THERMODYNAMICS CHEMICAL

WORKSHOP 2

MARIA JOSE CUEVAS SAUMET y LAURA ANDREA HOYOS BELTRAN

CHEMICAL ENGINEERING PROGRAM

UNIVERSIDAD DEL ATLANTICO

Exercise 1. Make the following binary phase diagrams for the benzene-toluene system a:

a) Constant temperature of 80 ° C.

b) Constant pressure of 101.325 KPa.

c) Constant pressure of 60.8 KPa and 188 KPa and compare the effect of pressure on
the phase diagram. It is suggested to put all three diagrams on one graph.

In Antoine's equation, pressure and temperature are expressed in mmHg and K

respectively, the constants of this equation are:

Substance Antonie's
Parameters
TO B C

Benze 15,900 2788. -52.36

ne 8 51

Toluen 16.013 3,096. -53.67

e 7 52

SOLUTION.

A.

T 80 °C

n Substances A B C Psat (Pka)

1 Benzene 15,9008 2788,51 -52,36 1,2333E-37
2 Toluene 16,0137 3096,52 -53,67 7,58199E-45
 TABLE 1

X1 X2 P(kPa) Y1 Y2
0 1 7,58199E-45 0 1
0,1 0,9 1,2333E-38 0,999999447 5,53297E-07
0,2 0,8 2,46659E-38 0,999999754 2,4591E-07
0,3 0,7 3,69989E-38 0,999999857 1,43447E-07
0,4 0,6 4,93318E-38 0,999999908 9,22162E-08
0,5 0,5 6,16648E-38 0,999999939 6,14774E-08
0,6 0,4 7,39978E-38 0,999999959 4,0985E-08
0,7 0,3 8,63307E-38 0,999999974 2,63475E-08
0,8 0,2 9,86637E-38 0,999999985 1,53694E-08
0,9 0,1 1,10997E-37 0,999999993 6,83083E-09
1 0 1,2333E-37 1 0

GRAPH 1

T CONSTANT

0
0
0
px1
0
Pa(KPa)

py1
0
0
0
0
0 0.2 0.4 0.6 0.8 1 1.2
x, y solute

B.