10475 - LOCTITE 495 REVISION DATE: May 1993

SAFETY DATA SHEET

LOCTITE 495

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY:

PRODUCT NAME: LOCTITE 495

SYNONYMS, TRADE NAMES: Item no. 123297, Item no. 123298, VOCAB6010010051, VOCAB6010010052

PART No.: 123297,123298

SUPPLIER: Loctite (International) NBD,

Tallaght Business Park,
Whitestown, Dublin 24,
Ireland
TELEPHONE: +353-1-510433
FAX: +353-1-519073

2. COMPOSITION/INFORMATION ON INGREDIENTS:

INGREDIENT NAME: CAS No.: CONTENT HEALTH: RISK:

ETHYLCYANOACRYLATE 95 % NC
STABILIZER 0.1
POLYALKYLMETHACRYLATE 6% NC

3. HAZARDS IDENTIFICATION:

Bonds skin and eyes in seconds. Highly reactive to water. (See Section 4 - First Aid).

4. FIRST AID MEASURES:

SPECIFIC FIRST AID TREATMENT:

SPECIFIC NOTES FOR SUPER GLUES:
SKIN BONDING. Prise the skin apart slowly working from the edge of the bonded area. This can be eased by using
warm soapy water.
EYE BONDING. DO NOT force eye lids apart. Apply a pad soaked in warm water and allow the eye to separate itself.

INHALATION: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.

INGESTION: Provide rest, warmth and fresh air. Get medical attention immediately! Ensure that breathing passages are not obstructed.
The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate
the solidified product from the mouth (several hours).

SKIN: See Specific First Aid.

EYES: See Specific First Aid.

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5. FIRE FIGHTING MEASURES:

EXTINGUISHING MEDIA:
Use: Dry powder. Foam. and Carbon dioxide (CO2).

UNUSUAL FIRE & EXPLOSION HAZARDS:

Non-flammable. (flash point is greater than 80 deg.c ) (CC)

PROTECTIVE MEASURES IN FIRE:

Self contained breathing apparatus and suitable protective clothing must be worn in fire conditions.

6. ACCIDENTAL RELEASE MEASURES:

PERSONAL PRECAUTION IN SPILL:

Wear hydrocarbon-proof clothing, gloves, safety goggles and boots. Refer to Section 8 for more detailed information.

SPILL CLEANUP METHODS:

Ventilate well. Do not use cloths for mopping up. Polymerise with water and scrape off floor. Transfer to suitable
container for later disposal.

7. HANDLING AND STORAGE:

USAGE PRECAUTIONS:
Avoid contact with eyes, skin, and clothing. Provide good ventilation. Use of dispensing equipment is recommended to
minimise the risk of skin or eye contact.

STORAGE PRECAUTIONS:
Keep in original container. Store between 5°C and 28°C and do not return residual materials to containers as
contamination may reduse the shelf life of the bulk product.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:

INGREDIENT COMMENTS:
The TLV for the closely related methyl cyanoacrylate is 2 ppm (ACGIH, TWA).

PROTECTIVE EQUIPMENT:

VENTILATION: Provide adequate general and local exhaust ventilation.

PROTECTIVE GLOVES:
Use protective gloves made of: Polyethylene. or Polypropylene. DO NOT use PVC, rubber or nylon gloves.

EYE PROTECTION:
Use safety goggles and face shield in case of splash risk.

9. PHYSICAL AND CHEMICAL PROPERTIES:

APPEARANCE: Clear. Liquid.

ODOUR/TASTE: Sharp Characteristic.
SOLUBILITY DESCRIPTION: Immiscible with water.
BOILING POINT (°C, interval): >100 PRESSURE:
DENSITY/SPECIFIC GRAVITY (g/ml): 1.1 TEMPERATURE (°C): 20
VAPOUR PRESSURE: <0.5 mmHg TEMPERATURE (°C): 25

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FLASH POINT (°C): >80 METHOD: CC (Closed cup).

10. STABILITY AND REACTIVITY:

HAZARDOUS POLYMERIZATION:
Polymerisation will occur in the presence of moisture.

HAZARDOUS DECOMP. PRODUCTS:

Thermal decomposition may generate toxic fumes/ gases.

11. TOXICOLOGICAL INFORMATION:

INHALATION: High vapour concentrations may cause irritation to mucous membranes and respiratory tract. Prolonged exposure to high
concentrations of vapours may lead to chronic effects in sensitive individuals.

INGESTION: Low Oral Toxicity Acute oral LD50 > 5,000 mg/kg rat. It is almost impossible to swallow as it rapidly polymerises in the
mouth.

SKIN: Bonds skin in seconds. Low toxicity. Acute dermal toxicity: > 2,000 mg/kg rabbit.

EYES: Liquid product will bond eyelids. In a dry atmosphere (RH < 50%) vapours may cause irritation and lachrymatory effect.

12. ECOLOGICAL INFORMATION:

DEGRADABILITY:
Biodegradable

13. DISPOSAL CONSIDERATIONS:

DISPOSAL METHODS:
Polymerise by slowly adding to water (10:1). Dispose of in accordance with Local Authority requirements. Controlled
landfill or incineration.

14. TRANSPORT INFORMATION:

LABEL FOR CONVEYANCE:

ROAD TRANSPORT:
UN No. ROAD: 1993
ADR CLASS No.: Class 3: Flammable liquids.
ADR CLASS: 3
ADR ITEM No.: 32(c)
ADR LABEL No.: 3
PROPER SHIPPING NAME I: FLAMMABLE LIQUID, NOS

RAIL TRANSPORT:
RID CLASS No.: 3
RID ITEM No.: 32(c)

SEA TRANSPORT:
SEA TRANSPORT NOTES: Not Classified for Sea Transport

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AIR TRANSPORT:
AIR TRANSPORT NOTES: Not Classified for Air Transport

15. REGULATORY INFORMATION:

RISK PHRASES: Not classified.

SAFETY PHRASES: P-3 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of
children.

16. OTHER INFORMATION:

REVISION COMMENTS: PTTEP APPROVED MATERIAL

REVISION DATE: May 1993

REV. No./REPL. SDS GENERATED: 1 / All versions

SDS No.: 10475

SAFETY DATA SHEET STATUS: Approved.

DATE: 19/08/99

THIS SDS IS PRODUCED WITH SAFECHEM for WINDOWS

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