Pot B (2) 3:2

3) 4:9
>V
Vo 3Vo (4) 9:4

PART B (CHEMISTRY)
The correct IUPAC name of the compound 32. Select the correct pair for matching, species withn
31.
CI maximum number of H-atoms participating in
hyperconjugation.

Y S

(1) 3-Chloro-6-fluoro-3-methyl-4-ethoxyheptan-4-one
(1)

C(CH,),
A

(2) 3-Chloro-5-ethoxy-6-fluoro-5-methylheptan-4-one

(3) 5-Chloro-3-ethoxy-2-fluoro-5-methylheptan-4-one 3
(2)
(4) 5-Chloro-2-fluoro-5-ethylethoxyheptan-4-one

Work
Space for Rough
 for J E E
(Main)-2020
A dibasic organic acid consiste
Test-5(Code
All
India
Aakash
Test
Series 36.
and the rest oxygen. The
acid if 1.77 g of it is
40.6t 7% C, S0RL
molecular
neutralised
base is y 30 ula ot th
mL o
(1) HCO
(3) HC,O
(2)
HC
(4) HCO,
N

CH 27 The number of alkenes pos

formula CH, is with molec
(4) 8 (2) 4 ecuar
(3) 7 (4) 6
correct
The
The correct order of % enol
33. For the structure,
CHCH TH,.
38.
molecule is content for the
order of bond length is
olcowing
(1) 42 > 4 OMe
(2) 4 2
(3) 4, Il. Ph-C-CH2-C-Ph
4) 2 > > to
is subjected
34. 0.85 g of an organic compound I. CH-8-CH-Ph
e s t i m a t i o n of nitrogen
the
Kjeldahl's method for mL
neutralized 12.75
present The ammonia evolved,
thee
of nitrogen in
of 1 M H,SO. The percentage
compound is
(2) 31.5
(1) 21
Il<I Il V
(3) 63 (4) 42 (1) < <
(2) IV< ll<<
functional I< II lll IV
35. Which of the following molecule is not
a (3) < <
(4) I< lI< Il <IV
Identify the most stable
39
following.
electrophile from t
isomer of o-CH,?
OH
(1) H
(1) CHO
e) OH
(2)
OH
3) Ph-CH,
() (4)
OH OH (4) Ph-CH-ÓH,
Space for Rough Work

Aakash
MedicalilIT-JEE/ Foundatons
 Test-5(Code
ahich correctly represents the dia Aakash Test Series for JEE
the given chemical species?order
on
of
ae Ope of
of the 43.
(Main)-2020
The

nature

Consider the
A0 basic following tentative order ot idic
strength given by
NH2
NH2 NH2 OH
student. ad
OH
COOH

CF OCH
NO2 CN
(0)
NO2 NO2
The correct (1)
statement is
(2) 4ÖNH2 CH-CH-NH2 (1) Only (1) order is
correct
h-NH,>CH,NH, (2) Only (11) order is correct
(3) (3) Both () and (l1) order are
CH)NH> (CH)N (in benzene) correct
4) (4) Neither (1) nor (1) order is correct
method for estimat of sulphur,
2g of an 44. From the
In Carius
4.66 g of barium
following order of
select the incorrect order.
stability of carbocations
41.
organic c o m p o u n d

ercentage of lphur in the compound iss

sulphate.
(1) CH-CH2-H,
The
(Atomic
mass of Ba
=
137)
CI
>
CH-CH-CH2
(1) 32% (2) CH2-CH-NH, >
H,-- NH-CH
2 ) 64% CH3
(3) CH-C*> CH,=CH-CH2
(3) 4 8 %
CH
(4) 24%

45. Consider the following molecules

molecule
HN
In the CEN
42 D CH-CH CH-CH
II. CCH =
CH-CH
H Select the correct statement.
NH2
a
(1) For both I and , cis-isomer have greater dipole
moment than trans
basic nitrogen is
the most
(2) For both I and l, trans-isomer have greater dipole
(1) a moment than cis
have
(3) For 1, cis-isomer and for l1, trans-isomer
(2) b isomer
greater dipole moment than their respective
cis-isomer have
(3) C (4) For I, trans-isomer and for I,
greater dipole moment than their respective isome-
(4) d
Work
Space for Rough

7/1

kash
T-JEEIFoundations
h Educatonal Services Linsed)
 Which of the followina
Test-5(Co
(Main)-2020

Series for JEE 49.

cannot
shon Qeomat
Test
resonating
isomerism?
Aakash
not
the
india are
All which

The pair
of
molecule

other.
CaHa
46.
of e a c h A. CgH,M
CH
structures

CH=¢-H

CH- H
and
CHs
(1) B. (CH,)C = CH-CH= C(CH

CH- -NH2
and
CH-NH2

C. CH-CH = CH CHJ
(2) CH,-0=CH,
and

3)
CH-O- H,
C H = C = C H

about
CH
and
C H = C = C H ,
is
correct

to CH
4) following
statement

is applied
Which of the this
technique
volatile
and D.
47. when
steam
distillation,

substances
which
are
steam
CHs
separate
with
water?
when
the CHs
immiscible
boils
are
the liquid liquid (1) Only D
distillation,
due to
organic (2) A,B
(1) In
steam
to
and
(4) Aand Cony
pressures equal
A, B, C and D
becomes

Sum of vapour
(3)
Donly
vapours
water
and due
to
atmospheric pressure
mixture of
liquids
boils 50. Among the
llowing
statement(s) is/are statements, the
the less than
.

mixture is
distillation,
steam
(2) In of
Formic acid is
when the vapour
pressure

S : a
stronger acid than
thar aceic
atmospheric pressure liquid
distillation,
the organic
steam
(3) During
S , :Acidic strength of CH=CH

(4)
decompose

For steam
distillation,

water soluble
the organic
compound

greater than acetic acid CH-C-OH s

should be considered
as
not
following is
Which of the
48.
structure of
p-nitrophenoxide?
S:Acidicstrength of CH,=CH- s lesser
resonating than acetic acid

S: The acidic strength of CH,=OH-

(2)
(1) more than CH OH

(1) Only S
-ON
(2) S, and S, only
(3) S,, S, and S, only
(4)
(3) (4) S. S and S only
Work
Space for Rough

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MedicallITJEE Founiras

8/14
Test 5(Code-c)

organic compound is ated with All India Aakash Test Series for JEE (Main)-2020
agent oxidising
fused mass is extracted with water. (1) H> H,
ike Na,2 and

o" jike solution conc. HNO, and ammonium

>H> Ha H
(2) H> H.> H,>
To this
resulting in formation of
a d d e d result
is
Ha> H
molybdate
orecipitates. The colour of precipitates and (3) H>H, > H,
element H> H
>

prech this test is performed is (4) H,> H,> H,>

for which

-Chlorine 4.
H> H.
Which of the following
groups, when attached
(1) White
to
Bromine
(2) Orange
zene ring will increase the electron density on
Sulphur and nitrogen the ring to maximum
(9) Red extent?
(4) Yelloww Phosphorus (1) -NO2 (2)-OH
Which
of the followingg molecule has maximumh
of geometrical isomers?
number (3) -NH-C-CH (4) - O
CH=C=CH2 . Which of the following cannot show tautomerism?
(1) O

C
(1) (CH),c-CHO

(2)
OH
() (4)
(3)
CH=C-Ç=CHC
56. Consider the
H H following resonating structures and
(4) select the correct statement.
Find out the correct order of acidic strength of thee
indicated protons in the given molecules. . CH2=CH-C-O Il. CH=CH-C=0

I. CH2CH=C-0
(1) Stability order of resonating structures is
H >1l>
(2) In resonance hybrid contribution of structure llI
is maximum

(3) Structure I and Il contribute equally towards

resonance hybrid
(4) Stability order of resonating structures is
Ha
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Foundatlons
1ercas Linited
9/14
 est-
ndergoingSCodec
the given molecule
(Main)-2020
ho
C o n s i d e r

59 of C-H bond.
J E E
fission
for a n d
C.
S e r i e s
B
A,
Test
compounds
Aakash

Al
India
following

2
the
Consider

57.
p
H The
correct
of
order of
C-H bond is
homolytic bond
A.
energy

(1) C-H,CH,>C-H, diSSOciation

(2) C-H>C-H2> cH,
(3) C-HCH,> C-H,
(4) CHCH,>C-H
How many
of the followina
C.
60. r e s o n a n c e ?

ecules show
NH NH
the
NH2
0 abstraction
of
of HN
order
of
e a s e
of
based
on
stability
H-N NH
EtNH
correct
atom

The hydrogen

indicated

conjugate base

CH3
(1) HpHa H a
NHCHO CH NH2 O=ÇNHCHO
Ha
(2) Hp Ha
(3) Hp>Ho >Hr
H
(4) Hp Ha homolysis,
undergoing

58. For the

compounds
NH
C H C H H and C H C H H -OCH
statement.
correct
Select the (1) 5
- b>a
(1) Bond length
(2) 8
b>a
(2) Bond strength
(3) 7
d>c
(3) Bond length
(4) 9
Cd
(4) Bond strength
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Space for Rough

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0/14 MedicalIT-E| Foundhiavd