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  • Calculating concentration and KSP from silver nitrate and potassium chloride reaction

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    Hafidh Putra
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    Kimia Medisinal

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    Perhitungan Uji Kelarutan

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    Kimia Medisinal

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    © All Rights Reserved
    Download as RTF, PDF, TXT or read online from Scribd
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    16 views6 pages

    Calculating concentration and KSP from silver nitrate and potassium chloride reaction

    Uploaded by

    Hafidh Putra
    Kimia Medisinal

    Copyright:

    © All Rights Reserved
    Download as RTF, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 6

    I.

    1 Perhitungan
    I.1.1 Pembuatan KOH 0,1 N 120 ml
    gram 1000
    N= x xe
    MR ml

    gram 1000
    0,1 = x x1
    56 120

    Massa = 0,672 gram

    I.1.2 Pembuatan AgNO3 0,075 N 30ml

    gram 1000
    N= x xe
    MR ml

    gram 1000
    0,075 = x x1
    170 30

    Massa= 0,3825 gram

    I.1.3 Pembuatan KCl 0,1 N 10ml

    gram 1000
    N= x xe
    MR ml

    gram 1000
    0,1 = x x1
    74,5 10

    Massa= 0,0745 gram

    I.1.4 Pembuatan Asam Oksalat 100 mg, 50 ml

    gram 1000
    N= x xe
    MR ml

    0,1 1000
    N= x x2
    126,07 50
    N= 0,0317

    I.1.5 Indikator PP 0,1%

    gram
    0,1% =
    100 ml

    Gram = 0,1% x 100 ml

    = 0,1 gram

    I.1.6 Pembakuan KOH dengan Asam Oksalat

    N1 x V1 x e = N2 x V2 x e

    0,0317 x 50 x 1= N2 x 20 x 1

    N2 =0,079 ≈ 0,08 N

    I.1.7 Perhtiungan Pengaruh Suhu Terhadap Larutan

    a. Suhu 10 ℃

    NKOH x VKOH x e = NAB x VAB x e

    0,08 x 5 = N2 x 25

    N2 = 0,016

    b. Suhu 20 ℃

    NKOH x VKOH x e = NAB x VAB x e

    0,08 x 5,4 = N2 x 25

    N2= 0,017

    c. Suhu 30 ℃

    NKOH x VKOH x e = NAB x VAB x e


    0,08 x 5,6 = N2 x 25

    ` N2 =0,018

    d. Suhu 40 ℃

    NKOH x VKOH x e = NAB x VAB x e

    0,08 x 5,7 = N2 x 25

    N2 =0,018

    e. Suhu 50 ℃

    NKOH x VKOH x e = NAB x VAB x e

    0,08 X 5,9 = N2 x 25

    N2 =0,019

    f. Suhu 60 ℃

    NKOH x VKOH x e = NAB x VAB x e

    0,08 x 6,1 = N2 x 25

    N2 =0,0195

    I.1.8 Perhitungan KSP

    a. Beaker 1( KCl 1ml)

    N XV 0,075 x 5
    [Ag+] = = = 0,0234
    Vtot 16

    N XV 0,1 x 1
    [Cl-] = = = 0,00625
    Vtot 16

    KSP = [Ag+] x [Cl-]


    = 0,0234 x 0,00625

    = 1,4625. 10-4

    b. Beaker 2 (KCl 1,2 ml)

    N XV 0,075 x 5
    [Ag+] = = = 0,0231
    Vtot 16,2

    N XV 0,1 x 1,2
    [Cl-] = = = 0,0074
    Vtot 16,2

    KSP = [Ag+] x [Cl-]

    = 0,0231 x 0,0074

    = 1,7094. 10-4

    c. Beaker 3 ( KCl 1,4 ml)

    N XV 0,075 x 5
    [Ag+] = = = 0,0228
    Vtot 16,4

    N XV 0,1 x 1,4
    [Cl-] = = = 0,00853
    Vtot 16,4

    KSP = [Ag+] x [Cl-]

    =0,0228 x 0,00853

    = 1,94484. 10-4

    d. Beaker 4 (KCl 1,6 ml)

    N XV 0,075 x 5
    [Ag+] = = = 0,0225
    Vtot 16,6

    N XV 0,1 x 1,6
    [Cl-] = = = 0,00963
    Vtot 16,6
    KSP = [Ag+] x [Cl-]

    =0,0225 x 0,00963

    = 2,16675. 10-4

    e. Beaker 5(KCl 1,8 ml)

    N XV 0,075 x 5
    [Ag+] = = = 0,0223
    Vtot 16,8

    N XV 0,1 x 1,8
    [Cl-] = = = 0,0107
    Vtot 16,8

    KSP = [Ag+] x [Cl-]

    = 0,0223 x 0,0107

    = 2,386. 10-4
    3.2.9. Menghitung log Ksp
    a. Beaker 1 : log 1,425.10-4
    : -3,835
    b. Beaker 2 : log 1,7098.10-4
    : -3,767
    c. Beaker 3 : log 1,94484.10-4
    : -3,711
    d. Beaker 4 : log 2,16675.10-4
    : 3,664
    e. Beaker 5 : log 2,386.10-4
    : -3,622

    1
    3.9.10. (KCl 0,1 N)
    V
    1
    a. V1 :
    V1
    1
    : :1
    1
    1
    b. V2 :
    V2
    1
    : : 0,833
    1,2
    1
    c. V3 :
    V3
    1
    : : 0,714
    1,4
    1
    d. V4 :
    V4
    1
    : : 0,625
    1,6
    1
    e. V5 :
    V5
    1
    : : 0,556
    1,8

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