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HW 120

2019AP FRQ I

9a spahybridization
Ib
i

14 5.39garea omfgI.ae 0.0897moiwea 0090 ea


17.9M
go are

Id Endothermic bc accordingto LeChHiei'sprincipleaddingheattoasystemwillcausetheendothermic


wayofreaction tobe molarityofthesolutionincreasedasthetemperaturewent
favoredandbecausethe
up
itmeansbuttheforwardreactionwasfavoredbythetempincrease thusshowingthedissolutionofureaisendothermic

e Massofwaterused
Massofureadissolved
InitialTempofwater
FinalTempofwater

If uso Espaus Esoceanh


70 I sonwww.hcae 104.6
SEH 174.751mmol K
neon
Hua

UreamoleculesinaqueoussolutionhaveahigherentropythensolidWeabk in aqueousureatherearemore
1g
accangementsofmolecules Becauseofthis goingfromsolidtoaqueousurea o
increaseinentropy ureaispositive
soso.info

1h Because 05 ispositive asthetemperatureisincreased oG becomesmoreandmorenegativesothecoke


itbecomesmorethermodynamicallyfavorable

a 111
b Ii
c 212
d 111 10
e 212
10
f 11
g Y
h ll
2009APformB 5

5A

N N H NH
H

5b 12OgHz Indth gymo notHz 34KJ


5.94
5 H 68KJ 0695 68KJ
2.02GHz 3mulHz

Jc Thetotalbonddissociationenergyoftheproducts islarger b c moleenergyischeesedfromproductbonds


beingmade then is absorbed byreactantbondsbeing broken

5d The picduckshavelessentropythanthereactants b c thereare 4mulesofgasinthereactants


theproducts soRuehle
as opposed to 2molesintheproducts Theceeck hhavemorepossiblestatesthen
entropy islost inthe reaction giving itits negative DSvalue
atsome
point
Ie i Asthetempincreases themagnitudeof Tos willKeanegoateethanthemagnitudeofOHtherefore
changingthesign of OGfromregime topositivesince OS OH ie e me

Iii lowtemperaturesfavoritetheauctionb c it is exothermic byLe Chettreisprinciple


lowtemperatureskvoirktheexothermicsideof aceectron
Higherpressuresfavoritethecentron b c therecce lessmiles of
gas intheproductthen
inthe cecuhnb
By Le Che
Hier'spimplewhenthepressureofasystemisinverted thesystemhrois
thesideofKeihinthatproducesthetentnumberofmiles ofyes

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