Lembar Perhitungan Reagen

1. Perhitungan NaOH 0,125 N 300 ml

gr 1000
x eq
N= BM x V x 98%

gr 1000
x1
0,125 = 40 x 300 x 98%

Gr = 1,53 gram NaOH

2. Densitas Minyak Jarak

M 2M 1
= 25
46,330 gr 21,51 gr
= 25 = 0,9928 g/ml

3. Densitas Katalis (HCl)

M 2M 1
= 25
43,763 gr 15,269 gr
= 25 = 1,13976 g/ml

4. Volume HCl
N x V basis x BM
VHCl = x e x

0,125 N x 0,27 ml x 36,5 gr /mol

VHCl = 25 x 1 x 1,13976 gr /ml

VHCl = 4,3233 ml
5. Perhitungan variabel 1 (Mol mj : Mol aq = 1 : 8)
mj x V mj aq x V aq 1
( ) : ( ) =
BM BM 8
0,9928 gr /ml x V mj 1 x V aq 1
( ) : ( ) =
1067 18 8

( 9,3046 x 104 ) Vmj 1

0,055Vaq = 8

Vmj = 7,3888 Vaq

VBasis = Vmj + Vaq + Vemulsifier + VHCl

270 = Vmj + Vaq + 15 + 4,3233
Vmj + Vaq = 250,6767
 7,3888 Vaq + Vaq = 250,6767
Vaq = 29,8016 ml
Vmj = 220 ml
6. Perhitungan variabel 2 (Mol mj : Mol aq = 1 : 9)
( 9,3046 x 104 ) Vmj 1
0,055Vaq = 9

Vmj = 6,5678 Vaq

Vmj + Vaq = 250,6767
(7,3888+1) Vaq = 250,6767
Vaq = 33,124 ml
Vmj = 217,55 ml
7. Perhitungan variabel 3 (Mol mj : Mol aq = 1 : 10)
( 9,3046 x 104 ) Vmj 1
0,055Vaq = 10

Vmj = 5,911 Vaq

Vmj + Vaq = 250,6767
(5,911+1) Vaq = 250,6767
Vaq = 36,27 ml
Vmj = 214,4067 ml
 LEMBAR PERHITUNGAN

1. Analisis Kadar Asam Lemak dalam Minyak

( VxN ) NaOH x BM
x 100
% kadar asam lemak = ( x V ) MJ

( 9,3 ml x 0,125 N ) x 1067 g /mol

x 100
gr
=
(
0,9928
ml
x 10 ml )
= 12,5 %

% gliserida = 100% - %kadar asam lemak

= 100% - 12,5% = 87,5%

2. Perhitungan Asam Lemak Awal

( V x N ) NaOH 9,3 ml x 0,125 N

CAo Asam lemak = ( x V ) MJ = 0,9928 gr /ml x 10 ml
mol asam lemak
= 0,117 /gr mj
gliserida
Gliserida = %asam lemak x CAo

87,5
mol asam lemak
= 12,5 x 0,117 /gr mj
mol gliserida
= 0,819 /gr mj
3. Perhitungan setelah Hidrolisa
( V x N ) NaOH V ml x 0,125 N
CA Asam lemak = ( x V ) MJ = 0,9928 gr /ml x 10 ml
mol asam lemak
= 0,0125V /gr mj
CAs = CA CAo
= 0,0125V 0,117
4. Perhitungan Nilai Konstanta Reaksi
 dC B
dt = k.CB
CB t
dC B

dt =k dt
C B0 0

CB
ln = k.t
CB0

C B 0 (1 X A )
ln = k.t
C Bo

ln ( 1X A )=k .t

y=mx

5. Menghitung Konversi (XA)

C A C As ( 0,0125 V 0,117 )
X A= =
MolGliserida 0,819 mol

6. Hasil Percobaan
a. Variabel 1 (Mol mj : Mol aq = 1 : 8)

t (Menit) V NaOH CA CAs XA 1 - XA

(ml) (Terhidrolisa) (Terbentuk)
0 24 0 0 0 0
5 25 0,3125 0,1955 0,079569 0,92043142
10 27 0,3375 0,2205 0,089744 0,91025641
15 29 0,3625 0,2455 0,099919 0,9000814

Variabel 1
0.12
f(x) = 0.01x
0.1 R = 0.92

0.08 LN(1-XA)
Linear (LN(1-XA))
0.06

0.04

0.02

0
0 2 4 6 8 10 12 14 16

b. Variabel 2 (Mol mj : Mol aq = 1 : 9)

t (Menit) V NaOH CA CAs XA 1 - XA
(ml) (Terhidrolisa) (Terbentuk)
0 19 0 0 0 0
5 20,2 0,2525 0,1355 0,055149 0,944851
10 21 0,2625 0,1455 0,059219 0,940781
15 25 0,3125 0,1955 0,079569 0,920431

Variabel 2
0.09
f(x) = 0.01x
0.08
R = 0.94
0.07
0.06 LN(1-XA)
0.05 Linear (LN(1-XA))
0.04
0.03
0.02
0.01
0
0 2 4 6 8 10 12 14 16

c. Variabel 3 (Mol mj : Mol aq = 1 : 10)

t (Menit) V NaOH CA CAs XA 1 - XA

(ml) (Terhidrolisa) (Terbentuk)
0 17,5 0,21875 0 0 1
5 18 0,225 0,108 0,043956 0,956044
10 18,4 0,23 0,113 0,045991 0,954009
15 18,5 0,23125 0,1142 0,046479 0,953521

Variabel 3
0.05
f(x) = 0x
R = 0.87
0.04

LN(1-XA)
0.03
Linear (LN(1-XA))
0.02

0.01

0
0 2 4 6 8 10 12 14 16
7. Perhitungan Kesetimbangan Reaksi
XA
K = XA1

a. Variabel 1
0,099919
K = 0,0,0999191 = 0,111

b. Variabel 2
0,079569
K = 0,0795691 = 0,0864
c. Variabel 3
0,046479
K = 0,0464791 = 0,0487