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28. The conversion for a first order liquid phase reaction A B in a CSTR is 50%. If another CSTR of the
same volume is connected in series, then the conversion at the exit of the second reactor will be
(a) 30% (b) 60% (c) 75% (d) Approach unity
29. With increase in the order of reaction (for all positive reaction orders), the ratio of the volume of mixed
reactor to the volume of plug flow reactor (for identical feed composition, flow rate and conversion)
(a) Increases. (b) Decreases.
(c) Remain the same. (d) Approach unity
30. For the reversible reaction A↔R ( = -14130 J/mole, = -75300 J/mole, CpA=CpR=
constant). The increasing in reaction temperature from 25° C to 85° C, will causes decreasing in
equilibrium conversion (XAe) from 0.993 to :
(a) 0.892 (b) 0.791 (c) 0.648 (d) 0.481
31. It is favor to get the best product distribution for the parallel reactions that the desired product has the
highest reaction order
(a) Keep CA high. (b) Keep CA low.
(c) Use recycle for the reactor. (d) None of the above!
32. A first order reaction requires two equal sized CSTR. The conversion is
(a) Less when they are connected in series. (b) More when they are connected in series.
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Entry Exam – PhD
Chemical Engineering Department
University of Baghdad
Date 2/9/2015 (2nd Attempt) Time: 3 hrs
(c) More when they are connected in parallel. (d) Same whether they are in series or in parallel
33. If helium is introduced in a reactor containing O2, SO2, and SO3 at equilibrium, so that the total pressure
increases while volume and temperature remain constant. In this case, the dissociation of SO3 (as per Le
Chatlier principle)
(a) increases. (b) decreases.
(c) remains unaltered. (d) changes unpredictably.
34. In quantitative analysis of a certain reaction ( A R S ) the selectivity of the desired product R can
be defined as
(a) moles of R formed/reacted moles of A. (b) moles of R formed/final moles of A only.
(c) moles of R formed/initial moles of A only. (d) moles of R formed/moles of S formed.
35. Mass transfer rate between two fluid phases does not necessarily depend on the -------- of the two phases
(a) chemical properties (b) physical properties (c) degree of turbulence (d) interfacial area
36. Which of the following is more suitable for extraction in a system having very low density difference?
(a) Mixer-settler extractor. (b) Centrifugal extractor.
(c) Pulsed extractor (d) Packed extraction tower.
37. Overall efficiency of the distillation column is
(a) the ratio of the number of ideal plates to actual plates. (b) same as Murphee efficiency.
(c) The ratio of the number of actual plates to ideal plates. (d) always more than point efficiency.
38. Drying operation under vacuum is carried out to
(a) dry materials having very high unbound moisture. (b) reduce drying temperature
(c) increase drying temperature. (d) drying materials having high bound moisture
39. Relative humidity is the ratio of
(a) partial pressure of the vapor to the vapor pressure of liquid at room temperature.
(b) partial pressure of the vapor to the vapor pressure of liquid at gas temperature.
(c) Actual humidity to saturation humidity (d) None of these.
40. The mass diffusivity, the thermal diffusivity, and the eddy diffusivity are same for Pr = Sc = ------.
(a) 1 (b) 0.5 (c) 10 (d) zero
Q.2 Answer the following questions (40%)
a. A capillary tube is 30 mm long and 1 mm diameter. The head required to produce a flow rate of 8
mm3/s is 30 mm. The fluid density is 800 kg/m3. Calculate the dynamic and kinematic viscosity of the
oil. Hint: Poiseuille‟s equation is: P 32Lu / D 2
Page 4 of 5
Entry Exam – PhD
Chemical Engineering Department
University of Baghdad
Date 2/9/2015 (2nd Attempt) Time: 3 hrs
b. The heat loss through a firebrick furnace wall 0.2 m thick is reduced by addition of a layer of insulating
brick to the outside. What is the thickness of insulating brick necessary to reduce the heat loss to 400
W/m2? The inside furnace wall temperature is 1573K, the ambient air adjacent to the furnace exterior is
at 293K and the natural convection heat transfer coefficient at the exterior surface is given by ho =
3ΔT0.25 W/m2K, where ΔT is the temperature difference between the surface and ambient air. Thermal
conductivity of fire brick is 1.5 W/mK. Thermal conductivity of insulating brick is 0.4 W/mK.
c. Make a qualitative discussion for the irreversible first order reaction in series to describe the effect of
mixing on the product distribution.
d. Write notes on “Mass Transfer Theories”.
e. A fluid is flowing through a tube (assume plug flow) as shown in the figure. Perform the material
balance for the flow to find the dynamic equation of the flow through the tube.
f. Find the Laplace transform for the functions e 3t cos 4t and the inverse of Laplace transform of the
1
function
s
s2 4
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