Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

stock conc. NaOH(CBs) 0.025 M M 1.0001834 Page (7 of 15)

stock conc. Et acetate(CAs) 0.03 M Va+Vb 2 L
Reactor Volume (Vr) 2 L 0.02Vb/0.02Va 1
Initial Molar ratio of reactants 1 Va 0.909 L
Operating Temperature (T) 35 °C Vb 1.091 L
Volume of NaOH added (Vb) 1091 mL Cao 0.013635 gmol/L
Volume of Et acetate added (Va) 909 mL Cbo 0.0136375 gmol/L

Time Time Conductivity Conductivity Cb Ca Xa f(Xa) 1/Ca-1/Cao Xa/1-Xa

(s) (min) (mS/cm) @30°C (mS/cm) @28°C (gmol/L) (gmol/L) (gmol/L)^-1
30 0.5 8.23 9.07 2.29E-03 2.29E-03 0.832 0.001 362.58 4.94
60 1 4.59 5.06 1.25E-03 1.25E-03 0.908 0.002 725.68 9.89
120 2 2.51 2.76 6.56E-04 6.56E-04 0.952 0.004 1451.42 19.79
180 3 1.78 1.96 4.47E-04 4.47E-04 0.967 0.005 2164.93 29.52
240 4 1.40 1.54 3.38E-04 3.38E-04 0.975 0.007 2885.71 39.35
300 5 1.17 1.29 2.72E-04 2.72E-04 0.980 0.009 3602.10 49.11
360 6 1.01 1.11 2.26E-04 2.26E-04 0.983 0.011 4346.47 59.26
420 7 0.90 0.99 1.95E-04 1.95E-04 0.986 0.013 5061.42 69.01
480 8 0.82 0.90 1.72E-04 1.72E-04 0.987 0.014 5746.03 78.35
540 9 0.75 0.83 1.52E-04 1.52E-04 0.989 0.016 6514.60 88.83
600 10 0.70 0.77 1.37E-04 1.37E-04 0.990 0.018 7200.81 98.18
660 11 0.66 0.73 1.26E-04 1.26E-04 0.991 0.019 7862.07 107.20
720 12 0.62 0.68 1.15E-04 1.15E-04 0.992 0.021 8655.57 118.02
780 13 0.59 0.65 1.06E-04 1.06E-04 0.992 0.023 9363.28 127.67
840 14 0.57 0.63 1.00E-04 1.00E-04 0.993 0.024 9902.49 135.02
900 15 0.54 0.59 9.17E-05 9.17E-05 0.993 0.027 10837.66 147.77
960 16 0.52 0.57 8.59E-05 8.59E-05 0.994 0.028 11565.01 157.69
1020 17 0.51 0.56 8.31E-05 8.31E-05 0.994 0.029 11966.31 163.16
1080 18 0.49 0.54 7.73E-05 7.73E-05 0.994 0.032 12858.07 175.32
1140 19 0.48 0.53 7.45E-05 7.45E-05 0.995 0.033 13355.39 182.10
1200 20 0.46 0.51 6.87E-05 6.87E-05 0.995 0.036 14474.36 197.36
1260 21 0.45 0.50 6.59E-05 6.59E-05 0.995 0.037 15106.81 205.98
1320 22 0.44 0.48 6.30E-05 6.30E-05 0.995 0.039 15796.75 215.39
1380 23 0.43 0.47 6.01E-05 6.01E-05 0.996 0.041 16552.40 225.69
1440 24 0.42 0.46 5.73E-05 5.73E-05 0.996 0.043 17383.60 237.03
1500 25 0.42 0.46 5.73E-05 5.73E-05 0.996 0.043 17383.60 237.03
1560 26 0.41 0.45 5.44E-05 5.44E-05 0.996 0.045 18302.29 249.55
1620 27 0.40 0.44 5.16E-05 5.16E-05 0.996 0.047 19323.04 263.47
1680 28 0.40 0.44 5.16E-05 5.16E-05 0.996 0.047 19323.04 263.47
1740 29 0.39 0.43 4.87E-05 4.87E-05 0.996 0.050 20463.87 279.02
1800 30 0.38 0.42 4.58E-05 4.58E-05 0.997 0.053 21747.29 296.52
1860 31 0.38 0.42 4.58E-05 4.58E-05 0.997 0.053 21747.29 296.52
1920 32 0.37 0.41 4.30E-05 4.30E-05 0.997 0.056 23201.80 316.36
1980 33 0.37 0.41 4.30E-05 4.30E-05 0.997 0.056 23201.80 316.36
2040 34 0.37 0.41 4.30E-05 4.30E-05 0.997 0.056 23201.80 316.36
2100 35 0.36 0.40 4.01E-05 4.01E-05 0.997 0.060 24864.07 339.02
2160 36 0.36 0.40 4.01E-05 4.01E-05 0.997 0.060 24864.07 339.02
2220 37 0.35 0.39 3.72E-05 3.72E-05 0.997 0.065 26782.03 365.17
2280 38 0.35 0.39 3.72E-05 3.72E-05 0.997 0.065 26782.03 365.17
2340 39 0.35 0.39 3.72E-05 3.72E-05 0.997 0.065 26782.03 365.17
2400 40 0.34 0.37 3.44E-05 3.44E-05 0.997 0.070 29019.60 395.68
2460 41 0.34 0.37 3.44E-05 3.44E-05 0.997 0.070 29019.60 395.68
2520 42 0.34 0.37 3.44E-05 3.44E-05 0.997 0.070 29019.60 395.68
2580 43 0.34 0.37 3.44E-05 3.44E-05 0.997 0.070 29019.60 395.68
2640 44 0.33 0.36 3.15E-05 3.15E-05 0.998 0.076 31663.93 431.74
2700 45 0.33 0.36 3.15E-05 3.15E-05 0.998 0.076 31663.93 431.74
2760 46 0.33 0.36 3.15E-05 3.15E-05 0.998 0.076 31663.93 431.74
2820 47 0.33 0.36 3.15E-05 3.15E-05 0.998 0.076 31663.93 431.74
2880 48 0.32 0.35 2.86E-05 2.86E-05 0.998 0.083 34837.01 475.00
2940 49 0.32 0.35 2.86E-05 2.86E-05 0.998 0.083 34837.01 475.00
3000 50 0.32 0.35 2.86E-05 2.86E-05 0.998 0.083 34837.01 475.00
3060 51 0.32 0.35 2.86E-05 2.86E-05 0.998 0.083 34837.01 475.00
3120 52 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3180 53 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3240 54 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3300 55 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3360 56 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3420 57 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3480 58 0.31 0.34 2.58E-05 2.58E-05 0.998 0.092 38715.06 527.88
3540 59 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3600 60 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3660 61 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3720 62 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3780 63 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3840 64 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3900 65 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
3960 66 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
4020 67 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97
4080 68 0.30 0.33 2.29E-05 2.29E-05 0.998 0.103 43562.39 593.97

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

Page (8 of 15)

f(Xa) vs time
0.120

0.100

0.080
y = 0.0017x
f(Xa)

R² = 0.9983

0.060

0.040

0.020

0.000
0 10 20 30 40 50 60 70 80
Time (min)

1/Ca-1/Cao vs t
50000.00

45000.00
1/Ca-1/Cao [(gmol/L)^(-1)]

40000.00

35000.00 y = 696.05x
R² = 0.9986

30000.00

25000.00

20000.00

15000.00

10000.00

5000.00

0.00
0 10 20 30 40 50 60 70 80
Time (min)

Xa/1-Xa vs t
700.00

600.00

500.00
y = 9.4907x
R² = 0.9986
Xa/1-Xa

400.00

300.00

200.00

100.00

0.00
0 10 20 30 40 50 60 70 80
Time (min)

k 690.21 gmol/L.min

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

stock conc. NaOH(CBs) 0.025 M M 1.0001834 Page (9 of 15)

stock conc. Et acetate(CAs) 0.03 M Va+Vb 2 L
Reactor Volume (Vr) 2 L 0.02Vb/0.02Va 1
Initial Molar ratio of reactants 1 Va 0.909 L
Operating Temperature (T) 40 °C Vb 1.091 L
Volume of NaOH added (Vb) 1091 mL Cao 0.013635 gmol/L
Volume of Et acetate added (Va) 909 mL Cbo 0.0136375 gmol/L

Time Time Conductivity Conductivity Cb Ca Xa 1/Ca-1/Cao Xa/1-Xa f(Xa)

(s) (min) (mS/cm) @40°C (mS/cm) @28°C (gmol/L) (gmol/L) (gmol/L)^-1
30 0.5 6.11 7.173 1.80E-03 1.80E-03 0.87 481.59 6.57 0.0012
60 1 3.37 3.956 9.66E-04 9.66E-04 0.93 962.22 13.12 0.0024
120 2 1.85 2.172 5.02E-04 5.02E-04 0.96 1919.91 26.18 0.0048
180 3 1.31 1.538 3.37E-04 3.37E-04 0.98 2895.21 39.48 0.0072
240 4 1.04 1.221 2.54E-04 2.54E-04 0.98 3856.71 52.59 0.0096
300 5 0.88 1.033 2.06E-04 2.06E-04 0.98 4790.21 65.31 0.0119
360 6 0.77 0.904 1.72E-04 1.72E-04 0.99 5739.44 78.26 0.0142
420 7 0.69 0.810 1.48E-04 1.48E-04 0.99 6701.01 91.37 0.0166
480 8 0.63 0.740 1.29E-04 1.29E-04 0.99 7660.54 104.45 0.0190
540 9 0.58 0.681 1.14E-04 1.14E-04 0.99 8695.57 118.56 0.0215
600 10 0.55 0.646 1.05E-04 1.05E-04 0.99 9461.18 129.00 0.0234
660 11 0.52 0.610 9.57E-05 9.57E-05 0.99 10373.27 141.44 0.0256
720 12 0.49 0.575 8.66E-05 8.66E-05 0.99 11478.33 156.51 0.0283
780 13 0.47 0.552 8.05E-05 8.05E-05 0.99 12354.76 168.46 0.0304
840 14 0.45 0.528 7.44E-05 7.44E-05 0.99 13375.11 182.37 0.0329
900 15 0.44 0.517 7.13E-05 7.13E-05 0.99 13950.80 190.22 0.0343
960 16 0.42 0.493 6.52E-05 6.52E-05 1.00 15263.89 208.12 0.0374
1020 17 0.41 0.481 6.21E-05 6.21E-05 1.00 16017.18 218.39 0.0393
1080 18 0.4 0.470 5.91E-05 5.91E-05 1.00 16848.28 229.73 0.0413
1140 19 0.39 0.458 5.60E-05 5.60E-05 1.00 17769.91 242.29 0.0435
1200 20 0.38 0.446 5.30E-05 5.30E-05 1.00 18797.72 256.31 0.0459
1260 21 0.37 0.434 4.99E-05 4.99E-05 1.00 19951.17 272.03 0.0487
1320 22 0.36 0.423 4.69E-05 4.69E-05 1.00 21254.81 289.81 0.0518
1380 23 0.36 0.423 4.69E-05 4.69E-05 1.00 21254.81 289.81 0.0518
1440 24 0.35 0.411 4.38E-05 4.38E-05 1.00 22740.00 310.06 0.0553
1500 25 0.35 0.411 4.38E-05 4.38E-05 1.00 22740.00 310.06 0.0553
1560 26 0.35 0.411 4.38E-05 4.38E-05 1.00 22740.00 310.06 0.0553
1620 27 0.34 0.399 4.08E-05 4.08E-05 1.00 24447.52 333.34 0.0593
1680 28 0.34 0.399 4.08E-05 4.08E-05 1.00 24447.52 333.34 0.0593
1740 29 0.33 0.387 3.77E-05 3.77E-05 1.00 26431.33 360.39 0.0640
1800 30 0.33 0.387 3.77E-05 3.77E-05 1.00 26431.33 360.39 0.0640
1860 31 0.32 0.376 3.47E-05 3.47E-05 1.00 28764.38 392.20 0.0694
1920 32 0.32 0.376 3.47E-05 3.47E-05 1.00 28764.38 392.20 0.0694
1980 33 0.32 0.376 3.47E-05 3.47E-05 1.00 28764.38 392.20 0.0694
2040 34 0.31 0.364 3.16E-05 3.16E-05 1.00 31547.81 430.15 0.0759
2100 35 0.31 0.364 3.16E-05 3.16E-05 1.00 31547.81 430.15 0.0759
2160 36 0.31 0.364 3.16E-05 3.16E-05 1.00 31547.81 430.15 0.0759
2220 37 0.3 0.352 2.86E-05 2.86E-05 1.00 34925.96 476.22 0.0837
2280 38 0.3 0.352 2.86E-05 2.86E-05 1.00 34925.96 476.22 0.0837
2340 39 0.3 0.352 2.86E-05 2.86E-05 1.00 34925.96 476.22 0.0837
2400 40 0.3 0.352 2.86E-05 2.86E-05 1.00 34925.96 476.22 0.0837
2460 41 0.3 0.352 2.86E-05 2.86E-05 1.00 34925.96 476.22 0.0837
2520 42 0.29 0.340 2.55E-05 2.55E-05 1.00 39112.23 533.30 0.0933
2580 43 0.29 0.340 2.55E-05 2.55E-05 1.00 39112.23 533.30 0.0933
2640 44 0.29 0.340 2.55E-05 2.55E-05 1.00 39112.23 533.30 0.0933
2700 45 0.29 0.340 2.55E-05 2.55E-05 1.00 39112.23 533.30 0.0933
2760 46 0.29 0.340 2.55E-05 2.55E-05 1.00 39112.23 533.30 0.0933
2820 47 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
2880 48 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
2940 49 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
3000 50 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
3060 51 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
3120 52 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053
3180 53 0.28 0.329 2.25E-05 2.25E-05 1.00 44435.99 605.88 0.1053

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

Page (10 of 15)

f(Xa) vs t
0.1200

0.1000

y = 0.0021x
0.0800 R² = 0.9982
f(Xa)

0.0600

0.0400

0.0200

0.0000
0 10 20 30 40 50 60
time (min)

1/Ca-1/Cao vs t
50000.00

45000.00
1/Ca-1/Cao [(gmol/L)^(-1)]

40000.00

35000.00 y = 896.13x
R² = 0.9986
30000.00

25000.00

20000.00

15000.00

10000.00

5000.00

0.00
0 10 20 30 40 50 60
Time (min)

Xa/1-Xa vs t
700.00

600.00

500.00 y = 12.219x
R² = 0.9986

400.00
Xa/1-Xa

300.00

200.00

100.00

0.00
0 10 20 30 40 50 60
Time (min)

k 877.43 gmol/L.min

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

stock conc. NaOH(CBs) 0.025 M M 1.0001834 Page (11 of 15)

stock conc. Et acetate(CAs) 0.03 M Va+Vb 2 L
Reactor Volume (Vr) 2 L 0.02Vb/0.02Va 1
Initial Molar ratio of reactants 1 Va 0.909 L
Operating Temperature (T) 45 °C Vb 1.091 L
Volume of NaOH added (Vb) 1091 mL Cao 0.013635 gmol/L
Volume of Et acetate added (Va) 909 mL Cbo 0.0136375 gmol/L

Time Time Conductivity Conductivity Cb Ca Xa 1/Ca-1/Cao Xa/1-Xa f(Xa)

(s) (min) (mS/cm) @45°C(mS/cm) @28°C(gmol/L) (gmol/L) (gmol/L)^-1
30 0.5 4.55 5.672 1.41E-03 1.41E-03 0.896 635.07 8.66 0.0016
60 1 2.49 3.104 7.44E-04 7.44E-04 0.945 1270.77 17.33 0.0032
120 2 1.38 1.720 3.84E-04 3.84E-04 0.972 2529.17 34.49 0.0063
180 3 0.99 1.234 2.58E-04 2.58E-04 0.981 3804.90 51.88 0.0095
240 4 0.8 0.997 1.96E-04 1.96E-04 0.986 5021.63 68.47 0.0125
300 5 0.68 0.848 1.57E-04 1.57E-04 0.988 6280.66 85.64 0.0156
360 6 0.6 0.748 1.31E-04 1.31E-04 0.990 7533.88 102.72 0.0187
420 7 0.54 0.673 1.12E-04 1.12E-04 0.992 8854.55 120.73 0.0219
480 8 0.5 0.623 9.90E-05 9.90E-05 0.993 10023.08 136.66 0.0247
540 9 0.47 0.586 8.93E-05 8.93E-05 0.993 11122.07 151.65 0.0274
600 10 0.44 0.548 7.96E-05 7.96E-05 0.994 12489.54 170.29 0.0307
660 11 0.42 0.524 7.31E-05 7.31E-05 0.995 13603.22 185.48 0.0334
720 12 0.4 0.499 6.66E-05 6.66E-05 0.995 14933.56 203.62 0.0366
780 13 0.38 0.474 6.02E-05 6.02E-05 0.996 16550.60 225.67 0.0405
840 14 0.37 0.461 5.69E-05 5.69E-05 0.996 17497.24 238.57 0.0428
900 15 0.36 0.449 5.37E-05 5.37E-05 0.996 18558.21 253.04 0.0453
960 16 0.35 0.436 5.04E-05 5.04E-05 0.996 19755.54 269.37 0.0482
1020 17 0.34 0.424 4.72E-05 4.72E-05 0.997 21117.32 287.93 0.0514
1080 18 0.33 0.411 4.39E-05 4.39E-05 0.997 22679.94 309.24 0.0551
1140 19 0.33 0.411 4.39E-05 4.39E-05 0.997 22679.94 309.24 0.0551
1200 20 0.32 0.399 4.07E-05 4.07E-05 0.997 24491.37 333.94 0.0594
1260 21 0.31 0.386 3.75E-05 3.75E-05 0.997 26616.17 362.91 0.0644
1320 22 0.31 0.386 3.75E-05 3.75E-05 0.997 26616.17 362.91 0.0644
1380 23 0.3 0.374 3.42E-05 3.42E-05 0.997 29143.36 397.37 0.0703
1440 24 0.3 0.374 3.42E-05 3.42E-05 0.997 29143.36 397.37 0.0703
1500 25 0.3 0.374 3.42E-05 3.42E-05 0.997 29143.36 397.37 0.0703
1560 26 0.29 0.361 3.10E-05 3.10E-05 0.998 32199.19 439.04 0.0774
1620 27 0.29 0.361 3.10E-05 3.10E-05 0.998 32199.19 439.04 0.0774
1680 28 0.28 0.349 2.77E-05 2.77E-05 0.998 35968.93 490.44 0.0861
1740 29 0.28 0.349 2.77E-05 2.77E-05 0.998 35968.93 490.44 0.0861
1800 30 0.28 0.349 2.77E-05 2.77E-05 0.998 35968.93 490.44 0.0861
1860 31 0.28 0.349 2.77E-05 2.77E-05 0.998 35968.93 490.44 0.0861
1920 32 0.27 0.337 2.45E-05 2.45E-05 0.998 40735.82 555.43 0.0970
1980 33 0.27 0.337 2.45E-05 2.45E-05 0.998 40735.82 555.43 0.0970
2040 34 0.27 0.337 2.45E-05 2.45E-05 0.998 40735.82 555.43 0.0970
2100 35 0.27 0.337 2.45E-05 2.45E-05 0.998 40735.82 555.43 0.0970
2160 36 0.27 0.337 2.45E-05 2.45E-05 0.998 40735.82 555.43 0.0970
2220 37 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110
2280 38 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110
2340 39 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110
2400 40 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110
2460 41 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110
2520 42 0.26 0.324 2.13E-05 2.13E-05 0.998 46955.83 640.24 0.1110

f(Xa) vs t
0.1400

0.1200

0.1000

0.0800 y = 0.0029x
R² = 0.9979
f(Xa)

0.0600

0.0400

0.0200

0.0000
0 5 10 15 20 25 30 35 40 45
Time (min)

1/Ca-1/Cao vs t

60000.00
1/Ca-1/Cao [(gmol/L)^(-1)]

50000.00

40000.00

y = 1203.8x
30000.00 R² = 0.9984

20000.00

10000.00

0.00
0 5 10 15 20 25 30 35 40 45
Time (min)

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020

Roll no.: 18CHE119

Page (12 of 15

Xa/1-Xa vs t

800.00

700.00

600.00
Xa/1-Xa

500.00

400.00
y = 16.414x
R² = 0.9984
300.00

200.00

100.00

0.00
0 5 10 15 20 25 30 35 40 45

Time (min)

k 1189.20 gmol/L.min

Kinetics of Batch Reactor

Name: Shubhalaxmi Diliip Swain Date: 12 / 10 / 2020
Roll no.: 18CHE119
Page (13 of 15)
k Temperature ln(k) 1/T
(gmol/L.min)(K) (1/K)
690.21 308.16 6.54 0.00325
877.43 313.16 6.78 0.00319
1189.2 318.16 7.08 0.00314

ko 22169870071 1/(gmol/L.min)
E 44315.2828 J/mol

ln(k) vs 1/T
7.50

7.00
lnk

6.50

6.00
y = -5330.2x + 23.822
R² = 0.9941
5.50

5.00
0.0031 0.0031 0.0032 0.0032 0.0032 0.0032 0.0032 0.0033
1/T (1/K)

Kinetics of Batch Reactor