TAC BLACK-SLH(415),Okuno Chemical Industries Co., Ltd.

,37_360415_J_E1-1,04/07/2016 1/5

Date of issue: 04/07/2016

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertaking

Product identifier:
Product name: TAC BLACK-SLH(415)
Product code(SDS NO): 37_360415_J_E1-1
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the product: dyes
Details of the supplier of the safety data sheet
Manufacturer/Supplier: Okuno Chemical Industries Co., Ltd.
Address: 1-10-25 Hanaten-Higashi, Tsurumi-ku, Osaka 538-0044 Japan
Division: Quality Control , Metal Finishing
Telephone number: 81-6-6965-4119
FAX: 81-6-6962-9300
Emergency telephone number (24h): 81-6-6965-4119

2. Hazards identification
GHS classification and label elements of the product
Classification of the substance or mixture
Not applicable to GHS classification
Label elements
No Signal word
PRECAUTIONARY STATEMENT
Storage
Store in a dry place.
Keep cool.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/container in accordance with local/national regulation.

3. Composition/information on ingredients
Substance/Mixture:
Mixture

Ingredient name CAS No. Content(%)

Metal complex dyes 74920-95-9 44.4
Metal complex dyes 1330-39-8 1.8
Organic compound Private 40-45
Organic acid salt Private Leftover

4. First-aid measures
Descriptions of first-aid measures
IF INHALED
Right away, remove to fresh air place and stay quiet.
If necessary, seek medical attention.
IF ON SKIN（or hair）
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Remove any soiled clothing, and, with soap and plenty of water, wash well any part of the
body that has come into contact with the substance. If there is any inflammation of the
skin, seek medical attention.
IF IN EYES
Wash with running water for at least 15 minutes, then immediately seek attention of an eye
doctor.
When washing, hold the eyelid wide open with the fingers and make sure the water gets all
over the eye.
IF SWALLOWED
Have the victim drink plenty of water, induce vomiting and immediately seek medical
attention.
If the victim is unconscious, put nothing in the mouth.

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media
foam, dry powder, CO2, water.
Advice for firefighters
Specific fire-fighting measures
Using an extinguishing agent, extinguish fire from upwind and make anyone downwind of fire
evacuate the area.
Special protective equipment and precautions for fire-fighters
By burning or heating to high temperature, harmful gases such as carbon oxide, nitrogen
oxide or others will generate, so it is required to wear protective gas mask at fire
extinguishing.

6. Accidental release measures

Personnel precautions, protective equipment and emergency procedures
Wear proper protective equipment.
Stand at upwind. Evacuate personnel at downwind.
When working with the substance, wear appropriate protective gear (protective face mask,
protective gloves and clothes) and work upwind of material.
Be careful not to let the substance's dust, etc. get on the skin or be inhaled.
Environmental precautions
Prevent spills from entering sewers, watercourses or low areas.
Avoid raising dust.
Be careful not to let the substance cause environmental impact by draining into rivers, etc.
Methods and materials for containment and cleaning up
In case of leakage for big amount, keep off other persons from the leaked place by putting
rope or others.
Promptly recover in an empty container, by wiping up, vacuuming up, etc.
When recovering, use methods that cause the dust to drift as little as possible, and never
work downwind.

7. Handling and storage

Precautions for safe handling
Preventive measures
(Exposure Control for handling personnel)
Wear appropriate protective gear so that the substance is not inhaled or put in contact
with the eyes or skin.
After handling the substance, wash the hands, face and body well and gargle.
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Handle substance in a well-ventilated place, and if the indoor workplace, provide local
ventilation.
If the substance soils the work clothing, wash the soiled area well.
Be careful to prevent dust from drifting.
Exhaust/ventilator
Exhaust/ventilator should be available.
Safety treatments
Avoid contact with skin.
Avoid contact with eyes.
Prevent deposition of dust.
Safety Measures/Incompatibility
Avoid hot objects, sparks and fire, and avoid having the substance in contact with or mixed
with strongly acidic substances.
Avoid contact or mixing with water or humidity.
Conditions for safe storage, including any incompatibilities
Recommendation for storage
Store tightly sealed in a dry, cool place out of direct sunlight.
Incompatible storage condition
Do not leave near any heat source (such as a boiler) or near flammable materials.
Storage separately from strong oxidizing agents.
Recommendation on container and packaging materials
Use containers provided by Okuno Chemical Industries Co., Ltd.

8. Exposure controls/personal protection

Exposure controls
Appropriate engineering controls
Exhaust/ventilator should be available.
Eye wash station should be available.
Washing facilities should be available.
Individual protection measures
Respiratory protection
Wear respiratory protection.
Dust mask etc.
Hand protection
Wear protective gloves.
Eye protection
Wear eye/face protection.
Skin and body protection
Wear face protection (as specified by the manufacturer/supplier or the competent authority.)
Wear protective clothing.

9. Physical and Chemical Properties

Information on basic physical and chemical properties
Physical properties
Appearance: Solid（powder）
Color: Black
Odor: Characteristic
pH data N.A.
Phase change temperature
Initial Boiling Point/Boiling point data N.A.
Boiling range data N.A.
Flash point data N.A.
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Auto-ignition temperature data N.A.

Explosive properties data N.A.
Vapor pressure data N.A.
Specific gravity/Density data N.A.
Solubility
Solubility in water: Dissolve in water easily.
Other information
Not explosive. However, there is a risk of explosion if the dust mixes with air.

10. Stability and Reactivity

Chemical stability
Stable under normal storage/handling conditions.
Conditions to avoid
Do not heat to high temperatures.
Incompatible materials
Strong oxidizing agents, sparks, fire
Hazardous decomposition products
By burning, harmful gases such as carbon oxide, nitrogen oxide, sulfur oxides or others
will generate.

11. Toxicological Information

Information on toxicological effects
Acute toxicity
Acute toxicity (Oral), Product
Rat LD50 >5,000 mg/kg (Includes 50% lethal dose, etc.)
No Irritant properties data available
No Allergenic and sensitizing effects data available
No Mutagenic effects data available
No Carcinogenic effects data available
No Teratogenic effects data available
No reproductive toxicity data available
No STOT-single/repeated exposure data available
No Aspiration hazard data available

12. Ecological Information

Toxicity
No Aquatic toxicity data available
No Persistence and degradability data available
No Bioaccumulative potential data available
Mobility in soil
Based on physical and chemical properties, it may move to soil environments.
Ozone depleting chemical data not available

13. Disposal considerations

Waste treatment methods
When disposing of the powder itself, the allowable concentration is determined by the
wastewater standards (living environment items) of the Water Pollution Control Law; also,
the material counts as an industrial waste under the Waste Management and Public Cleansing
Law. These laws must be complied with.
Large amounts: Processing must be done by an external contractor. An industrial waste
 TAC BLACK-SLH(415),Okuno Chemical Industries Co., Ltd.,37_360415_J_E1-1,04/07/2016 5/5

manifest must be provided.

Small amounts: Because hazardous gases such as carbon monoxide, oxides of nitrogen, etc.
occur during incineration, the material must be incinerated and disposed of a small
quantity at a time, in an incinerator with a scrubber or other removal device.
Contaminated packing
Wash empty containers thoroughly with water and mix the wash liquid into the making bath
solution. Or, process with the technique above. Have an external contractor dispose of the
containers.

14. Transport Information

UN No, UN CLASS
Not applicable to UN NO.
Special precautions for user
The water getting wet and moisture are noted, make sure there is no leakage from the
container, and load so that the container will not be damaged by falling or tipping over.

15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture
Other regulatory information
Law Relating to the Prevention of Marine Pollution and Maritime Disaster：Not applicable.
Ship Safety Law : Not applicable.
Civil Aeronautics Law : Not applicable.

16. Other information

Reference Book
Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 18th edit., 2013 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012)
2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT)
2015 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php
Supplier's data/information
General Disclaimer
This information contained in this data sheet represents the best information currently
available to us. However, no warranty is made with respect to its completeness and we
assume no liability resulting from its use. It are advised to make their own tests to
determinate the safety and suitability of each such product or combination for their own
purposes.
The data given here is based on current knowledge and experience. The purpose of this
Safety Data Sheet is to describe the products in terms of their safety requirements. The
data does not signify any warranty with regard to the products' properties.

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