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Calculate the molar volume of saturated liquid and the molar volume of saturated vapour by redlich kwong

Equation for one of the following

A. Propane at 40 C P sat = 13,71 bar

T = 40 C = 313,15 K
P sat = 13,71 bar
R = 83,14 cm3 bar/mol K
ῳ = 0,152
Tc = 369,8 K
Pc = 42,48 bar

The Redlich/Kwong Equation

Dimana,
β = 0,08664 0,3227401 ɛ = 0
0,8468091
ȏ = 1
= 0,0330207

q = 0,42748 0,5904519
0,8468091 0,08664

= 3,4403002

For Saturated Vapour,


Z Zn+1 Abs
1 0,9195435 0,0804565
0,9195435 0,9286943 -0,009151 Goalseek
0,9286943 0,9276534 0,0010409
0,9276534 0,9277718 -0,000118 Z 0,9277592
0,9277718 0,9277584 1,347E-05 Zn+1 0,9277598
0,9277584 0,9277599 -1,53E-06 Error -6,06E-07
0,9277599 0,9277597 1,742E-07
0,9277597 0,9277597 -1,98E-08
0,9277597 0,9277597 2,254E-09

V = Z R T
P

= 0,9277592 83,14 313,15


13,71
= 1761,8148 cm3/mol

For Saturated Liquid

Z Zn+1 Abs
1 0,3332912 0,6667088
0,3332912 0,7850291 -0,451738 Goalseek
0,7850291 0,9439983 -0,158969
0,9439983 0,9259127 0,0180856 Z 0,9178844
0,9259127 0,9279698 -0,002057 Zn+1 0,917637
0,9279698 0,9277358 0,000234 Error 0,0002474
0,9277358 0,9277624 -2,66E-05
0,9277624 0,9277594 3,027E-06
0,9277594 0,9277598 -3,44E-07
0,9277598 0,9277597 3,917E-08
0,9277597 0,9277597 -4,46E-09
0,9277597 0,9277597 5,067E-10
0,9277597 0,9277597 -5,76E-11

V = Z R T
P
= 0,9178844 83,14 83,14
313,15
= 20,260755 cm3/mol

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