The document discusses nitrous acid preparation for methyl orange synthesis and compound selection for crossed aldol condensation reactions. It also provides questions about azo dye color formation, diazonium salt formation mechanisms, dibenzalaceton synthesis, benzamide preparation methods, and steam distillation advantages and disadvantages.
The document discusses nitrous acid preparation for methyl orange synthesis and compound selection for crossed aldol condensation reactions. It also provides questions about azo dye color formation, diazonium salt formation mechanisms, dibenzalaceton synthesis, benzamide preparation methods, and steam distillation advantages and disadvantages.
The document discusses nitrous acid preparation for methyl orange synthesis and compound selection for crossed aldol condensation reactions. It also provides questions about azo dye color formation, diazonium salt formation mechanisms, dibenzalaceton synthesis, benzamide preparation methods, and steam distillation advantages and disadvantages.
1Preparation of nitrous acid in site the reaction when synthesis methyl
orange? To avoid hydrolysis HNO2 as it is a weak acid that is unstable and decomposes at room temperature
2Primary aromatic amine is selected in methyl orange synthesis than
secondary or tertiary amines? Because the formation process requires two protein transformation not found in secondary or triple amines
3Aldehyde is an excellent reagent for crossed aldols? Because it does
not contain hydogens so it can form a enoalate
4The compounds used in a crossed aldol condensation must be
carefully selected? To avoid unwanted product mixture
5We heat the mixture of benzamide hydrolysis without reflux for 3-5 min?to get rid excess ammonia
6Hydrolysis of benzamide reaction is reversible reaction? Because the
benzoite ion is in the state of residence and wants stability
Q2: answer the questions 15points
How the azo dye compounds give color1
Light absoption
Stir up electrons: happen electorin transation-------Then the light is
emitted------Then it gives us the color
2Write the mechanism for diazonizonium salt formation
3Illustrate the mechanism of dibenzalaceton synthesis
4Write two preparation methods of benzamide?1Carboxylic acid
reacts with sulphuric dichloride oxide followed by ammonia
22Carboxylic acid interacts with ammonia followed by dehydration of
ammonium salt 5What are advantages and disadvantages of steam distillation/ Advantage: Quality Control. ..Advantage: Wide Application. ...Disadvantage: Higher Equipment and Operating Cost