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Course Outcome
• Distinguish and illustrate the source, impact and control
infrastructure related to air, noise, water pollution and
solid waste.
Learning Outcome
At the end of this lecture, student should be able to
discuss:
• To describe the types, sources and effect of air
pollution.
• To explain the impact of air pollutants on human &
environment.
• To determine the measurement tools of air pollutants.
• To discuss the limit of air pollutants exposure.
• To discuss the control infrastructure of air pollution.
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Outline
2.1 Types of air pollution (gases & particulates)
2.2 Sources of air pollution (indoor & outdoor air pollution)
2.3 Dispersion of air pollution
2.4 Effects of air pollution (human health, vegetation &
material)
2.5 Measurements of air pollution
(high volume sampler: particulate)
(glass bubbler/diffuser: gases)
2.6 Emission Standards and Air Quality Index
2.7 Control infrastructure
(particulate pollutants: centrifugal collector, bag
filter, settling chambers, electrostatic precipitators)
(gaseous pollutants: absorber, adsorber, incinerator,
condenser)
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WHAT IS AIR POLLUTION?
• Is the presence in the outdoor atmosphere of
one or more air contaminants (dust, fumes, gas,
mist, odor, smoke, or vapor) in sufficient
quantities, of such characteristics, and of such
duration as to be or to threaten to be injurious to
human, plant or animal life or to property, or
which reasonably interferes with the
comfortable enjoyment of life or property.
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Hi
everyone
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2.1 Types of air pollution (gases & particulates)
AIR
POLLUTANTS
GASEOUS PARTICULATE
(GASEOUS & CHEMICAL
(SOLID & LIQUID STATE)
VAPOUR STATE)
SETTLEABLE
- larger particles
- 10µm diameter
SUSPENDABLE
- Smaller particles
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2.1 Types of air pollution (gases & particulates)
GASEOUS
(GASEOUS & CHEMICAL VAPOUR STATE)
Gaseous pollutants such as SO2, Cl2, NOx, mercury or organic vapour are
miscible with air in all proportions.
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2.1 Types of air pollution (gases & particulates)
Gaseous
Carbon Oxides
Pollutants
• Carbon Monoxide is a dangerous, poisonous
pollutant that harms our environment in many
ways. The major source of CO is incomplete
combustion of fossil fuels like coal, wood, charcoal
etc. Even exhaust from cars contains small amounts
of Carbon Monoxide.
• Carbon Dioxide is actually an essential element for
human survival because plants need it to perform
photosynthesis. However it is currently present in
our atmosphere and our surroundings, in extremely
large quantities, and this is harmful to humans.
Carbon Dioxide is mainly released due to the
burning of fossil fuels. From manufacturing
activities to running our cars to launching rockets
they all need to burn fossil fuels. This is why it is so
hard to control the emissions of CO2.
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2.1 Types of air pollution (gases & particulates)
Gaseous
Carbon Oxides
Pollutants
SOURCE
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2.1 Types of air pollution (gases & particulates)
Gaseous
Sulphur Oxides
Pollutants
• Major source for Sulphur Dioxide (SO2) is the
combustion of coal and petroleum products that
contain sulphur. One natural source of Sulphur
oxides is volcanic eruptions and hot springs. Other
sources are thermal power station, oil refineries
and copper industries.
• This may also get oxidized and turn to Sulphur
Trioxide (SO3). And then when reacted with
moisture or water it becomes Sulphuric Acid
(H2SO4) and precipitates on Earth as Acid Rain.
• Sulphur Dioxide (SO2) in particular is a nasty
pollutant that is very dangerous in high
concentration. In fact, these pollutants can cause
respiratory distress and lung diseases in humans.
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2.1 Types of air pollution (gases & particulates)
Gaseous
Nitrous Oxides
Pollutants
• Nitrogen the most abundant gas in our atmosphere.
(78% composition in air). However, oxides of
nitrogen are a major pollutant of atmospheric
pollution. Nitrous oxides (N2O) are majorly released
by vehicle emissions. Other natural activity that
produces nitrogen oxides is lightning. When lightning
strikes dioxygen and dinitrogen combine at very high
temperatures. Common products containing oxides
of nitrogen include nitrate fertilisers. Cigarette smoke
and other fuel burning activities, such as wood
burning heaters, can be sources of oxides of
nitrogen.
• Nitrogen Dioxide (NO2) is one of the most dangerous
pollutants there is. It has a red-brown color that one
often sees over traffic jams and in fumes coming out
of factories.
• To humans, it is particularly harmful as it directly
attacks our respiratory systems. It is toxic to plants
too and slows down their photosynthesis rate.
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2.1 Types of air pollution (gases & particulates)
Gaseous
Volatile Organic Compounds (VOCs)
Pollutants
• Organic chemicals that have a high vapor pressure at
ordinary room temperature.
• VOCs include a variety of chemicals, some of which may
have short- and long-term adverse health effects.
• Concentrations of many VOCs are consistently higher
indoors (up to ten times higher) than outdoors.
• VOCs are released from burning fuel such as gasoline,
wood, coal, or natural gas. They are also released from
many consumer products:
Building Copy
Air fresheners materials and machines and Pesticide
furnishings printers
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2.1 Types of air pollution (gases & particulates)
PARTICULATE
(SOLID & LIQUID STATE)
Particulate matter is the sum of all solid and liquid particles suspended in
air many of which are hazardous. This complex mixture includes both
organic and inorganic particles, such as dust, pollen, soot, smoke, and liquid
droplets.
These particles vary greatly in size, composition, and origin. Can only be
detected using an electron microscope.
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2.1 Types of air pollution (gases & particulates)
Coarse particles
• The coarse fraction contains the larger
Particulate particles with a size ranging from 2.5 to 10 µm
Pollutants (PM10 - PM2.5).
• Produced by the mechanical break-up of larger
solid particles. The coarse fraction can include
dust from roads, agricultural processes,
uncovered soil or mining operations, as well as
non-combustible materials released when
burning fossil fuels.
Fine particles
• The fine fraction contains the smaller
ones with a size up to 2.5 µm (PM2.5).
The particles in the fine fraction which
are smaller than 0.1 µm are called
ultrafine particles.
• Ultrafine particles (up to 0.1 µm) are
formed by nucleation, which is the initial
stage in which gas becomes a particle.
These particles can grow up to a size of
1 µm either through condensation,
when additional gas condensates on
the particles, or through coagulation,
when two or more particles combine to
form a larger particle.
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2.1 Types of air pollution (gases & particulates)
Particulate
Pollutants
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2.1 Types of air pollution (gases & particulates)
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Photochemical Smog Formation
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Photochemical Smog Formation
• Primary pollutants
– The two major primary pollutants, nitrogen oxides and VOCs, combine
to change in sunlight in a series of chemical reactions, outlined below,
to create what are known as secondary pollutants.
• Secondary pollutants
– The secondary pollutant that causes the most concern is the ozone
that forms at ground level. While ozone is produced naturally in the
upper atmosphere, it is a dangerous substance when found at ground
level. Many other hazardous substances are also formed, such as
peroxyacetyl nitrate (PAN).
• Major Sources of Photochemical Smog
– While nitrogen oxides and VOCs are produced biogenically (in nature),
there are also major anthropogenic (man-made) emissions of both.
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Photochemical Smog
• Harmful Effects
– Photochemical smog can have an effect on the environment, on people’s
health and even on various materials. The main visible effect is the brown
haze that can be seen above many cities. The brown tinge is caused by very
small liquid and solid particles scattering the light.
• Plants
– Chemicals such as nitrogen oxides, ozone and peroxyacetyl nitrate (PAN) can
have harmful effects on plants. These substances can reduce or even stop
growth in plants by reducing photosynthesis. Ozone, even in small
quantities, can achieve this, but PAN is even more toxic to plants than ozone.
• Materials
– Ozone can damage various compounds. It can cause the cracking of rubber,
the reduction in tensile strength of textiles, fading of dyed fibres and
cracking of paint. Ozone’s potential to damage artworks and books is of
cultural importance, and some museums and libraries have taken steps to
minimize this effect.
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Photochemical Smog
• Human Health
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2.1 Types of air pollution (gases & particulates)
CLASSIFICATION OF AIR POLLUTANT
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2.2 Sources of air pollution (indoor & outdoor air pollution)
SOURCE OF AIR
POLLUTION
NATURAL ANTHROPOGENIC
Volcanic eruption
Mobile sources
Lightning
Forest fire - cars, buses, planes, trucks, and
Dust storm trains
Stationary sources
- power plants, oil refineries,
industrial facilities, and factories
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2.2 Sources of air pollution (indoor & outdoor air pollution)
Indoor
Pollution
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2.2 Sources of air pollution (indoor & outdoor air pollution)
Indoor
Pollution
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2.2 Sources of air pollution (indoor & outdoor air pollution)
Here are some tips and best practices that you can implement to fix
indoor air pollution problem.
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2.3 Dispersion of air pollution
Sunshine, rain, air temperature and wind can affect the amount of air pollution
present:
• Higher air temperatures - speed up chemical reactions in the air.
• Wind speed, atmospheric turbulence/stability, and mixing depth - affect the
dispersal and dilution of pollutants.
Dispersion refers to what happens to the pollution during and after its
introduction; understanding this may help in identifying and controlling it.
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
Primary factors
affecting
transport and
dispersion of
pollutants
Atmospheric
Wind direction
stability
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
is the rate at which an atmospheric variable,
LAPSE RATE normally temperature in Earth's atmosphere,
changes with altitude.
• Environmental Lapse Rate (ELR)
LAPSE RATE TYPES • Dry Adiabatic Lapse Rate (DALR)
• Saturated / Wet Adiabatic Lapse Rate (SALR)
Atmospheric stability determines whether or not air will rise and cause storms, sink
and cause clear skies, or essentially do nothing. Stability is dependent upon the Dry
and Saturated Adiabatic Lapse Rates and the Environmental Lapse Rate.
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
STABILITY
• Tendency of an air parcel to move vertically following an initial dislocation (up or down).
• To determine stability, vertical motions of air parcels are assumed to be adiabatic processes.
• Rising parcels expand and cool, sinking parcels are compressed and warm.
• An Unsaturated (Dry) parcel will always rise and sink at 9.8˚C/km – known as Dry Adiabatic Lapse Rate.
• When parcels rise and cool, they will become saturated (Wet). As they continue to rise, the water vapor
will condense into liquid water (cloud). So instead of cooling usually around 6˚C /km it is known as Wet
Adiabatic Lapse Rate.
• Ambient Or Environment Lapse Rate: The actual atmospheric temperature change with altitude; not only
does water content modify lapse rates, but wind, sunlight on the Earth’s surface, and geographical features
change actual lapse rates.
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
STABILITY
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
STABILITY
Superadiabatic: ELR > DALR. It indicates unstable atmosphere. Vertical motion and mixing
processes are enhanced. Dispersion of pollution plume is enhanced. Tending to rise.
Subadiabatic: ELR < DALR. It indicates stable atmosphere, vertical motion, and mixing are
suppressed. Dispersion is suppressed, and contamination is trapped. Tending to sink.
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
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2.3 Dispersion of air pollution
LAPSE RATES AND ATMOSPHERIC STABILITY
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
In the stable atmosphere case (producing a fanning plume), there is horizontal dispersion
at a right angle to the wind due to turbulence and diffusion. In the vertical, dispersion is
suppressed by the stability of the atmosphere, so pollution does not spread toward the
ground. This results in very low pollution concentrations at the ground.
In unstable air, the plume will whip up and down as the atmosphere mixes around
(whenever an air parcel goes up, there must be air going down someplace else to
maintain continuity, and the plume follows these air currents). This gives the plume the
appearance that it is looping around.
An inversion a loft will trap pollutants underneath it, since the stable inversion prevents
vertical dispersion. Pollution released underneath the inversion layer will fumigate the
mixed layer. Note that if the smokestack was high enough to release the pollution within
the inversion layer, the plume would fan because the plume occurs within stable air.
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
DISPERSION MODEL
What is an atmospheric dispersion model?
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2.3 Dispersion of air pollution
DISPERSION MODEL
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
DISPERSION COEFFICIENT
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
EXAMPLE 1
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2.3 Dispersion of air pollution
S = 32
O + O = 16+16 = 32
SO2 = 32+32 = 64
EXAMPLE 1
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2.3 Dispersion of air pollution
EXAMPLE 1
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2.3 Dispersion of air pollution
EXAMPLE 1
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2.3 Dispersion of air pollution
At 3 km
EXAMPLE 1
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2.3 Dispersion of air pollution
75
EXAMPLE 1
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2.3 Dispersion of air pollution
STACK DESIGN
• Variations in stack height and pollutant exhaust velocity are considered to assess their influence
on the distribution of pollutant concentrations in the neighbourhood of the emitting building.
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
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2.3 Dispersion of air pollution
EXAMPLE 2
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2.3 Dispersion of air pollution
EXAMPLE 2
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2.3 Dispersion of air pollution
EXAMPLE 2
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2.3 Dispersion of air pollution
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2.4 Effects of air pollution
GLOBAL ISSUES
• ozone
AGRICULTURAL &
depletion
ECOSYSTEM
• greenhouse
• crop losses
effect
• eutrophication
• biodiversity
• soil
• global
acidification
warming &
dimming
HEALTH
• respiratory system
• nervous system
• cardiovascular
• allergy
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.4 Effects of air pollution
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2.5 Measurements of air pollution
Units of measurement. Air quality measurement are commonly reported in terms of:
micrograms per cubic meter (µg/m³) or parts per million (ppm).
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2.5 Measurements of air pollution
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2.5 Measurements of air pollution
EXAMPLE
A clean filter is found to weigh 10.00g. After 24 hours in a hi-vol, the filter
plus dust weighs 10.10g. The air flow at the start and end of the test is 60 and
40 ft³/min, respectively. What is the particulate concentration?
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2.5 Measurements of air pollution
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2.5 Measurements of air pollution
EXAMPLE
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2.5 Measurements of air pollution
Glass Bubbler
Gas is literally bubbled through the liquid, which either
reacts chemically with the gas of interest or into which the
gas is dissolved. Wet chemical techniques are then used to
measure the concentration of the gas.
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2.5 Measurements of air pollution
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2.5 Measurements of air pollution
Ringlemann scale
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2.6 Emission Standards and Air Quality Index
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2.6 Emission Standards and Air Quality Index
Emission Standards
• Emission standards are the legal requirements governing air pollutants
released into the atmosphere.
• Emission standards set quantitative limits on the permissible amount of
specific air pollutants that may be released from specific sources over specific
timeframes.
• They are generally designed to achieve air quality standards and to protect
human life.
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2.6 Emission Standards and Air Quality Index
Emission Standards
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2.6 Emission Standards and Air Quality Index
Emission Standards
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2.6 Emission Standards and Air Quality Index
Emission Standards
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2.7 Control infrastructure
The techniques employed to reduce or eliminate the emission into the atmosphere of
substances that can harm the environment or human health.
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2.7 Control infrastructure
centrifugal
absorber
collector
settling
incinerator
chambers
electrostatic
condenser
precipitators
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2.7 Control infrastructure
Particulate Pollutants
centrifugal collector
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2.7 Control infrastructure
Particulate Pollutants
centrifugal collector
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2.7 Control infrastructure
Particulate Pollutants
bag filter
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2.7 Control infrastructure
Particulate Pollutants
bag filter
Operating Priciple:
• Bag filters use fabric bags to remove particles
from dust-laden gas.
• They can achieve high efficiencies for fine
particles because of the build-up of particles
on either the inside or outside surface of the
bag depending on the design.
• As dust builds up, the pressure across the bag
increases, so the filters need regular cleaning.
Usually bag filters work in tandem—one filter
is working while the other filter is being
cleaned.
• Mechanical shaking, using a reverse airflow or
a pulse of compressed air are used to dislodge
the dust from the fabric surface, which then
falls by gravity into a collection system.
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2.7 Control infrastructure
Particulate Pollutants
settling chambers
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2.7 Control infrastructure
Particulate Pollutants
electrostatic
precipitators
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2.7 Control infrastructure
Gaseous Pollutants
absorber
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2.7 Control infrastructure
Gaseous Pollutants
absorber
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2.7 Control infrastructure
Gaseous Pollutants
adsorber
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2.7 Control infrastructure
Gaseous Pollutants
adsorber
Operating Priciple:
• Adsorption systems are configured either
as stationary bed units or as moving bed
units. In stationary bed adsorbers, the
polluted airstream enters from the top,
passes through a layer, or bed, of
activated carbon, and exits at the bottom.
In moving bed adsorbers, the activated
carbon moves slowly down through
channels by gravity as the air to be
cleaned passes through in a cross-flow
current.
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2.7 Control infrastructure
Gaseous Pollutants
incinerator
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2.7 Control infrastructure
Gaseous Pollutants
condenser
• Is a process used heavily throughout industry to convert a gas or vapor to liquid. Any
gas can be reduced to a liquid by sufficiently lowering the temperature (or increasing
the pressure).
• Common examples can include distillation of various hydrocarbons in refining
operations and drying of air.
• Condensation can be used to remove a pollutant from a gas stream if the dew point of
the pollutant is higher than the carrier gas (or non-pollutant gas).
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2.7 Control infrastructure
Gaseous Pollutants
condenser
• Condensers work when the warmer vapor stream contacts a cooling medium. The heat
from the warm gases is transferred to the cooler medium. Then, as the warm gas
stream begins to cool, the kinetic energy of the gas is reduced. Condensation occurs
because the pollutant molecules are slowed and crowded so close together that the
attractive forces between the molecules cause them to condense into a liquid. This
phenomenon is known as the van der Waals forces.
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