Sample 60 marks

1 Marks Questions:
Atomic Structure[b,b,b,d,a]

1) Mass of one mole of which is not universally constant?

a) Cathode ray particles b) α particles
c) β particles d) Anode ray particles
2) What is the mass of one mole of neutrons?
a) N A grams b) N A u
1
c) grams d) ¿
2
3) Which orbital among these higher Z eff (effective nuclear charge)?
a) 4f b) 6s
c) 6p d) 7s
4) Which of these follow the octet rule?
a) H b) Pd
c) Ne d) Br
5) What is the correct structure for 111Rg?
a) [ Rn ] 5 p 14 6 d10 7 s 1 b) [ Rn ] 7 s 2 5 f 14 6 d 10
b) [ Xe ] 7 s 2 5 f 14 6 d10 d) [ Rn ] 7 s 2 5 f 14 6 d 9

Periodic Table[b,c, a,a,d]

1) Electron gain enthalpy _________ with ionization enthalpy.

a) Increases b) Decreases
c) Doesn’t depend d) Is constant
2) The f orbital starts filling up first in which element?
a) 57La b) 89Ac
c) 58Ce d) 90Th
3) Arrange in descending order of atomic radius : 45Rh, 45Rh-1, 45Rh+1, 46Pd, 47Ag, 47Ag+1
a) R h−1 > Rh> R h+1 > Pd> Ag> A g+1 b) R h−1 > Pd > Rh> R h +1> Ag> A g+1
c) R h−1 > Rh> Pd> Ag> R h+1 > A g+1 d) R h+1 > Rh> R h−1 > Ag> Pd> A g+1
4) Arrange in ascending order of ionization enthalpy : 3Li, 4Be, 5B, 6C, 7N, 8O, 9F, 10Ne
a) Li< B< Be<C <O< N < F < Ne b) Li< B< Be<C <O< N < F < Ne
c) Li< Be< B<C < N <O< F < Ne d) Be< B< Li< N < C<O< F < Ne
5) Which element has the least electron gain enthalpy?
a) Fr b) F
 c) Cs d) Cl

Chemical Bonding

1) What are the oxidation states of Oxygen in N a2 O, H 2 O 2 , OF , K O 2 ,CO , F e 3 O 4

a) b)
c) d)
+
2) Lewis dot structure for NO

a) b) Resonance between a and c

c) d) None
3)
a) b)
c) d)
4)
a) b)
c) d)
5)
a) b)
c) d)

2 Marks Questions:
Atomic Structure[b,d,a,b,b]

1) What is the number of moles of β particles required to neutralize a body which is composed solely of α
particles and is of mass 100 gram?
a) 25 b) 50
c) 100 d) 200
2) Which of the following is wrong with
E=energy ; ν=frequency ; λ=wavelength; ν=wave number ; T =time period ?
a) E ∙T is constant b) E ∙ λ is constant
1
c) E ∝ ν d) E ∝
ν
+¿ ¿
3) An electron of H e atom jumps from one orbital to another to produce a green light of frequency 541
nmk. Which one of these transitions may have been occurred?
a) 74 b) 53
c) 96 d) 21
4) What is the de Broglie wave frequency of an average human being of 50 Kg weight and running at a speed
of 2 m s−1?
a) 4.5 × 1043 Hz b) 3 ×1035 Hz
c) 6.6 ×10−36 Hz d) 2.4 × 1012 Hz
5) If the velocity of an electron of an exited Hydrogen atom is in the 4 th shell, and its velocity is calculated with
60% accuracy, find the % accuracy in measuring the distance of the electron from the nucleus.
a) 60 % b) 2 %
c) 0 % d) 15 %

Periodic Table[c,d,a,c,a]

1) What is the general last shell configuration for Group-11 elements?

a) ( n−1 ) f 14 n d 9 ( n+ 1 ) s2∨n d 9 ( n+1 ) s2 b) ( n−1 ) f 14 n d 10 ( n+1 ) s 1∨n d 9 ( n+1 ) s 2
c) ( n−1 ) f 14 n d 10 ( n+1 ) s 1∨n d 10 ( n+1 ) s1 d) ( n−1 ) f 14 n d 9 ( n+ 1 ) s2∨n d 10 ( n+1 ) s 1
2) Electron gain enthalpy of Oxygen at 25 ° C is −141 kJ mo l−1. Find its electron affinity.
a) 189.3 kJ mol-1 b) 158.6 kJ mol-1
c) 205.6 kJ mol-1 d) 147.2 kJ mol-1
3) What is the 3rd ionization enthalpy of Lithium?
a) 11815.16 kJ mol −1 b) 3932.33 kJ mo l−1
c) 520 kJ mol−1 d) 7085.47 kJ mol−1
4) Ionic radius of Lithium matches most with which of the following?
a) Be b) Na
c) Mg d) Al
5) Arrange on basis of acidity : MgO, CaO, Al2O3, Na2O
a) A l 2 O 3 > MgO>CaO > N a2 O b) N a2 O> CaO> MgO> A l 2 O 3
c) N a2 O> MgO>CaO> A l 2 O 3 d) A l 2 O3 >CaO > MgO> N a2 O3

Chemical Bonding

1)
a) b)
c) d)
2)
a) b)
c) d)
3)
a) b)
c) d)
4)
a) b)
c) d)
5)
 a) b)
c) d)

5 Marks Questions:
Atomic Structure[c]

 A sample of ground state lithium metal is irradiated with infinite amount gamma ray of
Time period=3.5 2×10−17 s. Find the exited state configuration of any atom of the lithium sample after
exposure. Find the velocity(ies) in which electrons will be ejected from the sample. Also, find the total
charge in 102 grams of the substance. Consider that gamma ray can penetrate lithium.
6
a) K 0 L0 M 0 N 0 O 2 , velocity is 5.533× 10 m/s b)
K 2 , velocity is 1.46× 10 m/s Charge ∈102 grams is1.64 × 106 C
6

Charge ∈102 gramsis 1.75 ×106 C

c) No electrons rema∈, velocities are d) K 2 L1 , electrons do n' t eject , no charge
5.533 ×106 m/s∧6.21 ×106 m/ s ,Charge ∈102 gramsis+5 × 106 C

Periodic Table[d]

 A sample of some element X is taken. Its hydride is XH. If the vapour density of its oxide is 93, calculate the
density of the sample at STP.
a) 3.2 g /cc b) 1.56 g/cc
c) 2.7 g/cc d) 3.3 ×10−3 g/ cc

Chemical Bonding


a) b)
c) d)