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  • 220 Will KUO of Of: I I Ose Ge

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    Michael G. Higgins
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    This document contains chemistry worksheets and problems. 1. It provides calculations for the melting point of ice being 283K and discusses why ice melting is endothermic and has a positive entropy change. 2. Questions ask about the spontaneity of processes at different temperatures and the sign of the Gibbs free energy change. 3. Calculations are shown for the Gibbs free energy change of a reaction being non-spontaneous at 500K but spontaneous at 297K.

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    This document contains chemistry worksheets and problems. 1. It provides calculations for the melting point of ice being 283K and discusses why ice melting is endothermic and has a positive entropy change. 2. Questions ask about the spontaneity of processes at different temperatures and the sign of the Gibbs free energy change. 3. Calculations are shown for the Gibbs free energy change of a reaction being non-spontaneous at 500K but spontaneous at 297K.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    20 views2 pages

    220 Will KUO of Of: I I Ose Ge

    Uploaded by

    Michael G. Higgins
    This document contains chemistry worksheets and problems. 1. It provides calculations for the melting point of ice being 283K and discusses why ice melting is endothermic and has a positive entropy change. 2. Questions ask about the spontaneity of processes at different temperatures and the sign of the Gibbs free energy change. 3. Calculations are shown for the Gibbs free energy change of a reaction being non-spontaneous at 500K but spontaneous at 297K.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 2

    HW 121

    Worksheet I 7
    I oH t
    oset
    oGe

    6030 22.1 5810 220


    6030 22.1 6030 O
    6030 22 I 6250 220

    a Weknowwaterwillmeltspontaneously at 283KUOc because OGforthereaction isnegativeat2831

    b ThemeltingoficeisendothermicbecauseOHisgreaterthenzerowhichistypicalofendothermicreactions
    c Theentropychargeforthemeltingofwaterispositivebecausetheentropyofliquidwaterishigherthantheentropyofsolid
    waterduetothefactthatliquidwaterhasmorestatesitcouldbeinasit isfree flowing not inasetcrystalstructurelikeice

    3 a Anincreaseintemperaturewilldecreasethespontaneityoftheprocess
    b T 0932 279K
    TheKachinisspontaneous whenTc279K atequilibriumwhenT 279kandisnonspontaneouswhenT 279K
    Y a Because ifitwere OH then wouldhavetobe reaction ofCaenCesend02cg which ethe
    f it a components

    ofcalciumcubonateintheiractualfirmstohimCacozandsincethisreactiondoesn'tincludeanyoneofthem
    OHun'tbeconsidered DHg

    b DSisthechangeinentropyfromtheceechnbtotheproducts
    c OG OH Tos
    G 177kt 500110.161kJ Thereactionwillbenon
    spontaneous at500Kbc at500KOGO

    oo 96.5KJ297KJ

    5 OG OH Tos
    f f T Tbuthegivenin
    151mi 151nAKelvin
    usually The.mn
    www.k.mnwmusedinea.uatrm
    6 a 2Ccs t 2Hug 02cg CHCOO
    Hee

    b 0SEESproducts Es's b
    eaten
    OSE 160.0 25.711 2430.6 205.0
    OSE 317.651kmoi

    c Gf OH ToSf
    Gf 298kto
    481151mi k.mil
    3116ks

    oof 5816h51mn

    d Yesthereaction is spontaneous at 25C because0Gtco

    7 a OG OH TDS
    OG 162.2151mi 298K 0.0745KJK.mn
    0 184.4151not

    b Yes thedecomposition ofNz0 willbespontaneous at298k all othertemperatures as well b c


    inorder forOGtobe so makingthereactionnonspontaneous Twouldhavetobenegativewhichisimpossible
    asthelowesttemperaturepossibleisOK

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