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Alcohol Phenol Ether Full Assignment PDF
Alcohol Phenol Ether Full Assignment PDF
CHEMISTRY
Alcohol, Phenol & Ether
JKs Classes.
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Alcohols, Phenols & Ethers
Only ONE option is correct.
CH3 CH3
OH OH
2. 2 5 In this diol
O
+ H2O
A
(a) I < II < III (b) I < III < II (c) II < I < III (d) III < II < I
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+
5. H3O 1. B2H6 (excess)
Y H2C CH2 X.
2. H2O2 / OH
X and Y are
O CH3MgBr (excess)
O X , X is
6. H3 O
+
H3C OH HO
OH
(a) (b) OH
H3C H3C
OH
O O
(c) (d)
CH3
Mg /ether HCHO
7. Cl Br A, A is
+
H3O
MnO 2
8. CH2 CHCHCH2CH2OH A. A is
OH
O OH O
O O
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MnO 2
9. OH A, A is
OH
O OH O OH
O A O
10. O O A is
COOH CH2OH
O O
CH3
cold CrO3
12. alkaline KMno4 A B , A and B are
AcOH
CH3 CH3
OH OH
(a)
,
OH O
CH3 CH3
OH O
(b)
,
OH O
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CH3
CH3
OH
(c)
, OH
OH
NaBH4 H2/Pt
13. B CH CHCHO A,
A and B are
(c) CH CHCH2OH
(d) CH2CH2CH2OH
O HCHO
D , D is
H3O +
OH
(a) (c) (d)
(b)
H3C CH2OH CH2OH CH3
CH3 CH3 CH2OH
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H3O
16. R MgBr + A R and
CH3CH2CH2OH , A are
(a) CH3CH2 and HCHO (b) CH3 and CH2 CH2
17. HBO, oxymercuration-demercuration and acid catalysed hydration will give same product in
18. Rank the transition states that occur during the following reaction steps in order of increasing
stability (least most stable).
+ +
1. H3C OH2 CH3 + H2O
+ +
2. (CH3)3 C OH2 (CH3)3 C + H2O
+
3. (CH3)2 CH OH2 (CH3)2 CH + H2O
(a) 1 < 2 < 3 (b) 2 < 3 < 1 (c) 1 < 3 < 2 (d) 2 < 1 < 3
NaBH4
?
CH3OH
CO2H
OH O OH OH
20. What is the major organic product of the following sequence of reaction ?
O
OH OH
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21. Match the following
Column I Column II
(Alcohol/intermediate) (Grignard synthesis)
+
H 3O
CH2 CH2 + CH3MgBr
A CH3CH2CH2OH P
O
CH 3CHOH +
B Q H3O
CH3
CH3CH2MgBr + HCHO
CH3 O
H3O +
C CH3COH R CH3COCHCH3 + 2 CH3MgBr
CH3 CH3
O
D CH3CHO (intermediate) S H3O+
HCCH3CH3 + 2CH3MgBr
23. Alcoholic group at position ………. Reacts fastest with Lucas’ reagent.
O OH
HO OH
2 4
1 3 5
OH
25. Vitamin C also called ascorbic acid has number of COOH group ………… .
Step-Through Questions
(b) H2SO4
CH3 + CH3OH ...........
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(c) H2SO4
CH3 + CH3OH ...........
Hg(OAc)2 NaBH4
28. A, A is
CH3OH
OH O
(a) (b) (c) (d) OH
OH
OH
30. Decreasing order of reactivity of following alkyl halides in the Williamson’s ether synthesis is
(CH3)3CCH2Br (A), ClCH2CH CH2 (B), ClCH2CH2CH3 (C), BrCH2CH2CH3 (D)
(a) B > D > C > A (b) A > B > C > D (c) D > C > B > A (d) C > D > B > A
31. Consider the reaction of HI with the following
I: II :
O
O A
32. OH OH
OH
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OH
OC2H5
34. + C2H5I
anhy. C2H5OH
CH3 CH3
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45. Formaldehyde forms an addition product with CH3MgI which on hydrolysis gives :
(a) ethyl iodide (b) ethyl alcohol (c) methyl alcohol (d) methyl iodide
46. When CH3MgI is made to react with acetone and the addition product is hydrolysed, we get :
(a) primary alcohol (b) secondary alcohol (c) tertiary alcohol (d) an aldehyde
47. Identify (Z) in the following reaction series :
PBr3 Alc. KOH H2 SO4, room temp.
Ethanol (X) (Y) (Z)
H2O, heat
NH2 NH2 OH OH
OH
55. When 3,3-dimethyl butan-2-ol is heated with conc. H2SO4 the major product obtained is:
(a) 2,3-dimethyl but-1-ene (b) 3,3-dimethyl but-1-ene
(c) 2,3-dimethyl but-2-ene (d) cis and trans isomers of 2,3-dimethyl but-2-ene
56. The dimer of methanol will have the structure:
H
O O CH 3
(a) H O C H O CH3 (b) CH3 .
H H
H H
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H
57. 2-Phenylethanol may be prepared by the reaction of phenyl magnesium bromide with:
(a) HCHO (b) CH3CHO (c) CH3COCH3 (d) CH2 CH 2
58. Vinyl carbinol is:
OH O
(a) I > II > III > IV (b) I > III > II > IV (c) IV > III > II > I (d) IV > III > I > II
62. (CH3)3 CMgBr on reaction with D2O produces :
(a) (CH3)3CD (b) (CH3)3COD (c) (CD3)3 CD (d) (CD3)3OD
63. In the reaction given below, X is :
H2SO4
Neo-pentylalcohol X
(a) 2-methylpentane (b) Neo-pentane (c) 2-methylpent-2-ene (d) 2-methylbut-2-ene
64. Which one/ones of the following reactions will yield 2-propanol ?
+
H (i) CH MgI
(i) CH3CH CH2 + H2O (ii) CH3CHO (ii) 3
H 2O
(i) C H MgI
2 5 Neutral KMnO4
(iii) HCHO (ii) H O (iv) CH3CH CH2
2
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65. Which of the following enzymes convert glucose into ethyl alcohol ?
(a) Diastase (b) Invertase (c) Maltase (d) Zymase
66. Ethyl acetate reacts with CH3MgBr to form :
(a) secondary alcohol (b) tertiary alcohol
(c) primary alcohol and an acid (d) an acid
67. The correct order of boiling points for primary (1o), secondary (2 o) and tertiary alcohol (3o) is:
(a) 1 o > 2o > 3 o (b) 3 o > 2o > 1 o (c) 2 o > 1o > 3 o (d) 2 o > 3o > 1 o
68. Which one of the following will most readily be dehydrated in acidic condition ?
O OH OH O O
(a) (b) (c) (d)
CH3
74. CH3 +
H Br2
[F] C4H8Br2
H2O CCl4
5 such products
H3C OH are possible
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75. The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is :
(a) acidic permanganate (b) acidic dichromate
(c) chromic anhydride in glacial acetic acid (d) pyridinium chlorochromate
76. Acid catalysed hydration of alkenes except ethene leads to the formation of :
(a) primary alcohol (b) secondary or tertiary alcohol
(c) mixture of primary and secondary alcohols (d) mixture of secondary and tertiary alcohols
77. Which will give chiral molecule ?
LiAlH4 CH3MgBr
(a) CH3COCl (b) C2H5CHO +
H /H2O
H
Cu CH3
C C Cl2
(c) (CH3)2COC2H5 (d)
H3C CH3
78. A compound ‘X’ undergoes reduction with LiAlH4 to yield ‘Y’. When vapours of ‘Y’ are passed
over freshly reduced copper at 300 oC, ‘X’ is formed. What is ‘Y’ ?
(a) CH3COCH3 (b) CH3CHO (c) CH3CH2OH (d) CH3 O CH3
79. In the Victor Meyer’s test, the colours given by 1o, 2o and 3o alcohols are respectively :
(a) red, colourless, blue (b) red, blue, colourless
(c) colourless, red, blue (d) red, blue, violet (e) blue, red, violet
80. The major product formed in the following reaction is :
Aq. KOH
CH3CH(Cl)CH2CH2OH
H3C
83. P + Br2 Na
CH OH (X)
H3C
(X) is :
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CH3 CH3
CH3
H3C CH3
(c) CH CH (d) CH3 CH CH2CH2CH3
H3C CH3
TsCl KCN
(c) CH3CH2OH Pyridine CH3CH2OTs
PCl5 NaCN
(d) CH3CH2OH POCl , HCl CH3CH2Cl CH3CH2CN
3 NaCl
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(14) JKs : IIT-JEE Alcohols, Phenols & Ethers
This set contains questions with single correct answer :
92. Ethers are isomeric with monohydric alcohols. Both have the general formula :
(a) C nH2n+2O (b) CnH2nO (c) C nH2n+4O (d) CnH2n-2O
93. The IUPAC name of CH3OC2H5 is :
(a) ethoxy methane (b) methoxy ethane (c) ethyl methyl ether (d) methyl ethyl ether
94. The reaction,
C2H5ONa + C2H5I C2H5OC2H5 + NaI
is called
(a) Wurtz reaction (b) Kolbe’s reaction
(c) Williamson’s synthesis (d) Grignard synthesis
95. The product (D) in the following sequence of reactions is :
HBr NaOH(aq.) CH3I
C2H5 (A) (B) Na (C) (D)
(a) butane (b) ethane (c) propane (d) ethyl methyl ether
96. Ethers are obtained by reacting alkyl halides with :
(a) dry Ag 2O (b) moist Ag2O (c) dry ZnO (d) moist ZnO
97. According to Lewis concept of acids and bases, ethers are :
(a) neutral (b) acidic (c) basic (d) amphoteric
98. Oxygen atom of ether is :
(a) very active (b) replaceable (c) active (d) comparatively inert
99. The hybrid state of central oxygen atom in diethyl ether is :
(a) sp2 (b) sp3 (c) sp (d) sp3d
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(15) JKs : IIT-JEE Alcohols, Phenols & Ethers
105. Which of the following will not give anisole ?
(a) Phenol is reacted with dimethyl sulphate in presence of a base
(b) Sodium phenoxide is treated with methyl iodide
(c) Diazomethane is reacted with phenol
(d) Methyl magnesium iodide is treated with phenol
106. Anisole on treatment with Br2/CS2 gives :
(a) bromobenzene (b) methyl-2-bromophenyl ether
(c) o- and p-bromoanisole (d) phenol
(c) C H OC H (d)
6 5 3 7
O
hv C2H5OH + PCl3
(c) C2H5OC2H5 + Cl2 (d)
O
(C) is :
O
CH3
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(16) JKs : IIT-JEE Alcohols, Phenols & Ethers
Which of the following compounds will be formed ?
(a) CH3 CH CH OH + CH CH (b) CH3 CH CH3 + CH3CH2OH
2 3 3
CH3 CH3
CH3 CH3
112. From Williamson’s synthesis, the preparation of which of the following is possible ?
(a) Only symmetrical ethers (b) Only asymmetrical ethers
(c) Both (a) and (b) (d) None of the above
113. In which of the following reactions, the product obtained is tert. Butyl methyl ether?
CH3
Conc. H2SO4 HONa+
(a) CH3OH + HOCH2CH3 (b) CH3 C Br + CH3OH
CH3
CH3 CH3
+ +
(c) CH3Br + Na O C CH3 (d) CH3 ONa + CH3 C Br
CH3 CH3
This set contains the questions with two or more correct answers :
(c) I (d) OH
115. Which of the following reactions will give good yield of ether ?
OH OC2H5
(i) Na
(a) (ii) C2H5Br
(i) Na
(b) (CH3)3C OH C6H5 O C(CH3)3
(ii) C6H5 Br
(i) Na
(c) (CH3)3C OH (CH3)3C O CH2CH2CH3
(ii) CH3CH2CH2 Br
(i) Na
(d) CH3CH2CH2OH (ii) (CH3)3CBr
(CH3)3C O CH2CH2CH3
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(17) JKs : IIT-JEE Alcohols, Phenols & Ethers
116. Diethyl ether on treatment with HI in small amount, gives:
(a) C 2H5OH (b) C2H5I (c) C 4H10 (d) C3H7I
(a) Syn addition of –H (from BH3 ) and –OH (from solution) occur
Q.2.
OH
(a)
= (b) Br
Br CH2
(c) (d)
H OH H
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(18) JKs : IIT-JEE Alcohols, Phenols & Ethers
Q.4. Which of the following alcohols do not give white turbidity on treatment with HCl/ ZnCl 2 ?
CH3
OH
|
(a) CH3CH 2 OH (b) CH3 CH Ph
OH
(c) (d)
OH OH
(a) O (b) O
(c) (d)
O O O CH3
(c) CH3 CH O CH 3
HI
SN 2 (d) CH 3 O CH 2 CH 3
HI
SN 1
|
CH3
Q.8. Which of the following compounds will give positive Victor Meyer test ?
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(19) JKs : IIT-JEE Alcohols, Phenols & Ethers
CH3
|
(a) CH3CH 2 OH (b) CH 3 C O H
|
CH3
CH3
|
(c) CH3CH2 I (d) CH3 CH NO2
Q.9. Which of the following alcohols undergo rearrangement during dehydration reaction ?
CH 3 OH
|
(a) CH3 C CH CH 3 (b)
| |
CH3 OH
OH
CH 3
|
(c) (d) Ph CH CH CH3
|
OH
(a) aq, FeCl3 (b) Na metal (c) Tollen’s reagent (d) K 2Cr2 O7
O CH2
Q.11. The ether when treated with HI produces
C H 2O H
CH2I
(a) (b)
(c) I (d) OH
Q.12. Which of the following reaction will give ether as main product ?
OH
Na
(a) (b) Me3C OH
Na
C2H5Br C6 H 5Br
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(20) JKs : IIT-JEE Alcohols, Phenols & Ethers
(c) Me3C OH
Na
(d) CH3CH2 CH2 Br
Na
CH 3CH 2CH 2 Br Me3C Br
Q.18. Which of the following will oxidize to salt of acid by Br2 KOH ?
OH
(a) CH3 CH 2 OH (b)
CH CH3
OH
(c) (d) CH2OH
OH
Br
(a) H H (b) B is
A is H3C H
H3C OH
H H
A is H
OTs B is
(c) H2C (d) Br
H3C
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(21) JKs : IIT-JEE Alcohols, Phenols & Ethers
Conc.H2SO4 O3 OH
Q.20. A B C
OH
O
CH3
O
A is B is
(a) (b)
CH3
C is O C is O
(c) (d)
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ALCOH OL, PH EN OL & ET H ER (J EE-M AI N )
1. Picric acid is - [AIEEE-2002]
OH
COOH COOH NO2 COOH
NO2
3. The reaction of chloroform with alcoholic KOH and p-toluidine form- [AIEEE-2003]
4. An ether is more volatile than an alcohol having the same molecular formula. This is due to -
[AIEEE-2003]
(A) Inter molecular hydrogen bonding in ethers (B) Inter molecular hydrogen bonding in alcohols
(C) Dipolar character of ethers (D) Alcohols having resonance structures
5. When CH2 = CH–COOH is reduced with LiAlH4, the compound obtained will be - [AIEEE-2003]
(A) CH3–CH2–CH2OH (B) CH3–CH2–CHO (C) CH3–CH2–COOH (D) CH2=CH–CH2OH
7. Among the following compounds which can be dehydrated very easily is - [AIEEE-2004]
OH
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8. p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to
form, the compound B. The later on acidic hydrolysis gives chiral carboxylic acid. The structure of the
carboxylic acid is - [AIEEE-2005]
CH3 CH3
CH(OH)COOH
(A) (B)
CH(OH)COOH
OH OH
CH3
CH3
CH2COOH
(C) (D)
CH2COOH
OH
OH
9. The best reagent to convert pent–3–en–2–ol into pent –3–en –2–one is - [AIEEE-2005]
(A) Acidic dichromate (B) Acidic permanganate
(C) Pyridinium chloro-chromate (D) Chromic anhydride in glacial acetic acid
10. Among the following the one that gives positive iodoform test upon reaction with I2 and NaOH is-
[AIEEE-2006]
(A) CH3CH2CH(OH)CH2 CH3 (B) C6H5CH2 CH2 OH
CH3
11. HBr reacts with CH2 = CH – OCH3 under anhydrous conditions at room temperature to give -
(A) BrCH2CHO and CH3OH (B) BrCH2–CH2–OCH3 [AIEEE-2006]
(C) H3C–CHBr–OCH3 (D) CH3CHO and CH3Br
12. The structure of the compound that gives tribromo derivative on treatment with bromine water is -
[AIEEE-2006]
(A) butanal (B) n–butyl alcohol (C) n–propyl alcohol (D) propanal
14. Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives
[AIEEE-2008]
(A) 2, 4, 6– trinitrobenzene (B) o–nitrophenol
(C) p–nitrophenol (D) nitrobenzene
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15. The major product obtained on interaction of phenol with sodium hydroxide and carbon dioxide is :-
[AIEEE-2009]
(A) Salicylic acid (B) Phthalic acid (C) Benzoic acid (D) Salicyladehyde
16. From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2,
is :- [AIEEE-2010]
17. Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the above reaction
is :- [AIEEE-2011]
(A) Ethyl chloride (B) Ethyl ethanoate (C) Diethyl ether (D) 2–Butanone
18. Phenol is heated with a solution of mixture of KBr and KBrO3. The major product obtained in the above
reaction is :- [AIEEE-2011]
19. Compound (A), C8H9Br, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (A)
gives an acid (B), C8H6O4. (B) easily forms anhydride on heating. Identify the compound (A) :
[JEE-MAIN 2013]
CH2Br
CH2Br C2H5 CH2Br
(A) (B) (C) (D)
Br CH3
CH 3 CH3
20. An unknown alcohol is treated with the "Lucas reagent' to determine whether the alcohol is primary, secondary
or tertiary. Which alcohol reacts fastest and by what mechanism :- [JEE-MAIN 2013]
1 1
(A) secondary alcohol by SN (B) tertiary alcohol by SN
(C) secondary alcohol by SN2 (D) tertiary alcohol by SN2
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22. Sodium phenoxide when heated with CO2 under pressure at 1250 C yields a product which on acetylation
produces C. [JEE MAIN 2014]
ONa
125c H+
+CO2 5 Atm B Ac2O C
OCOCH3
OH
COOCH3
(A) (B)
COOH
OH
COCH3
OCOCH3
COOH
(C) (C)
COCH3
23. The most suitable reagent for the conversion of R CH 2 OH R CHO is [JEE MAIN 2014]
24. 2-chloro-2-methylpentane on reaction with sodium methoxide in methanol yields: [JEE MAIN 2016]
CH 3
| C2 H 5CH2 C CH 2 C2 H 5CH C CH 3
C H
(1). 2 5 CH 2 C OCH 3 (2).
|
(3). |
| CH 3 CH3
CH 3
(A) 1 And 3 (B) 3 only (C) (1) and (2) (D) all of these
25. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br2 to
form product B. A and B are respectively. [JEE MAIN 2018]
OH Br OH
(A) and
OCH3 OCH3
O O
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O O O O
(B) O and O
Br
O O O O
(C) O and O
Br
OH
OH
and
(D) OCH 3
OCH3
O Br O
26. The major product formed in the following reactions is [JEE MAIN 2018]
O HI
Heat
OH I
OH I
(A) (B)
OH I
I OH
(C) (D)
27. The major product of the following reaction is [JEE MAIN -(9-1-(M) 2019]
(i) Br2
(ii) EtOH
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OEt OEt
OEt
(A) (B)
Br Br
OEt Br
(C) (D)
28. The major product of the following reaction is [JEE MAIN -(9-1-(E) 2019]
O OH
CH3
O AlCl3,
+
OH OH
H3C CH3
O
O
(B)
(A)
OH OH
CH3 CH3
O
(C)
(D)
29. The major product obtained in the following reaction is [JEE MAIN -(9-1-(E) 2019]
OH
(CH3CO)2O/pyridine (1eqv.)
room temp
NH 2
COCH3
OH OCOCH3
NH2 NH2
(A) (B)
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OH
NHCOCH3 NHCOCH3
(C) (D)
30. The major product of the following reaction is [JEE MAIN -(10-1-(E) 2019]
CH 3
OH
(i) aq.NaOH
(ii) CH 3I
CH3 CH3
CH3 CH3
OH OCH3
OH OH
31. Which is the most suitable reagent for the following transformation? [JEE MAIN -(10-1-(E) 2019]
OH
|
CH 3 CH CH CH 2 CH 3
CH 3 CH CH CH 2CO2 H
(A) alkaline KMnO4 (B) I 2 / NaOH (C) Tollen’s reagent (D) CrO2 / CS 2
OH
|
CH 3CH 2 C CH 3
32. | cannot be prepared by [JEE MAIN -(12-1-(M) 2019]
Ph
33. An organic compound ‘X’ showing the following solubility profile is [JEE MAIN -(8-4-(M) 2019]
water
Insoluble
'x'
5% HCl
Insoluble
10% NaOH
Soluble
10% NaHCO3
Insoluble
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34. The major product of the following reactions: [JEE MAIN -(8-4-(M) 2019]
OCH3
CH=CH2
OH Br OH
Br
(A) (B) (C) (D)
35. The major product of the following reaction is [JEE MAIN -(9-4-(M) 2019]
1. PBr3
OH
2. KOH (alc.)
OH
O HO HO
(B) (C) (D)
O (A)
36. The major product of the following reaction is [JEE MAIN -(9-4-(M) 2019]
OH
CH2OH
H2SO4(cat.)
CHCl3
CO2Et
OH O
(A) (B)
OEt
COOH
O
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OH O
(C) (D)
O
CO2Et
O
Br O
O
Br
(B)
(A)
HO
HO
O O
Br
Br
(C) (D)
HO HO
39. The major product of the following reaction is [JEE MAIN -(10-4-(M) 2019]
O
HI(excess)
NC O
OH I OH I
(A) (B) (C) (D)
NC NC OH NC OH NC I
I
40. What will be the major product when m-cresol is reacdted with propargyl bromide
( HC C CH 2 Br ) in present of K 2CO3 in acetone [JEE MAIN -(12-4-(E) 2019]
OH OH
OH O
H3C H3 C H3C
CH3 CH3
(A) (B) (C) (D)
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41. Heating of 2-chloro-1-phenylbutane with EtOK/EtOH gives X as the major product. Reaction of X with
Hg OAc 2 / H 2O followed by NaBH 4 gives Y as the major product. Y is [JEE MAIN -(12-4-(E) 2019]
OH OH
44. The majoor product of the followig reaction is [JEE MAIN -(8-1-(M) 2020]
H3 C OH
dil.H2SO4
H3C H3C
OH CH 3
H 3C
(A) (B)
H 3C OH
OH CH 3
OH
H3C
CH 3
CH 3
H3C OH
(C) OH
(D)
OH H 3C
HO CH 3
H3C CH 3
45. Among the compounds A and B with molecular formula C9 H18O3 , A is having higher boiling point the B.
The possible structures of A and B are [JEE MAIN -(8-1-(E) 2020]
A=HO OH
HO
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B=H3CO OCH3 A=H3CO OCH3
(A)
OCH3 OCH3
B=HO
OH A=H3CO OCH3
(B)
OH
OCH3
B=HO OH A=HO
(C) OH
HO
HO
B=HO
OH
(D)
OH
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Page-33
NaOH(aq)/Br2
1. In the reaction the intermediate(s) is (are)
_
_ _
O O O O
Br
2. Identity the binary mixture(s) that can be separated into individual compounds, by differential
extraction, as shown in the given scheme. [+4, 0] [JEE-2012]
NaOH(aq)
Compound 1 + Compound 2
Binary mixture containing
Comound 1 and compound 2
NaHCO3(aq)
Compound 1 + Compound 2
SO 3H
OH OH OH
OH
Br Br Br
Br Br
Br Br Br
Br Br
SO3H SO3H
Br Br
P Q R S
(A) P (B) Q (C) R (D) S
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Page-34
OH
CHCl3
?
OH
CH3
OH O OH OH
OHC CHO CHO
P Q R S
(A) P (major) (B) Q (minor) (C) R (minor) (D) S (major)
5. The reactivity of compound Z with different halogens under appropriate conditions is given
below: [3, 0][JEE-2014]
mono halo substituted derivative when X2 = I2
OH
X2
di halo substituted derivative when X2 = Br2
acid
OR OH + ROH
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Page-35
HO
H3 C CH3
8. The major product U in the following reactions is [+4, -2] [JEE – 2015]
O H3C CH3
O
O
CH3
O H
(A) (B)
H
CH2
O O
O H
CH2
O
(C) (D)
NaOH
Q S
PhCH2Br
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Page-36
O O
O O
C OH
C O
H O
O
COOH
COOH [+4, -2] [JEE – 2016]
(A) LiAlH4 in (C2H5)2O (B) BH3 in THF
(C) NaBH4 in C2H5OH (D) Raney Ni / H2 in THF
Match each reaction in List –I with one or more products in List –II and choose the correct option.
(A) P1,5; Q2; R3; S4 (B) P1, 4; Q2; R4; S3
(C) P1, 4; Q1, 2; R3, 4; S4 (D) P4, 5; Q4; R4; S3, 4
ANSWER KEY
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