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Isaac H. Lehrer
Department of Chemical Engineering, Monash University, Victoria, Australia
Experimentally derived values of the over-all heat transfer coefficient and published
d a t a for the vessel side were used to derive a jacket-side Nusselt number. This was
compared with the Prandtl analogy relation N u = (f Re Pr)/2[1 +
4(Pr - 1)1 in
which f and 4 have empirically determined values. Published data were used for
f and the equivalent diameter. Three velocities that follow from apparatus dimensions,
flow rate, and temperature rise were combined to yield a characteristic velocity for
Re. Water was injected radially or tangentially into a vertical cylindrical jacket with
height/diometer 1. Flow rates varied from 0.12 to 0.57 Ib,/sec-sq ft of heat
transfer area. Experimentally derived and calculated results were in reasonable agreement.
The friction factor and equivalent diameter modifications, together with the characteristic
velocity, can be used also in other appropriate heat transfer equations, with similar
agreement.
Ind. Eng. Chem. Process Des. Develop., Vol. 9, No. 4, 1970 553
system was used to measure water temperature in the - 2tc
vessel. t, = ~
ZC
Cooling water flow rates between 80 and 376 lb, per
minute were used, estimated energy dissipation in the The second moment about the mean, 0 2 , is a measure
jacket ranging from 0.164/103 t o 0.032 hp per sq foot of the spread of the distribution about the mean, and
of heat transfer area. for a closed vessel (Levenspiel, 1962)
Flow measurement was by calibrated rotameter.
T o obtain some indication of flow conditions in the
jacket, pulse injections of tracer were made a t the water
inlet. Tracer concentrations were measured upstream of
this inlet and in the jacket exit branch; the concentration The jacket may be regarded as a closed vessel. The
difference between these two locations provided the input magnitude of the group ( D / u L ) is an indication of disper-
to a recorder via two conductivity meters. The tracer sion in the vessel, varying from D l u L = 0 for ideal plug
input tube restricted flow through the inlet fitting, so flow
- to D / u L = m for ideal backmixing. The ratio xf
that the highest flow rates attainable with the given equip- t may also provide an indication of dead space within
ment were lower than the highest flow rates used in heat the vessel-Le., dead space existing when Z f T < 1. Table
transfer tests. I lists some experimental observations and derived results.
The ratio f/Tfor the tangential inlet is significantly
General Calculations
less than 1.0, yet observation on an improvised transparent
The jacket-side heat transfer coefficient, h,, was obtained apparatus showed rotary motion throughout the jacket;
from known and experimentally derived values of the simple indication of dead space is not valid for the
Q = UAAT, (1) tangential case with diametrically opposite outlet. For
o', there are no significant differences a t the 95% level
l - -l _ - - d-
_ l between the two types of inlet, nor are differences due
-
h, U k h, to flow rate variation significant a t this level. Dispersion
is widespread if judged by Figure 10 (Chapter 9 of Leven-
The vessel side coefficient, h,, was estimated from the spiel, 1962).
dimensional equation
Radial Inlet
h, = 3.14 Re'"j8 for water a t 128"F, Re' = L 2 N / v ,
L = 1 2 inches (Lehrer, 1968), making adjustments for T o find a relation that predicts the heat transfer
physical properties a t the vessel temperatures during test coefficient, one has to envisage flow around a vertical
periods. jacketed cylinder of length-diameter ratio = 1, with liquid
h, values for the 16-inch paddle were deduced from entering a t a point near the bottom and leaving a t a
U values obtained for identical vessel temperatures and diametrically opposite point near the top. I n analysis
jacket water flow rates-Le., or comparison with known relations, the definition of
meaningful characteristic velocity and length is difficult.
With regard to velocity, there is not only forced convec-
tion, but also a buoyancy contribution that has increasing
significance with increasing temperature difference and
decreasing throughput.
The Martinelli-Boelter relation for combined natural
and forced convection in vertical tubes as quoted
(McAdams, 1954) may be applicable to jackets with low
The temperature difference, ATrn,was evaluated on a water throughput and high length-diameter ratios, but
log mean basis for long test intervals, and on a mean
basis for short test intervals.
Other simplifying assumptions were:
No allowance for a dirt factor was necessary in the Table I. Residence Time Distribution Data
clean stainless steel vessel and jacket. -
f , = (Ztc/
-
Heat losses to surroundings could be neglected in cal- Flow Rate, t, Zc) 1
culations. Inlet W Seconds Seconds U
With h, values of the same order of magnitude as h, Radial 5.060 13.5 12.8 0.126
values, the variation of h, with h, could be neglected. 13.0 0.066
A constant value of d h = 0.0026 (hr)(sq ft)('C)/Chu 3.133 22.3 22.1 0.062
could be used. 21.0 0.095
22.3 0.090
The nominal heat transfer area A was 11 sq feet. 1.333 51.2 46.7 0.177
Tracer Information 51.0 0.151
48.6 0.143
An indication of flow in a vessel can be obtained from Tangential 3.133 22.3 15.5 0.166
tracer information (Levenspiel, 1962). The nominal resi- 16.8 0.152
dence time in a vessel of volume V, through which a. 16.2 0.046
fluid passes at a volumetric flow rate V , is T = V / V . 15.4 0.114
1.333 51.2 34.2 0.184
The actual mean residence time of fluid leaving a vessel, 34.8 0.202
which can be established by measurement of tracer concen- 35.6 0.186
tration c a t the exit is
554 Ind. Eng. Chem. Process Des. Develop., Vol. 9, No. 4, 1970
fails t o yield the right answers for the conditions discussed UB A (gd1T)" (14)
here with respect to both magnitude and relativity.
The characteristic velocity, u, in the Reynolds group
I t was thought appropriate t o try a simple approach
thus becomes
for the turbulent case--Le., the Prandtl analogy that sup-
posed simultaneous resistance to transfer in a turbulent I: = (U,,04)05 + 1'8 (15)
zone and in a laminar sublayer. This model results in and the group itself is
the equation for smooth tubes (Grober et al., 1961)
f Re P r
Nu =
2 ( 1 + 4[Pr - 11) Values of Re based on Equation 16 with values of uti
and P r are listed in Table I11 together with the applicable
4 = 1.74 Re-' (7) test conditions. Stirrer case 1 refers to a 16-inch paddle
and the Blasius equation yields a t 150 rpm, stirrer case 2- to 12-inch paddle a t 84 rpm,
and stirrer case 3- to a 12-inch paddle a t 355 rpm.
f i 2 5 0.04 Re-' (8) A suitable friction factor can be evaluated by considering
The Reynolds group R e = d,u u can be evaluated as follows: Equation 8 together with the friction factor plot shown
For the estimation of the equivalent diameter d,, similarity in Figure 7 of Lohrenz and Kurata (1960). For the range
to flow between parallel flat plates has been assumed. of R e values met here-Le., 9000 to 40,000-the ratio
Then (Lohrenz and Kurata, 1960), de = (h/?)'" s, where
s is the perpendicular distance between parallel plates. Parallel plate friction factor
Thus in this case, + ? 4 (17)
Blasius friction factor
de = (4 3)"5 ( I 1.) f t = 0.136 f t (9) Substituting in 8
One can envisage two calculable characteristic velocities f / 2 = 0.03 Re-' (18)
pertaining to forced convection in the jacket; one is the
and substituting 18 in 6 yields
nozzle exit velocity
0.03 Reo7'Pr
Nu =
1 + @(Pr- 1)
Ind. Eng. Chem. Process Des. Develop., Vol. 9,No. 4, 1970 555
Table IV shows Nu evaluated by Equation 19, using
4 and Re as defined by 7 and 16, respectively, in juxtaposi- Table IV. Comparison of Nusselt Groups, Jacket-Side
tion to Nu values derived from experimental data-i.e., Vessel-Side
where Xu = h,>d,/k,and h, was obtained by use of Equa- Temp. Jacket Nu from Nu from Nufrom
Eq i p /
Interval, ' C Flow Rate, w Eq. 19 Experiment Nuexperimen+
tions l, 2, and 3.
Summarizing, the ratios of RADIAL
INLET
Stirrer Case 1
Nusselt number by calculation -
90-85 1.333 61.98 65.42 0.947
Nusselt number derived from experiment 90-40 1.333 56.07 55.22 1.015
45-40 1.333 45.30 55.22 0.820
x u 19 90-85 3.333 101.31 98.87 1.025
90-40 3.333 88.77 89.35 0.994
Nuexperiment 45-40 3.333 79.95 69.90 1.144
90-85 6.266 148.80 167.28 0.890
are average 1.014; minimum 0.794; maximum 1.258. For 90-40 6.266 140.79 128.52 1.095
45-40 6.266 128.22 113.15 1.133
the various vessel-side temperature intervals, the averages
are 90-85" C: 0.946; 90-40°C: 1.033; 4 5 4 0 ° C : 1.064. Stirrer Case 2
More uniform ratios could be achieved by introducing 90-85 1.333 65.10 61.60 1.057
the usual viscosity correction ( k / p & ) "1 4 , which by itself 90-40 1.333 54.75 55.22 0.991
45-40 1.333 44.85 46.24 0.970
would result in 0.968 instead of 0.946 for the 90" to 85°C 90-85 3.333 100.77 107.44 0.938
interval average and by allowing for the considerable back- 90-40 3.333 85.41 91.39 0.935
mixing in the jacket, which means actual water tem- 45-40 3.333 81.87 81.60 1.003
peratures that are higher than the mean values used in 90-85 6.266 152.13 179.38 0.848
90-40 6.266 139.71 129.34 1.080
calculation, in turn entailing physical property values that 45-40 6.266 132.81 110.57 1.201
result in relatively higher Nu values with increasing tem-
perature.
Stirrer Case 3
Tangential Inlet
90-85 1.333 60.15 75.75 0.794
Water was injected through an opening inclined approx- 90-40 1.333 55.35 55.90 0.990
imately 40" from vertical. R e was evaluated by Equation 45-40 1.333 47.01 49.64 0.947
90-85 3.333 102.33 89.62 1.142
16; however, instead of defining u 4 as a rise velocity, 90-40 3.333 95.22 84.32 1.129
the characterisiic second velocity here is the slot velocity- 45-40 3.333 89.46 71.13 1.258
Le., S in u s = V S is defined by 90-85 6.266 151.89 174.76 0.869
90-40 6.266 140.79 132.19 1.065
S = (height of annulus) (width of annulus) = 45-40 6.266 133.53 120.77 1.106
556 Ind. Eng. Chem. Process Des. Develop., Vol. 9, No. 4,1970
Table V. Forced Convection Velocities Table VII. Energy Dissipation and Over-All
Jacket Water Heat Transfer Coefficients
Flow Rate, w , Nozzle velocity, Slot Velocity, (V0V?)",
Jacket water temperatures ranged from 18" to 41° C. Representative
Lb, /Second yo, Fi/Second v.4, Ft/Second Ft/Second
averages indicated by the Prandtl numbers in Table I11 and VI.
Calculation Values
RADIAL INLET
1.333 15.67 0.1312 1.435
3.333 39.18 0.3282 3.59 U. 6.266 3.333 1.333
4.467 52.50 0.4374 4.78 Energy dissipation in jacket per sq foot of nominal heat transfer
area,
Table VI. Temperature Intervals, Flow Rates, E- ~
WL'd
E-
. ~
Leu,'
1100 g,A
90-85 4.467 80,320 5.3 0.0316 0.01314 0.00084
90-35 4.467 76,670 5.9
40-35 4.467 65,504 6.7 Over-all heat transfer coefficient U over vessel contents, tempera-
90-85 1.333 29,800 5.2 ture intervai 9 P to 35O C, derived from experiment
90-35 1.333 27,600 5.3 Stirrer case 1 196 170 121
40-35 1.333 22,558 6.7 Stirrer case 3 178 123
Stirrer Case 4 Stirrer case 4 175 157 122
Equation 19 provides a reasonable estimate of the Nus- N u = 0.026 ReosP r ' '
selt group, considering the lack of data on fluid friction
and heat transfer in curved ducts, the short length- with similar results.
Ind. Eng. Chem. Process Des. Develop., Vol. 9, No. 4, 1970 557
Nomenclature GREEKLETTERS
8 = coefficient of expansion,/OC
A = heat transfer area, sq ft A = difference
c = concentration, lb,/cu f t 0 = t t=reduced time, dimensionless
c, = specific heat a t constant pressure, Chu/lb,- p = viscosity, lb,/ft-sec
C = Btu/lb,-” F u = momentum diffusivity, sq ft/sec
D = mass or molecular diffusivity, ft’/sec $ = velocity ratio
d = thickness, ft
SUBSCRIPTS
di = jacket inner diameter, ft
d, = jacket outer diameter, ft i = vessel-side
d, = equivalent diameter, ft j = jacket-side
do = nozzle diameter, f t m = mass, mean
E = energy dissipation/ A , hpisq ft 1~ = a t wall
f = Fanning friction factor FUNCTIONS
AND DIMENSIONLESS
GROUPS
g = gravitational acceleration, ft. /secL
g, = conversion factor, lb,-ft/lbi-sec’ Nu = (hodelk)= Nusselt number
h, = vessel side heat transfer coefficient, Chuihr- uL’D = Peclet number (diffusion and mixing)
sq ft-”C = Btuihr-sq F f t - O P r = (c,l/k) = Prandtl number
h, = jacket-side heat transfer coefficient, Chu/ hr- Re = (d,v,v) = Reynolds number
sq ft-”C = Btu/hr-sq F f t - O
558 Ind. Eng. Chem. Process Des. Develop., Vol. 9, No. 4, 1970