The eto charge unr jerel Of am jac sueshong iss jn uate. 3 a Define the term enthalpy change of solution. 4 gia. sobbor mart b 4.84 g of rubidium chloride, RbCI, were completely dissolved in 45.0 cm’ of water. The . temperature of the resulting solution fell by 3.60 °C. We dilue ) gage ato'c at Jy \ => gk FT Y O 43412 5 a (ji) 207 = 1424 J 120 shed 0830 ane arteg 7m i Use the information in Data sheet 7 to calculate the number of moles of rubidium chloride that dissolves, Calculate the amoffg energy absorbed yhen the rubidium chloride was dissolved. mnificant Heyes heat capacity of water 4) ive your answel ers of gb fm chloride, Give your answer to 418IK') 6 imental value Calculate the enthalp 3 significant figures. © Apart from heat losses in the apparatus, suggest two Aeasons why the ex may not be accurate. V Reaction of dbslty ery be se) ook ines hein oncctniy Ui teemone od pint. (A not dilwe omnomghWorksheet: Enthalpy changes from experiments Zn wd be 1 The apparatus shown on the right was used ) WY Cxuess to measure the enthalpy change (a) measure tone of aud | nemomeer of the reaction see Sony Blk alka aps bake NiSO.(aq) eerecaners sit Hae martha + Ni(s) + ZnSOx(aq) [7 Se ie were Describe how you would use this” ‘the apparatus to carry out an experiment to? “47 78. obtain data to calculate the enthalpy " . change of this reaction 100 cm 0.200 mot dar? NiSO, b- The results of the experiment are as follows: (1) Q= bye any volume of NiSO, solution = 100 cm’ XO Y initial temperature of NiSO, solution = 19.5 °C . anon, = $4°C 7 final temperature of NiSO, solution = 23.5°C “""'Y = Mer Vv specific heat capacity of water = 4.18 JK" (ii) 0-02 "4 Use these results to calculate: wer + ithe energy released in the reaction (i) ae ii the number of moles of NiSO, present in 100 cm’ of the 0.200 mol dm” solution tom iii the enthalpy change of the reaction. 1) vA Weed -treniHerd +2 Sebo tosey Fe ‘© What assumptions have been made when calculating the enthalpy change of this re¥tion? 0% ond What advantages are there of using the apparatus shown above to carry out the reaction, we momen rather than a glass beaker. Give =regons for your answer, ore nek eabiy vot [ob fo te oe ree Fy ant, his gy am aswel, juan ab Jurwrnhey (ok sethig jm th vemter Prune) 2 pigtthe ond dae in a Vert Prenta, 1¢ 6) Austr be pamt Let (ey) wich tae eh Sodthsy be Te some oo it a VAR 14 uncetanhy in Dace omar eis ayomal Ae 2 A spirit bumer containing ethanol is used to heat up 200 cm’ of water in a copper calorimeter. ty ae Calculate the enthalpy change of combustion of ethanol using the information below 3s qssoee ee initial temperature of water = 18°C DEZ7'C duns Oe Sembien ‘ 23 highest temperature of water reached = 45 °C Q= 2009 x Hy ‘xere 1-009 fond initial mass of spirit burner + ethanol = 196.6 g G+ 220727 nt spear hat final mass of spirit burner + ethanol = 195.5 g amd ly eit sree fic he capacity of water = 4.18.1 ‘ » . b2b4 met 55, molar mass of ethanol = 46 g mol 9 pet zasm,E Why is the value of the enthalpy change of combustion in this experiment so different ~ b 0.0234 from the data book value (AH, = -1367 kJ mol ')? Pek wer [ork fe HHe suvemetingy, JS rool loss phon eel