitritosulphate, 8. 690
nitrate, 8. 48O
nitrite, 8. 484
octothioBtilphate, 10. 539
orthosulphoantimonite, 9. 542
silicododecamolybdate, 6. 87O
sulphate, 8. 454
sulphide, 8. 447
sulphite, 10. 28O
tetrathiosulphate, 10. 539
tritamminothiosulphate, IO. 539
sodide, 2. 48O
sodium alloys, 2. 480
-state, 9. 132
barium calcium carbonate, 3. 840
calcium carbonate, 3. 845
trimetasilicate, 6. 372
carbonate, 2. 769 ^
chlorosulphate, 2. 691
chlorothiosulphate, 10. 529
chromate, 11. 258
deuterohexavanadate, 9. 766
dimetaphosphate, 2. 877
dinitratoimidodisulphonate, 8.
653
ferrous titanium orthosilicate, 6.
843
heptasulphatoteti'aplumbite, 7.
821
hexavanadatohexatungstates, 9,
786
hydroarsenato. 9. 154
hydrorthophosphate, 2. 857
_ hydrosulphito, 10. 271
hydroxynitrilodisulphonate, 8.
677
hypophosphato, 8. 936
magnesium diorthoarsonate, 9.
179
sulphate, 4. 342
manganous permanganitomolyb-
date, 11. 573
mercuride, 4. IO15
molybdate, 11. 558
I orthohexacolumbate, 9. 865
. orthosulpharsenate, 9. 317
phosphatoctotungstate, 11. 872
_ � phosphatohemipentamolybdate,
11. 667
phosphatotungstate. 11. 873
pyrophosphate, 2. 867
sesquiphosphate, 2. 85O
silicate, 6. 337
I . _ simonytes, 4. 342
-sulphate, 2. 688
. _ sulphite, 10. 271
tetravanadatododeeamolybdate,
9. 784
thiosulphate, 10. 529
� � � � trihydrodiorthoarsenate, 9. 153
2 : 1-tungstate, 11. 782
solubility of hydrogen, 1. 308
stannate (a-), 7. 414
pentahydrato, 7. 415
tetrahydrate, 7. 415
trihydrate, 7. 415
stannate *(/3-), 7. 417
stannic amide, 8. 265
sulphoplatinite, 16. 394
stannite, 7. 391
stannous amide, 8. 265
stilbite, 6. 760
strontium arsenate, 9. 173
: cobalt nitrite, 8. 505
chromate, 11. 271
dimetaphosphate, S. 894
disulphato, 3. 806
hexametaphosphate, 3. 895
hydroxynitrilodisulphonate, 8.
677
_ imidodisulphonate, 8. 654
I nickel nitrite, 8. 512
71O GENEKAL, INDEX
-� pyrophosphate, 3. 892
tetrabromide, 3. 732
tetrachloride, 3. 719
tetrerotetradecavanadate, 9. 772
thiosulphato, IO. 544
trisulphate, 3. 806
subehloride, 2. 530
suboxide, 2. 485
sulfazidate, 8. 671
sulfazilate, 8. 685
sulfazinate, 8. 676
sulfazite, 8. 676
sulfazotate, 8. 675
�� sulphamidate, 8. 662
sulphate and sodium chloride, crystal
lization, 2. 689
occurrence, 2. 657
preparation, 2. 659
properties, chemical, 2. 672
physical, 2. 66O
sulphatohexanuodiantimonite, 9. 466
sulphatohypovanadate, 9. 818
sulphatoperiridite, 15. 784
� � sulphatophosphate, 8. 1071
� sulphatostannate, 7. 479
� sulphazite, 8. 680
sulphazotate, 8. 673, 674
sulphide, 11. 368
aulphimide, 8. 663
sxilphimidodiamide, 8. 665
-� tetrafluohexavanadate, 9. 802
tetranuohypovanadate, 9. 798
tetrafluotrioxypertungstate, 11. 84O
� tetrahydroarsenatododecamolybdate,
9. 211
tetrahydrodiarsenatoctodecatungstate,
9. 214
tetrahydrodiselenatouranate, 10. 877
tetrahy drophosphatohemipenatmolybdate,
11. 668
tetrahydrosulphitopyrosulphite, 10.
331
tetrahy drotriselenatourany luranate,
10. 878
tetrahydroxylaminotetramolybdate,
592
tetraiodoaluminate, 5. 328
tetraiodoantimonite, 9. 502
tetraiodobismuthite, 9. 677
tetraiodocarbonatoplumbite, 7. 854
tetraiododinitritoplatinate, 8. 524
tetraiodothallate, 5. 461
tetrametaphosphate, 2. 867
tetramidocadmiate, 8. 261
tetramidosulphonatoplatinite, 8. 645
GENERAL. INDEX
tetranitratoenneafluotriantimonite, 9.
466
tetrajaitritodiamminocofoaltiate, 8. 509
tetrarxitritoplatinite, 8. 514 ; 16. 322
tetrantimonate, 9. 443
tetraphosphatocuprate, 3. 290
tetrarsenido, 9. 61
totraselenide, 10. 768
tetrasUicate, 6. 328
tetrastannide, 7. 345
� ietrasulphammonate, 8. 668
tetrasulphatarsenate, 9. 334
tetrasulphatarsenite, 9. 333
tetrasulphide, 2. 630, 634
tetrasulphocuprate, 8. 228
tetrasulphothallato, 5. 464
tetratellurate, 11. 92
tetratellurite, 11. 79
tetrathionate, 10. 617
tetrauranate, 12. 67
� tetrorodocavanadate, 9. 765
tetroxide, 2. 485, 491
tetroxydisulphatodivanadate, 9. 825
thallate, 5. 435
enneachloride, 7. 235
enneafluoride, 7. 227
-_ henasulphate, 7. 247
hexachloride, 7. 235
-� hexamioride, 7. 228
_ hoxanitrate, 7. 251
hexasulphate, 7. 247
hydroxy chloride, 7. 232
hydroxy sulphite, 10. 303
orthophosphate, 7. 252
pentacarbonate, 7. 249
pentachloride, 7. 235
pentafluoride, 7. 228
pentanitrate, 7. 251
phosphate, 7. 253
tetrasulphate, 7. 246
trihydrodecanitrate, 7. 251
trisulphate, 7. 247
titanic sulphate, 7. 94
titanidodecamolybdate, 11. 600
titanium carbonate, 7. 96
titanous alum, 7. 93
titanyl sulphate, 7. 95
trialuminium trimesotrisilicate, 6. 665
triamidocalciate, 8. 26O
triamidocuprite, 8. 259
hydrate, 9. 431
triazoxnonosulphonate, 8. 684
triboratotetralurninotetraorthosili
cates, 6. 742
tribromide, 2. 587
tribromocuprite, 3. 195
tribromoplumbite, 7. 752
monohydrate, 7. 752
_ tritahydrate, 7. 752
tribromostannite, 7. 453
tribromotriiodobismuthite, 9. 679
tribromotrinitritoplatinate, 8. 524
tribromotrisodoantimonite, 9. 511
tricadmium sulphate, 4. 638
tricarbonatodiphimbite, 7. 854
trichloroacetonitrile, 16. 274
trichlorobromoantimonite, 9. 511
trichlorocuprate, 3. 187
trichlorocuprite, 3. 163
trichlorodibromide, 9. 673
trichloroferrite, 14. 32
trichloromagnesiate, 4. 307
trichloromercuriato, 4. 856
monohydrated, 4. 850
trichloroplumbite, 7. 729
tritahydrate, 7. 729
trichlorostannitc, 7. 432
trichlorotribromoantirrionite, 9. 5IO
uses, 2. 47O
tritabismuthide, 9. 635
� vanadatophosphate, 9. 828
tritadibismuthide, 9. 635
tritantimonide, 9. 403
_. tritaphosphide, 8. 834
vanadyl disulphate, 9. 824
tritarsenide, 9. 65
tnterodeoavanadatc, 9. 765
vanadyltrifluoride, 9. 8OO
triterohexacolumbate, 9. 864
vanadylpentafluorido, 9. 799
tritorohexavanadate, 9. 765
hexahydrato, 9. 765
sulphate, 5. 682
monohydrate, 9. 765
� pontahydrata, 9. 765
arsenate, 9. 182
carbonate, 4. 648
trititanyl pentasulphato, 7. 95
imidoamido, 8. 261
848
ultramarine, 6. 589
octohydrotetrahypophosphate, 8.
uranate, 12. 63
938
uranium hydroxydisulphotetraura
orthosulphoantimonite, 9. 543
nate, 12. 97
hydroxyhydrodisulphotetraura
pentanitrite, 8. 49O
nate, 12. 97
oxyoctofluoride, 12. 77
phosphate, 4- 661
peroxyfluoride, 12. 79
pyrophosphate, 4. 663
red, 12. 97
selenate, 10. 866
fluoride, 12. 18
hexabromide, 12. 92
silicate, 6. 444
hexachloride, 12. 83
sulphate, 4. 637
hexahydrated, 4. 637 ,
GENERAL, INDEX
774
thiosulphate, 10. 546
tribromide, 4. 572
triiodide, 4. 583
trioxybischrornate, 11. 279
triterodecavanadate, 9. 774
zincate, 4. 528
zincide, 4. 667
zirconate, 7. 135
� trioxydisulphate, 7. 158
tungstates, 11. 792
nate, 8. 679
imidosulphonate, 8. 6.52
mercuric imidodisulphonate, 8. 658
� nitratohydroxynitrilodisulphonate, 8.
676
� nitritohydroxynitrilodisulphonate, 8676
silver trihydroxydiamidophosphate, 8.
704
sodium nitrilotrisulphonate, 8. 669
tetrametaphosphimate, 8. 718
873
si licodeca tungstate, 6. 882
silicododecatungstate, 6. 876
silicohenatungstate, 6. 882
(penta)potassiurn hydroxybisnitrilodisulphonate,
8. 674
(tetra)potassium cuprous trihydrotetrasvilphite,
10. 276
�ran.�-dichlorodiimidodisuIphonato
platinite, 8. 659
silicododecamolybdate, 6. 869
tetrahydrosilicodecatungstate, 6. 882
tetrahydrosilioododecatungstate, 6.
876
octodecahydrate, 6. 876
tridecahydrate, 6. 876
10. 276
hydroxynitrilodisulphonate, 8. 673
hydroxynitrilo-iso-disulphonato, 8. 679
imidodisulphonate, 8. 651
nitritohydroxynitrilodisulphonato, 8.
674
pentahydrosilicododecatungstate, 6.
876
Potential, chemical, 1. 1Ol 1
contact difference of, 1. IO16
differences, 1. 1015
difference, 1. 963
discharge, 1. 1031
electrode, 1. 1016
energy, 1. 696
of energy, 1. 727
thermodynamic, 1. 727
Potentials, ionizing, 4. 17
Poterite, 15. 649
Potosi silver, 15. 208
Potstone, 6. 43O
Potter's ore, 7. 781
Pottery, 6. 512
fossil, 6. 512
Poudre de Chartreux, 9. 513
Pouillet effect, 1. 495
Poulad janher der, 12. 853
Pound-calorie, 1. 699
Poussiere, 4. 411
Powder of Algaroth, 9. 504
Powellite, 11. 488, 56O, 678, 783
Praesoodidymium, 5. 5Ol
Praseodymia, 5. 625
projiaration, 5. 588
Praseodymium, 5. 5Ol
� ammonium carbonate, 5. 666
hexahydrated, 5. 645
caesium sulphate, 5. 658
carbide, 5. 873
carbonate, 5. 664
eerie sulphate, 5. 662
chloride, 5. 642
_ heptahydrated, 5. 642
hexahydrated, 5. 642
monohydrated, 5. 642
trihydrated, 5. 642
sulphate, 5. 658
-- preparation, 5. 59O
� properties, chemical, 5. 601
physical, 5. 591
-- rubidium nitrate, 5. 670
� selenite, 10. 831
� sesquioxido, 5. 625
� silicododecatungstate, 6. 88O
� silver tungstate, 11. 791
� sodium carbonate, 5. 6HIi
� sulphatocerate, 5. 660
� sulphide, 5. 648
� triuranate, 12. 67
� tungstate, 11. 791
� uranyl sulphite, 10. 305
Precipitation, 3. 546
colloids, 3. 542
Hardy's rule, 8. 543
Schulze's rule, 3. 543
fractional, 5. 538
ionic theory, 1. 996
rhythmic, 1. 537
Predazzite, 4. 371
Pregrattite, 6. 607
Prehistoric chemistry, 1. 19
Prehnitoid, 6. 763
Preslite, 7. 877
INDEX
of liquids, 1. 841
normal, 1. 149, 161
of surface, 1. 846
solution, 1. 538, 539, 1Ol 7
electrolytic, 1. 1017
standard, 1. 149, 161
hypothesis, 1. 48
Primal element, 4. 1
Primaries, 4. 158
Primary X-rays, 4. 32
Princeite, 5. 89
Prince's metal, 4. 671
Principium spirituosum, 6. 1
Principle of least effort, 2. 146
reversibility, 1. 93
sulphurous, 1. 64
Print, 3. 412
Priorite, 5. 518 ; 9. 904 ; 12. 5
Prism powder, 2. 826
Prismatic habit, 1. 597
Prismatine, 6. 812
Probability, 1. 9O
Prochlorite, 6. 621, 622 ; 12. 53O
Prolectito, 6. 813
Promethians, 8. 1059
Promotors of catalysis, 16. 154
Properties, specific, 1. 84
Propezite, 3. 494
Propionic acid and hydrogen, 1. 303, 304
Propionylcholinechloroplatinato, 16. 312
Proplatinum, 15. 205
Proportion, laws of compound, 1. 100
Proportionality, law of, 1. 79
Proportions, law of definite, 1. 77
multiple, 1. 93, 96
reciprocal, 1. 97
Propyl orthosilicate, 6. 309
stannic bromide, 7. 455
iodide, 7. 463
stannonic acid, 7. 410
777
law, 1. 76
Prozane, 8. 329
Prussian blue, native, 14. 39O
Przibramite, 4. 409 ; 13. 877
Psaturose, 9. 54O
Pseudo-alums, 5. 354
argynim, 4. 4OO
carbon, 5. 721
Pseudoapatite, 3. 896
Pseudobiolite, 6. 609
Pseudoboleite, 7. 491, 743
Psoudobolite, 2. 15
Pseudobroskite, 7. 2, 59 ; 12. 53O
a-, 7. 6O
�-, 7. 6O
Pseudo-catalysis, 10. 673
Pseudocotunnia, 7. 729
Pseudocotunnite, 7. 491, 729
Pseudoeumidinium bromopalladite, 15. 677
picca, 12. 1
Pseudoisotopy, 4. 93
Pseudolaumontito, 6. 740
Pseudoleucite, 6. 651
Pseudolibethenite, 8. 289 ; 8. 733
Pseudomalachite, 8. 289
Pseudomendipite, 7. 491
Pseudomorphs, 1. 595
Pseudonatrolite, 6. 755, 768
Pseudonepheline, 6. 569, 570
Pseudoperoxides, 1. 958
Pseudophillipsite, 6. 736
Pseudopite, 6. 622
Pseudopyrophyllite, 6. 499
Pseudoscapolite, 6. 763
Pseudosmaragol, 6. 803
Pseudosommite, 6. 569, 570
Pseudosteatite, 6. 495
Pseudoternary system, 1. 524
Pseudotriphylite, 12. 463
Pseudotriplite, 2. 426
Pseudowavellite, 5. 366, 529
Psilomelane, 12. 15O, 265
Psimythite, 7. 852
Psittacinite, 9. 715, 778
Psittacinus, 9. 778
Pterolite, 6. 609
Ptilolite, 6. 748
Pucherite, 9. 589, 715
Puddle ore, 12. 53O
Puddled bars, 12. 637
Puddler's candles, 12. 636
Puddling, dry, 12. 636
angelicus, 9. 504
Carthusianorum, 9. 513
^ehrysoceraunius, 3. 582
"hypnoticus, 4. 943
substances, 1. 8O, 82
Purification gold, 3. 509
of gases by fractional solidification, 3.
172
Purpura, 9. 828
Purpurblende, 9. 578
Purpurea rubica, 7. 673
Purpureochromic dithionate, 10. 596
Purpurcovanadatophosphates, 9. 828
Purpurite, 12. 15O, 463, 530
Puschkinite, 6. 721
Pycnite, 6. 56O
Pycnophyllite, 6. 606
Pyrallolite, 6. 43O
Pyrargillite, 6. 812
Pyrargyrite, 3. 30O ; 9. 294, 343, 537
Pyrauxite, 6. 498
Pyrazinium pyrazinepentachloroplatinate,
16. 313
Pyreneite, 6. 921
Pvrgorn, 6. 817
Pyriaurite, 13. 895
Pyridine cerium sulphate, 5. 659
Pyritic smelting, 8. 23
Pyritolamprite, 9. 64
Pyroantimonic acid, 9. 442, 443
Pyroantimonite, 9. 577
Pyroantimonious acid, 9. 429
Pyroarsenic acid, 9. 14O
Pyroaurite, 4. 251, 376 ; IS. 53O ; 13. 916
Pyrobelonite, 7. 491 ; 9. 791
Pyrobenolite, 7. 491
Pyrobismuthous acid, 9. 650
Pyroboric acid, 5. 47
Pyrochlore, 5. 579 ; 7. 3, IOO ; 9. 839, 903
Pyrochloroantimonic acid, 9. 49O
Pyrochroite, 12. 150
Pyrochrolite, 9. 539
Pyrochrotite, 9. 539
Pyroclasite, 3. 866
Pyrocolumbate, 5. 516
Pyroconito, 5. 309
Pyrocrase, 9. 904
Pyroelectricity, 1. 648
Pyroomerald, 2. 3
Pyrogallol, 13. 615, 616
Pyroiodic acid, 2. 324
Pyrolusite, 5. 530 ; 12. 160, 265 ; 15. 9
Pyromelane, 6. 84O ; 15. 6
Pyromorphite, 2. 15 ; 7. 883, 896 ; 8. 733 ;
9. 261
Pyrope, 6. 714, 815
Pyrophanite, 7. 3, 56 ; 12. 150
Pyrophoric alloys, 5. 610
zinc, 4. 495
iron, 2. 768
Pyrophorus powders, 8. 1058
Pyrophosphates, 8. 975
Pyrophosphatotungstates, 11. 874
Pyrophosphodiamic acid, 8. 708, 717
Pyrophosphoric acid, 8. 948, 971
constitution, 8. 973
hydration, 8. 973
properties, chemical, 8. 975
physical, 8. 972
Pyrophosphorite, 3. 892
Pyrophosphorous acid, 8. 921
Pyrophosphoryl bromide, 8. 1036
chloride, 8. 1026
Pyrophyllite, 6. 498
pseudo, 6. 499
Pyrophysalite, 6. 56O
Pyroplumbio acid, 7. 685
Pyrorthite, 5. 509
Pyrosclerite, 6. 609
Pyroselenites, 10. 820, 822
Pyrosmalite, 2. 15 ; 6. 896 ; 12. 15O
Pyrosmargyd, 3. 693
Pyrostibite, 9. 577
Pyrostilpnite, 3. 300 ; 9. 343, 539
Pyrosulphamic acid, 8. 637
Pyrosulpharsenatosulphomolybdates, 9. 322
Pyrosulpharsenic acid, 9. 315
Pyrosulpharsenious acid, 9. 289
Pyrosulphates, 10. 440, 444
Pyrosulphites, 10. 327
Pyrosulphoantimonious acid, 9. 532
Pyrosulphoxylic acid, 10. 163
Pyrosulphuric acid, 10. 351, 357, 444
Pyrosulphurous acid, 1O- 327
Pyrosulphuryl chloride, 10. 678
Pyrotantalate, 5. 516
Pyrotelluric acid, 11. 89
GENERAL INDEX
Pyrotellurite, 11. 78
Pyrotellurous acid, 11. 77
Pyrotungstic acid, 11. 762
Pyrouranic acid, 12. 58
Pyrovanadio acid, 9. 753
Pyroxene, 6. 39O
ferrugineux, 8. 912
� monocliriic 6. 39O
rhombic, 6. 390
Pyroxenes, 6. 410, 818
zircon, 0. 857
Pyroxlerite, 12. 53O
Pyroxmangite, 6. 917 ; 12. 15O, 530
Pyroxone, 1. 946
Pyrrharsenifce, 9. 221
Pyrrhite, 5. 519 ; 9. 903
Pyrrholite, 6. 619
Pyrrhosiderite, IS. 877
Pyrrhotin, 14. 136
Pyrrhotite, 12. 53O ; 14. 137 ; 15. 9
nature of, 14. 137
Pythagoras, 1. 34
15, 4. 114
emanation, 7- 889
se,e Nitric
estimation in minerals, 4. 65
extraction of, 4. 60
V, 4. 115, 127
helium from, 4. 97
nitrate, 4. 93
nitride, 8. 103
occurrence, 4. 64
progenitors, 4. 118
properties, chemical. 4. 93
physical, 4. 90
radiations, analysis, 4. 80
Strutt's clock, 4. 84
sulphate, 4. 93
uranium ratio in minerals, 4. 67
Radelerz, 9. 55O
Raepperite, 12. 15O
Rauschgal, 9. 267
Rafaelite, 2- 15 ; 7. 491, 739
Raffinoradtjern, 12. 709
Raimondite, 14. 328, 333
RaIstonito, 2. 1 ; 4. 252 ; 5. 303, 309
Ramarite, 9. 777
Ramirite, 9. 715
Rammelsbergite, 9. 4, 81 ; 14. 424 ; 15. 6
Rammelsberg's theory mercury-nitrogen
compounds, 4. 785
Ramsayite, 6. 842
Ramsay's theory rotating electrons, 4. 186
Rancieite, 12. 234, 266
Raneierite, 12. 15O, 234, 266
Ranciorte, 12. 15O
Randite, 12. 5, 115
Ranite, 6. 573
Rankins' vapour-pressure formula, 1. 433
Ransomite, 14. 328, 347
Rapid steels, 18. 634
Rapidolito, 6. 762
Rare earth calcium columbatotantalate, 9.
904
ferrous uranyl pyrocolumbatotantalate,
9. 906
- orthocolumbatotantalate, 9.
904
� fluosilicates, 6. 954
� electronic structure, 5.
618
position in periodic table, 5.
612
valency, 5. 612
minerals, opening up, 5. 545
molybdatosulphites, 10. 307
oxalates, 5. 543
silicates, 6. 859
thiosulphates, 10. 549
Refractivity, 1. 673
Regent diamond, 5. 711
Regnolite, 9. 4, 324
Regula veneris, 3. 99 ; 9. 403
Regulus, 3. 23
antimonii jovialis, 9. 35O
lunaris, 9. 35O
martialis, 9. 350, 412
medicinalis, 9. 577
saturninus, 9. 35O
simplex, 9. 35O
stellatus, 9. 350, 355
venorus, 9. 35O
vulgaris, 9. 350
stellatus, 9. 340
Reichardite, 4. 321
Reinecke's salt, 11. 406
Reinite, 11. 678, 698 ; 12. 53O
Reinsch's test arsenic, 9. 39
Reisblei, 5. 714
Reiset's chloride, 16. 261
first base, 16. 239
Reissacherite, 12. 150, 267
Reissite, 6. 761
Rojalgar, 9. 267
Reluctivity magnetic, 13. 245
Remanence magnetic, 13. 246
Remingtonite, 14. 424, 808
Renardite, 12. 5
Reniforite, 9. 69
Rensselaerite, 6. 430
Roseau, 1. 624
Residual current, 1. 1030
Residues, theory of, 1. 219
Rosin blende, 4. 408
Resina cupri, 3. 157
Resistance, chemical, 1.
293
electrical, 1. 963
passive, 1. 152
specific electrical, 1. 978
Rostormelite, 6. 5OO
Retentivity, magnetic, 13. 246
Retger's colour test mixed crystals, 1. 660
law mixed crystals, 1. 66O
Reticular density, 1. 628
Retinalite, 6. 422
Retort charcoal, 5. 748
Retorts, zinc, 4. 413
Retzian, 5. 53O ; 9. 223 ; 12. 15O
Reuschgeel, 9. 267
Reverberatory furnace, 3. 25
smelting, 3. 23
Reversed spectrum, 4. 6
Reversibility, principle of, 1. 93, 706
Reversible cells, 1. 1021
colloid, 1. 771
processes, 1. 717
steels, 15. 264
Rewdanskite, 15. 6
Hey, J"., on calcination, 1. 56
Rezbanyite, 7. 491 ; 9. 549, 589, 694
Rhabdite, 8. 860 ; 12. 528, 530
Rhabdophane, 5. 529
Rhaetizite, 6. 458
Rhagite, 9. 5, 198, 589
Rhaphanosmite, 10. 788
Rhaphilite, 6. 821
Rhapidolite, 6. 762
Rhases, A. M., 1. 41
Rhenates, 12. 478
Rhenic acid, 12. 478
anhydride, 12. 478
Rhenium, 12. 465
analytical reactions, 12. 472
atomic -weight, 12. 472
bromide, 12. 479
compounds, 12. 472
dioxide, 12. 478
dihydrate, 12. 478
diselonide, 12. 48O
disulphide, 12. 480
electronic structure, 12. 472
herniheptasulphide, 12. 48O
hoptachloride, 12. 479
hoptaselenide, 12. 481
heptasulphide, 12. 48O
hoptoxido, 12. 473
hoxachlorido, 12. 479
iodide, 12. 479
iridium alloy, 15. 750
isolation of, 12. 467
isotopes, 12. 472
� occurrence, 12. 466
pontoxide, 12. 477
perrhenate, 12. 478
platinum alloy, 16. 216
potassium bromide, 12. 48O
chloride, 12. 480
iodide, 12. 480
properties, chemical, 12. 471
physical, 12. 469
rhenate, 12. 478
rhodium alloys, 15. 565
sulphate, 12. 479
tetrachloride, 12. 479
tetroxide, 12. 472
thallous bromide, 12. 480
chloride, 12. 480
trioxide, 12. 477
trisulphide, 12. 480
tritaditungstide, 12. 472
tungsten allovs, 12. 472
Rheotan, 15. 21O, 313
GENERAL INDEX
chloropentarnminochloroplatinate, 15.
577
chloropentamminohydrosulphate, 15.
604 587
sulphate, 15. 587 chloropentamminohydroxide, 15. 677
� chloropentamminonitrate, 15. 59O
Rhodium dibromoquaterpyridinobromide,
16. 58O
dichloride, 15. 573
dichloroaquotrispyridine, 15. 576
dichlorobisdiaminodiethylaminohy
581
dichloroquaterpyridinechloride, 15.577
dichloroquaterpyridinechloroplatinate,
15. 577
dichloroquaterpyridinehydroxide, 15.
577
dichloroquaterpyridtnohydroperos
� hexathiocarbamidochlorodinitrate, 15.
59O
hydride, 15. 561
VOL. XVI,
15. 59O
587
nitritopentamminosulf>hate, 15. 587
occurrence, 15. 545
osmium alloys, 15. 697
oxides, 15. 569
oxyphosphate, 15. 591
chloronitrite, 8. 513
! hexanitrite, 8. 513
trisulphito, 10. 326
� preparation, 15. 546
properties, chemical, 15. 561
physical, 15. 553
rhenium alloys, 15. 565
rubidium alum, 15. 588
disulphate, 15. 588
ruthenium alloys, 15. 565
sesquioxide, 15. 569
sesquisulphido, 15. 585
silver alloys, 15. 564
chloride, 15. 579
sodium aquopentamminopyrophosphate,
15. 591
disulphate, 15. 587
hexamminopyrophosphate, 15.
591
hexanitrite, 8. 513
nitrate, 15. 59O
sulphite, IO. 326
solubility of hydrogen, 1. 306
sponge, 15. 551
sulphate, 15. 586
sulphates, 15. 586
sulphides, 15. 584
tetrabromide, 15. 581
totraohlorobispyridines, 15. 576
tetrafluoride, 15. 572
tetrahydroxide, 15. 571
thallous alum, 15. 588
disulphate, 15. 588
thiocarbonate, 6. 129
ammine, 6. 129
tin alloy, 15. 565
triaminocyclopentanobromide, 15. 58O
triamminotrichloride, 15. 576
tribromido, 15. 58O
dihydrate, 15. 58O
tribromotriamminobromide, 15. 581
3 A
GENERAL INDEX
587
trisaminopentanochlorido, 15. 576
- trisdiaminocyclopentanochloride, 15.
576
trisdiaminopentaneiodide, 15. 582
trisdiaminopontanobromide, 15. 580
trisdiaminopentanonitrate, 15. 589
Z-trisethylenediaminobromide, 15. 58O
ti'isethylenediaminochlorido, 15. 576
X-radiogram, 1. 641
blue, 6. 916
Rhodophyllite, 6. 622
Rhodotilite, 6. 894
Rhodusite, 12. 530
Rhonitc, 6. 845 ; 12. 53O
Rhombarsenito, 0. 94
Rhombic system, 1. 619
Rhomboclase, 12. 53O ; 14. 318
Rhonite, 7. 3
Rhotanium, 15. 647
Rhombolite, 9. 343
Rhyacolite, 6. 662
Rhythmic crystallization, 1. 599
precipitation, 1. 537
Ribbon mica, 7. 613
Ricardite, 11. 2
Richardite, 2. 430 ; 3. 7 ; 11. 42
Richards' formula, 1. 835
Richellite, 12. 530 ; 14. 412
Richmondite, 5. 362 ; 9. 554
Richterite, 6. 391, 916 ; 12. 150, 53O
soda, 6. 916
Richters law, 1. 79, 97
Ricolite, 6. 422
Riemannite, 6. 497
Rionite, 9. 291
Ripidolite, 6. 621
Ripley, Q., 1. 48
Riponito, 6. 763
Risigallo, 9. 267
RisOrite, 5. 517 ; 7. 3 ; 9. 904
Risorite, 9. 839 ; 12. 6
Rittingerite, 9. 319
River-water, 13. 608
Riversideite, 6. 359
Rivotite, 9. 343, 437
Roast chloridizing, 8. 31, 306 ; 4. 415
sulphatizing, 3. 30, 306
Roaster acid, 2. 73O
smelting, 3. 25
Roasting blister, 3. 25
Robertson's formula, 1. 835
Robin's law, 2. 146
Rocca, 5. 148
Roche alum, 5. 148
Rochelle salt, 3. 12O
Rock alum, 5. 148
winning, 2. 525
Rodtguldenerz, 9. 294
Rooblingite, 6. 89O ; 7. 491, 821
Roemerite, 12. 53O ; 14. 319, 328, 350
Rontgen rays, 4. 31
Roepperito, 6. 386, 909 ; 12. 433, 530 ;
359
Roesslerite, 4. 252 ; 9. 176
ROssterite, 9. 5
Rottisite, 6. 932 ; 15. 6
Rogerium, 5. 504
Rogersite, 6. 516 ; 9. 839 ; 12. 5, 530 ;
308
Rogna, 3. 76
Roheisen, 12. 708
alums, 5. 149
cement, 6. 554
Romanechite, 12. 150, 266, 279
Rome, 1. 37
Romeite, 8. 623
Romeite, 9. 343, 432, 454
Rongalite, 10. 163
Rosagallum, 9. 267
Rosasite, 4. 646, 648
Roscherite, 5. 370 ; 14. 397
Roschgewachs, 9. 540
Roscoelite, 6. 605, 836; 9. 715; 12. 150
Rose, 5. 711
Rosein, 15. 235
Roselite, 4. 252 ; 9. 5, 230 ; 14. 424
Roselith, 3. 623
GENERAL. INDEX
317
Rubidium henadecachlorotetramercuriate,
4. 857
monohydrated, 4. 857
henamolybdate, 11. 598
heptachlorodiantimonite, 9. 480
� heptachlorodimercuriate, 4. 857
dihydrated, 4. 857
heptafiuotantalate, 9. 917
heptafluozirconate, 7. 141
hexabromohypoantimonate, 9. 496
hexabromoiridate, 15. 777
hexabromoselenate, 10. 901
hexabromotellurite, 11. 104
hexabromothallate monohydrated, 5.
453
hexachlorobismuthite, 9. 667
hexachlorohypoantimonate, 9. 485
hexachloroindate, 5. 4OO
hoxachlorotellurite, 11. 102
hexachlorothallate, 5. 446
dihydrated, 5. 446
monohydrated, 5. 446
hexadecabromotriantimonite, 9. 496
hexadecachlorobismuthite, 9. 667
hexadecachlorotriantimonito, 9. 4SO
hexafluoaluminate, 5. 307
hexafluocolumbate, 9. 872
hexafluoplumbate, 7. 705
hoxahydroarsenatoctodecamolybdate,
9. 211
hexaiodotellurite, 11. 106
hoxanitritobismuthito, 8. 499
hexasulphide, 2. 631, 640
history, 2. 422
hydroarsenate, 9. 155
monohydrate, 9. 155
hydrocarbonate, 2. 774
���� hydrodifluodiselenate, 10. 903
hydronitrate, 2. 821
hydrorthophosphate, 2. 851
hydroparamolybdate, 11. 586
hydropentabromide, 11. 104
hydrophosphatotellurato, 11. 121
hydroselenate, 10. 858
hydroselenito, 10. 823
hydrosulphatohydrotellurate, 11. 118
hydrosulphide, 2. 642
hydrosulphite, 10. 270
hydrotellurate, 11. 92
hydroxide, 2. 495
properties, 2. 5O0
hydroxypentachlorosmato, 15. 720
hydroxyperosmate, 15. 713
hypophosphate, 8. 936
hyposulphite, 10. 182
hypovanadous sulphate, 9. 818
iodate, 2. 333
iodide, 2. 596
properties, chemical, 2. 605
physical, 2. 598
iodoarsenite, 9. 257
iodoplatinate, 16. 390
iodostannate, 7. 463
iridium disulphate, 15. 785
langbeinite, 4. 339
lanthanum (hexa) henasulphate, 5. 658
hydronitrate, 5. 67O
nitrate, 5. 670
lead cobalt nitrite, 8. 506
trithiosulphate, 10. 552
\JTJU
monoxide, 2. 486
neodymium nitrate, 5. 671
nickel chromate, 11. 313
nitrate, 2. 802
properties, chemical, 2. 820
physical, 2. 808
nitratoaurate, 8. 6IO
nitride, 8. 99
�nitrite, 8. 478
� nitrosylchloroperruthenite, 15. 532
dihydrate, 16. 632
octodecachlorodiantimonitohypoanti
monate, 9. 485
octomoly bdate, 11. 596
octosulphate, 10. 448
oototungstate, 11. 83O
orthoarsenate, 9. 155
orthohexacolumbate, 9. 864
INDEX 725
� � oxypentabromocolumbate, 9. 88O
oxypentachlorocolumbate, 9. 879
oxypentachlorotungstito, 11. 869
� oxypentafluocolumbate, 9. 874
paramolybdate, 11. 586
paratungstate, 11. 817
pentaborate, 5. 78
pentabromoferrate, 14. 124
pentabromoindate monohydratod, 5.
4Ol
pontabromoperrhodite, 15. 581
pentabromotriplumbite, 7. 752
pentabromotungstito, 11. 854
pentaehloroaquoperrhodite, 15. 578
pentachlorodimercuriato, 4. 857
pentachlorodiplumbite, 7. 729
pen tachlorofer rate, 14. 103
pentachloroindato monohydrated, 5.
400
pentachloroperrhodite, 15. 578
pontachloropyridinoiridate, 15. 768
pentachlorothallate inonohydrated, 5.
446
pentachlorovanadite, 9. 804
pentaiodostannito, 7. 46O
pentarnminohemipeiitaphosphide, 8.
835
pentarnolybdatodisulphito, 10. 307
pentasulphide, 2. 631, 638
pontatungstato, 11. 829
percarbonate, 6. 84
perceric carbonate, 5. 667
perchlorate, 2. 395
perdecamolybdate, 11. 609
perhydroxycarbonate, 6. 85
periodates, 2. 407
permanganate, 12. 331
phosphatotetritaenneamolybdate, 11.
670
phosphide, 8. 835
potassium alloys, 2. 481
praseodymium nitrate, 5. 670
preparation, 2. 448
properties, chemical, 2. 468
physical, 2. 451
pyridinepentachloroplatinate, 16. 312,
' 324
726 LL INDEX
__ amminoheptathiosulphate, 10.
539
bromide, 3. 424
chloroaurate, 3. 594
cobaltic hexanitrites, 8- 504
nitrate, 3. 481
trithiosulphate, 10. 539
subchlorido, 2. 530
sulphate preparation, 2. 660
� properties, chemical, 2. 672
physical, 2. 66O
sulphatohypovanadite, 9. 818
� sulphatoperiridite, 15. 784
sulphatostannate, 7. 479
sulphatotitanite, 7. 93
sulphite, 10. 270
homialcoholate, 10. 270
sulphoniodide, 2. 607
� syngenite, 3. 810
tellurate, 11. 92
tetraborate, 5. 78
hoxahydrated, 5. 78
tetrabromopluznbite, 7. 752
tetrabromothallato xnonohydrated, 5.
452
tetrachlorobismuthite, 9. 666
tetrachlorodioxyruthenate, 15. 535
� tetrachloroferrite, 14. 32
tetrachloromercuriate, 4. 857
� tetrahydrated, 4. 857
tetrachloroplumbite, 7. 73O
hemihydrate, 7. 73O
tetraiodoplumbite, 7. 775
tetraiodothallate dihydrated, 5. 461
tetramereuride, 4. 1Ol 5
tetramolybdate, 11. 593
tetranitritodiamminocobaltiate, 8. 510
tetranitritoplatinite, 8. 519
titanous alum, 7. 95
pentachlorido, 7. 77
� sulphate, 7. 92
triamidosodiate, 8. 258
tribromide, 2. 587
trichloroferrite, 14. 32
trichloromercuriate, 4. 857
trichloroplumbite, 7. 73O
trichromate, 11. 351
tridecafluotantalate, 9. 916
tridecamolybdate, 11. 598
trifluorocuprates, 3. 156
trihydrodiselenite, 10. 823
triiodate, 2. 338 .
triiodide, 2. 609
triiodoplumbate, 7. 775
dihydrate, 7. 775
triiodostannite, 7. 46O
trimolybdite, 11. 589
vanaditodisulphate, 9. 820
tetrachloride, 4. 557
zirconium trioxydisulphate, 7. 158
(tetra)rubidium silicododecamolybdate, 6.
869
(tri)rubidium hydrosilicododecatungstate,
6. 897
Rubinblende, 9. 294
1007
Ruthenium, 16. 1, 3
ammines, 15. 543
analytical reactions, 15. 5IO
atomic disruption, 15. 513
528, 544
528
dichlorotetramminochloride, 15. 528
dichlorotetrapyridinechloride, 15. 528
528
hydroxytrichloride, 15. 535
iridium alloys, 15. 747, 75O
iron alloys, 15. 5IO
isotopes, 15. 512, 641
lead alloys, 15. 5IO
lithium alloy, 15. 510
monobromide, 15. 537
monochloride, 15. 522
monoselenide, 10. 802
monosilicide, 6. 213
monotelluride, 11. 65
monoxide, 15. 513
nickel alloys, 15. 5IO
nitrosylbromobisethylenediamminobromide,
15. 538
nitrosylhydroxybisethylened iaminoiodide,
15. 539
nitrosylhydroxyethylenediammoamminoiodide,
15. 539
GENERAL, INDEX
Ruthenium nitrosylhydroxyethylenedianunobispyridinoiodide,
15. 539
nitrosylhydroxyhydroehloridobisethylenediaminochloride,
15. 532
nitrosylhydroxyhydrochlorobisethylenedianiminoiodide,
15. 539
nitrosylhydroxytetramminocarbonate,
15. 544
nitrosylhydroxytetranuninochloroplatinite,
15. 537
nitrosy lhy droxy tetramminodiohloride,
15. 537
nitrosylhydroxytetramminonitrate,
15. 544
nitrosylhydroxytetramminosizlphate,
15. 542
nitrosyliodide, 15. 539
� nitrosyliodobisethylenediarninobromide,
15. 539
nitrosyliodobisethylenediaminoiodide,
15. 539
� nitrosyltribromide, 15. 537
nitrosyltrichloride, 15. 528
monohydrate, 15. 528
pentahydrate, 15. 528
1033, 1035
pentaphosphoennoadecachloride, 8.
1016
phosphobromide, 15. 537
phosphochloride, 15. 524
platinum alloy, 16. 221
potassium dihydroheptanitrite, 8. 513
hexanitrite, 8. 513
oxydodecanitrite, 8. 513
pentanitrite, 8. 513
Rutherfordine, 12. 5
Rutherfordite, 5. 517 ; 7. 897 ; 0. 839, 904;
12. 113
Rutherford's atom, 4. 166
Rutile, 7. 2, 30
X-radiogram, 1. 641
Ryacolite, 6. 662
Saccharite, 6. 693
Sacondios, 7. 98
Sacrificial metals, 1. 1025
Satersbergite, 9. 73
Safflor, 14. 420
Safflorite, 9. 4, 77 ,- 14. 424 ; 15. 6
Saffra, 14. 420
Saffran, 14. 420
d'or, 8. 582
Spiessglanz, 9. 5
Safre, 14. 42O
Sagenite, 7. 2, 3O, 34
Sahlite, 6. 39O, 409
Sajji-mati, 2. 71O
Sal alembroth, 4. 849
amarum, 4. 321
.ammoniac, 2. 15 ; 8. 144
� ammoniacum, 8. 144
fixum, 3. 697
anglicum, 4. 249, 321
armeniacum, 8. 144
armeniacus, 2. 20
pellucens, 2. 522
� gemma, 2. 522
� lacustus, 2. 522
� marinus, 2. 522
� microcosmicum, 2. 874
� mirabile Olauberi, 2. 656
� muriaticurn, 2. 522
� petrae, 2. 42O
� philosopherum, 10. 331
� polychrestum glaseri, 2. 656
� prunella, 2. 656
� sapientiae, 4. 849
SaIa, A., 1. 51
Salaccio, 5. 51
Saldanite, 5. 333
Salicor, 2. 713
Salis natura, 2. 20
nitri, 8. 618
Salite, 6. 409
Salmite, 12. 15O
Salmonsite, 12. 530 ; 14. 411
Salt, 1. 389 ; 2. 521
Armenian, 8. 144
cake, 2. 657, 730, 731
cerebros, 2. 526
decrepitating, 2. 533
(element), 1. 34
fish, 2. 526
gardens, 2. 525
Olauber's, 2. 656
glaze, 6. 514
history, 1. 382, 384
hydratod, 1. 397
lick, 2. 522
meadows, 2. 525
Metal of, 2. 421
neutral, 1. 384
of Sylvius, 2. 42O
wisdom, 4. 849
pickling, 2. 807
ponds, 2. 525
prunella, 2. 656
solutions and gas solubility, 1. 534
springs, 2. 522
Sylvius' digestive, 2. 522
table, 2. 526
tetragenic, 4. 343
Saltpeter, 6. 497
Saltpetre, 2. 42O
baryta, 8. 625
� Bengal, 2. 808
wall, 3. 849
brornate, 2. 354
bromide, 5. 645
hexahydrated, 5. 645
bromoaurate, 8. 608
carbonate, 5. 664
English, 6. 514
Samirescite, 9. 867
Samiresite, 5. 519 ; 9. 839, 905 ; 12. 5
Sammet-blende, 12. 530 ; 13. 877, 886
Samoite, 6. 497
Sancy diamond, 5. 711
Sand-cast pig iron, 12. 596
Sandaraca, 7. 672, 673
Sandarach, 9. 1, 267
Sandbergite, 9. 4, 291
Sandstein biegsame, 6. 140
Sandstone flexible, 6. 14O
Sandy limestone, 3. 815
Sanguinite, 9. 294
Sanidine, 6. 662
habit, 6. 67O
Sanidinite, 9. 839
Sanies draconis, 4. 942
Sanitary ware, 6. 515
Sanoerysin, 10. 541
Saphir d'eau, 6. 8IO
Saphiros, 5. 247
Sapo vitriariorum, 12. 140
Saponite, 6. 432, 498
Sapphire, 5. 154, 247 ; 14. 42O
Oriental, 5. 247
Sapphirin, 6. 584
Sapphirine, 6. 813
Sapphiros, 6. 586
Sarawakite, 9. 343, 504
Sarcolite, 6. 752
du Vicontin, 6. 734
Sarcopside, 12. 530 ; 14. 396
Sardinian, 7. 803
Sardonyx, 6. 14O
Sarkinite, 9. 5, 218 ,- 12. 150
Sarpu, 3. 295
Sartorite, 7. 491 ; 9. 4, 299
Sasbachite, 6. 736
Sassolin, 5. 3, 49
Sassolite, 5. 3, 49
Satan, fiery, 9. 341
Satellites of spectrum, 4. 7
Satin spar, 3. 761, 814
white, 5. 29O
Saturated compounds, 4. 191
Saturation, 1. 384
capacity, 1. 224
Saturnian atom, 4. 165
Saturnism, 7. 589
Saualpite, 6. 719
Sauces, 13. 616
Saulesite, 6. 933
Saussurite, 6. 693
Savite, 6. 653
Savon des verriers, 12. 140
Saynite, 9. 589, 696 ; 14. 424 ; 15. 6, 447
Scacchite, 6. 408 ; 12. 150, 348
Scsechite, 2. 15
Scandia, 5. 498
Scandium, 5. 480
sulphate, 5. 492
weight, 6. 487
bromate, 2. 353
bromide, 5. 49O
hexahydrated, 5. 49O
sesquihydrated, 5. 490
- carbonate, 5. 492
� chlorate, 2. 353
chloride, 5. 489
hexahydrated, 5. 490
sesquihydrated, 5. 490
chloroaurate, 8. 595
extraction, 5. 482
fluoride, 5. 488
fluosilicate, 6. 954
halides, 5. 488
history, 5. 480
hydrazine sulphate, 5. 492
hydroxide, 5. 488
hydroxynitrate, 5. 493
hydroxythiosulphate, 10. 546
iodate, 2. 353
isotopes, 5. 487
nitrate, 5. 493
nitride, 8. 114
� occurrence, 5. 480
orthoborate, 5. 104
orthodisilicato, 5. 482 ; 6. 859
oxide, 5. 488
oxynitrate, 5. 493
� oxysulphate, 5. 491
- porchlorate, 2. 402
- phosphate, 5. 493
sulphate, 5. 492
solubility of hydrogen, 1. 307
sulphate, 5. 491
dihydrated, 5. 491
hexahydrated, 5. 492
pentahydrated, 5. 491
tetrahydrated, 5. 491
sulphide, 5. 491
sulphite, 10. 302
sulphuric acid, 5. 491
trihydrosulphate, 5. 491
Scapolites, 6. 762
Scarboroite, 6. 497
Scattering X-rays, 4. 34
Schabasite, 6. 729
Schafarzikite, 8. 919 ; 12. 530
Schaffuerite, 9. 777
Schalenblende, 4. 408
Schalenmarcasite, 14. 218
Schallerite, 6. 836
Schalstein, 6. 354
Schanyawskite, 5. 275
Schapbachite, 7. 491 ; 9. 589, 694
Scheelbleispath, 11. 792
Scheele's green, 9. 121
Scheelin calcaire, 11. 674
X-radiogram, 1. 642
Soheelitine, 11. 792
Scheelium, 11. 674
Scheelocher, 11. 753
Scheelspath, 11. 674
Schefferite, 6. 390, 396 ; 12. 150
GENERAI, INDEX
Scherbenkobold, 9. 2, 3
Schertelite, 4. 385
Scheslerz, 11. 674
Schilfglaserz, 0. 551
Schiller, 6. 395
spar, 6. 392
Schillerstein, 6. 392
Schirlkobelt, 9. 3
Schirmerite, 7. 491 ; 9. 695
Schirmetite, 9. 589
Schist talc, 6. 430
Schistos, 13. 885
Schizolite, 6. 9OO
Schlippe's salt, 9. 570
Schlorlomite, 7. 3
Schmelzstein, 6. 763
Schmiedeison, 12. 709
Schmollnitzite, 14. 251
Schneebergite, 9. 343, 454
Sehneiderite, 6. 738
Schonherr's furnace, 8. 375
Schonite, 2. 43O, 657 ; 4. 252, 338, 340 ; 7. 897
Schoepite, 12. 5, 59
Schorl, 5. 4 ; 6. 74O, 821
� Hungarian rod, 7. 1
rouge, 7. 3O
Sehokoladenstein, 12. 433
Schomolnokite, 14. 245
Schorl, 6. 821
blanc, 6. 663
cruciforme, 6. 909
indigo blue, 7. 3O
octahedral, 7. 30
rayonnante en gouttiero, 6. 840
Schorlite, 6. 56O
Schorlomite, 6. 714, 836
Schreibersite, 8. 86O ; 12. 528, 531
Sohriftellur, 11. 1
Schrifterz, 11. 1, 47
Schrifttellur, 11. 47
Schrockingorite, 12. 115
Schrockingite, 12. 5
Sehrotterite, 6. 497
Schuchardtite, 6. 624 ; 12. 531 ; 15. 9
Schultenite, 9. 193
Schulzenite, 14. 424
Schulze's rule precipitation colloids, 3. 543
Schumann's waves, 4. 8
Schungite, 5. 718
Schurl, 6. 74O
Schutzkolloide, 3. 547
Schwartzembergite, 2. 17 ; 7. 491, 768
Schwartzite, 9. 291
Sohwarzbraunsteinerz, 6. 896
Schwarze SaIz, 14. 672
Schwarzerz, 9. 291, 54O
Schwarzgulden, 9. 540
Schwarzite, 9. 4
Schwarzspiessglanzerz, 9. 550
Schwatzite, 4. 697
Sohwazite, 9. 4
Schwofel, 10. 1
Schwein furt green, 9. 122
Schweissstahl, 12. 71O
Schweizerite, 6. 423
Schweizer's liquid, 8. 152
reagent, 3. 152
Schwerbleierz, 7. 681
Scientific chemistry, 1. 4
knowledge, 1. 8
Scleroclase, 9. 4, 301
Sclerodase, 9. 299
Scolecite, 6. 749
ammonium, 6. 75O
silver, 6. 75O
X-radiogram, 1. 642
Scolesite, 6. 575
Scolexerose, 6. 763
Scolopsite, 6. 584
plumbi, 7. 638
Scorodite, 9. 5, 224 ; 12. 531
Scorza, 6. 721
Scott's furnace, 8. 376
ammoniacum, 8. 144
de varee, 2. 713
febrifuge, 2. 522
gemme, 2. 522
sale, 5. 2
sodatif, 5. 2
urineux mineral, 5. 1
volatil de borax, 5. 2
Seladonite, 6. 92O
Selenates, 10. 853
Selenato di-iodic acid, 2. 363
oxidation, 5. 812
reduction, 8. 23
Seligmannite, 7. 401 ; 9. 4, 299
Sellaite, 2. 1 ; 4. 252, 296
SeIs mixtes, 2. 525, 657, 658
Selwynite, 6. 865
Semeline, 6. 84O
Semi-steel, 12. 711
whitneyite, 9. 62
Semseyite, 7. 491 ; 9. 343, 548
Senaite, 7. 3, 56 ; 12. 150, 531
Senarmontite, 9. 343, 421
Sendibogius, M., 1. 48
Seneca, A., 1. 38
Seng, 4. 399
Sensation, 1. 6
Senses, 1. 6
Separating element, 5. 541
Sepiolite, 6. 42O
a-, 6. 428
JS-, 6. 428
para, 6. 428
Sepiolitic acid, 6. 295
Serbian, 6. 865
Serendibite, 6. 462
Sericito, 6. 606
meta-, 6. 606
Sericitic mica, 6. 47O
Series of elements, 1. 255
even. 1. 255
odd, 1. 255
Serium and hydrogen, 1. 304
Serpentenstein, 6. 42O
Serpentine, 4. 251 ; 5. 531 ; 6. 420 ; 15. 9
noblo, 6. 422
blue, 13. 61
cold, 13. 61
hot, 13. 61
red, 13. 61
Shot metal, 7. 578
Shurl, 6. 740
Sialonite, 10. 694
Siberite, 6. 741
Sibiconice, 9. 435
Sical process hydrogen, 1. 284
Sickening of mercury, 8. 498
ozonizor, 1. 886
Sienna, 12. 531 ; 13. 887
Siglerite, 6. 663
Siglesite, 6. 663
Sliane, 6. 216
Silber, 3. 295
wismuthisches, 9. 694
Silberfahlerz, 9. 291
Silberglatte, 7. 644
Silberglanz, 3. 438
Silberglas. 3. 438
Silberwismuthglanz, 9. 691
Silox, 6. 14O
circonius. 7. 98
crucifor, 7. 766
Silfr, 3. 295
Silfver, 3. 295
Silica, 6. 236
alcogol, 6. 304
aleosol, 6. 304
etherogel, 6. 304
glass, 6. 288
glycerogel, 6. 304
hydrogel, 6. 290
hydrosol, 6. 291
occurrence, 6. 137
resinous, 6. 141
sulphatogel, 6. 304
uses, 6. 288
vitreous, 6. 288
GENERAL INDEX
Silica], 6. 233
acetate, 6. 233
bromide, 6. 233
chloride, 6. 233
formate, 6. 233
hydroxide, 6. 233
sulphate, 6. 233
constitution, 6. 308
nomenclature, 6. 308
temp, formation, 6. 314
acids, 6. 29O
nomenclature, 6. 308
Tschermak's, 6. 294
anhydride, 6. 307
Silicides, 6. 168
Silicifiuoridos, 6. 934
Silicipropionie acid, 6. 309
Silieite, 6. 693
Silicites, 6. 236
Silicium, 6. 136
Siliciumwasserstoff, 6. 216
Siliciuretted hydrogen, 6. 216
Siliooacetic acid, 6. 309
Silicoacetylene, 6. 226
Silicoaluminides, 6. 184
Silicoarsenides, 6. 188
Silieobenzoic acid, 6. 309
Silicobromoform, 6. 979
Silicobutano, 6. 224
Silicobutyric acid, 6-. 210
Silicochloroform, 6. 960, 968
Silicocyanogen, 8. 117
Silicoenneatungstic acid, 6. 881 �
anhydride, 6. 228
Silicohenatungstic acid, 6. 882
Silicohexane, 6. 225
Silicoiodoform, 6. 982
Silicol, 1. 284
Silicomanganese, 12. 194
Silicomesoxalic acid, 6. 229
Silicomolybdates, 11. 565
Silicomethane, 6. 216
Silicomethyl bromide, 6. 979
chloride, 6. 970
Silicomethylene bromide, 6. 979
chloride, 6. 670
weight, 6. 165
/8-, 6. 145, 157
bismuth alloys, 9. 639
borate, 5. 106
bromohydrides, 6. 979
bromoiodides, 6. 984
bromotriiodide, 6. 984
bronze, 7. 348
carbide, 5. 875
carboxides, 5. 884
chlorides, 6. 960
chlorobromides, 6. 980
chlorohydrides, 6. 967
chloroiodides, 6. 983
chlorotriiodide, 6. 983
chromium steels, 13. 616
cobaltic hexamminofiuoride, 14. 61O
colloidal, 6. 150
-� dicarbide, 5. 87O
dicarbonitride, 8. 115
-� dichlorodiiodide, 6. 983
dichlorosulphide, 6. 988
� dihydrotriimido, 8. 264
diimide, 8. 263
diimidodihydrochlorido, 8. 264
dioxide, 6. 236
_ preparation, 6. 237
mide, 6. 98O
hemihenadecamminotrichlorobromide,
6. 981
hemihenadecamminotrichloroiodide, 6.
983
� hemitrinitride, 8. 115
heptamminotetrabromide, 6. 978
hexaboride, 5. 27
hexaferrocarbide, 5. 884
hexamminotetrabromide, 6. 978
hexamminotetrachloride, 6. 965
hexanitridodichloride, 8. 116
history, 6. 135
hydrides, 6. 214
GENERAL
� octamrainototrachloride, 6. 965
oxycarbide, 5. 884
oxy chloride, 6. 974
oxyehlorides, 6. 973
oxydialuminate, 6. 455
-� oxydicarbide, 5. 884
oxyhexaluminate, 6. 455
oxyhydrides, 6. 227
oxysulphido, 6. 988
passive, 6. 146
pentamminodibromodichlorido, 6. 98O
pontamminodichloroiodide, 6. 983
pentatritacarbide, 5. 875
pentitarsenide, 6. 188
phosphate, 6. 835
phosphates, 6. 990
phosphide, 6. 188 ; 8. 847
phosphinotetrabromide, 8. 816
phosphinotetrachloride, 8. 816
phosphinotetrafluoride, 6. 938
potassioamidonitrido, 8. 264
preparation, 6. 145
properties, chemical, 6. 1 6O
physical, 6. 152
steel, 12. 752
subfluoride, 6. 924
suboxide, 6. 233
suboxides, 6. 227
sulphides, 6. 985
sulphocarbide, 6. 988
sulphodibromide, 6. 989
sulphodichloride, 6. 988
tetrabromide, 0. 977
tetrachloride, 6. 96O
properties, chemical, 6. 964
physical, 6. 963
tetranuoride, 6. 934
preparation, 6. 934
properties, chemical, 6. 937
physical, 6. 936
tetrahydrazinetetrachloride, 6. 965
tetrahydride, 6. 216
tetraiodide, 6. 982
tetramide, 8. 263
tetratritoxide, 6. 228
INDEX 735
X-radiogram, 1. 642
Silicone, 6. 231
Silicononane, 6. 216
Silico-oxalic acid, 6. 216, 229
Silicopentane, 6. 225
Silicophosgene, 6. 973
Silicophosphoric acid, 6. 835
Silicopropane, 6. 223
Silicopropionic acid, 6. 309
Silicopyrophosphoric acid, 6. 991
Silicopyrophosphoryl chloride, 6. 991
Silicospiegel, 12. 194
Silicothiourea, 6. 989
Silicotoluic acid, 6. 309
Silicotungstates, 11. 791
Silicozirconates, 6. 855
Silicyl, 6. 216
chloride, 6. 973
metaphosphate, 6. 835, 990
tetrahydrated, 6. 991
sulphide, 6. 988
Siline, 6. 216
Siliqua, 5. 712
Siliziumeisen, 6. 198
Sillimauito, 5. 155 ; 6. 455
Siloxanes, 6. 227
Siloxene, 6. 233
hexabromide, 6. 233
monobromide, 6. 233
moxioiodide, 6. 233
tribromide, 6. 233
Siloxide-T, 6. 288
Siloxide-Z, 6. 288
Silubr, 3. 295
Silumin, 13. 57O
Silundum, 5. 879
Silver absorption oxygen, 1. 371
alloys, 5. 232
dioxymolybdato, 11. 60O
nickel alloys, 15. 231
oxydodecamolybdate, 11. 600
� phosphate, 5. 37O
silicate, 6. 683
sulphate, 5. 341, 345
720
amidosulphonate, 8. 641
amminobromide, 8. 423
GENEBAL INDEX
amidosulphonate, 8. 642
chlorosulphite, IO. 28O
chromate, 11. 267
cobaltic hexanitrites, 8. 504
decahydropentaselenitododeca
11. 873
rhodium chloronitrate, 15. 59O
sulphite, 10. 28O
tetrahydroenneasulphite, 10. 280
thiosulphate, 10. 536
trithiosulphate, 10. 536, 545
analcite, 6. 683
and thallium, 5. 426
antimonatotungstate, 9. 459
antimonial, 3. 300
antimonito, 9. 432
antimonitotungstata, 9. 433
antimony sulphate, 9. 583
arsenatoctodeeamolybdate, 9. 210
arsenic alloys, 9. 64
arsenides, 9. 64
arsenite, 9. 122
colloidal, 9. 122
arsenochloride, 9. 244
atomic number, 8. 366
weight, 3. 363
azide, 8. 348
barium chloride, 3. 720
� phosphatododecatungstate, 11.
867
phosphatohenatungstato, 11. 868
trithiosulphate, 10. 545
bismuth alloys, 9. 635
thiosulphate, 10. 554
bismuthide, 9. 635
black, 3. 359
blende antimonial, 3. 300
arsenical, 3. 300
boride, 5. 24
borotungstate, 5. 110
Britannia, 8. 358
bromate, 2. 340
ammino-, 2. 341
bromatocarbide, 5. 855
bromide, 8. 418
colloidal, 3. 418
potassium, 3. 424
properties, chemical, 8. 421, 423
physical, 3. 419
rubidium, 8. 424
bromonitrato, 3. 468
bromoplatinate, 16. 379
' � ' bromosmate, 15. 724
nitrite, 8. 484
carbonate, 3. 456
colloidal, 8. 457
potassium, 8. 458
sodium, 3. 458
carbonyl, 5. 951
catalysis by, 1. 487
eerie dodecamolybdate, 11. 600
sulphate, 5. 662
cerium alloys, 5. 606
chabasite, 6. 683
China, 15. 209
chlorate, 2. 340
ammino-, 2. 34O
� chloroaurate, 3. 595
chlorocarbide, 5. 855
chlorodiamidotriamminochloride, 16.
308
chloroiridate, 15. 771
chloromercurite, 4. 812
chloronitrate, 8. 468
relations, 8. 617
lead, octoxyhenacosichloride, 7.
743
orthosulphotetrabismuthite,
9. 695
cyanodinitrate, 8. 469
cyanotetrazole, 8. 339
decametaphosphate, 3. 489
decapermanganite, 12. 276
decaphosphate, 8. 49O
dialuminyl orthosilicate, 6. 567
diamidodiphosphato, 8. 711
diamidophosphate, 8. 707
� diamminoehlorido, 3. 4OO
diamrninochloroplatjnate, 16. 327
diamminochlorosmate, 15- 72O
diamminohydroxide, 3. 382
� diamminoiodide, 8. 435
diamminometachloroantimonate, 9.
491
diamminometaiititnonate, 9. 454
d iaimninometasilicate, 6. 345
diamminomolybdate, 11. 559
diamminomtrate, 3. 478
diamminonitrite, 8. 483
diaraminopermanganate, 12. 333
� diamminoxido, 3. 382
diarsonatoctodecatungstate, 9. 214
diarsenide, 9. 65
dibromotetranitritoplatinate, 8. 524
dichloromercurite, 4. 812
� dihydroarsenato, 9. 164
dihydrophosphate, 3. 487
dihydropyrophosphate, 3. 488
dihydroxychloroplatinite, 16. 285
dihydroxydichloropalladate, 15. 673
dihydroxytetrabromoplatinate, 16. 381
dihydroxytetracbloroplatinate, 16. 334
clihydroxytetraiodoplatinate, 16. 391
diimidodiamidotetraphospliate, 8. 715
diiodonitritoplatinite, 8. 522
dimetaphosphate, 8. 488
dimolybdate, 11. 581
dinitrate, 3. 385, 484
dinitratocarbide, 5. 855
dinitratotriorthosilicate, 6. 345
dinitritohyponitrite, 8. 483
dioxide, 8. 383
dioxytellurate, 11. 93
diphosphate, 3. 49O
diphosphide, 8. 84O
diplatinous hoxasulphoplatinate, 16.
396
dipotassium cobaltic hexanitrite, 8.504
"- trihydroxy diamidophosphate, 8.
704
diselenide, IO. 771, 772
disodium imidodisulphonate, 8. 653
distillation, 8. 329
distribution, 3. 298
disulphatoaluminate, 5. 345
disulphatoaurate, 3. 615
VOL. XVI.
� Ziervogol's process, 3.
305
ferrate, 13. 934
ferric chloride, 14. 104
disulphide, 14. 193
hydrotetrasulphate, 14. 347
metaphosphate, 14. 415
. tetrahydrated, 3. 387
fluosilicate, 6. 95O
nuostannate, 7. 423
3 B
GENERAL, INDEX
Silver fluotitanate, 7. 72
frosted, 8. 359
fulminate, 4. 993
German, 4. 671
germanium lead sulphantimonite, 7.
255
amalgam, 4. 1029
copper alloys, 3. 576
monotelluride, 11. 49
palladium alloy, 15. 648
_ telluride, 11. 46
tellurobismuthite, 11. 62
halides, action light, 3. 408
hemialuminide, 5. 232
� hemiamminoiodide, 3. 434
hemiantimonide, 9. 405
hemiferrite, 13. 909
hemimanganeside, 12. 204
homipentaphosphide, 8. 84O
hemiphosphide, 8. 84O
hemitelluride, 11. 45
hemitrioxide, 3. 368, 385
heptabromoaluminate, 5. 326
heptapermanganite, 12. 276
heptitatetratelluride, 11. 44
hexabroraoselenate, 10. 901
hexahydroxyplatinate, 16. 246
hoxametaphosphato, 3. 489 ; 8. 989
sodium, 3. 489
hexamineselenato, 10. 861
hexamminochloroperiridite, 15. 765
hexamminochloroplatinite, 16. 282
hexasulpharsenide, 9. 306
hexasulphitocobaltate, 10. 315
hexitantimonide, 9. 404
history, 3. 295
horn, 3. 300, 390
hydrassinodisulphinate, 8. 682
hydrazinomonosulphonato, 8. 683
hydride, 8. 472
hydroarsenate, 9. 164
hydroarsenite, 9. 122
hydrocarbonate, 3. 456
hydroferrito, 13. 9IO
hydrofluorido, 3. 387
hydroiodide, 8. 432
hydromonamidophosphate, 8. 706
hydrophosphate, 3. 487
� hydrosols, 8. 561
hydrosulphate, 3. 452
hydrotellurate, 11. 93
hydroxide, 3. 380
hydroxychloroperiridite, 15. 76O
hydroxychloroplatinite, 16. 285
hydroxypentachloroplatinate, 16. 335
hypobromite, 2. 271
hypochlorite, 2. 271
hypoiodite, 2. 271
hyponitrite, 8. 412
hypophosphate, 8. 936
hypophosphite, 8. 883
�� hypophosphitotungstate, 8. 888
hypo vanadate, 9. 747
hypovanadatovanadate, 9. 793
imide, 3. 381 ; 8. 259
imidodiamide, 8. 665
ink, 6. 62O
iodide, 8. 426
alio tropes, 8. 427
caesium, 8. 433
lithium, 8. 433
potassium, 3. 432
preparation, 3. 426
I physical, 3. 427
rubidium, 3. 433
sodium, S. 433
Silver phosphatohemiheptadeoamolybdate,
11. 667
phosphatohemiheptatungstate, 11.
872, 873
phosphatohemipentarnolybdate, 11.
669
phosphatohenamolybdate, 11. 664
phosphatohexatungstate, 11. 872
phosphide, 8. 84O
phosphite, 8. 914
plating, 8. 359
platinic hydroxytriamidodiamminochloride,
16. 308
hydroxytriamidodiamminohydroxide,
16. 245
cositungstate, 11. 803
molybdate, 11. 576
platinosic sulphate, 16. 403
plat in ous ci�-sulphitodiarnminosulphite,
10. 321
trans -sulphitodiamminosulphite,
10. 321
platinum alloys, 16. 197
aluminium alloy, 16. 210
chromium alloys, 16. 216
cobalt alloys, 16. 219
copper alloys, 16. 2Ol
zinc alloy, 16. 207
gold alloys, 16. 205
aluminium alloy, 16. 210
copper alloys, 16. 205
iron alloys, 16. 219
manganese alloys, 16. 216
. mercury alloys, 16. 209
nickel alloys, 16. 22O
chromium alloy, 16. 22O
tin alloy, 16. 22O
oxychloride, 16. 335
thallium alloy, 16. 211
plumbite, 7. 668
potassium amide, 8. 259
amidosulphonate, 8. 642
amminoctothiosulphate, 10. 539
-�-� chromidodecamolybdate, 11. 6Ol
�� hyponitritosulphate, 8. 69O
nitrite, 8. 484
octothiosulphate, 10. 539
orthosulphoantimonite, 9. 542
silicododecamolybdate, 6. 87O
sulphite, 10. 28O
tetrathiosulphate, 10. 539
triamminothiosulphate, 10. 539
- potosi, 15. 208
- praseodymium tungstate, 11. 791
- properties, chemical, 8. 342
physical, 8. 321
- purification, 3. 314
Richards and Wells' process, 3.
308
Stas' process, 3. 308
- purple, 7. 418
- pyridinopermanganates, 12. 333
- pyrites, 14. 167, 193
- pyroarsenite, 0. 123
� pyrometaphosphate, 8. 490
pyrophosphate, S. 487
� sodium, 8. 488
- pyrosulpharsenatoxymolybdate, 0. 331
- pyrosulpharsenite, 9. 295
- pyrosulphate, 10. 446
766
tetrafluodioxytungstate, 11. 839
� tetraiodoplumbite, 7. 777
- tetramminocarbonate, 3. 458
tetramminochloroplatinate, 16. 327
tetramminochloroplatinite, 16. 282
tetramminochromate, 11. 266
tetramminodithionate, 10. 588
� tetrammino-orthophosphate, 8. 487
� tetramminopyroarsenite, 9. 123
- tetramminorthoarsenate, 9. 164
� tetramminoselenato, 10. 861
(hepta)silver tetrasulphuryltrimidodiamide,
8. 666
(hexa)silver tetrasuljjhuryltrimidodiamide,
8. 666
trimetaphosphimate. 8. 717
(octo)silver hexasulphosilicate, 6. 987
silicododecamolybdate, 6. 868
silicododecatungstate, 6. 877
tetrametaphosphimate, 8. 718
(penta)silver diammonium tetrasulphuryltriimidodiaraide,
8. 666
trihydroxydiamidophosphate, 8- 705
(tetra)silver hydrotrihy droxy diamidophosphate,
8. 704
imidodiphosphato, 8. 713
tetrahydrosilicododecamolybdate, 6.
87O
totrahydrosilicododecatungstate, 6.
877
totrametaphosphimato, 8. 718
trihydioxydiamidophosphate, 8. 705
(tri)silver ammonium trisulphuryldiimidodiamide,
8. 666
� imidodiphosphate, 8. 713
imidodisulphinite, 8. 646
imidodisvilphonate, 8. 653
pentahydrosilicododecamolybdate, 6.
87O
triamidodiphosphate, 8. 712
triliydroxydiamidophosphate, 8. 704
trimetaphosphimate, 8. 717
Silverine, 15. 210
Silvering of mirrors, 3. 359
Silvorite, 15. 208
Silveroid, 15. 208
Silverstrite, 8. 131
Silvialite, 6. 764
Similor, 4. 67
Simlaite, 6. 473
Simonyite, 4. 252, 326
Simonytos potassium sodium, 4. 342
Sineosite, 9. 826
Sines, Law of, 1. 670
Singles, 9. 350
Sinopische Earth, 6. 472
Sinopite, 6. 472
Sinopsis, 6. 472
Sinter calcareous, 3. 814
siliceous, 6. 141
Siphylite, 9. 9()4
Sipilite, 7. 185
Sipylite, 4. 206; 5. 517; 7. 100; 9. 839;
12. 6
Sirium, 5. 504
Sismondine, 6. 62O
Sismondite, 6. 620
Sitaparite, 12. 150, 280, 531
Size of molecules, 1. 752, 755
Sjogrufvite, 12. 531
Sjogrufvite, 9. 228
Skeleton crystals, 12. 886
Skemmatite, 12. 150, 266, 531 ; 18. 816, 923
Skidrl, 6. 74O
Skiorl, 6. 821
Sklerokles, 9. 3OO
Sklodoskite, 6. 883
Sklodowskite, 12. 5, 52
Skorl, 6. 821
Skogbolite, 9. 839, 909
Skotiolite, 6. 908
roverberatory, 3. 23
roaster, 3. 25
Smergel, 5. 247
Smidosjern, 12. 709
Smirgel, 5. 247
Smiris, 5. 247
Smith ore, 12. 531
Smithsonite, 4. 642 ; 6. 442 ; 12. 15O
Smithy scale, 13. 734
Smoke, 13. 613
Smokeless powders, 2. 829
Snarximite, 6. 396
Snellziinder. 8. 1059
Snow, 1. 464
white, 4. 507
Soamine, 9. 4O
Soap mountain, 6. 432
Soapstone, 6. 427, 430, 432
Sobralite, 6. 910
Society of Rosicrueians, 11. 4
Royal, 1. 5
Soda, 2. 421
alicante, 2. 713
alum, 5. 342
anorthite, 6. 698
berzeliite, 9. 222 ; 12. 15O
Bordeaux, 3. 267
caporcianite, 6. 740
cartagena, 2. 713
glauconite, 6. 92O
hornblende, 6. 916
leucite, 6. 647, 648, 649
lime, 3. 685
Malaga, 2. 713
mesolite, 6. 652
mesotype, 6. 652
mica, 6. 608
microclines, 6. 669
richterite, 6. 916
spodumene, 6. 643, 693
thomsonite, 6. 71O, 711
Sodaite, 6. 762
Sodalite, 2. 15 ; 6. 580, 582
acetato-, 6. 583
arsenate*-, 6. 583, 835
arsenito-, 6. 583, 835
borato-, 6. 583
bromato-, 6. 583
foromo-, 6. 583
calcium, 6. 583
brorno-, 6. 583
chlorato-, 6. 583
chromato-, 6. 583, 866
formato-, 6. 583
hydroxy-, 6. 583
hyposulphito-, 6. 583
iodato-, 6. 583
iodo-, 6. 583
load aulplio-, 6. 583
hthia, 6. 583
bromo-, 6. 583
sxilpho-, 6. 583
magnesia, 6. 583
metasilicato-, 6. 683
molybdato-, 6. 583, 871
nitrato-, 6. 583
oxalate-, 6. 583
perch lora to-, 6. 583
phosphato-, 6. 583
potash, 6. 583
molybdato-, 6. 583
phosphato, 6. 583
� sulphato-, 6. 583
sulpho-, 6. 583
selenato-, 6. 583
aelenito-, 6. 583
silver sulpho-, 6. 583
strontia, 6. 583
sulphito-, 6. 583
sulphohydrosulpho-, 6. 583
tin sulpho-, 6. 583
tungstato-, 6. 583
vanadato-, 6- 583
Sodamide, 8. 253
Sodammonium, 8. 244
Soddite, 6. 883 ; 12. 6, 52
Sodii hypophosphis, 8. 88O
Sodiophosphine, 8. 816
Sodium, 11. 78
a-, 2. 458
a-cupricarbonate, 8. 277
/?-oupricarbonate, 8- 277
acetylene carbide, 5. 847, 849
action on water, 1. 135
allylenide, 5. 85O
aluminato, 5. 288
aluminium alloys, 5. 229
amide, 8. 262
arsenitosilicate, 6. 835
carbonate, 5. 359
chlorotriorthosilicate, 6. 582
chromatosilicate, 6. 866
dimetasilicate, 6. 643, 644, 645
dodecamolybdate, 11. 599
. __ fluoarsenate, 9. 259
hydrocarbonatotriorthosilicate,
6. 580
hydrotrimotasilicate, 6. 651
hydroxyorthosilioate, 6. 574
hydroxysulphate, 5. 353
orthosiiicate, 6. 57O
INDEX 743
phosphatohemiheptadecamolybdate,
11. 667
phosphatomolybdate. 11. 663
pyrophosphate, 2. 876
pyrophosphatotungstato, 11. 874
744: GENERAL INDEX
Sodium ammonium sesquiphosphate, 2. 876
sulphate, 2. 706
sulphite, 10. 270
tetravanadatohextunolybdato, 9.
784
tetreroctocolumbate, 9. 865
tetrerotetradeoavanadate, 9. 765
trihydrodiorthoarsenate, 9. 153
triterodecavanadate, 9. 766
ammonoaluminate, 8. 262
crystallization, 2. 689
anhydro-iodate, 2. 337
antimonatotriiodobromide, 9. 512
antimonide, 9. 402
antimonysulphate, 9. 582
antimonyl tetraflluoride, 9. 503
aquochloroperiridite, 15. 765
aquodisulpbitotriamminocobal tate,
10. 318
dihydrate, 10. 318
� arsenoctoazidotriiodide, 9. 253
arsenohyposulphite, 9. 150
arsenothiosulphate, 10. 552
at. wt., 2. 47O
aurate, 3. 584
auric sulphite, 10. 281
auroaurichloride, 3. 589
aurochloride, 3. 589
aurous disulphite, 10. 280
677
� imidodisulphonate, 8. 655
nitrilotrisulphonate, 8. 669
� fran�-bischromatotetramminocobaltiate,
11. 311
� bismuth pyrophosphate, 9. 712
� thiosulphate, 10. 553
bismuthate, 9. 658
borate basic, 5. 66
boratofluoride, 5. 124
boride, 5. 23
borodimetasilicate, 6. 448
borosilicato, 6. 448
borylphosphate, 5. 147
borylsulphate, 5. 146
bromate, 2. 33O
bromide, 2. 577
physical, 2. 579
bromoaurate, 8. 607
bromobisarsonite, 9. 256
bromoiridate, 15. 776
bromopalladite, 15. 677
bromoperiridite, 15. 775
bromoplatinate, 16. 378
bromide, 4. 572
diorthoarsenate, 9. 183
dithiosulphate, 10. 547
hyposulphite, 10. 183
mercuride, 4. 1039
paratungstate, 11. 819
persulphate, 10. 479
phosphate, 4. 661
pyrophosphate, 4. 662
� sulphate, 4. 637
dihydrated, 4. 637
sulphide, 4. 604
sulphite, 10. 287
tetrachloride, 4. 554
Sodium cadmium tetraiodide, 4. 583
tetrametaphosphate, 4. 664
trimetaphosphate, 4. 663
triphosphate, 4. 664
trispyroarsenate, 9. 183
calcium alurninium sulphatotriorthosilicate,
6. 584
and aluminium fluorides, 5. 308
arsenate, 0. 173
carbonate, 8. 844
copper arsenate, 9. 174
dihydroxytetrasulphate, 3. 806
dimetaphosphate, 8. 894
disulphate, 3. 805
ferrous tetrantimonate, 9. 461
fluozirconatosilicate, 6. 857
hexafluoaluminate hydra ted, 5.
709
hexametaphosphafco, 3. 895
hexarsenate, 9. 173
hydrotrimetasilicate, 6. 367
irnidodisulphonate, 8. 654
magnesium fluoaluminate, 5. 309
manganese hydi'otrimetasilicate,
6. 9OO
raanganous ferrous phosphate,
12. 455
nitratodithiosulphate, 10. 544
octoxyfiuodicolumbate, 9. 877
� orthopertantalate, 9. 914
- paratungstate, 11. 818
- pentabromide, 8. 732
' pentametasilicate, 6. 366
pentasulphate, 3. 804
perorthocolumbate, 9. 87O
phosphate, 3. 878
pyroantirnonate, 9. 455
pyrophosphate, 3. 892
selenate, 10. 862
silioatozirconatocolumbates, 9.
867
tetrasulphate, S. 805
thiosulphato, 10. 544
titanium orthosilicate, 6. 844
zirconatosilicate, 6. 858
���� titanosiiicate, 6. 843
� trihydroxyzirconatomotasilicate ,
6. 856
trimetaphosphate, 3. 894
trisulphate, 3. 805
zirconatometasilicate, 6. 857
zirconium chlorotrimesotrisili
cate, 6. 857
chlorotriorthosilicate, 6. 857
columbatosilicate, 6. 858
carbamate, 2. 796
carbide, 6. 846, 847
carbonate ct-heptahydrate, 2. 753
/S-heptahydrate, 2. 753
ammonia process, 2. 737
and hydrogen, 1. 303
hydrates, 2. 751
in plant ashes, 2. 713
I^eblanc's process, 2. 728
origin natural, 2. 712
preparation, 2. 713
properties, chemical, 2. 767
physical, 2. 747
purification, 2. 724
Solvay's process, 2. 737
INDEX 745
726
chloropertitanate, 7. 83
chloroplumbite, 7. 727
316
hexamminohexasulphate, 10. 318
hexamminohypophosphate, 8.
939
hexamminopyrophosphate, 14.
858
hexanitrite, 8. 503
octamminohexasuIphite, 10. 318
oxyoctonitrite, 8. 503
10. 316
trisethylenediamineheptachloride,
14. 657
INDEX 747
dinitratobisethylthiolacetatoplatinite,
16. 41O
dinitrosylsulphite, 8. 434
dioxide, 2. 487
dicarbonate, 6. 86
tricarbonate, 6. 86
dioxydisulpharsenate, 9. 329
dioxypentasulphopyrovanadate, 9. 818
dioxytetrafluomolybdate, 11. 613
GENERAL INDEX
Sodium dioxytetraiodotrioarbonatotetra
plumbite, 7. 854
dipentitamercuride, 4-IO14dipentitaplumbide,
7. 606
dipermolybdate, 11. 607
dipertungstate, 11. 836
diphosphate, 2. 862
diphosphatoctovanadatopentadoca
molybdate, 9. 834
�� � d iphosphatoc to vanadatotetradecamolybdate,
9. 834
diphosphatodecavanadatotrideca
molybdate, 9. 834
diphosphatodistannate, 7- 482
diphosphatododecavanadatododeca
molybdate, 9. 833
diphosphatododecavanadatoonneamolybdate,
9. 834
diphosphatohexadeoavanadatodecamolybdate,
9. 834
diphosphatohexavanadatopentadecamolybdate,
9. 833
diphosphatoicosivanadatoctomolyb
date, 9. 834
diphosphatostannate, 7- 482
diphosphatotetradecavanadatohena
molybdate, 9. 334
diplatinous hexasulphoplatinate, 16.
395
diplumbide, 7. 607
dipotassium cobaltic nitrite, 8. 504
nitrilotrisulphonate, 8. 669
diselenide, 10. 768
diselenitopentamolybdate, 10. 837
diselenodisulphoarsenate, 10. 921
disilicate, 6. 336
hexadecahydrate, 5. 346
hoxahydrate, 5. 352
� disulphatochroiniate, 11. 454
� disulphatocuprate, 3. 256
- disulphatoindate, 5. 405
� disulphatoplumbite, 7. 821
- disulphatovanadite, 9. 820
ci�-disulphitotetramminocobaltate, 10.
317
� trans -disulphitotetrarnminocobaltate,
10. 318
disulphopersulphate, 10. 481
disulphuryliodide, 10. 690
ditelhiride, 11. 41
dithioaurate, 8. 612
dithiohydrophosphite, 8. 1063
dithionate, 10. 583
dihydrate, 10. 583
dithiophosphate, 8. 1068
ditritamercuride, 4. 1014
ditungstate, 11. 809
dodecahydrate, 11. 809
Hoxahydrate, 11. 809
� diuranate, 12. 65
� hexahydrate, 12. 65
fluodiorthoarsenate, 9. 258
fluoplumbite, 7. 703
fluoride, 2. 512
fluorophosphate, 2. 85O
fluorosulphate, 2. 691
fluoscandate, 5. 489
fluosilicate, 6. 947
fluostannate, 7. 423
fluotellurite, 11. 98
fluotitanate, 7. 70
fluozirconate, 7. 139
� hemipentaplumbide, 7. 607
hemiplumbide, 7. 606
hemistannide, 7. 345
hemithallide, 5. 425
hemitriplumbide, 7. 607
hemitritelluride, 11. 41
henafluodivanadite, 9. 797
heptabromoaluminate, 5. 326
heptafluotantalate, 9. 916
heptahydrotriphosphite, 8. 914
heptatungstate, 11. 83O
heulandite, 6. 757
hoxaborate, 5. 70, 76
hexabromoperrhodite, 15. 581
hexachloroaluminate, 5. 322
hoxaehlorobismuthite, 9. 677
hexachlorocalciate, 3. 719
hexachloroperruthenite, 15. 531
hexachlororhodate, 15. 579
octodecahydrate, 15. 679
hexachlorothallate dodecahydrated, 5.
445
hexadecamolybdate, 11. 603
hexadecapermanganite, 12. 275
hexafluoantimonate, 9. 468
hexafluoferrate, 14. 8
hemihydrate, 14. 8
hexafluoplumbate, 7. 704
hexafluotantalate, 9. 916
hexahydroarsenatoctodecamolybdate,
9. 211
hexahydrodiarsenitotetramolybdate,
9. 131
hexahydrotetraselenitohexavanadate,
10. 835
INDEX 749
11. 655
hydrotrioxysulpharsenate, 9. 328
hydrotrithiophosphate, 8. 1067
hydroxide, 2. 495 ; 13. 616
properties, 2. 500
750 GENERAL, INDEX
manganato-periodate, 2. 416
action, 2. 804
extraction, 2. 804
properties, chemical, 2. 82O
physical, 2. 808
X-radiogram, 1. 641
nitratoplumbite, 7. 864, 866
nitratosilicododecatungstate, 6. 875
nitratosulphate, 2. 691, 816
nitratosulphates, 8. 691
nitrilodithiophosphate, 8. 727
nitrilosulphonate, 8. 668
nitrilotrisulphonate, 8. 681
nitride, 8. 98
nitrite, 8. 473
nitritoperosmite, 15. 728
nitrohydroxy laminate, 8. 305
nitrosylchlororuthenate, 15. 537
nitroxyltrisulphonate, 8. 478
occurrence, 2. 423
octoborato, 5. 7O, 76
octomiotantalate, 9. 917
�� octofluovanadate, 9. 802
octomercuride, 4. 1013
octomolybdate, 11. 595
heptadocahydrate, 11. 595
octopermanganite, 12. 275
octorhodate, 15. 571
octosulphato, 10. 447
octotungstate, 11. 830
dodecahydrate, 11. 830.
octoxytriselenodiarsenato, 10. 874
orthoarsenate, 9. 15O
orthoarsonite, 9. 117
orthocolumbate, 9. 864
orthochromite, 11. 197
orthodecacolumbate, 9. 864
orthodiplumbate, 7. 698
orthododecacolumbate, 9. 865
dotricontahydrate, 9. 865
hemitricontahydrate, 9. 865
hexatricontahydrate, 9. 865
orthohexatantalate, 9. 9Ol
orthopertantalate, 9. 913
monohydrate, 9. 913
tetradecahydrate, 9. 913
orthophosphate normal, 2. 847
properties, chemical, 2. 849
physical, 2. 848
orthophosphite, 8. 912
orthoplumbate, 7. 698
orthoselenoantimonite, 10. 834
orthoselenoarsenate, 10. 874
orthosilicate, 6. 332
orthosulpharsenate, 9. 316
orthosulpharsenite, 9. 29O
orthosulphoantimonate, 9. 570
enneahydrate, 9. 670
orthosulphoantimonite, 9. 534
orthosulphotetrantimonite, 9. 534
orthotantalate, 9. 900
orthotetradecacolumbate, 9. 864
orthotetravanadate, 9. 763
orthotitanate, 7. 51
orthovanadate, 9. 761
decahydrate, 9. 761
761
heptahydrate, 9. 761
hexahydrate, 9. 761
tridecahydrate, 9. 761
orthozirconate, 7. 135
osmate, 15. 706
osmiamate, 15. 728
osmictetrasulphite, 10. 324
osmium dodecachloride, 16. 720
pentahydrate, 9. 817
palladium alloys, 16. 642
palladous tetrasulphite, 10. 325
paramolybdate, 11. 585
� pentachloromercuriate, 4. 854
� pentachloropyridinoiridate, 15. 768
pentafluoferrate, 14. 8
pentahydrodihypophosphate, 8. 934
pentahydroperoxytriorthoarsenate, 9.
15O
pentaiodide, 2. 610
pentamercuride, 4. 1013
pentametaphosphimate, 8. 718
pentamminobromoplatinate, 16. 378
pentamminochloroplatinate, 16. 325
pentamolybdatodisulphite, 10. 307
pentapermanganite, 12. 275
pentaplatinate, 16. 247
pentarsenatostannate, 9. 188
pentaselenide, 10. 768
pentasilicate, 6. 328
pentasulphate, 10. 448
pentasulphide, 2. 63O, 637
pentatantalate, 9. 901
heptahydrate, 9. 901
icosihydrate, 9. 9Ol
pentathionate, 10. 627
pentatungstate, 11. 828
pentauranate, 12. 68
� dodecahydrate, 12. 68
pentahydrate, 12. 68
pentoxytrisulphodiarsenate, 9. 33O
perarsenate, 9. ISO
decahydrate, 9. 151
Sodium perareenate dodecahydrate, 9. 161
hemienneahydrate, 9. 151
perborate, 5. 116
percarbonate, 6. 84
percerio carbonate, 5. 668
perchlorate, 2. 395
percobaltite, 14. 601
perdicarbonate, 6. 86
perdicbromate, 11. 359
perdi tungstate, 11. 835
perdiuranate, 12. 72
perferrate, 18. 936
perhydroxycarbonate, 6. 84
perhydroxyperdicarbonate, 6. 8&
perhydroxypermonocarbonate, 6. 85
periodates, 2. 406, 407, 409, 4IO
permanganate, 12. 302
permanganic tungstate, 11. 797*
permolybdate, 11. 607
permonocarbonate, 6. 85
permonostannate, 7. 413
permonosulphomolybdate, 11. 683
permonouranate, 12. 71
pentabydrate, 12. 71
perniclcelate, 15. 4Ol
perorthocolumbate, 9. 869
peroxyhypertitanate, 7. 65
peroxynitrate, 2. 816
peroxypentaftuocolumbate, 9. 874
peroxyportitanate, 7. 65
perphosphate, 8. 993
perrhenate, 12. 476
perrbodate, 15. 571
perruthonate, 15. 519
persulphate, 10. 476
pertetraborate, 5. 12O
pertbiocarbonate, 6. 13O
peruranato, 12. 72
pervanadate, 9. 795
perzirconate, 7. 132
phonylamide, 8. 257
phosphamido, 8. 834
phospha tocuprate, 8. 29O
phosphatodecarnoly bdate, 11. 663, 665
phosphatodocatungstate, 11. 869
phosphatododecatungstate, 11. 866
VOI*. XVI.
INDEX
753
arsenitophosphatotungstate, 9.
trimotasilicate, 6. 372
carbonate, 2. 769
chlorothiosulphate, 10. 529
chromate, 11. 258
deuterohexavanadate, 9. 766
� dinitratoimidodisulphonate, 8.
653
677
� hypophosphato, 8. 937
� magnesium diorthoarsenate, 9.
179
sulphate, 4. 342
� manganous permanganitomolybdate,
11. 572
mercuride, 4. 1015
molybdate, 11. 558
orthohexacolumbate, 9. 865
orthosulpharsenate, 9. 317
phosphatoctotungstate, 11. 872
phospha tohemipentamoly bdate,
667
phospha to tungstate, 11. 873
pyrophosphate, 2. 866
sesquiphosphate, 2. 850
silicate, 6. 337
simonytes, 4. 342
sulphate, 2. 687
sulphite, 10. 271
tetravanadatododecamolybdate,
9. 784
trihydrodiorthoarsenate, 9. 153
physical, 2. 451
326
pyroarsenate, 9. 153
pyroarsenite, 0. 119
enneahydrated, 9. 119
pyrocolumbate, 9. 863
pyrophosphate, 2. 862
silver, 3. 488
pyrophosphatododecamolybdate, 11.
671
pyrosulpharsenate, 9. 317
pyrosulpharsenatosulphomolybdate, 9.
322
pyrosulpharsonatoxymolybdate, 9. 331
pyrosulpharsenito, 9. 29O
octodecahydrate, 9. 762
octohydrate, 9. 762
. hexamminopyrophosphate, 15.
591
hexanitrate, 8. 513
sulphate, 5. 657
tungstate, 11. 791
scandium carbonate, 5. 492
sulphate, 5. 492
sesquiphosphate, 2. 850
sexiesdimethy laminechloroplat inate,
16. 325
silioatotitanatocolumbate, 9. 867
silicide, 6. 169
silicodecatungstate, 6. 882
silico-oxalate, 6. 235
silicovanadatodecatungstate, 6. 838
INDEX
decahydrate, 7. 416
enneahydrate, 7. 416
henicosihydrate, 7. 416
� octohydrate, 7. 416
� totrahydrato, 7. 416
(/S-), 7. 417
- stannatohexavanadate, 9. 776
- stannatopentavanadate, 9. 776
- stannatotetravanadate, 9. 776
- stannatotrivanadate, 9. 776
stilbite, 6. 76O
677
imidodisulphonate, 8. 654
oxytrisulpharsenate, 9. 33O
paratungstate, 11. 818
phosphate, 8. 878
octodecahydrated, 3. 878
pyrophosphate, 8. 892
silicate, 6. 371
tetrasulphate, 3. 805
trimetaphosphate, 8. 894
subchloride, 2. 530
suboxide, 2. 485
sulphamidate, 8. 662
sulphate, 2. 656
o-, 2. 661
P-, 2. 661
and hydrogen, 1. 303
potassium chloride crystalliza
tion, 2. 680
CuSO4-H^O, 3. 257
OuSO4-H8SO4-HaO, 8. 257
- hydrates, 2. 667
� occurrence, 2. 656
preparation, 2. 657
� properties, chemical, 2* 672
physical, 2. 660
solubility, 1. 614
GENERAL, INDEX
�� sulphometastannate, 7. 475
sulphomolybdate, 11. 651
sulphoniodide, 2. 607
Bulphoorthostannato, 7. 474
sulphopalladate, 16. 683
sulphoperrhodite, 15. 586
sulphoplatinate, 16. 398
sulphoplatinito, 16. 395
sulphoplumbite, 7. 796
sulphosilicate, 6. 986
sulphotellurate, 11. 115
sulphotellurito, 11. 113
sulphotriselenoarsenate, 10. 921
sulphotungstate, 11. 858
sulphovanadites, 9. 816
sulphoxylate, IO. 162
sulphurylbromide, IO. 689
sulphury !chloride, 10- 689
sulphuryinitrate, IO. 689
sulphurylthiocyanato, 10. 689
tellurate, 11. 89
telluratoa.rsena.te, 9. 204
telluride, 11. 4O
tellurite, 11. 78
hemienneahydrate, 11. 78
pentahydrate, 11. 78
telluritovanadate, 11. 81
tetraborate decahydrated, 5. 68, 7O
hexahydrate, 7. 776
tetrahydrate, 7. 776
tetrarnercuride, 4. 1Ol3
tetrametaphosphates, 2. 867
tetramidoaluminate, 5. 242
tetraznidosulphonatoplatinite, 8. 645
tetramminochloroplatinite, 16. 281
tetramolybdate, 11. iS92
tetranitratodinitrosohydrazinocobalt
iate, 8. 5IO
tetranitritoplatinite, 8. 519
tetrantimonate, 9. 443
totrantimonite, 9. 431
tetraphosphate, 8. 991
tetrarsenatostannate, 9. 189
� tetrarsenite, 9. 119
totraselenide, 10. 768
tetrasilicate, 6. 328
tetrasulphide, 2. 63O, 634
� dihydrate, 11. 81
trihydrate, 11. 81
tetravanadatopentatellurite, 11. 81
tetreroctocolumbate, 9. 864
totrerodecavanadate, 9. 764
tetrerohexadeeavanadate, 9. 764
tetrerooc to vanadate, 9. 764
tetrero tetra vanadate, 9. 764
tetritaplumbide, 7 606
tetxutastannide, 7. 345
tetritatritelluride, 11. 41
thaUic disuhphate, 5. 469
thallide, 5. 425
thallous chlorides, 5. 441
dithionates, 10. 594
pentathiosulphate, 10. 549
� trithiosulphate, 10. 549
thioaurite, 3. 611
thiocarbonate, 6. 123
thiophosphate, 8. 1064
octohydrate, 8. 1064
thiosesquicarbonatc, 6. 114
thiosulphate, 10. 516 ; 13. 616 ; 15.
159
dihydrate, 10. 519
a_, 10. 52O
/S-, 10. 52O
hemihydrate, 10. 57 9
hexahydrate, 10. 520
monohydrate, 10. 52O
a_, 10. 52O
�_, 10. 520
pentahydrate, 10. 519
a-, 10. 52O
GENERAI, INDEX
� zincido, 4. 667
zirconate, 7. 135
zirconium carbonate, 7. 161
octaorthophosphate, 7. 164
tetraorthophosphate, 7. 164
tetrasulphate, 7. 159
triorthophosphate, 7. 164
zirconyl(di) hexasulphate, 7. 159
(tri) tetrasulphate, 7. 159
(di)sodium cadmium phosphate, 4. 661
hexahydrosilioododecatungstate, 6.875
hydroxynitrilodisulphonate, 8. 676
hydroxvxutrilo-iso-disulphonate, 8. 679
imidosulphonate, 8. 650
imidotrithiophosphate, 8. 727
mercuric imidodioxysulphonate, 8. 657
imidodisulphonate, 8. 657
imidoxysulphonate, 8. 667
nitrite, 8. 478
nitrilohydroxynitrilodisulphonate, 8.
INDEX 757
nitrilodisulphonate, 8. 676
hydroxytrisnitrUodisulphonate, 8. 676
silicododecatungstate, 6. 875
8. 650
hemipentahydrate, 8. 65O
heptohydrato, 8. 65O
trimetaphosphimato, 8. 717
Solar pyrites, 12. 531
SoIv, 3. 295
Soft lead, 8. 311
ore, 3. 3OO
X-rays, 4. 33
Soil phosphate, 3. 905
Sol, 1. 771
Solder brazing, 4. 671
Solders, 7. 630
Solfatarite, 5. 333, 341
Solfo, 10. 1
Solid solution, 1. 659
apparent, 1. 996
chemical composition and, 1. .)�o
effect grain-size, 1. 508
of pressure, 1. 511
. temperature, 1. 5IO
temperature, 1. 532
product, 1. 996
real, 1. 996
Solute, 1. 506
metal, 7. 362
Solutio calcia antimonii cum sulphure, 0.
574
mercuria frigide parata, 4. 987
mercurii calide parata, 4. 991
529
electrolytic, 1. 1017
hypothesis osmotic pressure, 1.
558
rate of, 1. 537
solid, 1. 659
solvate theory, 1. 994
standard, 1. 391
temperature, critical, 1. 523
Solutions, 1. 95
and Avogadro's hypothesis, 1. 545
Solvent, 1. 506
effect on electrolysis, 1. 968
universal, 1. 5O
Sombrerite, 2. 1 ; 3. 896
Somorvillite, 6. 343, 752
Sommite, 6. 56
Son of satan, 9. 341
Sonnenstein, 6- 663
Sonomaite, 4. 252 ; 5. 3 54, 354
Sonstadt's heavy liquid, 4. 916
Soot, 2. 426
Sorbite, 12. 846
lamellar, 12. 847
Soretito, 6. 821
Sorption, 1. 311
Sosa-bruta, 2. 711
Soubeiran's mercurous salt, 4. 988
salt, 4. 789
liquid, 6. 94
nacre, 10. 26
Soumansite, 5. 367
Souring, 3. 243
Soushypoiodique oxyde, 2. 285
Soviet gold, 3. 493
Sow, 12. 597
Space lattice, 1. 624
Spadaite, 6. 368, 42O, 428
Spagyric art, 1. 91
Spandite, 6. 714 ; 12. 15O
Spangito, 6. 736
Spaniolite, 9. 291
Spanish black, 5. 749
shirl, 6. 458
white, 9. 707
Spanoilite, 4. 697
Spar adamantine, 5. 247
blue, 3. 274
chlorite, 6. 62O
schiller, 6. 392
soda table, 6. 366
tabular, 6. 354
zinc, 6. 442
en tables, 6. 354
Spathic ore, 12. 531
scintillans, 6. 661
vitreum, 2. 3
gases, 1. 175
heat gases, ratio of two, 1. 788
heats of gases, ratio of two, and
degree of freedom, 1.
79O
ratio of two, effect of
pressure, 1. 788
ratio of two, effect of
temperature, 1. 788
ratio of two, molecular
weights, 1. 788
volumes, 1. 228
colloids, 1. 774
Specificum purgans Paracelsi, 2. 656
Speckstein, 6. 429� 430
Spectra: halogens, 2. 57
GENERAL, INDEX
combination principle, 4. 14
constancy of, 4. 11
grouping of, 4. 13
reversed, 4. 6
spark, 4. 7
� X-ray, 1. 636
X-rays, 4. 37
Specular iron, 13. 775
ore, 12. 531
schist, 13. 775
Specularite, 18. 775
flaky, 13. 785
Speculite, 11. 48
Speculum metals, 7. 348
Speed, see Velocity
Speerkies, 14. 218
Speise, 3. 25
Speiskobalt, 9. 76
flasesigon weisson, 9. 77
Speiss cobalt. 9. 4 ; 14. 424
(nickel), 15. 19
Spelter, 4. 403
hard, 4. 403
primary, 4. 403
romelted, 4. 403
secondary, 4. 403
virgin, 4. 403
Spencerite, 4. 66O
Sperrylite, 9. 4, 82, 343 ; 16. 5
Spessartite, 6. 714, 9Ol ; 12. 15O
Spharite, 5. 367 ; 8. 733
Sphaarocobaltite, 14. 424, 808
Sphsero-siderite, 12. 531
Sphaerostilbite, 6. 759
Sphalerite, 4. 407, 586 ; 12. 150
Sphene, 6. 84O
Sphenodase, 6. 746 ; 12. 15O
Sphenomanganite, 12. 24O
Sphere, 7. 3, 30, 54
Spheroidization of graphite, 12. 725
Spheresiderite, 14. 355
Sphragid, 6. 472
Sphragieite, 6. 472
Sphragis, 6. 471
Spialter, 4. 403
Spiauter, 4. 403, 587
Spiauterite, 4. 587
Spiegeleisen, 12. 194
Spiesglanoe, 9. 564
Spiesglanzsilber, 9. 404
Spiesglasglanz prismatischer, 9. 55O
Spiesglassilber, 9. 404
Spiossglanz, 9. 341, 513
Spiessglanzbleierzi, 9. 55O
Spiessglanzblende, 9. 577
Spiessglanzbutter, 9. 469
Spiessglanzerz, 9. 513
Spiessglanzglas, 9. 420, 577
Spiessglanzocker, 9. 435
Spiessglanzsafran, 9. 577
Spiessglas, 9. 341, 513
Spinel, 4. 251 ; 5. 154, 295 11. 199 ; 12.
150
Spinels, 5. 276
chrome, 5. 154
chromium, 4. 251
iron, 4. 251 ; 5. 154
magnesia, 5. 154
magnesia, 5. 154, 295
iron, 5. 297
manganese, 4. 251 ; 5. 297
precious, 5. 295
ruby, 5. 154, 295
zinc, 4. 408 ; 5. 154
Spinthariscope, Crookes', 4. 8O
Spinthore, 6. 84O ; 7. 3
Spi r it, 1. 122
of hartshorn, 2. 781
nitre, 8. 557
salt : rectified, 2. 21
Spiritus, 1. 122
acidus nitri, 8. 55G
aethereus, 6. 1
animal is, 2. 78O
argenti vivi sublimati, 7. 436
elasticUB, 6. 1
fumans, Berguin's, 2. 645
Boyle's, 2. 645
Libavii, 7. 436
lothales, 6. 1, 6
mineralis, 6. 1
-�� nitri, 8. 555
fumans Glaubori, 8. 556
salis, 2. 2O
loth, 2. 78O
- resuscitatus, 9. 504
urinse, 2. 78O
sulfuris acidus, 10. 186
sulphureus, 6. 1, 2
sylvestris, 6. 1 ; 8. 417 ; 10. 186
urinse, 2. 78O
vitrioli eoagulabilis, 2. 656
volatilis salis annoniaci, 2. 780
Spitting of silver, 3. 342
Spodiophyllite, 6. 624
Spodiosite, 3. 897
didymium, 5. 675
Spodium, 4. 506
Spodos, 4. 506
Spodumene, 2. 425 ; 6. 390, 64O ; 7. 897
�x, 6. 641
� -fl, 6. 569, 641, 643
y, 6. 64O, 641
soda, 6. 643, 693
Spongy iron, 12. 635, 767
Sporadosiderites, 12. 523
Sporogelito, 5. 275
Sporting powder, 2. 826
Spraying, 4. 494
76O GENERAL INDEX
solids, 1. 824
Sprodglaserz, 9. 540
Spuma argonti, 7. 638
Spurrite, 6. 365
Stabeisen, 12. 709
Stability constant, 2. 227
silver, 3. 358
solution, 1. 391
Stangenbinnite, 9. 298
Stangenstein, 6. 560
Stannates, 7. 414
(�-), 7. 414
(/S-), 7. 417
Stannic acid, 7. 404
.� a.f 7. 405
colloidal, 7. 408
. properties, 7. 409
� /S-, 7. 405
colloidal, 7. 411
properties, 7. 411
ammonium phosphatohenatun*?state.
11. 868
phosphatohexitetradecamolybdate,
11. 670
" phosphatovanaditotungstate, 9.
827
antimonate, 9. 457
barium borate, 5. 105
bismuth hydroxytrisulphate, 9. 7Ol
bromide, 7. 454
ethyl, 7. 455
isopropyl, 7. 455
-� methyl, 7. 455
propyl, 7. 455
tetrahydrated, 7. 455
bromochlorides, 7. 457
�i bromotrichloride, 7. 457
dihyrated, 7. 437
enneahydrated, 7� 437
ethyl, 7. 446
isopropyl, 7. 446
(di), 7. 446
methyl, 7. 446
pentahydrated, 7. 457
properties, chemical, 7. 448
physical, 7. 457
tetrahydrated, 7. 437
trihydrated, 7. 437
chlorides, 7. 436
chloroantimonite, 9. 482
chlorodisulphohydrate, 7. 443
chlorohypophosphite, 8. 886
chloropentasulphohydrate, 7. 443
chloroplatinate, 16. 33O
chlorotetrasulphohydrate, 7. 443
chlorotriiodide, 7. 464
chromate, 11. 290
cobalt sulphide, 14. 757
cobaltic dichlorobisethylenediamine
bromide, 14. 729
��� dichlorobisethylenediaminechloride,
14. 67O
cobaltous hoxabromide, 14. 718
hexachloride, 14. 646
cuprous ferrous sulphide, 14. 168, 189
� diamminobromide, 7. 456
diarnminochloride, 7. 445
diarsenatoctodeeatungstate, 9. 214
diarsenite, 9. 129
dibromodichloride, 7. 457
dibromodiiodide, 7. 464
dichloride (0-), 7. 443
dichlorodiiodide, 7. 463
dihydroxysulphate, 7. 479
396
disulphododecachloride, 10. 647
disulph�tetrachloride, 7. 443
disulphotetraiodide, 10. 655
ditritaphosphinochloride, 7. 445
ferrite, 13. 921
ferrous bromide, 14. 122
- hexachloride, 14. 35
fluoride, 7. 422
fluosilicate, 6. 955
heptabromocerate, 5. 645
hexamminoiodide, 7. 463
hydroselenite, 10. 833
hydroxide, 7. 406, 408
hydroxytribromide, 7. 455
iodide, 7. 462
ethyl, 7. 463
methyl, 7. 463
propyl, 7. 463
lithium tungstate, 11. 792
manganous chloride, 12. 370
hexabrotnide, 12. 383
molybdate, 11. 566
nickel bromide, 15. 429
hexachloride, 15. 42O
GENERAL, INDEX
� octamminoiodide, 7. 463
Stannites, 7. 390
Stannones, 7. 410
metasulphoantimonite, 9. 544
� monamminoiodide, 7. 459
GENERAL, INDEX
preparation, 7. 386
properties, chemical, 7. 389
physical, 7. 387
oxycarbonate, 7. 48O
oxychloride, 7. 428
oxyiodides, 7. 459
oxynitrate, 7. 48O
oxysulphate, 7. 478
pentamminobromido, 7. 453
pentamminoiodide, 7. 459
pontoxyhexachloride, 7. 428
trihydrated, 7. 428
trihydrated, 7. 466
sulphoantimonate, 9. 575
sulphochromite, 11. 433
sulphomolyfodate, 11. 652
sulpho tellurite, 11. 114
sulphotungstate, 11. 859
telluride, 11. 55
tetrachloromercuriate, 4. 811
tetradecahydroxytetrachloride, 7. 428
tetraiodoplumbite, 7. 778
tetramminochloride, 7. 43O
tetramminochloroplatinite, 16. 284
tetramminoiodide, 7. 459
tetraphosphate, 7. 481
tetroxydichloride, 7. 428
thiocarbonate, 6. 128
thiohypophosphate, 8. 1064
thiophosphate, 8. 1065
thiosulphate, 10. 550
triamminobromide, 7. 453
triamminoiodide, 7. 459
trioxytetraohloride, 7. 428
tristannate, 7. 392
tungstate, 11. 792
vanadate, 9. 776
� calciforme, 7. 394
nativum, 7. 283
spathosum, 11. 673
Stanzaite, 6. 458
Starch : iodide, 2. 99
iodized, 2. 98
Stark effect, 4. 19
Stark's hypothesis valency, 4. 183, 186
Stars spectra, 4. 19
Stasite, 7. 491 ; 12. 136
Stassfurt potash beds, 2. 428
uses, 2. 435
Stassfurtite, 2. 43O ; 5. 137
Stassite, 12. 5
Stasziate, 9. 161
State, colloidal, 1. 771
183
Status nascens, 1. 331
Staurolite, 6. 766, 909 ; 12. 15O
manganese, 6. 909
zinc, 6. 909
Staurotide, 6. 909
Staurotite, 12. 531
Steadite, 3. 903 ; 6. 835
Steam curve, 1. 444
electrolysis, 1. 493
Steargillite, 6. 498
Steatargillite, 6. 498, 624 ; 12. 531
Steatite, 6. 42O, 429, 43O
Steel, 12. 645, 646, 709
� Eisen, 6. 473
Steinsalsc, 2. 430
Stellerite. 6. 768
Stellite, 6. 366 ; 14. 519
Stolznerite, 3. 265
Stephanite, 3. 300 ; 9. 343, 54O
Stercorite, 8. 733
Stere, 1. 237
Stereochemistry, 1. 214
Steric hindrance, 10. 24O
Sterline, 15. 210
Sterling gold, 3. 532
silver, 3. 358
Sterlingite, 6. 606, 909
Sternbergite, 12. 531 ; 14. 193
Sterro metal, 4. 671 ; 13. 545
Stetefeldtite, 9. 343, 437
Stevensite, 6. 430
Stiatile, 9. 461
Stibia femina, 9. 420
Stibianite, 9. 442
Stibiatil, 9. 343 ; 12. ISO
Stibioonite, 9. 343, 435, 437
Stibine, 9. 391, 513
decomposition, 9. 394
properties, chemical, 9. 396
physical, 9. 393
Stibiobismuthinite, 9. 696
Stibiodomcykite, 9. 63
Stibioferrite, 9. 437
Stibiogalenite, 9. 458
Stibiohexargentite, 9. 404
Stibiopalladinite, 15. 592 ; 16. 5
Stibiotantalate, 9. 904
Stibiotantalite, 9. 46O
Stibiotriargentite, 9. 404
Stibium, 9. 339, 34O, 341
Stiblite, 9. 343
Stiblith, 9. 435
Stibnite, 9. 343, 349, 513
Stichtite, 4. 376 ; 11. 473
Stickstoff, 8. 46
Stickstoffoxybaryt, 8. 485
Stickstofftitan, 8. 119
Stilbite, 6. 575, 738, 758
ammonium, 6. 76O
barium, 6. 76O
potassium, 6. 76O
sodium, 6. 760
thallo-, 6. 826
Stilpnomelane, 6. 624 ; 12. 531
Stilpnosiderito, 13. 886
Stilposidente, 13. 877
Stimmi, 9. 339, 34O, 341
Stimulants in chemical actions, 1. 359
Stinkstone, 2. 431 ; 3. 815
Stirlingite, 4. 506 ; 6. 909
Stochiolith, 9. 404
Stoffertite, 3. 88O
Stokesite, 6. 883 ; 7. 283
Stolpenite, 6. 498
Stolzite, 7. 491 ; 11. 678, 792
Stone age, 1. 19
baptismal, 6. 909
buff, 6. 468
Cornish, 6. 467
___ dry white, 6. 468
purple, 6. 467
Stoneware, 6. 515
Stopping power elements for a-rays, 4.
Stove charcoal, 5. 748
Strahlblende, 4. 408
Strahlpyritos, 14. 218
Strahlstein, 6. 405
Strahlzeolith, 6. 758
Strakonitzite, 6. 43O
Straight extinction, 1. 608
Strain, 1. 819
bases, 1. 981
ions, 1. 1015
Strontia, 3. 652
anorthite, 6. 707
dolomite, 4. 376
felspar, 6. 662, 698, 707
GENERAL INDEX
sulphate, 9. 583
arsenatotrimolybdate, 9. 209
arsenide, 9. 66
atomic wt., 3. 646
azide, 8. 35O
barium calcium hexachlorido, 3. 72O
bisbromoarsenite, 9. 256
hydrated, 2. 346
bromide, 3. 725
� properties, chemical, 3. 727
physical, 3. 726
bromoarsenatoapatite, 9. 262
bromopalladite, 15. 677
bromophosphate, 3. 897
bromoplatinate, 16. 379
bromosmate, 15. 724
bromostannate, 7. 456
�- bromotriorthoarsenate. 9. 262
bromotriorthovanadate vanadatobro
mapatite, 9. 813
bromovanadate, 9. 813
cadmium alloys, 4. 687
hexaehloride, 4. 658
totraiodide, 4. 584
tetrathiosulphate, 10. 547
carbamate, 2. 796
carbide, 5- 86O
carbonate occurrence, 3. 814
preparation, 3. 814
properties, chemical, 3. 839
physical, 3. 833
solubility, 8. 824
carbonyl, 5. 951
chlorate, 2. 344
chloride, 8. 697
and fluoride, 8. 718
BaCIa-NaCl, 3. 720
CaCl9-BaCl8, 8. 720
dihydrated, 3. 705
hexahydrated, 3. 705
hydrated, 8. 702
KCl-NaCl, 3. 720
preparation, 8. 697
properties, chemical, 8. 714
� chloroantimonate, 9. 491
chloroapatite, 8. 902
chloroarsenatoapatite, 9. 260
chloroaurate, 8. 595
tetrahydrato, 7. 449
chlorotriorthoarsenato, 9. 26O
chromate, 11. 27O
chromatosulphate, 11. 45O
oxyoctonitrite, 8. 504
cobaltite, 14. 594
cobaltous chloride, 14. 642
columbato, 9. 866
copper ammonium nitrite, 8. 488
silicate, 6. 373
decahoratodibromido, 5. 141
decatungstate, 11. 832
� deutoroctovanadate, 9. 771
deuterovanadate, 9. 77O
enneahydrate, 9. 77O
dialuminium dimesotrisilicate, 6. 758
diborate, 5. 87
dihydrated, 5. 88
pentahydrated, 5. 88
tetrahydrated, 5. 88
dichromate, 11. 341
diglycenylpermanganite, 12. 278
dihydroarsenate, 9. 172
dihydroarsenatotrimolybdate, 9. 208
dihydrohypophosphate, 8. 937
dihydrophosphate, 8. 886
monohydrated, 8. 887
dihydropyrophosphate, 8. 892
dihydropyrophosphite, 8. 922
dihydroxytetrasulphide, 3. 758
diiodonitritoplatinite, 8. 623
diiodotriarsenite, 9. 257
dimetaphosphate, 3. 893
dihydrated, 3. 893
dioxide, 3. 666, 668
diperoxyhydrate, 8. 668
hydroxyhydrate, 8. 671
octohydrated, 8. 667
dipermanganite, 12. 277
disilicide, 6. 178
disulphoniodide, 8. 737
disulphuryldiiodide, 10. 691
dithionate, 10. 580
dithiophosphate, 8. 1068
ditungstate, 11. 810
GENERAL INDEX
preparation, 8. 688
physical, 8. 689
fluoroapatite, 8. 9Ol
fluorohromide, 8. 731
fluorochloride, 8. 718
fluoroiodide, 8- 739
fluorophosphate, 3. 9Ol
� fluosilicate, 6. 951
fiuostannate, 7. 423
fluotitanate, 7. 72
dihydrated, 7. 72
� fiuotriorthoarsenate, 9. 259
� fiuozireonate, 7. 141
haidingerite, 9. 171
� hemiaraminobromide, 3. 73O
� henamercuride, 4. 1032
heptachlorodibismuthite, 9. 667
heptapermanganite, 12. 277
hexaborate, 5. 92
hexachloromercuriate, 4. 860
hexahydroarsenatoc todecamoly bdate,
9. 211
hexahydroxythiocarbonate, 6. 126
hexaiododiplumbite, 7. 777
hexamercuride, 4. 1032
hoxametaphosphate, 8. 895
hexamraine, 8. 248
hexamminoiodide, 8. 737
history, 3. 619
hydrazinosulphonate, 8. 683
hydride, 8. 629, 649
hydroarsenate, 9. 17O
monohydrato, 9. 171
- hydrodioxydiselenophosphatc, 10. 932
- hydroimidodisulphonate, 8. 654
- hydroimidosulphonate, 8. 658
hydrophosphate, 8. 88O
colloidal, 8. 882
- hydroselenite, 10. 825
- hydrosulphate, 3. 783
- hydrosulphide, 8. 75O
hydroxide, 8. 673
� monohydrated, 8. 676
octohydrated, 8. 675
properties, chemical, 8. 635
physical, 8. 681
solubility, 8. 677
hydroxyhydrosulphide, 8. 755
hydroxypentachloroplatinate, 16. 336
hydroxyphosphate, 8. 902
hypobromite, 2. 273
hypochlorite, 2. 272
hyponitrite, 8. 414
pentahydrate, 8. 414
- hypophosphate, 8. 937
hypophosphite, 8. 884
�iodotriorthovanadate, vanadatiodapatite,
9. 814
iron alloy, 18. 541
� isopropylstannonate, 7. 410
- isotetrahydroborododecatungstate, 5.
110
isotopes, 3. 648
silicate, 6. 371
magnesium carbonate, 4. 376
manganate, 12. 289
manganese metasilicate, 6. 897
manganitomanganate, 12. 29O
manganous chloride, 12. 368
octohydrated, 4. 939
monohydrated, 6. 36O
� metasulpharsenatoxymolybdate, 9.
332
� metasulpharsenite, 9. 296
� metavanadate, 9. 769
tetrahydrate, 9. 769
- metazirconate, 7. 136
molybdate, 11. 5OO
monomerouride, 4. 1033
monometaphosphate, 3. 893
monosulphide, 3. 741
monothiophosphate, 8. 1069
monoxide, 8. 653
nickelate, 15. 4Ol
nitrate, 8. 849
tetrahydrated, 3. 849
X-radiogram, 1. 642
nitratoplumbite, 7. 866
766 GENERAL INDEX
447
octodecachlorodialuminate, 5. 322
octomercuride, 4. 1032
octomolybdate, 11. 596
orthoarsenate, 9. 168
orthoarsenite, 9. 125
orthoborate, 5. 87
orthopertantaiato, 9. 914
orthophosphate, 3. 866
physical, 3. 867
orthoplumbate, 7. 699
orthosilicate, 6. 353
orthosulpharsenate, 9. 320
orthosulphoantimonate, 9. 574
orthosulphoantimonite, 9. 542
orthotetravanadate, 9. 769
orthovanadate, 9. 768
osmate, 15. 706
osmyl oxynitrite, 15. 729
oxide, higher, 8. 666
physical, 3. 660
oxides, 3. 652
oxybromide, 3. 730
oxychloride, 3. 716, 717
oxyiodide, 8. 738
paramolybdate, 11. 586
paratungstate, 11. 818
pentachlorobismuthite, 9. 667
pentahemimercurido, 4. 1033
pentahydroxychloroplatinate, 16. 333
pentamercuric dodecaiodide, 4.
939
� octohydrated, 4. 939
pentamolybdatodisulphite, 10. 307
tetrahydrated, 5. 92
tetrachlorobismuthite, 9. 667
tetrachloroplumbite, 7. 730
tetrachlorostannita, 7. 434
tetradecamercuride, 4. 1032
tetrahydrosilicododacatungstate, 6.878
tetrametaphosphate, 8. 894
octohydrate, 3. 895
tetranitritoplatinite, 8. 52O
tetrarsenite, 9. 125
tetrasulphidodihydrated, 3. 753
hexahydratod, 3. 753
tetrasulphoniodide, 3. 737
tetrasulphuryldiiodide, 10. 691
totreroetovanadate, 9. 771
tetrerotetradecavanadate, 9. 771
thallous chloride, 5. 441
uranium hydroxydisulphotetrauranate,
12. 98
red, 12. 98
uranous diphosphate, 12. 13O
hexachloride, 12. 83
uranyl dihydrotetraphosphate, 12. 136
tetrachloride, 4. 558
rincate, 4. 53O
(di)strontium diborate, 5. 87
89, 91
dialuminate, 5. 291
irnidodisulphonate, 8. 654
Striivenite, 2. 656
X-radiogram, 1. 642
Stuckgips, 3. 763
Studerite, 9. 291
Stutzite, 11. 2, 44
Stiivenite, 5. 342
Stupa, 1. 23
Stupp, 4. 698
Stylobate, 6. 713
Stypterite, 5. 333
Stypticite, 14. 3
Subbromides, 2. 238
Subchlorides, 2. 238
Subdelessite, 6. 624
Subiodides, 2. 238
Suboxides, 1. 118
Succinite, 6. 715
charcoal, 5. 747
Suhler Woisskupfar, 15. 234
Suida's reaction, 6. 294
Suint, 2. 425, 438
Sulfamidique acide, 8. 670
Sulfammonique acide, 8. 670
Sulfatammon, 8. 648
Sulfazeux, acide, 8. 67O
Sulfazidique acide, 8. 67O
Sulfazilique acide, 8. 670
Sulfazique acide, 8. 670
Sulfazotique acide, 8. 67O
Sulfite sulfure de soude, 10. 485
Sulfodialuminique hydrate, 5. 337
Sulfur apyron, 10. 1
vivum, 10. 1
Sulphalite, 2. 553
Sulphamic acid. 8. 637
Sulphamide, 8. 66O
Sulphamidinic acid, 8. 647
Sulphammonates, 8. 667
Sulphammonic acid, 8. 667
Sulphammonium, 8. 249
mercury, 4. 954
Sulphantimonides, 9. 589
Sulpharsenates, 9. 315
Sulpharsenic acid, 9. 315
Sulpharsenide, 9. 589
Sulpharsenides, 9. 305
Sulpharsenious acids, 9. 289
Sulphate platinosic acid, 16. 403
Sulphates, 10. 440
768 GENERAL
911
tetroxydibromide, 10. 911
trioxytetrabromide, 10. 911
trioxytetrachloride, 10. 911
Sulphosilicates, 6. 986
Sulphosilicon, 6. 987
Sulphostannates, 7. 473
Sulphosulphurous acid, 10. 563
INDEX
VO]L. XVI.
Siuphurite, 9. 5 ; 10. 5, 24
Sulphurium, 10. 1
Sulphurum, 10. 1
3 r>
GENERAL INDEX
Tabaschir, 6. 141
Tabergite, 6. 622
Tabular habit, 1. 597
Tachen, O., 52
Tachhydrite, 2. 15, 43O 4. 252, 298, 309
Tachyaphalite, 6. 847
Tachyaphaltite, 7. 1OO
Tachydrite, 3. 623, 697
Tachyhydrite, 7. 897
Tackjern, 12. 708
gratt, 12. 708
halfgratt, 12. 708
halfhwitt, 12. 708
hwitt, 12. 708
Teenite, 12. 528, 531 ; 15. 260
- ferrosol, 15. 262
Tagilite, 8. 289 ; 8. 734
Tail of band spectrum, 4. 7
Tainiolite, 6. 407 '
Talapite, 11. 2
Talbot process, 8. 416
Talc, 4. 251 ; 6. 42O ; 15. 9
bleu, 6. 458
blue, �. 622
chlorite, 6. 622 ; 12. 531
earthy, 6. 472
granuleux, 6. 472
hydrate, 4. 29O
iron, 8. 431
schist, 6. 48O
taleapatite, 8. 896
INDEX 771
Talchus, 6. 429
Talcite, 6. 606
Talcium, 4. 251
carbonatura, 4. 349
Talcoid, 6. 43O
Taloose slate, 8. 430
Talcosite, 6. 473
Talcum, 6. 429
Talkerde, 4. 25O, 28O ; 6. 472
reine, 4. 349
kohlensaurer, 4. 349
Tallingite, 2. 15 ; 8. 178
Tallow clays, 4. 406 ; 6. 442
Taltalite, 6. 741
Talutiae, 16. 1
Tamarite, 0. 162
Tamarugite, 2. 656 ; 5. 341
Tammeltantalite, 9. 909
Tangeite, 9. 772
Tan kite, 6. 693
Tannenite, 9. 690
Tannic acid, 18. 613, 616
Tantalate, 9. 868
Tantalates, 9. 9OO
Tantalic acid, 9. 896
Tantalite, 7. 255 ; 9. 839, 906, 907, 909
Tantalotungstates, 9. 904
Tantalum, 9. 837, 883
amminopentachloride, 9. 921
atomic number, 9. 894
weight, 9. 883
bromide, 9. 922
bromosulphate, 9. 925
carbide, 5. 888
carbonate, 9. 925
cassiterite, 7. 394
chlorides, 9. 919
chlorosulphate, 9. 925
chromium alloys, 11. 173
� colloidal, 9. 883
� copper-tungsten-nickel, 15. 251
� dichloride, 9. 919
� dinitrido, 8. 126
� dioxide, 9. 895
� dioxychloride, 9. 921
� disulphide, 9. 924
� electronic structure, 9. 884
� fluochlorosulphide, 9. 925
� fluorides, 9. 914
� heptatritabromide, 9. 922
� heptatritachloride, 9. 92O
� hexabromochloride, 9. 923
� hexabromoiodide, 9. 924
� history, 9. 837
� hydride, 9. 885
� hydroxide, 9. 898
colloidal, 9. 898
hydroxyhexabromide, 9. 923
iodides, 9. 923
iron alloy, 18. 585
isotopes, 9. 884
molybdate, 11. 570
Telgstein, 6. 429
Tellemarkite, 6. 715
Tellurates, 11. 2, 88
Tellurgoldsilber, 11. 49
Tellurgoldverbindung, 11. 46
number, H . 35
weight, 11. 32
� bismuth glance, 11. 2
� colloidal, 11. 9
disulphido, H. HO
physical, 11. 11
radio, 4. 114
selenate, 10. 875
selenide, 10. 796
selenotrioxides, 11. 114
sulphides, 11. 110
sulphotrioxide, 10. 306 11. 114, 115,
116
tetrabromide, 11. 103
tetrachloride, 11. 100
tetrachloride, 11. 98
tetrahydrate, 11. 98
tetraiodide, 11. 105
tetramminotetrachloride, 11. 101
triamminotetrachloride, 11. 101
trioxide, 11. 83
trioxysulpho tetrachloride, 11. 118
trisulphide, 11. 110
tritaheptoxide, 11. 88
tritatetranitride, 11. 58
ultramarine, 6. 590
uses, 11. 30
valency, 11. 32
Tellurobismuth, 9. 589
Tellurocupric acid, 8. 15O
Telluromolybdate, 11. 63
Telluronium salts, 11. 32
Tellurosic oxide, 11. 88
Tellurothionates, 11. 97
Tellurothiosulphux-ic acid, 11. 118
Tellurotungstate, 11. 63
Tellurous acid, 11. 72
Tellursilber, 11. 44, 49
Tellursilberblende, 11. 44
Tellursilberglanz, 11. 44
Telluryl bromide, 11. 109
carbon, 6. 739
colours, 12. 696
Temperament, influence on judgments, 3.
526
solution, 1. 523
eutectic, 1. 517
freezing, 1. 457
inversion, 1. 866
normal, 1. 161
standard, 1. 161
transition, 1. 513 ; 8. 113
Term, 7. 276
Tennantite, 3. 7 ; 9. 4, 201
Tennspar, 5. 507
Tenorite, 3. 7, 131
Tensile strength, 1. 821, 822
liquids, 1. 421
Tepalcate, 2. 711
Tephroite, 6. 386, 892 ; 12. 15O
Tephrowillemite, 6. 438
Tequezquite, 2. 711
Teratolite, 6. 473
Terbia, 5. 497, 693
weight, 5. 690
bromide, 5. 694
carbonate, 5. 695
chloride, 5. 693
chromate, 11. 288
family earths isolation, 5. 686
hydroxide, 5. 693
isolation, 5. 553
nitrate, 5. 695
occurrence, 5. 686
oxychloride, 5. 694
peroxide, 5. 693
properties, 5. 688
sesquioxide, 5. 693
silicododecatungstate, 6. 880
solubility of hydrogen, 1. 307
Torerite, 6. 619
Terlinguaite, 2. 15 ; 4. 697
Termierite, 6. 498
Ternary system, pseudo, 1. 524
Terno plates, 7. 63O
Terra alkalina, 3. 619
calcaris, 5. 150
eotta, 6. 514
� damnata, 1. 55
di siena, 13. 887
Verona, 6. 92O
fluida, 1. 64
lapida, 1. 64
mercurialis, 1. 64
� pinguis, 1. 64
plumbaria citrino, 7. 638
rubia, 7. 638
ponderosa, 8. 620
porcelanea, 6. 432
porcellana, 6. 472
rose, 13. 782
sigillate, 6. 471
vitrescibilis, 1. 64 ; 6. 135, 136
Terrar, 7. 121
trioxide, 5. 39
Tetrabromosilane, 6� 977
15. 538
bromosmate, 15. 723
chloroiridate, 15. 77O
chloropalladate, 15. 673
chloroperruthenite, 15. 532
chlororuthenate, 15. 534
chlorosmate, 15. 719
dimolybdate, 11. 581
enneachlorodirhodate, 15. 58O
ferroheptanitrosyltrisulphide, 8. 442
palladate, 15. 678
tetrabromoaquotungstito, 11. 854
tribromopalladite, 15. 678
uranyl chloride, 12. 89
Totraethylmonosilane, 6. 216
Tetraforrous ferric oxide, 13. 807
Tetrafluosilane, 6. 934
Totragenie salt, 4. 343
Tetragonal system. 1. 619
Tetragophosphite, 5. 37O
Tetrahedrite, 4. 406 ; 9. 4, 291, 343, 536 ;
15. 9
Tetrahedron theory, carbon atom, 1. 214
Tetrahydrated dodecamanganite, 12. 275
Tetrahydrododecamolybdates, 11. 582
Tetrahydrododecatungstates, 11. 773
Tetrahydrohexamolybdates, 11. 582
Tetrahydrohexatungstat.es, 11. 773
Tetrahydroxydichloroplatinic acid, 16. 334
Tetrahydroxysnlphatoplatinic acid, 16. 405
Tetraiodosilane, 6. 982
Tetraiodosilene, 6. 984
Tetraiodosilicoethene, 6. 984
Tetraiodosilicolthylene, 6. 984
Tetraiodosilicomethane, 6. 982
Tetrametaphosphimic acid, 8. 718
Totramethylammonium bromopalladate,
15. 678
bromopalladite, 15. 677
bromoperruthenite, 15. 538
bromosmate, 15. 722
chloroiridate, 15. 770
chloropalladate, 15. 673
chloropalladite, 15. 670
chloroperruthenite, 15. 532
chloroplatinate, 16. 318
chlororuthenate, 15. 534
chlorosmate, 15. 719
GENERAL INDEX
Tetramethylammonium enneachlorodirho
ferroheptanitrosyltrisulphide, 8. 442
fluoferrate, 14. 8
344
Tetranitritodiamminocobaltiates, 8. 509
Tetranitroxyltrinitric acid, 8. 542
Tetrantimonii' acid, 9. 443
Tetra-paper, 1. 95O
Tetraphosphonitrilic chloride, 8. 723
hydroxychloride, 8. 723
Tetraphosphoric acid, 8. 991
Tetraphylin, 12. 453
Tetraplumbic acid, 7. 685
Tetraquodiam.min.es, 11. 402
Tetraquodipyridines, 11. 402
Tetraselenitohexavanadic acid, IO. 835
14. 854
308
Tetravanadates, 9. 202
Tetrazenes, 8. 329
Tctrazone, 8. 329
Texasite, 15. 6
Thalackerite, 6. 396
Thales, 1. 31
Thalite, 6. 432
Thalliarsenates, 9. 187
Thallibromschwefelsaure, 5. 47O
chloroplumbite, 7. 732
INDEX 775
Thallochabazite, 6. 826
Thalloleucite, 6. 826
Thallomesolite, 6. 826
Thallonatrolite, 6. 826
Thallosic azide, 8. 352
bromide, 5. 453
bromoselenate, 10. 913
chloride, 5. 447
chloroselenate, 10. 913
iodide, 5. 46O
nitrate, 5. 475
oxide, 5. 43O, 432
selenide, 10. 782
sulphates, 5. 468
sulphides, 5. 464
tridecachlorodihypoantimonate, 9. 485
trinitrosyl chloride, 5. 432, 448
phosphate, 5. 478
antimonious thiosulphate, 10. 553
antimonitotungstate, 9. 433
� arsonatoctodeeamolybdate, 9. 210
arsenious thiosulphate, 10. 553
auric nitrate, 5. 476
azide, 8. 352
barium chlorides, 5. 441
disulphate, 5. 466
carbonate, 5. 471
cerous nitrate, 5. 671
. sulphate, 5. 659
chlorate, 2. 355
chloride, 5. 438
chloroaurate, 5. 441
chlorochromate, 11. 399
chloro-dioxyvanadato, 9. 809
chloroiridate, 15. 772
chloromanganite, 12. 380
chloropalladite, 15. 670
chloroperiridite, 15. 765
chloroplatinate, 16. 329
chloroplatinite, 16. 284
chlorostannate, 7. 45O
chlorothallate, 5. 447
chromate, 11. 285
chromic selenate, 10. 836, 876
chromium enneafluoride, 11. 364
enneafluoaluminate, 5. 437
enneafluoferrate, 14. 8
othoxide, 5. 431
ferric alum, 14. 349
colloidal, 6. 431
hydroxydisulphate, 16. 786
hydroxydithionate, 10. 594
hydroxypentachloroplatinate, 16. 335
hypophosphate, 8. 938
hypophosphite, 8. 886
iodate, 2. 355
iodide, 5. 468
iridium disulphate, 16. 785, 788
INDEX 777
� metaphosphate, 5. 479
metaplumbate, 7. 7Ol
metasulpharsenite, 9. 297
metatungstate, 11. 826
molybdate, 11. 563
molybdenum oxypentafluomolybdate,
11. 611
nickelonitrite, 8. 512
nickelous disulphate, 15. 476
nitrate, 5. 472
nitride, 8. 114
nitrite, 8. 496
nitrosyl chloride, 8. 617
octoborate, 5. 103
orthoarsenate, 9. 187
orthophosphate, 5. 477
orthosulpharsenate, 9. 321
orthosulpharsenite, 9. 297
osmiarnate, 15. 728
oxide, 5. 43O, 431
paramolybdate, 11. 587
paratungstate, 11. 819
pentaborate, 5. 103
pentabromobismuthite, 9. 673
pentachloroantimonite, 9. 482
pentachloroferrate, 14. 105
pentachlorohypoantimonate, 9. 485
pentaohloropicnoiridate, 15. 768
pentachloroplumbite, 7. 632
pentachloropyridinoiridate, 16. 768
pentachloropjrridinoperiridite, 15. 766
pentachlorostannite, 7. 434
pentafluovanadite, 9. 797
pentafluozirconate, 7. 142
pentahydroxychloroplatinate, 16. 333
Thiodiimide, 8. 25O
Thiogen process sulphur, 10. 17
Thiohypophosphates, 8. 1063
Thiol-compounds, 6. 119
Thiolcarbonic acid, 6. 119
Thiolthioncarbonic acid, 6. 119
Thiometaphosphoryl bromide, 8. 1078
Thion-eompounds, 6. 119
Thioncarbonic acid, 6. 119
Thionamide, 8. 629
Thionyl, 10. 655
amide, 8. 660
bromide, 10. 662
chloride, 10. 656
chlorobromide, 10. 664
fluoride, 10. 655
halides, 10. 655
hemipentamminofluoride, IO. 656
heptamminofluoride, IO. 656
iodide, 10. 664
oxide, 10. 184
Thioorthophosphates, 8. 1064
Thiopermonosulphuric acid, 10. 604
Thiophosgene, 6. 92
Thiophosphates, 8. 1061
Thiophosphites, 8. 1062
Thiophosphoric acids, 8. 1061
Thiophosphorous acid, 8. 1062
Thiophosphoryl amide, 8. 725
bromide, 8. 1076
hydrated, 8. 1077
chloride, 8. 1074
chlorodibromide, 8. 1078
diamidochloride, 8. 707, 1075
diamidonuoride, 8. 707, 1073
dichlorobromide, 8. 1078
fluoride, 8. 1071
halides, 8. 1071
hydrosulphodibromide, 8. 1076
nitrile, 8. 726
Thiopyrophosphoric acid, 8. 1062
Thiopyrophosphorous acid, 8. 1062
Thiopyrophosphoryl hexabromide, 8. 1077
tetrabromide, 8. 1077
Thiorsauite, 6. 693
Thioschwefelsaure, 10. 485
Thiosesquicarbonic acid, 6. 114
Thiostannates, 7. 473
Thiosulphates, 10. 514
constitution, 10. 507
Thiosulphuric acid, 10. 485
Thiotriazyl bromide, 8. 632
Thiotrithiazyl, 8. 631
chloride, 8. 631
hydrosulphate, 8. 631
iodide, 8. 632
nitrate, 8. 631
thiocyanate, 8. 632
Thiozincate, see Sulphozincate
Thiozone, 10. 36
Thiozomides, 10. 36
Thixotropy, 18. 852
Thomaite, 14. 355
Thomas Aquinas, 1. 46
Oilchrist steel, 12. 652
Thomasite, 8. 903 ; 6. 835
Thompson, sett Kelvin
Thomsenolite, 2. 1 ; 8. 623 ; 5. 154, 303, 309
Thomsonite, 6. 575� 709
hydro, 6. 711
GENERAL INDEX
enneasulphate, 7. 247
nitrate, 7. 251
trisulphate, 7. 247
tetrahydrate, 7. 247
trihydrate, 7. 247
thiosulphate, 10. 55O
trialuminide, 7. 208
triamminobromide, 7. 238
tridecaoxycarbonate, 7. 248
trioxide, 7. 225
5, 52
Thoron, 7. 192, 889
Thorotungstite, 11. 753
Thorsubstanz, 6. 473
Thortveitite, 5. 481 ; 6. 859
Thoryl chloride, 7. 231
sulphide, 7. 24O
Thraulite, 6. 908 ; 12. 531
Thrombolite, 3. 288 ; 9. 432
Thucholite, 12. 6
Thulia, 5. 702
isolation, 5. 698
Thulite, 6. 719
Thxilium, 5. 498, 696
� carbonate, 5. 704
chloride, 5. 703
hydroxide, 5. 703
isolation, 5. 554
nitrate, 5. 704
occurrence, 5. 696
oxide, 5. 702
properties, 5. 698
solubility of hydrogen, 1. 307
sulphate, 5. 704
Thumerstein, 6. 911
Thumite, 6. 911
Thuringite, 6. 623 ; 12. 531
Tico, 15. 257
Tiegelfiussstahl, 12. 711
Tiemannite, 4. 697 ; 10. 694, 779
Tiers-argent, 5. 233
Tigererz, 7. 782
Tiger's eye, 6. 913
Tilasite, 9. 5, 258
Tile ore, 3. 117
Tilkerodite, 10. 787 ; 14. 424
Tin, 7. 276, 277
weight, 7. 339
azide, 8. 352
barium alloys, 7. 372
bismuth alloys, 9. 639
bismuthide, 7. 33* ; 9. 639
black, 7. 287
block, 7. 289
boride, 5. 28
brass, 4. 67O
butter of, 7. 424, 436
cadmium alloys, 7. 376
calcite, 5. 93
calcium alloys, 7. 372
carbide, 5. 885
carbonate, 7. 48O
chloroform, 7. 437
chrome pink, 7. 421
chromium alloys, 11. 172
cobalt alloy, 14. 536
colloidal, 7. 292
concentrates, 7. 286
copper alloys, see Copper-tin
isotopes, 7. 340
lead alloys, 7. 020
colloidal, 7. 627
liquation, 7. 289
lode, 7. 286
GENEBAIi INDEX
Tincal, 5. 1, 3
Tincar, 5. 1
chromifere, 7. 31
siliceocalcaire, 6. 84O
Titaneisen, 7- 56
axotome, 7. 57
oxyde octahedral, 7. 56
Titaneisenstein, 7. 56
Titanerz, 7. 56
acid, 7. 27, 31
a-, 7. 39
/S-, 7. 39
meta-, 7. 4O
ortho-, 7. 39
alcogel, 7. 39
augites, 6. 818
barium sulphate, 7. 94
bromide, 7. 88
calcium sulphate, 7. 94
etherogel, 7. 39
glycerogel, 7. 39
iron ore, 12. 531
nitrosyl chloride, 8. 617
nitroxylchloride, 8. 646
potassium sulphate, 7. 94
salts, 7. 27
strontium sulphate, 7. 94
sulphatogel, 7. 39
Titanium, 7. 1
a-, 7. 16
0-, 7. 16
y-, 7. 16
GENERAL INDEX
Titanium alcoholotetranuoride, 7. 68
alloys, 7. 22
amminoohlorides, 7. 83
ammonium carbonate, 7. 96
chromate, 11. 288
oxysulphate, 7. 95
amorphous, 7. 8
analytical reactions, 7. 22
argento-, 7. 2O
arsenide, 9. 68
atomic number, 7. 24
weight, 7. 23
boride, 5. 27
bromides, 7. 87
bromonitride, 7. 88 ; 8. 265
bromotrichloride, 7. 88
calcium oxysulphide, 7. 91
carbide, 6. 884
carbonate, 7. 96
chlorides, 7. 74
chloronitride, 7. 84 ; 8. 265
chlorophosphate, 7. 96
chronuurn-niclcel-iron alloys, 15. 828
steels, 18. 616
cobalt alloys, 14. 536
cobaltic hexanuninofluorido, 14. 6IO
colloidal, 7. 14
columbate, 9. 866
cupro-, 7. 12, 18, 24
cuprosilico-, 7. 12
diamminotetrafluoride, 7. 67
dicbloride, 7. 74
dichlorodibromide, 7. 88
difluoride, 7. 66
dihydroxide, 7. 28
dihydroxydichlorido, 7. 83
diimide, 8. 265
diiodide, 7- 89
dinitrosyl hexachloride, 7. 84 ; 8. 438
dioxide, 7. 27, 31
colloidal, 7. 39
extraction, 7. 6
preparation, 7. 32
properties, chemical, 7. 41
physical, 7. 33
diphosphoryldecachloride, 7. 85 ; 8.
1025
discovery, 7. 1
disilicide, 6. 186
di sulphate, 7. 93
trihydrated, 7. 93
disulphide, 7. 9O
disulphohydrate, 7. 81
dititanite, 7. 28
electronic structure, 7. 24
ferrite, 18. 924
ferro-, 7. 11
ferrocarbo-, 7. 11
ferrosilico, 7. 11
ferrous sodium trimetasilicate, 6. 843
fluochloxide, 7. 81
fluorides, 7. 66
fiuosilicate, 6. 955
hemisilicide, 6. 186
hemitrisilicide, 6. 186
hexamminotetrachloride, 7. 84
hydride, 7. 18
hydro trichloride, 7. 8O
hydroxytribromide, 7. 88
hydroxytrichloride, 7. 83
Titanium iodides, 7. 89
iron alloys, 18. 571
isotopes, 7. 24
manganese-silicon steel, 13. 667
mangano-, 7. 12, 24
molybdate, 11. 565
molybdenum-tungsten alloys, 11. 744
mononitride, 8. 118
monosulphate, 7. 91
monosulphide, 7. 9O
monosulphohydrate, 7. 81
monoxide, 7. 27
nickel alloys, 15. 232
cobalt alloys, 15. 338
iron alloys, 15. 339
copper alloys, 15. 232
hexafluoride, 15. 405
iron alloys, 15. 315
nitrate, 7. 96
nitride, 8. 117
nitrites, 8. 497
nitrogen hexachlorotetrasulphide, 7. 77
sulphotetraehloride, 7. 84
sulphotrichloride, 7. 84
occurrence, 7. 2
octamminotetrabromide, 7. 88
octamminotetrachloride, 7. 84
oxydichloride, 7. 82
oxyfluoride, 7. 67
oxynitrate, 7. 96
oxytrisulphate, 7. 93
dihydrate, 7. 94
monohydrate, 7. 94
pentahydrato, 7. 94
pentitahexanitride, 8. 118
pentoxide, 7. 64
pentoxychromate, 11. 288
phosphate, 7. 96
phosphide, 8. 847
phosphinotetrachloride, 7. 85 ; 8. 816
phosphite, 7. 96 ; 8. 917
phosphoenneachloride, 8. 1016
phosphoric enneachloride, 7. 85
phosphorous heptachloride, 7. 85
phosphoryl heptachloride, 7. 85
potassioamidonitride, 8. 265
potassium carbonate, 7. 96
preparation, 7. 8
properties, chemical, 7. 18
physical, 7. 14
reactions, 9. 852
selenide, 10. 784
selenium dioxyoctachloride, 7. 85
dioxyoctochloride, 7. 81 ; 10. 910
sesquichloride, 7. 75
sesquioxide, 7. 27, 28
sesquisulphate, 7. 91
sesquisulphide, 7. 9O
silicate, 6. 839
sodium calcium orthosilicate, 6. 844
zirconatosilicate, 6. 858
dimesotrisiliVate, (}. 843
phosphate, 7. 96
potassium ferrous orthosilicate, 6.
843
solubility of hydrogen, 1. 307
steel, 12. 752
sulphates, 7. 91
sulphatotetrachloride, 7. 85
sulphides, 7. 9O
784 GENERAL
disulphohydrate, 7. 88
sulphohydrate, 7. 88
tetrachloride, 7. 78, 84
dihydrated, 7. 81
pentahydrated, 7. 81
properties, chemical, 7. 80
physical, 7. 79
tetrafluoride, 7. 67
dihydrated, 7. 67
tetraiodide, 7. 89
tetramide, 7. 84 ; 8. 265
tetramminotetrachloride, 7. 83
tetramminotetrafluoride, 7. 67
tetroxychromate, 11. 288
thiosulphate, 10. 550
tribromide, 7. 87
trichloride, 7. 75
hexahydrated, 7. 77
trifluoride, 7. 66
trihydroxide, 7. 29
trihydroxybromide, 7. 88
trihydroxychloride, 7. 82
trihydroxyorthophosphates, 7. 97
triiodide, 7. 89
trioxido, 7. 27
hydrated, 7. 63
trioxychromate, 11. 288
tritatetranitride, 8. 119
tungstates, 11. 791
uranium alloys, 12. 38
valency, 7. 23
Titanoantimonites, 7. 3
Titanocerite, 5. 514
Titanochloroform, 7. 80
Titanoeyanogen, 8. 118
Titanoferrite, 7. 2, 57
Titanohedenbergite, 6. 916
Titanolivine, 6. 846
Titanomagnetite, 7. 27, 28
Titanomorphite, 6. 840 ; 7. 3
Titanonium salts, 7. 82
Titano-olivine, 6. 386 ; 7. 54
Titanosic oxide, 7. 28
Titanosiderum, 7. 56
Titanosilicates, 7. 3
Titanosulphuric acid, 7. 92
Titanous acid, 7. 29
ammonium alum, 7. 92
sulphate, 7. 92
bromide, 7. 87
caesium alum, 7. 93
pentachloride, 7. 77
- chloride, 7. 75
- hydrosulphate, 7. 91
- hydroxide, 7. 29
- iodide, 7. 89
- oxide, 7. 28
� oxychloride, 7. 82
� potassium sulphate, 7. 93
� rubidium alum, 7. 93
pentachloride, 7. 77
sulphate, 7. 92
sodium sulphate, 7. 92
� sulphate, 7. 91
16. 375
Tolypite, 6. 624
Tombac, 4. 671 ; 15. 209
red, 4. 671
Viennese, 4. 671
Tombazite, 9. 310
INDEX
Titanous titanate, 7. 30
orthodisilicate, 6. 842
sulphate, 7. 95
sulphate, 7. 93
tetrarsenite, 0. 128
ate, 8. 5IO
16. 278
m-toluidinium bromosmate, 15. 723
o-toluidinium bromosmate, 15. 723
p-toluidinium bromosmate, 15. 723
p-toluoyl hexathionate, IO. 629
15. 723
Tolylammonium bromoplatinate, 16. 375
m-tolylammonium chlorosmate, 15. 719
o-tolylammonium chlorosmate, 15. 719
p-tolylammonium chlorosmate, 15. 719
ToIy ldimethy !ammonium bromoplatinate,
16. 375
Tolylenediammonium-1, 2, 4-chloropala
bromoplatinate,
bromoplatinate,
long, 8. 6
metric, 8. 6
net, 8. 6
short, 8. 6
Toneisenstein, 18. 775
Tonerde reine, 6. 338
Tong-pack, 15. 209
Tonne, 3. 6
Topaz, 2. 2 ; 6. 560 ; 7. 897
false, 6. 138
golden, 6. 562
oriental, 5. 247 ; 6. 562
Spanish, 6. 562
X-radiogram, 1. 642
Topazius, 6. 56O
Topfstein, 6. 43O
Tophas, 8. 814
Topic axes, 1. 656
parameters, 1. 656
Torberite, 12. 5
Torbernite, 12. 5, 133
Torendrikite, 6. 821
Torrelite, 5. 531 ; 9. 906
Torrensite, 6. 899 ; 12. 433
Torta, 8. 304
Totaigite, 6. 423
Total energy, 1. 717
Totan, 4. 4Ol
Totia, 4. 398
Toxicas's alloy, 15. 21O
Touchstone, 6. 14O
Tough pitch copper, 3. 27
Tourmaline, 2. 2 ; 5. 4 ; 6. 74O ; 7. 897
apyre, 6. 741
ferrous, 6. 742
lithium, 6. 742
� X-radiogram, 1. 642
Tourmalines alkali, 6. 741, 742
chrome, 6. 742
ferric. 6. 742
iron, 6. 741
Tourmalinic acid, 6. 742
Towanito, 3. 7 ; 14. 184
Transition point, 1. 513
action of pressure, 1. 429
temperature, 3. 113
Translation banding, 12. 895
lines of, 12. 895
Translations streifung, 12. 895
Transmutation of elements, 4. 147
metals, 1. 49
Transparency to X-rays, 4. 33
Transport numbers, 1. 985, 986
HittorTs, 1. 985
Transvaalite, 14. 424, 586 ; 15. 6
Traversellite, 6. 409. 416
Traversoite, 6. 344
Travertine, 8. 814 ; 6. 81
Treenium, 4. 205
Tremolite, 6. 391, 404
Trevorite, 12. 531 ; 18. 925 ; 15. 6
Tria prima, 1. 34
Triad, 1. 224
Triads, 1. 206
Dobereiner's, 1. 253
Triamide, 8. 329
Triatnidodiphosphoric acid, 8. 711
Triamminodichloroaquo-salts, 11. 416
Trianhydrosulphatophosphorio acid, 10. 346
Triantimonio acid, 8. 443
Triaquotriammines, 11. 402
Troaquotribromides, 11. 406
Triarsenatonianganio acid, 9. 22O
Triazane, 8. 329
vol*, aevr.
INDEX 785
diphosphatobisethylenediaminos, 14.
71O
diphosphatobispropylenediamines, 14.
71O
hexol-hexammines, 14. 710
salts, 14. 7IO
Tricobaltous disodium trimetaphosphato,
14. 854
_ henicosihydrate, 14. 854
sodium trimetaphosphate, 14. 854
Tridymite a-, 6. 24O
analyses, 6. 242
�,-, 6. 240
/5,-, 6. 24O
fibrous, 6. 240
preparation, 6. 237
3 E
GENERAL INDEX
Triethoxymonosilane, 6. 218
Triethyl phosphates, 8. 966
Triethylammonium bromoiridate, 15. 776
bromopalladate, 15. 678
bromoperruthenite, 15. 638
bromoruthenate, 15. 538
bromosmate, 16. 723
chloroiridate, 15. 770
chloropalladate, 16. 673
chloroperruthenite, 15. 532
chlororhodate, 15. 579
chlororuthenate, 15. 534
chloroamate, 16. 719
ferric chlorotribromide, 14. 125
trichlorobromide, 14. 125
Triethyloxyphosphoniurnchloroplatinate,
16. 315
Triferrous pentaferric, 18. 807
tetraferric oxide, 18. 807
Trigermane, 7. 264
Trigger reactions, 1. 358
Trigonal system, 1. 618
Trigonite, 7. 491 ; 9. 5, 132
Trihydrocalcite, 3. 822
Trihydrol, 1. 461
Trihydroxyaquodiammines, 11. 406
tetrahydrate, 11. 406
Trihydroxyaquodipyridinos, 11. 406
hexahydrate, 11. 406
Trihydroxyaquo-hexammines, 11. 408, 409
Trihydroxydiamidophosphoric acid, 8. 704
Trihydroxysitane, 6. 227
Triimide, 8. 329
Triimidodiphosphoric acid, 8. 711
Triimidotetraphosphoric acid, 8. 715
Tri-iodates, 2. 324
Triiodohydroxyiridic acid, 15. 779
Triiodosilane, 6. 982
Triiodylamine, 8. 606
Trimanganous sodium tetrasulphate, 12.
416
Trimerite, 4. 200 ; 6. 380, 381 ; 12. 150
Trimetaphosphimic acid, 8. 717
Trimetatolluric acid, 11. 88
Trimethyl platinic diamminoiodide, 16. 392
hydroxide, 16. 245
iodide, 16. 392
sulphate, 16. 405
Trimethylamine uranyl phosphate, 12. 132
Trimethylaminocarbonylfcriiodoplatinite,
16. 385
Trimethylammonium bromoiridate, 15. 776
bromopalladate, 15. 678
bromoperruthenite, 15. 538
=- bromoruthenate, 15. 538
bromosmate, 15. 722
chloroiridate, 15. 770
chloropalladate, 15. 673
chloroperruthenite, 15. 532
chlorohodate, 15. 579
chlororuthenate, 15. 534
chlorosmate, 15. 719
ferric fluoride, 14. 7
fluoferrate, 14. 8
� hexachloroperrhodite, 15. 579
molybdenyl tetrachloride, 11. 631
pentachloroferrate, 14. 101
ruthenate, 16. 518
Trimethyloxyphosphoniumohloroplatinate,
16. 315
547
periodates, 2. 417
Tungstatosodalite, 6. 583
Tungstato vanadates, 9. 785
Tungstein, 5. 496, 507
Tungsten, 5. 507 ; 11. 673, 674
INDEX 787
INDEX
periodates, 2. 406
Tungstene, 11. 674
Tungstenite, 11. 678, 856
Tungstic acid, 11. 762
61O
Turacine, 8. 8
Turanite, 9. 715, 767
Turbite, 4. 964
Turgite, 12. 631
Turite, 18. 874
Turjite, 13. 874
Turkey red, 13. 782
Turkish boracite, 5. 89
Turmale, 6. 74O
Turmali, 7. 98
Turnerite, 5. 523
Tumor's yellow, 2. 710 ; 7. 741, 742
Turpeth, 4. 964, 972
nitrous, 4. 989
Turpethura minerale, 4. 964
Turquoise, 5. 155, 368
bone, 5. 368
green, 14. 519
matrix, 5. 369
Tutanego, 4. 403
Tutenag, 4. 403
Tutenay, 15. 2IO
Tuteneque, 4- 403
Tutia, 4. 398, 399, 4Ol
alexandrina, 4. 5OO
blue, 4. 4Ol
green, 4. 401
white, 4. 4Ol
Tuttham, 4. 401
Tutthia, 4. 4Ol
Tutty, 14. 419
Tuxtlite, 6. 643
Tuyere, 12. 587
Tvattad, 12. 709
Twin, 1. 595
Twinning, 6. 670 ; 12. 891
albite, 6. 671
annealing, 12. 891
Haveno, 6. 671
Brazilian, 6. 246
Carlsbad, 0. 670
congenital* 12. 891
Dauphine, 6. 246
manebach, 6. 671
mimetic, 1. 595
of crystals, 1. 595
pericline, 6. 671
mixed, 1. 221
Tyrite, 5. 516 ; 9. 839 ; 12. 5
Tyrolite, 9. 5, 161
Tysonite, 2. 1 ; 5. 522 ; 12. 5
Tyuamyunite, 9. 716
Tyuyamunite, 9. 789
Tyuyamuyunite, 12. 5, 69
Tzanab, 8. 296
TJ
carbonatis, 7. 591
iodidi, 7. 591
TJhligite, 6. 855 ; 7. IOO, 137
Uigite, 6. 718
Ulexite, 3. 623 ; 5. 4, 93
Ullmanite X-radiogram, 1. 641
TJllmannite, 9. 343, 555 ; 15. 6
TJlrichite, 12. 5, 5O
Ultra-red rays, 4. 8
violet rays, 4. 8
TJltrabasite, 9. 552
Ultrafiltration, 1. 772
Ultramarine, 6. 586
ammonium, 6. 589
atnyl, 6. 59O
barium, 6. 59O
benzyl, 6. 59O
�� boron, 6. 59O
cadmium, 6. 59O
calcium, 6. 589
cobalt, 5. 298
ethyl, 6. 59O
ferrous, 6. 59O
germanium, 6. 59O
green, 6. 589, 591
lead, 6. 59O
�� blue, 6. 889
violet, 6. 889
manganese, 6. 59O
mercurous, 6. 590
native, 6. 43O
phenyl, 6. 59O
potassium, 6. 589
red, 6. 591
selenium, 6. 590
silver, 6. 589
tellurium, 6. 59O
violet, 6. 591
white, 0. 591, 594
yellow, 6. 591 ; 11. 273
zinc, 6. 59O
Undercooling, 1. 450
(Jngentum Aegyptiacum, 8. 120
Unghwarite, 6. 906 ; 12. 531
Unguentum hydrargyri rubri, 4. 916
Uniaxial crystals, 1. 607
Unionite, 6. 72O
Unitary theory matter, 4. 1
Units, electrical, 1. 963
of energy, 1. 693
Univariant systems, 1. 446, 447
Universal medicine, 1. 49
solvent, 1. 6O
Unoxidizable cast iron, 13. 545
Unsaturated, compounds, 4. 191
Unstable states, 1. 454
Unterniobsaure, 9. 862
Uraconite, 12. 5, 106
Uralite, 6. 426
Urallite, 6. 822
Uralorthite, 5. 509
Uranates, 12. 6O, 61
Uranbluthe, 12. 106
Uranglimmer, 12. 2
Urangummi, 12. 52
Uranic acid, 12. 58
hydratod, 12. 59
oxide, 12. 54
Uraninite, 5. 53O ; 7. 100, 491 ; 12. 5, 49
Uranisches Gummierz, 12. 52
Pittinerz, 12. 52
Uranite, 9. 787 ; 12. 1, 2, 5, 133
I, 4. 121
II, 4. 121
amalgam, 12. 38
ammonium hydroxydisulphotetraura
nate, 12. 97
hydroxyhydrodisulphotetraura
nate, 12. 97
oxytrifluoride, 12. 75
tetracarbonate, 12. 116
tungstate, 11. 797
analytical ractions, 12. 32
atomic number, 12. 36
weight, 12. 35
azide, 8. 354
barium hydroxydisulphotetrauranate,
12. 98
hydroxyhydrodisulphotetraura
nate, 12. 98
borotungstate, 5. Ill
bromides, 12. 91
calcium hydroxydisulphotetrauranate,
12. 98
metacolumbate, 9. 904
titanocolumbate, 9. 906
carbide, 5. 846
carbonates, 12. 112
chlorides, 12. 8O
chromite, 11. 2Ol
cobalt alloys, 14. 543
colloidal, 12. 13
copper alloys, 12. 38
decay of, 4. 120
descendants, 4. 126
dicarbide, 5. 890
dichromate, 11. 343
difluorido, 12. 73
INDEX
colloidal, 12. 4O
dihydrate, 12. 41
monohydrate, 12. 41
dioxytetrasulphide, 12. 95
diselenide, 10. 798
disilicide, 6. 194
disulphate, 12. 99
disulphide, 12. 94
disulphite, 10. 307
extraction, 12. 8
ferrous yttrium metatitanate, T. 59
fluorides, 12. 73
fluosilicate, 6. 956
hemipentoxide, 12. 39, 44
hemitrialuminide, 12. 38
hemitricarbide, 5. 89O
hemitrioxide, 12. 39
dihydrate, 12. 39
hydrate, 12. 39
hemitriselenide, 10. 798
hemitrisulphide, 12. 94
hexachloride, 12. 84
hexafiuoride, 12. 75
history, 12. 1
�� hydrazine hydroxydisulphotetrauranate,
12. 98
hydroxyhydrodisulphotetrauranate,
12. 98
hydrodisulphate, 12. 98
hydrohypophosphite, 8. 888
hydrophosphite, 8. 919
hydrosulphatosulphate, 12. 98
hypophosphite, 8. 888
iodides, 12. 91
iron alloys, 18. 643
calcium deuterohexacolumbate,
9. 905
titanocolumbate, 9. 905
deuterotetracolumbate, 9. 905
metacolumbate, 9. 905
isobutylalcosol, 12. 13
isolation, 12. 10
isotopes, 12. 36
lithium pyrophosphate, 12. 132
magnesium alloys, 12. 38
manganese alloys, 12. 218
iron alloys, 18. 668
mercury alloys, 12. 38
metavanadate, 9. 787
mica, 12. 2, 133
molybdate, 11. 571
trihydrate, 11. 571
molybdenum alloys, 12. 38
monosulphide, 12. 94
monoxide, 12. 39
nickel alloys, 16. 251
nitrates, 12. 117
occurrence, 12. 3
ochre, 12. 5
INDEX 791
oxides�intermediate, 12. 44
lower, 12. 39
oxychlorides, 12. 85
oxydifluoride, 12. 75
oxyfluorides, 12. 73
oxynitride, 8. 268
oxysulphides, 12. 94
oxytetrafluoride, 12. 77
pentabromide, 12. 92
pentachloride, 12. 83
pentitadinitride, 8. 13O
pent itatet rani tride, 8. 13O
pentoxynitride, 12. 62
peroxides, 12. 69
phosphates, 12. 128
phosphite, 8. 919
phosphodecachloride, 8. 1017; 12. 84
physiological action, 12. 32
tritaoctoxide, 12. 45
tritatetranitride, 8. 130
trithionate, IO. 609
tritungstate, 11. 811
tungstate, 11. 797
Uranmolybdate, 12. 5
Uranniobite, 12. 5O
Uranochalcite, 12. 5, HO; 15. 9
Uranochalzit, 12. HO
Uranocircito, 3. 625 ; 8. 734 ; 12. 5, 136
Uranocker, 12. 106
Uranokker, 12. 52
Uranomobite, 5. 516
Uranophane, 6. 883 ; 12. 5, 6O
Uranopilite, 3. 623 ; 12. 5, HO
Uranopitchblende, 12. 5
Uranopyrochlore, 9. 867
Uranosro oxide, 12. 45, 66
dihydrate, 12. 46
hexahydrate, 12. 46
hydra ted, 12. 46
arsenate, 9. 215
barium diphosphate, 12. 13O
hexachloride, 12. 83
bromide, 12. 18, 92
caesium hexachloride, 12. 83
calcium diphosphate, 12. 130
hexachloride. 12. 83
carbonate, 12. 112
chloride, 12. 1 8, 80
decoxytetrachloride, 12. 85
dihydropentasulphate, 12. 103
dihydrotrisulphate, 12. 103
dioxytetrachloride, 12. 85
INDEX 793
pentahydrate, 8. 889
disulphate, 12. 109
disulphite, 10. 308
hexafluoride, 12. 79
hydroxy sulphite, 10. 309
� � metaphosphate, 12. 18
� tetramminochloride, 12. 88
tetramminodifluoride, 12. 77
tetramminoiodide, 12. 94
tetramminonitrate, 12. 123
tetramminosulphate, 12. 107
tetraphosphate, 12. 132
thallium nickel nitrite, 8. 512
thallous disulphate, 12. 110
sulphate, 12. 17
tricarbonate, 12. 116
trinitrate, 12. 127
INDEX
8. 889
potassium pentahypophosphite, 8. 889
sodium pentahypophosphite, 8. 889
hexahydrate, 8. 889
XJranylvanadic acid, 9. 788
XJrao, 2. 424, 7IO
Urasite, 2. 656
TJrbaite, 5. 407
XJrbanite, 6. 915 ; 12. 15O
TJrdite, 5. 523
Urea, 18. 613
negative, 4. 191
positive, 4. 191
Valencianite, 6. 663
Valencies, affini-, 1. 225
- contra, 1. 212
- directed, 4. 186
- doctrine, 1. 222
alums, 9. 819
amalgam, 9. 783
ammonium tetroxydisulphate, 9. 825 occtirrence, 9. 715
arsenate, 9. 199 ochre, 3. 127 ; 9. 716, 748
184
Hofmann's process, 1. 185
Meyer's process, 1. 185
pressure, 1. 431
and. boiling-point, 1. 561, 565
molecular -weight of solute,
1. 548
558
Nernst's formula, 1. 434
of small drops, 1. 453
Kankine's formula, 1. 433
Raoult's law, 1. 550
van der Waals' formula, 1.
433
Vargasite, 6. 43O
Variables, dependent, 1. 446
independent, 1. 445
of a system, 1. 445
Variance of system, 1. 445
Variscite, 5. 155, 362 ; 8. 734
Varro, M. T., 1. 38
Varvacite, 12. 245
Varvicite, 12. 15O, 245
Vasheggite, 5. 366
Vasite, 5. 509
Vaterite, 3. 816
Vaucher's bearing alloy, 4. 671
Vaughan, T., 1. 48
Vaugrelinite, 7. 491 ; 11. 125
Vauquelin's red salt, 15. 667
Vauxite, 12. 53O ; 14. 395
Vedas, 1. 22
Vegasite, 14. 328, 349
Vegetable alkali, 2. 42O
Velardonite, 6. 692, 728
Velocity colloidal particles, 1. 776
sublimate, 8, 157
Venus* hair stone, 7. 34
Verd antique marble, 8. 815
Verde antiquo, 7. 357
de Corsioaduro, 6. 822
Verdigris, 8. 76, 270
Vergiiten, 18. 690
Vermeil!*, 6. 715
Vermieulito, 6. 609
Vermiculites, 6. 476, 603
Vermilion, 4. 944, 945
Veronese yellow, 7. 742
mangano, 6. 726
Veszelyite, 9. 182
Veszyelyite, 9. 5
Vibration frequency, 1. 828 ; 4. 7
ultramarine, 6. 591
Violobromide, 14. 729
Virginia silver, 15. 208
Viride montanum, 6. 343
Viridite, 6. 622, 921 ; 12. 531
Virtual work, principle of, 1. 714
Viscosities, colloids, 1. 774
Viscositv coefficient, 1. 749
fluids, 1. 749
Vitiated air, 1. 344
Vitrse lacrymae, 6. 53O
Vitreis guttis, 6. 53O
Vitroosil, 6. 288
Vitriol, 14. 242
blue, S. 234
� fresh, 1. 406
fusion heat of, 1. 428
gas, 1. 281
glass, 6. 317
boric acid, 5. 75
gravimetric composition, Dumas, 1.13O
Morley, 1. 132
ground, 1. 406
hard, 1. 407 ; 6. 78
in nature, 6. 81
heat conductivity, 1. 471
formation, 1. 489
ionization, 1. 477
influence in chemical action, 1. 377
ionizing constant, 1. 476
potential, 1. 476
Kerr's electro-optic effect, 1. 480
liquid, constitution, 1. 461
molecular state, 1. 460
Sutherland's theory constitution,
1.461
critical, 1. 438
properties, 6. 319
purification, 1. 409
rain, 1. 406, 407
Clarke's process, 6. 79
� lime process, 6. 79
soda process, 6. 79
soda-lime process, 6. 8O
tension, 1. 467
tensile strength, 1. 422
thermal expansion, 1. 412
to earth, transformation, 1.81
transition point, 1. 429
formulas, 1. 433
see Steam
sound, 1. 469
Verdet's constant, 1. 479
viscosity, 1. 465
volume effect pressure, 1. 410
synthesis, 1. 143
Cavendish, 1. 143
Hofmann, 1. 145
Wave -length, 4. 7
a-, 6. 354
P-, 6. 354
pseudo-, 6. 354
external, 1. 695
hardening, 13. 19
in changing volume of gases, 1. 69O
internal, 1. 699
maximum, 1. 703
of chemical reaction, 1. 73O
value of heat, 1. 719
virtual, principle of, 1. 714
Worobieffite, 6. 803
Worobyewite, 6. 803
Wrought iron, 12. 634, 709
Wullner's law, 1. 648
Wustite, 18. 702, 704
Wulfenite, 7. 491 ; 11. 488, 666
X-radiogram, 1. 642
Wurfelerz, 9. 226
Wyomingite, 5. 531
of, 4. 38
X-rays, 4. 31, 86
absorption coeff., mass, 4. 33, 34
exciting, 4. 32
fluorescent, 4. 35
hard, 4. 33
opacity to, 4. 33
penetrating power, 4. 33
primary, 4. 32
reflection, 4. 34
VOI*. XVI.
X-rays scattering, 4. 34
secondary, 4. 21
soft, 4. 33
transparency to, 4. 33
Xanorthite, 5. 509
Xantharsenite, 12. 15O
Xanthic acid, 6. 119
Xanthin, 5. 971
Xanthiosite, 9. 23O
Xanthitane, 6. 84O ; 7. 3
Xanthoarsenite, 9. 218
Xanthochromic dithionate, 10. 596
329
Xanthoxenite, 12. 531 ; 14. 409
Xenolite, 6. 456
Xenon, 7. 889
physical, 7. 900
Xenotime, 5. 527; 7. IOO, 185; 8. 734;
12. 6
sulphato, 5. 528
X-radiogram, 1. 642
Xiphonite, 6. 821
Xonotlite, 6. 36O
Xylene and hydrogen, 1. 304
Xylidinium-1 . 2 . 4-bromopalladite, 15. 677
Yang, 1. 23
Yanolite, 6. 911
Yellow atrament, 14. 329
cadmium, 4. 593
Cassel's, 7. 742
mineral, 7. 742
Turner's, 7. 741, 742
ultramarine, 6. 591 ; 11. 278
Veronese, 7. 742
Yenite, 6. 918
Yield point, 1. 819
Yin, 1. 23
3 F
802 GENERAL INDEX
isolation, 5. 705
Ytterbite, 5. 496, 508
Ytterbium, 5. 705
weight, 5. 706
borate, 5. 103
bromide, 5. 707
carbide, 5. 873
carbonate, 5. 707
chloride, 5. 707
chloroplatinate, 16. 330
chromate, 11. 288
hydroxide, 5. 707
hydroxyoarbonate, 5. 707
iodate, 2. 355
isolation, 5. 555
metaphosphate, 5. 708
metatungstate, 11. 826
nitrate, 5. 707
nitride, 8. 115
orthophosphate, 5. 708
- oxide, 5. 706
oxyehloride, 5. 707
oxymolybdate, 11. 565
oxyorthodecavanadate, 9. 775
oxytungstate, 11. 791
paramolybdate, 11. 587
para tungstate, 11. 819
properties, 5. 706
silicododecatungstate, 6. 880
sodium pyrophosphate, 5. 708
amalgam, 5. 680
ammonium carbonate, 5. 683
sulphate, 5. 682
analytical reactions, 5. 679
weight, 5. 680
bismuth sulphate, 9. 701
bromate, 2. 354
�- bromide, 5. 681
carbide, 5. 873
carbonate, 5. 682
chlorate, 2. 354
chloride, 5. 681
chloroaurate, 3. 595
chloroplatinate, 16. 330
chloroplatinite, 16. 284
chromate, 11. 288
dihydroarsenate, 9. 187
dihydrotetraselenite, 10. 832
dioxysulphate, 5. 682
dithionate, 10. 694
dodecanitritotriplatinite, 8. 521
ferrous uranium metatitanate, 7. 59
colloidal, 5. 681
iodate, 2. 354
iodide, 5. 681
isolation, 5. 553
isotopes, 5. 680
manganous nitrates, 12. 446
mercuric chloride, 5. 681
mercury alloys, 5. 681
metacolumbate, 9. 866
metaphosphate, 5. 684
metavanadate, 9. 775
molybdate, 11. 565
nitrate, 5. 683
nitrites, 8. 496
occurrence, 5. 676
orthoarsenate, 9. 187
orthocolumbate, 9. 866
� orthodisilicate, 5. 512
orthophosphate, 5. 684
oxide, 5. 680
oxynitrate, 5. 683
paratungstate, 11. 819
perchlorate, 2. 402
periodate, 2. 415
peroxide, 5. 681
potassium chromate, 11. 288
sulphate, 5. 682
preparation, 5. 678
properties, 5. 679
pyrophosphate, 5. 684
selenate enneahydrated, 10. 872
pyrophosphate, 5. 684
sulphate, 5. 682
sulphide, 5. 681
Yttroersite, 12. 6
Yttrofiuorite, 5. 52O
Yttrogarnet, 9. 839
Yttrogummite, 5. 515 ; 12. 5, 52
Yttroilmenite, 5. 616 ; 9. 839
Yttrotantalite, 5. 497, 516 ; 9. 839 ; 12. 5
Yttrotitanite, 6. 512 ; 6. 831 ; 7. 3
Yukonite, 9. 228 ; 12. 531
Zilver, 8. 295
aluminate, 5. 296
aluminite, 5. 354
aluminium alloys, 5. 237
copper alloys, 5. 24O
iron alloys, 13. 557
magnesium alloys, 5. 24O
nickel alloys, 15. 231
phosphate, 5. 371
sulphate, 5. 354
� aluminotungstate, 11. 789
� alunite, 5- 164
� amalgams, 4. 1037
� amide, 8- 260
� amidosulphonate, 8. 643
� aminomethyl sulphoxylate, 10. 162
axnmine, 8. 249
� amminochloromercuriato, 4. 861
� amminocblorosmate, 15. 72O
- amminochromate, 11. 277
monohydrate, 11. 277
amminometasilicate, 6. 441
amminonitrite, 8. 489
amminopotassamide, 8. 261
amminopyrophosphate, 4. 662
amminoselenite, 10. 827
amminosulphite, 10. 286
ammonium chromate, 11. 279
� cobaltous sulphate, 14. 782
�_� diamminobischromate, 11. 280
dihydrophosphate, 4. 661
dimetaphosphate, 4. 663
dithionate, IO. 592
��� ferrous sulphate, 14. 298
fluoride, 4. 534
hydroxydicarbonate, 4. 647
-� hyposulphite, 10. 183
manganous sulphate, 12. 423
nickelous sulphate, 15. 476
oxychlorides, 4. 546
� oxydodecachloride, 4. 546
oxyhenachloride, 4. 546
oxyhexadecachloride, 4. 546
oxyoctochloride, 4. 546
paramolybdate, 11. 586
paratungstate, 11. 819
- pentachloride, 4. 551, 552
persulphite, 10. 479
phosphate, 4. 661
monohydratod, 4. 661
polyiodido, 4. 581
selenate, 10. 865
sulphate, 4. 635
hexahydrated, 4. 635
sulphite, 10. 286
tetrachloride, 4. 552
tetraiodide, 4. 582
thiosulphate, 10. 546
triamminosexicliromate, 11. 280
tribromide, 4. 571
and stannous chlorides, 7. 434
thallium, 5. 427
anorthite, 6. 698
antimonatotriiodobromide, 9. 512
antimonite, 9- 432
arsenate hydrogel, 9. 180
arsenitomolybdate, 9. 131
atomic number, 4. 503
weight, 4. 5Ol
aside, 8. 35O
3 F
GENERAL INDEX
nitrate, 9. 7IO
Blanc de, 4. 607
blende, 4. 407 ; 7. 256. 897 ; 12. 16O
X-radiogram, 1. 640
bloom, 4. 408, 646
boracite, 5. 140
bromate, 2. 350
ammino-, 2. 350
bromide, 4. 564
____ dihydrated, 4. 567
monohydrated, 4. 566
. trihydrated, 4- 567
bromoaurate, 3. 607
� bromoiodobismuthite, 9. 677
bromopalladite, 15. 677
bromoplatinate, 16. 379
Buerre de, 4. 535
Butter of, 4. 535
�� pentachloride, 4. 557
pentaiodide, 4. 583
selenate, 10. 867
tetrabromide, 4. 572
� tetraiodide, 4. 583
calcium alloys, 4. 685
(di) orthodisilicate, 6. 444
hyposulphite, 10. 183
carbide, 5. 867
carbonate, 4. 642, 643
hemihydrated, 4. 643
monohydrated, 4. 643
carbonates basic, 4. 645
catalysis by, 1. 487
eerie nitrate, 5. 674
cerous nitrate, 5. 672
chlorate, 2. 349
ammino-, 2. 349
chloride, 4. 535 ; 13. 616
dihydrated, 4. 539
hemipentahydrated, 4. 540
monohydrated, 4. 54O
properties, chemical, 4. 548
physical, 4. 536
sesquihydrated, 4. 540
tetrahydrated, 4. 54O
trihydrated, 4. 540
chloroaurate, 3. 595
chlorobismuthite, 9. 667
chlorochromate, 11. 399
chloroiodide, 4. 581
chloromercuriate, 4. 861
ohloropalladate, 15. 673
ehloropalladite, 15. 67O
chloroplatinate, 16. 328
hexahydrate, 16. 329
chloroplatinite, 16. 283
ohloroplumbite, 7. 731
chlorostannate, 7. 449
chromate, 11. 277
monohydrate, 11. 277
chrome, 11. 278
� chloropyridinebisethylenediaminechloride,
14. 666
hexamminoiodide, 14. 743
_ � hexamminopentachloride, 14. 656
cobaltic oxytrinitrite, 8. 504
-� amminochloride, 4. 648
carbonate, 4. 648
dihydroxyhexametarsenite, 9. 127
� hydrosulphate, 4. 64O
-� manganese alloys, 12. 207
nickel-cobalt alloys, 15. 337
��� iron alloys, 15. 313
phosphatoarsenate, 9. 182
sulpharsenite, 9. 296
sulphates, 4. 639
basic, 4. 64O
cupric sulphide, 4. 604
cupride, 4. 672
decafluodicerate, 5. 638
decamminochrornate, 11. 278
deuterohexavanadate, 9. 773
diammine, 9. 773
dodecammine, 9. 773
� hexammine, 9. 773
diamidodiphosphate, 8. 711
diamminoazide, 8. 35O
diamminobromide, 4. 57O
diamminochloride, 4. 549
diamminodiiodotriarsenite, 9. 267
diamminoiodide, 4. 582
634
diamminosulphite, 10. 286
dianuninothiocarbonate, 6. 127
diamminothiosulphate, 10. 546
diamminotrioxydibromide, 4. 569
diamminotrioxydichloride, 4. 645
diamminoxide, 4. 624
diarsenatoctodecatungstate, 9. 214
diarsenide, 9. 66
dibenzylsulphone, 10. 162
diborate, 6. 100
dichromate, 11. 341
dihydrazinosulphite, 10. 286
GENERAL
� enneaoxydichloride, 4. 545
enneaoxydiiodide, 4. 58O
enneaoxy tetrachloride, 4. 545
ethylstannonate, 7. 41O
ethylsulphinate, 10. 163, 238
extraction, 4. 411
soln., 4. 415
-wet process, 4. 416
fayalite, 6. 906, 909
� felspar, 6. 662
ferrate, 18. 935
ferric alum, 14. 348
INT>EX 805
� hypochlorite, 2. 274
hypomolybdate, 11. 629
hyponitrite, 8. 414
hypophosphate, 8. 938
hypophosphite, 8. 885
iodate, 2. 350
ammino-, 2. 35O
-� iodide, 4. 574
. dihydrated, 4. 577
tetrahydrated, 4. 577
iodochloride, 4. 551, 581
iodoplatinate, 16. 391
iridium alloy, 15. 75O
iron alloys, .18. 543
hydroxyorthovanadate, 9. 777
� metasulpharsenatoxymolybdate, 9.332
metat^banate, 7. 55
metatungstate, 11. 826
hydrated, 4. 646
monoxydicarbonate, 4. 646
monohydrated, 4. 646
monoxydichloride, 4. 546
-� monoxynitrate, 4. 654
orthoarsenate, 9. 180
octohydrate, 9. 180
trihydrate* 9. 18O
orthoarsenite, 9. 127
Zinc orthoborate, 5. 1OO
orthodititanate, 7. 55
orthododecacoluinbate, 9. 866
orthophosphate, 4. 658
orthosilicate, 6. 438
monohydrated, 6. 442, 443
orthosulphoantimonate, 9. 575
orthosulphoantimonite, 9. 543
orthosulpharsenate, 9. 321
orthotitanate, 7. R5
osmiamate, 15. 728
osmium alloy, 15. 697
� oxalatodmitritohexarnminocobaltiate,
8. 51O
� oxide, 4. 506
properties, chemical, 4. 515
physical, 4. 5IO
� oxybischromate, 11. 279
� oxychromate, 11. 279
hemitrihydrate, 11. 279
monohydrate, 11. 279
oxydecachrornite, 11. 2OO
oxydibromide, 4. 57O
oxydichromite, 11. 2OO
oxydivanadyloctofluoride, 9. 8Ol
oxyhexachlorido, 4. 546
oxynitrito, 8. 489
oxypentafluocolumbato, 9. 874
oxyphosphide, 8. 843
oxysulphide, 4. 606
oxysulphoantimonate, 9. 575
oxytetrachromite, 11. 2OO
oxytrisphosphoryltrichloride, 8. 1026
oxy trisulphotungstate, 11. 860
palladium alloys, 15. 648
- pentanuoaluminate heptahydrated, 5.
310
- pentanuoferrate, 14. 8
- pentafluovanadite, 9. 797
- pentamminobromide, 4. 671
- pentamminochloride, 4. 55O
- pentamminodithionate, 10. 592
- pentamminoBulphate, 4. 633
- pentamminotetrathionate, 10. 619
- pentamminothioeulphate, 10. 546
- pen tapermanganite, 12. 278
- pentasulphide, 4. 607
- pentatbionate, 10. 628
- pentatungstate, 11. 829
- pentitahenicosixincide, 18. 544
- pentoxydibromide, 4. 569
heptabydrated, 4. 655
. octohydxated, 4. 655
tribydrated, 4. 655
- pentoxysulphate, 4. 626, 634
� pentoxytricarbonate, 4. 646
hexahydrated, 4. 646
perborate, 5. IdO
percblorate, 8. 400
peroobaltite, f 4, 602
INDEX
octohydrotetrahypophosphate, 8.
938
orthosulphoantimonite, 9. 543
paratungstate, 11. 819
pentanitrite, 8. 49O
persulphate, 10. 479
phosphate, 4. 661
pyrophosphate, 4. 663
trihydrate, 9. 182
pyrophoric alloys, 4. 495
pyrophosphate, 4. 661
pyrosulpharsenate, 9. 321
pyrosulpharsenatoxymolybdate, 9. 331
pyrosulphate, 10. 447
pyrovanadate, 9. 773
red oxide, 4. 506 ; 12. 15O
retorts, 4. 413
Belgian, 4. 413
Rhenish, 4. 413
Silesian, 4. 413
sulphate, 4. 638
hexahydrated, 4. 638
tetrachloride, 4. 557
samarium nitrate, 5. 672
selenate, 10. 865
_ silicododecatungstate, 6. 879
silver alloys, 4. 681
iodoazide, 8. 337
_ sulphide, 4. 604
. pyrophosphate, 4. 662
sulphate, 4. 636
tetrahydrated, 4. 636
sulphide, 4. 604
tetrachloride, 4. 554
tetrametaphosphate, 4. 664
tribromide, 4. 571
triiodide, 4. 583
trimetaphosphate, 4. 663
triphosphate, 4. 664
solubility of hydrogen, 1. 306
spongy, 4. 417
tetrachloride, 4. 558
subchloride, 4. 548
suboxide, 4. 505
subsulphide, 4. 586
sulfure, 6. 629
sulpharsenatosulphomolybdate, 9. 323
sulpharsenite, 9. 296
sulphate, 4. 612 ; 11. 831
ammines, 4. 633
complexes, 4. 633
dihydrated, 4. 615
-� phosphorescent, 4. 592
__ physical, 4. 593
sulphite, 10. 286
dihydrate, 10. 286
hemipentahydrate, 10. 286
monohydrate, IO. 286
sulphitodihyposulphite, 10. 183
-weight, 7. 118
borate, 5- 106
basic, 5. 106
bo ride, 5. 28
borocarbide, 5. 28
borotungstate, 5. HO
bromides, 7. 149
carbide, 5. 885
carbonate, 7. 160
chlorides, 7. 143
chromate, 11. 288
chromium steels, 18- 616
cobalt, 7. 117
colloidal, 7. 109
columbate, 9. 867
columbium, 7. 117
copper, 7. 116
� crystalline, 7. HO
cuprous trithiosulphate, 10- 550
decahydroxychromate, 11. 289
deeahydroxytrisulphate, 7. 157
decahydrated, 7. 156
dihydrated, 7. 156
dicarbide, 5. 885
dichloride, 7. 143
dihydride, 7. 114
dihydrotrisulphate, 7. 154
trihydrated, 7. 154
dihydrotrisulphide, 7. 154
monohydrated, 7. 154
dihy droxy trior thosilieate, 7- 846
dioxide, 7. 124
physical, 7. 1 25
disilicide, 6. 186
electronic structure, 7. 118
ferrite, 13. 921
fluorides, 7. 137
fluosilicate, 6. 955
gold, 7. 116
graphitic, 7. 106, 1IO
hemipentoxide, 7. 123
hemitrinitride, 8. 120
heptoxypentasulphide, 7. 165
dodecahydrate, 7. 155
hexacosioxypentachromate, 11. 289
hexahydroxychromate, 11. 289
hexaiodide, 7. 151
history, 7. 98
hydride, 7. 114
hydroarsenate, 9. 188
hydroazide, 8. 352
hydrophosphate, 7. 163
hydroxide hydrogel, 7. 131
hydrosol, 7. 130
hydroxides, 7. 128
hypophosphate, 8. 938
hypophosphite, 8. 886
iodate, 2. 354, 357
iodides, 7. 149
iron, 7. 117
I monoxide, 7. 123
nickel, 7. 117
alloys, 15. 232
columbium alloys, 16. 238
hexafluoride, 16. 405
octofLuoride, 15. 405
tantalum alloys, 16. 238
nitrate, 7. 161
pentahydrated, 7. 162
nitride, 8. 120
nitrites, 8. 497
occurrence, 7. 99
octohydroxychromate, 11. 289
octohydroxydiorthosilicate, 6. 847
octoxytetrachloride, 1. 147
orthoarsenate, 9. 188
orthosilicate, 6. 848
oxides, 7. 123
oxychloride, 11. 831
� oxychloromolybdate, 11. 565
oxychlorovanadate, 9. 776
--- oxysulphite, 10. 303
� oxytrisulphate, 7. 166
-� pentoxytrisulphate, 7. 155
� octohydrated, 7. 155
peroxide, 7. 131
phosphates, 7. 163
phosphide, 8. 847
phosphorus oxyhenichloiude, 7. 145
tridecachloride, 7. 145
phosphotridecachloride, 8. IO16
��� potassium carbonate, 7. 161
(di) octohydroxypentasulphate,
7. 159
diorthophosphate, 7. 164
nickel dodecafluoride* 15. 405
(tetra) octohydroxypentasulphate,
7. 159
tetrasulphate, 7. 159
. __ triorthophosphate, 7. 164
trioxydisulphate, 7. 158
tungstate, 11. 792
preparation, 7. 106
properties, chemical, 7. 114
physical, 7. HO
pyrophosphate, 7. 163
selenate, 10. 873
� � selenide, 10. 784
selenite, 10. 832
monohydrate, IO. 832
sesquioxide, 7. 123
silver, 7. 116
sodium calcium chlorotrimesotrisilicate,
6. 857
chlorotriorthosilicate, 6. 867
columbatosilicate, 6. 868
carbonate, 7. 161
octa-orthophosphate, 7. 164
tetraorthophosphate, 7. 164
tetrasulphate, 7. 159
triorthophosphate, 7. 164
solubility of hydrogen, 1. 306
sulpharsenate, 9. 322
sulpharsenite, 9. 297
sulphate, 7. 152
monohydrated, 7. 153
tetrahydrated, 7. 163
sulphide, 7. 152
sulphite, 10. 803
OENEKAL
INDEX 811